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USGS2007

Hydrologic significance of carbon monoxide concentrations in ground water

Dissolved carbon monoxide (CO) is present in ground water produced from a variety of aquifer systems at concentrations ranging from 0.2 to 20 nanomoles per liter (0.0056 to 0.56 μg/L). In two shallow aquifers, one an unconsolidated coastal plain aquifer in Kings Bay, Georgia, and the other a fractured‐bedrock aquifer in West Trenton, New Jersey, long‐term monitoring showed that CO concentrations varied over time by as much as a factor of 10. Field and laboratory evidence suggests that the delivery of dissolved oxygen to the soil zone and underlying aquifers by periodic recharge events stimulates oxic metabolism and produces transiently high CO concentrations. In between recharge events, the aquifers become anoxic and more substrate limited, CO is consumed as a carbon source, and CO concentrations decrease. According to this model, CO concentrations provide a transient record of oxic metabolism affecting ground water systems after dissolved oxygen has been fully consumed. Because the delivery of oxygen affects the fate and transport of natural and anthropogenic contaminants in ground water, CO concentration changes may be useful for identifying predominantly anoxic ground water systems subject to periodic oxic or microaerophilic conditions.

Ground Water↗

USGS2002

Simulation of Transient Ground-Water Flow in the Valley-Fill Aquifers of the Upper Rockaway River Basin, Morris County, New Jersey

More than 90 percent of the public water supply in the upper Rockaway River Valley in Morris County, New Jersey, is obtained from ground-water withdrawals from the valley-fill aquifers. During 1997, an average of 9.6 million gallons per day of ground water was withdrawn from these aquifers. The aquifer system consists of an unconfined aquifer (upper aquifer) and a locally confined aquifer (lower aquifer), which are composed of sands and gravels. These aquifers are separated by a discontinuous confining unit that consists mostly of silt and clay. Increases in ground-water withdrawals can induce movement of water from streams to wells, increase flow from the upper aquifer to the lower aquifer, and reduce base flow in the Rockaway River downstream. A ground-water-flow model was used to simulate and quantify the effects of current withdrawals on the valley-fill aquifer system under transient monthly conditions. Recharge over the model area varies both spatially and temporally. Part of model calibration consisted of adjusting percentages of monthly precipitation that recharges the valley-fill aquifer system. More recharge occurs during winter and spring than during summer and fall. This seasonal variation affects ground-water discharge to the Rockaway River. Ground-water withdrawals from the valleyfill aquifers also affect ground-water discharge to the Rockaway River. Three scenarios were simulated to observe the effects of ground-water withdrawals on ground-water discharge to the Rockaway River and to determine the extent to which variations in rates of withdrawals correspond to variations in rates of streamflow depletion. Streamflow depletion was estimated by comparing model-computed ground-water discharge for the three scenarios with the modelcomputed ground-water discharge under transient conditions. In scenario 1, all pumpage was removed from the model. In scenarios 2 and 3, 1 million gallons per day of ground-water withdrawals in excess of the current pumpage was withdrawn from the valley-fill aquifers. In scenario 2, the additional 1 million gallons per day of withdrawals were made from a hypothetical well located in the upper aquifer about 250 feet from the river. In scenario 3, the additional withdrawals were made from a hypothetical well located in the lower aquifer about 1,750 feet from the river. Results of scenario 1 indicated that the difference between the streamflow depletion and withdrawals is small; increases in ground-water withdrawals from the valley-fill aquifers correspond to decreases in ground-water discharge to the Rockaway River of approximately the same amount. Results of scenario 2 and 3 indicated that a lag time could occur between the introduction of withdrawals and the full magnitude of the effects of the withdrawals on streamflow depletion. A lag time of about seven months occurred for scenario 2 with the well placed in the upper aquifer. A longer lag time of more than 1.5 years occurred with the well placed in the lower aquifer and separated from the upper aquifer by a confining unit (scenario 3). Extreme low flow in the Rockaway River is mostly base flow. A flow-duration analysis of the Rockaway River at the surface-water gaging station upstream from the Boonton Reservoir during the drought of 1961-66 indicated that streamflow from the upper Rockaway River Basin alone might not be sufficient to meet the minimum passing flow of 7 million gallons per day during a drought. Under similar drought conditions today, during 3.2 percent of the drought time, streamflow at this station upstream from the reservoir would be less than the minimum passing flow requirement downstream from the reservoir.

Water-Resources Investigations Report↗

USGS1998

Flow and geochemistry along shallow ground-water flowpaths in an agricultural area in southeastern Wisconsin

Water-quality and geohydrologic data were collected from 19 monitor wells and a stream in an agricultural area in southeastern Wisconsin. These sites were located along a 2,700-ft transect from a local ground-water high to the stream. The transect is approximately parallel to the horizontal direction of ground-water flow at the water table. Most of the wells were installed in unconsolidated deposits at five locations along the transect and include an upgradient well nest, a midgradient well nest, a downgradient well nest, wells in the lowland area near the stream, and wells installed in the stream bottom. The data collected from this study site were used to describe the water quality and geohydrology of the area and to explain and model the variations in water chemistry along selected ground-water flowpaths. Water samples from most wells and the stream were analyzed for major ions, nutrients, pesticides, dissolved organic carbon, aluminum, tritium, CFCs, 15N, 18O, and dissolved gases. Measurements of temperature, pH, specific conductance, and dissolved oxygen were made in the field. Concentrations of all dissolved constituents were below Wisconsin ground-water quality enforcement standards. The concentrations of both nitrate and ammonium in precipitation concentrated by evapotranspiration are roughly equal to the concentrations of either in the shallow ground waters. The nitrogen and oxygen isotope data, however, indicate that soil ammonium, ammonium fertilizer, and animal waste are possible nitrate sources. Concentrated precipitation can also supply dissolved sulfate to the shallow ground waters and may be a principal source of pesticides to the ground water. However, some input of dissolved chloride to the ground water from mineral or anthropogenic sources is necessary. X-ray diffraction analyses of samples from 2 cores show the most abundant mineral to be dolomite, with subordinate quartz, microclme, and plagioclase, and minor amounts of mica, hornblende, and chlorite. Hydraulic conductivities determined from slug tests at selected wells range from 0.006 to 55 feet per day, with most values between 0.4 and 12 feet per day. A cross-sectional ground-water flow model, representing the water-table flow system, was developed for the site and was used to identify possible ground-water flowpaths for geocli^mical modeling. The model was calibrated against measured water levels and was most sensitive to variation in recharge and hydraulic conductivity. The calibrated model shows that downward flow from shallow to deeper wells within a nest may occur at the upgradient and midgradient well nests, but that flow from each well nest travels beneath downgradient nests to the stream. Pathline and travel-time analysis performed on the calibrated flow-model output yielded travel times to well screens that range from 5.8 to 59 years with a recharge of 4 inches per yr. Recharge dates based on tritium and CFC concentrations range from pre-1955 to 1986 and are consistent with flowpaths1 and travel times in the calibrated flow model. Changes in water quality along ground-water flowpaths were evaluated using the geochemical model PHREEQC. Geochemical mole balance models of shallow ground-water formation show that the principal reaction, by an order of magnitude, is dissolution of dolomite with CO2 . Concentration factors in the mole-balance models range from 1 to 11, with most values between 5 and 10, which provides independent support for the concentration factor of 8 based on recharge estimates used in the flow model. Ground water recharging at mid- and downgradient wells is oxic and contains dissolved nitrate, whereas the ground water discharging to the stream is anoxic and contains dissolved ammonium. Redox environments were defined at each well on the basis of relative concentrations of various dissolved redox-active species. Chemically permissible flowpaths inferred from the observed sequence of redox environments at well sites are consistent with flowpaths in the ground-water flow model. The transition from nitrate in recharging ground water to ammonium in ground water discharging to the stream suggests the possibility of nitrate reduction along the flowpath. None of the techniques employed in this study, however, were able to prove the occurrence of this reaction.

Michigan, Wisconsin↗

USGS1954

Geology and ground-water resources of Wichita and Greeley Counties, Kansas

This report describes the geography, geology, and ground-water resources of Wichita and Greeley counties in western Kansas. The area consists of a flat to gently rolling plain, which slopes eastward [at] about 15 feet per mile. A short reach of Ladder Creek (Beaver) is the only perennially flowing stream in the two counties. Ephemeral streams, which flow only during and after heavy rains, are White Woman and Sand Creeks and the western reach of Ladder Creek. The climate is semiarid, the normal annual precipitation being about 17 inches in Wichita County and 16 inches in Greeley County. Agriculture is the principal occupation in the area, and wheat is the most important crop. A considerable area is irrigated; sugar beets and sorghums are the principal irrigated crops. The outcropping rocks range in age from late Cretaceous to Recent; the Smoky Hill chalk member of the Niobrara formation, which is exposed along White Woman Creek in western Greeley County, is the oldest. The Niobrara is almost everywhere overlain by the Ogallala formation of Pliocene age. Generally the Ogallala is overlain by windblown silt of the Pleistocene Sanborn formation, but in places it is exposed along streams. The most recent deposits are dune sand and the alluvium along the streams. The Dakota formation, which is an important aquifer in parts of Kansas, is 300 to 450 feet beneath the Niobrara formation. The ground water that is available to wells in Wichita and Greeley counties is derived entirely from precipitation in the area or in areas immediately west and north. Ground water moves in a generally easterly direction with a gradient that varies inversely with the permeability of the water-bearing beds. The ground-water reservoir is recharged principally by precipitation within the area or within adjacent areas, Ground-water discharge takes place principally by pumping from wells, subsurface outflow, and evaporation and transpiration. Most of the domestic, stock, public, and irrigation supplies are obtained from wells. It is estimated that probably more than 2 billion gallons of water is pumped annually from wells in the area. Since 1947, ground-water recharge has been about equal to ground-water discharge. The use of ground water for irrigation has increased greatly since 1946 and indications are that many more wells may be drilled and pumped without dangerously lowering the water table. Approximately 11,000 to 12,000 acres were irrigated in 1951. A map showing the thickness of water-bearing materials indicates that although much of the area has enough water-bearing material to support irrigation wells, parts of Wichita and Greeley counties have little or none. The Ogallala is the principal water-bearing formation in the area. Small amounts of water may also be obtained locally from alluvial deposits and from cracks in the Niobrara formation. Two deep test wells to the Dakota formation have been drilled but, because of the poor quality of the water, have never been used. The ground water in Wichita and Greeley counties, though hard, is suitable for most purposes. Water from the Ogallala is generally high in fluoride and in some cases may be injurious to the teeth of children. Water from the Dakota, though soft, is unfit for irrigation because of a high content of sodium. The field data upon which most of this report is based are given in tables; they include records of 417 wells, chemical analyses of 31 samples of water, and logs of 57 test holes and wells.

Kansas Geological Survey Bulletin↗

USGS2008

Ground-water quality data in the Central Eastside San Joaquin Basin 2006: Results from the California GAMA program

Ground-water quality in the approximately 1,695-square-mile Central Eastside study unit (CESJO) was investigated from March through June 2006 as part of the Statewide Basin Assessment Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Statewide Basin Assessment project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the California State Water Resources Control Board (SWRCB) in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory (LLNL). The study was designed to provide a spatially unbiased assessment of raw ground-water quality within CESJO, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 78 wells in Merced and Stanislaus Counties. Fifty-eight of the 78 wells were selected using a randomized grid-based method to provide statistical representation of the study unit (grid wells). Twenty of the wells were selected to evaluate changes in water chemistry along selected lateral or vertical ground-water flow paths in the aquifer (flow-path wells). The ground-water samples were analyzed for a large number of synthetic organic constituents [volatile organic compounds (VOCs), gasoline oxygenates and their degradates, pesticides and pesticide degradates], constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), and 1,2,3-trichloropropane (1,2,3-TCP)], inorganic constituents that can occur naturally [nutrients, major and minor ions, and trace elements], radioactive constituents, and microbial indicators. Naturally occurring isotopes [tritium, carbon-14, and uranium isotopes and stable isotopes of hydrogen, oxygen, nitrogen, sulfur, and carbon], and dissolved noble and other gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, samples for matrix spikes) were collected for approximately one-sixth of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control results showed that the environmental data were of good quality, with low bias and low variability, and resulted in censoring of less than 0.3 percent of the detections found in ground-water samples. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CADPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CADPH. VOCs and pesticides were detected in approximately half of the grid wells, and all detections in samples from CESJO wells were below health-based thresholds. All detections of nutrients and major elements in grid wells also were below health-based thresholds. Most detections of constituents of special interest, trace elements, and radioactive constituents in samples from grid wells were below health-based thresholds. Exceptions included two detections of arsenic that were above the USEPA maximum contaminant level (MCL-US), one detection of lead above the USEPA action level (AL-US), and one detection of vanadium and three detections of 1,2,3-TCP that were above the CADPH notification levels (NL-CA). All detections of radioactive constituents were below health-based thresholds, although fourteen samples had activities of radon-222 above the lower proposed MCL-US. Most of the samples from CESJO grid wells had concentrations of major elements, total dissolved solids, and trace elements below the non-enforceable thresholds set for aesthetic concerns. A few samples contained manganese or total dissolved solids at concentrations above the SMCL-CA thresholds.

California↗

USGS2004

Questa baseline and pre-mining ground-water-quality investigation. 16. Quality assurance and quality control for water analyses

The Questa baseline and pre-mining ground-water quality investigation has the main objective of inferring the ground-water chemistry at an active mine site. Hence, existing ground-water chemistry and its quality assurance and quality control is of crucial importance to this study and a substantial effort was spent on this activity. Analyses of seventy-two blanks demonstrated that contamination from processing, handling, and analyses were minimal. Blanks collected using water deionized with anion and cation exchange resins contained elevated concentrations of boron (0.17 milligrams per liter (mg/L)) and silica (3.90 mg/L), whereas double-distilled water did not. Boron and silica were not completely retained by the resins because they can exist as uncharged species in water. Chloride was detected in ten blanks, the highest being 3.9 mg/L, probably as the result of washing bottles, filter apparatuses, and tubing with hydrochloric acid. Sulfate was detected in seven blanks; the highest value was 3.0 mg/L, most likely because of carryover from the high sulfate waters sampled. With only a few exceptions, the remaining blank analyses were near or below method detection limits. Analyses of standard reference water samples by cold-vapor atomic fluorescence spectrometry, ion chromatography, inductively coupled plasma-optical emission spectrometry, inductively coupled plasma-mass spectrometry, FerroZine, graphite furnace atomic absorption spectrometry, hydride generation atomic spectrometry, and titration provided an accuracy check. For constituents greater than 10 times the detection limit, 95 percent of the samples had a percent error of less than 8.5. For constituents within 10 percent of the detection limit, the percent error often increased as a result of measurement imprecision. Charge imbalance was calculated using WATEQ4F and 251 out of 257 samples had a charge imbalance less than 11.8 percent. The charge imbalance for all samples ranged from -16 to 16 percent. Spike recoveries were performed by spiking ground-water samples from SC2B, SC3A, SC3B, CC2A, and Hottentot with a mixed-element standard and then analyzing them by ICP-OES. The mean recovery for all the constituents by ICP-OES was 103 percent with a standard deviation of 16 percent. Fifteen surface- and ground-water sequential duplicates were collected from Straight Creek, Hottentot, and the Red River from 2002 to 2003. Except for chloride from well SC5B and low concentrations of iron (<0.05 mg/L) and aluminum (<0.01 mg/L), constituents of sequential duplicates are generally within 10 percent of each other. Analytical results from different methods and different laboratories, with rare exceptions, were within 10 percent. Chromium analyses were in poor agreement when comparing analyses from the USGS and a contract laboratory, but USGS analyses by ICP-OES and ICP-MS were usually within 10 percent for chromium concentrations above 0.03 mg/L and analyses by ICP-OES and GFAAS were usually within 15 percent for chromium concentrations as much as 0.1 mg/L. Filtration studies also were performed to study the effects of filtration apparatuses (Minitan, plate, capsule, and syringe), pore sizes, and timing on dissolved metal concentrations. Except for iron and aluminum, constituents with concentrations greater than about 0.05 mg/L were generally not affected by the filtration apparatus, membrane pore-size, and filtration delays. Iron, aluminum, and some dissolved metals concentrations less than about 0.05 mg/L, especially copper, were generally lowest in filtrates from the tangential flow Minitan system containing a filter membrane with a pore size of 10,000 Daltons. As part of a filtration timing study, grab samples were collected from two sites along the Red River and were processed immediately and then again 1 to 3 hours later. Aluminum and iron colloids formed during the delay in the sample collected at the USGS gaging station and, after the delay, 0.1-ìm filtrate aluminum and iron concentrations approached the ultrafiltrate (Minitan) concentrations. In the upstream site below Fawn Lakes, aluminum in the 0.1-ìm filtrate decreased but did not decrease in the 0.45-ìm filtrate, signifying that the colloids formed during the delay are between 0.1 and 0.45 ìm. Dissolved nickel and pH also decreased in both samples during the delay. Except for ferrous iron and barium, a sequential filtration study 2 demonstrated that water collected from the Red River at the gage did not affect dissolved metal concentrations with increasing sample volume passing through a plate filter with 0.45- or 0.1-ìm membranes. Barium and ferrous iron both slightly decreased in the filtrate from the 0.45-ìm filter.

Open-File Report↗

USGS2008

Quality of Shallow Ground Water in Three Areas of Unsewered Low-Density Development in Wyoming and Montana, 2001

The quality of shallow ground water underlying unsewered low-density development outside of Sheridan and Lander, Wyo., and Red Lodge, Mont., was evaluated. In 2001, 29 wells (10 each in Sheridan and Lander and 9 in Red Lodge) were installed at or near the water table and sampled for a wide variety of constituents to identify potential effects of human activities on shallow ground-water quality resulting from development on the land surface. All wells were completed in unconfined aquifers in unconsolidated deposits of Quaternary age with shallow water tables (less than 50 feet below land surface). Land use and land cover was mapped in detail within a 500-meter radius surrounding each well, and potential contaminant sources were inventoried within the radii to identify human activities that may affect shallow ground-water quality. This U.S. Geological Survey National Water-Quality Assessment ground-water study was conducted to examine the effects of unsewered low-density development that often surrounds cities and towns of many different sizes in the western United States?a type of development that often is informally referred to as ?exurban? or ?rural ranchette? development. This type of development has both urban and rural characteristics. Residents in these developments typically rely on a private ground-water well for domestic water supply and a private septic system for sanitary waste disposal. Although the quality of shallow ground water generally was suitable for domestic or other uses without treatment, some inorganic constituents were detected infrequently in ground water in the three study areas at concentrations larger than U.S. Environmental Protection Agency drinking-water standards or proposed standards. Natural factors such as geology, aquifer properties, and ground-water recharge rates likely influence most concentrations of these constituents. These inorganic constituents generally occur naturally in the study areas and were more likely to limit suitability of water for drinking or other intended uses rather than any constituents suspected of being introduced as a result of human activities. Effects of human activities associated with low-density development, such as septic systems; fertilizer and pesticide use on pastures, lawns and gardens; manure from horses, cattle, and pets; and increases in road construction and vehicular traffic, were minimal at the time of sampling (2001) but were apparent in the presence of a few types of constituents in shallow ground water. Concentrations of nitrate generally were less than a national background level (1.1 milligrams per liter) assumed to indicate effects from human activities. Total coliform bacteria were detected infrequently (in samples from three wells), and Escherichia coli were not detected in samples from a subset of wells. Trace concentrations of methylene blue active substances (ingredients in laundry detergents) were detected at concentrations slightly greater than laboratory reporting levels in samples from 11 wells, but it is unclear if the detections are indicative of natural sources or possible aquifer contamination from septic-tank effluent. Pesticides were detected in both the Sheridan and Lander, Wyo., study areas. Volatile organic compounds were detected very infrequently in all three study areas. Most pesticides and volatile organic compounds were found in water from a few wells in each study area, and commonly as mixtures. The primary exception to this generalization was the relatively widespread detection of the pesticide prometon at trace levels in the Sheridan and Lander study areas. Concentrations of pesticides and volatile organic compounds generally were small and always were smaller than applicable drinking-water standards. Detections of all constituents indicating possible human effects on shallow ground-water quality were consistent with overlying land use mapped during the study, and potential sources of contamination inventoried du

Scientific Investigations Report↗

USGS2007

Nitrogen species in soil, sediment, and ground water at a former sewage-treatment wastewater lagoon: Naval Air Station Whidbey Island, Island County, Washington

The potential for contamination of ground water from remnant sewage sludge in re-graded sediments of a deconstructed sewage-treatment lagoon was evaluated. Ground-water levels were measured in temporary drive-point wells, and ground-water samples were collected and analyzed for nutrients and other water-quality characteristics. Composite soil and sediment samples were collected and analyzed for organic carbon and nitrogen species. Multiple lines of evidence, including lack of appreciable organic matter in sediments of the former lagoon, agronomic analysis of nitrogen, the sequestration of nitrogen in the developing soils at the former lagoon, and likely occurrence of peat deposits within the aquifer material, suggest that the potential for substantial additions of nitrogen to ground water beneath the former sewage lagoon resulting from remnant sewage sludge not removed from the former lagoon are small. Concentrations of nitrogen species measured in ground-water samples were small and did not exceed the established U.S. Environmental Protection Agency’s maximum contaminant levels for nitrate (10 milligrams per liter). Concentrations of nitrate in ground-water samples were less than the laboratory reporting limit of 0.06 milligram per liter. Seventy to 90 percent of the total nitrogen present in ground water was in the ammonia form with a maximum concentration of 7.67 milligrams per liter. Concentrations of total nitrogen in ground water beneath the site, which is the sum of all forms of nitrogen including nitrate, nitrite, ammonia, and organic nitrogen, ranged from 1.15 to 8.44 milligrams per liter. Thus, even if all forms of nitrogen measured in ground water were converted to nitrate, the combined mass would be less than the maximum contaminant level. Oxidation-reduction conditions in ground water beneath the former sewage lagoon were reducing. Given the abundant supply of ambient organic carbon in the subsurface and in ground water at the former lagoon, any nitrate that may leach from residual sludge and be transported to ground water with recharge is expected to be quickly denitrified or transformed to nitrite and ammonia under the strongly reducing geochemical conditions that are present. Concentrations of organic carbon, the primary constituent of sewage sludge, in sediments of the former sewage lagoon were less than 1 percent, indicating a near absence of organic matter. The amount of total nitrogen present in the sediments at the former sewage lagoon was only about 25 percent of the amount typically present in developed agricultural soils. The lack of substantial carbon and nitrogen in sediments of the former sewage lagoon indicates that surficial sediments of the former lagoon are essentially devoid of residual sewage sludge. The largest concentration of total nitrogen measured in soil samples from the former sewage lagoon (330 milligrams per kilogram) was used to calculate an estimate of the amount of nitrogen that might be leached from residual sewage sludge by recharge. During the first two years following deconstruction of the former sewage lagoon, the concentration of total nitrogen in recharge leachate might exceed 10 milligrams per liter but the recharge leachate would not likely result in substantial increases in the nitrate concentration in ground water to concentrations greater than the drinking-water maximum contaminant level of 10 milligrams per liter.

Washington↗

USGS2003

Geohydrology, geochemistry, and ground-water simulation-optimization of the Central and West Coast Basins, Los Angeles County, California

Historical ground-water development of the Central and West Coast Basins in Los Angeles County, California through the first half of the 20th century caused large water-level declines and induced seawater intrusion. Because of this, the basins were adjudicated and numerous ground-water management activities were implemented, including increased water spreading, construction of injection barriers, increased delivery of imported water, and increased use of reclaimed water. In order to improve the scientific basis for these water management activities, an extensive data collection program was undertaken, geohydrological and geochemical analyses were conducted, and ground-water flow simulation and optimization models were developed. In this project, extensive hydraulic, geologic, and chemical data were collected from new multiple-well monitoring sites. On the basis of these data and data compiled and collected from existing wells, the regional geohydrologic framework was characterized. For the purposes of modeling, the three-dimensional aquifer system was divided into four aquifer systems?the Recent, Lakewood, Upper San Pedro, and Lower San Pedro aquifer systems. Most pumpage in the two basins is from the Upper San Pedro aquifer system. Assessment of the three-dimensional geochemical data provides insight into the sources of recharge and the movement and age of ground water in the study area. Major-ion data indicate the chemical character of water containing less than 500 mg/L dissolved solids generally grades from calcium-bicarbonate/sulfate to sodium bicarbonate. Sodium-chloride water, high in dissolved solids, is present in wells near the coast. Stable isotopes of oxygen and hydrogen provide information on sources of recharge to the basin, including imported water and water originating in the San Fernando Valley, San Gabriel Valley, and the coastal plain and surrounding hills. Tritium and carbon-14 data provide information on relative ground-water ages. Water with abundant tritium (greater than 8 tritium units) is found in and downgradient from the Montebello Forebay and near the seawater barrier projects, indicating recent recharge. Water with less than measurable tritium is present in, and downgradient from, the Los Angeles Forebay and in most wells in the West Coast Basin. Water from several deep wells was analyzed for carbon-14. Uncorrected estimates of age for these samples range from 600 to more than 20,000 years before present. Chemical and isotopic data are combined to evaluate changes in chemical character along flow paths emanating from the Montebello and Los Angeles Forebays. A four-layer ground-water flow model was developed to simulate steady-state ground-water conditions representative of those in 1971 and transient conditions for the period 1971?2000. Model results indicate increases in ground-water storage in all parts of the study area over the simulated thirty-year period. The model was used to develop a three-dimensional ground-water budget and to assess impacts of two alternative future (2001?25) ground-water development scenarios?one that assumes continued pumping at average current rates and a second that assumes increasing pumping from most wells in the Central Basin. The model simulates stable or slightly increasing water levels for the first scenario and declining water levels (25 to 50 ft in the Central Basin) in the second scenario. Model sensitivity to parameter values and to the assumed Orange County boundary condition was evaluated. Particle tracking was applied to simulate advective transport of water from the spreading ponds, the coastline, and the seawater injection barriers. Particle tracking results indicate that most flow within the Upper San Pedro aquifer system occurs within about 20 percent of the total aquifer system thickness and that virtually all water injected into the seawater barrier projects has flowed inland. The simulation model was linked with optimizatio

California↗

USGS1997

Geohydrology and Numerical Simulation of the Ground-Water Flow System of Molokai, Hawaii

A two-dimensional, steady-state, areal ground-water flow model was developed for the island of Molokai, Hawaii, to enhance the understanding of (1) the conceptual framework of the ground-water flow system, (2) the distribution of aquifer hydraulic properties, and (3) the regional effects of ground-water withdrawals on water levels and coastal discharge. The model uses the finite-element code AQUIFEM-SALT, which simulates flow of fresh ground water in systems that may have a freshwater lens floating on denser underlying saltwater. Model results are in agreement with the general conceptual model of the flow system on Molokai, where ground water flows from the interior, high-recharge areas to the coast. The model-calculated ground-water divide separating flow to the northern and southern coasts lies to either the north or the south of the topographic divide but is generally not coincident with the topographic divide. On the basis of model results, the following horizontal hydraulic conductivities were estimated: (1) 1,000 feet per day for the dike-free volcanic rocks of East and West Molokai, (2) 100 feet per day for the marginal dike zone of the East Molokai Volcano, (3) 2 feet per day for the West Molokai dike complex, (4) 0.02 feet per day for the East Molokai dike complex, and (5) 500 feet per day for the Kalaupapa Volcanics. Three simulations to determine the effects of proposed ground-water withdrawals on water levels and coastal discharge, relative to model-calculated water levels and coastal discharge for 1992-96 withdrawal rates, show that the effects are widespread. For a withdrawal rate of 0.337 million gallons per day from a proposed well about 4 miles southeast of Kualapuu and 3 miles north of Kamiloloa, the model-calculated drawdown of 0.01 foot or more extends 4 miles southeast and 6 miles northwest from the well. For a withdrawal rate of 1.326 million gallons per day from the same well, the model-calculated drawdown of 0.01 foot or more extends 6 miles southeast and 9 miles northwest from the well. In a third scenario, the withdrawal rate from an existing well near Kualapuu was increased by 0.826 million gallons per day. The model-calculated drawdown of 0.01 foot or more extends 6 miles southeast and 8 miles northwest from the well. In all scenarios, coastal discharge is reduced by an amount equal to the additional withdrawal. Additional data needed to improve the understanding of the ground-water flow system on Molokai include: (1) a wider spatial distribution and longer temporal distribution of water-levels, (2) independent estimates of hydraulic conductivity, (3) improved recharge estimates, (4) information about the vertical distribution of salinity in ground water, (5) streamflow data at additional sites, and (6) improved information about the subsurface geology.

Water-Resources Investigations Report↗

USGS2008

Ground-Water Conditions and Studies in the Albany Area of Dougherty County, Georgia, 2007

The U.S. Geological Survey (USGS) has been working with the Albany Water, Gas, and Light Commission to monitor ground-water quality and availability since 1977. This report presents an overview of ground-water conditions and studies in the Albany area of Dougherty County, Georgia, during 2007. Historical data are also presented for comparison with 2007 data. Ongoing monitoring activities include continuous water-level recording in 24 wells and monthly water-level measurements in 5 wells. During 2007, water levels in 21 of the continuous-recording wells were below normal, corresponding to lower than average rainfall. Ground-water samples collected from the Upper Floridan aquifer indicate that nitrate levels have decreased or remained about the same since 2006. Water samples were collected from the Flint River and wells at the Albany wellfield, and data were plotted on a trilinear diagram to show the percent composition of selected major cations and anions. Ground-water constituents (major cations and anions) of the Upper Floridan aquifer at the Albany wellfield are distinctly different from those in the water of the Flint River. To improve the understanding of the ground-water flow system and nitrate movement in the Upper Floridan aquifer, the USGS is developing a ground-water flow model in the southwestern Albany area of Georgia. The model is being calibrated to simulate periods of dry (October 1999) and relatively wet (March 2001) hydrologic conditions. Preliminary water-level simulations indicate a generally good fit to measured water levels.

Georgia↗

USGS2003

Estimating Ground-Water Recharge from Precipitation on Whidbey and Camano Islands, Island County, Washington, Water Years 1998 and 1999

Ground-water recharge from precipitation to unconsolidated deposits on Whidbey and Camano Islands, Washington, was estimated for water years 1998-99 using a near-surface water-balance method and a chloride mass-balance method. A daily near-surface water-balance method, the Deep Percolation Model (DPM), was used to simulate water budgets for October 1, 1997 through September 30, 1999 (water years 1998-99) for six small drainage basins?four on Whidbey Island and two on Camano Island. Adjusted parameters from the DPM for each small basin were then used in island-wide DPM simulations. A spatial distribution of annual recharge was simulated for each island, with island averages of 5.71 inches per year for Whidbey Island and 5.98 inches per year for Camano Island. The spatial distribution of simulated annual recharge for each island reflects variations in precipitation amounts and the distribution of surficial materials. DPM results indicate that recharge generally is higher in areas underlain by coarse-grained deposits (outwash) than in areas underlain by fine-grained deposits (till). A chloride mass-balance method was used to estimate combined recharge to unconsolidated deposits on Whidbey and Camano Islands. The average combined recharge for Whidbey and Camano Islands estimated by this method was 2.00 inches per year. The range of chloride concentrations in ground-water samples from selected wells indicates that the average recharge to unconsolidated deposits ranges from 0.78 to 7.81 inches per year. Sources of chloride in ground water other than from the atmosphere would cause recharge estimated by the chloride mass-balance method to be less than the actual recharge, therefore, these estimates may represent lower limits.

Water-Resources Investigations Report↗

USGS1995

Assessment of information on ground-water/surface-water interactions in the northern midcontinent

Ground-water/surface-water interactions are important to the hydrology of shallow aquifers, streams, lakes, and wetlands. Information on ground-water/surface-water interactions in the northern midcontinent was assessed. The ground-water/surface-water interactions in physiographic and climatic areas that contain many wetlands differed from the interactions in areas that consisted predominantly of alluvial aquifers along large streams. In both types of areas, however, the interactions are complex. The distribution of shallow ground-water observation wells in the northern midcontinent and the frequency of measurement were evaluated. Most shallow wells are located adjacent to major streams, especially in areas where wetlands are not a dominant surface-water feature. The frequency of measurement was inconsistent between states.

Conference Paper↗

USGS2001

Ground-water discharge determined from estimates of evapotranspiration, Death Valley regional flow system, Nevada and California

The Death Valley regional flow system (DVRFS) is one of the larger ground-water flow systems in the southwestern United States and includes much of southern Nevada and the Death Valley region of eastern California. Centrally located within the ground-water flow system is the Nevada Test Site (NTS). The NTS, a large tract covering about 1,375 square miles, historically has been used for testing nuclear devices and currently is being studied as a potential repository for the long-term storage of high-level nuclear waste generated in the United States. The U.S. Department of Energy, as mandated by Federal and State regulators, is evaluating the risk associated with contaminants that have been or may be introduced into the subsurface as a consequence of any past or future activities at the NTS. Because subsurface contaminants can be transported away from the NTS by ground water, components of the ground-water budget are of great interest. One such component is regional ground-water discharge. Most of the ground water leaving the DVRFS is limited to local areas where geologic and hydrologic conditions force ground water upward toward the surface to discharge at springs and seeps. Available estimates of ground-water discharge are based primarily on early work done as part of regional reconnaissance studies. These early efforts covered large, geologically complex areas and often applied substantially different techniques to estimate ground-water discharge. This report describes the results of a study that provides more consistent, accurate, and scientifically defensible measures of regional ground-water losses from each of the major discharge areas of the DVRFS. Estimates of ground-water discharge presented in this report are based on a rigorous quantification of local evapotranspiration (ET). The study identifies areas of ongoing ground-water ET, delineates different ET areas based on similarities in vegetation and soil-moisture conditions, and determines an ET rate for each delineated area. Each area, referred to as an ET unit, generally consists of one or more assemblages of local phreatophytes or a unique moist soil environment. Ten ET units are identified throughout the DVRFS based on differences in spectral-reflectance characteristics. Spectral differences are determined from satellite imagery acquired June 21, 1989, and June 13, 1992. The units identified include areas of open playa, moist bare soils, sparse to dense vegetation, and open water. ET rates estimated for each ET unit range from a few tenths of a foot per year for open playa to nearly 9 feet per year for open water. Mean annual ET estimates are computed for each discharge area by summing estimates of annual ET from each ET unit within a discharge area. The estimate of annual ET from each ET unit is computed as the product of an ET unit's acreage and estimated ET rate. Estimates of mean annual ET range from 450 acre-feet in the Franklin Well area to 30,000 acre-feet in Sarcobatus Flat. Ground-water discharge is estimated as annual ET minus that part of ET attributed to local precipitation. Mean annual ground-water discharge estimates range from 350 acre-feet in the Franklin Well area to 18,000 acre-feet in Ash Meadows. Generally, these estimates are greater for the northern discharge areas (Sarcobatus Flat and Oasis Valley) and less for the southern discharge areas (Franklin Lake, Shoshone area, and Tecopa/ California Valley area) than those previously reported.

California;Nevada↗

USGS2000

Effects of alternative Missouri River management plans on ground-water levels in the lower Missouri River flood plain

In 1998, the U.S. Army Corps of Engineers (USACE) proposed eight Alternative River Management Plans (ARMPs) for managing reservoir levels and water-release rates for the Missouri River. The plans include the Current Water Control Plan (CWCP), Conservation 18, 31, and 44 (C18, C31, and C44) that provide different levels of water conservation in the reservoirs during droughts, Fish and Wildlife 10, 15, and 20 (FW10, FW15, and FW20) that vary water-release rates to provide additional fish and wildlife benefits, and Mississippi River 66 (M66) that maintains a 66,000 cubic feet per second discharge at St. Louis to provide navigation support for the Mississippi River. Releases from Gavin?s Point Dam affect both the lower 1,305 kilometers of the Missouri River and ground-water levels in the lower Missouri River flood plain. Changes in the magnitude and timing of ground-water-level fluctuations in response to changes in river management could impact agriculture, urban development, and wetland hydrology along the lower Missouri River flood plain. This study compared simulated ground-water altitude and depth to ground water for the CWCP in the Missouri River alluvial aquifer near the Kansas City area between 1970 and 1980 with each ARMP, determined the average change in simulated ground-water level for selected river-stage flood pulses at selected distances from the river, and compared simulated flood pulse, ground-water responses with actual flood pulse, and ground-water responses measured in wells located at three sites along the lower Missouri River flood plain.For the model area, the percent total shallow ground-water area (depth to ground water less than 0.3048 meter) is similar for each ARMP because of overall similarities in river flow between ARMPs. The percent total shallow ground-water area for C18 is the most similar to CWCP followed by C31, M66, C44, FW10, FW15, and FW20. ARMPs C18, C31, C44, and M66 do not cause large changes in the percent shallow ground-water area when compared to CWCP. FW10 and FW15 each cause a spring increase and a summer decrease in the shallow ground-water area. FW20 has a larger spring increase in the shallow ground-water area, but the largest decrease is delayed into November. Analysis of daily changes between the ARMPs indicate large differences can exist in both duration and extent of shallow ground-water areas.A series of 12 flood pulses of 0.5-, 1-, and 3-meters in magnitude and 1-, 8-, 32-, and 128-days in duration were simulated using the ground-water flow model. A ground-water response factor (GWRF, defined as the change in ground-water level at a known distance from the river, at a specified time after the beginning of a flood pulse divided by the magnitude of the flood pulse) was determined daily for selected distances from the river. The GWRF multiplied by the magnitude of the flood pulse can be used to estimate the change in ground-water level at a known time after the beginning of a flood pulse for a known distance from the river. Flood-pulse simulation results indicate the relatively small impact on ground-water levels of small river-stage fluctuations of short duration as might occur daily or weekly. The larger impact on ground-water levels from larger river-stage increases of longer duration indicate the importance of river management flow releases, seasonal changes in river flow, and the effects of continuous high-river stage for long periods on ground-water levels of the lower Missouri River flood plain.A comparison of model results to well hydrographs from three areas along the lower Missouri River flood plain was used to determine how closely the simulated GWRFs matched the measured GWRFs for similar flood pulses and the transferability of GWRFs to other parts of the lower Missouri River flood plain. The comparison between the measured and simulated ground-water responses indicate that the simulated ground-water responses can provide a reasonable estimate of the ground-water resp

Water-Resources Investigations Report↗

USGS1944

Ground-water resources of the Houston district, Texas

This report covers the current phase of an investigation of the supply of ground water available for the Houston district and adjacent region, Texas,- that has been in progress during the past 10 years. The field operations included routine inventories of pumpage, measurements of water levels in observation wells and collection of other hydrologic data, pumping tests on 21 city-owned wells to determine coefficients of permeability and storage, and the drilling of 13 deep test wells in unexplored parts of the district. Considerable attention has been given to studies of the location of areas or beds of sand that contain salt water. The ground water occurs in beds of sand, sandstone, and gravel of Miocene, Pliocene, and Pleistocene age. These formations crop out in belts that dip southeastward from their outcrop areas and are encountered by wells at progressively greater depths toward the southeast. The beds throughout the section are lithologically similar, and there is little agreement among geologists as to their correlation. -In this investigation, however, the sediments, penetrated by the wells are separated into six zones, chiefly on the basis of electrical logs. Most of the water occurs in zone 3, which ranges in thickness from 800 to 1,200 feet. Large quantities of ground water are pumped in three areas in the Houston district, as follows: The Houston tromping area, which includes Houston and the areas immediately adjacent; the Pasadena pumping area, which includes the industrial section extending along the ship channel from the Houston city limits eastward to Deer Park; and the Katy pumping area, an irregular-shaped area of several hundred square miles, which is roughly centered around the town of Katy, 30 miles west of Houston. In 1930 the total combined withdrawal of ground water in the Houston and Pasadena pumping areas averaged about 50 million gallons a day. It declined somewhat during 1932 and 1933 and then gradually increased, until in 1935 the total pumpage was about the same as it was in 1930. About March 1, 1937, the pumpage was increased by about 40 percent, when new wells near Pasadena were put into operation. During 1940 it is estimated that the total pumpage in the Houston and Pasadena areas averaged about 79 million gallons a day, an increase of about 65 percent over the pumpage in 1935. About 25 million gallons of this increase has occurred in the Pasadena area. In the Katy rice-growing area the pumpage in 1935 was about 14 million gallons a day; in 1937 it was about 30 million gallons a day; in 1939 about 40 million gallons a day; and in 1940 about 45 million gallons a day. In 1940 the estimated total pumpage from the Houston, Pasadena, and Katy pumping areas was about 124 million gallons a day, or twice as much as it was in 1935. The increase in pumping at Pasadena in the spring-of 1937 caused the water leveling wells in the Houston and Pasadena areas, which had not varied materially for about 7 years, to decline at a rapid rate. Further increases in the pumping both at Houston and Pasadena in 1939 and 1940 has caused further substantial decline. The water levels in wells in the Katy rice-growing area also declined materially. The evidence points to the probability that in all parts of the Houston district, except the Katy rice-growing area, the rainfall is recharging the aquifers at a rate greater than that at which the water is transmitted down the dip. In the Katy area the recharge is insufficient to balance the joint discharge by transmission down the dip and withdrawal from rice-irrigating wells. The average coefficient of transmissibility was. calculated as 160,000 gallons a day. On the basis of these estimates the inflow in February 1940 across the artesian contour 10 feet below sea level (see pl. 10) was computed as 72 million gallons a day. The amount of water taken out of artesian storage in the 300-square mile area within the -10 contour during the period February 1939 to February

Water Supply Paper↗

USGS1999

Geostatistical applications in ground-water modeling in south-central Kansas

This paper emphasizes the supportive role of geostatistics in applying ground-water models. Field data of 1994 ground-water level, bedrock, and saltwater-freshwater interface elevations in south-central Kansas were collected and analyzed using the geostatistical approach. Ordinary kriging was adopted to estimate initial conditions for ground-water levels and topography of the Permian bedrock at the nodes of a finite difference grid used in a three-dimensional numerical model. Cokriging was used to estimate initial conditions for the saltwater-freshwater interface. An assessment of uncertainties in the estimated data is presented. The kriged and cokriged estimation variances were analyzed to evaluate the adequacy of data employed in the modeling. Although water levels and bedrock elevations are well described by spherical semivariogram models, additional data are required for better cokriging estimation of the interface data. The geostatistically analyzed data were employed in a numerical model of the Siefkes site in the project area. Results indicate that the computed chloride concentrations and ground-water drawdowns reproduced the observed data satisfactorily.This paper emphasizes the supportive role of geostatistics in applying ground-water models. Field data of 1994 ground-water level, bedrock, and saltwater-freshwater interface elevations in south-central Kansas were collected and analyzed using the geostatistical approach. Ordinary kriging was adopted to estimate initial conditions for ground-water levels and topography of the Permian bedrock at the nodes of a finite difference grid used in a three-dimensional numerical model. Cokriging was used to estimate initial conditions for the saltwater-freshwater interface. An assessment of uncertainties in the estimated data is presented. The kriged and cokriged estimation variances were analyzed to evaluate the adequacy of data employed in the modeling. Although water levels and bedrock elevations are well described by spherical semivariogram models, additional data are required for better cokriging estimation of the interface data. The geostatistically analyzed data were employed in a numerical model of the Siefkes site in the project area. Results indicate that the computed chloride concentrations and ground-water drawdowns reproduced the observed data satisfactorily.

Journal of Hydrologic Engineering↗

USGS1999

Distribution of major herbicides in ground water of the United States

Information on the concentrations and spatial distributions of pesticides and their transformation products, or degradates, in the hydrologic system is essential for managing pesticide use in both agricultural and nonagricultural settings to protect water resources. This report examines the occurrence of selected herbicides and their degradates in ground water, primarily on the basis of results from two large-scale, multistate investigations by the U.S. Geological Survey—the National Water-Quality Assessment (NAWQA) Program and the Midwest Pesticide Study (MWPS). The NAWQA pesticide data were derived from 2,227 sites (wells and springs) sampled in 20 major hydrologic basins across the United States from 1993 to 1995; the MWPS data were obtained from the sampling of 303 wells in a 12-state area of the northern midcontinent from 1991 to 1994. Data are presented for seven high-use herbicides: five of current interest to the U.S. Environmental Protection Agency for designing Pesticide Management Plans (atrazine, cyanazine, simazine, alachlor and metolachlor), a largely nonagricultural herbicide (prometon), and an agricultural herbicide first registered in 1994 for use in the United States (acetochlor). Six of the herbicides (all except acetochlor) were detected by the U.S. Geological Survey studies in shallow ground water—that is, ground water recharged within the past 10 years—in a variety of agricultural and nonagricultural settings, as well as in several aquifers that are sources of drinking-water supply. Acetochlor was not detected by the MWPS in the summer of 1994, but was detected in shallow ground water during the NAWQA Program by early 1995, and during another U.S. Geological Survey study in Iowa during the summers of 1995 and 1996. The acetochlor observations suggest that, in agreement with results from previous field studies, some pesticides may be detected in shallow ground water within 1 year following their application. In accord with the results from other largescale multistate studies of pesticides in ground water, more than 98 percent of the detections during the NAWQA and MWPS investigations were at concentrations of less than 1 microgram per liter. Consequently, water quality criteria for drinking water—that is, standards established to protect human health—were exceeded at fewer than 0.1 percent of the sites sampled by NAWQA (all of these exceedances involving atrazine alone) and at none of those sampled in 1992 by the MWPS. These criteria, however, may not accurately reflect the overall health risks associated with pesticide detections in water resources because they have been established only for a relatively small number of pesticides and they do not account for the additive or synergistic effects of mixtures, impacts on the health of aquatic ecosystems, or the effects of pesticide degradates. Among the sites sampled during the NAWQA and MWPS investigations, 19.7 and 13.8 percent, respectively, had detections of two or more of the herbicides of interest. Furthermore, for most of the herbicides for which degradates were examined, detection frequencies for major degradates were typically higher than for their respective parent compounds, particularly for the herbicides that are less persistent in aerobic soil. Frequencies of detection at or above 0.01 microgram per liter in shallow ground water beneath agricultural areas during the NAWQA study were significantly correlated with agricultural use in those areas for atrazine, cyanazine, alachlor, and metolachlor (P<0.05; Spearman rank correlations), but not for simazine (P>0.05). In urban areas, overall frequencies of detection of these five herbicides in shallow ground water were positively correlated with their total nonagricultural use nationwide (P=0.026; simple linear correlation). Multivariate statistical analysis indicated that frequencies of detection in shallow ground water beneath agricultural areas were positively correlated with half-lives for transformation in aerobic soil and agricultural use of the compounds (P≤0.0001 for both parameters). Although frequencies of detection were not significantly correlated with their subsurface mobility (K oc ; P=0.19) or the median well depths of the sampled networks (P=0.72), the range of K oc values among the five herbicides and the range of well depths were limited.

Water-Resources Investigations Report↗