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Ground-Water Resources in the Black Hills Area, South Dakota

The availability of ground-water resources in the Black Hills area is influenced by many factors including location, local recharge and ground-water flow conditions, and structural features. Thus, the availability of ground water can be extremely variable throughout the Black Hills area, and even when water is available, it may not be suitable for various uses depending on the water quality. The major bedrock aquifers in the Black Hills area are the Deadwood, Madison, Minnelusa, Minnekahta, and Inyan Kara aquifers. Minor bedrock aquifers occur in other hydrogeologic units, including confining units, due to fracturing and interbedded permeable layers. Various information and maps are presented in this report that describe availability and quality of ground-water resources in the Black Hills area. However, there is no guarantee of obtaining usable water at any location due to the extreme potential variability in conditions that can affect the availability and quality of ground water in the area. Maps presented in this report include the distribution of hydrogeologic units; depth to the top of the five formations that contain major aquifers; thickness of the five formations that contain major aquifers; potentiometric maps for the five major aquifers; saturated thickness of the Madison and Minnelusa aquifers; water temperature in the Madison aquifer; specific conductance in the Madison, Minnelusa, and Inyan Kara aquifers; hardness in the Inyan Kara aquifer; sulfate concentrations in the Minnelusa aquifer; and radon concentrations in the Deadwood aquifer. Water quality of the major aquifers generally is very good in and near outcrop areas but deteriorates progressively with distance from the outcrops. In the Minnelusa aquifer, an abrupt increase in concentrations of dissolved sulfate occurs downgradient from outcrop areas, where a zone of active anhydrite dissolution occurs. Most limitations for the use of ground water are related to aesthetic qualities associated with hardness and high concentrations of chloride, sulfate, sodium, manganese, and iron. Very few health-related limitations exist for ground water; most limitations are for radionuclides, such as radon and uranium. In addition, high concentrations of arsenic have been measured in a few samples from the Minnelusa aquifer.

Water-Resources Investigations Report↗

Effects of ground-water chemistry and flow on quality of drainflow in the western San Joaquin Valley, California

Chemical and geohydrologic data were used to assess the effects of regional ground-water flow on the quality of on-farm drainflows in a part of the western San Joaquin Valley, California. Shallow ground water beneath farm fields has been enriched in stable isotopes and salts by partial evaporation from the shallow water table and is being displaced by irrigation, drainage, and regional ground-water flow. Ground-water flow is primarily downward in the study area but can flow upward in some down- slope areas. Transitional areas exist between the downward and upward flow zones, where ground water can move substantial horizontal distances (0.3 to 3.6 kilometers) and can require 10 to 90 years to reach the downslope drainage systems. Simulation of ground-water flow to drainage systems indicates that regional ground water contributes to about 11 percent of annual drainflow. Selenium concentrations in ground water and drainwater are affected by geologic source materials, partial evaporation from a shallow water table, drainage-system, and regional ground-water flow. Temporal variability in drainflow quality is affected in part by the distribution of chemical constituents in ground water and the flow paths to the drainage systems. The mass flux of selenium in drainflows, or load, generally is proportional to flow, and reductions in drainflow quantity should reduce selenium loads over the short-term. Uncertain changes in the distribution of ground-water quality make future changes in drainflow quality difficult to quantify.

Open-File Report↗

Rock-Bound Arsenic Influences Ground Water and Sediment Chemistry Throughout New England

The information in this report was presented at the Northeastern Region Geological Society of America meeting held March 11-14, 2007, in Durham, New Hampshire. In the New England crystalline bedrock aquifer, concentrations of arsenic that exceed the drinking water standard of 10 ?g/L occur most frequently in ground water from wells sited in specific metamorphic and igneous rock units. Geochemical investigations indicate that these geologic units typically have moderately elevated whole-rock concentrations of arsenic compared to other rocks in the region. The distribution of ground water wells with As > 5 ?g/L has a strong spatial correlation with specific bedrock units where average whole-rock concentrations of arsenic exceed 1.1 mg/kg and where geologic and geochemical factors produce high pH ground water. Arsenic concentrations in stream sediments collected from small drainages reflect the regional distribution of this natural arsenic source and have a strong correlation with both rock chemistry and the distribution of bedrock units with elevated arsenic chemistry. The distribution of ground water wells with As > 5 ?g/L has a strong spatial correlation with the distribution of stream sediments where concentrations of arsenic exceed 6 mg/kg. Stream sediment chemistry also has a weak correlation with the distribution of agricultural lands where arsenical pesticides were used on apple, blueberry, and potato crops. Elevated arsenic concentrations in bedrock wells, however, do not correlate with agricultural areas where arsenical pesticides were used. These results indicate that both stream sediment chemistry and the solubility and mobility of arsenic in ground water in bedrock are influenced by host-rock arsenic concentrations. Stream sediment chemistry and the distribution of geologic units have been found to be useful parameters to predict the areas of greatest concern for elevated arsenic in ground water and to estimate the likely levels of human exposure to elevated arsenic in drinking water in New England. However, the extreme local variability of arsenic concentrations in ground water from these rock sources indicate that arsenic concentrations in ground water are affected by other factors in addition to arsenic concentrations in rock.

Open-File Report↗

Ground-water quality data in the San Francisco Bay study unit, 2007: Results from the California GAMA Program

Ground-water quality in the approximately 620-square-mile San Francisco Bay study unit (SFBAY) was investigated from April through June 2007 as part of the Priority Basin project of the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of raw ground-water quality, as well as a statistically consistent basis for comparing water quality throughout California. Samples in SFBAY were collected from 79 wells in San Francisco, San Mateo, Santa Clara, Alameda, and Contra Costa Counties. Forty-three of the wells sampled were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells). Thirty-six wells were sampled to aid in evaluation of specific water-quality issues (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater-indicator compounds), constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]), naturally occurring inorganic constituents (nutrients, major and minor ions, trace elements, chloride and bromide isotopes, and uranium and strontium isotopes), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14 isotopes, and stable isotopes of hydrogen, oxygen, nitrogen, boron, and carbon), and dissolved noble gases (noble gases were analyzed in collaboration with Lawrence Livermore National Laboratory) also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blank samples, replicate samples, matrix spike samples) were collected for approximately one-third of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control information from the field blanks resulted in applying “V” codes to approximately 0.1 percent of the data collected for ground-water samples (meaning a constituent was detected in blanks as well as the corresponding environmental data). See the Appendix section “Quality-Control-Sample Results.” This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is delivered to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. VOCs were detected in about one-half of the grid wells, while pesticides were detected in about one-fifth of the grid wells. Concentrations of all VOCs and pesticides detected in samples from all SFBAY wells were below health-based thresholds. No pharmaceutical compounds were detected in any SFBAY well. One potential wastewater-indicator compound, caffeine, was detected in one grid well in SFBAY. Concentrations of most trace elements and nutrients detected in samples from all SFBAY wells were below health-based thresholds. Exceptions include nitrate, detected above the USEPA maximum contaminant level (MCL-US) in 3samples; arsenic, above the USEPA maximum contaminant level (MCL-US) in 3 samples; cadmium, above the MCL-US in 1 sample; boron, above the CDPH notification level (NL-CA) in 2 samples; and strontium, above the USEPA lifetime health advisory level (HAL-US) in 2 samples. The radioactive constituent radon-222 was detected above the proposed MCL-US in two grid wells, but no wells had detections above the proposed alternative MCL-US. Most of the samples from all SFBAY wells had concentrations of major ions, total dissolved solids, and trace elements below the non-enforceable thresholds set for aesthetic concerns. Six or fewer samples contained chloride, sulfate, or iron at concentrations above the SMCL-CA thresholds. No microbial indicators were detected in SFBAY grid wells.

California↗

Hydrogeology and simulated ground-water flow through the unconsolidated aquifers of northeastern St. Joseph County, Indiana

The U.S. Geological Survey investigated ground-water resources of northeastern St. Joseph County, Indiana, during 1990-93. The investigation included field measurements of water levels and numerical models of ground-water flow. This report documents results of that work and includes descriptions of (1) hydrogeologic framework, (2) water levels, (3) model sensitivity to variations in hydrogeologic parameters, (4) simulated aquifer response to increased ground-water withdrawals, (5) recharge areas for significant water- withdrawal facilities, (6) flow paths and discharge points for ground-water solutes originating beneath known contamination sites. Water-level data indicated (1) regional ground- water flow towards the St. Joseph River, (2) depth to water is small in the St. Joseph aquifer system compared to that in the Hilltop and Nappanee aquifer systems, (3) water levels in deep and shallow parts of the aquifer system are not equal where a confining unit is present. Model results indicate increasing withdrawals by 50 percent at significant water-withdrawal facilities would cause drawdowns less than 6 feet in the 1/4-square-mile area surrounding pumping sites. The response of Juday Creek and the St. Joseph River to increased ground-water pumpage is reductions of ground-water contribution to streamflow of 23 percent and 6 percent, respectively. Particle-tracking analyses indicate flow paths for solutes originating beneath known contamination sites may pass near to, or be intercepted by, significant water-withdrawal facilities. Most particles are discharged to the St. Joseph River but some may be discharged to Juday Creek.

Indiana↗

Anomalous gold, antimony, arsenic, and tungsten in ground water and alluvium around disseminated gold deposits along the Getchell Trend, Humboldt County, Nevada

Ground-water, alluvium, and bedrock samples were collected from drill holes near the Chimney Creek, Preble, Summer Camp, and Rabbit Creek disseminated gold deposits in northern Nevada to determine if Au and ore-related metals, such as As, Sb, and W, are being hydromorphically mobilized from buried mineralized rock, and, if they are, to determine whether the metal-enriched ground water is reacting with the alluvial material to produce a geochemical anomaly within the overburden. Results of chemical analyses of drill-hole water samples show the presence of hydromorphic dispersion anomalies of Au, As, Sb, and W in the local ground-water systems associated with these deposits. Background concentrations for Au in the ground water up-gradient from the buried deposits was less than 1 nanogram per liter (ng/L), near the deposits the Au values ranged from 1 to 140 ng/ L, and in drill holes penetrating mineralized rock, concentrations of Au in the ground water were as high as 4700 ng/L. Highest concentrations of Au were found in ground-water samples where the measured E h and the distribution of arsenic species, arsenite [As(III)] and arsenate [As(V)], indicated oxidizing redox potentials. Similarly, As, Sb, and W concentrations in the ground water near the deposits were significantly enriched relative to concentrations in the ground water up-gradient from the deposits. In general, however, the highest concentrations of As, Sb, and W occurred in ground-water samples where the measured E h and the distribution of arsenic species indicated reducing conditions. Arsenic concentrations ranged from 9 to 710 micrograms per liter (μg/L); Sb, from less than 0.1 to 250 μg/L; and W, from 1 to 260 μg/L. In addition, analysis of sequential dissolution and extraction solutions of drill cuttings of alluvium and bedrock indicate geochemical anomalies of gold and ore-related metals in the overburden at depths corresponding to the location of the present-day water table. This relationship suggests that water-rock reactions around these buried deposits are active and that this information could be very useful in exploration programs for concealed disseminated gold deposits.

Journal of Geochemical Exploration↗

Age, double porosity, and simple reaction modifications for the MOC3D ground-water transport model

This report documents modifications for the MOC3D ground-water transport model to simulate (a) ground-water age transport; (b) double-porosity exchange; and (c) simple but flexible retardation, decay, and zero-order growth reactions. These modifications are incorporated in MOC3D version 3.0. MOC3D simulates the transport of a single solute using the method-of-characteristics numerical procedure. The age of ground water, that is the time since recharge to the saturated zone, can be simulated using the transport model with an additional source term of unit strength, corresponding to the rate of aging. The output concentrations of the model are in this case the ages at all locations in the model. Double porosity generally refers to a separate immobile-water phase within the aquifer that does not contribute to ground-water flow but can affect solute transport through diffusive exchange. The solute mass exchange rate between the flowing water in the aquifer and the immobile-water phase is the product of the concentration difference between the two phases and a linear exchange coefficient. Conceptually, double porosity can approximate the effects of dead-end pores in a granular porous media, or matrix diffusion in a fractured-rock aquifer. Options are provided for decay and zero-order growth reactions within the immobile-water phase. The simple reaction terms here extend the original model, which included decay and retardation. With these extensions, (a) the retardation factor can vary spatially within each model layer, (b) the decay rate coefficient can vary spatially within each model layer and can be different for the dissolved and sorbed phases, and (c) a zero-order growth reaction is added that can vary spatially and can be different in the dissolved and sorbed phases. The decay and growth reaction terms also can change in time to account for changing geochemical conditions during transport. The report includes a description of the theoretical basis of the model, a detailed description of input requirements and output options, and the results of model testing and evaluation. The model tests illustrate use of these modifications and demonstrate that accurate solutions can be obtained for these simple cases. Two test cases have no dispersion, illustrating the suitability of this method-of-characteristics model for simulation of advection-dominated transport in ground water.

Water-Resources Investigations Report↗

Effects of farming systems on ground-water quality at the management systems evaluation area near Princeton, Minnesota, 1991-95

Ground-water quality in an unconfined sand and gravel aquifer was monitored during 1991-95 at the Minnesota Management Systems Evaluation Area (MSEA) near Princeton, Minnesota. The objectives of the study were to: (1) describe the effects of three farming systems on groundwater quality, and (2) evaluate the factors affecting ground-water quality and transport of agricultural chemicals at the site. Concentrations of nitrate nitrogen (nitrate-N) in the upper 1 meter (m) of the saturated zone were greatest beneath the two cropped areas having a potato-sweet corn annual rotation (median concentrations of 23 and 22 mg/L). Concentrations of nitrate-N were least beneath a cropped area having a field cornsoybean annual rotation (median of 14 mg/L); another cropped area having the field corn-soybean rotation had similar nitrate-N concentrations to those beneath a cropped area having field corn in consecutive years (continuous corn)(medians of 17 mg/L). Concentrations of atrazine plus metabolites de-ethylatrazine (DEA) and de-isopropylatrazine (DIA), atrazine plus metabolites, were significantly greater during 1994-95 than during 1992- 93 beneath all cropped areas in the upper 1 m of the saturated zone. Concentrations of atrazine plus metabolites during 1994-95 were greatest beneath the continuous corn (median of 1.07 ( μ g/L), intermediate beneath one cropped area with the potato-sweet corn rotation (median of 0.37 μ g/L), and least beneath the other cropped area with the potato-sweet corn rotation, the field corn-soybean rotation, and background areas (medians ranging from 0.11 to 0.21 μ g/L), for which concentrations were not significantly different. Concentrations of atrazine plus metabolites during 1992-93 were mostly similar beneath the different cropped areas and background areas. DEA was the predominant atrazine-metabolite detected in ground water; the average DEA to atrazine ratio was 8.0. The herbicides metribuzin, alachlor, and metolachlor were rarely detected in ground water at trace levels and could not be linked to the MSEA farming systems, with the exception of metribuzin detections during 1993-94 at concentrations of 0.14-1.24 ( μ g/L beneath one cropped area where metribuzin was applied to potatoes. Peak concentrations of chloride and bromide tracers were usually detected in the upper 2 m of the saturated zone 11 to 19 months after application. Peak concentrations of nitrate-N and atrazine plus metabolites were usually detected about 13 to 27 months and 2 years after application, respectively. The estimated proportion of applied nitrogen that reached ground water ranged from about 13 to 50 percent with an average of 30 percent. Differences in the concentrations of nitrate-N in ground water between different cropped areas were related to varying nitrogen application rates, timing of nitrogen application, timing of recharge in relation to crop rotation, and differences in nitrogen uptake by crops. In order of importance, plant uptake and leaching to ground water likely account for most of the nitrogen applied. Denitrification likely is an important mechanism affecting nitrate-N concentrations at depths greater than 2 m below the water table. The proportion of applied atrazine in ground water, detected as atrazine or its metabolites, ranged from 0 to about 1 percent with an average of 0.37 percent. The small proportion of applied atrazine detected in ground water indicates that atrazine was predominantly affected by processes occurring in the soil such as adsorption and degradation. Concentrations of atrazine plus metabolites were related to application rates.

Minnesota↗

Hydrology and simulation of ground-water flow, Lake Point, Tooele County, Utah

Water for new residential development in Lake Point, Utah may be supplied by public-supply wells completed in consolidated rock on the east side of Lake Point. Ground-water flow models were developed to help understand the effect the proposed withdrawal will have on water levels, flowing-well discharge, spring discharge, and ground-water quality in the study area. This report documents the conceptual and numerical ground-water flow models for the Lake Point area. The ground-water system in the Lake Point area receives recharge from local precipitation and irrigation, and from ground-water inflow from southwest of the area. Ground water discharges mostly to springs. Discharge also occurs to evapotranspiration, wells, and Great Salt Lake. Even though ground water discharges to Great Salt Lake, dense salt water from the lake intrudes under the less-dense ground water and forms a salt-water wedge under the valley. This salt water is responsible for some of the high dissolved-solids concentrations measured in ground water in Lake Point. A steady-state MODFLOW-2000 ground-water model of Tooele Valley adequately simulates water levels, ground-water discharge, and ground-water flow direction observed in Lake Point in 1969 and 2002. Simulating an additional 1,650 acre-feet per year withdrawal from wells causes a maximum projected drawdown of about 550 feet in consolidated rock near the simulated wells and drawdown exceeding 80 feet in an area encompassing most of the Oquirrh Mountains east of Lake Point. Drawdown in most of Lake Point ranges from 2 to 10 ft, but increases to more than 40 feet in the areas proposed for residential development. Discharge to Factory Springs, flowing wells, evapotranspiration, and Great Salt Lake is decreased by about 1,100 acre-feet per year (23 percent). The U.S. Geological Survey SUTRA variable-density ground-water-flow model generates a reasonable approximation of 2002 dissolved-solids concentration when simulating 2002 withdrawals. At most locations with measured dissolved-solids concentration in excess of 1,000 milligrams per liter, the model simulates salt-water intrusion with similar concentrations. Simulating an additional 1,650 acre-feet per year withdrawal increased simulated dissolved-solids concentration by 200 to 1,000 milligrams per liter throughout much of Lake Point and near Fac­tory Springs at a depth of about 250 to 300 feet below land surface. The increase in dissolved-solids concentration with increased withdrawals is greater at a depth of about 700 to 800 feet and exceeds 1,000 milligrams per liter throughout most of Lake Point. At the north end of Lake Point, increases exceed 10,000 milligrams per liter.

Utah↗

Water-quality assessment of part of the upper Mississippi River Basin, Minnesota and Wisconsin — Nitrogen and phosphorus in streams, streambed sediment, and ground water, 1971-94

Nitrogen and phosphorus in streams, streambed sediment, and ground water were summarized using data from Federal, state, and local agencies as part of an analysis of historical water-quality data for the Upper Mississippi River Basin study unit of the U.S. Geological Survey's National Water-Quality Assessment Program. The Upper Mississippi River Basin study unit encompasses the drainage of the Mississippi River from the source to the outlet of Lake Pepin. This report focuses on a 19,500-square-mile study area in the eastern part of the study unit. The study area included the part of the Upper Mississippi River Basin from Royalton, Minnesota, to the outlet of Lake Pepin, located near Red Wing, Minnesota; the Minnesota River Basin from Jordan, Minnesota, to the confluence with the Mississippi River; and the entire drainage basins of the St. Croix, Cannon, and Vermillion Rivers. The Twin Cities metropolitan area, with a population of approximately 2.3 million people, is located in the south-central part of the study area. Fertilizers and livestock manure were the greatest sources of nitrogen and phosphorus applied to the land surface of the study unit. Approximately 60 percent of the fertilizer was applied to the Minnesota River Basin, which drains agricultural areas in the southern and western parts of the study unit. Concentrations of total nitrite plus nitrate nitrogen, total nitrogen, and total phosphorus in streams, generally were greatest in the tributaries to the Mississippi River draining agricultural areas in the western and southern part of the study area. Concentrations of these constituents generally were least in tributaries draining forested land. The greatest total nitrite plus nitrate nitrogen concentrations generally occurred during the spring and summer in streams draining agricultural areas and in the winter in streams draining forested areas. Total phosphorus concentrations generally were greatest in the spring and summer for all streams. Total nitrite plus nitrate nitrogen, total nitrogen, and total phosphorus concentrations in the Mississippi River increased substantially downstream from the Minnesota River and downstream from wastewater discharges in the Twin Cities metropolitan area. Total ammonia and dissolved orthophosphate concentrations generally were greatest at sites on the Mississippi and Minnesota Rivers downstream from wastewater discharges from the Twin Cities metropolitan area. Total nitrite plus nitrate nitrogen concentrations in streams generally were less than the Maximum Contaminant Level of 10 mg/L (as nitrogen) established by the U.S. Environmental Protection Agency. Total phosphorus concentrations in streams generally were greater than the 0.1 mg/L concentration recommended by the U.S. Environmental Protection Agency at sites located in agricultural areas and on the Mississippi River downstream from its confluence with the Minnesota River. Phosphorus and nitrogen yields were greatest in watersheds primarily draining agricultural land. The majority of the nitrogen and phosphorus loading to the Mississippi River was from the Minnesota River. In the Minnesota River, the nitrogen load primarily was total nitrite plus nitrate nitrogen. Despite increases in fertilizer usage during 1982-91, most stream sites outside of the Twin Cities metropolitan area had no temporal trends in total nitrite plus nitrate nitrogen, total phosphorus, or dissolved orthophosphate concentrations for water years 1984-93. Most sites had a decrease in total ammonia nitrogen concentrations, possibly a result of improvements in wastewater treatment. In the Twin Cities metropolitan area, decreases in total ammonia concentrations in the Mississippi and Minnesota Rivers coincided with increases in total nitrite plus nitrate nitrogen concentrations, probably a result of wastewater treatment plants initiating nitrification processes. Nitrite plus nitrate nitrogen concentrations in ground water reflect land uses and hydrogeologic settings of major aquifers in the study area. Unconfined sand and gravel, buried sand and gravel, and the Prairie du Chien-Jordan were the aquifers most frequently sampled for nitrite plus nitrate nitrogen because they are the principal sources of ground water in the study area. The greatest nitrite plus nitrate nitrogen concentrations reported by Federal and state agencies, some exceeding the U.S. Environmental Protection Agency's Maximum Contaminant level of 10 mg/L by a factor of four, were in water from shallow wells in agricultural and mixed forested and agricultural areas. Water sampled from buried sand and gravel aquifers, which are more shielded from substances leaching from the land surface by layers of clay or till, generally had lower nitrite plus nitrate nitrogen concentrations than water from unconfined sand and gravel aquifers. Nitrite plus nitrate nitrogen concentrations in water samples from the Prairie du Chien-Jordan aquifer were greatest in the Wisconsin part of the study area and in the vicinity of the Cannon River, where the aquifer is commonly unconfined, exposed at land surface, and overlain by agricultural or by mixed forested and agricultural land covers. Dissolved phosphorus concentrations in ground water in the study area generally were near detection limits of 0.01 mg/L or lower, indicating that surface-water eutrophication from phosphorus may be more likely to occur from overland runoff of phosphorus compounds and from direct discharges of treated wastewater than from ground-water base flow. The greatest concentrations of dissolved phosphorus in ground water generally were detected in water samples from wells in urban portions of the study area.

Minnesota, Wisconsin↗

Analysis of ground-water flow along a regional flow path of the Midwestern Basins and Arches aquifer system in Ohio

A cross-sectional analysis of ground-water flow in central-western and northwestern Ohio was done as part of the Midwestern Basins and Arches Regional Aquifer-System Analysis project. The Midwestern Basins and Arches aquifer system is composed of carbonate bedrock of Silurian and Devonian age and overlying glacial flow analysis of the Scioto and Blanchard rivers in the study area were used to describe patrems of ground-water flow, to evaluate stream-aquifer interaction, and to quantify recharge and discharge within the ground-water-flow system along a regional ground-water-flow path. The selected regional flow path begins at a regional topographic high in Logan County, Ohio, and ends in Sandusky Bay (Lake Erie), a regional topographic low. Recharge to the ground-water system along the selected regional flow path was estimated from hydrograph separation of streamflow and averaged 3.24 inches per year. Computer model simulations indicate that 84 percent of the water entering the ground-water system flows less than 5 miles from point of recharge to point of discharge and no deeper than the upper surficial aquifers. The distance and depth that ground water travels and traveltime from point of recharge to point of discharge is controlled largely by where ground water enters the flow system. Ground water entering the flow system in the vicinity of major surface- water divides generally travels further, deeper, and longer than ground water entering the flow system elsewhere along the regional flow path. Particle tracking simulations substantiate the concept that the 80-mile-long regional flow path is within a continuous ground-water basin. Estimated traveltimes for ground-water from the regional high to Sandusky Bay range from 22,000 to 40,700 years, given a range of porosities from 8 to 22 percent for the carbonate-rock aquifer.

Ohio↗

Chemical quality of ground water in Yolo and Solano counties, California

Ground-water-quality conditions were investigated in Yolo and Solano Counties during the summers of 1980 and 1981 by sampling 188 representative wells. Chemical analyses of the water samples show that the ground water is suitable for domestic and most agricultural purposes. Water samples from wells near the Sacramento River generally contained lower concentrations of dissolved solids and higher concentrations of trace elements than the rest of the study area. Ninety percent of the water sampled had a dissolved-solids concentration of less than 850 milligrams per liter. Chemical water types varied, with 72 percent of the wells sampled containing either sodium bicarbonate, magnesium bicarbonate, sodium-magnesium bicarbonate , or magnesium-sodium bicarbonate type water. A large part of the study area contains ground water with boron concentrations that exceed tolerance levels for many crops. Other toxic trace elements were present in negligible amounts. (USGS)

Water-Resources Investigations Report↗

Well-response model of the confined area, Bunker Hill ground-water basin, San Bernardino County, California

The Bunker Hill ground-water basin, in the vicinity of San Bernardino, Calif., is being artificially recharged with imported water. Current and future artificial recharge of the basin may cause the potentiometric surface in an area of confined ground water to rise above land surface and water to flow from uncapped and unplugged wells. This could cause damage to structures where the soil becomes waterlogged and where buried wells begin to flow beneath the structures. A well-response model was used to generate a series of water-level hydrographs representing the response of the ground-water basin to six possible combinations of conditions for each well; one pumping rate, two artificial-recharge rate, and three natural-recharge rates. Inflow to the ground-water basin exceeds outflow for all tested combinations. According to model predictions, the accumulation of stored ground water resulting from the excess of inflow is sufficient to cause the water level in the selected wells to rise above land surface for all but one of the combinations of conditions tested. Water levels in wells are predicted to rise above the land surface as early as 1981 for the combination with the greatest excess of inflow. (Woodard-USGS)

California↗

Predictive analyses of ground-water discharges in the Willow Creek Watershed, northeast Nebraska

Ground-water discharge to Willow Creek, which drains a 204 mi 2 watershed in northeast Nebraska was predicted for six combinations of conditions of climate and ground-water development. A digital model of the ground water/surface-water system was stressed with recharge and withdrawal functions determined from a linear reservoir model of the soil zone. The geohydrologic system includes a regional aquifer which containssand and gravel ranging in age from Pliocene through Pleistocene. The regional aquifer is unconfined in the western part of the watershed and confined in the eastern part. The confining layer, or blue clay, in the east is of Pleistocene age and comprises principally saturated eolian silts with very fine sand interbeds overlying a basal lacustrine clay. Where unconfined conditions exist in the regional aquifer, perennial flow of Willow Creek is sustained principally by ground-water discharge. Where confined conditions exist, the low hydraulic conductivity of the blue clay effectively isolates the regional aquifer from Willow Creek. The stream-aquifer models were tested by comparing simulated against measured water levels and streamflow during 1975 and 1976. Agreement between simulated and observed values was obtained by modifying initial estimates of aquifer hydraulic conductivity and specific storage. Future ground-water discharge to Willow Creek (base flow) was simulated by super-imposing different patterns of ground-water withdrawals upon variations from average recharge for a monthly climatic sequence identical with the period 1931 to 1954. Frequency analyses of the simulated monthly base flows showed that they would be less than 12 feet 3 per second at least 50 percent of the time under all but completely undeveloped conditions. Simulated water-level declines in the regional aquifer at the end of the pumping season after a drought period similar to that of the 1930's were less than 5 feet where unconfined conditions exist and were more than 80 feet where confined conditions exist.

Nebraska↗

The outlook for ground-water resources in Texas

The future of ground-water supplies in Texas presents a problem that is very important to the economy of Texas and to the well-being of almost every citizen of the state. It is of particular importance to more than 580 municipalities using ground water as the sole source of water supply; to many thousands of farmers using ground water for irrigation and also to others living in irrigated areas or dependent on irrigated agriculture for their livelihood, to more than 2 million people living in rural areas who are dependent on ground water for domestic supply, and to a large number of industries throughout the State, including some o the biggest ones.

Texas↗

Historical water-quality data for the High Plains Regional Ground-Water Study Area in Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming, 1930-98

The High Plains aquifer underlies 174,000 square miles in parts of eight States and includes eight primary hydrogeologic units, including the well-known Ogallala Formation. The High Plains aquifer is an important resource, providing water for 27 percent of the Nation?s irrigated agricultural lands in an otherwise dry landscape. Since the 1980?s there has been concern over the sustainability of the aquifer due to water-level declines caused by substantial pumping. Water quality of the aquifer is a more recent concern. As part of the U.S. Geological Survey?s National Water-Quality Assessment Program, historical water-quality data have been gathered for the High Plains Regional Ground-Water Study Area into a retrospective data base, which can be used to evaluate the occurrence and distribution of water-quality constituents of concern.Data from the retrospective data base verify that nitrate, pesticides, and dissolved solids (salinity) are important water-quality concerns in the High Plains study area. Sixteen percent of all measured nitrate concentrations were larger than the U.S. Environmental Protection Agency drinking-water standard of 10 milligrams per liter. In about 70 percent of the counties within the High Plains study area, nitrate concentrations for 1980-98 were significantly larger than for 1930-69. While nitrate concentrations are largest where depth to water is shallow, concentrations also have increased in the Ogallala Formation where depth to water is large. Pesticide data primarily are available only in the northern half of the study area. About 50 pesticides were detected in the High Plains study area, but only four pesticides (atrazine, alachlor, cyanazine, and simazine) had concentrations exceeding a drinking-water standard. The occasional detection of pesticides in deeper parts of the Ogallala Formation indicates that contamination pathways exist. Dissolved solids, which are a direct measure of salinity, had 29 percent of measured concentrations in excess of the secondary drinking-water standard of 500 milligrams per liter. Comparison of dissolved-solids concentrations prior to 1980 to concentrations after 1980 indicates dissolved-solids concentrations have increased in the alluvial valleys of the Platte, the Republican, and the Arkansas Rivers, as well as in the Ogallala Formation?South hydrogeologic unit.Water-quality results indicate that human activities are affecting the water of the High Plains aquifer. Because there is a potential for water quality to become impaired relative to the historical uses of the aquifer, water quality needs to be considered when evaluating the sustainability of the High Plains aquifer. Data collected as part of the High Plains Regional Ground-Water Study will help to fill in gaps in water-quality information and provide additional information for understanding the factors that govern ambient water quality.

Colorado, Kansas, Nebraska, New Mexico, Oklahoma, ↗

Observation-well network for collection of ground-water level data in Massachusetts

Aquifers--water-bearing deposits of sand and gravel, glacial till, and fractured bedrock--provide an extensive and readily accessible ground-water supply in Massachusetts. Ground water affects our everyday lives, not just in terms of how much water is available, but also in terms of the position of ground-water levels in relation to land surface. Knowledge of ground-water levels is needed by Federal, State, and local agencies to help plan, manage, and protect ground-water supplies, and by private construction companies for site planning and evaluation. A primary part of the mission of the U.S. Geological Survey (USGS), Water Resources Division, is the systematic collection of ground-water, surface-water, and water-quality data. These data are needed to manage and protect the nation's water resources. The Massachusetts-Rhode Island District of the USGS, in cooperation with the Massachusetts Department of Environmental Management (DEM), Office of Water Resources, and county and town environmental agencies, has maintained a network of observation wells throughout the Commonwealth since the mid 1930's. The purpose of this network is to monitor seasonal and long-term changes in groundwater storage in different lithologic, topographic, and geographic settings. These data are analyzed to provide a monthly index of ground-water conditions to aid in water-resources management and planning, and to define long-term changes in water levels resulting from manmade stresses (such as pumping and construction-site drainage) and natural stresses (such as floods and droughts).

Massachusetts↗

Vulnerability of ground water to contamination, northern Bexar County, Texas

The Trinity aquifer, composed of Lower Cretaceous carbonate rocks, largely controls the ground-water hydrology in the study area of northern Bexar County, Texas. Discharge from the Trinity aquifer recharges the downgradient, hydraulically connected Edwards aquifer one of the most permeable and productive aquifers in the Nation and the sole source of water for more than a million people in south-central Texas. The unconfined, karstic outcrop of the Edwards aquifer makes it particularly vulnerable to contamination resulting from urbanization that is spreading rapidly northward across an "environmentally sensitive" recharge zone of the Edwards aquifer and its upgradient "catchment area," composed mostly of the less permeable Trinity aquifer. A better understanding of the Trinity aquifer is needed to evaluate water-management decisions affecting the quality of water in both the Trinity and Edwards aquifers. A study was made, therefore, in cooperation with the San Antonio Water System to assess northern Bexar County's vulnerability to ground-water contamination. The vulnerability of ground water to contamination in this area varies with the effects of five categories of natural features (hydrogeologic units, faults, caves and (or) sinkholes, slopes, and soils) that occur on the outcrop and in the shallow subcrop of the Glen Rose Limestone. Where faults affect the rates of recharge or discharge or the patterns of ground-water flow in the Glen Rose Limestone, they likewise affect the risk of water-quality degradation. Caves and sinkholes generally increase the vulnerability of ground water to contamination, especially where their occurrences are concentrated. The slope of land surface can affect the vulnerability of ground water by controlling where and how long a potential contaminant remains on the surface. Disregarding the exception of steep slopes which are assumed to have no soil cover the greater the slope, the less the risk of ground-water contamination. Because most soils in the study area are uniformly thin, they have only minimal effect on the vulnerability of ground water to contamination. The results of hydrogeologic mapping during the present study divide the outcrop of the Glen Rose Limestone into five mappable intervals, labeled (youngest to oldest) A through E. Of these intervals, only the middle (C) and the lowermost (E) generally provide appreciable permeability. The vulnerability assessment provided herein was determined by combining the presumed effects of selected natural features (with individual vulnerability ratings ranging from 0 through 35) using a grid-based, multilayer system of digital datasets and geographic information system analysis. The resulting vulnerability map comprises composite vulnerability ratings that range from 26 through 104. The relatively less vulnerable areas those containing no faults, sinkholes, or caves occupy about 92 percent of the study area. The most vulnerable areas are those containing both a fault and one or more caves. The distribution of the most vulnerable areas which trend from southwest to northeast, roughly parallel to the Balcones fault zone occur mainly where faults intersect caves.

Texas↗