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An update of the distribution of selected radiochemical and chemical constituents in perched ground water, Idaho National Laboratory, Idaho, Emphasis 1999-2001

Radiochemical and chemical wastes generated at facilities at the Idaho National Laboratory (INL) were discharged since 1952 to infiltration ponds at the Reactor Technology Complex (RTC) (known as the Test Reactor Area [TRA] until 2005), and the Idaho Nuclear Technology and Engineering Center (INTEC) and buried at the Radioactive Waste Management Complex (RWMC). Disposal of wastewater to infiltration ponds and infiltration of surface water at waste burial sites resulted in formation of perched ground water in basalts and in sedimentary interbeds above the Snake River Plain aquifer. Perched ground water is an integral part of the pathway for waste-constituent migration to the aquifer. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains ground-water monitoring networks at the INL to determine hydrologic trends, and to monitor the movement of radiochemical and chemical constituents in wastewater discharged from facilities to both perched ground water and the aquifer. This report presents an analysis of water-quality and water-level data collected from wells completed in perched ground water at the INL during 1999-2001, and summarizes historical disposal data and water-level-and water-quality trends. At the RTC, tritium, strontium-90, cesium-137, dissolved chromium, chloride, sodium, and sulfate were monitored in shallow and deep perched ground water. In shallow perched ground water, no tritium was detected above the reporting level. In deep perched ground water, tritium concentrations generally decreased or varied randomly during 1999-2001. During October 2001, tritium concentrations ranged from less than the reporting level to 39.4?1.4 picocuries per milliliter (pCi/mL). Reportable concentrations of tritium during July-October 2001 were smaller than the reported concentrations measured during July-December 1998. Tritium concentrations in water from wells at the RTC were likely affected by: well's distance from the radioactive-waste infiltration ponds (commonly referred to as the warm-waste ponds); water depth below the ponds; the amount of tritium discharged to radioactive-waste infiltration ponds in the past; discontinued use of radioactive-waste infiltration ponds; radioactive decay; and dilution from disposal of nonradioactive water. During 1999-2001, the strontium-90 concentrations in two wells completed in shallow perched water near the RTC exceeded the reporting level. Strontium-90 concentrations in water from wells completed in deep perched ground water at the RTC varied randomly with time. During October 2001, concentrations in water from five wells exceeded the reporting level and ranged from 2.8?0.7 picocuries per liter (pCi/L) in well USGS 63 to 83.8?2.1 pCi/L in well USGS 54. No reportable concentrations of cesium-137, chromium-51, or cobalt-60 were present in water samples from any of the shallow or deep wells at the RTC during 1999-2001. Dissolved chromium was not detected in shallow perched ground water at the RTC during 1999-2001. Concentrations of dissolved chromium during July-October 2001 in deep perched ground water near the RTC ranged from 10 micrograms per liter (?g/L) in well USGS 61 to 82 ?g/L in well USGS 55. The largest concentrations were in water from wells north and west of the radioactive-waste infiltration ponds. During July-October 2001, dissolved sodium concentrations ranged from 7 milligrams per liter (mg/L) in well USGS 78 to 20 mg/L in all wells except well USGS 68 (413 mg/L). Dissolved chloride concentrations in shallow perched ground water ranged from 10 mg/L in wells CWP 1, 3, and 4 to 53 mg/L in well TRA A 13 during 1999-2001. Dissolved chloride concentrations in deep perched ground water ranged from 5 mg/L in well USGS 78 to 91 mg/L in well USGS 73. The maximum dissolved sulfate concentration in shallow perched ground water was 419 mg/L in well CWP 1 during July 2000. Concentrations of dissolved sulfate in water from wells USGS 54, 60

Scientific Investigations Report

An international borderland of concern: Conservation of biodiversity in the Lower Rio Grande Valley

The Lower Rio Grande Valley (LRGV) of southern Texas is located on the United States-Mexico borderland and represents a 240-kilometer (150-mile) linear stretch that ends at the Gulf of Mexico. The LRGV represents a unique transition between temperate and tropical conditions and, as such, sustains an exceptionally high diversity of plants and animals—some of them found in few, or no other, places in the United States. Examples include Leopardus pardalis albescens (northern ocelot) and Falco femoralis septentrionalis (northern aplomado falcon)—both endangered in the United States and emblematic of the LRGV. The U.S. Fish and Wildlife Service (USFWS) manages three national wildlife refuges (Santa Ana, Lower Rio Grande Valley, and Laguna Atascosa) that together make up the South Texas Refuge Complex, which actively conserves biodiversity in about 76,006 hectares (187,815.5 acres) of native riparian and upland habitats in the LRGV. These diminished habitats harbor many rare, threatened, and endangered species. This report updates the widely used 1988 USFWS biological report titled “Tamaulipan Brushland of the Lower Rio Grande Valley of South Texas: Description, Human Impacts, and Management Options” by synthesizing nearly 400 peer-reviewed scientific publications that have resulted from biological and sociological research conducted specifically in the four Texas counties of the LRGV in the past nearly 30 years. This report has three goals: (1) synthesize scientific insights gained since 1988 related to the biology and management of the LRGV and its unique biota, focusing on flora and fauna of greatest conservation concern; (2) update ongoing challenges facing Federal and State agencies and organizations that focus on conservation or key natural resources in the LRGV; and (3) redefine conservation opportunities and land-acquisition strategies that are feasible and appropriate today, given the many new and expanding constraints that challenge conservation activities in the LRGV. The LRGV faces every contemporary conservation challenge of the 21st century, but ongoing human population growth and its associated demands, international border issues, and oil, gas, and alternative energy development dominate impacts that affect conservation in the LRGV. Continued careful syntheses of existing and future information collected in the LRGV are needed on many biological and sociological topics to guide conservation activities. Quick response will no doubt be necessary to face contemporary and difficult-to-predict challenges such as climate change, diminished water availability and quality, spread of invasive species, and habitat loss and fragmentation. Complexities of a guarded international borderland add pressure to small patches of native habitat that remain in many places of the LRGV, particularly along the Rio Grande. Large connected corridors of restored native habitat could be the best option to maintain, and even enhance, the exceptional biodiversity of the LRGV in the face of exceptional human demand.

Texas

Assessment of the presence of sewage in the Mill River under low-flow conditions, Springfield, Massachusetts, 2010–11

The U.S. Geological Survey, in cooperation with the Pioneer Valley Planning Commission, the U.S. Environmental Protection Agency, and the Massachusetts Department of Environmental Protection Senator William X. Wall Experiment Station, assessed the presence of 14 commonly used human-health pharmaceutical compounds, fecal indicator bacteria, and other man-made compounds indicative of the presence of human sewage in the lower reach of the Mill River near its confluence with the Connecticut River in Springfield, Massachusetts. The study was part of the Tri-State Connecticut River Targeted Watershed Initiative and involved the collection and analysis of raw river water at three sites along the reach, extending from Watershops Pond to the mouth, over the course of a low-flow period, July through November 2010. Previous studies in the region indicated that nonpoint or undocumented sources of wastewater contributed a variety of organic contaminants and potentially harmful bacteria to rivers under both high- and low-flow conditions. Additional samples, including a raw sewage sample collected near a Mill River combined sewer overflow during a non-overflow period, were collected in March 2011. The study was designed to determine if city sewage or other domestic sources of wastewater were entering the river within this reach during low-flow conditions. No definitive evidence of sewage was measured in Mill River water samples collected during the study period. Fecal indicator bacteria, including Escherichia coli ( E. coli ) and enterococci bacteria, were detected in all Mill River water samples. In the DNA analysis of enterococci cultures from the Mill River, samples generally tested negative for the Enterococcus faecium ( esp ) human-specific genetic marker, whereas the raw sewage sample tested positive. Samples also generally tested negative in the human-specific rDNA marker assay for the anaerobic bacterium Bacteroidetes . Samples tested negative in 2010 for two Bacteroidetes human-specific genetic markers, HF134 and HF183, except samples from near the mouth of the Mill River, which tested positive. Samples collected in March 2011 from all three measurement sites tested positive for both markers. The results of bacterial analyses suggest that the fecal bacteria in summer and fall months are most likely of animal origin rather than human. Despite the urban setting, long history of development, and many potential sources of man-made contamination in the Mill River, none of the 12 water samples collected during the study contained targeted pharmaceutical compounds at concentrations greater than the analytical reporting levels. Other man-made compounds, like fluorescent whitening agents, were measured and detected in samples at low concentrations 4 out of 5 times the samples were collected; however, the other lines of evidence do not support a sewer source but rather other nonpoint sources upstream in the watershed. The results of this study do not support the hypothesis that aging sewer lines or combined sewer overflow infrastructure leak into the Mill River as tested during the low-flow conditions during sampling for this study. None of the results from Mill River samples offer conclusive evidence of the presence of sewage. Some low-level detections of pharmaceutical compounds, other man-made chemicals, and bacteria suggest an upstream, nonpoint source. A single raw sewage sample was collected, diluted, and examined for comparison with Mill River water samples and to ensure that the analytical methods could detect typical wastewater constituents. High levels of bacteria were measured, and low levels of three anthropogenic pharmaceutical compounds were detected, confirming the effectiveness of the sub-part-per-million method. The concentration of fluorescent whitening agent-1 in the sewage sample was 90,000 times greater than the median concentration in the Mill River samples.

Massachusetts

Development of a screening tool to examine lake and reservoir susceptibility to eutrophication in selected watersheds of the eastern and southeastern United States

This report describes a new screening tool to examine lake and reservoir susceptibility to eutrophication in selected watersheds of the eastern and southeastern United States using estimated nutrient loading and flushing rates with measures of waterbody morphometry. To that end, the report documents the compiled data and methods (R-script) used to categorize waterbodies by Carlson’s Trophic State Index. Assessments were completed for 232 lakes and reservoirs having a surface area greater than or equal to 0.1 square kilometer in watersheds that drain to the Atlantic and eastern Gulf of Mexico coasts of the United States and in watersheds within the Tennessee River Basin. Waterbodies were categorized by type—natural lakes, headwater reservoirs, and downstream reservoirs—and were assessed independently. Recursive partitioning and the model-based boosting routine were used to create four-node regression trees to group waterbodies into five endpoints from low-to-high measures of Secchi depth, and concentrations of chlorophyll a and microcystin according to shared nutrient loading, flushing rate, and morphometric characteristics. Trophic state designations were assigned based on the average value within each of the five endpoints. An application (procedure) is provided using the tool to examine the susceptibility of a given waterbody of interest to eutrophication. Results of this study can aid water-resource managers in prioritizing lake and reservoir protection and restoration efforts based on the susceptibility of these waterbodies to eutrophication relative to nutrient loading, flushing rate, and morphometric characteristics.

Scientific Investigations Report

Assessment of water quality, benthic invertebrates, and periphyton in the Threemile Creek basin, Mobile, Alabama, 1999-2003

The U.S. Geological Survey conducted a 4-year investigation of water quality and aquatic-community structure in Threemile Creek, an urban stream that drains residential areas in Mobile, Alabama. Water-quality samples were collected between March 2000 and September 2003 at four sites on Threemile Creek, and between March 2000 and October 2001 at two tributary sites that drain heavily urbanized areas in the watershed. Stream samples were analyzed for major ions, nutrients, fecal-indicator bacteria, and selected organic wastewater compounds. Continuous measurements of dissolved-oxygen concentrations, water temperature, specific conductance, and turbidity were recorded at three sites on Threemile Creek during 1999?2003. Aquatic-community structure was evaluated by conducting one survey of the benthic invertebrate community and multiple surveys of the algal community (periphyton). Benthic invertebrate samples were collected in July 2000 at four sites on Threemile Creek; periphyton samples were collected at four sites on Threemile Creek and the two tributary sites during 2000 ?2003. The occurrence and distribution of chemical constituents in the water column provided an initial assessment of water quality in the streams; the structure of the benthic invertebrate and algal communities provided an indication of the cumulative effects of water quality on the aquatic biota. Information contained in this report can be used by planners and resource managers in the evaluation of proposed total maximum daily loads and other restoration efforts that may be implemented on Threemile Creek. The three most upstream sites on Threemile Creek had similar water chemistry, characterized by a strong calcium-bicarbonate component; the most downstream site on Threemile Creek was affected by tidal fluctuations and mixing from Mobile Bay and had a strong sodium-chloride component. The water chemistry at the tributary site on Center Street was characterized by a strong sodium-chloride component; the water chemistry at the second tributary site, Toulmins Spring Branch, was characterized by a strong calcium component without a dominant anionic species. The ratios of sodium to chloride at the tributary at Center Street were higher than typical values for seawater, indicating that sources other than seawater (such as leaking or overflowing sewer systems or industrial discharge) likely are contributors to the increased levels of sodium and chloride. Concentrations of fluoride and boron also were elevated at this site, indicating possible anthropogenic sources. Dissolved-oxygen concentrations were not always within levels established by the Alabama Department of Environmental Management; continuous monitors recorded dissolved-oxygen concentrations that were repeatedly less than the minimum criterion (3.0 milligrams per liter) at the most downstream site on Threemile Creek. Water temperature exceeded the recommended criterion (32.2 degrees Celsius) at five of six sites in the Threemile Creek basin. The pH values were within established criteria (6.0 ? 8.5) at sites on Threemile Creek; however, pH values ranged from 7.2 to 10.0 at the tributary at Center Street and from 6.6 to 9.9 at Toulmins Spring Branch. Nutrient concentrations in the Threemile Creek basin reflect the influences of both land use and the complex hydrologic systems in the lower part of the basin. Nitrite-plus-nitrate concentrations exceeded U.S. Environmental Protection Agency ecoregion nutrient criteria in 88 percent of the samples. In 45 percent of the samples, total phosphorus concentrations exceeded the U.S. Environmental Protection Agency goal of 0.1 milligram per liter for preventing nuisance aquatic growth. Ratios of nitrogen to phosphorus indicate that both nutrients have limiting effects. Median concentrations of enterococci and fecal coliform bacteria were highest at the two tributary sites and lowest at the most upstream site on Threemile Creek. In general, concentrations o

Scientific Investigations Report

Coeur d'Alene Lake, Idaho: Insights gained From limnological studies of 1991-92 and 2004-06

More than 100 years of mining and processing of metal-rich ores in northern Idaho’s Coeur d’Alene River basin have resulted in widespread metal contamination of the basin’s soil, sediment, water, and biota, including Coeur d’Alene Lake. Previous studies reported that about 85 percent of the bottom of Coeur d’Alene Lake is substantially enriched in antimony, arsenic, cadmium, copper, lead, mercury, silver, and zinc. Nutrients in the lake also are a major concern because they can change the lake’s trophic status—or level of biological productivity—which could result in secondary releases of metals from contaminated lakebed sediments. This report presents insights into the limnological functioning of Coeur d’Alene Lake based on information gathered during two large-scale limnological studies conducted during calendar years 1991–92 and water years 2004–06. Both limnological studies reported that longitudinal gradients exist from north to south for decreasing water column transparency, loss of dissolved oxygen, and increasing total phosphorus concentrations. Gradients also exist for total lead, total zinc, and hypolimnetic dissolved oxygen concentrations, ranging from high concentrations in the central part of the lake to lower concentrations at the northern and southern ends of the lake. In the southern end of the lake, seasonal anoxia serves as a mechanism to release dissolved constituents such as phosphorus, nitrogen, iron, and manganese from lakebed sediments and from detrital material within the water column. Nonparametric statistical hypothesis tests at a significance level of α=0.05 were used to compare analyte concentrations among stations, between lake zones, and between study periods. The highest dissolved oxygen concentrations were measured in winter in association with minimum water temperatures, and the lowest concentrations were measured in the Coeur d’Alene Lake hypolimnion during late summer or autumn as prolonged thermal stratification restricted mixing of the oxygenated upper water column and the hypolimnion, where oxygen was consumed. Large differences in median concentrations of dissolved inorganic nitrogen were measured between the euphotic zone and hypolimnion in the deep areas of the lake. These differences in nitrogen concentrations were attributable to several limnological processes, including seasonal inflow plume routing, isolation from wind-driven circulation and associated hypolimnetic enrichment, phytoplanktonic assimilation during summer months, and benthic flux. Increased chlorophyll- a and total phosphorus concentrations were measured throughout the lake in the 2004–06 study compared with results from the 1991–92 study. No significant change in hypolimnetic dissolved inorganic nitrogen concentration throughout the lake was noted even though total nitrogen loads into the lake decreased between study periods. Total zinc and total lead decreased throughout the lake from the 1991-92 study to the 2004-06 study except in the southern part of the lake, where concentrations were typically low. Median detected nitrogen-to-phosphorus ratios decreased from the 1991–92 study to the 2004–06 study. Whereas the lake was clearly phosphorus-limited in 1991–92, in 2004–06 the lake may have been much closer to the boundary value of 7.2 that separates nitrogen from phosphorus limitation. However, due to changes in analytical reporting limits in the period between the two studies, the data are insufficiently certain to draw reliable conclusions with regard to limiting nutrients. For both studies, the trophic state of the lake was classified as oligotrophic (less productive) or mesotrophic (moderately productive), depending on the constituent used for classification. Internal circulation from wind-generated waves and changes in the lake’s thermocline are important processes for distribution of water-quality constituents throughout Coeur d’Alene Lake. Surficial distribution of trace metals throughout most of the lake, including bays, is relatively uniform. Even south of the Coeur d’Alene River mouth, lakebed sediments are contaminated with trace metals. Inflow plume routing of the two primary inflow sources, the Coeur d’Alene and St. Joe Rivers, also significantly affects the fate and transport of contaminants. Most riverine inflows appear to move through the lake as overflow during summer, interflow during spring and autumn, and underflow during winter. Benthic flux is another key transport process for contaminants in Coeur d’Alene Lake. The results of in situ benthic flux chamber experiments indicated movement of dissolved metals, nutrients, and dissolved organic carbon out of the lakebed sediments. However, the lake is an overall sink for these constituents when they are associated with particulate material.

Idaho

Constituent concentrations, loads, and yields to Beaver Lake, Arkansas, water years 1999-2008

Beaver Lake is a large, deep-storage reservoir used as a drinking-water supply and considered a primary watershed of concern in the State of Arkansas. As such, information is needed to assess water quality, especially nutrient enrichment, nutrient-algal relations, turbidity, and sediment issues within the reservoir system. Water-quality samples were collected at three main inflows to Beaver Lake: the White River near Fayetteville, Richland Creek at Goshen, and War Eagle Creek near Hindsville. Water-quality samples collected over the period represented different flow conditions (from low to high). Constituent concentrations, flow-weighted concentrations, loads, and yields from White River, Richland Creek, and War Eagle Creek to Beaver Lake for water years 1999-2008 were documented for this report. Constituents include total ammonia plus organic nitrogen, dissolved nitrite plus nitrate nitrogen, dissolved orthophosphorus (soluble reactive phosphorus), total phosphorus, total nitrogen, dissolved organic carbon, total organic carbon, and suspended sediment. Linear regression models developed by computer program S-LOADEST were used to estimate loads for each constituent for the 10-year period at each station. Constituent yields and flow-weighted concentrations for each of the three stations were calculated for the study. Constituent concentrations and loads and yields varied with time and varied among the three tributaries contributing to Beaver Lake. These differences can result from differences in precipitation, land use, contributions of nutrients from point sources, and variations in basin size. Load and yield estimates varied yearly during the study period, water years 1999-2008, with the least nutrient and sediment load and yields generally occurring in water year 2006, and the greatest occurring in water year 2008, during a year with record amounts of precipitation. Flow-weighted concentrations of most constituents were greatest at War Eagle Creek near Hindsville than White River near Fayetteville and Richland Creek at Goshen. Loads and yields of most constituents were greater at the War Eagle Creek and White River stations than at the Richland Creek Station.

Scientific Investigations Report

Groundwater and surface-water interaction and potential for underground water storage in the Buena Vista-Salida Basin, Chaffee County, Colorado, 2011

By 2030, the population of the Arkansas Headwaters Region, which includes all of Chaffee and Lake Counties and parts of Custer, Fremont, and Park Counties, Colorado, is forecast to increase about 73 percent. As the region’s population increases, it is anticipated that groundwater will be used to meet much of the increased demand. In September 2009, the U.S. Geological Survey, in cooperation with the Upper Arkansas Water Conservancy District and with support from the Colorado Water Conservation Board; Chaffee, Custer, and Fremont Counties; Buena Vista, Cañon City, Poncha Springs, and Salida; and Round Mountain Water and Sanitation District, began a 3-year study of groundwater and surface-water conditions in the Buena Vista-Salida Basin. This report presents results from the study of the Buena Vista-Salida Basin including synoptic gain-loss measurements and water budgets of Cottonwood, Chalk, and Browns Creeks, changes in groundwater storage, estimates of specific yield, transmissivity and hydraulic conductivity from aquifer tests and slug tests, an evaluation of areas with potential for underground water storage, and estimates of stream-accretion response-time factors for hypothetical recharge and selected streams in the basin. The four synoptic measurements of flow of Cottonwood, Chalk, and Browns Creeks, suggest quantifiable groundwater gains and losses in selected segments in all three perennial streams. The synoptic measurements of flow of Cottonwood and Browns Creeks suggest a seasonal variability, where positive later-irrigation season values in these creeks suggest groundwater discharge, possibly as infiltrated irrigation water. The overall sum of gains and losses on Chalk Creek does not indicate a seasonal variability but indicates a gaining stream in April and August/September. Gains and losses in the measured upper segments of Chalk Creek likely are affected by the Chalk Cliffs Rearing Unit (fish hatchery). Monthly water budgets were estimated for selected segments of five perennial streams (Cottonwood, North Cottonwood, Chalk, and Browns Creeks, and South Arkansas River) in the Buena Vista-Salida Basin for calendar year 2011. Differences between reported diversions and estimated crop irrigation requirements were used to estimate groundwater recharge in the areas irrigated by water supplied from the diversions. The amount of groundwater recharge in all the basins varied monthly; however, the greatest amount of recharge was during June and July for Cottonwood, North Cottonwood, and Chalk Creeks and South Arkansas River. The greatest amount of recharge in 2011 in Browns Creek occurred in July and August. The large seasonal fluctuations of groundwater near irrigated areas in the Buena Vista-Salida Basin indicate that the increased groundwater storage resulting from infiltration of surface-water diversions has dissipated by the following spring. Areas within the Buena Vista-Salida Basin with the potential for underground storage were identified using geographic information system data, including topographic, geologic, and hydrologic data, excluding the mountainous areas that border the Buena Vista-Salida Basin and igneous and metamorphic rock outcrop areas. The areas that met the selection criteria for underground water storage are located on terrace deposits near the Arkansas River and adjacent to its major tributaries. The selected areas also contain much of the irrigated land within the basin; consequently, irrigation ditches and canals could provide a means of conveying water to potential recharge sites.

Colorado

The discovery and character of Pleistocene calcrete uranium deposits in the Southern High Plains of west Texas, United States

This report describes the discovery and geology of two near-surface uranium deposits within calcareous lacustrine strata of Pleistocene age in west Texas, United States. Calcrete uranium deposits have not been previously reported in the United States. The west Texas uranium deposits share characteristics with some calcrete uranium deposits in Western Australia—uranium-vanadium minerals hosted by nonpedogenic calcretes deposited in saline lacustrine environments. In the mid-1970s, Kerr-McGee Corporation conducted a regional uranium exploration program in the Southern High Plains province of the United States, which led to the discovery of two shallow uranium deposits (that were not publicly reported). With extensive drilling, Kerr-McGee delineated one deposit of about 2.1 million metric tons of ore with an average grade of 0.037 percent U 3 O 8 and another deposit of about 0.93 million metric tons of ore averaging 0.047 percent U 3 O 8 . The west-Texas calcrete uranium-vanadium deposits occur in calcareous, fine-grained sediments interpreted to be deposited in saline lakes formed during dry interglacial periods of the Pleistocene. The lakes were associated with drainages upstream of a large Pleistocene lake. Age determinations of tephra in strata adjacent to one deposit indicate the host strata is middle Pleistocene in age. Examination of the uranium-vanadium mineralization by scanning-electron microscopy indicated at least two generations of uranium-vanadium deposition in the lacustrine strata identified as carnotite and a strontium-uranium-vanadium mineral. Preliminary uranium-series results indicate a two-component system in the host calcrete, with early lacustrine carbonate that was deposited (or recrystallized) about 190 kilo-annum, followed much later by carnotite-rich crusts and strontium-uranium-vanadium mineralization in the Holocene (about 5 kilo-annum). Differences in initial 234 U/ 238 U activity ratios indicate two separate, distinct fluid sources.

Texas

Mapping the altitude of the top of the Dockum Group and paleochannel analysis using surface geophysical methods on and near Cannon Air Force Base in Curry County, New Mexico, 2020

The hydrogeology on and near Cannon Air Force Base (AFB) in eastern New Mexico was assessed to gain a better understanding of preferential groundwater flow paths through paleochannels. In and near the study area, paleochannels incised the top surface of the Dockum Group (Chinle Formation) and were subsequently filled in with electrically resistive coarse-grained sediments of the overlying Ogallala Formation, resulting in a preferential groundwater flow path in the form of a paleochannel network. A better understanding of the spatial characteristics of this preferential groundwater flow path is needed to support ongoing efforts to remediate groundwater contamination at Cannon AFB. Therefore, the U.S. Geological Survey, in cooperation with the U.S. Air Force Civil Engineer Center, used surface geophysical resistivity methods and data compiled from previous studies to better understand the spatial distribution and characteristics of the paleochannel network incised into the top of the Dockum Group. Previous studies have shown these paleochannels incised into the top of the Dockum Group with increasing resolution, but limited borehole data on and near Cannon AFB continued to make accurately mapping the top of Dockum Group challenging. For this study, surface geophysical resistivity measurements in the form of time-domain electromagnetic soundings made by the U.S. Geological Survey were used in conjunction with data previously published by Architecture, Engineering, Construction, Operations, and Management and borehole data compiled from the New Mexico Water Rights Reporting System database to prepare an updated map of the top of the Dockum Group that includes the location and characteristics of paleochannels incised into the top of the Dockum Group (Chinle Formation). A total of 149 borehole picks (determinations of the tops and bases of geologic units and their hydrogeologic-unit equivalents) were obtained from previous studies, along with 72 additional borehole picks from the New Mexico Water Rights Reporting System database and 43 picks from newly collected time-domain electromagnetic soundings. The data were gridded and contoured using Oasis Montaj v. 9.8.1. The updated map of the top of Dockum Group has many areas of uncertainty greater than 20 feet, because there are not enough data for the gridding process to reliably determine a value. However, this interpretation of the altitude of the top of the Dockum Group represents a substantial improvement in data resolution compared to previous studies. Two methodologies were used to evaluate paleochannels incised in the top of the Dockum Group across the study area: (1) trend-removal grid analysis and (2) analysis with Esri’s ArcMap Hydrology toolset. These two paleochannel analysis techniques show groundwater flow direction as well as areas having the deepest saturated thickness. Hydrologically, these techniques show where aquifer storage is highest (in the deepest parts of the paleochannel network), as well as the spatial distribution of preferential groundwater flow paths (the paleochannels). The analyses indicate a large paleochannel trending to the southeast, with smaller channels feeding in from the west. Areas where groundwater management could be more beneficial are indicated by locations where these flow lines intersect the deeper parts of the paleochannel.

New Mexico

Factors Affecting Water Quality in Domestic Wells in the Upper Floridan Aquifer, Southeastern United States, 1998-2005

The Floridan aquifer system is a highly productive carbonate aquifer that provides drinking water to about 10 million people in Florida, Georgia, and South Carolina. Approximately 1.6 million people rely on domestic wells (privately owned household wells) for drinking water. Withdrawals of water from the Floridan aquifer system have increased by more than 500 percent from 630 million gallons per day (2.38 cubic meters per day) in 1950 to 4,020 million gallons per day (15.2 cubic meters per day) in 2000, largely due to increases in population, tourism, and agriculture production. Water samples were collected from 148 domestic wells in the Upper Floridan aquifer in Florida, Georgia, South Carolina, and Alabama during 1998-2005 as part of the U.S. Geological Survey (USGS) National Water-Quality Assessment Program. The wells were located in different hydrogeologic settings based on confinement of the Upper Floridan aquifer. Five networks of wells were sampled con-sisting of 28 to 30 wells each: two networks were in unconfined areas, two networks were in semiconfined areas, and one network was in the confined area. Physical properties and concentrations of major ions, trace elements, nutrients, radon, and organic compounds (volatile organic compounds and pesticides) were measured in water samples. Concentrations were compared to water-quality benchmarks for human health, either U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Levels (MCLs) for public water supplies or USGS Health-Based Screening Levels (HBSLs). The MCL for fluoride of 4 milligrams per liter (mg/L) was exceeded for two samples (about 1 percent of samples). A proposed MCL for radon of 300 picocuries per liter was exceeded in about 40 percent of samples. Nitrate concentrations in the Upper Floridan aquifer ranged from less than the laboratory reporting level of 0.06 to 8 mg/L, with a median nitrate concentration less than 0.06 mg/L (as nitrogen). Nitrate concentrations did not exceed the MCL of 10 mg/L. Statistical comparisons indicated that median nitrate concentrations were significantly different by degree of confinement where the highest median nitrate concentration was 1.46 mg/L for 58 samples from unconfined areas, and by network, where the highest median nitrate concentration was 2.43 mg/L in 28 samples from unconfined areas in southwestern Georgia. Nitrate concentrations in unconfined areas were positively correlated to: (1) the percentage of agricultural land use around the well, (2) the amount of nitrogen fertilizer applied, and (3) the dissolved oxygen concentrations in groundwater. Volatile organic compounds (VOCs) were detected in about 63 percent of all samples. Chloroform, carbon disulfide, and 1,2-dichloropropane were the most frequently detected VOCs. Chloroform, a byproduct of water chlorination, was most frequently detected in unconfined urban areas. Carbon disulfide, a solvent, was most frequently detected in confined areas in southeastern Georgia. Pesticides were detected in about 21 percent of all samples, but were detected in about 69 percent of the 28 samples from unconfined areas in southwestern Georgia. The herbicides atrazine, deethylatrazine, and metolachlor were the most frequently detected pesticides.

Scientific Investigations Report

A conceptual site model of contaminant transport pathways from the Bremerton Naval Complex to Sinclair Inlet, Washington, 2011–21

Historical activities on the Bremerton Naval Complex (BNC) in Puget Sound, Washington, have resulted in Sinclair Inlet sediments with elevated concentrations of contaminants, including organic contaminants such as polychlorinated biphenyls and trace elements including mercury. Six U.S. Geological Survey–U.S. Navy datasets have been collected since the last major assessment, in 2013, of soil and groundwater contaminant transport pathways and mercury loading estimates from the BNC to Sinclair Inlet. These include: mercury isotope analysis to support sourcing of mercury in Sinclair Inlet; mercury sampling within the dry dock systems; nearshore thermal surveys to identify potential groundwater discharge locations to Sinclair Inlet; time-series monitoring in nearshore wells to understand the inland extent and dynamics of the tidal mixing zone; tidal studies of mercury in nearshore monitoring wells in an area of contaminated fill material called Site 1; and a spatial survey of trace elements and other parameters in nearshore monitoring wells, pore water, seeps, surface water, and sediment along unwalled shorelines in the western part of the BNC. The results were incorporated into an updated Conceptual Site Model and used to update contaminant load estimates from the terrestrial BNC to Sinclair Inlet. The results from these studies provide data to the U.S. Navy to support prioritization of on-going remediation actions to manage contamination on the BNC that reduce potential impacts to Sinclair Inlet sediment, surface water, and fish and shellfish tissue. Mercury isotope analysis of surface sediments and particulate material indicated that a similar industrial mercury profile is present throughout Puget Sound, including terrestrial and marine BNC samples and in other Sinclair Inlet sediments and persists across regions with low and elevated mercury concentrations. Two sources of mercury at the BNC are Sites 1 and 2 subsurface soils/fill material, with total mercury concentrations in particulates collected from the bottom of monitoring wells drilled in these materials ranging from 18,000 to 44,000 nanograms per gram (as compared to the Washington State Marine Sediment Cleanup Screening Level of 590 nanograms per gram). Contaminants are transported from the terrestrial BNC to Sinclair Inlet via three primary pathways, (1) stormwater outfalls, (2) dry dock discharges, and (3) direct discharge along unwalled shorelines. Previous loading estimates (based on filtered total mercury) ranked stormwater outfalls, particularly outfall PSNS015 in Site 2 soils, as the largest soil and groundwater contaminant transport pathway from the terrestrial BNC to Sinclair Inlet. Updated loading estimates in this report suggest that the dry dock systems may be a larger pathway of mercury from the terrestrial BNC to Sinclair Inlet than previously thought, within the same order of magnitude as the PSNS015 storm-drain system. Trace-element loads via direct shoreline discharge are difficult to estimate due to the large and dynamic tidal mixing zone of groundwater and seawater in the nearshore along unwalled shorelines. However, current best estimated ranges suggest that direct shoreline discharge is one of the three main pathways and may contribute smaller mercury loads than the stormwater and the dry dock systems. Along unwalled shorelines, direct groundwater discharge of terrestrial contaminants may be less important than recirculating seawater in the nearshore mixing zone that can extract contaminants from nearshore subsurface material. Total estimated mercury loads from the terrestrial BNC to Sinclair Inlet range from approximately 40 to 200 grams of filtered total mercury per year and a minimum of 70–350 grams of particulate total mercury per year, for a minimum total of 110–525 grams of whole (filtered plus particulate) total mercury per year. Data gaps are identified that, if filled, would further refine the Conceptual Site Model and contaminant loading estimates from the terrestrial BNC to Sinclair Inlet.

Washington

Water-quality characteristics of Montana streams in a statewide monitoring network, 1999-2003

A statewide monitoring network of 38 sites was operated during 1999-2003 in cooperation with the Montana Department of Environmental Quality to provide a broad geographic base of water-quality information on Montana streams. The purpose of this report is to summarize and describe the water-quality characteristics for those sites. Samples were collected at U.S. Geological Survey streamflow-gaging stations in the Missouri, Yellowstone, and Columbia River basins for stream properties, nutrients, suspended sediment, major ions, and selected trace elements. Mean annual streamflows were below normal during the period, which likely influenced water quality. Continuous water-temperature monitors were operated at 26 sites. The median of daily mean water temperatures for the June-August summer period ranged from 12.5 degC at Kootenai River below Libby Dam to 23.0 degC at Poplar River near Poplar and Tongue River at Miles City. In general, sites in the Missouri River basin commonly had the highest water temperatures. Median daily mean summer water temperatures at four sites (Jefferson River near Three Forks, Missouri River at Toston, Judith River near Winifred, and Poplar River near Poplar) classified as supporting or marginally supporting cold-water biota exceeded the general guideline of 19.4 degC for cold-water biota. Median daily mean temperatures at sites in the network classified as supporting warm-water biota did not exceed the guideline of 26.7 degC for warm-water biota, although several sites exceeded the warm-water guideline on several days during the summer. More...

Scientific Investigations Report

Evaluation of mercury in rainbow trout collected from Duck Valley Indian Reservation reservoirs, southwestern Idaho and northern Nevada, 2007, 2009, and 2013

The U.S. Geological Survey, in cooperation with the Shoshone-Paiute Tribes of the Duck Valley Indian Reservation, analyzed mercury (Hg) concentration in rainbow trout ( Oncorhynchus mykiss ) collected from three reservoirs on the reservation (Mountain View, Lake Billy Shaw, and Sheep Creek) during sampling events in 2007, 2009, and 2013, to determine the risk of Hg exposure to Tribal members and the general public. Mercury concentration in predatory fish tends to increase with fish length, and this tendency was true for rainbow trout in the reservoirs on the reservation (r 2 = 0.44–0.70). Mean (average) and median Hg concentrations in fish tissue were determined for each reservoir for each sample year. All Hg concentrations were less than the U.S. Environmental Protection Agency’s water-quality criterion of 0.30 milligram per kilogram (mg/kg wet weight [ww]) and the Idaho Department of Environmental Quality’s reasonable potential to exceed threshold of 0.24 mg/kg. Idaho Department of Health and Welfare toxicologists determined that the Hg concentrations in rainbow trout in this study would not warrant a fish-consumption advisory for this species. Throughout this report, statistical findings with a p -value of less than 0.05 are referred to as “significant.” Mean Hg concentrations in fish-tissue samples collected from Mountain View Reservoir were higher in 2007 (0.12 mg/kg ww) than in 2009 and 2013 (0.07 and 0.06 mg/kg ww, respectively), indicating a significant mean decrease. Mean Hg concentrations in fish-tissue samples collected from Lake Billy Shaw showed no significant differences among sample years (2007, 0.12 mg/kg ww; 2009, 0.07 mg/kg ww; 2013, 0.09 mg/kg ww). Mean Hg concentrations in fish-tissue samples collected from Sheep Creek Reservoir significantly increased in 2013 (0.10 mg/kg ww) from concentrations in 2007 and 2009 (0.06 and 0.05 mg/kg ww, respectively). These temporal and spatial variations are not unexpected, as each body of water may differ in the factors and conditions affecting the rate of methylation and demethylation. Coupled with the dynamic put-and-take fishery, the outcomes reflect the system complexities among reservoirs despite their fairly close proximity to one another. The influence of these other factors is evident when the analysis of atmospheric Hg deposition at Mercury Deposition Network site NV02 in northern Nevada showed no significant linear trend in wet Hg deposition rates for 2003–2013 (average 3.02 micrograms per square meter).

Idaho, Nevada

Borehole analysis, single-well aquifer testing, and water quality for the Burnpit well, Mount Rushmore National Memorial, South Dakota

Mount Rushmore National Memorial (hereafter referred to as “the memorial”), in western South Dakota, is maintained by the National Park Service (NPS) and includes 1,278 acres of land in the east-central part of the Black Hills. An ongoing challenge for NPS managers at the memorial is providing water from sustainable and reliable sources for operations, staff, and the increasing number of visitors. In 2020, the U.S. Geological Survey (USGS) and NPS completed a hydrological study of the Burnpit well (well 5), a 580-foot-deep open hole groundwater well completed in metamorphic (crystalline) rock at the memorial. The purpose of this study was to estimate the geological and hydraulic properties of the aquifer supplying the well and to determine the water quality of the groundwater from the well. The study provides NPS staff and managers background information for assessing future uses for the well. Methods for data collection and analysis for the study included borehole and video camera analysis in 2020, aquifer testing by the NPS in 2009 and the USGS in 2020, and water-quality sampling in 2020. Borehole camera video generally matched the lithology recorded in the well log. Fractures recorded in the well log and observed with the borehole camera, including more than 20 less prominent fractures and rough sidewall areas, indicated a fractured aquifer. The fractures are the primary conduits for groundwater flow through the rock and into the well. Transmissivity was estimated for the upper and lower water-level drawdown zones at the Burnpit well with data from the NPS and USGS using the Theis and Cooper-Jacob methods. Transmissivity for the NPS test using the Theis method was 9.0 and 11 feet squared per day (ft 2 /d) for the upper and lower drawdown zones, respectively. Using the Cooper-Jacob method, the transmissivity was 22 and 14 ft 2 /d for the upper and lower drawdown zones of the aquifer, respectively. Transmissivity estimates from data from the USGS test were similar. The Theis method, applied to the upper and lower drawdown zones of the aquifer, produced transmissivity estimates of 7.7 and 10 ft 2 /d, and the Cooper-Jacob method produced estimates of 9.7 and 12 ft 2 /d, respectively. Storativity (specific yield) estimated using the Theis method for the NPS aquifer-test data was 0.85 and 0.92 for the upper and lower drawdown zones of the aquifer, respectively. The Cooper-Jacob method applied to the NPS aquifer-test data produced storativity estimates of 0.11 and 0.50 for the upper and lower drawdown zones, respectively. The Theis method applied to the USGS aquifer-test data estimated storativity values of 0.77 and 1.0 for the upper and lower drawdown zones, respectively. The Cooper-Jacob method estimated storativity of 0.50 and 0.60 for the upper and lower drawdown zones of the USGS aquifer test, respectively. The estimated storativity values from the NPS and USGS aquifer tests for the upper and lower drawdown zones were higher than expected for limestones and schists. The hypothetical equilibrium drawdown for the Burnpit well was estimated after the NPS test in 2009 at no more, and possibly less, than 35 gallons per minute. The NPS noted that the sustainable yield likely was overestimated because the water level did not stabilize during the NPS aquifer test. The specific capacity for the NPS aquifer test in 2009 was 0.16 gallon per minute per foot ([gal/min]/ft) of drawdown at 3 hours, and the specific capacity for the USGS aquifer test in 2020 was 0.13 (gal/min)/ft of drawdown at 3 hours. The rate of water-level recovery after pumping ceased was 0.017 and 0.013 (gal/min)/ft for the NPS and USGS aquifer tests, respectively. The water-level recovery rate was nearly an order of magnitude less than the specific capacity estimated during pumping, indicating that water levels in the Burnpit well may not recover quickly enough during pumping to provide for a continuous source of water. Water-quality samples were collected at the Burnpit well on June 24 and July 23, 2020, and analyzed for field-measured properties, major ions, metals, nutrients, and perchlorate. Iron, zinc, and lithium concentrations for unfiltered samples in the well were at least three times greater than the mean filtered sample concentrations reported for crystalline aquifers in the Black Hills. Manganese concentrations were less than the mean concentration for crystalline aquifers but exceeded the U.S. Environmental Protection Agency (EPA) secondary drinking-water standards. The iron concentration from the June 24 sample was about 11 times greater than the EPA secondary drinking-water standards and mean concentrations from crystalline aquifers in the Black Hills. Arsenic concentrations in Burnpit well samples collected in 2020 were greater than the EPA primary drinking-water standard and the mean concentration for crystalline aquifers in the Black Hills. Arsenic occurs naturally in the rock of crystalline aquifers, and concentrations from samples in the Black Hills commonly exceed the EPA primary drinking-water standard of 10 micrograms per liter. High concentrations of arsenic, iron, and manganese metals in the Burnpit well make groundwater from the well in its natural state unusable as a drinking-water source, and water treatment would be necessary to reduce the trace element concentrations to less than the EPA primary and secondary drinking-water standards. However, if the memorial has immediate nonpotable water requirements, such as for construction and fire suppression, groundwater from the Burnpit well could provide water without causing additional stress to current (2021) drinking-water sources.

South Dakota

Hydrologic conditions, groundwater quality, and analysis of sink hole formation in the Albany area of Dougherty County, Georgia, 2009

The U.S. Geological Survey, in cooperation with the Albany Water, Gas, and Light Commission has conducted water resources investigations and monitored groundwater conditions and availability in the Albany, Georgia, area since 1977. This report presents an overview of hydrologic conditions, water quality, and groundwater studies in the Albany area of Dougherty County, Georgia, during 2009. Historical data also are presented for comparison with 2009 data. During 2009, groundwater-level data were collected in 29 wells in the Albany area to monitor water-level trends in the surficial, Upper Floridan, Claiborne, Clayton, and Providence aquifers. Groundwater-level data from 21 of the 29 wells indicated an increasing trend during 2008–09. Five wells show no trend due to lack of data and three wells have decreasing trends. Period-of-record water levels (period of record ranged between 1957–2009 and 2003–2009) declined slightly in 10 wells and increased slightly in 4 wells tapping the Upper Floridan aquifer; declined in 1 well and increased in 2 wells tapping the Claiborne aquifer; declined in 4 wells and increased in 2 wells tapping the Clayton aquifer; and increased in 1 well tapping the Providence aquifer. Analyses of groundwater samples collected during 2009 from 12 wells in the Upper Floridan aquifer in the vicinity of a well field located southwest of Albany indicate that overall concentrations of nitrate plus nitrite as nitrogen increased slightly from 2008 in 8 wells. A maximum concentration of 12.9 milligrams per liter was found in a groundwater sample from a well located upgradient from the well field. The distinct difference in chemical constituents of water samples collected from the Flint River and samples collected from wells located in the well-field area southwest of Albany indicates that little water exchange occurs between the Upper Floridan aquifer and Flint River where the river flows adjacent to, but downgradient of, the well field. Water-quality data collected during 2008 from two municipal wells located in northern Albany and downgradient from a hazardous waste site indicate low-level concentrations of pesticides in one of the wells; however, no pesticides were detected in samples collected during 2009. Detailed geologic cross sections were used to create a three-dimensional, hydrogeologic diagram of the well field southwest of Albany in order to examine the occurrence of subsurface features conducive to sinkhole formation. Monitored groundwater-level data were used to assess the possible relations between sinkhole formation, precipitation, and water levels in the Upper Floridan aquifer. Although the water levels in well 12L382 oscillated above and below the top of the aquifer on a regular basis between 2007 and 2009, sinkhole development did not appear to correlate directly with either well-field pumping or water levels in the Upper Floridan aquifer. Specifically, two sinkholes formed in each of the years 2003 and 2005 when water levels were almost 20 feet above the top of the aquifer during most of the year. Water-level and sinkhole-formation data continue to be collected to allow further study and analysis.

Georgia

Assessment of diel cycling in nutrients and trace elements in the Eagle River Basin, 2017–18

Diel cycles are known to occur in all types of waters, and increasing studies indicate routine water samples may not provide an accurate snapshot in concentrations of trace elements and nutrients. Diel behavior in neutral to alkaline pH ranges is independent of streamflow variability and concentration. Extensive historical U.S. Geological Survey (USGS) water-quality data have been collected in the Eagle River Basin during daylight hours, which is defined as the period of time between one-half hour prior to sunrise and one-half hour after sunset. However, no USGS data have been collected throughout the nighttime, defined as the time between one-half hour after sunset and one-half hour prior to sunrise, making the evaluation of diel cycles impossible. To assess the importance of diel cycling within the Eagle River Basin, the USGS, in cooperation with Eagle River Watershed Council, developed a study to assess the mechanisms, patterns, and magnitude of change during the diel cycle for selected constituents. Water-quality monitors at five USGS streamgage sites (09065500, Gore Creek at Upper Station, near Minturn, Colorado, 09063000, Eagle River at Red Cliff, Colorado, 09064600, Eagle River near Minturn, Colorado, 09066325, Gore Creek above Red Sandstone Creek at Vail, Colorado, and 394220106431500, Eagle River below Milk Creek near Wolcott, Colorado) were deployed in 2017 to evaluate the water-quality field parameters and to determine if water conditions were favorable for the diel cycling of nutrients and trace elements. Based on the evaluation of water-quality parameters, three of the five sites were sampled for nutrient and trace-element concentrations in 2018 to confirm the presence and magnitude of diel cycling. Historical data were also analyzed to assess the effect of time of day on measured nutrient and trace-element concentrations. An assessment of the effect of land use on diel cycling was also investigated. Measurable nutrients displayed a diel cycle at all three sites with the largest percentage change at the most downstream site (394220106431500), located on the Eagle River. More notable diel cycles at this site include filtered nitrate plus nitrite, which varied 179 percent, with concentrations from 0.24 to 0.67 milligrams per liter (mg/L) and filtered orthophosphate, which varied 71 percent, with concentrations from 0.07 to 0.12 mg/L. Filtered nitrate plus nitrite at site 09066325 varied 57 percent, ranging from 0.14 to 0.22 mg/L. Maximum concentrations occurred prior to noon, decreased through the afternoon (between noon and sunset), and increased during the night (between sunset and sunrise). That pattern is consistent with nutrient uptake in response to daytime (between sunrise and sunset) photosynthesis along with biologically driven denitrification and nitrification cycles. Nutrient concentrations at sites 09064600 and 09066325 were generally low and below laboratory reporting limits, which is the smallest measured concentration that nutrients could be measured by a given analytical method. Trace-element concentrations were detectable at all sites with the largest percentage change at the most downstream site (394220106431500) and exhibited diel concentration variation from 11.6 to 284 percent. Appreciable diel cycles included filtered copper (0.98–1.40 micrograms per liter [µg/L], 42.9 percent), filtered zinc (less than [<] 4.00–5.50 µg/L, greater than [>] 37.5 percent), total manganese (9.70–19.5 µg/L, 101 percent), and total arsenic (0.30–0.40 µg/L, 33.3 percent). The largest percentage change in concentration was filtered manganese (2.84–10.9 µg/L, 284 percent). Diel cycles at site 09064600 ranged from 9.1 to 64.5 percent across the trace elements measured. Dissolved trace elements with appreciable diel cycles during the sampling period include filtered cadmium (0.09–0.12 µg/L, 33.3 percent), filtered copper (0.99–1.40 µg/L, 41.4 percent), and total arsenic (0.20–0.30 µg/L, 50 percent). The largest percentage change was filtered zinc (38.3–63.0 µg/L, 65 percent). Trace-element concentrations at site 09066325 were below laboratory reporting limits for many parameters, and no diel cycle could be assessed for these parameters. However, total recoverable iron, filtered barium, filtered manganese, and filtered selenium exhibited changes in concentrations of <10.0–19.4 µg/L (>94 percent), 115–121 µg/L (5 percent), 1.44–1.72 µg/L (19.4 percent), and 0.25–0.28 µg/L (12 percent), respectively. At sites 09064600 and 394220106431500, maximum trace-element concentrations occurred during nighttime with some variation regarding the timing of the peak. The exceptions to this were filtered copper, total arsenic, and filtered selenium, which had maximum concentrations around noon or as the sun disappeared below the horizon. The timing of minimum concentrations occurred in the afternoon for many trace elements, with filtered copper, total arsenic, and filtered selenium having minimum concentrations in the morning or just prior to the appearance of the sun. Analysis of historical data also showed evidence of diel cycling. Historical samples collected from July through October were used to identify diel cycling in base-flow conditions. The resulting diel pattern in the median concentration for filtered manganese, filtered zinc at water-quality site 09064600, and filtered manganese and filtered nitrate plus nitrite at water-quality site 39422016431500 were consistent with the diel pattern in the September 2018 samples, and indicate time of day can bias sampling results even during daylight hours. Diel cycling in the Eagle River Basin appears to be driven primarily by instream, biological processes. However, land use, particularly human effects downstream from urban areas, mining, and agriculture, may affect these processes. At some locations, diel variations in nutrient and trace-element concentrations are small enough to be of low concern. At other locations, however, variations in concentrations up to 284 percent in the data collected for this study and 214 percent in base-flow historical data, indicate daytime-only sampling, particularly in late afternoon, can underestimate daily average nutrient and trace-element concentrations. When feasible, the potential of diel cycling warrants consideration in sample design to account for the potential of diel cycles, or at a minimum, be recognized as a component of the river dynamic and the potential consequences that diel cycles may have in data interpretation and river management decisions.

Colorado

Generalized water-level contours, September-October 2000 and March-April 2001, and long-term water-level changes, at the U.S. Air Force Plant 42 and vicinity, Palmdale, California

Historically, the U.S. Air Force Plant 42 has relied on ground water as the primary source of water owing, in large part, to the scarcity of surface water in the region. Groundwater withdrawal for municipal, industrial, and agricultural use has affected ground-water levels at U.S. Air Force Plant 42, and vicinity. A study to document changes in groundwater gradients and to present historical water-level data was completed by the U.S. Geological Survey in cooperation with the U.S. Air Force. This report presents historical water-level data, hydrographs, and generalized seasonal water-level and water-level contours for September?October 2000 and March?April 2001. The collection and interpretation of ground-water data helps local water districts, military bases, and private citizens gain a better understanding of the ground-water flow systems, and consequently water availability. During September?October 2000 and March?April 2001 the U.S. Geological Survey and other agencies made a total of 102 water-level measurements, 46 during September?October 2000 and 56 during March?April 2001. These data document recent conditions and, when compared with historical data, document changes in ground-water levels. Two water-level contour maps were drawn: the first depicts water-level conditions for September?October 2000 map and the second depicts water-level conditions for March?April 2001 map. In general, the water-level contour maps show water-level depressions formed as result of ground-water withdrawal. One hundred sixteen long-term hydrographs, using water-level data from 1915 through 2000, were constructed to show water-level trends in the area. The hydrographs indicate that water-level decline occurred throughout the study area, with the greatest declines south of U.S. Air Force Plant 42.

Scientific Investigations Report