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At least 937 records · Page 52Linked to original sources
USGS2007

Organic petrology of Paleocene Marcelina Formation coals, Paso Diablo mine, western Venezuela: Tectonic controls on coal type

About 7??Mt of high volatile bituminous coal are produced annually from the four coal zones of the Upper Paleocene Marcelina Formation at the Paso Diablo open-pit mine of western Venezuela. As part of an ongoing coal quality study, we have characterized twenty-two coal channel samples from the mine using organic petrology techniques. Samples also were analyzed for proximate-ultimate parameters, forms of sulfur, free swelling index, ash fusion temperatures, and calorific value. Six of the samples represent incremental benches across the 12-13??m thick No. 4 bed, the stratigraphically lowest mined coal, which is also mined at the 10??km distant Mina Norte open-pit. Organic content of the No. 4 bed indicates an upward increase of woody vegetation and/or greater preservation of organic material throughout the life of the original mire(s). An upward increase in telovitrinite and corresponding decrease in detrovitrinite and inertinite illustrate this trend. In contrast, stratigraphically higher coal groups generally exhibit a 'dulling upward' trend. The generally high inertinite content, and low ash yield and sulfur content, suggest that the Paso Diablo coals were deposited in rain-fed raised mires, protected from clastic input and subjected to frequent oxidation and/or moisture stress. However, the two thinnest coal beds (both 0.7??m thick) are each characterized by lower inertinite and higher telovitrinite content relative to the rest of Paso Diablo coal beds, indicative of less well-established raised mire environments prior to drowning. Foreland basin Paleocene coals of western Venezuela, including the Paso Diablo deposit and time-correlative coal deposits of the Ta??chira and Me??rida Andes, are characterized by high inertinite and consistently lower ash and sulfur relative to Eocene and younger coals of the area. We interpret these age-delimited coal quality characteristics to be due to water availability as a function of the tectonic control of subsidence rate. It is postulated that slower subsidence rates dominated during the Paleocene while greater foreland basin subsidence rates during the Eocene-Miocene resulted from the loading of nappe thrust sheets as part of the main construction phases of the Andean orogen. South-southeastward advance and emplacement of the Lara nappes during the oblique transpressive collision of the Caribbean and South American tectonic plates in the Paleocene was further removed from the sites of peat deposition, resulting in slower subsidence rates. Slower subsidence in the Paleocene may have favored the growth of raised mires, generating higher inertinite concentrations through more frequent moisture stress. Consistently low ash yield and sulfur content would be due to the protection from clastic input in raised mires, in addition to the leaching of mineral matter by rainfall and the development of acidic conditions preventing fixation of sulfur. In contrast, peat mires of Eocene-Miocene age encountered rapid subsidence due to the proximity of nappe emplacement, resulting in lower inertinite content, higher and more variable sulfur content, and higher ash yield.

International Journal of Coal Geology↗
USGS2021

GIS-based identification of areas that have resource potential for sediment-hosted Pb-Zn deposits in Alaska

A state-wide Geographic Information System analysis was conducted to assess prospectivity for lead (Pb) and zinc (Zn) in sediment-hosted deposits in Alaska. The datasets that were utilized include publicly available geospatial datasets of lithologic, geochemical, and mineral occurrence data. Key characteristics of Pb-Zn deposits were identified in available datasets and scored with respect to relative importance. To evaluate resource potential, drainage basins of the smallest size were chosen, each of which covers approximately 100 square kilometers (km 2 ). Drainage basins are the most logical and efficient unit for evaluation because the most regionally robust dataset comes from stream sediment geochemistry. Sediment-hosted Pb-Zn deposits in Alaska include those contained in carbonate rocks (similar to Mississippi Valley Type or MVT deposits) and those contained in clastic-dominated (CD) sequences (CD Pb-Zn), historically referred to as SEDEX (sedimentary exhalative). The latter include the deposits currently being mined in the Red Dog district in the western Brooks Range. Host rocks for the two subtypes are distinct: carbonate versus fine-grained clastic rocks for CD Pb-Zn deposits. However, there are exceptions: some CD Pb-Zn deposits are hosted in carbonate layers within a thick clastic-dominated rock sequence. The statewide geologic map database contains units that commonly include mixed carbonate-clastic sequences that cannot be subdivided. The most significant difference between the two deposit types is their respective depositional environments and tectonic settings, but at the reconnaissance level of mapping in most areas of the state, these distinctions are not possible. Furthermore, nearly all critical geochemical parameters (silver [Ag], barium [Ba], Pb, Zn) are common to both types, and therefore it was not possible to do separate assessments for carbonate-hosted and CD Pb-Zn deposits. Areas identified that have moderate to high potential for sediment-hosted Pb-Zn deposits include the (1) western and central Brooks Range, referred to in this report as the Brooks Range zinc belt; (2) Seward Peninsula (and adjacent St. Lawrence Island); (3) Farewell terrane in Interior Alaska; (4) two spatially distinct belts in east-central Alaska; and (5) the central Alaska Range. All areas contain some known deposits, and that provides credibility to the scoring process. Some hydrologic unit codes (HUCs) that have high potential for sediment-hosted Pb-Zn deposits are located adjacent to areas of known deposits and indicate the potential for expansion of known Pb-Zn districts. There are a few areas that have high potential but contain no known sediment hosted Pb-Zn occurrences, prospects, or deposits. In such areas, future investigations could be focused on better defining and constraining prospectivity with additional data.

Alaska↗
USGS1979

Chemical analyses of coal from the Emery and Ferron Sandstone members of the Mancos Shale, Henry Mountains Field, Wayne and Garfield counties, Utah

As part of a continuing program by the U.S. Geological Survey to collect and chemically analyze representative samples of U.S. coals, 18 samples were collected from the Upper Cretaceous Emery and Ferron Sandstone Members of the Mancos Shale in the Henry Mountains coal field, Wayne and Garfield Counties, Utah (fig. 1). The 18 samples are briefly described in table 1. Thirteen of these samples were collected from seven holes that were drilled in connection with the Henry Mountains EMRIA (Energy Mineral Rehabilitation Inventory and Analyses) study (U.S. Department of the Interior, 1978). The locations of the seven core holes and the four other sampling sites are shown on figure 2. The Henry Mountains coal field is adjacent to the Henry Mountains of southeastern Utah. The basin is a long, narrow syncline about 110 km long and 24 km wide bounded on the west by the Waterpocket Fold and on the east by the Henry Mountains. The most comprehensive geologic report available on the area is by Hunt and others (1953). Their work included a considerable amount of information on the coal resources. Other work in the area concerning coal or stratigraphy of coal bearing units includes: Doelling (1972), Peterson and Ryder (1975), Doelling (1975), Law (1977; 1978; 1979 a,b), and U.S. Department of the Interior (1978). In the Henry Mountains field, there are three coal bearing units in rocks of Late Cretaceous age. In ascending order they are the Dakota Sandstone, the Ferron Sandstone Member of the Mancos Shale, and the Emery Sandstone Member of the Mancos Shale. The coal beds of the Henry Mountains coal field originated as layers of peat that were deposited, for the most part, in coastal swamp environments. Individual coal beds are discontinuous and exhibit large variations in thickness and quality. The thickest and most continuous coal beds occur in the Emery Sandstone Member along or near the axis of the Henry Mountains syncline (Law, 1978).

Utah↗
USGS2008

Seasonal and event variations in δ 34 S values of stream sulfate in a Vermont forested catchment: Implications for sulfur sources and cycling

Stable sulfur (S) isotope ratios can be used to identify the sources of sulfate contributing to streamwater. We collected weekly and high-flow stream samples for S isotopic analysis of sulfate through the entire water year 2003 plus the snowmelt period of 2004. The study area was the 41-ha forested W-9 catchment at Sleepers River Research Watershed, Vermont, a site known to produce sulfate from weathering of sulfide minerals in the bedrock. The δ 34 S values of streamwater sulfate followed an annual sinusoidal pattern ranging from about 6.5‰ in early spring to about 10‰ in early fall. During high-flow events, δ 34 S values typically decreased by 1 to 3‰ from the prevailing seasonal value. The isotopic evidence suggests that stream sulfate concentrations are controlled by: (1) an overall dominance of bedrock-derived sulfate ( δ 34 S ~ 6–14‰); (2) contributions of pedogenic sulfate ( δ 34 S ~ 5–6‰) during snowmelt and storms with progressively diminishing contributions during base flow recession; and (3) minor effects of dissimilatory bacterial sulfate reduction and subsequent reoxidation of sulfides. Bedrock should not be overlooked as a source of S in catchment sulfate budgets.

Vermont↗
USGS2017

Constraining the thermal history of the North American Midcontinent Rift System using carbonate clumped isotopes and organic thermal maturity indices

The Midcontinent Rift System (MRS) is a Late Mesoproterozoic (∼1.1 Ga) sequence of volcanic and sedimentary rocks exposed in the Lake Superior Region of North America. The MRS continues to be the focus of much research due to its economic mineral deposits as well as its archive of Precambrian life and tectonic processes. In order to constrain the post-depositional thermal history of the MRS, samples were analyzed for carbonate clumped isotope composition and organic thermal maturity. Clumped isotope values from sedimentary/early-diagenetic samples were partially reset during burial to temperatures between 68 and 75 °C. Solid-state reordering models indicate that maximum burial temperatures of 125–155 °C would reset the clumped isotope values to the observed temperature range prior to the onset of regional cooling and uplift. Clumped isotope results from late-stage veins in the White Pine Mine encompass a greater temperature range (49–116 °C), indicative of spatially variable hydrothermal activity and vein emplacement after burial temperatures fell below 100 °C during regional cooling and uplift. Clumped isotope and organic thermal maturity data do not indicate significant spatial differences in thermal history along the MRS. Observed variability in bulk organic matter composition and biomarker indices are therefore more likely a result of shifts in primary productivity or early-degradation processes. These results demonstrate that the MRS experienced a spatially consistent, relatively mild thermal history (125–155 °C) and is therefore a valuable archive for understanding the Late Mesoproterozoic environment.

Lake Superior↗
USGS2024

Hydrothermal plume fallout, mass wasting, and volcanic eruptions contribute to sediments at Loki’s Castle vent field, Mohns Ridge

Sediments surrounding hydrothermal vents are important transition spaces between hydrothermal and pelagic environments. These sediments accumulate through diverse processes that include water column plume fallout, volcanic ash deposition, and mass wasting of hydrothermal chimneys and mounds superimposed upon background sedimentation which may originate from pelagic, terrestrial, and volcanic sources. In addition to being a sink for elements discharged from hydrothermal vents, elements may also be scavenged from seawater onto oxidized hydrothermal material. Preservation of these hydrothermal sediments may occur depending on the extent of oxidative and/or reductive dissolution processes after burial. Sediments remaining adjacent to active venting may also be hydrothermally altered after emplacement. To better understand these processes, here we evaluate sediment push cores collected from the Loki's Castle vent field at the intersection of the slow-ultraslow spreading Mohns and Knipovich mid-ocean ridges. All samples were collected within ∼225 m of current high-temperature (299–316°C) “black smoker” fluid discharge. These sediment cores are highly heterogeneous and lack stratigraphic correlation, even for samples taken within meters of each other. Most sediment cores are dominated by either pelagic sediments or mass wasted hydrothermal material, with hydrothermal plume fallout contributing a low proportion of material, and only a single volcanic ash layer occurring in one of the 13 cores. Dominant hydrothermal minerals found include talc, goethite, pyrite, pyrrhotite, and sphalerite. We find that even after several thousand years, most mass wasted hydrothermal material remains minimally altered, with sedimentation rates indistinguishable from background rates within several hundred meters of the hydrothermal vent source.

Geochemistry, Geophysics, Geosystems↗
USGS1991

Sedimentary facies and depositional environments of early Mesozoic Newark Supergroup basins, eastern North America

The early Mesozoic Newark Supergroup consists of continental sedimentary rocks and basalt flows that occupy a NE-trending belt of elongate basins exposed in eastern North America. The basins were filled over a period of 30–40 m.y. spanning the Late Triassic to Early Jurassic, prior to the opening of the north Atlantic Ocean. The sedimentary rocks are here divided into four principal lithofacies. The alluvial-fan facies includes deposits dominated by: (1) debris flows; (2) shallow braided streams; (3) deeper braided streams (with trough crossbeds); or (4) intense bioturbation or hyperconcentrated flows (tabular, unstratified muddy sandstone). The fluvial facies include deposits of: (1) shallow, ephemeral braided streams; (2) deeper, flashflooding, braided streams (with poor sorting and crossbeds); (3) perennial braided rivers; (4) meandering rivers; (5) meandering streams (with high suspended loads); (6) overbank areas or local flood-plain lakes; or (7) local streams and/or colluvium. The lacustrine facies includes deposits of: (1) deep perennial lakes; (2) shallow perennial lakes; (3) shallow ephemeral lakes; (4) playa dry mudflats; (5) salt-encrusted saline mudflats; or (6) vegetated mudflats. The lake margin clastic facies includes deposits of: (1) birdfoot deltas; (2) stacked Gilbert-type deltas; (3) sheet deltas; (4) wave-reworked alluvial fans; or (5) wave-sorted sand sheets. Coal deposits are present in the lake margin clastic and the lacustrine facies of Carnian age (Late Triassic) only in basins of south-central Virginia and North and South Carolina. Eolian deposits are known only from the basins in Nova Scotia and Connecticut. Evaporites (and their pseudomorphs) occur mainly in the northern basins as deposits of saline soils and less commonly of saline lakes, and some evaporite and alkaline minerals present in the Mesozoic rocks may be a result of later diagenesis. These relationships suggest climatic variations across paleolatitudes, more humid to the south where coal beds are preserved, and more arid in the north where evaporites and eolian deposits are common. Fluctuations in paleoclimate that caused lake levels to rise and fall in hydrologically closed basins are preserved as lacustrine cycles of various scales, including major shifts in the Late Triassic from a wet Carnian to an arid Norian. In contrast, fluvial deposits were mainly formed in response to the tectonic evolution of the basins, but to some extent also reflect climatic changes. The Newark Supergroup illustrates the complexity of rift-basin sedimentation and the problems that may arise from using a single modern analog for sedimentary deposition spanning millions of years. It also shows that a tremendous wealth of depositional, climatic, and tectonic information is preserved in ancient rift-basin deposits which can be recovered if the depositional processes of modern rift-basin deposits are understood.

eastern North America↗
USGS2026

Geochemical disequilibrium at the brittle-ductile transition

We investigate the microtextural, microchemical, and isotopic effects of late-stage ductile deformation in quartzite mylonites and kyanite–muscovite–quartz veins from the Raft River shear zone (Utah). Quartz microstructures record pervasive disequilibrium, expressed by unannealed features including undulatory extinction, deformation lamellae, and poorly defined fabrics, typical of waning deformation in shear zones. Microchemical disequilibrium is best preserved in kyanite quartzites, where CL-zoned kyanite records repeated fractures, overgrowth, and mineral precipitation, and in muscovite from muscovite-poor quartzite mylonites that shows minor-element zoning consistent with syn-deformational overgrowth on detrital cores. In contrast, muscovite from muscovite-rich kyanite quartzites exhibits minimal chemical zoning. These microchemical variations correlate with 40 Ar/ 39 Ar age systematics. Chemically zoned muscovite preserves variable single-step ages, including ∼150 Ma ages, reflecting retention of detrital cores. In contrast, syndeformational muscovite consistently yields Miocene ages, indicating recrystallization and new growth below argon closure temperatures that reset inherited isotopic signatures. Similar trends are observed in quartzite mylonites, where increasing quartz recrystallization and stronger crystallographic preferred orientations occur toward deeper structural levels. Together, these observations indicate increasing retrograde deformation and recrystallization with depth in the Raft River shear zone and demonstrate that strain-driven recrystallization exerts a first-order control on muscovite ages. We suggest that apparent thermochronologic gradients in retrograde shear zones may reflect recrystallization gradients rather than temperature gradients. Where cooling limits the thermal driving force for recrystallization, isotopic relics are preserved, and local deformation and fluid availability control re-equilibration. Consequently, isotopic disequilibrium—particularly in the 40 Ar/ 39 Ar system—may be the rule rather than the exception of retrograde tectonic environments.

Idaho, Utah↗
USGS1988

Natural aggregates of the conterminous United States

Crushed stone and sand and gravel are the two main sources of natural aggregates. These materials are commonly used construction materials and frequently can be interchanged with one another. They are widely used throughout the United States, with every State except two producing crushed stone. Together they amount to about half the mining volume in the United States. Approximately 96 percent of sand and gravel and 77 percent of the crushed stone produced in the United States are used in the construction industry. Natural aggregates are widely distributed throughout the United States in a variety of geologic environments. Sand and gravel deposits commonly are the results of the weathering of bedrock and subsequent transportation and deposition of the material by water or ice (glaciers). As such, they commonly occur as river or stream deposits or in glaciated areas as glaciofluvial and other deposits. Crushed stone aggregates are derived from a wide variety of parent bedrock materials. Limestone and other carbonates account for approximately three quarters of the rocks used for crushed stone, with granite and other igneous rocks making up the bulk of the remainder. Limestone deposits are widespread throughout the Central and Eastern United States and are scattered in the West. Granites are widely distributed in the Eastern and Western United States, with few exposures in the Midwest. Igneous rocks (excluding granites) are largely concentrated in the Western United States and in a few isolated localities in the East. Even though natural aggregates are widely distributed throughout the United States, they are not universally available for consumptive use. Some areas are devoid of sand and gravel, and potential sources of crushed stone may be covered with sufficient unconsolidated material to make surface mining impractical. In some areas many aggregates do not meet the physical property requirements for certain uses, or they may contain mineral constituents that react adversely when used as concrete aggregate. In areas where suitable natural aggregate is not available or accessible, it may become necessary to improve the quality of existing aggregate, to import aggregate from outside the area, or to substitute artificial aggregate for natural aggregate. In most cases, all of these alternatives add substantially to the cost of the final product. Even though an area may be blessed with an abundance of aggregate suitable for the intended purpose, existing land uses, zoning, or regulations may preclude commercial exploitation of the aggregate. This report also discusses the aggregate industry in general terms, including exploration, mining, and processing, as well as aggregate production rates. Proper long-range planning based on an understanding of the aggregate industry can help assure adequate supplies of aggregate.

conterminous United States↗
USGS1994

Use of geoelectrical methods in groundwater pollution surveys in a coastal environment

The pollution of coastal aquifers by old landfills can contaminate valuable and scarce water resources in the freshwater lens utilized seasonably by overcrowded communities. The pollutants will ultimately flow into the sea where they may also cause a coastal water pollution problem. We have detected pollution in the freshwater lens from a sanitary landfill near Provincetown, Cape Cod, using the geoelectrical resistivity method. This survey included Schlumberger geoelectrical depth soundings and a horizontal geoelectrical profile using the Wenner configuration. The geoelectrical survey was conducted at a site along Highway 6 where it passes the coastal town of Provincetown and a sanitary landfill that has been in operation since 1954. The depth soundings suggest the characteristic decrease in resistivity vs. depth from the high resistivity of the unsaturated zone to the low resistivity of the saltwater saturated zone. The freshwater lens is clearly identified by the change in slope of the steeply dipping curve of resistivity versus electrode spacing. Interpretations made using a multilayer program, Geomate, resulted in layer resistivities between 460 and 95 ohm?m for the freshwater lens. A comparison with well water resistivities suggests that a layer resistivity of 230 ohm?m or lower is indicative of pollution in the freshwater lens. The results of the geoelectrical depth soundings were confirmed in the Wenner horizontal profile. Both measurements suggest that the pollutants do not spread evenly as one would expect for a homogeneous and isotropic medium. Instead, a preferred channel for the flow of the pollutants is observed along a path from the landfill toward the shoreline. The depth to the saltwater/freshwater interface or, more specifically, to the low resistivity-high resistivity interface appears to be shallow where the freshwater lens is polluted. This was confirmed by pore water well samples that were highly mineralized. The equilibrium postulated by the Ghyben-Herzberg relation appears to be disturbed in the area of aquifer pollution. This rise in the conductivity boundary is caused by the highly mineralized bottom of the contaminant plume that submerges into the saltwater saturated zone. In the area of high freshwater pollution the groundwater can be subdivided into three layers that show a decrease in resistivity with depth. The formation factor, F, defined as the ratio of bulk aquifer resistivity to pore water resistivity, shows unusually high values between 10 and 12. These high values are unexpected for an unconsolidated sand. Pollution residues are suspected to clog the pores and thus to increase the resistivity. It is possible that iron-oxidizing bacteria and the precipitation of dissolved iron or organic pollutants are the cause of the high values of F. If proven correct, these interesting possibilities could lead to future new applications of the geoelectrical resistivity method in contaminant hydroloy.

Journal of Applied Geophysics↗
USGS2001

Geologic map and database of the Roseburg 30' x 60' quadrangle, Douglas and Coos Counties, Oregon

The Roseburg 30' x 60' Quadrangle covers the southeastern margin of the Oregon Coast Range and its tectonic boundary with Mesozoic terranes of the Klamath Mountains (see figures 1 and 2 in pamphlet, also shown on map sheet). The geologic framework of the Roseburg area was established by the pioneering work of Diller (1898), Wells and Peck, (1961) and Ewart Baldwin (1974) and his students (see figure 3 in pamphlet, also shown on map sheet). Baldwin and his students focussed on the history of the Eocene Tyee basin, where the sediments lap across the tectonic boundary with the Mesozoic terranes and record the accretion of the Coast Range basement to the continent. Others have examined the sedimentary fill of the Tyee basin in detail, recognizing the deep marine turbidite facies of the Tyee Formation (Snavely and others, 1964) and proposing several models for the Eocene evolution of the forearc basin (Heller and Ryberg, 1983; Chan and Dott, 1983; Heller and Dickinson, 1985; Molenaar, 1985; see Ryu and others, 1992 for a comprehensive summary). Along the eastern margin of the quadrangle, both the Tyee basin and the Klamath terranes are overlain by Eocene volcanic rocks of the Western Cascade arc (Walker and MacLeod, 1991). The thick Eocene sedimentary sequence of the Tyee basin has significant oil and gas potential (Armentrout and Suek, 1985; Gautier and others, 1993; Ryu and others, 1996). Although 13 deep test wells have been drilled in the Roseburg quadrangle (see figure 2 and table 1 in pamphlet, also shown on map sheet), exploration to date has been hampered by an incomplete understanding of the basin�s tectonic setting and evolution. In response, the Oregon Department of Geology and Mineral Industries (DOGAMI) initiated a five year assessment of the oil and gas potential of the Tyee basin. This map is a product of a cooperative effort by the U. S. Geological Survey, Oregon State University, and DOGAMI to systematically map the sedimentary facies and structure of the Tyee basin. New geologic mapping of twenty-eight 7.5' quadrangles is summarized on the map (see figure 3, also shown on map sheet), and the digital database contains geologic information suitable for both 1:100K and 1:24K scale analysis. DOGAMI has published a compilation and synthesis of previous mapping (Niem and Niem, 1990), a basin-wide sequence stratigraphic model and correlations (Ryu and others, 1992), and a report on the oil and gas potential (Ryu and others, 1996). Readers interested in the oil and gas potential of the Roseburg quadrangle should use the map in combination with Ryu and others (1996) to address specific stratigraphic units and structural plays. Stratigraphic terminology for the Tyee basin adopts the type sections, formation names, and framework of Ryu and others (1992, 1996), which were developed concurrently with the mapping and are recognized throughout the basin. For detailed discussion of nomenclature, type sections, lithology, thickness and distribution, age, contact relationships, and depositional environment of stratigraphic units, the reader is referred to Ryu and others (1992). In this report we focus on the spatial, temporal, and structural relationships between units revealed by geologic mapping. Map unit ages (see figure 4 in pamphlet, also shown on map sheeet) are adjusted slightly from Ryu and others (1992, 1996) to fit new coccolith age determinations (D. Bukry, cited in pamphlet), paleomagnetic polarity data (Simpson, 1977 and new data cited in pamphlet), and the time scale of Berggren and others (1995).

Oregon↗
USGS1976

The source of hydrothermal solutions at Puerto Maunabo and its bearing on the base-metal-potassium feldspar association in Puerto Rico

A quartz oligoclase porphyry exposed near Puerto Maunabo may provide evidence to further our understanding of the base-metal-potassium feldspar association known to occur in many of the porphyry-type copper deposits of Puerto Rico. The porphyry appears to be a magmatic differentiate on the border of the San Lorenzo batholith that may represent a source of mineralizing hydrothermal solutions. The porphyry intrudes an albitized quartz diorite border phase of the batholith that contains large roof pendants of metavolcanic rock. These roof pendants are mostly metamorphosed to greenschist metamorphic facies, but in the vicinity of Puerto Maunabo south of the porphyry, they reach amphibolite metamorphic facies; north of the porphyry, similar xenolithic lenses of metavolcanic rock appear to have been converted entirely to an oligoclase quartz felsite. The layered albitized quartz felsite has the same composition and texture as irregular veinlets in the albitized quartz diorite and as the groundmass in the porphyry. The K + ions arid basic ions of Fe +2 , Cu +2 , Mg +2 apparently were mobilized during final magmatic crystallization and then escaped as hydrothermal solutions that followed open conduits within a zone of structural weakness which also permitted the emplacement of the porphyry. The volcanic rock of Cerro Piedra Hueca, in contact with the albitized quartz diorite, and generally along strike west of the porphyry, has been altered to a quartz sericite rock entirely devoid of mafic silicates. This is the southeasternmost exposure of hydrothermally altered volcanic rock in the regional zone of northwest-trending faults that contains the principal porphyry-type copper deposits of Puerto Rico. The texture, mineralogy, and geologic environment of the porphyry at Puerto Maunabo are similar to those of the ore-bearing porphyries but differ in one important aspect. Most ore-bearing porphyries contain hydrothermal potassium feldspar and reddish-brown biotite intimately associated with the base-metal sulfides. In the porphyry of Puerto Maunabo, potassium feldspar is conspicuously absent, and only a trace of biotite is present; the only sulfide present is pyrite. The physical and chemical environment required to precipitate K + ions, either as potassium feldspar or biotite, apparently is very similar to that required to precipitate base-metal sulfides. At Puerto Maunabo, these conditions evidently did not prevail, and potassium and the base metals may have been carried in solution to a more favorable environment.

Puerto Maunabo↗
USGS2017

Manganese

Manganese is an essential element for modern industrial societies. Its principal use is in steelmaking, where it serves as a purifying agent in iron-ore refining and as an alloy that converts iron into steel. Although the amount of manganese consumed to make a ton of steel is small, ranging from 6 to 9 kilograms, it is an irreplaceable component in the production of this fundamental material. The United States has been totally reliant on imports of manganese for many decades and will continue to be so for at least the near future. There are no domestic reserves, and although some large low-grade resources are known, they are far inferior to manganese ores readily available on the international market. World reserves of manganese are about 630 million metric tons, and annual global consumption is about 16 million metric tons. Current reserves are adequate to meet global demand for several decades. Global resources in traditional land-based deposits, including both reserves and rocks sufficiently enriched in manganese to be ores in the future, are much larger, at about 17 billion metric tons. Manganese resources in seabed deposits of ferromanganese nodules and crusts are larger than those on land and have not been fully quantified. No production from seabed deposits has yet been done, but current research and development activities are substantial and may bring parts of these seabed resources into production in the future. The advent of economically successful seabed mining could substantially alter the current scenario of manganese supply by providing a large new source of manganese in addition to traditional land-based deposits. From a purely geologic perspective, there is no global shortage of proven ores and potential new ores that could be developed from the vast tonnage of identified resources. Reserves and resources are very unevenly distributed, however. The Kalahari manganese district in South Africa contains 70 percent of the world’s identified resources and about 25 percent of its reserves. South Africa, Brazil, and Ukraine together accounted for nearly 65 percent of reserves in 2013. The combination of total import reliance for manganese, the mineral commodity’s essential uses in our industrialized society, and the potential for supply disruptions because of the limited sources of the ore makes manganese among the most critical minerals for the United States. Manganese is the 12th most abundant element in Earth’s crust. Its concentration varies among common types of rocks, mostly in the range of from 0.1 to 0.2 percent. The highest quality manganese ores contain from 40 to 45 percent manganese. The formation of these ores requires specialized geologic conditions that concentrate manganese at several hundred times its average crustal abundance. The dominant processes in forming the world’s principal deposits take place in the oceans. As a result, most important manganese deposits occur in ancient marine sedimentary rocks that are now exposed on continents as a result of subsequent tectonic uplift and erosion. In many cases, other processes have further enriched these manganiferous sedimentary rocks to form some of today’s highest grade ores. Modern seabed resources of ferromanganese nodules cover vast areas of the present ocean floor and are still forming by complex interactions of marine microorganisms, manganese dissolved in seawater, and chemical processes on the seabed. Manganese is ubiquitous in soil, water, and air. It occurs most often in solid form but can become soluble under acidic conditions. Manganese mining, like any activity that disturbs large areas of Earth’s surface, has the potential to produce increases in manganese concentrations that could be harmful to humans or the environment if not properly controlled. Although manganese is an essential nutrient for humans and most other organisms, overexposure can lead to neurotoxicity in humans. Workers at manganese mining and processing facilities have the greatest potential to inhale manganese-rich dust. Without proper protective equipment, these workers may develop a permanent neurological disorder known as manganism. Each manganese mine is unique and presents its own suite of potential hazards and preventative measures. Likewise, various nations have their own sets of standards to ensure safe mining, isolation of mine waste, treatment of mine waters, and mine closure and restoration. Interest in mining trace metals contained in ferromanganese nodules and crusts on the seabed has increased rapidly in the past decade. Prime areas for future research include overcoming the technological challenges presented by mining as deep as 6,500 meters below sea level and understanding and mitigating the potential impacts of seabed mining on marine ecosystems.

Professional Paper↗
USGS1985

Hydrogeologic appraisal of five selected aquifers in Erie County, New York

Hydrogeologic conditions and water quality at four stratified-drift aquifers and a bedrock (Onondaga Limestone) aquifer were investigated by the U.S. Geological Survey in cooperation with the Erie County Department of Environment and Planning. The Clarence-Lancaster-Newstead area includes two aquifers--one is a complex of morainal, beach, and outwash sand and gravel; the second is the underlying production aquifer in Onondage Limestone. Most wells tap the limestone aquifer. Water quality is suitable for most uses in both aquifers except for road-salt contamination at shallow wells near the New York State Thruway. A landfill on the aquifer has affected the water quality in some areas along its perimeter. The Sardinia and Springville areas each include an aquifer consisting of surficial outwash sand and gravel ranging in thickness from less than 10 feet to 95 feet. Several deeper water-bearing zones occur within till and lacustrine deposits 400 to 600 feet thick in the valleys. Ground water moves from the north and from the aquifer 's edges to the center of the valley and discharges into the main streams in the middle of the valley and to springs along the southern edge of the aquifers. Water quality is generally suitable for most uses. A landfill adjacent to the Sardinia aquifer has not significantly affected the aquifer. The Alden area includes an aquifer that consists of two sand and gravel zones separated by 10 to 20 feet of clay or till. The more productive lower zone has mineralized water derived from underlying shale.

New York↗
USGS2000

Mercury mine drainage and processes that control its environmental impact

Mine drainage from mercury mines in the California Coast Range mercury mineral belt is an environmental concern because of its acidity and high sulfate, mercury, and methylmercury concentrations. Two types of mercury deposits are present in the mineral belt, silica-carbonate and hot-spring type. Mine drainage is associated with both deposit types but more commonly with the silica-carbonate type because of the extensive underground workings present at these mines. Mercury ores consisting primarily of cinnabar were processed in rotary furnaces and retorts and elemental mercury recovered from condensing systems. During the roasting process mercury phases more soluble than cinnabar are formed and concentrated in the mine tailings, commonly termed calcines. Differences in mineralogy and trace metal geochemistry between the two deposit types are reflected in mine drainage composition. Silica-carbonate type deposits have higher iron sulfide content than hot- spring type deposits and mine drainage from these deposits may have extreme acidity and very high concentrations of iron and sulfate. Mercury and methylmercury concentrations in mine drainage are relatively low at the point of discharge from mine workings. The concentration of both mercury species increases significantly in mine drainage that flows through and reacts with calcines. The soluble mercury phases in the calcines are dissolved and sulfate is added such that methylation of mercury by sulfate reducing bacteria is enhanced in calcines that are saturated with mine drainage. Where mercury mine drainage enters and first mixes with stream water, the addition of high concentrations of mercury and sulfate generates a favorable environment for methylation of mercury. Mixing of oxygenated stream water with mine drainage causes oxidation of dissolved iron(II) and precipitation of iron oxyhydroxide that accumulates in the streambed. Both mercury and methylmercury are strongly adsorbed onto iron oxyhydroxide over the pH range of 3.2-7.1 in streams impacted by mine drainage. The dissolved fraction of both mercury species is depleted and concentrated in iron oxyhydroxide such that the amount of iron oxyhydroxide in the water column reflects the concentration of mercury species. In streams impacted by mine drainage, mercury and methylmercury are transported and adsorbed onto particulate phases. During periods of low stream flow, fine-grained iron hydroxide sediment accumulates in the bed load of the stream and adsorbs mercury and methylmercury such that both forms of mercury become highly enriched in the iron oxyhydroxide sediment. During high-flow events, mercury- and methylmercury-enriched iron hydroxide sediment is transported into larger aquatic systems producing a high flux of bioavailable mercury. (C) 2000 Elsevier Science B.V.

Science of the Total Environment↗
USGS2012

Peralkaline- and calc-alkaline-hosted volcanogenic massive sulfide deposits of the Bonnifield District, East-Central Alaska

Volcanogenic massive sulfide (VMS) Zn-Pb-Cu-Ag-Au deposits of the Bonnifield mining district formed during Late Devonian-Early Mississippian magmatism along the western edge of Laurentia. The largest deposits, Dry Creek and WTF, have a combined resource of 5.7 million tonnes at 10% Zn, 4% Pb, 0.3% Cu, 300 grams per tonne (g/t) Ag, and 1.6 g/t Au. These polymetallic deposits are hosted in high field strength element (HFSE)- and rare-earth element (REE)-rich peralkaline (pantelleritic) metarhyolite, and interlayered pyritic argillite and mudstone of the Mystic Creek Member of the Totatlanika Schist Formation. Mystic Creek metarhyolite and alkali basalt (Chute Creek Member) constitute a bimodal pair that formed in an extensional environment. A synvolcanic peralkaline quartz porphyry containing veins of fluorite, sphalerite, pyrite, and quartz intrudes the central footwall at Dry Creek. The Anderson Mountain deposit, located ~32 km to the southwest, occurs within calc-alkaline felsic to intermediate-composition metavolcanic rocks and associated graphitic argillite of the Wood River assemblage. Felsic metavolcanic rocks there have only slightly elevated HFSEs and REEs. The association of abundant graphitic and siliceous argillite with the felsic volcanic rocks together with low Cu contents in the Bonnifield deposits suggests classification as a siliciclastic-felsic type of VMS deposit. Bonnifield massive sulfides and host rocks were metamorphosed and deformed under greenschist-facies conditions in the Mesozoic. Primary depositional textures, generally uncommon, consist of framboids, framboidal aggregates, and spongy masses of pyrite. Sphalerite, the predominant base metal sulfide, encloses early pyrite framboids. Galena and chalcopyrite accompanied early pyrite formation but primarily formed late in the paragenetic sequence. Silver-rich tetrahedrite is a minor late phase at the Dry Creek deposit. Gold and Ag are present in low to moderate amounts in pyrite from all of the deposits; electrum inclusions occur in Dry Creek sphalerite. Contents and ratios of trace elements in graphitic argillite that serve as proxies for the redox state of the bottom waters in the basin indicate that Dry Creek mineralization took place in suboxic to periodically anoxic bottom waters. Trace element data show higher contents of Tl-Mn-As in pyrite from the Anderson Mountain deposit compared to the Dry Creek or WTF deposits and thus suggest that Anderson Mountain may have formed at lower temperatures or under slightly more oxidizing conditions. No exact modern analogue for the tectonic setting of the Bonnifield VMS deposits is known, although the back-arc regions of the Okinawa Trough and Woodlark Basin satisfy the requirement for a submarine, extensional setting adjacent to a continental margin. Limited occurrences of peralkaline volcanic rocks occur in these two potential analogues, but the peralkalinity of those rocks is much less than that of the Mystic Creek Member metarhyolites in the Bonnifield district. The highly elevated trace element (e.g., Zr, Nb) contents of Mystic Creek metarhyolites suggest that a better analogue may be a submarine rifted continental margin. The calc-alkaline composition of the host rocks to the Anderson Mountain deposit suggests that mineralization there formed in a continental margin arc, outboard of the extended continental margin setting of the peralkaline-hosted Dry Creek and WTF deposits.

Alaska↗
USGS1983

Late Proterozoic island-arc complexes and tectonic belts in the southern part of the Arabian Shield, Kingdom of Saudi Arabia

Two main subdivisions of layered rocks are recognized in the southern Arabian Shield south of lat 22? N. These are an older ensimatic-arc complex, which formed 1100-800 m.y. ago, and a younger marginal-arc complex, which formed 800-690 m.y. ago. The older ensimatic-arc complex, located in the southwestern part of the Shield, includes graywacke and mafic to intermediate volcanic rocks of the essentially contemporaneous Baish, Bahah, and Jiddah groups. Although the younger arc complex is also dominantly ensimatic in character, it is also partly superimposed over the older ensimaticarc complex. The superimposed portions of the younger arc complex are represented by the Ablah, Samran, and possibly the Ararat groups. The ensimatic portion of the younger arc group is represented by the Halaban group, which was deposited to the east and northeast of the older ensimatic-arc complex. The Halaban group includes andesitic and dacitic volcanic rocks and associated clastic sedimentary rocks. The layered rocks of both arc complexes are intruded by dioritic (quartz diorite, tonalite, trondhjemite) plutonic rocks. The southern Shield is also subdivided into a number of structurally bounded, north-trending tectonic belts. Within the older ensimatic complex, three belts are recognized. From west to east, these are the Lith, Bidah, and Tayyah belts. Within these three belts, progressive facies changes indicate a gradation from deep-water facies in the south to shallow-water or-terrestrial facies in the north. The distribution of dioritic batholiths, as well as the distribution of layered-rock facies, suggests a northwest-trending axis for the older ensimatic-arc complex. The younger arc complex is present within six belts, the Makkah source papers. In Fleck and others (1980), the term 'quartz diorite' includes both tonalite and quartz diorite as defined in the International Union of Geological Sciences (IUGS) system of plutonic rock classification (Streckeisen, 1973). Initial 87Sr/86Sr ratios are not included in the appendix, but all rocks more than 660 m.y. old have initial ratios in the range 0.7021-0.7035, with only two greater than 0.7030. Thus, nothing in the Rb-Sr data suggests involvement of an older continental crust during the evolution of the southern Shield. A lead isotope study of ore minerals and potassium feldspars of the Arabian Shield by Stacey and others (1980) also suggests that no older (Archean to early Proterozoic) evolved continental-type crust underlies the southern Shield. An early summary of mapping (Schmidt and others, 1973) suggests that older sialic basement underlies the late Proterozoic layered rocks in the southern Shield. However, subsequent-mapping and the isotopic studies cited above have established that all of these rocks are of late Proterozoic age and that all rocks of the southern Shield that are more than 660 m.y. old have ensimatic or mantle isotopic characteristics. Figure 2 shows, with only two exceptions, that rocks more than 800 m.y. old are present west of the boundary separating the Tayyah and Khadra belts. The exceptions are two poorly controlled Rb-Sr ages obtained by Fleck (1980) on two quartz diorite plutons in the Malahah region (appendix 1, localities 26 and 27). Preliminary uranium-thorium zircon data of Stacey now suggest that one of these quartz diorite plutons (locality 26) has an age of approximately 640 m.y. Therefore, we prefer to discount the two dates of Fleck until further information is available. As noted earlier and as described below, most of the rocks of the southern Arabian Shield have characteristics typical of those formed in the island-arc environment by subduction-related processes. We shall refer to the group of rocks in the western part of the southern Shield, which formed from 1100 to 800 m.y. ago, as the 'older ensimatic-arc complex' and those in the eastern and northwestern parts, which formed from 800 to 690 m.y. ago, as the 'younger marginal-arc compl

Open-File Report↗
USGS2000

Geochemical investigations by the U.S. Geological Survey on uranium mining, milling, and environmental restoration

Recent research by the U.S. Geological Survey has characterized contaminant sources and identified important geochemical processes that influence transport of radionuclides from uranium mining and milling wastes. 1) Selective extraction studies indicated that alkaline earth sulfates and hydrous ferric oxides are important hosts of 226 Ra in uranium mill tailings. The action of sulfate-reducing and ironreducing bacteria on these phases was shown to enhance release of radium, and this adverse result may temper decisions to dispose of uranium mill tailings in anaerobic environments. 2) Field studies have shown that although surface-applied sewage sludge/wood chip amendments aid in revegetating pyritic spoil, the nitrogen in sludge leachate can enhance pyrite oxidation, acidification of groundwater, and the consequent mobilization of metals and radionuclides. 3) In a U.S. Environmental Protection Agencyfunded study, three permeable reactive barriers consisting of phosphate-rich material, zero-valent iron, or amorphous ferric oxyhydroxide have been installed at an abandoned uranium upgrader facility near Fry Canyon, UT. Preliminary results indicate that each of the permeable reactive barriers is removing the majority of the uranium from the groundwater. 4) Studies on the geochemistry of rare earth elements as analogues for actinides such as uranium and thorium in acid mine drainage environments indicate high mobility under acid-weathering conditions but measurable attenuation associated with iron and aluminum colloid formation. Mass balances from field and laboratory studies are being used to quantify the amount of attenuation. 5) A field study in Colorado demonstrated the use of 234 U/ 238 U isotopic ratio measurements to evaluate contamination of shallow groundwater with uranium mill effluent.

Utah↗