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At least 955 records · Page 53Linked to original sources
USGS2015

ChemCam results from the Shaler outcrop in Gale crater, Mars

The ChemCam campaign at the fluvial sedimentary outcrop “Shaler” resulted in observations of 28 non-soil targets, 26 of which included active laser induced breakdown spectroscopy (LIBS), and all of which included Remote Micro-Imager (RMI) images. The Shaler outcrop can be divided into seven facies based on grain size, texture, color, resistance to erosion, and sedimentary structures. The ChemCam observations cover Facies 3 through 7. For all targets, the majority of the grains were below the limit of the RMI resolution, but many targets had a portion of resolvable grains coarser than ∼0.5 mm. The Shaler facies show significant scatter in LIBS spectra and compositions from point to point, but several key compositional trends are apparent, most notably in the average K 2 O content of the observed facies. Facies 3 is lower in K 2 O than the other facies and is similar in composition to the “snake,” a clastic dike that occurs lower in the Yellowknife Bay stratigraphic section. Facies 7 is enriched in K 2 O relative to the other facies and shows some compositional and textural similarities to float rocks near Yellowknife Bay. The remaining facies (4, 5, and 6) are similar in composition to the Sheepbed and Gillespie Lake members, although the Shaler facies have slightly elevated K 2 O and FeO T . Several analysis points within Shaler suggest the presence of feldspars, though these points have excess FeO T which suggests the presence of Fe oxide cement or inclusions. The majority of LIBS analyses have compositions which indicate that they are mixtures of pyroxene and feldspar. The Shaler feldspathic compositions are more alkaline than typical feldspars from shergottites, suggesting an alkaline basaltic source region, particularly for the K 2 O-enriched Facies 7. Apart from possible iron-oxide cement, there is little evidence for chemical alteration at Shaler, although calcium-sulfate veins comparable to those observed lower in the stratigraphic section are present. The differing compositions, and inferred provenances at Shaler, suggest compositionally heterogeneous terrain in the Gale crater rim and surroundings, and intermittent periods of deposition.

Icarus↗
USGS2012

Experimentally derived salinity tolerance of hatchling Burmese pythons (Python molurus bivittatus) from the Everglades, Florida (USA)

In a laboratory setting, we tested the ability of 24 non-native, wild-caught hatchling Burmese pythons (Python molurus bivittatus) collected in the Florida Everglades to survive when given water containing salt to drink. After a one-month acclimation period in the laboratory, we grouped snakes into three treatments, giving them access to water that was fresh (salinity of 0, control), brackish (salinity of 10), or full-strength sea water (salinity of 35). Hatchlings survived about one month at the highest marine salinity and about five months at the brackish-water salinity; no control animals perished during the experiment. These results are indicative of a "worst-case scenario", as in the laboratory we denied access to alternate fresh-water sources that may be accessible in the wild (e.g., through rainfall). Therefore, our results may underestimate the potential of hatchling pythons to persist in saline habitats in the wild. Because of the effect of different salinity regimes on survival, predictions of ultimate geographic expansion by non-native Burmese pythons that consider salt water as barriers to dispersal for pythons may warrant re-evaluation, especially under global climate change and associated sea-level-rise scenarios.

Florida↗
USGS2018

Computational fluid dynamics simulations of the Late Pleistocene Lake Bonneville flood

At approximately 18.0 ka, pluvial Lake Bonneville reached its maximum level. At its northeastern extent it was impounded by alluvium of the Marsh Creek Fan, which breached at some point north of Red Rock Pass (Idaho), leading to one of the largest floods on Earth. About 5320 km 3 of water was discharged into the Snake River drainage and ultimately into the Columbia River. We use a 0D model and a 2D non-linear depth-averaged hydrodynamic model to aid understanding of outflow dynamics, specifically evaluating controls on the amount of water exiting the Lake Bonneville basin exerted by the Red Rock Pass outlet lithology and geometry as well as those imposed by the internal lake geometry of the Bonneville basin. These models are based on field evidence of prominent lake levels, hypsometry and terrain elevations corrected for post-flood isostatic deformation of the lake basin, as well as reconstructions of the topography at the outlet for both the initial and final stages of the flood. Internal flow dynamics in the northern Lake Bonneville basin during the flood were affected by the narrow passages separating the Cache Valley from the main body of Lake Bonneville. This constriction imposed a water-level drop of up to 2.7 m at the time of peak-flow conditions and likely reduced the peak discharge at the lake outlet by about 6%. The modeled peak outlet flow is 0.85·10 6 m 3 s −1 . Energy balance calculations give an estimate for the erodibility coefficient for the alluvial Marsh Creek divide of ∼0.005 m y −1 Pa −1.5 , at least two orders of magnitude greater than for the underlying bedrock at the outlet. Computing quasi steady-state water flows, water elevations, water currents and shear stresses as a function of the water-level drop in the lake and for the sequential stages of erosion in the outlet gives estimates of the incision rates and an estimate of the outflow hydrograph during the Bonneville Flood: About 18 days would have been required for the outflow to grow from 10% to 100% of its peak value. At the time of peak flow, about 10% of the lake volume would have already exited; eroding about 1 km 3 of alluvium from the outlet, and the lake level would have dropped by about 10.6 m.

Lake Bonneville↗
USGS2023

Decadal shifts in the population growth, regeneration, and health of Taxodium distichum in swamps of the Cache River Watershed, Illinois

Population projection models based on long-term trends in regeneration and tree survival can be used to predict the future stability of swamp forest species using water management. Population growth and regeneration of a foundational tree species in North American cypress swamps ( Taxodium distichum ) were compared in the Cache River watershed of southern Illinois USA over several decades. This study examined T. distichum population growth in several regional swamps within the Cache River watershed along a moisture gradient to model growth, stability, or decline based on data of life history stage transitions, using data from the following time periods: the 1990s, 2002–2011, and 2012–2022. Using data from the 1990s, T. distichum populations in Crawford Tract in Buttonland Swamp were projected to increase over time because of the high frequency of juvenile stages at elevations with growing season drawdown and winter flooding. The situation in Crawford Tract had changed by 2019–2021 because T. distichum seedlings had not transitioned (i.e., saplings and young trees were absent) although no old-growth trees had died during or after the 1990s. In other regional swamps, projection models were constructed over two decades (2006–2021) along a dry-to-wet flood gradient including Section 8 Woods, Deer Pond, Wildcat Bluff, Snake Hole, and Heron Pond. Populations in swamps on the drier end of the gradient had more support from juvenile stages. In a tree health survey in 2022 within the impounded interior of Buttonland Swamp (not Crawford Tract), seventy percent of the old-growth T. distichum trees were stressed or declining. Coupled with the fact that no seedlings or saplings were observed, the populations in the interior of the swamp were not stable. Many factors could further stress these ancient T. distichum including interactions of impoundment with chemicals, disease, and changes in air temperature and precipitation. Overall, the seedling abundance in these swamps increased in these environments from 2012 to 2021, except in the most flooded swamps. From a management perspective, drier conditions were more conducive to the success of the earlier life history stages of T. distichum in these old-growth forests.

Illinois↗
USGS2017

The Tule Springs local fauna: Rancholabrean vertebrates from the Las Vegas Formation, Nevada

A middle to late Pleistocene sedimentary sequence in the upper Las Vegas Wash, north of Las Vegas, Nevada, has yielded the largest open-site Rancholabrean vertebrate fossil assemblage in the southern Great Basin and Mojave Deserts. Recent paleontologic field studies have led to the discovery of hundreds of fossil localities and specimens, greatly extending the geographic and temporal footprint of original investigations in the early 1960s. The significance of the deposits and their entombed fossils led to the preservation of 22,650 acres of the upper Las Vegas Wash as Tule Springs Fossil Beds National Monument. These discoveries also warrant designation of the assemblage as a local fauna, named for the site of the original paleontologic studies at Tule Springs. The large mammal component of the Tule Springs local fauna is dominated by remains of Mammuthus columbi as well as Camelops hesternus , along with less common remains of Equus (including E. scotti ) and Bison . Large carnivorans including Canis dirus , Smilodon fatalis , and Panthera atrox are also recorded. Micromammals, amphibians, lizards, snakes, birds, invertebrates, plant macrofossils, and pollen also occur in the deposits and provide important and complementary paleoenvironmental information. The fauna occurs within the Las Vegas Formation, an extensive and stratigraphically complex sequence of groundwater discharge deposits that represent a mosaic of desert wetland environments. Radiometric and luminescence dating indicates the sequence spans the last ∼570 ka, and records hydrologic changes in a dynamic and temporally congruent response to northern hemispheric abrupt climatic oscillations. The vertebrate fauna occurs in multiple stratigraphic horizons in this sequence, with ages of the fossils spanning from ∼100 to ∼12.5 ka.

Quaternary International↗
USGS2018

History and dynamics of the Greater Yellowstone Glacial System during the last two glaciations

The Greater Yellowstone Glacial System (GYGS) covered about 20,000 km2 at its maximum Pleistocene extent. The initiation, culmination, and ultimate decay of the GYGS involved complex interactions between several coalescent ice masses flowing from glacial source areas adjoining and including the Yellowstone Plateau. Here, we present an updated review of the history and dynamics of the GYGS during the penultimate (Bull Lake) and last (Pinedale) glaciations, drawing upon an integration of glacial-geologic mapping with >130 cosmogenic 10Be and 3He exposure ages. Bull Lake glacial deposits in greater Yellowstone are dated to ca. 150–140 ka and correlate with marine isotope stage 6. The Bull Lake glaciation extended well beyond the Pinedale along the southern and western GYGS margins, but Pinedale glaciers overrode Bull Lake ice limits on the north and east sides. The northeastward shift of the center of ice mass from Bull Lake to Pinedale time may be explained by uplift on the leading edge of the Yellowstone hotspot and subsidence on the trailing margin. In early Pinedale time (∼22–18 ka), ice buildup culminated in the high terrain of the Beartooth Uplift and High Absaroka Range. Glaciers from these source regions flowed onto the northeastern margin of the Yellowstone Plateau and advanced to terminal moraines beyond Clarks Fork Canyon and in Jackson Hole. By middle Pinedale time (∼18–16 ka), the Yellowstone Plateau ice cap surface had risen above the equilibrium-line altitude, stimulating orographic glacial buildup nourished by storms funneled eastward through the Snake River Plain. The plateau ice cap eventually thickened to >1000 m and joined glaciers from the Beartooth Uplift and Gallatin Range to form the northern Yellowstone outlet glacier. Terrain east and downwind of the ice cap crest was placed in a precipitation shadow, resulting in glacial recession in these regions. During the late Pinedale (∼16–13 ka), the plateau ice cap prograded southwestward toward the direction of moisture supply, leading to advances along the southern and western margins of the GYGS. Northern sectors of the plateau ice cap were nearly stagnant at this time. The Yellowstone region experienced widespread deglaciation ca. 15–14 ka in response to warming climate. Unloading of the ∼1 km-thick plateau ice cap and consequent release of pressure on the magmatic system beneath Yellowstone was not accompanied by volcanism, indicating that the magma chamber was not primed to erupt via decompression during the last deglaciation.

Idaho, Montana Wyoming↗
USGS2020

Short- and long-term responses of riparian cottonwoods (Populus spp.) to flow diversion: Analysis of tree-ring radial growth and stable carbon isotopes

Long duration tree-ring records with annual precision allow for the reconstruction of past growing conditions. Investigations limited to the most common tree-ring proxy of ring width can be difficult to interpret, however, because radial growth is affected by multiple environmental processes. Furthermore, studies of living trees may miss important effects of drought on tree survival and forest changes. Stable carbon isotopes can help distinguish drought from other environmental factors that influence tree-ring width and forest stand condition. We quantified tree-ring radial expansion and stable carbon isotope ratios (δ 13 C) in riparian cottonwoods ( Populus angustifolia and P. angustifolia x P. trichocarpa) along Snake Creek in Nevada, USA. We investigated how hydrological drought affected tree growth and death at annual to half-century scales in a partially dewatered reach (DW) compared to reference reaches immediately upstream and downstream. A gradual decline in tree-ring basal area increment (BAI) began at DW concurrent to streamflow diversion in 1961. BAI at DW diverged from one reference reach immediately but not from the other until nearly 50 years later. In contrast, tree-ring δ 13 C had a rapid and sustained increase following diversion at DW only, providing the stronger and clearer drought signal. BAI and δ 13 C were not significantly correlated prior to diversion; after diversion they both reflected drought and were correlated for DW trees only. Cluster analyses distinguished all trees in DW from those in reference reaches based on δ 13 C, but BAI patterns left trees intermixed across reaches. Branch and tree mortality were also highest and canopy vigor was lowest in DW. Results indicate that water scarcity strongly limited cottonwood photosynthesis following flow diversion, thus reducing carbon assimilation, basal growth and survival. The dieback was not sudden, but occurred over decades as carbon deficits mounted and depleted streamflow left trees increasingly vulnerable to local meteorological drought.

Nevada↗
USGS2017

The Snowmastodon Project

Studies of terrestrial biotic and environmental dynamics of the last interglacial period, Marine Oxygen Isotope Stage (MIS) 5, provide insight into the effects of long-term climate change on Pleistocene ecosystems. In North America, however, there are relatively few fossil sites that definitively date to MIS 5. Even fewer contain multiple ecosystem components (vertebrates, invertebrates, plants) that have been studied in detail, and none are located at high elevation. Thus, our view of North American ecosystems during MIS 5 is, at best, an incomplete composite view, and alpine ecosystems are entirely undocumented. The Ziegler Reservoir fossil site allows us to begin filling these gaps. Discovered on October 14, 2010 by a construction crew while enlarging a small reservoir near Snowmass Village, Colorado (USA), the site is situated high in the Rocky Mountains at an elevation of ~ 2705 m. Initial excavations exposed a series of stacked fossil ecosystems, including abundant faunal and floral components. Subsequent work revealed an exceptionally diverse biota composed of nearly 6000 large bones of late Pleistocene megafauna, including mastodons, mammoths, ground sloths, horses, camels, deer, bison, black bear, coyotes, and big horn sheep. This collection is complemented by more than 200 bones from at least 40 species of small animals including otters, muskrats, minks, rabbits, beavers, frogs, lizards, snakes, fish, and birds, and more than 20,000 salamander bones. Geomorphic evidence and multiple dating techniques show that the small, ridge-top basin containing the site was formed by a lateral lobe of a valley glacier that filled, and ultimately overtopped, the Snowmass Creek drainage during the Bull Lake glaciation (MIS 6). When the glacier receded, a lake that occupied the basin began to fill slowly with what is hypothesized to be eolian sediment and occasional input from slope failures of the impounding moraine. As sedimentation continued, the lake transformed first into a shallow pond, then a marsh, and later an alpine meadow. In all, the Ziegler Reservoir sedimentary record spans the time encompassed by the end of MIS 6, all of MIS 5 and MIS 4, and the earliest part of MIS 3. MIS 5e, which is considered to be the peak warmth of the last interglacial period, is especially well represented. Preservation of organic material at the Ziegler Reservoir fossil site is exceptional. Even after more than 100,000 years of burial, sedge and willow leaves were still green, mollusks and gastropods showed color, beetle parts remained iridescent, fossil conifer cones were intact, and an entire beach of 20-meter-long driftwood logs was found intact. The exquisite preservation allowed for detailed analysis of pollen, plant macrofossils, conifer cones, and fossil wood, as well as insects, chironomids, mollusks, ostracodes, and other invertebrates — all in addition to the spectacular faunal remains. This special volume of Quaternary Research represents a comprehensive scientific report of “The Snowmastodon Project,” as the investigations at the Ziegler Reservoir fossil site came to be known. Summarizing the work of scientists from more than 20 institutions, the volume details the environments in which the animals lived, provides insight into how they died, and forms the foundation of our understanding of alpine ecosystem dynamics during the last interglacial period in the Rocky Mountains.

Quaternary Research↗
USGS2017

A high-elevation, multi-proxy biotic and environmental record of MIS 6-4 from the Ziegler Reservoir fossil site, Snowmass Village, Colorado, USA

In North America, terrestrial records of biodiversity and climate change that span Marine Oxygen Isotope Stage (MIS) 5 are rare. Where found, they provide insight into how the coupling of the ocean–atmosphere system is manifested in biotic and environmental records and how the biosphere responds to climate change. In 2010–2011, construction at Ziegler Reservoir near Snowmass Village, Colorado (USA) revealed a nearly continuous, lacustrine/wetland sedimentary sequence that preserved evidence of past plant communities between ~ 140 and 55 ka, including all of MIS 5. At an elevation of 2705 m, the Ziegler Reservoir fossil site also contained thousands of well-preserved bones of late Pleistocene megafauna, including mastodons, mammoths, ground sloths, horses, camels, deer, bison, black bear, coyotes, and bighorn sheep. In addition, the site contained more than 26,000 bones from at least 30 species of small animals including salamanders, otters, muskrats, minks, rabbits, beavers, frogs, lizards, snakes, fish, and birds. The combination of macro- and micro-vertebrates, invertebrates, terrestrial and aquatic plant macrofossils, a detailed pollen record, and a robust, directly dated stratigraphic framework shows that high-elevation ecosystems in the Rocky Mountains of Colorado are climatically sensitive and varied dramatically throughout MIS 5.

Colorado↗
USGS2002

High-resolution aeromagnetic mapping of volcanic terrain, Yellowstone National Park

High-resolution aeromagnetic data acquired over Yellowstone National Park (YNP) show contrasting patterns reflecting differences in rock composition, types and degree of alteration, and crustal structures that mirror the variable geology of the Yellowstone Plateau. The older, Eocene, Absaroka Volcanic Supergroup, a series of mostly altered, andesitic volcanic and volcaniclastic rocks partially exposed in mountains on the eastern margin of YNP, produces high-amplitude, positive magnetic anomalies, strongly contrasting with the less magnetic, younger, latest Cenozoic, Yellowstone Plateau Group, primarily a series of fresh and variably altered rhyolitic rocks covering most of YNP. The Yellowstone caldera is the centerpiece of the Yellowstone Plateau; part of its boundary can be identified on the aeromagnetic map as a series of discontinuous, negative magnetic anomalies that reflect faults or zones along which extensive hydrothermal alteration is localized. The large-volume rhyolitic ignimbrite deposits of the 0.63-Ma Lava Creek Tuff and the 2.1-Ma Huckleberry Ridge Tuff, which are prominent lithologies peripheral to the Yellowstone caldera, produce insignificant magnetic signatures. A zone of moderate amplitude positive anomalies coincides with the mapped extent of several post-caldera rhyolitic lavas. Linear magnetic anomalies reflect the rectilinear fault systems characteristic of resurgent domes in the center of the caldera. Peripheral to the caldera, the high-resolution aeromagnetic map clearly delineates flow unit boundaries of pre- and post-caldera basalt flows, which occur stratigraphically below the post-caldera rhyolitic lavas and are not exposed extensively at the surface. All of the hot spring and geyser basins, such as Norris, Upper and Lower Geyser Basins, West Thumb, and Gibbon, are associated with negative magnetic anomalies, reflecting hydrothermal alteration that has destroyed the magnetic susceptibility of minerals in the volcanic rocks. Within Yellowstone Lake, which is mostly within the Yellowstone caldera, aeromagnetic lows also are associated with known hydrothermal activity in the lake. Many of the magnetic lows extend beyond the areas of alteration and hot springs, suggesting a more extensive currently active or fossil hydrothermal system than is currently mapped. Steep magnetic gradients, suggesting faults or fractures, bound the magnetic lows. This implies that fractures localize the hot springs. Magnetic gradient trends reflect the mapped Basin and Range structural trends of north and northwest, as well as northeasterly trends that parallel the regional trend of the Snake River Plain and the track of the Yellowstone hot spot which follow the Precambrian structural grain. These trends are found both at small scales such as in hydrothermal basins and at more regional fault scales, which suggests that the regional stress field and reactivated older structures may exert some control on localization of hydrothermal activity. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗
USGS2016

Late Paleocene glyptosaur (Reptilia: Anguidae) osteoderms from South Carolina, USA

Heavily tuberculated glyptosaur osteoderms were collected in an active limestone quarry in northern Berkeley County, South Carolina. The osteoderms are part of a highly diverse late Paleocene vertebrate assemblage that consists of marine, terrestrial, fluvial, and/or brackish water taxa, including chondrichthyan and osteichthyan fish, turtles (chelonioid, trionychid, pelomedusid, emydid), crocodilians, palaeopheid snakes, and a mammal. Calcareous nannofossils indicate that the fossiliferous deposit accumulated within subzone NP9a of the Thanetian Stage (late Paleocene, upper part of Clarkforkian North American Land Mammal Age [NALMA]) and is therefore temporally equivalent to the Chicora Member of the Williamsburg Formation. The composition of the paleofauna indicates that the fossiliferous deposit accumulated in a marginal marine setting that was influenced by fluvial processes (estuarine or deltaic). The discovery of South Carolina osteoderms is significant because they expand the late Paleocene geographic range of glyptosaurines eastward from the US midcontinent to the Atlantic Coastal Plain and provide one of the few North American records of these lizards inhabiting coastal habitats. This discovery also brings to light a possibility that post-Paleocene expansion of this group into Europe occurred via northeastward migration along the Atlantic coast of North America.

South Carolina↗
USGS2016

Amphibian conservation: clarifications to comments from Andreone

We appreciate the comments from Andreone (2016) regarding our proposed alternative strategy for addressing the amphibian crisis. Andreone recognizes the utility of an Incident Command System approach but doubts the feasibility of implementation at an international level. We stated in our original article, however, that ‘the feasibility of our suggestion is debatable, but our point is that radically different approaches are necessary to effectively manage the largest extinction event in modern history’ (Muths & Fisher, 2015). There are examples of where such top-down strategies are being applied; e.g. for the brown tree snake Boiga irregularis (Stanford & Rodda, 2007), and biosecurity planning for Micronesia and Hawaii (NAVFAC Pacific, 2016). Another example is presented by Andreone. In Madagascar a community-wide conservation plan has been developed complete with prioritization of specific actions (Andreone, 2016). As with any top-down strategy, challenges will surface, especially when making decisions that affect economics. We note this caveat in our article, and Andreone points out such issues in Madagascar, where there are mismatches in priorities between biodiversity conservation and civil needs. Our suggestion is that a new paradigm needs to be considered given the gravity of amphibian decline, and one option may be to take a global approach focusing on specific, major threats. Application of an Incident Command System would not necessitate competition with, or emasculation of, local conservation priorities or actions.

Oryx↗
USGS2009

Recent status and trends of the land bird avifauna on Saipan, Mariana Islands, with emphasis on the endangered Nightingale Reed-warbler Acrocephalus luscinia

The avifauna of the Mariana Islands, an archipelago in the western Pacific, faces the threats of rapid economic development and the spread of non-native species, particularly a devastating predator, Brown Tree Snake Boiga irregularis. In this paper, we examine the status and trends of the land bird fauna of Saipan Island based on three island-wide surveys conducted in 1982, 1997, and 2007. During this period, the human population on Saipan increased more than four-fold and much of the island has been developed. The surveys employed standard point-transect methods based on Distance Sampling. Remarkably, we found nearly all species of land birds - 11 native species and three introduced species - to be common or abundant. The exception was the Micronesian Megapode Megapodius laperouse, a historically rare species that was not observed on the 2007 survey, although it does persist on Saipan and other Mariana islands. A comparison of species densities among the three surveys showed that seven species, mainly fruit and seed-eaters, had increased and three species of insectivorous birds had decreased - Rufous Fantail Rhipidura rufifrons, Nightingale Reed-warbler Acrocephalus luscinia, and Golden White-eye Cleptornis marchei. Of these three, Nightingale Reed-warbler is listed as Endangered on the IUCN Red List and as an Endangered Species by the U.S. Fish and Wildlife Service. Reed-warbler densities on Saipan decreased by more than half between 1982 and 2007. Although point transect sampling worked well for this species, density estimates and trends assessment could be improved by reallocating sampling stations among habitats and by more frequent sampling. ?? BirdLife International 2009.

Bird Conservation International↗
USGS2022

In-reservoir physical processes modulate aqueous and biological methylmercury export from a seasonally anoxic reservoir

Anoxic conditions within reservoirs related to thermal stratification and oxygen depletion lead to methylmercury (MeHg) production, a key process governing the uptake of mercury in aquatic food webs. Once formed within a reservoir, the timing and magnitude of the biological uptake of MeHg and the relative importance of MeHg export in water versus biological compartments remain poorly understood. We examined the relations between the reservoir stratification state, anoxia, and the concentrations and export loads of MeHg in aqueous and biological compartments at the outflow locations of two reservoirs of the Hells Canyon Complex (Snake River, Idaho-Oregon). Results show that (1) MeHg concentrations in filter-passing water, zooplankton, suspended particles, and detritus increased in response to reservoir destratification; (2) zooplankton MeHg strongly correlated with MeHg in filter-passing water during destratification; (3) reservoir anoxia appeared to be a key control on MeHg export; and (4) biological MeHg, primarily in zooplankton, accounted for only 5% of total MeHg export from the reservoirs (the remainder being aqueous compartments). These results improve our understanding of the role of biological incorporation of MeHg and the subsequent downstream release from seasonally stratified reservoirs and demonstrate that in-reservoir physical processes strongly influence MeHg incorporation at the base of the aquatic food web.

Idaho, Oregon↗
USGS2023

Reservoir stratification modulates the influence of impoundments on fish mercury concentrations along an arid land river system

Impoundment is among the most common hydrologic alterations with impacts on aquatic ecosystems that can include effects on mercury (Hg) cycling. However, landscape-scale differences in Hg bioaccumulation between reservoirs and other habitats are not well characterized nor are the processes driving these differences. We examined total Hg (THg) concentrations of Smallmouth Bass ( Micropterus dolomieu ) collected from reservoir, tailrace, and free-flowing reaches along an 863 km segment of the Snake River, USA, a semiarid river with 22 impoundments along its course. Across three size-classes (putative 1-year-old, first reproductive, and harvestable sized fish), THg concentrations in reservoirs and tailraces averaged 76% higher than those in free-flowing segments. Among reservoirs, THg concentrations were highest in reservoirs with inconsistent stratification patterns, 47% higher than annually stratified, and 144% higher than unstratified reservoirs. Fish THg concentrations in tailraces immediately downstream of stratified reservoirs were higher than those below unstratified (38–130%) or inconsistently stratified (32–79%) reservoirs. Stratification regimes influenced the exceedance of fish and human health benchmarks, with 52–80% of fish from stratifying reservoirs and downstream tailraces exceeding a human consumption benchmark, compared to 6–17% where stratification did not occur. These findings suggest that impoundment and stratification play important roles in determining the patterns of Hg exposure risk across the landscape.

Environmental Science & Technology↗
USGS2017

Assessing the dietary bioavailability of metals associated with natural particles: Extending the use of the reverse labeling approach to zinc

We extend the use of a novel tracing technique to quantify the bioavailability of zinc (Zn) associated with natural particles using snails enriched with a less common Zn stable isotope. Lymnaea stagnalis is a model species that has relatively fast Zn uptake rates from the dissolved phase, enabling their rapid enrichment in 67 Zn during the initial phase of labeling. Isotopically enriched snails were subsequently exposed to algae mixed with increasing amounts of metal-rich particles collected from two acid mine drainage impacted rivers. Zinc bioavailability from the natural particles was inferred from calculations of 66 Zn assimilation into the snail’s soft tissues. Zinc assimilation efficiency (AE) varied from 28% for the Animas River particles to 45% for the Snake River particles, indicating that particle-bound, or sorbed Zn, was bioavailable from acid mine drainage wastes. The relative binding strength of Zn sorption to the natural particles was inversely related to Zn bioavailability; a finding that would not have been possible without using the reverse labeling approach. Differences in the chemical composition of the particles suggest that their geochemical properties may influence the extent of Zn bioavailability.

Environmental Science & Technology↗
USGS2020

Seasonal dynamics and interannual variability in mercury concentrations and loads through a three-reservoir complex

The Hells Canyon Complex (HCC) along the Snake River (Idaho-Oregon border, USA) encompasses three successive reservoirs that seasonally stratify, creating anoxic conditions in the hypolimnion that promote methylmercury (MeHg) production. This study quantified seasonal dynamics and interannual variability in mercury concentrations (inorganic divalent mercury (IHg) and MeHg) and loads at four reservoir inflow and outflow locations through the HCC (2014-2017). We observed (1) that the HCC is a net sink for both IHg and MeHg, (2) interannual variability in IHg and MeHg loads largely reflecting streamflow conditions, and (3) seasonal variability in particulate IHg loading at the inflow (greatest from February to April) and MeHg export from the outflow (greatest from September to December) of the HCC. Seasonal export of MeHg was evidenced by increases in monthly mean concentrations of unfiltered MeHg (approximately twofold) and the percentage of total mercury (THg) as MeHg (≥ fourfold) coincident with reservoir destratification. Despite evidence of seasonal export of MeHg from the HCC, annual loads indicate a 42% decrease in unfiltered MeHg from HCC inflow to outflow. Results from this study improve the understanding of seasonal variability in mercury transport through and transformation within a reservoir complex.

Idaho, Oregon↗
USGS2001

Enantiomeric composition of chiral polychlorinated biphenyl atropisomers in aquatic and riparian biota

The enantiomeric composition of polychlorinated biphenyl (PCB) atropisomers was measured in river and riparian biota (fish, bivalves, crayfish, water snakes, barn swallows) from selected sites throughout the United States by using chiral gas chromatography/mass spectrometry. Nonracemic enantiomeric fractions (EFs) were observed for PCBs 91, 95, 136, and 149 for aquatic and riparian biota from Lake Hartwell, SC, a reservoir heavily contaminated with PCBs, and for these congeners and PCBs 132, 174, 176, and 183 in river fish and bivalves nationwide. Fish and bivalves showed marked differences in EFs as compared to sediment found at the same sampling sites, thus suggesting that PCBs are bioprocessed in biota in a different manner from those found in sediment (e.g., reductive dechlorination). Species-dependent patterns in PCB EFs were observed, which suggest differences in the ability of different species to bioprocess PCBs enantioselectively, most likely by metabolism. The presence of nonracemic PCBs in fish and bivalves suggests greater metabolic degradation of PCBs in these organisms than indicated from previous achiral studies and underscores the powerful potential of chiral analysis as a tracer of environmental bioprocesses.

Environmental Science & Technology↗