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At least 937 records · Page 52Linked to original sources

Multiphase, multicomponent parameter estimation for liquid and vapor fluxes in deep arid systems using hydrologic data and natural environmental tracers

Multiphase, multicomponent numerical models of long-term unsaturated-zone liquid and vapor movement were created for a thick alluvial basin at the Nevada Test Site to predict present-day liquid and vapor fluxes. The numerical models are based on recently developed conceptual models of unsaturated-zone moisture movement in thick alluvium that explain present-day water potential and tracer profiles in terms of major climate and vegetation transitions that have occurred during the past 10 000 yr or more. The numerical models were calibrated using borehole hydrologic and environmental tracer data available from a low-level radioactive waste management site located in a former nuclear weapons testing area. The environmental tracer data used in the model calibration includes tracers that migrate in both the liquid and vapor phases (δD, δ 18 O) and tracers that migrate solely as dissolved solutes (Cl), thus enabling the estimation of some gas-phase as well as liquid-phase transport parameters. Parameter uncertainties and correlations identified during model calibration were used to generate parameter combinations for a set of Monte Carlo simulations to more fully characterize the uncertainty in liquid and vapor fluxes. The calculated background liquid and vapor fluxes decrease as the estimated time since the transition to the present-day arid climate increases. However, on the whole, the estimated fluxes display relatively little variability because correlations among parameters tend to create parameter sets for which changes in some parameters offset the effects of others in the set. Independent estimates on the timing since the climate transition established from packrat midden data were essential for constraining the model calibration results. The study demonstrates the utility of environmental tracer data in developing numerical models of liquid- and gas-phase moisture movement and the importance of considering parameter correlations when using Monte Carlo analysis to characterize the uncertainty in moisture fluxes.

Vadose Zone Journal↗

Improving groundwater predictions utilizing seasonal precipitation forecasts from general circulation models forced with sea surface temperature forecasts

Recent studies have found a significant association between climatic variability and basin hydroclimatology, particularly groundwater levels, over the southeast United States. The research reported in this paper evaluates the potential in developing 6-month-ahead groundwater-level forecasts based on the precipitation forecasts from ECHAM 4.5 General Circulation Model Forced with Sea Surface Temperature forecasts. Ten groundwater wells and nine streamgauges from the USGS Groundwater Climate Response Network and Hydro-Climatic Data Network were selected to represent groundwater and surface water flows, respectively, having minimal anthropogenic influences within the Flint River Basin in Georgia, United States. The writers employ two low-dimensional models [principle component regression (PCR) and canonical correlation analysis (CCA)] for predicting groundwater and streamflow at both seasonal and monthly timescales. Three modeling schemes are considered at the beginning of January to predict winter (January, February, and March) and spring (April, May, and June) streamflow and groundwater for the selected sites within the Flint River Basin. The first scheme (model 1) is a null model and is developed using PCR for every streamflow and groundwater site using previous 3-month observations (October, November, and December) available at that particular site as predictors. Modeling schemes 2 and 3 are developed using PCR and CCA, respectively, to evaluate the role of precipitation forecasts in improving monthly and seasonal groundwater predictions. Modeling scheme 3, which employs a CCA approach, is developed for each site by considering observed groundwater levels from nearby sites as predictands. The performance of these three schemes is evaluated using two metrics (correlation coefficient and relative RMS error) by developing groundwater-level forecasts based on leave-five-out cross-validation. Results from the research reported in this paper show that using precipitation forecasts in climate models improves the ability to predict the interannual variability of winter and spring streamflow and groundwater levels over the basin. However, significant conditional bias exists in all the three modeling schemes, which indicates the need to consider improved modeling schemes as well as the availability of longer time-series of observed hydroclimatic information over the basin.

Georgia↗

Evaluating changes in matrix based, recovery-adjusted concentrations in paired data for pesticides in groundwater

Pesticide concentration data for waters from selected carbonate-rock aquifers in agricultural areas of Pennsylvania were collected in 1993–2009 for occurrence and distribution assessments. A set of 30 wells was visited once in 1993–1995 and again in 2008–2009 to assess concentration changes. The data include censored matched pairs (nondetections of a compound in one or both samples of a pair). A potentially improved approach for assessing concentration changes is presented where (i) concentrations are adjusted with models of matrix-spike recovery and (ii) area-wide temporal change is tested by use of the paired Prentice-Wilcoxon (PPW) statistical test. The PPW results for atrazine, simazine, metolachlor, prometon, and an atrazine degradate, deethylatrazine (DEA), are compared using recovery-adjusted and unadjusted concentrations. Results for adjusted compared with unadjusted concentrations in 2008–2009 compared with 1993–1995 were similar for atrazine and simazine (significant decrease; 95% confidence level) and metolachlor (no change) but differed for DEA (adjusted, decrease; unadjusted, increase) and prometon (adjusted, decrease; unadjusted, no change). The PPW results were different on recovery-adjusted compared with unadjusted concentrations. Not accounting for variability in recovery can mask a true change, misidentify a change when no true change exists, or assign a direction opposite of the true change in concentration that resulted from matrix influences on extraction and laboratory method performance. However, matrix-based models of recovery derived from a laboratory performance dataset from multiple studies for national assessment, as used herein, rather than time- and study-specific recoveries may introduce uncertainty in recovery adjustments for individual samples that should be considered in assessing change.

Pennsylvania↗

Measuring environmental change in forest ecosystems by repeated soil sampling: a North American perspective

Environmental change is monitored in North America through repeated measurements of weather, stream and river flow, air and water quality, and most recently, soil properties. Some skepticism remains, however, about whether repeated soil sampling can effectively distinguish between temporal and spatial variability, and efforts to document soil change in forest ecosystems through repeated measurements are largely nascent and uncoordinated. In eastern North America, repeated soil sampling has begun to provide valuable information on environmental problems such as air pollution. This review synthesizes the current state of the science to further the development and use of soil resampling as an integral method for recording and understanding environmental change in forested settings. The origins of soil resampling reach back to the 19th century in England and Russia. The concepts and methodologies involved in forest soil resampling are reviewed and evaluated through a discussion of how temporal and spatial variability can be addressed with a variety of sampling approaches. Key resampling studies demonstrate the type of results that can be obtained through differing approaches. Ongoing, large-scale issues such as recovery from acidification, long-term N deposition, C sequestration, effects of climate change, impacts from invasive species, and the increasing intensification of soil management all warrant the use of soil resampling as an essential tool for environmental monitoring and assessment. Furthermore, with better awareness of the value of soil resampling, studies can be designed with a long-term perspective so that information can be efficiently obtained well into the future to address problems that have not yet surfaced.

Journal of Environmental Quality↗

A 50-year Sr/Ca time series from an enclosed, shallow-water Guam coral: In situ monitoring and extraction of a temperature trend, annual cycle, and ENSO and PDO signals

Located on the northern edge of the West Pacific Warm Pool and having a developed economy and modern infrastructure, Guam is well positioned and equipped for obtaining natural records of the west Pacific maritime paleoclimate. This study was a proof of concept to explore whether useful climate proxy records might be obtained from coral at readily accessible, even if geochemically nonoptimal, coastal sites. A 50-year Sr/Ca record (1960–2010) was thus obtained from a shallow-water, near-shore Porites lutea colony at a recreational facility inside Guam's Apra Harbor and compared with local and regional meteorological records, including the El Niño–Southern Oscillation (ENSO) and Pacific Decadal Oscillation (PDO) indices. The accessibility of the site enabled documentation of relevant environmental variables for 16 months (September 2009–December 2010): seawater δ 18 O, pH, seawater cations, and nitrate. Time series of seawater δ 18 O, pH, and cations show evidence of freshwater input from direct rainfall and stream discharge into the harbor. An anomalously higher mean and variable concentrations of Ba suggest the presence of river-borne, fine-grained terrigenous sediment. Nevertheless, the Sr/Ca time series reproduces a long-term warming trend seen in historical records of local air temperature and regional sea-surface temperature (SST) and closely tracks the ENSO and PDO indices over the entire 50-year record. The consistency of the results with Guam's historical instrumental records, previous coral δ 18 O results from Guam obtained by others, and previous Sr/Ca proxy results for SST in similar environments elsewhere demonstrate that accessible near-shore sites—where environmental conditions can be monitored—can produce useful Sr/Ca records of local and regional climate phenomena.

Journal of Coastal Research↗

Application of multiple isotopic and geochemical tracers for investigation of recharge, salinization, and residence time of water in the Souss-Massa aquifer, southwest of Morocco

Groundwater and surface water in Souss-Massa basin in the west-southern part of Morocco is characterized by a large variation in salinity, up to levels of 37 g L-1. The high salinity coupled with groundwater level decline pose serious problems for current irrigation and domestic water supplies as well as future exploitation. A combined hydrogeologic and isotopic investigation using several chemical and isotopic tracers such as Br/Cl, ??18O, ??2H, 3H, 87Sr/86Sr, ??11B, and 14C was carried out in order to determine the sources of water recharge to the aquifer, the origin of salinity, and the residence time of water. Stable isotope, 3H and 14C data indicate that the high Atlas mountains in the northern margin of the Souss-Massa basin with high rainfall and low ??18O and ??2H values (-6 to -8??? and -36 to -50???) is currently constitute the major source of recharge to the Souss-Massa shallow aquifer, particularly along the eastern part of the basin. Localized stable isotope enrichments offset meteoric isotopic signature and are associated with high nitrate concentrations, which infer water recycling via water agricultural return flows. The 3H and 14C data suggest that the residence time of water in the western part of the basin is in the order of several thousands of years; hence old water is mined, particularly in the coastal areas. The multiple isotope analyses and chemical tracing of groundwater from the basin reveal that seawater intrusion is just one of multiple salinity sources that affect the quality of groundwater in the Souss-Massa aquifer. We differentiate between modern seawater intrusion, salinization by remnants of seawater entrapped in the middle Souss plains, recharge of nitrate-rich agricultural return flow, and dissolution of evaporate rocks (gypsum and halite minerals) along the outcrops of the high Atlas mountains. The data generated in this study provide the framework for a comprehensive management plan in which water exploitation should shift toward the eastern part of the basin where current recharge occurs with young and high quality groundwater. In contrast, we argued that the heavily exploited aquifer along the coastal areas is more vulnerable given the relatively longer residence time of the water and salinization processes in this part of the aquifer. ?? 2008 Elsevier B.V. All rights reserved.

Journal of Hydrology↗

Machine-learning model to delineate sub-surface agricultural drainage from satellite imagery

Knowing subsurface drainage (tile-drain) extent is integral to understanding how landscapes respond to precipitation events and subsequent days of drying, as well as how soil characteristics and land management influence stream response. Consequently, a time series of tile-drain extent would inform one aspect of land management that complicates our ability to explain streamflow and water-quality as a function of climate variability or conservation management. We trained a UNet machine-learning model, a convolutional neural network designed to highlight objects of interest within an image, to delineate tile-drain networks in panchromatic satellite imagery without additional data on soils, topography, or historical tile-drain extent. This was done by training the model to match the accuracy of human experts manually tracing the surface representation of tile drains in satellite imagery. Our approach began with a library of images that were used to train and quantify the accuracy of the model, with model performance tested on imagery from two areas that were not used to train the model. Satellite imagery included acquisition dates from 2008 to 2020. Training imagery was from agricultural areas within the US Great Lakes basin. Validation imagery was from the upper Maumee River, tributary to western Lake Erie, and an Indiana, Ohio-River headwater tributary. Our analysis of the satellite imagery paired with meteorological and soil data found that during spring, a combination of relatively high solar radiation, intermediate soil-water content and bare fields enabled the best model performance. Each area of interest was heavily tile-drained, where better understanding the movement of water, nutrients, and sediment from fields to downstream water bodies is key to managing harmful algal blooms and hypoxia. The trained UNet model successfully identified tile drains visible in the validation imagery with an accuracy of 93%–96% and balanced accuracy of 52%–54%, similar to performance for training data (95% and 63%, respectively). Model performance will benefit from ongoing contributions to the training library.

Indiana, Michigan, Ohio, Wisconsin↗

The history of recent limnological changes and human impact on Upper Klamath Lake, Oregon

Hypereutrophic Upper Klamath Lake has been studied for almost 50 years to evaluate the nature, cause, and effects of its very productive waters. Mitigation of undesirable effects of massive cyanobacterial blooms requires understanding their modern causes as well as their history. Knowledge of the pre-settlement natural limnology of this system can provide guidelines for lake restoration and management of land and water use strategies to maximize the benefits of this aquatic resource. This investigation uses a paleolimnological approach to document the nature and chronology of limnological and biological changes in Upper Klamath Lake for the past 200 years, covering the time when the lake was first described until today. A 45-cm gravity core, dated by 210 Pb and diatom correlations, was analyzed for diatoms, pollen, akinetes (resting spores) of the cyanobacterium Aphanizomenon flos-aquae , reworked tephra shards, and sediment magnetic characteristics. Pollen profiles show little vegetation change during this time. In contrast, diatoms indicative of increased nutrient fluxes (P and Si) increase moderately, coinciding with the settlement of the region by Euro-Americans. Numerous settlement activities, including draining of lake-margin marshes, upstream agriculture and timber harvest, road construction, and boat traffic, may have affected the lake. Magnetic properties and reworked tephra suggest riparian changes throughout the basin and increased lithogenic sediment delivery to the lake, especially after 1920 when the marshes near the mouth of the Williamson River were drained and converted to agricultural and pasture land. Drainage and channelization also decreased the ability of the marshes to function as traps and filters for upstream water and sediments. Akinetes of Aphanizomenon flos-aquae record progressive eutrophication of Upper Klamath Lake beginning in the 20th century and particularly after 1920 when lake-margin marsh reclamation more than doubled. The coincidence of limnological changes and human activities following European settlement suggests a major impact on the Upper Klamath Lake ecosystem, although ascribing specific limnological changes to specific human activities is difficult.

Oregon↗

Non-water-ice constituents in the surface material of the icy Galilean satellites from the Galileo near-infrared mapping spectrometer investigation

We present evidence for several non‐ice constituents in the surface material of the icy Galilean satellites, using the reflectance spectra returned by the Galileo near infrared mapping spectrometer (NIMS) experiment. Five new absorption features are described at 3.4, 3.88, 4.05, 4.25, and 4.57 μm for Callisto and Ganymede, and some seem to exist for Europa as well. The four absorption bands strong enough to be mapped on Callisto and Ganymede are each spatially distributed in different ways, indicating different materials are responsible for each absorption. The spatial distributions are correlated at the local level in complex ways with surface features and in some cases show global patterns. Suggested candidate spectrally active groups, perhaps within larger molecules, producing the five absorptions include C‐H, S‐H, SO 2 , CO 2 , and C≡N. Organic material like tholins are candidates for the 4.57‐ and 3.4‐μm features. We suggest, based on spectroscopic evidence, that CO 2 is present as a form which does not allow rotational modes and that SO 2 is present neither as a frost nor a free gas. The CO 2 , SO 2 , and perhaps cyanogen (4.57 μm) may be present as very small collections of molecules within the crystal structure, perhaps following models for radiation damage and/or for comet and interstellar grain formation at low temperatures. Some of the dark material on these surfaces may be created by radiation damage of the CO 2 and other carbon‐bearing species and the formation of graphite. These spectra suggest a complex chemistry within the surface materials and an important role for non‐ice materials in the evolution of the satellite surfaces.

Journal of Geophysical Research E: Planets↗

Mineralogy and geochemistry of a sediment‐hosted hydrothermal sulfide deposit from the Southern Trough of Guaymas Basin, Gulf of California

Samples dredged from a 15‐m‐high hydrothermal mound atop the flat turbidite pond in the Southern Trough of Guaymas Basin consist of pyrrhotite‐rich massive sulfide, barite, barite + calcite, talc, and opaline silica as well as substrate material composed of fossiliferous, clay‐rich ooze. An 11‐m‐long sediment core taken near the dredge site shows increasing hydrothermal alteration with depth; anhydrite‐filled fractures near the base of the core appear to be channels for hydrothermal discharge. Oxidation of the sulfide‐rich samples to an assemblage of geothite, lepidocrocite, and amorphous Fe oxyhydroxide is ubiquitous. Compared to other massive sulfide deposits on sediment‐starved oceanic ridges, the hydrothermal deposit dredged in Guaymas Basin has a high pyrrhotite/pyrite ratio, a low Zn sulfide and combined ore metal (Cu + Zn + Pb + Ag + Cd) content, and a greater abundance of sulfate, carbonate, and silicate phases. Venting hydrothermal solutions are alkaline with moderately high p H; high Ca, Ba, and SiO 2 content; low ƒS 2 and ƒo 2 ; and very low transition metal content. Disequilibrium assemblages of pyrrhotite and sulfate minerals form during rapid mixing of this evolved vent fluid with ambient bottom waters at the discharge site. Talc is formed at a temperature near 270°C by mixing or entrainment of Mg‐rich bottom water or pore fluid with upwelling hydrothermal fluid that is saturated with silica. Calcite may precipitate from the alkaline, Ca‐rich fluid during degassing of CO 2 . The minimum temperature range for sulfide and nonsulfide deposition is approximately 190°–326°C. The composition of hydrothermal deposits, vent solutions, and altered sediment requires that circulating fluids evolve during deep penetration into the basaltic basement complex, further interaction with the organic‐and carbonate‐rich sediment pile, and near‐surface mixing with ambient seawater. Although the stable assemblage albite‐epidote‐clinochlore present at depth in the sediment pile requires very low dissolved Mg and Fe in the altering fluid, the addition of Mg to deeply buried sediment indicates significant recharge of the system by Guaymas Basin bottom water.

Southern Trough of Guaymas Basin↗

Use of airborne and terrestrial lidar to detect ground displacement hazards to water systems

We investigate the use of multiepoch airborne and terrestrial lidar to detect and measure ground displacements of sufficient magnitude to damage buried pipelines and other water system facilities that might result, for example, from earthquake or rainfall-induced landslides. Lidar scans are performed at three sites with coincident measurements by total station surveying. Relative horizontal accuracy is evaluated by measurements of lateral dimensions of well defined objects such as buildings and tanks; we find misfits ranging from approximately 5 to 12 cm, which is consistent with previous work. The bias and dispersion of lidar elevation measurements, relative to total station surveying, is assessed at two sites: (1) a power plant site (PP2) with vegetated steeply sloping terrain; and (2) a relatively flat and unvegetated site before and after trenching operations were performed. At PP2, airborne lidar showed minimal elevation bias and a standard deviation of approximately 70 cm, whereas terrestrial lidar did not produce useful results due to beam divergence issues and inadequate sampling of the study region. At the trench site, airborne lidar showed minimal elevation bias and reduced standard deviation relative to PP2 (6-20 cm), whereas terrestrial lidar was nearly unbiased with very low dispersion (4-6 cm). Pre- and posttrench bias-adjusted normalized residuals showed minimal to negligible correlation, but elevation change was affected by relative bias between epochs. The mean of elevation change bias essentially matches the difference in means of pre- and posttrench elevation bias, whereas elevation change standard deviation is sensitive to the dispersion of individual epoch elevations and their correlation coefficient. The observed lidar bias and standard deviations enable reliable detection of damaging ground displacements for some pipelines types (e.g., welded steel) but not all (e.g., concrete with unwelded, mortared joints). ?? ASCE 2009.

Journal of Surveying Engineering↗

Interannual climate variability and snowpack in the western United States

An important part of the water supply in the western United States is derived from runoff fed by mountain snowmelt Snow accumulation responds to both precipitation and temperature variations, and forms an interesting climatic index, since it integrates these influences over the entire late fall-spring period. Here, effects of cool season climate variability upon snow water equivalent (SWE) over the western part of the conterminous United States are examined. The focus is on measurements on/and 1 April, when snow accumulation is typically greatest. The primary data, from a network of mountainous snow courses, provides a good description of interannual fluctuations in snow accumulations, since many snow courses have records of five decades or more. For any given year, the spring SWE anomaly at a particular snow course is likely to be 25%–60% of its long-term average. Five separate regions of anomalous SWE variability are distinguished, using a rotated principal components analysis. Although effects vary with region and with elevation, in general, the anomalous winter precipitation has the strongest influence on spring SWE fluctuations. Anomalous temperature has a weaker effect overall, but it has great influence in lower elevations such as in the coastal Northwest, and during spring in higher elevations. The regional snow anomaly patterns are associated with precipitation and temperature anomalies in winter and early spring. Patterns of the precipitation, temperature, and snow anomalies extend over broad regional areas, much larger than individual watersheds. These surface anomalies are organized by the atmospheric circulation, with primary anomaly centers over the North Pacific Ocean as well as over western North America. For most of the regions, anomalously low SWE is associated with a winter circulation resembling the PNA pattern. With a strong low in the central North Pacific and high pressure over the Pacific Northwest, this pattern diverts North Pacific storms northward, away from the region. Both warm and cool phases of El Niño-Southern Oscillation tend to produce regional patterns with out-of-phase SWE anomalies in the Northwest and the Southwest.

Arizona, California, Colorado, Idaho, Montana, Nev↗

Intraglacial volcanism in the Wells Gray–Clearwater volcanic field, east-central British Columbia, Canada

Small-volume, subaerial, subaqueous and subglacial basaltic eruptions occurred in the Wells Gray–Clearwater area during Quaternary time. Part of this time, significant thicknesses of glacial ice were present. Dating of intraglacial volcanic features corroborates other evidence of an Early Pleistocene, Cordilleran-wide ice sheet. Of the intraglacial volcanoes investigated, three were studied in detail and of these, two probably erupted during the Fraser glaciation (11–20 ka), when maximum ice level exceeded 2100 m elevation. Major-element and sulphur concentrations were measured in glass from the volcanoes to provide insight into vent conditions at the time of eruption. Hyalo Ridge (2102 m elevation, whole-rock K–Ar age of 0.02 ± 0.01 Ma) is a small volcanic edifice capped by lava flows with coherent pillowed lavas and interbedded hyaloclastite exposed over nearly 400 m altitude on its east flank. Low sulphur content (<0.03 wt.%) in pillow rim glasses indicates that the lavas are degassed. It is interpreted that the vent built above the water (or ice) surface then fed lava flows that crossed a shoreline and produced pillowed flows. Pyramid Mountain is a volcanic cone 240 m high, comprised of glassy, vesicular, lapilli-tuff breccia. The highly alkalic glass contains 0.1 wt.% S (considered high), and indicates a high original volatile content and drastic quenching, probably during phreatomagmatic eruption from a meltwater-flooded vent. East of the Clearwater River a sequence of massive pillowed flows and pillow joint-block breccias is exposed from 880 to 1320 m elevation (0.27 ± 0.05 Ma). The vent location is unknown. Moderate S content (0.040–0.055 wt.%) indicates that the lavas were erupted in shallow water and are largely degassed. The S content of glass in dykes cutting the pillow breccias is low. The dykes are interpreted as lava that has flowed laterally or down into cracks

British Columbia↗

Four decades of regional wet deposition, local bulk deposition, and stream-water chemistry show the influence of nearby land use on forested streams in Central Appalachia☆

Hydrologic monitoring began on two headwater streams (<1 km 2 ) on the University of Kentucky's Robinson Forest in 1971. We evaluated stream-water (1974–2013) and bulk-deposition (wet + dust) (1984–2013) chemistry in the context of regional wet-deposition patterns that showed decreases in both sulfate and nitrate concentrations as well as proximal surface-mine expansion. Decadal time steps (1974–83, 1984–93, 1994–2003, 2004–2013) were used to quantify change. Comparison of the first two decades showed similarly decreased sulfate (minimum flow-adjusted annual-mean concentration of ≈13.5 mg/L in 1982 to 8.8 mg/L in 1992) and increased pH (6.6–6.8) in both streams, reflecting contemporaneous changes in both bulk and wet deposition. In contrast, concentrations of nitrate (0.14 to >0.25 mg/L) and base cations increased between these two decades, coinciding with expansion of surface mining between 1985 and 1995. In 2004, stream-water pH (6.7 in 2004), sulfate (9.2 mg/L), and nitrate (>0.11 mg/L) were similar to 1982, despite wet-deposition concentrations being lower. Base-cation concentrations were higher in the stream adjacent to ongoing surface mining relative to the stream situated near the middle of the experimental forest. However, pH decreased to approximately 5.7 by 2013 for both streams, which, combined with a shift in dominant cations from calcium to magnesium and potassium, indicates that the soil-buffering capacity of this landscape has been exceeded. Ratios of bulk deposition and stream-water concentrations indicate enrichment of sulfate (1.7–25.2) and cations (0.5–64.8), but not nitrogen (0.1–5.6), indicating that the Forest is not nitrogen saturated and that ongoing changes in water-quality are sulfate driven. When concentrations were adjusted to account for changes in streamflow (climate) over the 4 decades, external influences (land management/regulation) explained most change. The amount and direction of change differed among constituents, both between consecutive decades and between the first and last decades, reflecting the influence of localized surface mining even as regional wet deposition continued to improve due to the Clean Air Act. The implication is that localized stressors have the potential to out-pace the benefits of national environmental policies for communities that depend on local water-resources in similar environments.

Kentucky↗

Permeability of fault gouge under confining pressure and shear stress

The permeability of both clay-rich and non-clay gouges, as well as several pure clays, was studied as a function of confining pressures from 5 to 200 MPa and shear strain to 10. Permeability ranged over four orders of magnitude, from around 10 −22 to 10 −18 m 2 (1 darcy = 0.987 × 10 −12 m 2 ). The lowest values were characteristic of the montmorillonite-rich and finer grained non-clay gouges. Illite, kaolinite, and chlorite had intermediate permeabilities, while the highest values were typical of the serpentine and coarser grained non-clay gouges. Grain size was an important factor in determining permeability, particularly for the clay-rich samples. The coarse grained gouges were the most permeable and decreased in permeability after shearing. Conversely, the fine grained gouges had characteristically lower permeabilities that did not vary significantly after various amounts of shearing. The permeabilities of the non-clay samples were not significantly different than those of the clays. Therefore, comminuted rock flours can be equally as effective in reducing the flow of water as the characteristically low permeability clay gouges. The strengths of the samples were quite variable. The non-clay gouges were consistently the strongest, with yield points (beginning of nonelastic behavior) around 850 MPa, while montmorillonite had an anomalously low strength in relation to all the other gouges at 250 MPa. Strength of the saturated samples under drained (low pore pressure) conditions did not correlate with high or low permeability. However, the low permeabilities of these gouges could be a factor in the measured low shear stresses along fault regions if excess pore pressures were created as a result of shearing or compaction, and this pressure was unable to dissipate through a thick section of the material.

Journal of Geophysical Research Solid Earth↗

Silurian and Devonian miogeosynclinal and transitional rocks of the Fish Creek Reservoir window, central Idaho

Documentation of Devonian continental-shelf shallow-water carbonate rocks in the core of the Fish Creek Reservoir window shifts the known westernmost limit of the Devonian miogeosyncline 50 km (30 mi) southwest across the structural grain from the well-known miogeosynclinal sequence in the Lost River Range. The miogeosynclinal carbonate sequence in the window has a minimum thickness of 450 m (1,500 ft). It comprises the upper Lower Devonian (Emsian) and lower Middle Devonian (Eifelian) Carey Dolomite (new), the upper Middle Devonian (Givetian) and Upper Devonian Jefferson Formation, and the Upper Devonian Picabo Formation (new). Conodont faunas precisely date the Carey. The Picabo Formation, composed of interbedded sandy dolomite-pebble conglomerate and dolomitic quartzose sandstone, is unlike any previously described formation of Late Devonian or Early Mississippian age in central Idaho. It resembles parts of the Stansbury, Beirdneau, Leatham, and Victoria Formations, which reflect areas of local Late Devonian uplift and erosion of older shelf rocks in northern Utah and southeastern Idaho. Transitional (continental-slope) rocks of the Roberts Mountains Formation representing reef and offreef facies are thrust over the Devonian shelf sequence within the Fish Creek Reservoir window. The Roberts Mountains Formation here is precisely dated as latest Silurian (Pridolian, eosteinhornensis Zone) through earliest Devonian (Lochkovian) by a sequence of conodont faunas. The easternmost known exposures of possible Devonian siliceous facies rocks assigned to the Milligen(?) Formation are present less than 4.8 km (3 mi) southwest of the shelf sequence. Structural relations and paleotectonic reconstructions suggest that they have a minimum eastward translation of 32 km (20 mi). The Devonian continent-ocean basin interface, along which the Antler orogenic belt developed at this latitude, probably was located near the east edge of the present Idaho batholith.

Idaho↗

Spatiotemporal patterns in community structure of macroinvertebrates inhabiting calcareous periphyton mats

Calcareous floating periphyton mats in the southern Everglades provide habitat for a diverse macroinvertebrate community that has not been well characterized. Our study described this community in an oligotrophic marsh, compared it with the macroinvertebrate community associated with adjacent epiphytic algae attached to macrophytes in the water column, and detected spatial patterns in density and community structure. The floating periphyton mat (floating mat) and epiphytic algae in the water column (submerged epiphyton) were sampled at 4 sites (???1 km apart) in northern Shark River Slough, Everglades National Park (ENP), in the early (July) and late (November) wet season. Two perpendicular 90-m transects were established at each site and ???100 samples were taken in a nested design. Sites were located in wet-prairie spikerush-dominated sloughs with similar water depths and emergent macrophyte communities. Floating mats were sampled by taking cores (6-cm diameter) that were sorted under magnification to enumerate infauna retained on a 250-??m-mesh sieve and with a maximum dimension >1 mm. Our results showed that floating mats provide habitat for a macroinvertebrate community with higher densities (no. animals/g ash-free dry mass) of Hyalella azteca, Dasyhelea spp., and Cladocera, and lower densities of Chironomidae and Planorbella spp. than communities associated with submerged epiphyton. Densities of the most common taxa increased 3x to 15x from early to late wet season, and community differences between the 2 habitat types became more pronounced. Floating-mat coverage and estimated floating-mat biomass increased 20 to 30%, and 30 to 110%, respectively, at most sites in the late wet season. Some intersite variation was observed in individual taxa, but no consistent spatial pattern in any taxon was detected at any scale (from 0.2 m to 3 km). Floating mats and their resident macroinvertebrate communities are important components in the Everglades food web. This community should be included in environmental monitoring programs because degradation and eventual loss of the calcareous periphyton mat is associated with P enrichment in this ecosystem. ?? 2005 by The North American Benthological Society.

Journal of the North American Benthological Societ↗

Modeling consolidation and dewatering near the toe of the northern Barbados accretionary complex

At the toe of the northern Barbados accretionary complex, temperature and pore water chemistry data indicate that fluid flow is channeled along the décollement and other shallow thrust faults. We examine mechanisms that may prevent consolidation and maintain high permeability over large sections of the décollement. High-resolution bulk density data from five boreholes show that the décollement is well consolidated at some sites while other sites remain underconsolidated. Underconsolidated décollement behavior is associated with kilometer-scale negative-polarity seismic reflections from the décollement plane that have been interpreted to be fluid conduits. We use a coupled fluid flow/consolidation model to simulate the loading response of a 10-km-long by 680-m-thick slice of sediment as it enters the accretionary complex. The simulations capture 185 ka (5 km) of subduction, with a load function representing the estimated effective stress of the overriding accretionary prism (3.8° taper angle). Simulation results of bulk density in the décollement 3.2 km arcward of the deformation front are compared with observations. The results show that persistent high pore pressures at the arcward edge of the simulation domain can explain underconsolidated behavior. The scenario is consistent with previous modeling results showing that high pore pressures can propagate intermittently along the décollement from deeper in the complex. Simulated seaward fluxes in the décollement (1–14 cm yr −1 ) lie between previous estimates from modeling studies of steady state (<1 cm yr −1 ) and transient (>1 m yr −1 ) flow. Maximum simulated instantaneous fluid sources (2.5×10 −13 s −1 ) are comparable to previous estimates. The simulations show minor swelling of incoming sediments (fluid sources ∼−3×10 −15 s −1 ) up to 3 km before subduction that may help to explain small-scale shearing and normal faulting proximal to the protodécollement.

Atlantic Ocean, Northern Barbados Accretionary Com↗