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USGS2002

Estimation of shoreline position and change using airborne topographic lidar data

A method has been developed for estimating shoreline position from airborne scanning laser data. This technique allows rapid estimation of objective, GPS-based shoreline positions over hundreds of kilometers of coast, essential for the assessment of large-scale coastal behavior. Shoreline position, defined as the cross-shore position of a vertical shoreline datum, is found by fitting a function to cross-shore profiles of laser altimetry data located in a vertical range around the datum and then evaluating the function at the specified datum. Error bars on horizontal position are directly calculated as the 95% confidence interval on the mean value based on the Student's t distribution of the errors of the regression. The technique was tested using lidar data collected with NASA's Airborne Topographic Mapper (ATM) in September 1997 on the Outer Banks of North Carolina. Estimated lidar-based shoreline position was compared to shoreline position as measured by a ground-based GPS vehicle survey system. The two methods agreed closely with a root mean square difference of 2.9 m. The mean 95% confidence interval for shoreline position was ?? 1.4 m. The technique has been applied to a study of shoreline change on Assateague Island, Maryland/Virginia, where three ATM data sets were used to assess the statistics of large-scale shoreline change caused by a major 'northeaster' winter storm. The accuracy of both the lidar system and the technique described provides measures of shoreline position and change that are ideal for studying storm-scale variability over large spatial scales.

Maryland, North Carolina, Virginia↗

USGS2003

Morphological variation in glochidia shells of six species of Elliptio from Gulf of Mexico and Atlantic Coast drainages in the southeastern United States

The genus Elliptio, with 36 currently recognized species, is the largest genus in the family Unionidae in North America. The genus is represented by two species, Elliptio crassidens and E. dilatata, in the Interior Basin and 34 species in drainages of the eastern Gulf of Mexico and Atlantic Coast. The paucity and variation of conchological characters in the genus Elliptio makes it extremely difficult to define species and determine relationships. We examined glochidia from six species of Elliptio in an effort to determine if there are useful characteristics for species level identification and/or characters for identification of species groups. Elliptio species were selected to represent different morphological groups from four drainages in the southeastern United States. The glochidia from E. crassidens, E. dariensis, E. hopetonensis, E. icterina, E. shepardiana, and E. mcmichaeli were qualitatively compared, using scanning electron microscopy, with each other and with descriptions of these and other Elliptio glochidia described in the literature. Two groups were identified. The crassidens group, including E. crassidens, E. dariensis, and E. mcmichaeli, had subtriangular glochidia with a triangular styliform hook extending from the ventral margin of the valve and rough exterior valve sculpturing. Adults of this group had wrinkled or corrugated sculpturing on the posterior slope of the shell. The complanata group, including E. hopetonensis, E. icterina, and E. shepardiana, had subelliptical glochidia with a broad flange extending the entire ventral margin and loose-looped exterior valve sculpturing. Adults of this group lack sculpturing on the posterior slope of the shell. Differences in glochidial morphometrics were found, however, additional work is needed to determine if they are reliable for species level identification.

Proceedings of the Biological Society of Washingto↗

USGS2003

Evaluation of airborne topographic lidar for quantifying beach changes

A scanning airborne topographic lidar was evaluated for its ability to quantify beach topography and changes during the Sandy Duck experiment in 1997 along the North Carolina coast. Elevation estimates, acquired with NASA's Airborne Topographic Mapper (ATM), were compared to elevations measured with three types of ground-based measurements - 1) differential GPS equipped all-terrain vehicle (ATV) that surveyed a 3-km reach of beach from the shoreline to the dune, 2) GPS antenna mounted on a stadia rod used to intensely survey a different 100 m reach of beach, and 3) a second GPS-equipped ATV that surveyed a 70-km-long transect along the coast. Over 40,000 individual intercomparisons between ATM and ground surveys were calculated. RMS vertical differences associated with the ATM when compared to ground measurements ranged from 13 to 19 cm. Considering all of the intercomparisons together, RMS ??? 15 cm. This RMS error represents a total error for individual elevation estimates including uncertainties associated with random and mean errors. The latter was the largest source of error and was attributed to drift in differential GPS. The ??? 15 cm vertical accuracy of the ATM is adequate to resolve beach-change signals typical of the impact of storms. For example, ATM surveys of Assateague Island (spanning the border of MD and VA) prior to and immediately following a severe northeaster showed vertical beach changes in places greater than 2 m, much greater than expected errors associated with the ATM. A major asset of airborne lidar is the high spatial data density. Measurements of elevation are acquired every few m2 over regional scales of hundreds of kilometers. Hence, many scales of beach morphology and change can be resolved, from beach cusps tens of meters in wavelength to entire coastal cells comprising tens to hundreds of kilometers of coast. Topographic lidars similar to the ATM are becoming increasingly available from commercial vendors and should, in the future, be widely used in beach surveying.

Journal of Coastal Research↗

USGS2003

Sand volume and distribution on the paraglacial inner continental shelf of the northwestern Gulf of Maine

In an extensive program of side-scan sonar and seismic reflection profiling, bottom sampling and vibracoring, we have mapped the western Gulf of Maine between Canada and Massachusetts, from the shoreline to the 100 m isobath. The purpose of the program was, in part, to locate and evaluate sand resources on the inner shelf. Surficial sand occurs on only 7% of this formerly glaciated region, and most is located seaward of southern Maine's large beaches in Wells Embayment, Saco Bay, and off Cape Small. Sand deposits occur 1) at the lowstand position of sea level, between 50 and 60 m depth, 2) on parts of the inner shelf between 50 m and the shoreface, and 3) in the shoreface. A paleodelta of the region's largest river, the Kennebec, occurs off Cape Small. Elsewhere, the lowstand deposits are thinner (<3 m) and form a mantle over notches cut into glacial sediment. Inner shelf deposits are found as thin (<1 m) layers unconformably overlying glacial sediment. These are widespread in Wells and Cape Small, but are confined to rock valleys by high-relief bedrock in Saco Bay. In Wells Embayment, numerous moraines were eroded during lower stands of sea level, but still possess >5 m of relief on the inner shelf and contain large quantities of material. The shoreface contains the greatest concentration of sand in each of the regions. A wedge-shaped deposit of sand overlies estuarine muddy sands in each area and is inferred to have formed during a slowdown in the rate of sea-level rise between 7.5 and 9.5 ka. The volume of shoreface sand varies from less than 60 million cubic meters in Saco Bay to more than 300 million cubic meters off Cape Small, and is loosely correlated with the erosional state of adjacent beaches.

Journal of Coastal Research↗

USGS2003

Fault trends on the seaward slope of the Aleutian Trench: Implications for a laterally changing stress field tied to a westward increase in oblique convergence

Normal faults along the seaward trench slope (STS) commonly strike parallel to the trench in response to bending of the oceanic plate into the subduction zone. This is not the circumstance for the Aleutian Trench, where the direction of convergence gradually changes westward, from normal to transform motion. GLORIA side-scan sonar images document that the Aleutian STS is dominated by faults striking oblique to the trench, west of 179??E and east of 172??W. These images also show a pattern of east-west trending seafloor faults that are aligned parallel to the spreading fabric defined by magnetic anomalies. The stress-strain field along the STS is divided into two domains west and east, respectively, of 179??E. Over the western domain, STS faults and nodal planes of earthquakes are oriented oblique (9??-46??) to the trench axis and (69??-90??) to the magnetic fabric. West of 179??E, STS fault strikes change by 36?? from the E-W trend of STS where the trench-parallel slip gets larger than its orthogonal component of convergence. This rotation indicates that horizontal stresses along the western domain of the STS are deflected by the increasing obliquity in convergence. An analytical model supports the idea that strikes of STS faults result from a superposition of stresses associated with the dextral shear couple of the oblique convergence and stresses caused by plate bending. For the eastern domain, most nodal planes of earthquakes strike parallel to the outer rise, indicating bending as the prevailing mechanism causing normal faulting. East of 172??W, STS faults strike parallel to the magnetic fabric but oblique (10??-26??) to the axis of the trench. On the basis of a Coulomb failure criterion the trench-oblique strikes probably result from reactivation of crustal faults generated by spreading. Copyright 2003 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

USGS2004

Comparison of AMSR-E and SSM/I snow parameter retrievals over the Ob river basin

Passive microwave observations from the Advanced Microwave Scanning Radiometer - EOS (AMSR-E) and from the Special Sensor Microwave Imager (SSM/I) are used to analyse the evolution of the snow pack in the Ob river basin during the snow season of 2002-03. The Ob river is the biggest Russian river with respect to its watershed area (2 975 000 km2). The Ob originates in the Altai mountains and flows northward across the vast West Siberian lowland towards the Arctic Ocean. The majority of snow cover is contained in the lowlands rather than in mountainous regions and persists for six months or more. During the snow season, surface air temperatures are very cold. Therefore, the combination of cold dry snow and large areas of uniform topography is ideal for snowpack extent and water equivalent retrievals from passive microwave observations. The thermal gradient through the snow pack is estimated and used to model the growth of the snow grain size and to compute the evolution of the passive microwave derived snow depth over the region. A comparison between the AMSR-E and SSM/I estimates is performed and the differences between the snow parameters from the two satellite instruments are analysed.

Conference Paper↗

USGS2006

Impact of quaternary climate on seepage at Yucca Mountain, Nevada

Uranium-series ages, oxygen-isotopic compositions, and uranium contents were determined in outer growth layers of opal and calcitefrom 0.5- to 3-centimeter-thick mineral coatings hosted by lithophysal cavities in the unsaturated zone at Yucca Mountain, Nevada, the proposed site of a permanent repository for high-level radioactive waste. Micrometer-scale growth layering in the minerals was imaged using a cathodoluminescence detector on a scanning electron microscope. Determinations of the chemistry, ages, and delta oxygen-18 (??18O) values of the growth layers were conducted by electron microprobe analysis and secondary ion mass spectrometry techniques at spatial resolutions of 2 to about 20 micrometers (??m) and 25 to 40 ??m, respectively. Growth rates for the last 300 thousand years (k.y.) calculated from about 300 new high-resolution uranium-series ages range from approximately 0.5 to 1.5 ??m/k.y. for 1- to 3-centimeter-thick coatings, whereas coatings less than about 1-centimeter-thick have growth rates less than 0.5 ??m/k.y. At the depth of the proposed repository, correlations of uranium concentration and ??18O values with regional climate records indicate that unsaturated zone percolation and seepage water chemistries have responded to changes in climate during the last several hundred thousand years.

Conference Paper↗

USGS2006

Mineralogical anomalies and their influences on elemental geochemistry of the main workable coal beds from the Dafang Coalfield, Guizhou, China

Mineralogy and geochemistry of the No. 11 Coal bed were investigated by using inductively-coupled plasma mass spectrometry (ICP-MS), X-ray fluorescence (XRF), scanning electron microscopy equipped with energy-dispersive X-ray (SEM-EDX), sequential chemical extraction procedure (SCEP), and optical microscopy. The results show that the No. 11 Coal bed has very high contents of veined quartz (Vol. 11.4%) and veined ankerite (Vol. 10.2 %). The veined ankerite was generally coated by goethite and the veined quartz embraced chalcopyrite, sphalerite, and selenio-galena. In addition, a trace amount of kaolinite was filled in the veins. These seven minerals often occur in the same veins. The formation temperatures of the veined ankerite and quartz are 85??C and 180??C respectively, indicating their origins of iron-rich calcic and siliceous low-temperature hydrothermal fluids in different epigenetic periods. Studies have also found that the veined quartz probably formed earlier than the veined ankerite, and at least three distinct ankerite formation stages were observed by the ration of Ca/Sr and Fe/Mn of ankerite. The mineral formation from the early to late stage is in order of sulfide, quartz, kaolinite, ankerite, and goethite. The veined ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn, which are as high as 0.09%, 74.0 ??g/g, 33.6 ??g/g, 185 ??g/g, and 289 ??g/g in this coal seam, respectively. However, the veined quartz is the main carrier of Pd, Pt, and Ir, which are 1.57 ??g/g, 0.15 ??g/g, and 0.007 ??g/g in this coal seam, respectively. In addition, chalcopyrite, sphalerite, and selenio-galena of hydrothermal origin were determined in the veined quartz, and these three sulfide minerals are also important carriers of Cu, Zn and Pb in the No. 11 Coal bed.

Acta Geologica Sinica↗

USGS2006

A discovery of extremely-enriched boehmite from coal in the Junger Coalfield, the northeastern Ordos Basin

The authors found an extremely-enriched boehmite and its associated minerals for the first time in the super-thick No. 6 coal seam from the Junger Coalfield in the northeastern Ordos Basin by using technologies including the X-ray diffraction analysis (XRD), scanning electron microscope equipped with an energy dispersive X-ray spectrometer, and optical microscope. The content of boehmite is as high as 13.1%, and the associated minerals are goyazite, zircon, rutile, goethite, galena, clausthalite, and selenio-galena. The heavy minerals assemblage is similar to that in the bauxite of the Benxi Formation from North China. The high boehmite in coal is mainly from weathering crust bauxite of the Benxi Formation from the northeastern coal-accumulation basin. The gibbsite colloidstone solution was removed from bauxite to the peat mire, and boehmite was formed via compaction and dehydration of gibbsite colloidstone solution in the period of peat accumulation and early period of diagenesis.

Acta Geologica Sinica↗

USGS2011

What's new in well logging and formation evaluation

A number of significant new developments is emerging in well logging and formation evaluation. Some of the new developments include an ultrasonic wireline imager, an electromagnetic free-point indicator, wired and fiber-optic coiled tubing systems, and extreme-temperature logging-while-drilling (LWD) tools. The continued consolidation of logging and petrophysical service providers in 2010 means that these innovations are increasingly being provided by a few large companies. Weatherford International has launched a slimhole cross-dipole tool as part of the company's line of compact logging tools. The 26-ft-long Compact Cross-Dipole Sonic (CXD) tool can be run as part of a quad-combo compact logging string. Halliburton has introduced a version of its circumferential acoustic scanning tool (CAST) that runs on monoconductor cable (CAST-M) to provide high-resolution images in open hole and in cased hole for casing and cement evaluation.

World Oil↗

USGS2007

WSR-88D observations of volcanic ash

Conclusions that may impact operations are summarized below: ??? Current VCPs may not be optimal for the scharacterization of volcanic events. Therefore, the development of a new VCP that combines the enhanced low level elevation density and increased temporal resolution of VCP 12 with the enhanced sensitivity of VCP 31. ??? Given currently available scan strategies, this preliminary investigation would suggest that it is advisable to use VCP 12 during the initial explosive phase of an eruptive event. Once the maximum reflectivity has dropped below 30 dBZ, VCP 31 should be used. ??? This study clearly indicates that WSR-88D Level II data offers many advantages over Level III data currently available in Alaska. The ability to access this data would open up greater opportunities for research. Given the proximity of WSR-88D platforms to active volcanoes in Alaska, as well as in the western Lower 48 states and Hawaii, radar data will likely play a major operational role when volcanic eruptions again pose a threat to life and property. The utilization of this tool to its maximum capability is vital.

Conference Paper↗

USGS1974

Abstracting and indexing guide

These instructions have been prepared for those who abstract and index scientific and technical documents for the Water Resources Scientific Information Center (WRSIC). With the recent publication growth in all fields, information centers have undertaken the task of keeping the various scientific communities aware of current and past developments. An abstract with carefully selected index terms offers the user of WRSIC services a more rapid means for deciding whether a document is pertinent to his needs and professional interests, thus saving him the time necessary to scan the complete work. These means also provide WRSIC with a document representation or surrogate which is more easily stored and manipulated to produce various services. Authors are asked to accept the responsibility for preparing abstracts of their own papers to facilitate quick evaluation, announcement, and dissemination to the scientific community.

Monograph↗

USGS2012

Foraminiferal repopulation of the late Eocene Chesapeake Bay impact crater

The Chickahominy Formation is the initial postimpact deposit in the 85km-diameter Chesapeake Bay impact crater, which is centered under the town of Cape Charles, Virginia, USA. The formation comprises dominantly microfossil-rich, silty, marine clay, which accumulated during the final ~1.6myr of late Eocene time. At cored sites, the Chickahominy Formation is 16.8-93.7m thick, and fills a series of small troughs and subbasins, which subdivide the larger Chickahominy basin. Nine coreholes drilled through the Chickahominy Formation (five inside the crater, two near the crater margin, and two ~3km outside the crater) record the stratigraphic and paleoecologic succession of 301 indigenous species of benthic foraminifera, as well as associated planktonic foraminifera and bolboformids. Two hundred twenty of these benthic species are described herein, and illustrated with scanning electron photomicrographs. Absence of key planktonic foraminiferal and Bolboforma species in early Chickahominy sediments indicates that detrimental effects of the impact also disturbed the upper oceanic water column for at least 80-100kyr postimpact. After an average of ~73kyr of stressed, rapidly fluctuating paleoenvironments, which were destabilized by after-effects of the impact, most of the cored Chickahominy subbasins maintained stable, nutrient-rich, low-oxygen bottom waters and interstitial microhabitats for the remaining ~1.3myr of late Eocene time.

Maryl;Virginia↗

USGS2012

Fragilariopsis diatom evolution in Pliocene and Pleistocene Antarctic shelf sediments

The late Pliocene – early Pleistocene sediment record in the AND-1B core from the McMurdo Sound, Ross Sea, Antarctica, displays a rich diversity and high abundance of diatoms, including several new morphologies within the genus Fragilariopsis. These new morphologies exhibit similarities to the extinct late Miocene/early Pliocene species Fragilariopsis aurica Gersonde and Fragilariopsis praecurta Gersonde, as well as to the modern sea ice-associated species Fragilariopsis ritscheri Hustedt and Fragilariopsis obliquecostata van Heurck. From the diverse morphologies present, we use light microscopy and scanning electron microscopy to identify and describe the characteristics of three new taxa, Fragilariopsis laqueata Riesselman, Fragilariopsis bohatyi Sjunneskog et Riesselman, and Fragilariopsis robusta Sjunneskog, which are common in the diatom-bearing intervals from ~3.2 to 1.95 Ma. Comparisons with extant and extinct species are made to assess possible environmental affinities, evolutionary relationships, and potential for future biostratigraphic utility. This complex of newmorphologies diversified as conditions cooled during the Pliocene, then went into decline as heavy sea ice conditions of the Pleistocene were established. Only the lineage of F. robusta appears to continue into the late Pleistocene, where it is interpreted to have evolved into F. obliquecostata.

Micropaleontology↗

USGS1989

Mineralogic and textural relations in deeply buried rocks of the Simpson Group (Middle Ordovician)--implications in diagenesis and petroleum geology

The mineral composition and petrography of sandstones, shales, carbonates, and intermediate lithologies were determined on 112 core samples of the Middle Ordovician Simpson Group in the Sunray DX Parker No. 1 Mazur well, Grady County, Oklahoma. Core was recovered from present depths of about 15,900-17,200 ft and included all or parts of the Bromide, Tulip Creek, McLish, Oil Creek, and Joins Formations. The bulk-rock mineral composition of Simpson Group rocks is diverse. The mean weighted composition of 50 sandstone samples is 66% quartz, 14% clay, and 18% carbonate, as determined by X-ray powder diffraction (XRD). Some sandstones from the Oil Creek and Tulip Creek Formations contain as much as 96% quartz. These quartz-rich sandstones were cemented early by silica. Feldspar averages 2%; some sandstones from the McLish Formation contain as much as 15% feldspar. Potassium feldspar is commonly more abundant than plagioclase; potassium feldspar overgrowths are found in some of the sandstones. Most of the shales are clay-rich and quartz-poor, averaging about 85% clay minerals, 7% quartz, and 3% feldspar, by weight, as determined by XRD. Carbonate, fluorapatite, and pyrite are present in variable amounts. Such high clay/quartz ratios are not characteristic of shales and suggest that silica has been expelled by diagenetic processes during burial. The main clay mineral in the Simpson Group at these depths is illite, although iron-rich chlorite is locally concentrated in sandstones. Illite typically makes up >90 wt. % of the clay minerals in sandstones and >95 wt. % of those in shale and carbonate. Total clay content, determined from XRD, correlates closely with total gamma-ray intensity from geophysical logs, because illite is the primary potassium-bearing phase in these deeply buried rocks. Therefore, the gamma-ray log is a good indicator of "shaliness" in potential Simpson reservoirs at similar depths. Much of the carbonate was introduced into the sandstones during burial as calcite, dolomite, or ankerite cement. Early iron-free calcite is commonly replaced by iron-bearing calcite, dolomite, or ankerite. Sandstones and carbonate rocks also contain rhombic dolomite. Many of the dolomite rhombs contain overgrowths of ferroan dolomite or ankerite, as evidenced by staining. Ankerite cementation is later and less selective than earlier dolomite and commonly replaces earlier carbonate or silica cements. Dolomite commonly replaces detrital clay and calcite. Spatial and textural relations suggest that the conversion of smectite to illite contributed, in part, to the formation of dolomite and ankerite cements. Scanning electron miscroscopy reveals that much of the diagenetic illite occurs as tabular fibers in pores or as pseudomorphic intergrowths after smectite. Most chlorite in sandstones is authigenic and occurs as a pore-lining cement or as a pseudomorphic replacement after kaolinite. Secondary porosity, formed mainly from the dissolution of intergranular carbonate cements, is best developed in sandstones from the Oil Creek and Tulip Creek Formations.

Oklahoma↗

USGS2013

Unpaved road dust management, a successful practitioner’s handbook

This handbook provides broad programmatic aspects of unpaved road management. It is based on observations made during a national scan tour and provides useful and insightful excerpts of realworld examples and includes practical how-to instructions for determining what type of treatment may be needed for different situations. It ultimately strives to encourage road managers to think broadly about the process of unpaved road management rather than just focusing on a specific type of chemical treatment.

Report↗

USGS2002

U.S. Geological Survey spatial data access

The U.S. Geological Survey (USGS) has done a progress review on improving access to its spatial data holdings over the Web. The USGS EROS Data Center has created three major Web-based interfaces to deliver spatial data to the general public; they are Earth Explorer, the Seamless Data Distribution System (SDDS), and the USGS Web Mapping Portal. Lessons were learned in developing these systems, and various resources were needed for their implementation. The USGS serves as a fact-finding agency in the U.S. Government that collects, monitors, analyzes, and provides scientific information about natural resource conditions and issues. To carry out its mission, the USGS has created and managed spatial data since its inception. Originally relying on paper maps, the USGS now uses advanced technology to produce digital representations of the Earth’s features. The spatial products of the USGS include both source and derivative data. Derivative datasets include Digital Orthophoto Quadrangles (DOQ), Digital Elevation Models, Digital Line Graphs, land-cover Digital Raster Graphics, and the seamless National Elevation Dataset. These products, created with automated processes, use aerial photographs, satellite images, or other cartographic information such as scanned paper maps as source data. With Earth Explorer, users can search multiple inventories through metadata queries and can browse satellite and DOQ imagery. They can place orders and make payment through secure credit card transactions. Some USGS spatial data can be accessed with SDDS. The SDDS uses an ArcIMS map service interface to identify the user’s areas of interest and determine the output format; it allows the user to either download the actual spatial data directly for small areas or place orders for larger areas to be delivered on media. The USGS Web Mapping Portal provides views of national and international datasets through an ArcIMS map service interface. In addition, the map portal posts news about new map services available from the USGS, many simultaneously published on the Environmental Systems Research Institute Geography Network. These three information systems use new software tools and expanded hardware to meet the requirements of the users. The systems are designed to handle the required workload and are relatively easy to enhance and maintain. The software tools give users a high level of functionality and help the system conform to industry standards. The hardware and software architecture is designed to handle the large amounts of spatial data and Internet traffic required by the information systems. Last, customer support was needed to answer questions, monitor e-mail, and report customer problems.

Journal of Geospatial Engineering↗

USGS1996

Colloidal-facilitated transport of inorganic contaminants in ground water: part 1, sampling considerations

Investigations at Pinal Creek, Arizona, evaluated routine sampling procedures for determination of aqueous inorganic geochemistry and assessment of contaminant transport by colloidal mobility. Sampling variables included pump type and flow rate, collection under air or nitrogen, and filter pore diameter. During well purging and sample collection, suspended particle size and number as well as dissolved oxygen, temperature, specific conductance, pH, and redox potential were monitored. Laboratory analyses of both unfiltered samples and the filtrates were performed by inductively coupled argon plasma, atomic absorption with graphite furnace, and ion chromatography. Scanning electron microscopy with Energy Dispersive X-ray was also used for analysis of filter particulates. Suspended particle counts consistently required approximately twice as long as the other field-monitored indicators to stabilize. High-flow-rate pumps entrained normally nonmobile particles. Difference in elemental concentrations using different filter-pore sizes were generally not large with only two wells having differences greater than 10 percent in most wells. Similar differences (>10%) were observed for some wells when samples were collected under nitrogen rather than in air. Fe 2+ /Fe 3+ ratios for air-collected samples were smaller than for samples collected under a nitrogen atmosphere, reflecting sampling-induced oxidation.

Arizona↗