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Ground-water problems in the Philadelphia area [Pennsylvania]

Large quantities of ground water are used by the Philadelphia Naval Base and many industries in south Philadelphia, as well as by municipalities near Philadelphia in both Pennsylvania and New Jersey. The areal contact between unconsolidated sand, gravel, and clay strata of the Atlantic Coastal Plain and consolidated rocks of the Piedmont province extends in a northeast-southwest line through central Philadelphia. This line of contact, the so-called Fall Line, sharply separates the area of highly productive sand and gravel aquifers of the Coastal Plain from the less productive bedrock aquifers of the Piedmont Plateau. The daily withdrawal of ground water from sand and gravel in the Philadelphia area, including Bristol, Pa., and Trenton, N. J., is approximately 110 million gallons. Wells around Philadelphia yield an additional 13 million gallons a day from consolidated rocks of the Piedmont province. The Raritan formation of Cretaceous age is the principal aquifer for wells in south Philadelphia and the adjacent Camden area. The large quantity of water pumped and the limited extent of this aquifer in the area provide a potentially serious interstate water problem. Ground-water levels in the strategically important Naval Base area have not declined seriously as yet, but increasing withdrawal planned in adjacent New Jersey is expected to lower water levels in south Philadelphia The Delaware and Schuylkill Rivers are believed to be the chief sources of recharge to the Raritan formation, even though heavy pumping on either side of the Delaware River may be expected to affect water levels on the other side. Recharge appears to be adequate generally for present rates of withdrawal, but further studies are needed for an evaluation of the safe maximum yield of the area. The chemical quality of ground water pumped from the Raritan formation is satisfactory for most purposes, but periodic analyses indicate that the concentration of dissolved solids is increasing. This deterioration of the chemical quality probably is due to the character of the water and bottom sediments of the Delaware and Schuylkill Rivers. Shallow aquifers in south Philadelphia contain large amounts of gases generated by the decay of river silts and city refuse occupying low areas. The States of Pennsylvania and New Jersey, together with the municipalities concerned, are coordinating their efforts for a practical solution to the ground-water problems of the Philadelphia area.

Pennsylvania↗

Numerical simulation of ground-water flow in La Crosse County, Wisconsin, and into nearby pools of the Mississippi River

This report describes a two-dimensional regional screening model and two associated three-dimensional ground-water flow models that were developed to simulate the ground-water flow systems in La Crosse County, Wisconsin, and Pool 8 of the Mississippi River. Although the geographic extents of the three-dimensional models were slightly different, both were derived from the same geologic interpretation and regional screening model, and their calibrations were performed concurrently. The objectives of the La Crosse County (LCC) model were to assess the effects of recent (1990s) and potential future ground-water withdrawals and to provide a tool suitable to evaluate the effects of proposed water-management programs. The Pool 8 model objectives were to quantify the magnitude and distribution of ground-water flow into the Pool. The Wisconsin Geological and Natural History Survey and the U.S. Geological Survey developed the models cooperatively. The report describes: 1) the conceptual hydrogeologic model; 2) the methods used in simulating flow; 3) model calibration and sensitivity analysis; and 4) model results, such as simulation of predevelopment conditions and location and magnitude of ground-water discharge into Pool 8 of the Mississippi. Three aquifer units underlie the model area: 1) a shallow unconsolidated sand and gravel aquifer; 2) an upper bedrock aquifer, composed of Cambrian and Ordovician sandstone and dolomite; and 3) a lower bedrock aquifer composed of Cambrian sandstone of the Eau Claire Formation and the Mount Simon Formation. A shale layer that is part of the Eau Claire Formation forms a confining unit separating the upper and lower bedrock aquifers. This confining unit is absent in the Black River and parts of the La Crosse and Mississippi River valleys. Precambrian crystalline basement rock forms the lower base of the ground-water flow system. The U.S. Geological Survey ground-water flow model code, MODFLOW, was used to develop the La Crosse County (LCC) and Pool 8 ground-water flow models. Boundary conditions for the MODFLOW model were extracted from an analytic element screening model of the regional flow system surrounding La Crosse County. Model input was obtained from previously published and unpublished geologic and hydrologic data. Pumpages from municipal and high-capacity wells were also simulated. Model calibration included a comparison of modeled and field-measured water levels and field-measured base flows to simulated stream flows. At calibration, most measured water levels compared favorably to model-calculated water levels. Simulated streamflows at two targets were within 3 percent of estimated measured base flows. Mass balance results from the LCC and Pool 8 models indicated that 63 to 74 percent of ground water was from recharge and 19 to 26 percent was from surface-water sources. Ground-water flow out of the model was to rivers and streams (85 to 87 percent) and pumping wells (11 and 13 percent). The model demonstrates the effects of development on ground water in the study area. The maximum simulated water-level decline in the city of La Crosse metropolitan area is 9.3 feet. Simulated stream losses are similar to the amount of ground water pumped by wells. This indicates that ground water withdrawn by La Crosse County wells is water that under predevelopment conditions discharged to streams and lakes. The models provide estimates of the locations and amount of ground-water flow into Pool 8 and the southern portion of Pool 7 of the Mississippi River. Ground-water discharges into all areas of the pools, except along the eastern shore in the vicinity of the city of La Crosse and immediately downgradient from lock and dam 7 and 8. Ground-water flow into the pools is generally greatest around the perimeter with decreasing amounts away from the perimeter. An area of relatively high ground-water discharge extends out towards the center of Pool 7 from the upper reaches of the pool and may

Wisconsin↗

Hydrogeologic investigation and simulation of ground-water flow in the Upper Floridan Aquifer of north-central Florida and southwestern Georgia and delineation of contributing areas for selected city of Tallahassee, Florida, water-supply wells

A 4-year investigation of the Upper Floridan aquifer and ground-water flow system in Leon County, Florida, and surrounding counties of north-central Florida and southwestern Georgia began in 1990. The purpose of the investigation was to describe the ground-water flow system and to delineate the contributing areas to selected City of Tallahassee, Florida, water-supply wells. The investigation was prompted by the detection of low levels of tetrachloroethylene in ground-water samples collected from several of the city's water-supply wells. Hydrologic data and previous studies indicate that; ground-water flow within the Upper Floridan aquifer can be considered steady-state; the Upper Floridan aquifer is a single water-bearing unit; recharge is from precipitation; and that discharge occurs as spring flow, leakage to rivers, leakage to the Gulf of Mexico, and pumpage. Measured transmissivities of the aquifer ranged from 1,300 ft 2 /d (feet squared per day) to 1,300,000 ft2/d. Steady-state ground-water flow in the Upper Floridan aquifer was simulated using a three-dimensional ground- water flow model. Transmissivities ranging from less than 5,000 ft2/d to greater than 11,000,000 ft 2 /d were required to calibrate to observed conditions. Recharge rates used in the model ranged from 18.0 inches per year in areas where the aquifer was unconfined to less than 2 inches per year in broad areas where the aquifer was confined. Contributing areas to five Tallahassee water-supply wells were simulated by particle- tracking techniques. Particles were seeded in model cells containing pumping wells then tracked backwards in time toward recharge areas. The contributing area for each well was simulated twice, once assuming a porosity of 25 percent and once assuming a porosity of 5 percent. A porosity of 25 percent is considered a reasonable average value for the Upper Floridan aquifer; the 5 percent porosity simulated the movement of ground-water through only solution-enhanced bedding plains and fractures. The contributing areas were generally elliptical in shape, reflecting the influence of the sloping potentiometric surface. The contributing areas delineated for a 5 percent porosity were always much larger than those determined using a 25 percent porosity. The lowest average ground-water velocity computed within a contributing area, using a 25 percent porosity, was 1.0 ft/d (foot per day) and the highest velocity was 1.6 ft/d. The lowest average ground-water velocity, determined using a 5 percent porosity, was 2.4 ft/d and the highest was 7.4 ft/d. The contributing areas for each of the five wells was also determined analytically and compared to the model-derived areas. The upgradient width of the simulated contributing areas were larger than the upgradient width of the analytically determined contributing areas for four of the five wells. The model could more accurately delineate contributing areas because of the ability to simulate wells as partially penetrating and by incorporating complex, three-dimensional aquifer characteristics, which the analytical method could not.

Florida, Georgia↗

Quantifying time-varying ground-water discharge and recharge in wetlands of the northern Florida Everglades

Developing a more thorough understanding of water and chemical budgets in wetlands depends in part on our ability to quantify time-varying interactions between ground water and surface water. We used a combined water and solute mass balance approach to estimate time-varying ground-water discharge and recharge in the Everglades Nutrient Removal project (ENR), a relatively large constructed wetland (1544 hectare) built for removing nutrients from agricultural drainage in the northern Everglades in South Florida, USA. Over a 4-year period (1994 through 1998), ground-water recharge averaged 13.4 hectare-meter per day (ha-m/day) or 0.9 cm/day, which is approximately 31% of surface water pumped into the ENR for treatment. In contrast, ground-water discharge was much smaller (1.4 ha-m/day, or 0.09 cm/day, or 2.8% of water input to ENR for treatment). Using a water-balance approach alone only allowed net ground-water exchange (discharge — recharge) to be estimated (−12±2.4 ha-m/day). Discharge and recharge were individually determined by combining a chloride mass balance with the water balance. For a variety of reasons, the ground-water discharge estimated by the combined mass balance approach was not reliable (1.4±37 ha-m/day). As a result, ground-water interactions could only be reliably estimated by comparing the mass-balance results with other independent approaches, including direct seepage-meter measurements and previous estimates using ground-water modeling. All three independent approaches provided similar estimates of average ground-water recharge, ranging from 13 to 14 ha-m/day. There was also relatively good agreement between ground-water discharge estimates for the mass balance and seepage meter methods, 1.4 and 0.9 ha-m/day, respectively. However, ground-water-flow modeling provided an average discharge estimate that was approximately a factor of four higher (5.4 ha-m/day) than the other two methods. Our study developed an initial understanding of how the design and operation of the ENR increases interactions between ground water and surface water. A considerable portion of recharged ground water (73%) was collected and returned to the ENR by a seepage canal. Additional recharge that was not captured by the seepage canal only occurred when pumped inflow rates to ENR (and ENR water levels) were relatively high. Management of surface water in the northern Everglades therefore clearly has the potential to increase interactions with ground water.

Florida↗

Geochemistry of ground water in alluvial basins of Arizona and adjacent parts of Nevada, New Mexico, and California

Chemical and isotope analyses of ground water from 28 basins in the Basin and Range physiographic province of Arizona and parts of adjacent States were used to evaluate ground-water quality, determine processes that control ground-water chemistry, provide independent insight into the hydrologic flow system, and develop information transfer. The area is characterized by north- to northwest-trending mountains separated by alluvial basins that form a regional topography of alternating mountains and valleys. On the basis of ground-water divides or zones of minimal basin interconnection, the area was divided into 72 basins, each representing an individual aquifer system. These systems are joined in a dendritic pattern and collectively constitute the major water resource in the region. Geochemical models were developed to identify reactions and mass transfer responsible for the chemical evolution of the ground water. On the basis of mineralogy and chemistry of the two major rock associations of the area, a felsic model and a mafic model were developed to illustrate geologic, climatic, and physiographic effects on ground-water chemistry. Two distinct hydrochemical processes were identified: (1) reactions of meteoric water with minerals and gases in recharge areas and (2) reactions of ground water as it moves down the hydraulic gradient. Reactions occurring in recharge and downgradient areas can be described by a 13-component system. Major reactions are the dissolution and precipitation of calcite and dolomite, the weathering of feldspars and ferromagnesian minerals, the formation of montmorillonite, iron oxyhydroxides, and probably silica, and, in some basins, ion exchange. The geochemical modeling demonstrated that relatively few phases are required to derive the ground-water chemistry; 14 phases-12 mineral and 2 gas-consistently account for the chemical evolution in each basin. The final phases were selected through analysis of X-ray diffraction and fluorescence data, aqueous speciation and saturation data, and mass-balance and isotopic constraints and through chemical models developed from mineral combinations among the 27 phases that were considered realistic in these geologically and mineralogically complex basins. X-ray diffraction of basin-fill sediments confirm the presence of the postulated minerals and their weathering sequences. High partial pressures of soil CO2 and large concentrations of dissolved CO2 in recharge areas, and the rapid depletion of CO2 downgradient, accompanied by high weathering rates of the silicates which also decrease downgradient, indicate that carbonic acid is the impetus in the weathering process. Reactions in the soil zone and the unsaturated zone are influential and, in some instances, are as important as the mineralogy of the source rock in determining ground-water compositions. The basins can be divided geochemically into two general categories-closed systems, which evolve under closed hydrologic conditions, and open systems, which are open to CO2 and other constituents along the flow path. The ground-water chemistry of the unconfined aquifers in the eastern part of the study area and of the aquifers underlying the flood plain along the Colorado River generally evolves under open conditions. The ground-water chemistry of most basins in the central and western parts and of the confined aquifers in the eastern part evolves under closed conditions. The factors that determine whether a basin is an open or closed system are the amount of and the spatial and seasonal distribution of annual precipitation and the presence or absence of fine-grained confining units. The basins along the Colorado River are unique among basins in the region. Virtually all ground water underlying the flood plain originated as seepage or overbank flow from the Colorado River. Initial deuterium content of about -120 per mil is indicative of precipitation from the central part of Colorado. Using chemical m

Professional Paper↗

Ground-water resources and simulated effects of withdrawals in the Bountiful area, Utah

Ground-water resources in the Bountiful area, Utah, were studied to document changes in ground-water conditions and to simulate the effects of increased ground-water withdrawals and changes in recharge. The aquifer system is in basin-fill deposits and is primarily a confined system with unconfined parts along the mountain front. Recharge to the aquifer system was estimated to range from about 22,000 to 32,000 acre-feet per year during 1947-85. Discharge was estimated to range from 26,000 to 30,000 acre-feet per year during 1947-85. Long-term trends of ground-water levels indicate a steady decline at most observation wells from 1952 to 1962. Importation of surface water for irrigation in 1962 resulted in decreased ground-water withdrawals, causing water levels to rise. Water levels fluctuated from 1962 to 1985, depending on changes in withdrawals and precipitation. A computer model of the aquifer system was constructed and calibrated using water-level data from 1946 and changes in ground-water withdrawals from 1947-86. Simulations of aquifer responses to projected withdrawals were based on a 50-percent increase in the 1981-85 rate of municipal and industrial withdrawals for 20 years using both average and less-than-average recharge rates. The simulations indicated water-level declines between 5 and 50 feet; a decrease in natural discharge to drains, by evapotranspiration, and to Great Salt Lake; and a decrease of ground water in storage after 20 years between 25,000 acre-feet using the average recharge rate, and 70,000 acre-feet using the less-than-average recharge rate.

Utah↗

Availability of ground water in the area surrounding the Trident submarine construction facility, Kitsap County, Washington

This report provides general information on the water resources--with emphasis on ground-water occurrence and availability--in that part of Kitsap County (referred to as Trident Impact Area) that would be most affected by the development of the Trident submarine-construction facility at Bangor. Ground water occurs principally in a lower, confined aquifer near and below sea level and an upper, unconfined aquifer above sea level; both aquifers are extensive beneath the study area and are composed of sand and gravel layers separated by poorly permeable silt, clay, and till layers. Locally throughout the area efficiently constructed wells tapping each of the two aquifers are capable of yielding 100 to 1,300 or more gallons per minute. The estimated 1970 water use in the study area averaged about 13 million gal/day (gallons per day); of this amount about 9 million gal/day came from surface-water sources--from a large reservoir outside the study area--and about 4 million gal/day came from ground water pumped from the two aquifers. Anticipated water use soon will be about 18 to 21 million gal/day; virtually all the additional quantity required (about 5 to 8 million gal/day) above present use must come from ground-water sources. Preliminary evaluation of the aquifers suggests that an additional 1.5 million gal/day can be developed from the upper aquifer and 7 million gal/day from the lower aquifer. Existing wells tapping the lower aquifer might yield additional water and increase the total yield in the area by 3.5 million gal/day, and new wells drilled in selected areas could produce an additional 3.5 million gal/day from this aquifer. However, additional, large-scale ground-water withdrawal from the lower aquifer could induce saltwater intrusion into wells situated in coastal areas. Recommended future studies include additional data collection, monitoring of chloride concentrations in water from large-yield coastal wells, confirmation of well yields and capacities, and test-well drilling and analysis.

Washington↗

Ground-water quality data in the Monterey Bay and Salinas Valley Basins, California, 2005— Results from the California GAMA program

Ground-water quality in the approximately 1,000-square-mile Monterey Bay and Salinas Valley study unit was investigated from July through October 2005 as part of the California Ground-Water Ambient Monitoring and Assessment (GAMA) program. The study was designed to provide a spatially unbiased assessment of raw ground-water quality, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 94 public-supply wells and 3 monitoring wells in Monterey, Santa Cruz, and San Luis Obispo Counties. Ninety-one of the public-supply wells sampled were selected to provide a spatially distributed, randomized monitoring network for statistical representation of the study area. Six wells were sampled to evaluate changes in water chemistry: three wells along a ground-water flow path were sampled to evaluate lateral changes, and three wells at discrete depths from land surface were sampled to evaluate changes in water chemistry with depth from land surface. The ground-water samples were analyzed for volatile organic compounds (VOCs), pesticides, pesticide degradates, nutrients, major and minor ions, trace elements, radioactivity, microbial indicators, and dissolved noble gases (the last in collaboration with Lawrence Livermore National Laboratory). Naturally occurring isotopes (tritium, carbon-14, helium-4, and the isotopic composition of oxygen and hydrogen) also were measured to help identify the source and age of the sampled ground water. In total, 270 constituents and water-quality indicators were investigated for this study. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain water quality. In addition, regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. In this study, only six constituents, alpha radioactivity, N-nitrosodimethylamine, 1,2,3-trichloropropane, nitrate, radon-222, and coliform bacteria were detected at concentrations higher than health-based regulatory thresholds. Six constituents, including total dissolved solids, hexavalent chromium, iron, manganese, molybdenum, and sulfate were detected at concentrations above levels set for aesthetic concerns. One-third of the randomized wells sampled for the Monterey Bay and Salinas Valley GAMA study had at least a single detection of a VOC or gasoline additive. Twenty-eight of the 88 VOCs and gasoline additives investigated were found in ground-water samples; however, detected concentrations were one-third to one-sixty-thousandth of their respective regulatory thresholds. Compounds detected in 10 percent or more of the wells sampled include chloroform, a compound resulting from the chlorination of water, and tetrachloroethylene (PCE), a common solvent. Pesticides and pesticide degradates also were detected in one-third of the ground-water samples collected; however, detected concentrations were one-thirtieth to one-fourteen-thousandth of their respective regulatory thresholds. Ten of the 122 pesticides and pesticide degradates investigated were found in ground-water samples. Compounds detected in 10 percent or more of the wells sampled include the herbicide simazine, and the pesticide degradate deethylatrazine. Ground-water samples had a median total dissolved solids (TDS) concentration of 467 milligrams per liter (mg/L), and 16 of the 34 samples had TDS concentrations above the recommended secondary maximum contaminant level (SMCL-a threshold established for aesthetic qualities: taste, odor, and color) of 500 mg/L, while four samples had concentrations above the upper SMCL of 1,000 mg/L. Concentrations of nitrate plus nitrite ranged from 0.04 to 37.8 mg/L (as nitrogen), and two samples had concentrations above the health-based threshold for nitrate of 10 mg/L (as nitrogen). The median sulfate concentration

California↗

A three-dimensional numerical model of predevelopment conditions in the Death Valley regional ground-water flow system, Nevada and California

In the early 1990's, two numerical models of the Death Valley regional ground-water flow system were developed by the U.S. Department of Energy. In general, the two models were based on the same basic hydrogeologic data set. In 1998, the U.S. Department of Energy requested that the U.S. Geological Survey develop and maintain a ground-water flow model of the Death Valley region in support of U.S. Department of Energy programs at the Nevada Test Site. The purpose of developing this 'second-generation' regional model was to enhance the knowledge an understanding of the ground-water flow system as new information and tools are developed. The U.S. Geological Survey also was encouraged by the U.S. Department of Energy to cooperate to the fullest extent with other Federal, State, and local entities in the region to take advantage of the benefits of their knowledge and expertise. The short-term objective of the Death Valley regional ground-water flow system project was to develop a steady-state representation of the predevelopment conditions of the ground-water flow system utilizing the two geologic interpretations used to develop the previous numerical models. The long-term objective of this project was to construct and calibrate a transient model that simulates the ground-water conditions of the study area over the historical record that utilizes a newly interpreted hydrogeologic conceptual model. This report describes the result of the predevelopment steady-state model construction and calibration. The Death Valley regional ground-water flow system is situated within the southern Great Basin, a subprovince of the Basin and Range physiographic province, bounded by latitudes 35 degrees north and 38 degrees 15 minutes north and by longitudes 115 and 118 degrees west. Hydrology in the region is a result of both the arid climatic conditions and the complex geology. Ground-water flow generally can be described as dominated by interbasinal flow and may be conceptualized as having two main components: a series of relatively shallow and localized flow paths that are superimposed on deeper regional flow paths. A significant component of the regional ground-water flow is through a thick Paleozoic carbonate rock sequence. Throughout the flow system, ground water flows through zones of high transmissivity that have resulted from regional faulting and fracturing. The conceptual model of the Death Valley regional ground-water flow system used for this study is adapted from the two previous ground-water modeling studies. The three-dimensional digital hydrogeologic framework model developed for the region also contains elements of both of the hydrogeologic framework models used in the previous investigations. As dictated by project scope, very little reinterpretation and refinement were made where these two framework models disagree; therefore, limitations in the hydrogeologic representation of the flow system exist. Despite limitations, the framework model provides the best representation to date of the hydrogeologic units and structures that control regional ground-water flow and serves as an important information source used to construct and calibrate the predevelopment, steady-state flow model. In addition to the hydrogeologic framework, a complex array of mechanisms accounts for flow into, through, and out of the regional ground-water flow system. Natural discharges from the regional ground-water flow system occur by evapotranspiration, springs, and subsurface outflow. In this study, evapotranspiration rates were adapted from a related investigation that developed maps of evapotranspiration areas and computed rates from micrometeorological data collected within the local area over a multiyear period. In some cases, historical spring flow records were used to derive ground-water discharge rates for isolated regional springs. For this investigation, a process-based, numerical model was developed to estimat

Water-Resources Investigations Report↗

Ground-water/surface-water interaction in nearshore areas of Three Lakes on the Grand Portage Reservation, northeastern Minnesota, 2003-04

The U.S. Geological Survey (USGS), in cooperation with the Grand Portage Band of Chippewa Indians, applied three techniques to assess ground-water/surface-water interaction in nearshore areas of three lakes (North, Teal, and Taylor) on the Grand Portage Reservation in northeastern Minnesota. At each lake, analyses of existing aerial photographs, in-situ temperature measurements of shoreline lake sediment, and chemical analyses of surface water and pore water were conducted. Surface-water and pore-water samples were analyzed for major constituents, nutrients, and stable isotopes of oxygen and hydrogen. Bulk precipitation samples were collected and analyzed (1) for nutrient concentrations to determine nutrient input to the lakes through atmospheric deposition and (2) for stable isotope ratios of oxygen and hydrogen to determine a meteoric waterline that was needed for the stable isotope analyses of surface-water and pore-water samples. Total nitrogen concentrations in the precipitation samples ranged from 0.51 to 8.4 mg/L (milligrams per liter) as nitrogen at the North Lake precipitation station and from 0.42 to 2.3 mg/L as nitrogen at the Grand Portage precipitation station. Oxygen-18/oxygen-16 and deuterium/protium isotope ratios for the bulk precipitation samples lie relatively close to a meteoric waterline for northern Wisconsin, except for the ratios for samples collected on May 20, 2004. Analyses of existing aerial photographs, nearshore lake-sediment temperatures, and seasonal isotope ratios of surface-water and pore-water samples were the most valuable data for identifying locations of ground-water inflow and surface-water outseepage. Analyses of existing aerial photographs of the three lakes indicated the location of potential inflow channels and lineaments identifying potential ground-water inflow locations for pore-water sampling. Lake-sediment temperatures at potential ground-water inflow locations ranged from 4 to 16 ºC, varying between lakes, seasons, and climatic conditions. Major constituent chemistry was valuable at Taylor Lake, and to a limited extent at North and Teal Lakes, in confirming results from the isotope and lake-sediment temperature data. Ground-water inflow to North Lake likely occurs along the southwest and south shores, and along portions of the west, southeast, north, and northeast shores. Relatively cool lake-sediment temperatures along the southwest, south, west, and southeast shores, and in isolated beaver channels along the north and northeast shores of North Lake indicate potential ground-water inflow at these locations. Both localized ground-water inflow and surface-water outseepage occurs along portions of the north, northeast, southeast, and south shores, varying seasonally. Conflicting evidence for ground-water flow conditions exist for the northwest and north-northwest pore-water samples. Only minor differences in the major constituent concentrations were seen between the surface-water and pore-water samples from the North Lake area with the exception of iron and manganese concentrations. Ground-water inflow likely takes place along the south-southwest and north shores of Teal Lake, with a mixture of ground-water inflow and surface-water outseepage occurring in other areas of the lake. Cooler lake-sediment temperatures occurred along the south-southwest, west, and northwest shores, portions of the north shore, and in channels identified in aerial photographs throughout the lake, indicating potential ground-water inflow at those locations. Warmer lake-sediment temperatures along the northeast and portions of the southwest and northwest shores of Teal Lake indicate potential locations where surface-water outseepage or little ground- and surface-water interaction occurs. The major constituent concentrations were higher in the pore-water samples collected from the south-southwest and northeast shores of Teal Lake, indicating ground-water inflow. Cation adsorption, cation exchanges with hydrogen ions, and chelation with organic materials occurring in the fen surrounding the lake likely resulted in the low dissolved calcium, magnesium, and sodium concentrations in north, northwest, and west pore-water samples from the Teal Lake area. Pore-water samples from the south-southwest, north, and southwest shores of Teal Lake had isotopic compositions that plotted closest to the meteoric waterline, indicating that little evaporation or transpiration occurred in these samples and that ground-water inflow may be occurring at these locations. Surface-water outseepage from Teal Lake likely occurs along the northeast shore even though major constituent concentrations were high. Major constituent concentrations may be high because of a nearby beaver dam. Ground-water inflow to Taylor Lake likely occurs at the north and south pore-water sampling sites. Higher major constituent concentrations and the least evaporative isotope ratios were found in pore-water samples along the south, north, and west shores of Taylor Lake, indicating potential locations of ground-water inflow. However, a combination of warmer and cooler lake-sediment temperatures along the west lowland indicated that ground-water inflow and surface-water outseepage may occur at that location. Surface-water outseepage likely occurs from Taylor Lake along the south shore through a surface-water drainage channel to a downgradient bog. Warmer lake-sediment temperatures along portions of the south and southeast shores indicate that surface-water outseepage may occur at those locations. Both ground-water inflow and surface-water outseepage may occur along the west, southeast, and east shores of Taylor Lake, varying seasonally and with local precipitation. Knowledge of general water-flow directions in lake watersheds and how they may change seasonally can help water-quality specialists and lake managers address a variety of water-quality and aquatic habitat protection issues for lakes. Results from this study indicate that ground-water and surface-water interactions at the study lakes are complex, and the ability of the applied techniques to identify ground-water inflow and surface-water outseepage locations varied among the lakes. Measurement of lake-sediment temperatures proved to be a reliable and relatively inexpensive reconnaissance technique that lake managers may apply in complex settings to identify general areas of ground-water inflow and surface-water outseepage.

Minnesota↗

Geohydrology and Numerical Simulation of Alternative Pumping Distributions and the Effects of Drought on the Ground-Water Flow System of Tinian, Commonwealth of the Northern Mariana Islands

Ground water in a freshwater lens is the main source of freshwater on Tinian, Commonwealth of the Northern Mariana Islands. Four major geologic units make up the island with high-permeability limestone units overlying low-permeability volcanic rocks. Estimates of limestone hydraulic conductivity range from 21 to 23,000 feet per day. Estimates of water-budget components for Tinian are 82 inches per year of rainfall, about 6 inches per year of runoff, 46 inches per year of evapotranspiration, and 30 inches per year of recharge. From 1990?97, ground-water withdrawal from the Municipal well, the major source of water, averaged about 780 gallons per minute. A two-dimensional, steady-state, ground-water flow model using the computer code SHARP was developed for Tinian, to enhance the understanding of (1) the distribution of aquifer hydraulic properties, (2) the conceptual framework of the ground-water flow system, and (3) the effects of various pumping distributions and drought on water levels and the freshwater/saltwater transition zone. For modeling purposes, Tinian was divided into three horizontal hydraulic-conductivity zones: (1) highly permeable limestone, (2) less-permeable, clay-rich limestone, and (3) low-permeability volcanic rocks. The following horizontal hydraulic conductivities were estimated: (1) 10,500 feet per day for the highly permeable limestone, (2) 800 feet per day for the less-permeable clay-rich limestone, and (3) 0.2 foot per day for the volcanic rocks. To estimate the hydrologic effects of different pumping distributions on the aquifer, three different steady-state pumping scenarios were simulated, (1) a scenario with no ground-water pumping, (2) a 2001-pumping scenario, and (3) a maximum-pumping scenario. The results of the no-pumping scenario showed that the freshwater/saltwater interface beneath the Municipal well would be about 7 feet deeper and ground-water discharge to the coast would be higher along both the east and west coasts of the island when compared with 1990-97 pumping conditions. For the maximum pumping scenario, the model-calculated freshwater/saltwater interface is about 7 feet shallower than the position calculated in the base-case scenario. To estimate the hydrologic effects of drought on the freshwater lens, the 2001- and maximum-pumping scenarios were simulated using three combinations of aquifer porosity values covering a range of possible limestone properties. In all scenarios, recharge was reduced to 10 percent of average estimated recharge and the transient response was simulated for 1 year. These simulations demonstrated that the ground-water resource is adequate to withstand a drought similar to that experienced in 1998 using existing infrastructure.

Water-Resources Investigations Report↗

Ground-water resources and simulated effects of withdrawals in the East Shore area of Great Salt Lake, Utah

The ground-water resources in the East Shore area of Great Salt Lake, Utah, were studied to better define the ground-water system; to document changes in ground-water levels, quality, and storage; and to simulate effects of an increase in ground-water withdrawals. The East Shore aquifer system is in basin-fill deposits, and is primarily a confined system with unconfined parts near the mountain front. Recharge to and discharge from the East Shore aquifer system were estimated to average about 160,000 acre-feet per year during 1969-84, with minor amounts of water being removed from storage during that period. Major sources of ground-water recharge are seepage from surface water in natural channels and irrigation canals, and subsurface inflow from consolidated rock to the basin-fill deposits. Discharge of ground water is primarily to wells, water courses, springs, and as diffuse seepage to Great Salt Lake. Average annual surface-water inflow to the study area was estimated to be 860,000 acre-feet for the period 1969-84. Annual withdrawal of ground water for municipal and industrial use increased from about 10,000 acre-feet in 1960 to more than 30,000 acre-feet in 1980 to supply a population that increased from 175,000 in 1960 to 290,000 in 1980. Long-term trends of ground-water levels indicate a steady decline at most observation wells since 1952, despite near normal or increased precipitation since the late 1960's. Water levels declined as much as 50 feet near the principal pumping center in the east-central part of the study area. They declined as much as 35 feet more than five miles from the pumping center. The increase in withdrawals and subsequent water-level declines have caused about 700 wells within 30 square miles to cease flowing since 1954. A numerical model of the East Shore aquifer system in the Weber Delta area was constructed and calibrated using water-level data and changes in ground-water withdrawals for 1955-85. Predictive simulations were made based on doubling the 1980-84 rate of municipal and industrial withdrawals for 20 years, and using both average and below-average recharge rates. The simulations indicated water-level declines of an additional 35 to 50 feet near the principal pumping center; a decrease in natural discharge to drains, evapotranspiration, and Great Salt Lake; and a decrease in ground-water storage of 80,000 to 115,000 acre-feet after 20 years.

Utah↗

Ground-water discharge and nitrate loadings to the coastal bays of Maryland

Nitrate in ground water discharged to the Atlantic coastal bays of Maryland enhances the growth of phytoplankton and algae in the bays, which in turn contributes to the process of eutrophication (changes in a body of water as nutrients and sediments accumulate), which is one of the principal environmental problems in the bays. Information on nitrate loading to the bays has been identified as a major data gap by State and Federal resource managers. This report presents results of a study to estimate ground-water discharge and potential nitrate loads to the coastal bays of Maryland, which include Chincoteague, Newport, Sinepuxent, Isle of Wight, and Assawoman Bays. The nitrate load from the discharge of ground water to the coastal bays is dependent on the concentration of nitrate in the water and the volume of ground water being discharged. Data from 388 wells completed in the surficial aquifer that discharges to the bays were used to construct a map of the distribution of nitrate concentration in the ground water. On the basis of those data, and on several simplifying assumptions, the potential nitrate load to the coastal bays from direct discharge of ground water was estimated to be 272,000 pounds of nitrate per year, distributed throughout the 108-square-mile surface area of the bays. Nitrate from ground water can also enter the coastal bays by way of base flow to streams that discharge to the bays. The potential nitrate load to the bays from the base flow of streams was estimated to be 862,000 pounds per year, assuming that the concentration of nitrate in stream base flow is 3.2 milligrams per liter, which is the median concentration of nitrate in ground water in the study area.

Maryland↗

Geohydrology and conceptual model of a ground-water-flow system near a Superfund site in Cheshire, Connecticut

Degradation of ground-water quality has been identified in an area of the north-central part of the town of Cheshire, Connecticut. An investigation by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, was done during 1994-95 to characterize the unconsolidated glacial deposits and the sedimentary bedrock, integrate the local geohydrologic conditions with the regional geohydrologic system, and develop a conceptual understanding of ground-water flow in the study area. A regional ground-water-flow model developed for the region near the study area indicates that perennial streams, including Judd Brook and the Tenmile River, form hydrologic divides that separate the larger region into hydraulically independent flow systems. In the local study area, synoptic water-level measurements made in June 1995 indicate that ground water near the water table flows west and southwestward from the low hill on the eastern side of the area toward the pond and wetlands along Judd Brook. Water-level data indicate that there is good hydraulic connection between the unconsolidated materials and underlying fractured bedrock. Unconsolidated materials in the study area consist principally of glacial stratified deposits that are fine sand, silt, and clay of glaci- olacustrine origin; locally these overlie thin glacial till. The glacial sediments range in thickness from a few feet to about 25 ft in the eastern part of the study area and are as much as 100 ft thick in the western and southern part of the study area beneath the Judd Brook and Tenmile River valleys. Fluvial redbeds of the New Haven Arkose underlie the glacial deposits in the region; in the study area, the redbeds consist of (1) channel sandstone units, which are coarse sandstone to fine conglomerate, generally in 6- to 15-ft- thick sequences; and (2) overbank mudstone units, which are siltstone and silty sandstone with some fine sandstone, generally in 6- to 50-ft-thick sequences. Thin-bedded zones of siltstone that are particularly fissile are present locally within the mudstone units. Rock units strike northward and dip eastward at about 20. The eastward-dipping strata are cut by a consistent set of west to west-northwest dipping, high-angle fractures. These fractures are oriented perpendicular to bedding and are present mostly in the channel sandstone units, but locally extend into the mudstone units as well. Borehole-geophysical logging indicates that ground water flows along bedding planes in fissile zones and between fissile zones in high-angle fractures, which are perpendicular to bedding. The combined fracture types form an aquifer system in which ground water follows a stair-step flowpath, flowing horizontally through fissile zones and vertically through high-angle fractures. Heat-pulse flow meter measurements and borehole fluid-conductivity and temperature logs indicate that only a small subset of the fissile zones and some high-angle fractures are hydraulically significant. A generalized local-scale ground-water flow model based on a nonspecific, but realistic, rock and fracture geometry was developed for the study area. Simulations show that under nonpumping conditions at a hypothetical well located in the middle of the model, ground-water flow was separated into upper and lower zones in which flow paths differed but were generally from northeast to southwest. Several short-duration aquifer tests conducted in the study area indicate that there is good hydraulic connection in the fractures between the pumping well (CS-221) and two bedrock wells located approximately 100 ft to the north and south along bedding strike. During the short duration of the aquifer tests, there was no hydraulic connection in bedrock wells located to the east, perpendicular to the strike. A range of transmissivity of 27 to 46 ft2/d was calculated from the aquifer-test data for the fractured-bedrock aquifer at CS-221 and TH-2. Individual fracture zones identified by bo

Open-File Report↗

Ground-water quality data in the coastal Los Angeles Basin study unit, 2006: Results from the California GAMA Program

Ground-water quality in the approximately 860 square-mile Coastal Los Angeles Basin study unit (CLAB) was investigated from June to November of 2006 as part of the Statewide Basin Assessment Project of the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Statewide Basin Assessment was developed in response to the Ground-Water Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The Coastal Los Angeles Basin study was designed to provide a spatially unbiased assessment of raw ground-water quality within CLAB, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 69 wells in Los Angeles and Orange Counties. Fifty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (?grid wells?). Fourteen additional wells were selected to evaluate changes in ground-water chemistry or to gain a greater understanding of the ground-water quality within a specific portion of the Coastal Los Angeles Basin study unit ('understanding wells'). Ground-water samples were analyzed for: a large number of synthetic organic constituents [volatile organic compounds (VOCs), gasoline oxygenates and their degradates, pesticides, polar pesticides, and pesticide degradates, pharmaceutical compounds, and potential wastewater-indicators]; constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), 1,4-dioxane, and 1,2,3-trichloropropane (1,2,3-TCP)]; inorganic constituents that can occur naturally [nutrients, major and minor ions, and trace elements]; radioactive constituents [gross-alpha and gross-beta radiation, radium isotopes, and radon-222]; and microbial indicators. Naturally occurring isotopes [stable isotopic ratios of hydrogen and oxygen, and activities of tritium and carbon-14] and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. Quality-control samples (blanks, replicates, and samples for matrix spikes) were collected at approximately one-fourth of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias. Differences between replicate samples were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most compounds. Assessment of the quality-control information resulted in applying ?V? codes to approximately 0.1 percent of the data collected for ground-water samples (meaning a constituent was detected in blanks as well as the corresponding environmental data). This study did not attempt to evaluate the quality of drinking water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable drinking-water quality. Regulatory thresholds are applied to the treated drinking water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA), California Department of Public Health (CDPH, formerly California Department of Health Services [CADHS]) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only, and are not indicative of compliance or non-compliance with those thresholds. VOCs were detected in alm

California↗

Ground-water quality in Nevada -- A proposed monitoring program

A program was designed for the systematic monitoring of ground-water quality in Nevada. Basic hydrologic and water-quality principles are discussed in the formulation of a rational approach to developing a statewide monitoring program. A review of ground-water monitoring efforts in Nevada through 1977 indicates that few requirements for an effective statewide program are being met. A suggested program has been developed that consists of five major elements: (1) A Background-Quality Network to assess the existing water quality in Nevada aquifers, (2) a Contamination Source Inventory of known or potential threats to ground-water quality, (3) Surveillance Networks to monitor ground-water quality in selected hydrographic areas, (4) Intensive Surveys of individual instances of known or potential ground-water contamination, and (5) Ground-Water Data File to manage data generated by the other monitoring elements. Two indices have been developed to help assign rational priorities for monitoring ground water in the 255 hydrographic areas of Nevada: (1) A Hydrographic-Area Priority Index for surveillance monitoring, and (2) A Development-Potential Index for background monitoring of areas with little or no current development. Requirements for efficient management of data from ground-water monitoring are discussed and the three major systems containing Nevada ground-water data are reviewed. More than 11,000 chemical analyses of ground water have been acquired from existing systems and incorporated into a prototype data base.

Nevada↗

Preliminary estimates of residence times and apparent ages of ground water in the Chesapeake Bay watershed, and water-quality data from a survey of springs

Knowledge of the residence times of the ground-water systems in Chesapeake Bay watershed helps resource managers anticipate potential delays between implementation of land-management practices and any improvements in river and estuary water quality. This report presents preliminary estimates of ground-water residence times and apparent ages of water in the shallow aquifers of the Chesapeake Bay watershed. A simple reservoir model, published data, and analyses of spring water were used to estimate residence times and apparent ages of ground-water discharge. Ranges of aquifer hydraulic characteristics throughout the Bay watershed were derived from published literature and were used to estimate ground-water residence times on the basis of a simple reservoir model. Simple combinations of rock type and physiographic province were used to delineate hydrogeomorphic regions (HGMR's) for the study area. The HGMR's are used to facilitate organization and display of the data and analyses. Illustrations depicting the relation of aquifer characteristics and associated residence times as a continuum for each HGMR were developed. In this way, the natural variation of aquifer characteristics can be seen graphically by use of data from selected representative studies. Water samples collected in September and November 1996, from 46 springs throughout the watershed were analyzed for chlorofluorocarbons (CFC's) to estimate the apparent age of ground water. For comparison purposes, apparent ages of water from springs were calculated assuming piston flow. Additional data are given to estimate apparent ages assuming an exponential distribution of ages in spring discharge. Additionally, results from previous studies of CFC-dating of ground water from other springs and wells in the watershed were compiled. The CFC data, and the data on major ions, nutrients, and nitrogen isotopes in the water collected from the 46 springs are included in this report. The apparent ages of water discharging from 30 of the 46 springs sampled were less than 20 years, including 5 that were "modern" (0-4 years). Four samples had apparent ages of 22 to 34 years, and two others from thermal springs were 40 years or greater. The remaining ten samples were contaminated with local sources of CFC and could not be dated. Nitrate concentrations and nitrate delta 15 nitrogen (d 15 N) values in water from many springs are similar to those in shallow ground water beneath fertilized fields, and some values are high enough to indicate a probable source from animal-waste components. The nitrogen data reported here highlight the significance of the springs sampled during this study as pathways for nutrient transport in the Chesapeake Bay watershed. Ground-water samples were collected from springs during an unusually high flow period and thus may not be representative of low base-flow conditions. Residence times estimated from plausible ranges of aquifer properties and results of previous age-dating analyses generally corroborate the apparent-age analysis made in the current study and suggests that some residence times could be much longer. The shortest residence times tend to be in the Blue Ridge and northern carbonate areas; however, the data are preliminary and not appropriate for statistical tests of significance or variance. Because the age distributions in the aquifer discharging to the springs are not known, and because the apparent ages of water from the springs are based on various combinations of CFC criteria, the apparent ages and calculated residence times are compared for illustrative purposes but are considered preliminary until further work is accomplished.

Maryland, Virginia↗

Ground-water quality data in the San Fernando-San Gabriel study unit, 2005— Results from the California GAMA program

Ground-water quality in the approximately 460 square mile San Fernando-San Gabriel study unit (SFSG) was investigated between May and July 2005 as part of the Priority Basin Assessment Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Assessment Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The San Fernando-San Gabriel study was designed to provide a spatially unbiased assessment of raw ground-water quality within SFSG, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 52 wells in Los Angeles County. Thirty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and seventeen wells were selected to aid in the evaluation of specific water-quality issues or changes in water chemistry along a historic ground-water flow path (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents [volatile organic compounds (VOCs), pesticides and pesticide degradates], constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), 1,2,3-trichloropropane (1,2,3-TCP), and 1,4-dioxane], naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, and carbon), and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, samples for matrix spikes) were collected at approximately one-fifth (11 of 52) of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control results showed that the data had very little bias or variability and resulted in censoring of less than 0.7 percent (32 of 4,484 measurements) of the data collected for ground-water samples. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. VOCs were detected in more than 90 percent (33 of 35) of grid wells. For all wells sampled for SFSG, nearly all VOC detections were below health-based thresholds, and most were less than one-tenth of the threshold values. Samples from seven wells had at least one detection of PCE, TCE, tetrachloromethane, NDMA, or 1,2,3-TCP at or above a health-based threshold. Pesticides were detected in about 90 percent (31 of 35) grid wells and all detections in samples from SFSG wells were below health-based thresholds. Major ions, trace elements, and nutrients in samples from 17 SFSG wells were all below health-based thresholds, with the exception of one detection of nitrate that was above the USEPA maximum contaminant level (MCL-US). With the exception of 14 samples having radon-222 above the proposed MCL-US, radioactive constituents were below health-based thresholds for 16 of the SFSG wells sampled. Total dissolved solids in 6 of the 24 SFSG wells that were sampled ha

California↗