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At least 937 records · Page 52Linked to original sources

Coal in sub-Saharan-African countries undergoing desertification

Coal has been reported in 11 of the 16 sub-Saharan countries discussed in this appraisal: Mauritania, Senegal, Mali, Niger, Benin, Nigeria, Cameroon, Central African Republic, Sudan, Ethiopia, and Somalia. No coal occurrences have been reported in Gambia, Togo, Burkina, Chad, and Djibouti but coal may be present within these countries because neighboring countries do contain coal-bearing rocks. Most of these countries are undergoing desertification or will in the near future. Wood, directly or in the form of charcoal, constitutes two-thirds of the fuel used in Africa. Destruction of forest and shrub lands for fuel is occurring at an increasing rate because of desertification and increasing energy demands. The decline in biological productivity, coupled with concentration of population in areas where water is available and crops may be grown, leads to increasing shortages of wood for fuel. Part of the present and future energy needs of the sub-Saharan region could be met by use of indigenous coal and peat. Nine sedimentary basins, completely or partially within the sub-Saharan region, have the potential of either coal and/or peat deposits of economic value: 1- Senegal Basin, 2- Taoudeni Basin and Gao Trough, 3- Niger Basin, 4- Chad Basin, 5- Chari Basin, 6- Benue Trough (Depression), 7- Sudan Trough, 8- Plateau and Rift Belt, and 9- Somali Basin. Niger and Nigeria are the only countries in sub-Saharan Africa in which coal is presently being mined as a fuel source for powerplants and domestic use. Peat occurs in the deltas, lower river, and interdunal basin areas of Senegal, Mauritania, and Sudan. Peat can be used as an alternate fuel source and is currently being tested as a soil amendment in the agricultural sector.

Journal of African Earth Sciences↗

Eolian sediments

The origin and nature of eolian (wind-blown) sediments are reviewed, with an emphasis on the occurrence of these features in the Quaternary. Eolian sediments consist of windblown sand, loess, and long-range-transported (LRT) dust, in order of decreasing particle size. Eolian sand forms some of the most dramatic landscapes in the world, particularly when these sediments are deposited as dunes in sand seas. The largest eolian sand seas are found in subtropical deserts and in mid-latitude basins that are arid because of rainshadow effects. Dunes can be helpful in interpreting past climates, both for understanding past moisture balance and paleowinds (past wind directions). Loess is windblown silt that can be recognized in the field and mapped as a geologic body. It can be many tens of meters thick, but usually decreases systematically with distance from its source or sources. Much loess is glaciogenic, the result of glacial grinding of bedrock into “rock flour” that is easily entrained by the wind, but some loess owes its origins to nonglacial processes or is simply inherited from silt-rich rocks. The geologic record shows that both glacial loess and non-glacial loess accumulated mostly during glacial periods, suggesting that particular environmental conditions are favorable for loess accumulation. These conditions include increased source sediments, a dry, windy environment with minimal vegetation cover, and a decreased intensity of the hydrological cycle. The same conditions apparently enhance the production of LRT dust, which consists of particles generally less than 10 μm. At present, most dust sources are in the same regions where the largest eolian sand seas occur, although sandy sediments are not the only sources of finer-grained dust. LRT dust can be transported across oceans, from continent to continent, and may play important roles in the overall planetary radiation balance, as fertilizer to the world's primary producers in the oceans, and as a soil parent material. Geologic records of LRT dust transport can be found in deep-sea sediments, ice caps, lakes, distal loess deposits, and soils. These records indicate that, like loess, the flux of dust was greater during glacial periods. Although eolian sand, loess, and LRT dust all have rich geologic records in the Quaternary, there is an increasing recognition of the importance of all these features in the longer, pre-Quaternary geologic record.

Book chapter↗

Petroleum system analysis of the Hunton Group in West Edmond field, Oklahoma

West Edmond field, located in central Oklahoma, is one of the largest oil accumulations in the Silurian–Devonian Hunton Group in this part of the Anadarko Basin. Production from all stratigraphic units in the field exceeds 170 million barrels of oil (MMBO) and 400 billion cubic feet of gas (BCFG), of which approximately 60 MMBO and 100 BCFG have been produced from the Hunton Group. Oil and gas are stratigraphically trapped to the east against the Nemaha uplift, to the north by a regional wedge-out of Hunton strata, and by intraformational diagenetic traps. Hunton Group reservoirs are the Bois d'Arc and Frisco Limestones, with lesser production from the Chimneyhill subgroup, Haragan Shale, and Henryhouse Formation. Hunton Group cores from three wells that were examined petrographically indicate that complex diagenetic relations influence permeability and reservoir quality. Greatest porosity and permeability are associated with secondary dissolution in packstones and grainstones, forming hydrocarbon reservoirs. The overlying Devonian–Mississippian Woodford Shale is the major petroleum source rock for the Hunton Group in the field, based on one-dimensional and four-dimensional petroleum system models that were calibrated to well temperature and Woodford Shale vitrinite reflectance data. The source rock is marginally mature to mature for oil generation in the area of the West Edmond field, and migration of Woodford oil and gas from deeper parts of the basin also contributed to hydrocarbon accumulation.

Oklahoma↗

Minerals of the cassiterite-bearing veins at Irish Creek, Virginia, and their paragenetic relations

Major rock types of the Irish Creek district are gneisses and schists, intruded by granodiorite. All these rocks are believed to be Precambrian. The ore deposits are fissure veins consisting largely of quartz veins bordered by greisen, and enriched by recurrent deposition. From field and microscopic evidence six stages of mineral formation have been deduced: 1. Crystallization of the granodiorite with the formation of hypersthene, augite, hornblende, andesine, orthoclase, microcline, and quartz; and accessory apatite, rutile, ilmenite, titanomagnetite, and zircon. 2. Metamorphism of the granodiorite and gneiss with formation of uralitic actinolite, epidote, and sphene. 3. A period of fracturing and formation of quartz veins. 4. Greisenization of the host rock producing first: coarse muscovite, brown biotite, cassiterite, beryl, wolframite, and quartz; then producing a second group of minerals-fluorite, green biotite, chlorite, phenakite, siderite, ankerite, parisite, sphalerite, sulfides, including aikinite and galeno-bismutite, leucoxene, fine muscovite, and quartz. 5. Formation of late vein minerals, clinozoisite, calcite, nontronite, and montmorillonite. 6. Formation of surficial alteration products, kaolinite, vermiculite, hematite, limonite, and scorodite. The italicized mineral names indicate the minerals heretofore unreported from Irish Creek; parisite, aikinite, and galenobismutite are new minerals for Virginia. Included in the detailed descriptions of all the minerals is a chemical analysis of beryl.

Virginia↗

Geologic Map of the Edwards Aquifer In Northern Medina and Northeastern Uvalde Counties, South-central Texas

The southern segment of the Edwards aquifer in south-central Texas is one of the most productive subsurface reservoirs of potable water in the world, providing water of excellent quality to more than a million people in the San Antonio region, where the Environmental Protection Agency (EPA) has declared it to be a sole-source aquifer (van der Leeden and others, 1990). Depending on the depositional province within which the associated carbonate rocks originated (Maclay and Small, 1984), the Edwards aquifer is composed of several geologic formations (primarily limestone and dolostone) of Early Cretaceous age. Most water pumped from the Edwards aquifer comes form the Person and Kainer Formations, which were deposited over the San Marcos Platform. The principal source of ground water in study area is the Devils River Formation, which was deposited in the Devils River trend. The Devils River Formation provides large quantities of irrigation water to fertile bottomland areas of Medina and Uvalde Counties, where the success of farming and ranching activities has long depended upon water from the Edwards aquifer. The study area includes all of the Edwards aquifer recharge zone between the Sabinal River (on the west) and the Medina River (on the east) plus an updip fringe of the confined zone in east-central Uvalde and central Medina Counties. Over about ninety percent of the study area--within the Devils River trend--the Edwards aquifer is composed of the Georgetown Formation plus the underlying Devils River Formation. Over the remaining area--over the southwestern margin of the San Marcos platform--the Edwards aquifer consists of the Georgetown Formation plus the underlying Edwards Group (Rose, 1972), which comprises the Kainer and Person Formations.

Open-File Report↗

Stockton and Stanley Hill clay deposits, Kootenai County, Idaho

The Stockton and Stanley Hill deposits, Kootenai County, Idaho, are about 25 to 30 miles east of Spokane, Wash. During World War II, the areas were studied by the U. S. Geological Survey in cooperation with the U. S. Bureau of Mines. The Bureau of Mines hand-augered 162 holes and made chemical analyses of the samples for available alumina, and available ferric oxide, and measured the ignition loss. The deposit contains two types of clay: granite residual clay derived from the weathering of Cretaceous granite gneiss in place; and transported clays of the Latah formation derived from the weathered. debris of the granodiorite and older rocks. The Stockton deposits average more than 20 percent available alumina and less than 10 percent available ferric oxide. The deposits, therefore, could serve as a small source of low-grade high alumina clay. Clays containing more than 15 percent available alumina and less than 5 percent available ferric oxide would be suitable for many ceramic products and some may meet the requirements for high-heat or super-heat duties. Therefore, the Stockton and Stanley Hill clay deposits contain ceramic-grade clays.

Idaho↗

Influences of environmental settings on aquatic ecosystems in the Apalachicola-Chattahoochee-Flint River basin

The watershed boundary of the Apalachicola-Chattahoochee-Flint (ACF) River basin defines an aquatic ecosystem whose water quality is the result of complex interactions of natural and human influences on land and water resources. Topics relating to the basin's environmental setting-its physical, biological, and cultural characteristics-are summarized to provide an understanding of factors that influence water quality and the health of aquatic ecosystems. The ACF River basin lies partly in southwestern Georgia, southeastern Alabama, and northwestern Florida and covers 19,800 square miles in the Blue Ridge, the Piedmont, and the Coastal Plain Provinces. The basin includes the drainages of the Chattahoochee River and the Flint River, which meet to form the Apalachicola River. The Apalachicola River flows into the Gulf of Mexico at Apalachicola Bay. Basin hydrology and water quality are influenced by 16 mainstem reservoirs, 13 of which are on the Chattahoochee River. Ground water in the basin is contained in six aquifers-the surficial aquifer system, the Floridan aquifer system, the Claiborne aquifer, the Clayton aquifer, the Providence aquifer, and the crystalline-rock aquifer. Physiography, climate, and hydrology of the ACF River basin provide natural conditions that support a rich and abundant diversity of plants and animals. Although most of the ACF River basin has been altered by human activities, the basin's environment is noteworthy for its remaining biological diversity and the role it plays in sustaining biological productivity in Apalachicola Bay. The Bay produces 90 percent of Florida's and 13 percent of the Nation's oyster harvest; and functions as a nursery for penaeid shrimp, blue crabs, and a variety of fin fish. The diversity of the basin's aquatic fauna is noteworthy because the basin is home to (1) the largest number of fish species among Gulf Coast drainages east of the Mississippi River, (2) the largest assemblage of freshwater fish in Florida, (3) the largest number of mollusc species among western Florida drainages, and (4) the highest species density of amphibians and reptiles on the continent north of Mexico. Population of the ACF River basin in 1990 was estimated at 2.6 million. Nearly 90 percent of the total population lived in Georgia, and nearly 60 percent lived in the Metropolitan Atlanta area. The 1990 basin population is projected to increase by 15 percent to 3.0 million by the year 2000, and by 30 percent to 3.4 million by 2010. The largest increases in populations are projected for the Metropolitan Atlanta area. In 1972-76, approximately 59 percent of the basin was covered by forest, 29 percent was agricultural, 5 percent was wetland, 4 percent was urban, and 3 percent was water or barren land. Most of the original land cover of the basin has been transformed by human activity. Timber is the basin's largest cash crop and most forests consist of second-growth stands or large acreages of planted pine. The dominant agricultural land use in the Piedmont Province is pasture and confined feeding for dairy, livestock, and poultry production. Row-crop agriculture, orchards, and silviculture are most common in the Coastal Plain Province. The top five crops in order from most to least acres harvested in 1990 were peanuts, corn, soybeans, wheat, and cotton. The water in the basin is used for public and industrial supply, irrigation, power generation, navigation, and recreation. Although most public-supply withdrawals in the Blue Ridge and Piedmont Provinces are from surface-water sources, with the exception of counties near or immediately below the Fall Line, all publicly supplied water in the Coastal Plain is withdrawn from ground-water sources. Ground water supplied 18 percent of the basin's population served by public supply. Total water withdrawn in the ACF River basin in 1990 was 2,098 million gallons per day (Mgal/d), of which Georgia withdrew 82 percent and Florida and Alabama each withdrew 9 percent. Power generation is the single largest water use. Sixteen of the basin's 22 power generating plants are located along the mainstem of the Chattahoochee River. The U.S. Army Corps of Engineers maintains a navigation channel from the mouth of the Apalachicola River to Columbus, Ga., on the Chattahoochee River and to Bainbridge, Ga., on the Flint River. Water quality in the basin is influenced by the operation of 137 municipal wastewater-treatment facilities. In 1990, 354 Mgal/d of municipal wastewater was discharged within the ACF River basin. Eighty-eight percent of the wastewater was discharged into the Chattahoochee River basin, 10.6 percent into the Flint River basin, and 1.4 percent into the Apalachicola River basin. Two-thirds of the 938 stream miles in the Georgia portion of the ACF River basin having water quality that does not meet or only partially meets the designated-use criteria in the Chattahoochee River basin. The Chattahoochee River is the most heavily-used water resource both in the ACF River basin and in Georgia. Urban runoff or unknown nonpoint sources are cited as the causes of water-quality regulations in 72 percent of violations. The remaining causes primarily are combined sewer overflows in the Atlanta area, and discharges from municipal or industrial treatment facilities with inadequate treatment capabilities or operational deficiencies.

Alabama, Florida, Georgia↗

Geochemistry of the 1989-1990 eruption of redoubt volcano: Part I. Whole-rock major- and trace-element chemistry

The 1989-1990 eruption of Redoubt Volcano produced medium-K calc-alkaline andesite and dacite of limited compositional range (58.2-63.4% SiO2) and entrained quenched andesitic inclusions (55% SiO2) which bear chemical similarities to the rest of the ejecta. The earliest (December 15) magmas are pumiceous, often compositionally banded, and the majority is relatively mafic (< 59% SiO2). The most silicic magmas of the eruption are the late December to early January domes (up to 63.4% SiO2). Subsequent magmas formed domes and rare pumices which converge on 60% SiO2. Chemical variations among ejecta comprise tight, linear, two-component arrays for all elements for which the analytical uncertainty is much less than the compositional range. The two-component arrays are interpreted as mixing arrays between unrelated magmas because several of the arrays are at steep angles to the normal liquid line of descent. Additionally, the felsic endmember cannot be easily related to the mafic endmember by normal high-temperature igneous processes (e.g., the silicic endmember has higher Zr yet lower Hf than the mafic endmember). Also relative enrichments of highly incompatible elements are dramatically different across the arrays. The mixing event must have preceded eruption by a significant, yet unspecified amount of time because groundmass glass compositions are homogeneous for all post-December samples (Swanson et al., 1994-this volume), in spite of the whole-rock chemical diversity. This implies time for additional crystallization after the mixing event. Swanson et al. (1994-this volume) discuss evidence for a potentially different mixing event recorded only in December 15 magmas. Cognate cumulate xenoliths composed of pl+cpx+opx+hb+mt+melt were recovered from January and April deposits. These blocks differ from local batholithic country rock in their low concentrations of incompatible elements (e.g., Rb < 5 ppm vs 20-90 ppm, Ba < 150 ppm vs 300-2000 ppm) and low SiO2 (< 50 wt.% vs > 60 wt.%). They have Mg, Cr, Ni, Sc, and V contents higher than the andesites, but lower than Redoubt basalts and basaltic andesites. Thus, they may be crystallization products of andesites, but do not represent the cumulate residue of basalt fractionation. The xenoliths were probably derived from a shallow or intermediate crustal chamber. ?? 1994.

Journal of Volcanology and Geothermal Research↗

Geochemical and petrological diversity of mafic magmas from Mount St. Helens

Quaternary eruptive products in the Cascade arc include a variety of different basalt types. At Mount St. Helens (MSH), the most active volcano in the Cascades throughout the last 35 ka, three different mafic endmembers erupted at the end of the Castle Creek period (1900–1700 years B.P.): (1) high-field strength element (HFSE)-rich basalt enriched in K, Ti, P, and incompatible trace elements; (2) low-K olivine tholeiite (LKOT) with lower amounts of incompatible trace elements; and (3) calc-alkaline (arc-type) basaltic andesite with a typical subduction signature, i.e., enrichment in fluid-mobile large ion lithophile elements (LILE) relative to immobile high-field strength elements (HFSE). Each type has compositions projecting backwards to more primitive endmembers in the Cascades. Single units encompassing basaltic-to-basaltic andesitic compositions with intermediate trace-element abundances form two almost continuous trends towards basaltic andesite. These trends are interpreted to result from assimilation of pre-existing, more evolved, calc-alkaline material (and in one case mixing of different mafic magma types) during migration of the magmas through the crust. Most of the erupted basalts are porphyritic (10–30%) with an assemblage dominated by olivine and plagioclase and show disequilibrium textures preventing detailed reconstruction of mantle melting processes. Although typical hydrous arc basalt produced by flux melting in the mantle is absent in the eruptive products of MSH, arc-type basaltic andesite suggests its presence at depth. LKOT magmas are interpreted as decompression melts from the upper mantle, whereas HFSE-rich basalts are likely derived from the water-poor periphery of the main flux melting regime, potentially tapping a trace-element-enriched source. Primitive spinel compositions and whole-rock trace-element variations indicate at least two distinct, relatively fertile lherzolite sources for these two basalt types. Weak crustal zones associated with an old fracture system beneath MSH likely provide conduits for fast and isolated ascent of distinct batches of magma, bypassing the lower crustal mush zone. The eruption of the basalts through the upper crustal magma system and main edifice is consistent with an offset plumbing system suggested by geophysical data.

Washington↗

Analysis of stress-induced oval fractures in a borehole at Deep Sea Drilling Project Site 504, eastern equatorial Pacific

Deep Sea Drilling Project (DSDP) Hole 504B is located in the eastern equatorial Pacific Ocean and extends to a total depth of 2111 m beneath the seafloor (mbsf). Several acoustic televiewer logs have been obtained in this well during successive stages of drilling, and the resulting digital images have revealed numerous oval-shaped fractures seemingly etched into the borehole wall. A theoretical examination of these stress-induced features identifies a unique and ephemeral set of stress distributions and magnitudes that are necessary for their production. Consequently, the ovals provide a basis for quantifying the magnitudes and orientations of the maximum and minimum horizontal principal stresses, S H and S h at this site. Vertical, truncated breakouts and horizontal tensile fractures define the spatial boundaries of the ovals. Explicit criteria for their occurrence are combined with estimates for various physical properties of the rock to yield a range of possible values for the horizontal principal stresses. The conspicuous oval geometry is completed by a curved fracture that joins the vertical and horizontal components. Its degree of curvature is delineated by the modified Griffith failure criterion and is directly related to the principal stress difference ( S H − S h ). Matching a series of type curves corresponding to specific values for ( S H − S h ) with the actual undistorted well bore images allows the magnitude of the stress difference to be further constrained. With a value for ( S H − S h ) of 45 ± 5 MPa the individual magnitudes of S H and S h are determined more precisely. Final estimates for the horizontal principal stresses in DSDP Hole 504B at a depth of 1200 mbsf are 141 MPa ≤ S H ≤ 149 MPa and 91 MPa ≤ S h ≤ 109 MPa. Stress magnitudes derived from this approach rely heavily upon the values of a variety of physical properties, and complementary laboratory measurements performed on relevant rock samples provide critical information. Uncertainties in estimating these properties translate into less precise predictions of principal stresses.

Journal of Geophysical Research B: Solid Earth↗

Assessment of geothermal resources of the United States, 1975

This assessment of geothermal resources of the United States consists of two major parts: (1) estimates of total heat in the ground to a depth of 10 km and (2) estimates of the part of this total heat that is recoverable with present technology, regardless of price. No attempt has been made to consider most aspects of the legal, environmental, and institutional limitations in exploiting these resouces. In general, the average heat content of rocks is considerably higher in the Western United States than in the East. This also helps to explain why the most favorable hydrothermal convection systems and the hot young igneous systems occur in the West. Resources of the most attractive identified convection systems (excluding national parks) with predicted reservoir temperatures above 150 deg C have an estimated electrical production potential of about 8,000 megawatt century, or about 26,000 megawatt for 30 years. Assumptions in this conversion are: (1) one-half of the volume of the heat reservoirs is porous and permeable, (2) one-half of the heat of the porous, permeable parts is recoverable in fluids at the wellheads, and (3) the conversion efficiency of heat in wellhead fluids to electricity ranges from about 8 to 20 percent , depending on temperature and kind of fluid (hot water or steam). The estimated overall efficiency of conversion of heat in the ground to electrical energy generally ranges from less than 2 to 5 percent, depending on type of system and reservoir temperature. (See also W77-07477)

Circular↗

Mineral deposits and occurrences in the McCarthy Quadrangle, Alaska

The McCarthy quadrangle contains numerous and diverse mineral deposits in various geologic settings. Copper is the dominant mineral commodity, both historically and in terms of potential future production. Gold and silver are the only other metals that have been produced. The metalliferous deposits are concentrated in a northwest-trending belt along the southern flank of the Wrangell Mountains, and, to a lesser extent, in a similar belt along the northeast flank of the range. Both belts have upper Paleozoic (Skolai Group) basements, abundant Mesozoic rocks, and some Tertiary intrusive rocks. They are marked by numerous faults, mainly northwest-striking. Mineral deposits are uncommon elsewhere in the quadrangle, especially in large tracks underlain by Wrangell Lava and in smaller areas underlain by the Kaskawulsh Group of Kindle (1953). Both the Wrangell Lava and the Kaskawulsh underlie rugged mountainous regions with extensive snow and ice cover, and could conceivably contain undetected concealed deposits. The metallic, nonmetallic, and energy resources of the quadrangle are described sequentially. Copper, gold, and silver, because of their importance, are described early in the section on metal commodities; descriptions of the other metals follows in alphabetic sequence. Locations of the deposits and relative supplementary data for individual deposits are given in the accompanying map and table.

Alaska↗

Availability of ground water in Montgomery County, Maryland

Montgomery County, Md., is underlain by consolidated rocks that, on the basis of well yields, have been subdivided into six hydrogeologic units. The distribution of the hydrogeologic units are shown on a map (scale 1:62,500). Most wells drilled in the county yield between 6 and 25 gal/min (0.4 to 1.6 L/s); however, about one-third of the wells drilled in the most productive hydrogeologic unit yielded more than 25 gal/min (1.6 L/s). Water from all units is suitable for domestic, public supply, and most industrial uses, but may require treatment for the removal of iron and hardness.

Open-File Report↗

Methods for synthesis of some jarosites

Experimental procedures in this report summarize attempts to synthesize potassium-, hydronium-, sodium-, and mixed-composition (hydronium-bearing) jarosites. After experimentation, some acceptable combinations of chemical and physical factors were found to routinely synthesize chemically different jarosites, which were used as part of a characterization study of some natural and synthetic jarosites. Jarosite is a sulfate mineral that is common in geologic settings where iron sulfide minerals such as pyrite or marcasite are subject to oxidative weathering. The presence of jarosite is a hallmark of acidic conditions. Jarosite forms as a secondary mineral in weathered sulfidic ores, coal mine wastes, on oxidizing mine wastes, and in streams affected by acid mine drainage. Jarosite also forms in acid-sulfate soils, as an alteration product of sulfidic shales, and in hydrothermal environments. Because of its important role in earth surface processes, the USGS is conducting mineralogical, geochemical, and remote sensing studies to characterize natural jarosites and to elucidate its stability range and conditions of formation. The presence of jarosite is not limited to the Earth. The recent identification of jarosite in the rocks at the Meridiani Planum on Mars has given planetary geologists reason to think that jarosite may be evidence of relict lacustrine (lake systems) or hydrothermal (water enriched magma emanations) systems on the Martian surface. USGS scientists are currently developing jarosite detection systems that can be placed on orbiting spectrometers. One day these systems may guide Mars landers to sites abundant in jarosite, sites most likely to have sheltered ancient Martian life.

Techniques and Methods↗

Hydrogeology, digital solute-transport simulation, and geochemistry of the Lower Cretaceous aquifer system near Baltimore, Maryland

This study was made to develop information on the hydrogeology and ground-water geochemistry of the Patuxent and Patapsco aquifers (Lower Cretaceous) near Baltimore, Maryland. This information is needed to evaluate the availability and chemical quality of water from these aquifers. The Patuxent aquifer unconformably overlies Lower Paleozoic and Precambrian basement rocks and consists primarily of medium- to coarse-grained quartz sand. Discontinuous lenses of gravel and silty clay are commonly interbedded with the sand-sized material. The Patuxent aquifer in this area attains a thickness of 250 feet and transmissivities range from 2,000 to 8,000 feet squared per day. The Patuxent is the most productive source of ground water in the Baltimore area. In 1982, approximately 11 million gallons of water per day was produced from this unit. Several cones of depression, ranging from 30 to 50 feet below sea level, have developed in response to this pumping stress. The Arundel Formation conformably overlies the Patuxent aquifer. The Arundel is composed predominantly of clay and ranges from 0 to 150 feet thick. The Arundel exhibits very low vertical hydraulic conductivities that are on the order of 10 -9 to 10 -11 feet per second. This unit acts as the upper confining bed of the Patuxent aquifer in much of the project area. The Patapsco aquifer unconformably overlies the Arundel Formation and is a medium- to fine-grained quartz sand. The Patapsco functions as a water-table aquifer in much of the project area. Although the Patapsco has been heavily pumped in the past, pumpage from that aquifer in Baltimore was negligible in 1982. Brackish-water contamination of the Patuxent and Patapsco aquifers has been a major water-quality problem since the early 1900's. The Patuxent aquifer presently (1982) contains a circular plume of brackish-water contamination about 5 miles in diameter. This plume is centered on the Harbor district and has enlarged measurably since 1945. The Patapsco aquifer has a smaller zone of brackish-water contamination that has decreased in size since 1945. Borehole data demonstrate that the Arundel Formation has been breached by Pleistocene river channels near the Harbor district. These erosional channels provide a conduit for brackish water to intrude into the Patuxent aquifer. A two-dimensional areal solute-transport model of the Patuxent aquifer was constructed. This model was designed to estimate the future movement of the brackish-water plume based on alternative scenarios of aquifer use. Model simulations suggest that the plume will remain relatively immobile if 1982 pumping patterns continue into the foreseeable future. However, increased pumpage in the Marley Neck peninsula could draw the plume to the southeast and increase contamination of the Fairfield area. The water quality of the Patuxent aquifer is extremely variable. Because of this variability, it is useful to divide the aquifer into three water-quality zones: Zone 1 -- This zone corresponds to the plume of brackish-water contamination. Zone 2 -- This zone exhibits evidence of urbanization-related contamination such as measurable concentrations of organic chemicals and elevated concentrations of trace elements and total organic carbon. Zone 3 -- Water composition in this zone is controlled exclusively by naturally occurring chemical processes. These processes are dominated by reactions involving dissolved iron. Near the outcrop area, oxidation of pyrite and lignite consumes dissolved oxygen and produces ledges of iron hydroxide-cemented sandstones and conglomerates. The predominant dissolved iron species in oxic water is Fe(OH) 2 + . Downgradient, the water becomes anoxic and sulfate reduction becomes an important process. The predominant dissolved iron species in anoxic water is Fe 2+ .

Maryland↗

Elevated carbon dioxide flux at the Dixie Valley geothermal field, Nevada; relations between surface phenomena and the geothermal reservoir

In the later part of the 1990s, a large die-off of desert shrubs occurred over an approximately 1 km2 area in the northwestern section of the Dixie Valley (DV) geothermal field. This paper reports results from accumulation-chamber measurements of soil CO2 flux from locations in the dead zone and stable isotope and chemical data on fluids from fumaroles, shallow wells, and geothermal production wells within and adjacent to the dead zone. A cumulative probability plot shows three types of flux sites within the dead zone: Locations with a normal background CO2 flux (7 g m-2 day-1); moderate flux sites displaying "excess" geothermal flux; and high flux sites near young vents and fumaroles. A maximum CO2 flux of 570 g m-2 day-1 was measured at a location adjacent to a fumarole. Using statistical methods appropriate for lognormally distributed populations of data, estimates of the geothermal flux range from 7.5 t day-1 from a 0.14-km2 site near the Stillwater Fault to 0.1 t day-1 from a 0.01 -km2 location of steaming ground on the valley floor. Anomalous CO2 flux is positively correlated with shallow temperature anomalies. The anomalous flux associated with the entire dead zone area declined about 35% over a 6-month period. The decline was most notable at a hot zone located on an alluvial fan and in the SG located on the valley floor. Gas geochemistry indicates that older established fumaroles along the Stillwater Fault and a 2-year-old vent in the lower section of the dead zone discharge a mixture of geothermal gases and air or gases from air-saturated meteoric water (ASMW). Stable isotope data indicate that steam from the smaller fumaroles is produced by ??? 100??C boiling of these mixed fluids and reservoir fluid. Steam from the Senator fumarole (SF) and from shallow wells penetrating the dead zone are probably derived by 140??C to 160??C boiling of reservoir fluid. Carbon-13 isotope data suggest that the reservoir CO2 is produced mainly by thermal decarbonation of hydrothermal calcite in veins that cut reservoir rocks. Formation of the dead zone is linked to the reservoir pressure decline caused by continuous reservoir drawdown from 1986 to present. These reservoir changes have restricted flow and induced boiling in a subsurface hydrothermal outflow plume extending from the Stillwater Fault southeast toward the DV floor. We estimate that maximum CO2 flux in the upflow zone along the Stillwater Fault in 1998 was roughly seven to eight times greater than the pre-production flux in 1986. The eventual decline in CO2 flux reflects the drying out of the outflow plume. Published by Elsevier Science B.V.

Chemical Geology↗

Water-Table Levels and Gradients, Nevada, 1947-2004

In 1999, the U.S. Environmental Protection Agency began a program to protect the quality of ground water in areas other than ground-water protection areas. These other sensitive ground water areas (OSGWA) are areas that are not currently, but could eventually be, used as a source of drinking water. The OSGWA program specifically addresses existing wells that are used for underground injection of motor-vehicle waste. To help determine whether a well is in an OSGWA, the Nevada Division of Environmental Protection needs statewide information on depth to water and the water table, which partly control the susceptibility of ground water to contamination and contaminant transport. This report describes a study that used available maps and data to create statewide maps of water-table and depth-to-water contours and surfaces, assessed temporal changes in water-table levels, and characterized water-table gradients in selected areas of Nevada. A literature search of published water-table and depth-to-water contours produced maps of varying detail and scope in 104 reports published from 1948 to 2004. Where multiple maps covered the same area, criteria were used to select the most recent, detailed maps that covered the largest area and had plotted control points. These selection criteria resulted in water-table and depth-to-water contours that are based on data collected from 1947 to 2004 being selected from 39 reports. If not already available digitally, contours and control points were digitized from selected maps, entered into a geographic information system, and combined to make a statewide map of water-table contours. Water-table surfaces were made by using inverse distance weighting to estimate the water table between contours and then gridding the estimates. Depth-to-water surfaces were made by subtracting the water-table altitude from the land-surface altitude. Water-table and depth-to-water surfaces were made for only 21 percent of Nevada because of a lack of information for 49 of 232 basins and for most consolidated-rock hydrogeologic units. Depth to water is commonly less than 50 feet beneath valley floors, 50 to 500 feet beneath alluvial fans, and more than 500 feet in some areas such as north-central and southern Nevada. In areas without water-table information, greasewood and mapped ground-water discharge areas are good indicators of depth to water less than 100 feet. The average difference between measured depth to water and depth to water estimated from surfaces was 90 feet. More recent and detailed information may be needed than that presented in this report to evaluate a specific site. Temporal changes in water-table levels were evaluated for 1,981 wells with 10 or more years between the first depth-to-water measurement and last measurement made since 1990. The greatest increases in depth to water occurred where the first measurement was less than 200 feet, where the time between first and last measurements was 40 years or less, and for wells between 100 and 600 feet deep. These characteristics describe production wells where ground water is fairly shallow in recently developing areas such as the Las Vegas and Reno metropolitan areas. In basins with little pumping, 90 percent of the changes during the past 100 years are within ?20 feet, which is about the natural variation in the water table due to changes in the climate and recharge. Gradients in unconsolidated sediments of the Great Basin are generally steep near mountain fronts, shallow beneath valley floors, and depend on variables such as the horizontal hydraulic conductivity of adjacent consolidated rocks and recharge. Gradients beneath alluvial fans and valley floors at 58 sites were correlated with selected variables to identify those variables that are statistically related. Water-table measurements at three sites were used to characterize the water table between the valley floor and consolidated rock. Water-table gradients beneath alluvial fan

Scientific Investigations Report↗

Equatorial origin for Lower Jurassic radiolarian chert in the Franciscan Complex, San Rafael Mountains, southern California

Lower Jurassic radiolarian chert sampled at two localities in the San Rafael Mountains of southern California (∼20 km north of Santa Barbara) contains four components of remanent magnetization. Components A , B ′, and B are inferred to represent uplift, Miocene volcanism, and subduction/accretion overprint magnetizations, respectively. The fourth component ( C ), isolated between 580° and 680°C, shows a magnetic polarity stratigraphy and is interpreted as a primary magnetization acquired by the chert during, or soon after, deposition. Both sequences are late Pliensbachian to middle Toarcian in age, and an average paleolatitude calculated from all tilt-corrected C components is 1° ± 3° north or south. This result is consistent with deposition of the cherts beneath the equatorial zone of high biologic productivity and is similar to initial paleolatitudes determined for chert blocks in northern California and Mexico. This result supports our model, in which deep-water Franciscan-type cherts were deposited on the Farallon plate as it moved eastward beneath the equatorial productivity high, were accreted to the continental margin at low paleolatitudes, and were subsequently distributed northward by strike-slip faulting associated with movements of the Kula, Farallon, and Pacific plates. Upper Cretaceous turbidites of the Cachuma Formation were sampled at Agua Caliente Canyon to determine a constraining paleolatitude for accretion of the Jurassic chert sequences. These apparently unaltered rocks, however, were found to be completely overprinted by the A component of magnetization. Similar in situ directions and demagnetization behaviors observed in samples of other Upper Cretaceous turbidite sequences in southern and Baja California imply that these rocks might also give unreliable results.

Journal of Geophysical Research B: Solid Earth↗