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Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

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At least 919 records · Page 51Linked to original sources
USGS2013

MODIS phenology image service ArcMap toolbox

Seasonal change is important to consider when managing conservation areas at landscape scales. The study of such patterns throughout the year is referred to as phenology. Recurring life-cycle events that are initiated and driven by environmental factors include animal migration and plant flowering. Phenological events capture public attention, such as fall color change in deciduous forests, the first flowering in spring, and for those with allergies, the start of the pollen season. These events can affect our daily lives, provide clues to help understand and manage ecosystems, and provide evidence of how climate variability can affect the natural cycle of plants and animals. Phenological observations can be gathered at a range of scales, from plots smaller than an acre to landscapes of hundreds to thousands of acres. Linking these observations to diverse disciplines such as evolutionary biology or climate sciences can help further research in species and ecosystem responses to climate change scenarios at appropriate scales. A cooperative study between the National Park Service (NPS), the U.S. Geological Survey (USGS), and the National Aeronautics and Space Administration (NASA) has been exploring how satellite information can be used to summarize phenological patterns observed at the park or landscape scale and how those summaries can be presented to both park managers and visitors. This study specifically addressed seasonal changes in plants, including the onset of growth, photosynthesis in the spring, and the senescence of deciduous vegetation in the fall. The primary objective of the work is to demonstrate that seasonality even in protected areas changes considerably across years. A major challenge is to decouple natural variability from possible trends—directional change that can lead to a permanent and radically different ecosystem state. Trends can be either a gradual degradation of the landscape (often from external influences) or steady improvement (by implementing long-term conservation plans). In either case, it is important to first grasp the magnitude of natural variation so that it is not confused with actual trends. This work used existing and freely available remote sensing data, specifically the NASA-funded 250-meter (m) spatial resolution land-surface phenology product for North America. This product is calculated from an annual record of vegetation health observed by NASA’s Moderate Resolution Imaging Spectroradiometer (MODIS) instrument. The land-surface phenology product is, in essence, a method to summarize all the observations throughout a year into a few key, ecologically relevant “metrics”.

Open-File Report↗
USGS2026

Post-wildfire water quality and aquatic ecosystem response in the U.S. Pacific Northwest: science and monitoring gaps

An increase in the occurrence of large, high severity wildfires in the western Pacific Northwest (PNW), USA, has created an urgent need for science to better inform forest management and policy decisions to maintain source water quality in the region. The western PNW faces similar challenges to other regions with shifting wildfire regimes and large population centers reliant on surface water from forested catchments. However, the uniquely wet and highly seasonal climate of the western PNW suggests that findings from other, more frequently burned regions may not be directly applicable. To identify science, monitoring, and management gaps and opportunities in the western PNW, this review was collaboratively undertaken by academics, non-government and industry representatives, and local, state, and federal government entities who have been working together since the 2020 Labor Day fires in Oregon. Focusing on Oregon and Washington, we found that monitoring networks for continuous water quantity and quality cover much of the state with greater representation in western U.S. ecoregions, but few studies have analyzed and published these data to capture and communicate the post-wildfire response. Approximately half of the streamgages in Oregon and Washington record major water quality parameters, and hundreds of sites in the area have discrete sampling for a wide range of water quality constituents. Still, numerous gaps exist in understanding the short- and long-term impacts of wildfire on hydrology, water chemistry, including pH and dissolved oxygen, mobilization of metals, aquatic ecosystems, and downstream drinking water treatment. Collective action to further collect, analyze, interpret, and publish the key data could help improve our understanding of post-wildfire water quality impacts in this and other increasingly wildfire-affected regions.

Oregon, Washington↗
USGS2015

Estimating mercury exposure of piscivorous birds and sport fish using prey fish monitoring

Methylmercury is a global pollutant of aquatic ecosystems, and monitoring programs need tools to predict mercury exposure of wildlife. We developed equations to estimate methylmercury exposure of piscivorous birds and sport fish using mercury concentrations in prey fish. We collected original data on western grebes ( Aechmophorus occidentalis ) and Clark’s grebes ( Aechmophorus clarkii ) and summarized the published literature to generate predictive equations specific to grebes and a general equation for piscivorous birds. We measured mercury concentrations in 354 grebes (blood averaged 1.06 ± 0.08 μg/g ww), 101 grebe eggs, 230 sport fish (predominantly largemouth bass and rainbow trout), and 505 prey fish (14 species) at 25 lakes throughout California. Mercury concentrations in grebe blood, grebe eggs, and sport fish were strongly related to mercury concentrations in prey fish among lakes. Each 1.0 μg/g dw (∼0.24 μg/g ww) increase in prey fish resulted in an increase in mercury concentrations of 103% in grebe blood, 92% in grebe eggs, and 116% in sport fish. We also found strong correlations between mercury concentrations in grebes and sport fish among lakes. Our results indicate that prey fish monitoring can be used to estimate mercury exposure of piscivorous birds and sport fish when wildlife cannot be directly sampled.

Environmental Science & Technology↗
USGS2022

Volcano and earthquake monitoring plan for the Yellowstone Caldera system, 2022–2032

Executive Summary The Yellowstone Volcano Observatory (YVO) is a consortium of nine Federal, State, and academic agencies that: (1) provides timely monitoring and hazards assessment of volcanic, hydrothermal, and earthquake activity in and around Yellowstone National Park, and (2) conducts research to develop new approaches to volcano monitoring and better understand volcanic activity in the Yellowstone region and elsewhere. The U.S. Geological Survey (USGS) arm of YVO is also responsible for monitoring and reporting on volcanic activity in the Intermountain West of the United States. The previous YVO monitoring plan for the Yellowstone region spanned 2006–2015 and focused on strengthening the region-wide coverage, or backbone, of monitoring systems (Yellowstone Volcano Observatory, 2006). The goals of that plan have largely been achieved thanks to significant investments in instrumentation and infrastructure, especially by the National Science Foundation EarthScope Plate Boundary Observatory (now known as the Network Of The Americas, or NOTA) and the American Reinvestment and Recovery Act. This revision of the monitoring plan, covering 2022–2032, builds upon these improvements to monitoring systems in the Yellowstone region while also accounting for new insights into the dynamics of the area’s seismic, volcanic, and hydrothermal activity. These additional improvements are designed to fill gaps in the monitoring network and to better understand and track hazards associated with hydrothermal processes. These improvements include: Conversion of remaining analog seismic stations to digital, Addition of Global Positioning System (GPS) stations in the vicinity of Norris Geyser Basin and other areas where changes in deformation rate and style have been observed, Implementation of continuous gas monitoring in several areas of Yellowstone National Park, and Improvements to lake, meteorological, and hydrological monitoring to better track hydrothermal activity, including that occurring on lake bottoms, and to aid in understanding of whether such activity might be influenced by external forces, like environmental conditions. The 2022–2032 monitoring plan for the Yellowstone volcanic system also proposes to improve monitoring of hydrothermal areas to better understand these dynamic systems and their associated hazards. To date, only a single seismometer has been placed within one of Yellowstone National Park’s geyser basins because seismic noise associated with boiling water can hinder interpretation of overall seismic and magmatic activity, but this concern has been mitigated by improvements to backbone monitoring. Deployment of geophysical, geochemical, hydrological, and geological monitoring instruments in geyser basins will be accompanied by campaigns to measure gas and water chemistry and flux, as well as aerial and satellite surveys of gas and thermal emissions. Close collaboration between YVO member institutions and other research agencies is needed to achieve these monitoring goals and to use the derived data to advance understanding of how Yellowstone Caldera and similar volcanic systems work. At the same time, attention must be paid to minimize the impact of monitoring efforts and infrastructure on the environment. YVO thus commits to serving as stewards of the natural, cultural, and historical resources in and around Yellowstone National Park while maximizing scientific gain for the betterment of society.

Wyoming↗
USGS2023

Ice and ocean constraints on early human migrations into North America along the Pacific Coast

Founding populations of the first Americans likely occupied parts of Beringia during the Last Glacial Maximum (LGM). The timing, pathways, and modes of their southward transit remain unknown, but blockage of the interior route by North American ice sheets between ~26 and 14 cal kyr BP (ka) favors a coastal route during this period. Using models and paleoceanographic data from the North Pacific, we identify climatically favorable intervals when humans could have plausibly traversed the Cordilleran coastal corridor during the terminal Pleistocene. Model simulations suggest that northward coastal currents strengthened during the LGM and at times of enhanced freshwater input, making southward transit by boat more difficult. Repeated Cordilleran glacial-calving events would have further challenged coastal transit on land and at sea. Following these events, ice-free coastal areas opened and seasonal sea ice was present along the Alaskan margin until at least 15 ka. Given evidence for humans south of the ice sheets by 16 ka and possibly earlier, we posit that early people may have taken advantage of winter sea ice that connected islands and coastal refugia. Marine ice-edge habitats offer a rich food supply and traversing coastal sea ice could have mitigated the difficulty of traveling southward in watercraft or on land over glaciers. We identify 24.5 to 22 ka and 16.4 to 14.8 ka as environmentally favorable time periods for coastal migration, when climate conditions provided both winter sea ice and ice-free summer conditions that facilitated year-round marine resource diversity and multiple modes of mobility along the North Pacific coast.

Pacific Coast↗
USGS2015

Initiation of migration and movement rates of Atlantic salmon smolts in fresh water

Timing of ocean entry is critical for marine survival of both hatchery and wild Atlantic salmon ( Salmo salar ) smolts. Management practices and barriers to migration such as dams may constrain timing of smolt migrations resulting in suboptimal performance at saltwater entry. We modeled influences of stocking location, smolt development, and environmental conditions on ( i ) initiation of migration by hatchery-reared smolts and ( ii ) movement rate of hatchery- and wild-reared Atlantic salmon smolts in the Penobscot River, Maine, USA, from 2005 through 2014 using acoustic telemetry data. We also compared movement rates in free-flowing reaches with rates in reaches with hydropower dams and head ponds. We compared movement rates before and after (1) removal of two mainstem dams and (2) construction of new powerhouses. Initiation of movement by hatchery fish was influenced by smolt development, stocking location, and environmental conditions. Smolts with the greatest gill Na + , K + -ATPase (NKA) activity initiated migration 24 h sooner than fish with the lowest gill NKA activity. Fish with the greatest cumulative thermal experience initiated migration 5 days earlier than those with lowest cumulative thermal experience. Smolts released furthest from the ocean initiated migration earlier than those released downstream, but movement rate increased by fivefold closer to the ocean, indicating behavioral trade-offs between initiation and movement rate. Dams had a strong effect on movement rate. Movement rate increased from 2.8 to 5.4 km·h −1 in reaches where dams were removed, but decreased from 2.1 to 0.1 km·h −1 in reaches where new powerhouses were constructed. Movement rate varied throughout the migratory period and was inversely related to temperature. Fish moved slower at extreme high or low discharge. Responses in fish movement rates to dam removal indicate the potential scope of recovery for these activities.

Maine↗
USGS2016

The automated reference toolset: A soil-geomorphic ecological potential matching algorithm

Ecological inventory and monitoring data need referential context for interpretation. Identification of appropriate reference areas of similar ecological potential for site comparison is demonstrated using a newly developed automated reference toolset (ART). Foundational to identification of reference areas was a soil map of particle size in the control section (PSCS), a theme in US Soil Taxonomy. A 30-m resolution PSCS map of the Colorado Plateau (366,000 km 2 ) was created by interpolating ∼5000 field soil observations using a random forest model and a suite of raster environmental spatial layers representing topography, climate, general ecological community, and satellite imagery ratios. The PSCS map had overall out of bag accuracy of 61.8% (Kappa of 0.54, p < 0.0001), and an independent validation accuracy of 93.2% at a set of 356 field plots along the southern edge of Canyonlands National Park, Utah. The ART process was also tested at these plots, and matched plots with the same ecological sites (ESs) 67% of the time where sites fell within 2-km buffers of each other. These results show that the PSCS and ART have strong application for ecological monitoring and sampling design, as well as assessing impacts of disturbance and land management action using an ecological potential framework. Results also demonstrate that PSCS could be a key mapping layer for the USDA-NRCS provisional ES development initiative.

Soil Science Society of America Journal↗
USGS2001

Recent formation of arroyos in the Little Missouri Badlands of southwestern North Dakota

In the Little Missouri Badlands of southwestern North Dakota, the channels of ephemeral streams are incised 2 to 10 m or more into mid-to-late Holocene alluvium. The objectives of this study were to determine the timing and cause(s) of the most recent episodes of fluvial incision and to develop a process-response model that illustrates the formation and evolution of arroyos in this region. The purpose was to distinguish natural from anthropogenic changes to the landscape and to discriminate allogenic from autogenic causes of incision, thereby gaining a greater sense of how steep, relatively small, ephemeral streams evolve. Dendrochronologic and dendrogeomorphic analyses of riparian cottonwoods provide an inexpensive, high-resolution dating method to constrain the time of incision, thereby permitting determination of the cause(s) of incision by evaluating environmental conditions prior to and at the onset of fluvial incision. An examination of seven small (10 to 100 km2) drainage basins indicated ephemeral streams have undergone a four-stage cycle of change within the past 200 years, comprising(i) an initial period of relative geomorphic stability with pedogenesis on the flood plain and low rates of lateral channel migration, (ii) a period of channel incision with subsequent widening of the flood plain through lateral corrasion along middle and upstream reaches, (iii) a concomitant period of aggradation along downstream reaches and, finally, (iv) a period of downstream incision. Dendrochronologic data and dendrogeomorphic relations indicate there have been three distinct periods of fluvial incision in the past 200 years. The first period of incision began in the 1860s and 1870s prior to the onset of European settlement and intensive grazing by domesticated cattle in the area. This period of incision occurred along the middle reaches of all seven of the streams examined and coincided with a severe, protracted drought, suggesting an allogenic cause. The second period of incision occurred during the end of the 19th century and into the 20th century along the upstream reaches of streams. This period of incision was mentioned in some written accounts of early settlers and coincided with the introduction of cattle and historical overgrazing of the region. However, overgrazing may not have caused the incision of this period, but instread exacerbated or accelerated the upstream migration of knickpoints formed earlier along middle reaches. A third period of incision has occurred in the past 20 years along the lower reaches of two of the seven streams examined. This incision was caused by the process of meander cutoff. This autogenic process decreases sinuosity and increases channel slope, stream power, and the potential to incise along adjacent stream reaches. ?? 2001 Elsevier Science B.V. All rights reserved.

Geomorphology↗
USGS2010

Water-the Nation's Fundamental Climate Issue A White Paper on the U.S. Geological Survey Role and Capabilities

Of all the potential threats posed by climatic variability and change, those associated with water resources are arguably the most consequential for both society and the environment (Waggoner, 1990). Climatic effects on agriculture, aquatic ecosystems, energy, and industry are strongly influenced by climatic effects on water. Thus, understanding changes in the distribution, quantity and quality of, and demand for water in response to climate variability and change is essential to planning for and adapting to future climatic conditions. A central role of the U.S. Geological Survey (USGS) with respect to climate is to document environmental changes currently underway and to develop improved capabilities to predict future changes. Indeed, a centerpiece of the USGS role is a new Climate Effects Network of monitoring sites. Measuring the climatic effects on water is an essential component of such a network (along with corresponding effects on terrestrial ecosystems). The USGS needs to be unambiguous in communicating with its customers and stakeholders, and with officials at the Department of the Interior, that although modeling future impacts of climate change is important, there is no more critical role for the USGS in climate change science than that of measuring and describing the changes that are currently underway. One of the best statements of that mission comes from a short paper by Ralph Keeling (2008) that describes the inspiration and the challenges faced by David Keeling in operating the all-important Mauna Loa Observatory over a period of more than four decades. Ralph Keeling stated: 'The only way to figure out what is happening to our planet is to measure it, and this means tracking changes decade after decade and poring over the records.' There are three key ideas that are important to the USGS in the above-mentioned sentence. First, to understand what is happening requires measurement. While models are a tool for learning and testing our understanding, they are not a substitute for observations. The second key idea is that measurement needs to be done over a period of many decades. When viewing hydrologic records over time scales of a few years to a few decades, trends commonly appear. However, when viewed in the context of many decades to centuries, these short-term trends are recognized as being part of much longer term oscillations. Thus, while we might want to initiate monitoring of important aspects of our natural resources, the data that will prove to be most useful in the next few years are those records that already have long-term continuity. USGS streamflow and groundwater level data are excellent examples of such long-term records. These measured data span many decades, follow standard protocols for collection and quality assurance, and are stored in a database that provides access to the full period of record. The third point from the Keeling quote relates to the notion of ?poring over the records.? Important trends will not generally jump off the computer screen at us. Thoughtful analyses are required to get past a number of important but confounding influences in the record, such as the role of seasonal variation, changes in water management, or influences of quasi-periodic phenomena, such as El Ni?o-Southern Oscillation (ENSO) or the Pacific Decadal Oscillation (PDO). No organization is better situated to pore over the records than the USGS because USGS scientists know the data, quality-assure the data, understand the factors that influence the data, and have the ancillary information on the watersheds within which the data are collected. To fulfill the USGS role in understanding climatic variability and change, we need to continually improve and strengthen two of our key capabilities: (1) preserving continuity of long-term water data collection and (2) analyzing and interpreting water data to determine how the Nation's water resources are changing. Understanding change in water resources

Circular↗
USGS2002

Anthropogenic sources of arsenic and copper to sediments in a suburban lake, Northern Virginia

Mass balances of total arsenic and copper for a suburban lake in densely populated northern Virginia were calculated using data collected during 1998. Mass-balance terms were precipitation; stream inflow, including road runoff; stream outflow; and contributions from leaching of pressure-treated lumber. More mass of arsenic and copper was input to the lake than was output; the 1998 lake-retention rates were 70% for arsenic and 20% for copper. The arsenic mass balance compared well with a calculated annual mass accumulation in the top 1 cm of the lake sediments; however, the calculated contribution of copper to the lake was insufficient to account for the amount of copper in this zone. Leaching experiments were conducted on lumber treated with chromated copper arsenate (CCA) to quantify approximate amounts of arsenic and copper contributed by this source. Sources to lake sediments included leaching of CCA-treated lumber (arsenic, 50%; copper, 4%), streamwater (arsenic, 50%; copper, 90%), and atmospheric deposition (arsenic, 1%; copper, 3%). Results of this study suggest that CCA-treated lumber and road runoff could be significant nonpoint sources of arsenic and copper, respectively, in suburban catchments.

Virginia↗
USGS2022

Long-term impacts of impervious surface cover change and roadway deicing agent application on chloride concentrations in exurban and suburban watersheds

Roadway deicing agents, including rock salt and brine containing NaCl, have had a profound impact on the water quality and aquatic health of rivers and streams in urbanized areas with temperate climates. Yet, few studies evaluate impacts to watersheds characterized by relatively low impervious surface cover (ISC; < 15 %). Here, we use long-term (1997-2019), monthly streamwater quality data combined with daily streamflow for six exurban and suburban watersheds in southeastern Pennsylvania to examine the relations among chloride (Cl − ) concentrations and ISC. Both flow-normalized Cl − concentrations and ISC increased over time in each of the six watersheds, consistent with changes in watershed management (e.g., ISC, road salt application, etc.). The watersheds that experienced the greatest changes in percent ISC (e.g., agriculture replaced by residential and commercial development) experienced the greatest changes in flow-normalized Cl − concentrations. We also utilized a comprehensive mass-balance model (2011–2018) that indicated Cl − inputs exceeded the outputs for the study watersheds. Road salt applied to state roads, non-state roads, and other impervious surfaces accounted for the majority of Cl − inputs to the six watersheds. Furthermore, increasing Cl − concentrations during baseflow conditions confirm impacts to shallow groundwater. Although flow-normalized Cl − concentrations are below the U.S. Environmental Protection Agency's chronic threshold value for impacts to aquatic organisms, year-round exceedances may result before the end of this century based on current trends. Though reduced Cl − loading to streams may be achieved by limiting the expansion of impervious surfaces in exurban and suburban watersheds, changes in baseflow concentrations are likely to be gradual because of the accumulated Cl − in groundwater.

Pennsylvania↗
USGS2012

Flood-inundation maps for the Saddle River from Rochelle Park to Lodi, New Jersey, 2012

Digital flood-inundation maps for a 2.75-mile reach of the Saddle River from 0.2 mile upstream from the Interstate 80 bridge in Rochelle Park to 1.5 miles downstream from the U.S. Route 46 bridge in Lodi, New Jersey, were created by the U.S. Geological Survey (USGS) in cooperation with the New Jersey Department of Environmental Protection (NJDEP). The inundation maps, which can be accessed through the USGS Flood Inundation Mapping Science Web site at http://water.usgs.gov/osw/flood_inundation , depict estimates of the areal extent and depth of flooding corresponding to selected water levels (stages) at the USGS streamgage at Saddle River at Lodi, New Jersey (station 01391500). Current conditions for estimating near real-time areas of inundation using USGS streamgage information may be obtained on the Internet at http://waterdata.usgs.gov/nwis/uv?site_no=01391500 . The National Weather Service (NWS) forecasts flood hydrographs at many places that are often collocated with USGS streamgages. NWS-forecasted peak-stage information may be used in conjunction with the maps developed in this study to show predicted areas of flood inundation. In this study, flood profiles were computed for the stream reach by means of a one-dimensional step-backwater model. The model was calibrated using the most current stage-discharge relations at the Saddle River at Lodi, New Jersey streamgage and documented high-water marks from recent floods. The hydraulic model was then used to determine 11 water-surface profiles for flood stages at the Saddle River streamgage at 1-ft intervals referenced to the streamgage datum, North American Vertical Datum of 1988 (NAVD 88), and ranging from bankfull, 0.5 ft below NWS Action Stage, to the extent of the stage-discharge rating, which is approximately 1 ft higher than the highest recorded water level at the streamgage. Action Stage is the stage which when reached by a rising stream the NWS or a partner needs to take some type of mitigation action in preparation for possible significant hydrologic activity. The simulated water-surface profiles were then combined with a geographic information system 3-meter (9.84-ft) digital elevation model (derived from Light Detection and Ranging (LiDAR) data) in order to delineate the area flooded at each water level. The availability of these maps, along with Internet information regarding current stage from USGS streamgages and forecasted stream stages from the NWS, provide emergency management personnel and residents with information that is critical for flood response activities, such as evacuations and road closures, as well as for post-flood recovery efforts.

New Jersey↗
USGS2000

Atmospheric nitrogen in the Mississippi River Basin: Amissions, deposition and transport

Atmospheric deposition of nitrogen has been cited as a major factor in the nitrogen saturation of forests in the north-eastern United States and as a contributor to the eutrophication of coastal waters, including the Gulf of Mexico near the mouth of the Mississippi River. Sources of nitrogen emissions and the resulting spatial patterns of nitrogen deposition within the Mississippi River Basin, however, have not been fully documented. An assessment of atmospheric nitrogen in the Mississippi River Basin was therefore conducted in 1998-1999 to: (1) evaluate the forms in which nitrogen is deposited from the atmosphere; (2) quantify the spatial distribution of atmospheric nitrogen deposition throughout the basin; and (3) relate locations of emission sources to spatial deposition patterns to evaluate atmospheric transport. Deposition data collected through the NADP/NTN (National Atmospheric Deposition Program/National Trends Network) and CASTNet (Clean Air Status and Trends Network) were used for this analysis. NO(x) Tier 1 emission data by county was obtained for 1992 from the US Environmental Protection Agency (Emissions Trends Viewer CD, 1985-1995, version 1.0, September 1996) and NH3 emissions data was derived from the 1992 Census of Agriculture (US Department of Commerce. Census of Agriculture, US Summary and County Level Data, US Department of Commerce, Bureau of the Census. Geographic Area series, 1995:1b) or the National Agricultural Statistics Service (US Department of Agriculture. National Agricultural Statistics Service Historical Data. Accessed 7/98 at URL, 1998. http://www.usda.gov/nass/pubs/hisdata.htm). The highest rates of wet deposition of NO3- were in the north-eastern part of the basin, downwind of electric utility plants and urban areas, whereas the highest rates of wet deposition of NH4+ were in Iowa, near the center of intensive agricultural activities in the Midwest. The lowest rates of atmospheric nitrogen deposition were on the western (windward) side of the basin, which suggests that most of the nitrogen deposited within the basin is derived from internal sources. Atmospheric transport eastward across the basin boundary is greater for NO3- than NH4+, but a significant amount of NH4+ is likely to be transported out of the basin through the formation of (NH4)2SO4 and NH4NO3 particles - a process that greatly increases the atmospheric residence time of NH4+. This process is also a likely factor in the atmospheric transport of nitrogen from the Midwest to upland forest regions in the North-East, such as the western Adirondack region of New York, where NH4+ constitutes 38% of the total wet deposition of N.

Science of Total Environment↗
USGS2019

Hormones and pharmaceuticals in groundwater used as a source of drinking water across the United States

This is the first large-scale, systematic assessment of hormone and pharmaceutical occurrence in groundwater used for drinking across the United States. Samples from 1091 sites in Principal Aquifers representing 60% of the volume pumped for drinking-water supply had final data for 21 hormones and 103 pharmaceuticals. At least one compound was detected at 5.9% of 844 sites representing the resource used for public supply across the entirety of 15 Principal Aquifers, and at 11.3% of 247 sites representing the resource used for domestic supply over subareas of nine Principal Aquifers. Of 34 compounds detected, one plastics component (bisphenol A), three pharmaceuticals (carbamazepine, sulfamethoxazole, and meprobamate), and the caffeine degradate 1,7-dimethylxanthine were detected in more than 0.5% of samples. Hydrocortisone had a concentration greater than a human-health benchmark at 1 site. Compounds with high solubility and low K oc were most likely to be detected. Detections were most common in shallow wells with a component of recent recharge, particularly in crystalline-rock and mixed land-use settings. Results indicate vulnerability of groundwater used for drinking water in the U.S. to contamination by these compounds is generally limited, and exposure to these compounds at detected concentrations is unlikely to have adverse effects on human health.

Environmental Science & Technology↗
USGS2019

Hydrocarbons in upland groundwater, Marcellus Shale Region, Northeastern Pennsylvania and Southern New York, USA

Water samples from 50 domestic wells located <1 km (proximal) and >1 km (distal) from shale-gas wells in upland areas of the Marcellus Shale region were analyzed for chemical, isotopic, and groundwater-age tracers. Uplands were targeted because natural mixing with brine and hydrocarbons from deep formations is less common in those areas compared to valleys. CH 4 -isotope, predrill CH 4 -concentration, and other data indicate that one proximal sample (5% of proximal samples) contains thermogenic CH 4 (2.6 mg/L) from a relatively shallow source (Catskill/Lock Haven Formations) that appears to have been mobilized by shale-gas production activities. Another proximal sample contains five other volatile hydrocarbons (0.03–0.4 μg/L), including benzene, more hydrocarbons than in any other sample. Modeled groundwater-age distributions, calibrated to 3 H, SF 6 , and 14 C concentrations, indicate that water in that sample recharged prior to shale-gas development, suggesting that land-surface releases associated with shale-gas production were not the source of those hydrocarbons, although subsurface leakage from a nearby gas well directly into the groundwater cannot be ruled out. Age distributions in the samples span ∼20 to >10000 years and have implications for relating occurrences of hydrocarbons in groundwater to land-surface releases associated with recent shale-gas production and for the time required to flush contaminants from the system.

New York, Pennsylvania↗
USGS2006

Influence of potentially confounding factors on sea urchin porewater toxicity tests

The influence of potentially confounding factors has been identified as a concern for interpreting sea urchin porewater toxicity test data. The results from >40 sediment-quality assessment surveys using early-life stages of the sea urchin Arbacia punctulata were compiled and examined to determine acceptable ranges of natural variables such as pH, ammonia, and dissolved organic carbon on the fertilization and embryological development endpoints. In addition, laboratory experiments were also conducted with A. punctulata and compared with information from the literature. Pore water with pH as low as 6.9 is an unlikely contributor to toxicity for the fertilization and embryological development tests with A. punctulata. Other species of sea urchin have narrower pH tolerance ranges. Ammonia is rarely a contributing factor in pore water toxicity tests using the fertilization endpoint, but the embryological development endpoint may be influenced by ammonia concentrations commonly found in porewater samples. Therefore, ammonia needs to be considered when interpreting results for the embryological development test. Humic acid does not affect sea urchin fertilization at saturation concentrations, but it could have an effect on the embryological development endpoint at near-saturation concentrations. There was no correlation between sediment total organic carbon concentrations and porewater dissolved organic carbon concentrations. Because of the potential for many varying substances to activate parthenogenesis in sea urchin eggs, it is recommended that a no-sperm control be included with every fertilization test treatment. ?? 2006 Springer Science+Business Media, Inc.

Archives of Environmental Contamination and Toxico↗
USGS2016

Endocrine disrupting activities of surface water associated with a West Virginia oil and gas industry wastewater disposal site

Currently, >95% of end disposal of hydraulic fracturing wastewater from unconventional oil and gas operations in the US occurs via injection wells. Key data gaps exist in understanding the potential impact of underground injection on surface water quality and environmental health. The goal of this study was to assess endocrine disrupting activity in surface water at a West Virginia injection well disposal site. Water samples were collected from a background site in the area and upstream, on, and downstream of the disposal facility. Samples were solid-phase extracted, and extracts assessed for agonist and antagonist hormonal activities for five hormone receptors in mammalian and yeast reporter gene assays. Compared to reference water extracts upstream and distal to the disposal well, samples collected adjacent and downstream exhibited considerably higher antagonist activity for the estrogen, androgen, progesterone, glucocorticoid and thyroid hormone receptors. In contrast, low levels of agonist activity were measured in upstream/distal sites, and were inhibited or absent at downstream sites with significant antagonism. Concurrent analyses by partner laboratories (published separately) describe the analytical and geochemical profiling of the water; elevated conductivity as well as high sodium, chloride, strontium, and barium concentrations indicate impacts due to handling of unconventional oil and gas wastewater. Notably, antagonist activities in downstream samples were at equivalent authentic standard concentrations known to disrupt reproduction and/or development in aquatic animals. Given the widespread use of injection wells for end-disposal of hydraulic fracturing wastewater, these data raise concerns for human and animal health nearby.

Science of the Total Environment↗
USGS2017

Effects of an extreme flood on trace elements in river water—From urban stream to major river basin

Major floods adversely affect water quality through surface runoff, groundwater discharge, and damage to municipal water infrastructure. Despite their importance, it can be difficult to assess the effects of floods on streamwater chemistry because of challenges collecting samples and the absence of baseline data. This study documents water quality during the September 2013 extreme flood in the South Platte River, Colorado, USA. Weekly time-series water samples were collected from 3 urban source waters (municipal tap water, streamwater, and wastewater treatment facility effluent) under normal-flow and flood conditions. In addition, water samples were collected during the flood at 5 locations along the South Platte River and from 7 tributaries along the Colorado Front Range. Samples were analyzed for 54 major and trace elements. Specific chemical tracers, representing different natural and anthropogenic sources and geochemical behaviors, were used to compare streamwater composition before and during the flood. The results differentiate hydrological processes that affected water quality: (1) in the upper watershed, runoff diluted most dissolved constituents, (2) in the urban corridor and lower watershed, runoff mobilized soluble constituents accumulated on the landscape and contributed to stream loading, and (3) flood-induced groundwater discharge mobilized soluble constituents stored in the vadose zone.

Colorado↗