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USGS2017

Scenario Evaluator for Electrical Resistivity survey pre-modeling tool

Geophysical tools have much to offer users in environmental, water resource, and geotechnical fields; however, techniques such as electrical resistivity imaging (ERI) are often oversold and/or overinterpreted due to a lack of understanding of the limitations of the techniques, such as the appropriate depth intervals or resolution of the methods. The relationship between ERI data and resistivity is nonlinear; therefore, these limitations depend on site conditions and survey design and are best assessed through forward and inverse modeling exercises prior to field investigations. In this approach, proposed field surveys are first numerically simulated given the expected electrical properties of the site, and the resulting hypothetical data are then analyzed using inverse models. Performing ERI forward/inverse modeling, however, requires substantial expertise and can take many hours to implement. We present a new spreadsheet-based tool, the Scenario Evaluator for Electrical Resistivity (SEER), which features a graphical user interface that allows users to manipulate a resistivity model and instantly view how that model would likely be interpreted by an ERI survey. The SEER tool is intended for use by those who wish to determine the value of including ERI to achieve project goals, and is designed to have broad utility in industry, teaching, and research.

Groundwater↗

USGS1996

Small watershed studies: Analytical approaches for understanding ecosystem response to environmental change

Biogeochemical studies in small watersheds provide an analytical approach to understand how ecosystems respond to natural climatic variations and human-induced environmental change. Small watersheds, usually less than 5 km2, are small enough to permit characterization and understanding of ecosystem processes within relatively simple, homogeneous biological and physical settings; yet they are large enough to incorporate more complex processes and element cycles than can be studied at plot scales. Watersheds comprise discrete hydrochemical environments allowing quantification of hydrologic, element, and energy budgets. Element budgets, or mass balances, can be quantified as the difference between the mass of a solute that enters a watershed in wet and dry deposition and leaves a watershed in streamflow. Element budgets are primary tools used to investigate biogeochemical processes. Monitoring various aspects of element budgets to assess ecosystem health and stability is analogous to measuring the pulse or blood chemistry of a patient. Monitoring streamwater chemistry, basic climate, soil, and biotic variables provide a means to integrate complex biogeochemical processes and evaluate trends in water quality. Small watershed studies provide a scientific basis to develop predictive models of watershed function. Major emphases of small watershed studies include investigation of hydrologic and chemical responses to natural climate variation, anthropogenic stressors, and alternate forest-management practices. The nature and significance of biogeochemical research in small watersheds is reviewed by Moldan and Cerny (1994). The U.S. Geological Survey, U.S. Department of Agriculture Forest Service, and other federal agencies support several long-term small watershed studies to provide insight into a variety of ecosystem processes. Long-term records are essential to distinguish trends resulting from natural climatic variations or other stressors. The following sites, with noted periods of records, are examples of intensively studied forested watersheds in eastern USA supported by federal agencies: ■ Coweeta Hydrologic Laboratory, North Carolina, (1939-present), Swank and Crossley (1988). ■ Hubbard Brook Experimental Forest, New Hampshire, (1956-present), Bormann and Likens (1979). ■ Sleepers River Research Watershed, Vermont, (1958-present), Shanley et al. (1995). ■ Walker Branch Watershed, Tennessee, (1967-present), Johnson and Van Hook (1989). ■ Catoctin Mountains Research Site, Maryland, (1982-present), Rice and Bricker (1995). ■ Catskill Stream Network, New York, (1983- present), Murdoch and Stoddard (1992). ■ Panola Mountain Research Watershed, Georgia, (1985-present), Huntington et al. (1993). Small watershed studies also provide essential baseline information for understanding variations in water quality and element cycling in "pristine" ecosystems that can be used as benchmarks to evaluate anthropogenic impacts and alternate watershed management practices. This paper provides examples of how analytical tools developed through watershed research provide insight into ecosystem processes and can contribute to the management of watershed resources.

Conference Paper↗

USGS2024

The LTAR cropland Common Experiment at Lower Chesapeake Bay

The Lower Chesapeake Bay (LCB) Long-Term Agroecosystem Research (LTAR) Common Experiment (CE) located in Beltsville, MD, focuses on research of concern to producers of the major regional crops, which are corn ( Zea mays L.), soybean [ Glycine max (L.) Merr.], wheat ( Triticum aestivum L.), and various forage species. Livestock production in the region includes broiler and laying chickens ( Gallus gallus domesticus L.) and dairy and beef cattle ( Bos taurus L.). The LCB region is among the most heavily populated in the United States. Urban development pressure is high for both farms and natural areas. The need to restore Chesapeake Bay water quality is a major influence on regional agricultural practices. Conservation practices such as cover cropping, no-till agriculture, and nutrient management planning are more common in the region compared to nationally. However, farmers still face management challenges implementing practices that address water quality and the rise of herbicide-resistant weeds. Researchers at the LCB site recognize the need to protect the Chesapeake and Delaware Bays and maintain farmer profitability. The LCB CE compares a 3-year crop rotation system featuring alternative crop management (cover crop intensification, crop rotation diversification, and integrated weed management [IWM]) with a prevailing 2-year system (no cover crops and no IWM), both under continuous no-tillage, to identify the optimal balance to promote the sustainability of regional cropping systems. The LTAR LCB site provides data-driven tools and solutions to support farmers in the mid-Atlantic region.

Delaware, Maryland, New Jersey, Pennsylvania, Virg↗

USGS2009

Hepatic pathologies in the brackish water catfish (Chrysichthys nigrodigitatus) from contaminated locations of the Lagos lagoon complex

Several toxicological studies into the effects of aquatic pollutants on the liver of teleost fish exist in literature. The focus on the liver in these studies is predicated on its central nature in the scheme of biotransformation and excretion of xenobiotics following exposure in polluted water bodies. As a consequence of the latter primary role of the liver in these processes it is regarded as a predilective site for the sub lethal effects of xenobiotics on the organism usually detectable at histological level. Hepatic histopathology recorded in livers from feral populations of the brackish water catfish Chrysichthys nigrodigitatus from locations on the Lagos lagoon complex with significant anthropogenic inputs from denizen populations and industries are presented. Liver sections from sixty specimens from two locations on the Lagos lagoon complex (Badagry lagoon: 6°24'N, 2°56'E; and Lagos lagoon: 6°29'N, 3°22'E) were analysed. Observed pathologies included hydropic degeneration (58%), portal / sinusoidal congestion (33%), hepatic necrosis (26%), hemosiderosis (12%) and foci of cellular alterations (FCA's). No obvious oncologic features were observed; the presence of the hydropic Vacuolation lesion was taken as prelude to the development of neoplasms and discussed as such.

Badagry Lagoon, Lagos Lagoon↗

USGS1989

Assessing the relationship between Section 404 and wetland losses: a feasibility study

The primary objective of the Clean Water Act of 1977 (33 U.S.C. 1251) is to restore and maintain the physical, chemical, and biological integrity of the Nation's waters. Section 404 of the Act regulates the discharge of dredged or fill materials into wetlands and represents the primary Federal authority for regulation of wetland alterations. Since its inception, the Section 404 program has been controversial in regard to the extent to which it was intended to provide wetlands regulation. Section 404 requires those who wish to discharge dredged or fill material into waters of the United States, which include many wetlands, to first obtain a Federal permit. The Environmental Protection Agency (EPA) has overall responsibility for administration of the Section 404 program and promulgates guidelines that must be followed in issuing permits. In addition, EPA has the final authority to prohibit specific discharges if the environmental impacts are unacceptable. The U.S. Army Corps of Engineers (Corps) issues Section 404 permits, which can be of two types. Individual Permits are issued following case-by-case reviews of proposed discharges. General Permits, which can be either nationwide or regional in scope, are authorized by the Corps for categories of activities that are similar in nature and that have only minimal individual and cumulative adverse environmental impacts. EPA, the National Marine Fisheries Service (NMFS), the Fish and Wildlife Service (Service), and State natural resource agencies review and comment on permit applications and offer recommendations on appropriate mitigation measures. Although comments from the Service and other natural resource agencies are advisory in nature (EPA's veto authority excepted), they can serve as the basis for modifying, conditioning, or denying a Section 404 permit. In 1986, in a survey conducted by the National Ecology Research Center, Service personnel indicated interest in additional information concerning both wetland trends and the impacts of activities authorized by the Corps under Section 404 (Roelle 1986). Although there is some information concerning wetland losses for certain geographic areas and for the Nation as a whole (Frayer et al. 1983; Tiner 1984), there appears to be little information on how these losses relate to the Section 404 permitting process. The primary objective of this study was to determine the feasibility of estimating wetland losses in relationship to Individual and General Permits issued under Section 404. A secondary objective was to assemble data on acceptance and implementation of specific mitigation recommendations offered by the Service and other natural resource agencies in connection with development activities on wetlands examined. At present, 26 categories of Nationwide permits have been authorized by the Corps. Nationwide permit 26 was of particular interest in this study because it specifically authorizes discharges into wetlands under certain circumstances (see Figure 1 and related text for a more complete discussion of circumstances under which Nationwide Permit 26 is applicable). All subsequent references to Nationwide or General permits pertain to Nationwide Permit 26.

Report↗

USGS1978

Natural radioactivity in geothermal waters, Alhambra Hot Springs and nearby areas, Jefferson County, Montana

Radioactive hot springs issue from a fault zone in crystalline rock of the Boulder batholith at Alhambra, Jefferson County, in southwestern Montana. The discharge contains high concentrations of radon, and the gross alpha activity and the concentration of adium-226 exceed maximum levels recommended by the Environmental Protection Agency for drinking water. Part of the discharge is diverted for space heating, bathing, and domestic use. The radioactive thermal waters at measured temperatures of about 60°C are of the sodium bicarbonate type and saturated with respect to calcium carbonate. Radium-226 in the rock and on fractured surfaces or coprecipitated with calcium carbonate probably is the principal source of radon that is dissolved in the thermal water and discharged with other gases from some wells and springs. Local surface water and shallow ground water are of the calcium bicarbonate type and exhibit low background activity. The temperature, percent sodium, and radioactivity of mixed waters adjacent to the fault zone increase with depth. Samples from most of the major hot springs in southwestern Montana have been analyzed for gross alpha and beta activity. The high level of radioactivity at Alhambra appears to be related to leaching of radioactive material from siliceous veins by ascending thermal waters and is not a normal characteristic of hot springs issuing from fractured crystalline rock in Montana.

Montana↗

USGS2018

Limited nitrate retention capacity in the Upper Mississippi River

The Mississippi River and other large rivers have the potential to regulate nitrogen export from terrestrial landscapes, and thus mitigate eutrophication in downstream aquatic ecosystems. In large rivers, human-constructed impoundments and connected backwaters may facilitate nitrogen removal; however, the capacity of these features is poorly quantified and incompletely incorporated into model frameworks. Using a high-resolution and spatially intensive sampling technique, we assessed the contribution of individual navigation pools, as well as impounded open waters and backwater wetlands within them, to overall nitrate retention by mapping the entire length (1370 km) of the Upper Mississippi River (UMR) main channel. Based on this single spatial survey of water chemistry, the river appeared to act primarily as a passive nitrate transporter, retaining only 12.5% of the incoming load, most of which occurred in the upper 150 km of the river, which includes the largest and only naturally impounded reach of the river. Although reservoirs typically are nitrogen sinks, our data indicate that UMR dams do not impede river flows to the extent necessary to promote substantial changes in water residence times and subsequent nitrogen removal. Backwaters routinely had lower nitrate concentrations than the main channel, but their limited hydrologic connectivity to the through-flowing river channel constrained their influence on downstream export. As a whole, the UMR did not remove a substantial proportion of its nitrate load despite optimal N removal conditions, numerous impoundments, and the presence of extensive backwater habitats. These results suggest that efforts to reduce delivery of nitrogen to the Gulf of Mexico should emphasize mitigation strategies that target upland nutrient sources rather than relying on removal within the Mississippi River.

Upper Mississippi River↗

USGS2014

Response of plant community structure and primary productivity to experimental drought and flooding in an Alaskan fen

Northern peatlands represent a long-term net sink for atmospheric CO 2 , but these ecosystems can shift from net carbon (C) sinks to sources based on changing climate and environmental conditions. In particular, changes in water availability associated with climate control peatland vegetation and carbon uptake processes. We examined the influence of changing hydrology on plant species abundance and ecosystem primary production in an Alaskan fen by manipulating the water table in field treatments to mimic either sustained flooding (raised water table) or drought (lowered water table) conditions for 6 years. We found that water table treatments altered plant species abundance by increasing sedge and grass cover in the raised water table treatment and reducing moss cover while increasing vascular green area in the lowered water table treatment. Gross primary productivity was lower in the lowered treatment than in the other plots, although there were no differences in total biomass or vascular net primary productivity among the treatments. Overall, our results indicate that vegetation abundance was more sensitive to variation in water table than total biomass and vascular biomass accrual. Finally, in our experimental peatland, drought had stronger consequences for change in vegetation abundance and ecosystem function than sustained flooding.

Alaska↗

USGS2009

Integrating scientific knowledge into large-scale restoration programs: the CALFED Bay-Delta Program experience

Integrating science into resource management activities is a goal of the CALFED Bay-Delta Program, a multi-agency effort to address water supply reliability, ecological condition, drinking water quality, and levees in the Sacramento-San Joaquin Delta of northern California. Under CALFED, many different strategies were used to integrate science, including interaction between the research and management communities, public dialogues about scientific work, and peer review. This paper explores ways science was (and was not) integrated into CALFED's management actions and decision systems through three narratives describing different patterns of scientific integration and application in CALFED. Though a collaborative process and certain organizational conditions may be necessary for developing new understandings of the system of interest, we find that those factors are not sufficient for translating that knowledge into management actions and decision systems. We suggest that the application of knowledge may be facilitated or hindered by (1) differences in the objectives, approaches, and cultures of scientists operating in the research community and those operating in the management community and (2) other factors external to the collaborative process and organization.

Environmental Science and Policy↗

USGS2017

Advancements in hydrochemistry mapping: methods and application to groundwater arsenic and iron concentrations in Varanasi, Uttar Pradesh, India

The area east of Varanasi is one of numerous places along the watershed of the Ganges River with groundwater concentrations of arsenic surpassing the maximum value of 10 parts per billion (ppb) recommended by the World Health Organization in drinking water. Here we apply geostatistics and compositional data analysis for the mapping of arsenic and iron to help in understanding the conditions leading to the occurrence of elevated level of arsenic in groundwater. The methodology allows for displaying concentrations of arsenic and iron as maps consistent with the limited information from 95 water wells across an area of approximately 210 km 2 ; visualization of the uncertainty associated with the sampling; and summary of the findings in the form of probability maps. For thousands of years, Varanasi has been on the erosional side in a meander of the river that is free of arsenic values above 10 ppb. Maps reveal two anomalies of high arsenic concentrations on the depositional side of the valley, which has started seeing urban development. The methodology using geostatistics combined with compositional data analysis is completely general, so this study could be used as a prototype for hydrochemistry mapping in other areas.

Uttar Pradesh↗

USGS2022

Protocols for collecting and processing macroinvertebrates from the benthos and water column in depressional wetlands

Freshwater aquatic macroinvertebrates are key links in food webs and nutrient cycles, and thus often serve as biological indicators of ecosystem health. Macroinvertebrate investigations in research and monitoring require consistent and reliable field and laboratory procedures. Comprehensive standard operating procedures for sampling macroinvertebrates from depressional wetlands, which can range from riverine floodplain lakes to wetlands of any size and hydrologic regime, remain relatively sparse. This report provides step-by-step protocols for efficient use of time and resources while collecting and processing aquatic macroinvertebrate samples; for example, a single wetland can typically be field surveyed in less than 1 hour, and the samples can be processed in the laboratory in less than 2 hours. Samples can be collected from inside a motorboat or canoe or while wading. This procedures manual describes dip netting to collect macroinvertebrates from the wetland bottom and water column separately to facilitate investigations of habitat use by species occupying different areas of the wetland. This report also provides descriptive supplemental materials and data sheets to assist with the preparation of survey maps, the acquisition of field and laboratory equipment, and the calculation of macroinvertebrate densities from the wetland bottom and water column. These procedures can be applied to most macroinvertebrate species and communities that inhabit a variety of wetland sizes and types. Uses and applications can range from elementary and secondary environmental education to rigorous scientific evaluations of community abundance, diversity, distribution, or species-habitat relations.

Open-File Report↗

USGS2022

Analysis of surface water trends for the conterminous United States using MODIS satellite data, 2003–2019

Satellite imagery is commonly used to map surface water extents over time, but many approaches yield discontinuous records resulting from cloud obstruction or image archive gaps. We applied the Dynamic Surface Water Extent (DSWE) model to downscaled (250-m) daily Moderate Resolution Imaging Spectroradiometer (MODIS) data in Google Earth Engine to generate monthly surface water maps for the conterminous United States (US) from 2003 through 2019. The aggregation of daily observations to monthly maps of maximum water extent produced records with diminished cloud and cloud shadow effects across most of the country. We used the continuous monthly record to analyze spatiotemporal surface water trends stratified within Environmental Protection Agency Ecoregions. Although not all ecoregion trends were significant ( p < 0.05), results indicate that much of the western and eastern US underwent a decline in surface water over the 17-year period, while many ecoregions in the Great Plains had positive trends. Trends were also generated from monthly streamgage discharge records and compared to surface water trends from the same ecoregion. These approaches agreed on the directionality of trend detected for 54 of 85 ecoregions, particularly across the Great Plains and portions of the western US, whereas trends were not congruent in select western deserts, the Great Lakes region, and the southeastern US. By describing the geographic distribution of surface water over time and comparing these records to instrumented discharge data across the conterminous US, our findings demonstrate the efficacy of using satellite imagery to monitor surface water dynamics and supplement traditional instrumented monitoring.

Water Resources Research↗

USGS2016

Biomass offsets little or none of permafrost carbon release from soils, streams, and wildfire: an expert assessment

As the permafrost region warms, its large organic carbon pool will be increasingly vulnerable to decomposition, combustion, and hydrologic export. Models predict that some portion of this release will be offset by increased production of Arctic and boreal biomass; however, the lack of robust estimates of net carbon balance increases the risk of further overshooting international emissions targets. Precise empirical or model-based assessments of the critical factors driving carbon balance are unlikely in the near future, so to address this gap, we present estimates from 98 permafrost-region experts of the response of biomass, wildfire, and hydrologic carbon flux to climate change. Results suggest that contrary to model projections, total permafrost-region biomass could decrease due to water stress and disturbance, factors that are not adequately incorporated in current models. Assessments indicate that end-of-the-century organic carbon release from Arctic rivers and collapsing coastlines could increase by 75% while carbon loss via burning could increase four-fold. Experts identified water balance, shifts in vegetation community, and permafrost degradation as the key sources of uncertainty in predicting future system response. In combination with previous findings, results suggest the permafrost region will become a carbon source to the atmosphere by 2100 regardless of warming scenario but that 65%–85% of permafrost carbon release can still be avoided if human emissions are actively reduced.

Environmental Research Letters↗

USGS2018

Geochemistry of groundwater in the eastern Snake River Plain aquifer, Idaho National Laboratory and vicinity, eastern Idaho

Nuclear research activities at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) in eastern Idaho produced radiochemical and chemical wastes that were discharged to the subsurface, resulting in detectable concentrations of some waste constituents in the eastern Snake River Plain (ESRP) aquifer. These waste constituents may pose risks to the water quality of the aquifer. In order to understand these risks to water quality the U.S. Geological Survey, in cooperation with the DOE, conducted a study of groundwater geochemistry to improve the understanding of hydrologic and chemical processes in the ESRP aquifer at and near the INL and to understand how these processes affect waste constituents in the aquifer. Geochemistry data were used to identify sources of recharge, mixing of water, and directions of groundwater flow in the ESRP aquifer at the INL. The geochemistry data were analyzed from 167 sample sites at and near the INL. The sites included 150 groundwater, 13 surface-water, and 4 geothermal-water sites. The data were collected between 1952 and 2012, although most data collected at the INL were collected from 1989 to 1996. Water samples were analyzed for all or most of the following: field parameters, dissolved gases, major ions, dissolved metals, isotope ratios, and environmental tracers. Sources of recharge identified at the INL were regional groundwater, groundwater from the Little Lost River (LLR) and Birch Creek (BC) valleys, groundwater from the Lost River Range, geothermal water, and surface water from the Big Lost River (BLR), LLR, and BC. Recharge from the BLR that may have occurred during the last glacial epoch, or paleorecharge, may be present at several wells in the southwestern part of the INL. Mixing of water at the INL primarily included mixing of surface water with groundwater from the tributary valleys and mixing of geothermal water with regional groundwater. Additionally, a zone of mixing between tributary valley water and regional groundwater, trending southwesterly, extended from near the northeastern boundary of the INL to the southern boundary of the INL. Groundwater flow directions for regional groundwater were southwesterly, and flow directions for tributary groundwater were southeasterly upon entering the ESRP, but eventually began to flow southwesterly in a direction parallel with regional groundwater. Several discrepancies were identified from comparison of sources of recharge determined from geochemistry data and backward particle tracking with a groundwater-flow model. Some discrepancies observed in the particle tracking results included representation of recharge from BC near the north INL boundary, groundwater from the BC valley not extending far enough south, regional groundwater that extends too far west in the southern part of the INL, and no representation of recharge from geothermal water in model layer 1 or recharge from the BLR in the southwestern part of the INL.

Idaho↗

USGS2021

Hierarchical clustering for paired watershed experiments: Case study in southeastern Arizona, U.S.A.

Watershed studies are often onerous due to a lack of data available to portray baseline conditions with which to compare results of monitoring environmental effects. A paired-watershed approach is often adopted to simulate baseline conditions in an adjacent watershed that can be comparable but assumes there is a quantifiable relationship between the control and treated watersheds. Finding suitably matched pairs that can most accurately depict similar responses is challenging and attributes are rarely quantified. In southeastern Arizona, United States, researchers are investigating the effectiveness of watershed restoration techniques employed by land managers. We selected Smith Canyon to develop a rigorous and quantitatively defensible paired-watershed experimental design. The Smith Canyon watershed consists of 91 structurally similar sub-basins that have a defined basin-like structure and flow channel, allowing for consideration as replicate units. We developed a statistical approach to group sub-basins based on similar structural, biophysical, and hydrologic traits. Our geospatial database consisted of 35 environmental variables, which we reduced to 12 through a correlation analysis. We identified three primary collections of paired sub-basins within the larger watershed. These clusters are being used to inform studies actively being employed in the watershed. Overall, we propose a hierarchical clustering protocol for justification of watershed pairing experiments.

Arizona↗

USGS2014

Mass loads of dissolved and particulate mercury and other trace elements in the Mt. Amiata mining district, Southern Tuscany (Italy)

Total dissolved and particulate mercury (Hg), arsenic (As), and antimony (Sb) mass loads were estimated in different seasons (March and September 2011 and March 2012) in the Paglia River basin (PRB) (central Italy). The Paglia River drains the Mt. Amiata Hg district, one of the largest Hg-rich regions worldwide. Quantification of Hg, As, and Sb mass loads in this watershed allowed (1) identification of the contamination sources, (2) evaluation of the effects of Hg on the environment, and (3) determination of processes affecting Hg transport. The dominant source of Hg in the Paglia River is runoff from Hg mines in the Mt. Amiata region. The maximum Hg mass load was found to be related to runoff from the inactive Abbadia San Salvatore Mine (ASSM), and up to 30 g day −1 of Hg, dominantly in the particulate form, was transported both in high and low flow conditions in 2011. In addition, enrichment factors (EFs) calculated for suspended particulate matter (SPM) were similar in different seasons indicating that water discharge controls the quantities of Hg transported in the PRB, and considerable Hg was transported in all seasons studied. Overall, as much as 11 kg of Hg are discharged annually in the PRB and this Hg is transported downstream to the Tiber River, and eventually to the Mediterranean Sea. Similar to Hg, maximum mass loads for As and Sb were found in March 2011, when as much as 190 g day −1 each of As and Sb were measured from sites downstream from the ASSM. Therefore, the Paglia River represents a significant source of Hg, Sb, and As to the Mediterranean Sea.

Tuscany↗

USGS2014

Agricultural conversion without external water and nutrient inputs reduces terrestrial vegetation productivity

Driven by global population and standard of living increases, humanity co-opts a growing share of the planet's natural resources resulting in many well-known environmental trade-offs. In this study, we explored the impact of agriculture on a resource fundamental to life on Earth: terrestrial vegetation growth (net primary production; NPP). We demonstrate that agricultural conversion has reduced terrestrial NPP by ~7.0%. Increases in NPP due to agricultural conversion were observed only in areas receiving external inputs (i.e., irrigation and/or fertilization). NPP reductions were found for ~88% of agricultural lands, with the largest reductions observed in areas formerly occupied by tropical forests and savannas (~71% and ~66% reductions, respectively). Without policies that explicitly consider the impact of agricultural conversion on primary production, future demand-driven increases in agricultural output will likely continue to drive net declines in global terrestrial productivity, with potential detrimental consequences for net ecosystem carbon storage and subsequent climate warming.

Geophysical Research Letters↗

USGS2008

A national reconnaissance of pharmaceuticals and other organic wastewater contaminants in the United States - I) Groundwater

As part of the continuing effort to collect baseline information on the environmental occurrence of pharmaceuticals, and other organic wastewater contaminants (OWCs) in the Nation's water resources, water samples were collected from a network of 47 groundwater sites across 18 states in 2000. All samples collected were analyzed for 65 OWCs representing a wide variety of uses and origins. Site selection focused on areas suspected to be susceptible to contamination from either animal or human wastewaters (i.e. down gradient of a landfill, unsewered residential development, or animal feedlot). Thus, sites sampled were not necessarily used as a source of drinking water but provide a variety of geohydrologic environments with potential sources of OWCs. OWCs were detected in 81% of the sites sampled, with 35 of the 65 OWCs being found at least once. The most frequently detected compounds include N , N -diethyltoluamide (35%, insect repellant), bisphenol A (30%, plasticizer), tri(2-chloroethyl) phosphate (30%, fire retardant), sulfamethoxazole (23%, veterinary and human antibiotic), and 4-octylphenol monoethoxylate (19%, detergent metabolite). Although sampling procedures were intended to ensure that all groundwater samples analyzed were indicative of aquifer conditions it is possible that detections of some OWCs could have resulted from leaching of well-construction materials and/or other site-specific conditions related to well construction and materials. Future research will be needed to identify those factors that are most important in determining the occurrence and concentrations of OWCs in groundwater.

Science of the Total Environment↗