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Introduction to Regional Geology, Tectonics, and Metallogenesis of Northeast Asia

Purpose This introduction presents an overview of the regional geology, tectonics, and metallogenesis of Northeast Asia. The major purposes are to provide a relatively short summary of these features for readers who are unfamiliar with Northeast Asia; a general scientific introduction for the succeeding chapters of this volume; and an overview of the methodology of metallogenic and tectonic analysis employed for Northeast Asia. The introduction also describes how a high-quality metallogenic and tectonic analysis, including synthesis of an associated metallogenic-tectonic model will greatly benefit refinement of mineral deposit models and deposit genesis; improvement of assessments of undiscovered mineral resources as part of quantitative mineral resource assessment studies; land-use and mineral exploration planning; improvement of interpretations of the origins of host rocks, mineral deposits, and metallogenic belts; and suggestions for new research. The compilation, synthesis, description, and interpretation of metallogenesis and tectonics of major regions, such as Northeast Asia (Eastern Russia, Mongolia, northern China, South Korea, and Japan) and the Circum-North Pacific (Russian Far East, Alaska, and Canadian Cordillera) requires a complex methodology. The methodology includes: (1) definitions of key terms; (2) compilation of a regional geologic base map that can be interpreted according to modern tectonic concepts and definitions; (3) compilation of a mineral deposit database that enables the determination of mineral deposit models, and relations of deposits to host rocks and tectonic origins; (4) synthesis of a series of mineral deposit models that characterize the known mineral deposits and inferred undiscovered deposits of the region; (5) compilation of a series of maps of metallogenic belts constructed on the regional geologic base map; and (6) formulation of a unified metallogenic and tectonic model. The summary of regional geology and metallogenesis in this introduction is based on publications of the major international collaborative studies of the metallogenesis and tectonics of Northeast Asia that were led by the U.S. Geological Survey. These studies have produced two broad types of publications. One type is a series of regional geologic, mineral deposit, and metallogenic belt maps and companion descriptions for the regions. Examples of major publications of this type are Obolenskiy and others (2003a, b, 2004), Parfenov and others (2003, 2004a, b), Nokleberg and others (2004), Rodionov and others (2004), and Naumova and others (2006). The other type is a suite of metallogenic and tectonic analyses of these same regions. Examples of major publications of this type are Rodionov and others (2004), Nokleberg and others (2000, 2004, 2005), and Naumova and others (2006). The Northeast Asia project area consists of eastern Russia (most of Siberia and most of the Russian Far East), Mongolia, Northern China, South Korea, Japan, and adjacent offshore areas. This area is approximately bounded by 30 to 82? N. latitude and 75 to 144? E. longitude. The major participating agencies are the Russian Academy of Sciences, Academy of Sciences of the Sakha Republic (Yakutia), VNIIOkeangeologia and Ministry of Natural Resources of the Russian Federation, Mongolian Academy of Sciences, Mongolian University of Science and Technology, Mongolian National University, Jilin University, Changchun, China, the China Geological Survey, the Korea Institute of Geosciences and Mineral Resources, the Geological Survey of Japan/AIST, University of Texas Arlington, and the U.S. Geological Survey. The Northeast Asia project extends and build on data and interpretations from a previous project on the Major Mineral Deposits, Metallogenesis, and Tectonics of the Russian Far East, Alaska, and the Canadian Cordillera that was conducted by the USGS, the Russian Academy of Sciences, the Alaska Division of Geological and Geophysical Surveys,

Open-File Report↗

Rio Grande transboundary integrated hydrologic model and water-availability analysis, New Mexico and Texas, United States, and Northern Chihuahua, Mexico

Errata **September 28, 2018: The purpose of a USGS Open-file report (OFR) is dissemination of information that must be released immediately to fill a public need or information that is not sufficiently refined to warrant publication in one of the other USGS series. As part of that refinement process, an error was discovered in one of the input data sets of the Rio Grande Transboundary Integrated Hydrologic Model (RGTIHM) that this OFR was based upon. The error involved the assignment of storage properties to “phantom cells.” Phantom cells are required for most variants of MODFLOW that use a structured finite-difference grid when individual stratigraphic layers are represented as separate layers. Using phantom cells is a common practice that allows separate model layers to be maintained without having to combine stratigraphic layers into equivalent model layers or to use an unstructured grid. Typically, phantom cell horizontal hydraulic conductivities and storage properties are set to a small number and vertical hydraulic conductivities are set to a number large enough to allow vertical flow between the vertically adjacent layers. In the RGTIHM, the specific storage properties of the phantom cells for the upper (RGTIHM layers 3 and 4), middle (RGTIHM layers 5 and 6), and lower (RGTIHM layers 7 and 8) members of the Santa Fe Group were inadvertently assigned a value of 1 feet -1 . The revision of these specific storage values to a small number (1.0 x 10 -09 feet -1 ) required additional trial-and-error model calibration and a new sensitivity analysis. After calibration, the overall model fit remained similar to the fit described in the OFR, but the fit for many individual features such as project water available for diversions at the American Canal and Acequia Madre improved due to the reduction in flow coming from lower layers. Overall, there is still an average net depletion of groundwater flow, and the conclusions of the report are not changed. The revised average annual groundwater flow depletion simulated for the period 1953-2014 is -1,480 acre-feet/year for the entire model region, and -3,660 acre-feet/year for the portion of the model in the United States. The final version of the model will be the basis of the USGS Scientific Investigations Report that will supersede this OFR. An updated Model Archive of RGTIHM is available upon request to the USGS California Water Science Center. The corrected version of the model WAS the basis for the USGS Scientific Investigations Report that SUPERSEDED this Open-File Report.** Abstract Changes in population, agricultural development and practices (including shifts to more water-intensive crops), and climate variability are increasing demands on available water resources, particularly groundwater, in one of the most productive agricultural regions in the Southwest—the Rincon and Mesilla Valley parts of Rio Grande Valley, Doña Ana and Sierra Counties, New Mexico, and El Paso County, Texas. The goal of this study was to produce an integrated hydrological simulation model to help evaluate water-management strategies, including conjunctive use of surface water and groundwater for historical conditions, and to support long-term planning for the Rio Grande Project. This report describes model construction and applications by the U.S. Geological Survey, working in cooperation and collaboration with the Bureau of Reclamation. This model, the Rio Grande Transboundary Integrated Hydrologic Model, simulates the most important natural and human components of the hydrologic system, including selected components related to variations in climate, thereby providing a reliable assessment of surface-water and groundwater conditions and processes that can inform water users and help improve planning for future conditions and sustained operations of the Rio Grande Project (RGP) by the Bureau of Reclamation. Model development included a revision of the conceptual model of the flow system, construction of a Transboundary Rio Grande Watershed Model (TRGWM) water-balance model using the Basin Characterization Model (BCM), and construction of an integrated hydrologic flow model with MODFLOW-One-Water Hydrologic Flow Model (referred to as One Water). The hydrologic models were developed for and calibrated to historical conditions of water and land use, and parameters were adjusted so that simulated values closely matched available measurements (calibration). The calibrated model was then used to assess the use and movement of water in the Rincon Valley, Mesilla Basin, and northern part of the Conejos-Médanos Basin, with the entire region referred to as the “Transboundary Rio Grande” or TRG. These tools provide a means to understand hydrologic system response to the evolution of water use in the region, its availability, and potential operational constraints of the RGP. The conceptual model identified surface-water and groundwater inflows and outflows that included the movement and use of water both in natural and in anthropogenic systems. The groundwater-flow system is characterized by a layered geologic sedimentary sequence combined with the effects of groundwater pumping, operation of the RGP, natural runoff and recharge, and the application of irrigation water at the land surface that is captured and reused in an extensive network of canals and drains as part of the conjunctive use of water in the region. Historical groundwater-level fluctuations followed a cyclic pattern that were aligned with climate cycles, which collectively resulted in alternating periods of wet or dry years. Periods of drought that persisted for one or more years are associated with low surface-water availability that resulted in higher rates of groundwater-level decline. Rates of groundwater-level decline also increased during periods of agricultural intensification, which necessitated increasing use of groundwater as a source of irrigation water. Agriculture in the area was initially dominated by alfalfa and cotton, but since 1970 more water-intensive pecan orchards and vegetable production have become more common. Groundwater levels substantially declined in subregions where drier climate combined with increased demand, resulting in periods of reduced streamflows. Most of the groundwater was recharged in the Rio Grande Valley floor, and most of the pumpage and aquifer storage depletion was in Mesilla Basin agricultural subregions. A cyclic imbalance between inflows and outflows resulted in the modeled cyclic depletion (groundwater withdrawals in excess of natural recharge) of the groundwater basin during the 75-year simulation period of 1940–2014. Changes in groundwater storage can vary considerably from year to year, depending on land use, pumpage, and climate conditions. Climatic drivers of wet and dry years can greatly affect all inflows, outflows, and water use. Although streamflow and, to a minor extent, precipitation during inter-decadal wet-year periods replenished the groundwater historically, contemporary water use and storage depletion could have reduced the effects of these major recharge events. The average net groundwater flow-rate deficit for 1953–2014 was estimated to be about 8,990 acre-feet per year.

New Mexico, Northern Chihuahua, Texas↗

Field Surveys of Rare Plants on Santa Cruz Island, California, 2003-2006: Historical Records and Current Distributions

Santa Cruz Island is the largest of the northern Channel Islands located off the coast of California. It is owned and managed as a conservation reserve by The Nature Conservancy and the Channel Islands National Park. The island is home to nine plant taxa listed in 1997 as threatened or endangered under the federal Endangered Species Act, because of declines related to nearly 150 years of ranching on the island. Feral livestock were removed from the island as a major conservation step, which was part of a program completed in early 2007 with the eradication of pigs and turkeys. For the first time in more than a century, the rare plants of Santa Cruz Island have a chance to recover in the wild. This study provides survey information and living plant materials needed for recovery management of the listed taxa. We developed a database containing information about historical collections of the nine taxa and used it to plan a survey strategy. Our objectives were to relocate as many of the previously known populations as possible, with emphasis on documenting sites not visited in several decades, sites that were poorly documented in the historical record, and sites spanning the range of environmental conditions inhabited by the taxa. From 2003 through 2006, we searched for and found 39 populations of the taxa, indicating that nearly 80 percent of the populations known earlier in the 1900s still existed. Most populations are small and isolated, occupying native-dominated habitat patches in a highly fragmented and invaded landscape; they are still at risk of declining through population losses. Most are not expanding beyond the edges of their habitat patches. However, most taxa appeared to have good seed production and a range of size classes in populations, indicating a good capacity for plant recruitment and population growth in these restricted sites. For these taxa, seed collection and outplanting might be a good strategy to increase numbers of populations for species recovery. Several taxa have particular problems evidenced by lack of fruit set, very small population sizes, or unstable habitats. We collected seeds of all but two taxa for seed banking, and live cuttings of two clonal shrubs for cultivation at the Santa Barbara Botanic Garden. The survey data, seeds and cuttings provide a baseline and a foundation for planning, conducting, and tracking recovery of the nine federally listed plant taxa of Santa Cruz Island.

Scientific Investigations Report↗

Ground-Water Nutrient Flux to Coastal Waters and Numerical Simulation of Wastewater Injection at Kihei, Maui, Hawaii

Water sampling and numerical modeling were used to estimate ground-water nutrient fluxes in the Kihei area of Maui, where growth of macroalgae (seaweed) on coral reefs raises ecologic concerns and accumulation on beaches has caused odor and removal problems. Fluxes and model results are highly approximate, first-order estimates because very few wells were sampled and there are few field data to constrain model calibration. Ground-water recharge was estimated to be 22.6 Mgal/d (million gallons per day) within a 73-square-mile area having a coastline length of 8 miles or 13 km (kilometers). Nearly all of the recharge discharges at the coast because ground-water withdrawals are small. Another 3.0 Mgal/d of tertiary-treated wastewater effluent is injected into the regional aquifer at a County treatment plant midway along the coast and about a mile from shore. The injection plume is 0.93 miles wide (1.5 km) at the shore, as estimated from a three-dimensional numerical ground-water model. Wastewater injected beneath the brackish ground-water lens rises buoyantly and spreads out at the top of the lens, diverting and mixing with ambient ground water. Ground water discharging from the core of the injection plume is less than 5 years old and is about 60 percent effluent at the shore, according to the model. Dissolved nitrogen and phosphorus concentrations in treated effluent were 7.33 and 1.72 milligrams per liter, roughly 6 and 26 times background concentrations at an upgradient well. Background nitrogen and phosphorus fluxes carried by ground water are 7.7 and 0.44 kg/d-km (kilograms per day per kilometer of coast). Injected wastewater fluxes distributed across the plume width are 55 and 13 kg/d-km nitrogen and phosphorus, roughly 7 and 30 times background flux. However, not all of the injected load reaches coastal waters because nutrients are naturally attenuated in the oxygen-depleted effluent plume. Water from a downgradient well reflects this attenuation and provides a more conservative estimate of injection flux approaching the shore: 27 and 1.5 kg/d-km nitrogen and phosphorus, roughly one-half and one-ninth the injection-source estimates, and 3.5 and 3.4 times background flux. Effluent has 8 O and 2 H stable-isotope signatures that are distinct from local ground water, as well as 15 N and 11 B signatures diagnostic of domestic waste and laundry detergents, respectively. Pharmaceuticals and organic wastewater compounds also were present in effluent and the downgradient well. These isotopes and chemicals served as wastewater tracers in Kihei ground water and may be useful tracers in nearshore marine waters and aquifers elsewhere in Hawaii.

Scientific Investigations Report↗

Modeling Escherichia coli in the Missouri River near Omaha, Nebraska, 2012–16

The city of Omaha, Nebraska, has a combined sewer system in some areas of the city. In Omaha, Nebr., a moderate amount of rainfall will lead to the combination of stormwater and untreated sewage or wastewater being discharged directly into the Missouri River and Papillion Creek and is called a combined sewer overflow (CSO) event. In 2009, the city of Omaha began the implementation of their Long Term Control Plan (LTCP) to mitigate the effects of CSOs on the Missouri River and Papillion Creek. As part of the LTCP, the city partnered with the U.S. Geological Survey (USGS) in 2012 to begin monitoring in the Missouri River. Since 2012, monthly discrete water-quality samples for many constituents have been collected from the Missouri River at four sites. At 3 of the 4 sites, water quality has been monitored continuously for selected constituents and physical properties. These discrete water-quality samples and continuous water-quality monitoring data (from July 2012 to 2020) have been collected to better understand the water quality of the Missouri River, how it is changing with time, how it changes upstream from the city of Omaha to downstream, and how it varies during base-flow conditions and during periods of runoff. The purpose of this report is to document the development of Escherichia coli ( E. coli ) concentration models for these four Missouri River sites. Analysis was completed using the first 5 years of data (through 2016) to determine if the current approach is sufficient to meet future analysis goals and to understand if proposed models such as Load Estimator (LOADEST) models will be able to represent water-quality changes in the Missouri River. Multiple linear regression models were developed to estimate E. coli concentration using LOADEST as implemented in the rloadest package in the R statistical software program. A set of explanatory variables, including streamflow and streamflow anomalies, precipitation, information about CSOs, and continuous water quality, were evaluated for potential inclusion in regression models. The best model at Missouri River at NP Dodge Park at Omaha, Nebr. (USGS station 412126095565201; hereafter “NP Dodge”) included basin explanatory variables of upstream antecedent precipitation index measured at Tekamah, Nebr.; decimal time; season; and turbidity. The best model at Missouri River at Freedom Park Omaha, Nebr. (USGS station 411636095535401; hereafter “Freedom Park”) included the same explanatory variables as the NP Dodge model with the addition of turbidity anomalies and flow anomalies. The best models at the two downstream sites (Missouri River near Council Bluffs, Iowa, USGS station 06610505 and Missouri River near La Platte, Nebr., USGS station 410333095530101) included the same explanatory variables as the Freedom Park model with the addition of local antecedent precipitation index as measured at Eppley Airport in Omaha, Nebr., and additional turbidity and flow anomalies. The final selected models were the best models given our modeling design constraint in which explanatory variables included in the model for the upstream site were included in the downstream models. Explanatory variables currently (2020) being collected and included in the selected models through 2016 explained 64–75 percent of the variability of E. coli concentration in the Missouri River. Explaining 64–75 percent of the variability might be considered low when working with physical constituents (total nitrogen or sediment), but with the natural variability of biological constituents such as E. coli , the uncertainty of E. coli laboratory measurements, and the added complexity of modeling in a large drainage basin with multiple sources, these results are adequate and indicate that the explanatory variables being collected and models such as LOADEST can represent water-quality changes in the Missouri River for E. coli concentration from 2012 to 2016.

Nebraska↗

Simulation of daily streamflow for nine river basins in eastern Iowa using the Precipitation-Runoff Modeling System

The U.S. Geological Survey, in cooperation with the Iowa Department of Natural Resources, constructed Precipitation-Runoff Modeling System models to estimate daily streamflow for nine river basins in eastern Iowa that drain into the Mississippi River. The models are part of a suite of methods for estimating daily streamflow at ungaged sites. The Precipitation-Runoff Modeling System is a deterministic, distributed- parameter, physical-process-based modeling system developed to evaluate the response of streamflow and general drainage basin hydrology to various combinations of climate and land use. Calibration and validation periods used in each basin mostly were October 1, 2002, through September 30, 2012, but differed depending on the period of record available for daily mean streamflow measurements at U.S. Geological Survey streamflow-gaging stations. A geographic information system tool was used to delineate each basin and estimate values for model parameters based on basin physical and geographical features. A U.S. Geological Survey auto-calibration tool that uses a shuffled complex evolution algorithm was used for initial calibration, and then manual modifications were made to parameter values to complete the calibration of each basin model. The main objective of the calibration was to match daily discharge values of simulated streamflow to measured daily discharge values. The accuracy of Precipitation-Runoff Modeling System model streamflow estimates of nine river basins in eastern Iowa as compared to measured values at U.S. Geological Survey streamflow-gaging stations varied. The Precipitation-Runoff Modeling System models of nine river basins in eastern Iowa were satisfactory at estimating daily streamflow at 57 of the 79 calibration sites and 13 of the 14 validation sites based on statistical results. Unsatisfactory performance can be contributed to several factors: (1) low flow, no flow, and flashy flow conditions in headwater subbasins having a small drainage area; (2) poor representation of the groundwater and storage components of flow within a basin; (3) lack of accounting for basin withdrawals and water use; and (4) the availability and accuracy of meteorological input data. The Precipitation- Runoff Modeling System models of nine river basins in eastern Iowa will provide water-resource managers with a consistent and documented method for estimating streamflow at ungaged sites and aid in environmental studies, hydraulic design, water management, and water-quality projects.

Iowa↗

Apparent Resistivity and Estimated Interaction Potential of Surface Water and Groundwater along Selected Canals and Streams in the Elkhorn-Loup Model Study Area, North-Central Nebraska, 2006-07

In 2005, the State of Nebraska adopted new legislation that in part requires local Natural Resources Districts to include the effect of groundwater use on surface-water systems in their groundwater management plan. In response the U.S. Geological Survey, in cooperation with the Upper Elkhorn, Lower Elkhorn, Upper Loup, Lower Loup, Middle Niobrara, Lower Niobrara, Lewis and Clark, and Lower Platte North Natural Resources Districts, did a study during 2006-07 to investigate the surface-water and groundwater interaction within a 79,800-square-kilometer area in north-central Nebraska. To determine how streambed materials affect surface-water and groundwater interaction, surface geophysical and lithologic data were integrated at four sites to characterize the hydrogeologic conditions within the study area. Frequency-domain electromagnetic and waterborne direct- current resistivity profiles were collected to map the near-surface hydrogeologic conditions along sections of Ainsworth Canal near Ainsworth, Nebraska; Mirdan and Geranium Canals near Ord, Nebraska; North Loup River near Ord, Nebraska; and Middle Loup River near Thedford, Nebraska. Lithologic data were collected from test holes at each site to aid interpretation of the geophysical data. Geostatistical analysis incorporating the spatial variability of resistivity was used to account for the effect of lithologic heterogeneity on effective hydraulic permeability. The geostatistical analysis and lithologic data descriptions were used to make an interpretation of the hydrogeologic system and derive estimates of surface-water/groundwater interaction potential within the canals and streambeds. The estimated interaction potential at the Ainsworth Canal site and the Mirdan and Geranium Canal site is generally low to moderately low. The sediment textures at nearby test holes typically were silt and clay and fine-to-medium sand. The apparent resistivity values for these sites ranged from 2 to 120 ohm-meters. The vertical and horizontal variability of the apparent resistivity data were consistently low. Low resistive variability indicates little lithologic heterogeneity for either canal site. The surface-water/groundwater interaction-potential estimates are in agreement with the narrow frequency distribution of resistivity, low apparent resistivities, low spatial heterogeneity, and test-hole grain-size ranges. The estimated surface-water/groundwater interaction potential at the North Loup and Middle Loup River sites is moderate to moderately high. The sediment textures at nearby test holes were predominantly fine, medium, and coarse sand with some silt and silty to sandy clay. The apparent resistivity values for these sites ranged from 34 to 1,338 ohm-meters. The vertical variability of the resistivity data was moderately high. The horizontal variability at these sites is low to moderately low. The higher resistive variability at these sites indicates generally greater lithologic heterogeneity than at either the Ainsworth Canal site or the Mirdan and Geranium Canal site. The surface-water/groundwater interaction-potential estimates are in agreement with the generally moderate to high apparent resistivity, the greater spatial heterogeneity, and the variable lithologic texture. A higher interaction potential as compared to the canal sites is expected because of the higher subsurface resistivity and greater lithologic heterogeneity.

Scientific Investigations Report↗

Effects of irrigation practices on water use in the groundwater management districts within the Kansas high plains, 1991-2003

Data compiled for the High Plains region of Kansas that includes five Groundwater Management Districts (GMDs) were analyzed for trends in irrigation water use, acres irrigated, precipitation, irrigation system types, and irrigated crop types to determine the effects of irrigation practices on water use over time. For the study period 1991 through 2003, precipitation decreased significantly (with 95-percent confidence) in northwestern and west-central Kansas but not in the southwestern and south-central parts of the State. Irrigation water use had no statistically significant trend during this period. There was a good (R= -0.77) relation between average regional precipitation and total GMD irrigation water use. When irrigation water use was adjusted for this relation, there was a positive trend (90-percent confidence level) in the adjusted irrigation water use. Another adjustment to water use was made using the ratio of annual precipitation to 1991-2005 average precipitation, which resulted in a negative trend (95-percent confidence level) in irrigation water use. This demonstrated the contradictory nature of precipitation adjustments to water use, making their utility somewhat suspect. GMD 3 in southwestern Kansas used 63 percent of the total acre-feet of irrigation water within all the GMDs. When all GMDs are considered, the number of irrigated acres for flood and center pivot systems without drop nozzles decreased significantly during the study period. At the same time the number of drop nozzle irrigated acres increased significantly. The number of irrigated acres of water-intensive crops (corn, alfalfa, and soybeans) also increased significantly, whereas the number of less- or non-water-intensive crops (grain sorghum and wheat), and multiple crop type acres decreased. Drop nozzle irrigation systems used approximately 2 percent less water in a year-by-year comparison than center pivot systems and 8 to 11 percent less water than flood irrigation. The best estimator of irrigation water use incorporated total acres irrigated and annual average or March-October regional precipitation. A conclusion that can be drawn from the trend analyses described in this report is that, although irrigation water use for all GMDs showed no statistically significant trend, an apparent increased efficiency of center pivots irrigation systems with drop nozzles has allowed more water-intensive crops to be grown on more irrigated acres.

Scientific Investigations Report↗

Water-quality trends in the Kansas River, Kansas, since enactment of the Clean Water Act, 1972–2020

The Clean Water Act was passed by Congress in 1972 to regulate pollution within the waters of the United States. The U.S. Geological Survey (USGS), in cooperation with the Kansas Department of Health and Environment (KDHE), the Kansas Water Office, the Nature Conservancy, the City of Lawrence, the City of Manhattan, the City of Olathe, the City of Topeka, WaterOne, and Evergy, compiled and analyzed historical streamflow and water-quality data collected by USGS and KDHE to characterize trends in water-quality constituents of interest because of their relation to water supply, drinking-water treatment, and sediment and nutrient transport, among others (total dissolved solids, chloride, ammonia, dissolved inorganic nitrogen [ammonia and nitrate plus nitrite], total nitrogen, orthophosphate, total phosphorus, total suspended solids, and fecal coliform bacteria) during mean- and low-flow conditions in the Kansas River since the passage of the Clean Water Act in 1972 through 2020. Trends in water-quality concentrations, or densities, and loads were analyzed using the Exploration and Graphics for RivER Trends R package and Weighted Regressions on Time, Discharge, and Season (WRTDS) model at upstream (Kansas River at Wamego, Kansas; USGS station 06887500) and downstream (Kansas River at De Soto, Kansas; USGS station 06892350) locations along the Kansas River using streamflow and water-quality data collected by the USGS and KDHE during 1972 through 2020. The Exploration and Graphics for RivER Trends Confidence Intervals R package and WRTDS bootstrap test estimated direction, uncertainty, and likelihood of trends in concentration and loads for each water-quality constituent of interest. Downward trends in concentration and load were observed for 5 of the 9 water-quality constituents at both sites during mean-flow conditions during the study period. During low-flow conditions, 7 of the 9 constituents exhibited downward trends, possibly reflecting reductions in point-source contributions to the Kansas River. Downward trends in ammonia, dissolved inorganic nitrogen, and total nitrogen during mean- and low-flow conditions were observed at both Kansas River sites, which were similar to patterns observed nationally. Upward trends were generally observed for orthophosphate and total phosphorus, which were similar to patterns observed at sites in the Mississippi River Basin. Downward trends, or no trend, were observed for chloride. Upward and downward trends were observed for total dissolved solids. Downward trends in total suspended solids and fecal coliform bacteria were observed at both sites, which were also similar to patterns observed nationally. The long-term trend analyses in this report are an essential step to understanding how water-quality conditions have changed in the Kansas River since the passage of the Clean Water Act.

Kansas↗

Groundwater quality and hydrology with emphasis on selenium mobilization and transport in the Lower Gunnison River Basin, Colorado, 2012–16

Dissolved selenium is a contaminant of concern in the lower Gunnison River Basin, Colorado. Selenium is naturally present in the Cretaceous Mancos Shale and is leached to groundwater and surface water by irrigation. The groundwater on the east side of the Uncompahgre River in Delta and Montrose Counties is one of the primary sources of selenium concentration and load to surface water in the lower Gunnison River Basin. Although little information about the contribution of groundwater to surface water has been historically available, groundwater has often been implicated as an appreciable source of selenium to surface water. From 2012 to 2016, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, the Colorado Water Conservation Board, and the Gunnison Basin Selenium Management Program, established a 30-well groundwater-monitoring network on irrigated land to characterize the hydrology and groundwater quality of the shallow groundwater system on the east side of the Uncompahgre River in the lower Gunnison River Basin. The installation of the 30-well network and the data collected allowed for the development of a conceptual model of selenium mobilization and transport in the shallow groundwater system. Monitoring wells were completed in surficial deposits and in weathered Mancos Shale, which generally exhibited unconfined and confined conditions, respectively. Groundwater-quality monitoring provides information on the distribution of selenium and the geochemical processes controlling selenium concentrations in shallow groundwater. Monitoring wells were sampled between August 2013 and March 2015 to understand groundwater quality, seasonality, sources of recharge, and groundwater age. Concentrations of dissolved selenium ranged from below the limit of detection to 4,100 micrograms per liter (µg/L), with a median concentration of 14 µg/L. Concentrations showed a high degree of spatial variability and no seasonal difference. Similarly, no seasonal pattern was observed in specific conductance values of groundwater despite the considerably lower specific conductance value of irrigation water. Reduction-oxidation processes are important controls on selenium mobility. Nitrate derived from geologic material was a primary control on reduction-oxidation conditions in groundwater and inhibited selenium reduction to less mobile forms. Nitrate was reduced by denitrification in groundwater, but it was not reduced to the extent necessary to allow for selenium reduction. Groundwater ages were determined for groundwater samples from eight wells and ranged from 6 to 20 years old. Isotopic data indicate groundwater was recharged by irrigation water; no information collected supported an older, deeper source of recharge to the shallow groundwater system. Data on water level in all wells showed response to irrigation practices, but the response was delayed in some wells, which may be an indication of distance from recharge source.

Colorado↗

Public views of wetlands and waterfowl conservation in the United States—Results of a survey to inform the 2018 update of the North American Waterfowl Management Plan

Executive Summary This report provides information from a general public survey conducted in early 2017 to help inform the North American Waterfowl Management Plan (NAWMP) 2018 update. This report is intended for use by the NAWMP advisory committees and anyone interested in the human dimensions of wetlands and waterfowl management. A mail-out survey was sent to 5,000 addresses in the United States, which were selected randomly in proportion to the population of each State. A total of 1,030 completed surveys representing 49 States were returned, resulting in a 23 percent overall response rate. When comparing the demographics of the respondents to the U.S. census data, this sample overrepresented people who are male, older, highly educated, and white. Data were weighted on gender and age to make the results more representative of the overall U.S. population. Additionally, this sample had higher participation rates in all wildlife-related recreation activities than has been found in previous studies; this indicates there may have been selection bias, with people interested in nature-related topics more likely to complete the survey. Therefore, results likely represent a segment of the U.S. public that is more oriented toward and aware of wildlife and conservation issues than the general public as a whole. Because of this bias, responses for each question were also broken down by recreationist type (hunters, anglers, wildlife viewers, and no wildlife-related recreation). Additionally, responses for each question were split by administrative flyway (Atlantic, Central, Mississippi, Pacific) and residency (urban, urban cluster, rural) to better understand the different groups. Most respondents knew of wetlands in their local area or community, and more than half had visited wetlands in the previous 12 months. Of those who had visited wetlands, the most common reasons were for walking/hiking/biking and enjoying nature/picnicking. In addition, this sample was very concerned about the reduction or loss of ecosystem services resulting from wetlands degradation or loss. A majority of respondents were somewhat or very concerned about 9 out of 10 wetlands benefits, with hunting opportunities being the only benefit the majority of people were not concerned about. People were the most concerned about clean water, clean air, and providing a home for wildlife. In contrast, people were least concerned about hunting opportunities and wetlands providing scenic places for inspiration or spiritual renewal. Communication about wetlands that focuses on habitat, clean air, and clean water may resonate with the widest variety of people. However, if communication is targeted toward wildlife-related recreationists, including more information about the recreation benefits of wetlands and emphasizing habitat benefits may be the most effective. Many people reported having participated in conservation behaviors in the last year. The most popular activity was making the yard more desirable to wildlife, with more than three-fourths of respondents participating, followed by donating money to support wildlife/habitat conservation and talking to others in their community about conservation issues. There was lower participation in conservation behavior specifically related to wetlands and waterfowl, with two-fifths of respondents voting for candidates or ballot issues to support wetlands/waterfowl conservation and one-third advocating for political action to conserve wetlands/waterfowl. In order to better understand how to reach out to the public on nature-related topics, preferences in information channels and trust in information sources were explored. Respondents were mostly likely to want to receive their information through personal experience, by reading or accessing online content, and through watching visual media online. People were least likely to want to receive information through listening to recorded audio media, attending educational opportunities, and listening to live audio media. These results emphasize the importance of having content available online in an easily accessible and appealing format. Visual media in particular seems to be preferred across a wide variety of people. Additionally, people had the highest trust in scientific organizations, universities/educational organizations, and friends/family/neighbors/colleagues. The least trusted sources were national media/news, religious organizations, and local media/news. Urban respondents had higher trust levels overall, particularly for the government. Hunters and those in rural areas had lower levels of trust in the government but higher trust in family/friends. In this sample, few respondents reported hunting waterfowl (5 percent) or hunting other game (16 percent) in the last year. Additionally, few respondents said they were very or somewhat likely to hunt waterfowl in the following 12 months. Even after considering that self-selection bias would make it more likely for hunters to respond to the survey, the relatively small number of respondents who identified as hunters reinforces that engagement of other wildlife-related recreationists is critical to meeting the third goal of the NAWMP 2012 revision—to increase numbers of wetlands/waterfowl conservationists. Many people also had negative perceptions of hunting. Half of the respondents stated that hunting would be unpleasant, and two-fifths believed hunting would be boring. In contrast, people had more favorable attitudes toward birdwatching, with only one-sixth saying it would be unpleasant and less than one-third saying it would be boring. A majority of respondents thought they could easily go hunting or birdwatching in the following 12 months. Overall, people had much more positive views toward birdwatching and expressed fewer barriers to participating in it. When asked what would prevent them from hunting, the most frequently stated reasons were moral opposition, no interest, personal health, and time constraints; for birdwatching, the most popular responses were nothing, no interest, and time constraints. These responses indicate it may be beneficial to move beyond hunting and find ways for other groups, such as birdwatchers, to play a more active role in conservation. Although not many people hunted and many people tended to have negative attitudes toward hunting, over three-fourths of people said they knew a hunter. Given that wildlife viewers, those who did not participate in wildlife-related recreation, and urban residents tended to have negative attitudes toward hunting and (or) were not interested in participating, attempting to recruit them to participate in hunting may not be effective. However, given how many people across all groups knew a hunter and the relatively high levels of trust people had in their friends/family, hunters may be effective ambassadors for promoting waterfowl and wetlands conservation among nonhunters. Additionally, because people had less preference for viewing waterfowl and other game birds compared to their preference for seeing hummingbirds and birds of prey, conservation efforts that extend beyond waterfowl and include other species that benefit from wetlands may have more appeal to a broader range of people.

Open-File Report↗

Application of hydrogeology and groundwater-age estimates to assess the travel time of groundwater at the site of a landfill to the Mahomet Aquifer, near Clinton, Illinois

The U.S. Geological Survey used interpretations of hydrogeologic conditions and tritium-based groundwater age estimates to assess the travel time of groundwater at a landfill site near Clinton, Illinois (the “Clinton site”) where a chemical waste unit (CWU) was proposed to be within the Clinton landfill unit #3 (CLU#3). Glacial deposits beneath the CWU consist predominantly of low-permeability silt- and clay-rich till interspersed with thin (typically less than 2 feet in thickness) layers of more permeable deposits, including the Upper and Lower Radnor Till Sands and the Organic Soil unit. These glacial deposits are about 170 feet thick and overlie the Mahomet Sand Member of the Banner Formation. The Mahomet aquifer is composed of the Mahomet Sand Member and is used for water supply in much of east-central Illinois. Eight tritium analyses of water from seven wells were used to evaluate the overall age of recharge to aquifers beneath the Clinton site. Groundwater samples were collected from six monitoring wells on or adjacent to the CLU#3 that were open to glacial deposits above the Mahomet aquifer (the upper and lower parts of the Radnor Till Member and the Organic Soil unit) and one proximal production well (approximately 0.5 miles from the CLU#3) that is screened in the Mahomet aquifer. The tritium-based age estimates were computed with a simplifying, piston-flow assumption: that groundwater moves in discrete packets to the sampled interval by advection, without hydrodynamic dispersion or mixing. Tritium concentrations indicate a recharge age of at least 59 years (pre-1953 recharge) for water sampled from deposits below the upper part of the Radnor Till Member at the CLU#3, with older water expected at progressively greater depth in the tills. The largest tritium concentration from a well sampled by this study (well G53S; 0.32 ± 0.10 tritium units) was in groundwater from a sand deposit in the upper part of the Radnor Till Member; the shallowest permeable unit sampled by this study. That result indicated that nearly all groundwater sampled from well G53S entered the aquifer as recharge before 1953. Tritium was detected in a trace concentration in one sample from a second monitoring well open to the upper part of the Radnor Till Member (well G07S; 0.11 ± 0.09 tritium units), and not detected in samples collected from two monitoring wells open to a sand deposit in the lower part of the Radnor Till Member, from two samples collected from two monitoring wells open to the Organic Soil unit, and in two samples collected from a production well screened in the middle of the Mahomet aquifer (a groundwater sample and a sequential replicate sample). The lack of tritium in five of the six groundwater samples collected from the shallow permeable units beneath CLU#3 site and the two samples from the one Mahomet aquifer well indicates an absence of post-1952 recharge. Groundwater-flow paths that could contribute post-1952 recharge to the lower part of the Radnor Till Member, the Organic Soil unit, or the Mahomet aquifer at the CLU#3 are not indicated by these data. Hypothetical two-part mixtures of tritium-dead, pre-1953 recharge water and decay-corrected tritium concentrations in post-1952 recharge were computed and compared with tritium analyses in groundwater sampled from monitoring wells at the CLU#3 site to evaluate whether tritium concentrations in groundwater could be represented by mixtures involving some post-1952 recharge. Results from the hypothetical two-part mixtures indicate that groundwater from monitoring well (G53S) was predominantly composed of pre-1953 recharge and that if present, younger, post-1955 recharge, contributed less than 2.5 percent to that sample. The hypothetical two-part mixing results also indicated that very small amounts of post-1952 recharge composing less than about 2.5 percent of the sample volume could not be distinguished in groundwater samples with tritium concentrations less than about 0.15 TU. The piston-flow based age of recharge determined from the tritium concentration in the groundwater sample from monitoring well G53S yielded an estimated maximum vertical velocity from the land surface to the upper part of the Radnor Till Member of 0.85 feet per year or less. This velocity, ifassumed to apply to the remaining glacial till deposits above the Mahomet aquifer, indicates that recharge flows through the 170 feet of glacial deposits between the base of the proposed chemical waste unit and the top of the Mahomet aquifer in a minimum of 200 years or longer. Analysis of hydraulic data from the site, constrained by a tritium-age based maximum groundwater velocity estimate, computed minimum estimates of effective porosity that range from about 0.021 to 0.024 for the predominantly till deposits above the Mahomet aquifer. Estimated rates of transport of recharge from land surface to the Mahomet aquifer for the CLU#3 site computed using the Darcy velocity equation with site-specific data were about 260 years or longer. The Darcy velocity-based estimates were computed using values that were based on tritium data, estimates of vertical velocity and effective porosity and available site-specific data. Solution of the Darcy velocity equation indicated that maximum vertical groundwater velocities through the deposits above the aquifer were 0.41 or 0.61 feet per year, depending on the site-specific values of vertical hydraulic conductivity (laboratory triaxial test values) and effective porosity used for the computation. The resulting calculated minimum travel times for groundwater to flow from the top of the Berry Clay Member (at the base of the proposed chemical waste unit) to the top of the Mahomet aquifer ranged from about 260 to 370 years, depending on the velocity value used in the calculation. In comparison, plausible travel times calculated using vertical hydraulic conductivity values from a previously published regional groundwater flow model were either slightly less than or longer than those calculated using site data and ranged from 230 to 580 years. Tritium data from 1996 to 2011 USGS regional sampling of groundwater from domestic wells in the confined part of the Mahomet aquifer—which are 2.5 to about 40 miles from the Clinton site—were compared with site-specific data from a production well at the Clinton site. Tritium-based groundwater-age estimates indicated predominantly pre- 1953 recharge dates for USGS and other prior regional samples of groundwater from domestic wells in the Mahomet aquifer. These results agreed with the tritium-based, pre-1953 recharge age estimated for a groundwater sample and a sequential replicate sample from a production well in the confined part of the Mahomet aquifer beneath the Clinton site. The regional tritium-based groundwater age estimates also were compared with pesticide detections in samples from distal domestic wells in the USGS regional network that are about 2.5 to 40 miles from the Clinton site to identify whether very small amounts of post-1952 recharge have in places reached confined parts of the Mahomet aquifer at locations other than the Clinton site in an approximately 2,000 square mile area of the Mahomet aquifer. Very small amounts of post-1952 recharge were defined in this analysis as less than about 2.5 percent of the total recharge contributing to a groundwater sample, based on results from the two-part mixing analysis of tritium data from the Clinton site. Pesticide-based groundwater-age estimates based on 22 detections of pesticides (13 of these detections were estimated concentrations), including atrazine, deethylatrazine (2-Chloro-4-isopropylamino-6-amino- s-triazine), cyanazine, diazinon, metolachlor, molinate, prometon, and trifluralin in groundwater samples from 10 domestic wells 2.5 to about 40 miles distant from the Clinton site indicate that very small amounts of post-1956 to post-1992 recharge can in places reach the confined part of the Mahomet aquifer in other parts of central Illinois. The relative lack of tritium in these samples indicate that the amounts of post-1956 to post-1992 recharge contributing to the 10 domestic wells were a very small part of the overall older groundwater sampled from those wells. The flow process by which very small amounts of pesticide-bearing groundwater reached the screened intervals of the 10 domestic wells could not be distinguished between well-integrity related infiltration and natural hydrogeologic features. Potential explanations include: (1) infiltration through man-made avenues in or along the well, (2) flow of very small amounts of post-1956 to post-1992 recharge through sparsely distributed natural permeable aspects of the glacial till and diluted by mixing with older groundwater, or (3) a combination of both processes. Presuming the domestic wells sampled by the USGS in 1996–2011 in the regional study of the confined part of the Mahomet aquifer are adequately sealed and produce groundwater that is representative of aquifer conditions, the regional tritium and pesticide-based groundwater-age results indicate substantial heterogeneity in the glacial stratigraphy above the Mahomet aquifer. The pesticide-based groundwater-age estimates from the domestic wells distant from the Clinton site also indicate that parts of the Mahomet aquifer with the pesticide detections can be susceptible to contaminant sources at the land surface. The regional pesticide and tritium results from the domestic wells further indicate that a potential exists for possible contaminants from land surface to be transported through the glacial drift deposits that confine the Mahomet aquifer in other parts of central Illinois at faster rates than those computed for recharge at the Clinton site, including CLU#3. This analysis indicates the potential value of sub-microgram-per-liter level concentrations of land-use derived indicators of modern recharge to indicate the presence of very small amounts of modern, post-1952 age recharge in overall older, pre-1953 age groundwater.

Illinois↗

Status of water levels and selected water-quality conditions in the Sparta-Memphis aquifer in Arkansas, Spring-Summer 2003

During the spring of 2003, water levels were measured in 341 wells in the Sparta-Memphis aquifer in Arkansas. Waterquality samples were collected for temperature and specificconductance measurements during the spring-summer of 2003 from 70 wells in Arkansas in the Sparta-Memphis aquifer. Maps of areal distribution of potentiometric surface, change in waterlevel measurements from 1999 to 2003, and specific-conductance data reveal spatial trends across the study area. The highest water-level altitude measured in Arkansas was 328 feet above National Geodetic Vertical Datum of 1929 (NGVD of 1929) in Craighead County; the lowest water-level altitude was 199 feet below NGVD of 1929 in Union County. Three large cones of depression are shown in the 2003 potentiometric surface map, centered in Columbia, Jefferson, and Union Counties in Arkansas as a result of large withdrawals for industrial and public supplies. A broad depression exists in western Poinsett County in Arkansas. The potentiometric surface indicates that large withdrawals have altered or reversed the natural direction of flow in most areas. In the northern third of the study area the flow is from the east, west, and north towards the broad depression in Poinsett County. In the central third of the study area the flow is dominated by the cone of depression centered in Jefferson County. In the southern third of the study area the flow is dominated by the two cones of depression in Union and Columbia Counties. A map of water-level changes from 1999 to 2003 was constructed using water-level measurements from 281 wells. The largest rise in water level measured was about 57.8 feet in Columbia County. The largest decline in water level measured was about -71.6 feet in Columbia County. Areas with a general rise are shown in Arkansas, Bradley, Calhoun, Cleveland, Columbia, Ouachita, and Union Counties. Areas with a general decline are shown in Craighead, Crittenden, Cross, Desha, Drew, Jefferson, Lonoke, Phillips, Poinsett, Prairie, and Woodruff Counties. Hydrographs were constructed for wells with a minimum of 25 years of water-level measurements. A trend line using a linear regression was calculated for the period of record from spring of 1978 to spring of 2003 to determine the annual decline or rise in feet per year for water levels in each well. The hydrographs were grouped by county. The mean values for county annual water-level decline or rise ranged from -1.42 to 0.27 foot per year. Specific conductance ranged from 82 microsiemens per centimeter at 25 degrees Celsius in Jefferson County to about 1,210 microsiemens per centimeter at 25 degrees Celsius in Lee County. The mean specific conductance was 400 microsiemens per centimeter at 25 degrees Celsius.

Scientific Investigations Report↗

Thermal effects of dams in the Willamette River basin, Oregon

Methods were developed to assess the effects of dams on streamflow and water temperature in the Willamette River and its major tributaries. These methods were used to estimate the flows and temperatures that would occur at 14 dam sites in the absence of upstream dams, and river models were applied to simulate downstream flows and temperatures under a no-dams scenario. The dams selected for this study include 13 dams built and operated by the U.S. Army Corps of Engineers (USACE) as part of the Willamette Project, and 1 dam on the Clackamas River owned and operated by Portland General Electric (PGE). Streamflows in the absence of upstream dams for 2001-02 were estimated for USACE sites on the basis of measured releases, changes in reservoir storage, a correction for evaporative losses, and an accounting of flow effects from upstream dams. For the PGE dam, no-project streamflows were derived from a previous modeling effort that was part of a dam-relicensing process. Without-dam streamflows were characterized by higher peak flows in winter and spring and much lower flows in late summer, as compared to with-dam measured flows. Without-dam water temperatures were estimated from measured temperatures upstream of the reservoirs (the USACE sites) or derived from no-project model results (the PGE site). When using upstream data to estimate without-dam temperatures at dam sites, a typical downstream warming rate based on historical data and downstream river models was applied over the distance from the measurement point to the dam site, but only for conditions when the temperature data indicated that warming might be expected. Regressions with measured temperatures from nearby or similar sites were used to extend the without-dam temperature estimates to the entire 2001-02 time period. Without-dam temperature estimates were characterized by a more natural seasonal pattern, with a maximum in July or August, in contrast to the measured patterns at many of the tall dam sites where the annual maximum temperature typically occurred in September or October. Without-dam temperatures also tended to have more daily variation than with-dam temperatures. Examination of the without-dam temperature estimates indicated that dam sites could be grouped according to the amount of streamflow derived from high-elevation, spring-fed, and snowmelt-driven areas high in the Cascade Mountains (Cougar, Big Cliff/Detroit, River Mill, and Hills Creek Dams: Group A), as opposed to flow primarily derived from lower-elevation rainfall-driven drainages (Group B). Annual maximum temperatures for Group A ranged from 15 to 20 degree(s)C, expressed as the 7-day average of the daily maximum (7dADM), whereas annual maximum 7dADM temperatures for Group B ranged from 21 to 25 degrees C. Because summertime stream temperature is at least somewhat dependent on the upstream water source, it was important when estimating without-dam temperatures to use correlations to sites with similar upstream characteristics. For that reason, it also is important to maintain long-term, year-round temperature measurement stations at representative sites in each of the Willamette River basin's physiographic regions. Streamflow and temperature estimates downstream of the major dam sites and throughout the Willamette River were generated using existing CE-QUAL-W2 flow and temperature models. These models, originally developed for the Willamette River water-temperature Total Maximum Daily Load process, required only a few modifications to allow them to run under the greatly reduced without-dam flow conditions. Model scenarios both with and without upstream dams were run. Results showed that Willamette River streamflow without upstream dams was reduced to levels much closer to historical pre-dam conditions, with annual minimum streamflows approximately one-half or less of dam-augmented levels. Thermal effects of the dams varied according to the time of year, from cooling in mid-summer to warm

Scientific Investigations Report↗

Geologic framework and hydrogeologic characteristics in the southern part of the Rancho Diana Natural Area, northern Bexar County, Texas, 2008-10

The area designated by the city of San Antonio as the Rancho Diana Natural Area is in northern Bexar County, near San Antonio, Texas. During 2008-10, the U.S. Geological Survey, in cooperation with the city of San Antonio, documented the geologic framework and mapped the hydrogeologic characteristics for the southern part of the Rancho Diana Natural Area. The geologic framework of the study area and its hydrogeologic characteristics were documented using field observations and information from previously published reports. Many of the geologic and hydrogeologic features were found by making field observations through the dense vegetation along gridlines spaced approximately 25 feet apart and documenting the features as they were located. Surface geologic features were identified and hydrogeologic features such as caves, sinkholes, and areas of solutionally enlarged porosity were located using hand-held Global Positioning System units. The location data were used to create a map of the hydrogeologic subdivisions and the location of karst features. The outcrops of the Edwards and Trinity aquifer recharge zones were mapped by using hydrogeologic subdivisions modified from previous reports. All rocks exposed within the study area are of sedimentary origin and Lower Cretaceous in age. The valley floor is formed in the cavernous member of the upper Glen Rose Limestone of the Trinity Group. The hills are composed of the basal nodular member, dolomitic member, Kirschberg evaporite member, and grainstone member of the Kainer Formation of the Edwards Group. Field observations made during this study of the exposed formations and members indicate that the formations and members typically are composed of mudstones, wackestones, packstones, grainstones, and argillaceous limestones, along with marls. The upper Glen Rose Limestone is approximately 410 to 450 feet thick but only the upper 70 feet is exposed in the study area. The Kainer Formation is approximately 255 feet thick in the study area and is composed of, in ascending order, the basal nodular member, dolomitic member, Kirschberg evaporite member, and grainstone member. The Edwards and Trinity aquifers contain a combination of fabric-selective and not-fabric-selective porosities. Porosity types observed in the study area that can increase the effective porosity and increase permeability include solutionally enlarged caves, sinkholes, fractures, bedding planes, channels, molds and vugs. Caves found during hydrogeologic mapping might have been spring discharge points, but sufficient downcutting over geologic time in the rocks has occurred so that springs discharge at lower elevations near the creek channel. The mapped caves, sinkholes, and other areas of solutionally enlarged porosity might facilitate recharge during large storm events when runoff occurs on the hillsides; additional areally distributed recharge in the study area occurs as a result of infiltration.

Texas↗

Hydrogeologic framework and hydrologic budget components of the Columbia Plateau Regional Aquifer System, Washington, Oregon, and Idaho

The Columbia Plateau Regional Aquifer System (CPRAS) covers an area of about 44,000 square miles in a structural and topographic basin within the drainage of the Columbia River in Washington, Oregon, and Idaho. The primary aquifers are basalts of the Columbia River Basalt Group (CRBG) and overlying sediment. Eighty percent of the groundwater use in the study area is for irrigation, in support of a $6 billion per year agricultural economy. Water-resources issues in the Columbia Plateau include competing agricultural, domestic, and environmental demands. Groundwater levels were measured in 470 wells in 1984 and 2009; water levels declined in 83 percent of the wells, and declines greater than 25 feet were measured in 29 percent of the wells. Conceptually, the system is a series of productive basalt aquifers consisting of permeable interflow zones separated by less permeable flow interiors; in places, sedimentary aquifers overly the basalts. The aquifer system of the CPRAS includes seven hydrogeologic units-the overburden aquifer, three aquifer units in the permeable basalt rock, two confining units, and a basement confining unit. The overburden aquifer includes alluvial and colluvial valley-fill deposits; the three basalt units are the Saddle Mountains, Wanapum, and Grande Ronde Basalts and their intercalated sediments. The confining units are equivalent to the Saddle Mountains-Wanapum and Wanapum-Grande Ronde interbeds, referred to in this study as the Mabton and Vantage Interbeds, respectively. The basement confining unit, referred to as Older Bedrock, consists of pre-CRBG rocks that generally have much lower permeabilities than the basalts and are considered the base of the regional flow system. Based on specific-capacity data, median horizontal hydraulic conductivity (Kh) values for the overburden, basalt units, and bedrock are 161, 70, and 6 feet per day, respectively. Analysis of oxygen isotopes in water and carbon isotopes in dissolved inorganic carbon from groundwater samples indicates that groundwater in the CPRAS ranges in age from modern (<50 years) to Pleistocene (>10,000 years). The oldest groundwater resides in deep, downgradient locations indicating that groundwater movement and replenishment in parts of this regional aquifer system have operated on long timescales under past natural conditions, which is consistent with the length and depth of long flow paths in the system. The mean annual recharge from infiltration of precipitation for the 23-year period 1985-2007 was estimated to be 4.6 inches per year (14,980 cubic feet per second) using a polynomial regression equation based on annual precipitation and the results of recharge modeling done in the 1980s. A regional-scale hydrologic budget was developed using a monthly SOil WATer (SOWAT) Balance model to estimate irrigation-water demand, groundwater flux (recharge or discharge), direct runoff, and soil moisture within irrigated areas. Mean monthly irrigation throughout the study area peaks in July at 1.6 million acre-feet (MAF), of which 0.45 and 1.15 MAF are from groundwater and surface-water sources, respectively. Annual irrigation water use in the study area averaged 5.3 MAF during the period 1985-2007, with 1.4 MAF (or 26 percent) supplied from groundwater and 3.9 MAF supplied from surface water. Mean annual recharge from irrigation return flow in the study area was 4.2 MAF (1985-2007) with 2.1 MAF (50 percent) occurring within the predominately surface-water irrigated regions of the study area. Annual groundwater-use estimates were made for public supply, self-supplied domestic, industrial, and other uses for the period 1984 through 2009. Public supply groundwater use within the study area increased from 200,600 acre-feet per year (acre-ft/yr) in 1984 to 269,100 acre-ft/yr in 2009. Domestic self-supplied groundwater use increased from 54,580 acre-ft/yr in 1984 to 71,160 acre-ft/yr in 2009. Industrial groundwater use decreased from 53,390 acre-ft/yr in 1984 t

Scientific Investigations Report↗

Water-Quality Conditions and Constituent Loads, Water Years 1996-2002, and Water-Quality Trends, Water Years 1983-2002, in the Scituate Reservoir Drainage Area, Rhode Island

The Scituate Reservoir is the primary source of drinking water for more than 60 percent of the population of Rhode Island. Water-quality data and streamflow data collected at 37 surface-water monitoring stations in the Scituate Reservoir drainage area, Rhode Island, from October 1, 1995 through September 30, 2002, (water years (WY) 1996-2002) were analyzed to determine water-quality conditions and constituent loads in the drainage area. Trends in water quality, including physical properties and concentrations of constituents, were investigated for the same period and for a longer period from October 1, 1982 through September 30, 2002 (WY 1983-2002). Water samples were collected and analyzed by Providence Water Supply Board, the agency that manages the Scituate Reservoir. Streamflow data were collected by the U.S. Geological Survey. Median values and other summary statistics were calculated for WY 1996-2002 for all 37 monitoring stations for pH, color, turbidity, alkalinity, chloride, nitrite, nitrate, total coliform bacteria, Escherichia coli (E. coli) bacteria, orthophosphate, iron, and manganese. Instantaneous loads and yields (loads per unit area) of total coliform and E. coli bacteria (indicator bacteria), chloride, nitrite, nitrate, orthophosphate, iron, and manganese were calculated for all sampling dates during WY 1996-2002 for the 23 stations with streamflow data. Values of physical properties and concentrations of constituents were compared to State and Federal water-quality standards and guidelines, and were related to streamflow, land-use characteristics, and road density. Tributary stream water in the Scituate Reservoir drainage area for WY 1996-2002 was slightly acidic (median pH of all stations equal to 6.1) and contained low concentrations of chloride (median 13 milligrams per liter (mg/L)), nitrate (median 0.04 mg/L as N), and orthophosphate (median 0.04 mg/L as P). Turbidity and alkalinity values also were low with median values of 0.62 nephelometric turbidity units and 4.8 mg/L as calcium carbonate, respectively. Indicator bacteria were detected in samples from all stations, but median concentrations were low, 23 and 9 colony-forming units per 100 mL for total coliform and E. coli bacteria, respectively. Median values of several physical properties and median concentrations of several constituents that can be related to human activities correlated positively with the percentages of developed land and correlated negatively with the percentages of forest cover in the drainage areas of the monitoring stations. Median concentrations of chloride also correlated positively with the density of roads in the drainage areas of monitoring stations, likely reflecting the effects of road-salt applications. Median values of color correlated positively with the percentages of wetlands in the drainage areas of monitoring stations, reflecting the natural sources of color in tributary stream waters. Negative correlations of turbidity, indicator bacteria, and chloride with streamflow likely reflect seasonal patterns, in which higher values and concentrations of these properties and constituents occur during low-flow conditions at the ends of water years. Similar seasonal patterns were observed for pH, alkalinity, and color. Loads and yields of chloride, nitrate, orthophosphate, and bacteria varied among monitoring stations in the Scituate Reservoir drainage area. Loads generally were higher at stations with larger drainage areas and at stations in the eastern, more developed parts of the Scituate Reservoir drainage area. Yields generally were higher at stations in the eastern parts of the drainage area. Upward trends in pH were identified for nearly half the monitoring stations and may reflect regional reductions in acid precipitation. Upward and downward trends were identified in chloride concentrations at various stations; upward trends may reflect the effects of increasing development, whereas strong downward trends at

Scientific Investigations Report↗

Specific Conductance and Dissolved-Solids Characteristics for the Green River and Muddy Creek, Wyoming, Water Years 1999-2008

Southwestern Wyoming is an area of diverse scenery, wildlife, and natural resources that is actively undergoing energy development. The U.S. Department of the Interior's Wyoming Landscape Conservation Initiative is a long-term science-based effort to assess and enhance aquatic and terrestrial habitats at a landscape scale, while facilitating responsible energy development through local collaboration and partnerships. Water-quality monitoring has been conducted by the U.S. Geological Survey on the Green River near Green River, Wyoming, and Muddy Creek near Baggs, Wyoming. This monitoring, which is being conducted in cooperation with State and other Federal agencies and as part of the Wyoming Landscape Conservation Initiative, is in response to concerns about potentially increased dissolved solids in the Colorado River Basin as a result of energy development. Because of the need to provide real-time dissolved-solids concentrations for the Green River and Muddy Creek on the World Wide Web, the U.S. Geological Survey developed regression equations to estimate dissolved-solids concentrations on the basis of continuous specific conductance using relations between measured specific conductance and dissolved-solids concentrations. Specific conductance and dissolved-solids concentrations were less varied and generally lower for the Green River than for Muddy Creek. The median dissolved-solids concentration for the site on the Green River was 318 milligrams per liter, and the median concentration for the site on Muddy Creek was 943 milligrams per liter. Dissolved-solids concentrations ranged from 187 to 594 milligrams per liter in samples collected from the Green River during water years 1999-2008. Dissolved-solids concentrations ranged from 293 to 2,485 milligrams per liter in samples collected from Muddy Creek during water years 2006-08. The differences in dissolved-solids concentrations in samples collected from the Green River compared to samples collected from Muddy Creek reflect the different basin characteristics. Relations between specific conductance and dissolved-solids concentrations were statistically significant for the Green River (p-value less than 0.001) and Muddy Creek (p-value less than 0.001); therefore, specific conductance can be used to estimate dissolved-solids concentrations. Using continuous specific conductance values to estimate dissolved solids in real-time on the World Wide Web increases the amount and improves the timeliness of data available to water managers for assessing dissolved-solids concentrations in the Colorado River Basin.

Scientific Investigations Report↗