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At least 919 records · Page 51Linked to original sources

Preparation and certification of Re-Os dating reference materials: Molybdenites HLP and JDC

Two Re-Os dating reference material molybdenites were prepared. Molybdenite JDC and molybdenite HLP are from a carbonate vein-type molybdenum-(lead)-uranium deposit in the Jinduicheng-Huanglongpu area of Shaanxi province, China. The samples proved to be homogeneous, based on the coefficient of variation of analytical results and an analysis of variance test. The sampling weight was 0.1 g for JDC and 0.025 g for HLP. An isotope dilution method was used for the determination of Re and Os. Sample decomposition and pre-concentration of Re and Os prior to measurement were accomplished using a variety of methods: acid digestion, alkali fusion, ion exchange and solvent extraction. Negative thermal ionisation mass spectrometry and inductively coupled plasma-mass spectrometry were used for the determination of Re and 187 Os concentration and isotope ratios. The certified values include the contents of Re and Os and the model ages. For HLP, the Re content was 283.8 ± 6.2 μg g −1 , 187 Os was 659 ± 14 ng g −1 and the Re-Os model age was 221.4 ± 5.6 Ma. For JDC, the Re content was 17.39 ± 0.32 μg g −1 , 187 Os was 25.46 ± 0.60 ng g −1 and the Re-Os model age was 139.6 ± 3.8 Ma. Uncertainties for both certified reference materials are stated at the 95% level of confidence. Three laboratories (from three countries: PR. China, USA, Sweden) joined in the certification programme. These certified reference materials are primarily useful for Re-Os dating of molybdenite, sulfides, black shale, etc.

Geostandards and Geoanalytical Research↗

Estimating hydraulic properties of the Floridan Aquifer System by analysis of earth-tide, ocean-tide, and barometric effects, Collier and Hendry Counties, Florida

Aquifers are subjected to mechanical stresses from natural, non-anthropogenic, processes such as pressure loading or mechanical forcing of the aquifer by ocean tides, earth tides, and pressure fluctuations in the atmosphere. The resulting head fluctuations are evident even in deep confined aquifers. The present study was conducted for the purpose of reviewing the research that has been done on the use of these phenomena for estimating the values of aquifer properties, and determining which of the analytical techniques might be useful for estimating hydraulic properties in the dissolved-carbonate hydrologic environment of southern Florida. Fifteen techniques are discussed in this report, of which four were applied. An analytical solution for head oscillations in a well near enough to the ocean to be influenced by ocean tides was applied to data from monitor zones in a well near Naples, Florida. The solution assumes a completely non-leaky confining unit of infinite extent. Resulting values of transmissivity are in general agreement with the results of aquifer performance tests performed by the South Florida Water Management District. There seems to be an inconsistency between results of the amplitude ratio analysis and independent estimates of loading efficiency. A more general analytical solution that takes leakage through the confining layer into account yielded estimates that were lower than those obtained using the non-leaky method, and closer to the South Florida Water Management District estimates. A numerical model with a cross-sectional grid design was applied to explore additional aspects of the problem. A relation between specific storage and the head oscillation observed in a well provided estimates of specific storage that were considered reasonable. Porosity estimates based on the specific storage estimates were consistent with values obtained from measurements on core samples. Methods are described for determining aquifer diffusivity by comparing the time-varying drawdown in an open well with periodic pressure-head oscillations in the aquifer, but the applicability of such methods might be limited in studies of the Floridan aquifer system.

Florida↗

Individual encounter data of six African carnivore species optimized for multi-species density estimation

The ability to estimate abundances of multiple wildlife species within an area is valuable for both conservation and ecological inquiry. Spatially explicit capture–recapture (SCR) methods are commonly used to obtain reliable population size estimates, particularly for low-density and individually identifiable carnivore species. However, estimating abundance within multi-species communities poses a methodological challenge as survey designs and analytical tools are primarily tailored for single target species. Here, we present a dataset of spatially referenced individual encounter histories of six carnivore species with varying space requirements (lion, Panthera leo ; leopard, Panthera pardus ; spotted hyena, Crocuta crocuta ; cheetah, Acinonyx jubatus ; serval, Leptailurus serval ; large-spotted genet, Genetta tigrina ). These data were collected in a South African game reserve using a camera trap array optimized for multi-species density estimation using SCR methods. This dataset will be a valuable resource for studying spatial processes among potentially interacting carnivores without the common pitfalls that come with by-catch data of non-target species, and will provide a much-needed case study for the further development of multi-species statistical method development.

Munywana Conservancy↗

Potential sources of analytical bias and error in selected trace element data-quality analyses

Potential sources of analytical bias and error associated with laboratory analyses for selected trace elements where concentrations were greater in filtered samples than in paired unfiltered samples were evaluated by U.S. Geological Survey (USGS) Water Quality Specialists in collaboration with the USGS National Water Quality Laboratory (NWQL) and the Branch of Quality Systems (BQS). Causes for trace-element concentrations in filtered samples to exceed those in associated unfiltered samples have been attributed to variability in analytical measurements, analytical bias, sample contamination either in the field or laboratory, and (or) sample-matrix chemistry. These issues have not only been attributed to data generated by the USGS NWQL but have been observed in data generated by other laboratories. This study continues the evaluation of potential analytical bias and error resulting from matrix chemistry and instrument variability by evaluating the performance of seven selected trace elements in paired filtered and unfiltered surface-water and groundwater samples collected from 23 sampling sites of varying chemistries from six States, matrix spike recoveries, and standard reference materials. Filtered and unfiltered samples have been routinely analyzed on separate inductively coupled plasma-mass spectrometry instruments. Unfiltered samples are treated with hydrochloric acid (HCl) during an in-bottle digestion procedure; filtered samples are not routinely treated with HCl as part of the laboratory analytical procedure. To evaluate the influence of HCl on different sample matrices, an aliquot of the filtered samples was treated with HCl. The addition of HCl did little to differentiate the analytical results between filtered samples treated with HCl from those samples left untreated; however, there was a small, but noticeable, decrease in the number of instances where a particular trace-element concentration was greater in a filtered sample than in the associated unfiltered sample for all trace elements except selenium. Accounting for the small dilution effect (2 percent) from the addition of HCl, as required for the in-bottle digestion procedure for unfiltered samples, may be one step toward decreasing the number of instances where trace-element concentrations are greater in filtered samples than in paired unfiltered samples. The laboratory analyses of arsenic, cadmium, lead, and zinc did not appear to be influenced by instrument biases. These trace elements showed similar results on both instruments used to analyze filtered and unfiltered samples. The results for aluminum and molybdenum tended to be higher on the instrument designated to analyze unfiltered samples; the results for selenium tended to be lower. The matrices used to prepare calibration standards were different for the two instruments. The instrument designated for the analysis of unfiltered samples was calibrated using standards prepared in a nitric:hydrochloric acid (HNO 3 :HCl) matrix. The instrument designated for the analysis of filtered samples was calibrated using standards prepared in a matrix acidified only with HNO 3 . Matrix chemistry may have influenced the responses of aluminum, molybdenum, and selenium on the two instruments. The best analytical practice is to calibrate instruments using calibration standards prepared in matrices that reasonably match those of the samples being analyzed. Filtered and unfiltered samples were spiked over a range of trace-element concentrations from less than 1 to 58 times ambient concentrations. The greater the magnitude of the trace-element spike concentration relative to the ambient concentration, the greater the likelihood spike recoveries will be within data control guidelines (80–120 percent). Greater variability in spike recoveries occurred when trace elements were spiked at concentrations less than 10 times the ambient concentration. Spike recoveries that were considerably lower than 90 percent often were associated with spiked concentrations substantially lower than what was present in the ambient sample. Because the main purpose of spiking natural water samples with known quantities of a particular analyte is to assess possible matrix effects on analytical results, the results of this study stress the importance of spiking samples at concentrations that are reasonably close to what is expected but sufficiently high to exceed analytical variability. Generally, differences in spike recovery results between paired filtered and unfiltered samples were minimal when samples were analyzed on the same instrument. Analytical results for trace-element concentrations in ambient filtered and unfiltered samples greater than 10 and 40 μg/L, respectively, were within the data-quality objective for precision of ±25 percent. Ambient trace-element concentrations in filtered samples greater than the long-term method detection limits but less than 10 μg/L failed to meet the data-quality objective for precision for at least one trace element in about 54 percent of the samples. Similarly, trace-element concentrations in unfiltered samples greater than the long-term method detection limits but less than 40 μg/L failed to meet this data-quality objective for at least one trace-element analysis in about 58 percent of the samples. Although, aluminum and zinc were particularly problematic, limited re-analyses of filtered and unfiltered samples appeared to improve otherwise failed analytical precision. The evaluation of analytical bias using standard reference materials indicate a slight low bias for results for arsenic, cadmium, selenium, and zinc. Aluminum and molybdenum show signs of high bias. There was no observed bias, as determined using the standard reference materials, during the analysis of lead.

Scientific Investigations Report↗

Genetic analyses of Astragalus sect. Humillimi (Fabaceae) resolve taxonomy and enable effective conservation

Premise of the Study Astragalus sect. Humillimi is distributed across the southwestern United States and contains two endangered taxa, A. cremnophylax var. cremnophylax and A. humillimus . The former was originally described from the South Rim of the Grand Canyon. Analysis of individuals discovered on the North Rim of the Grand Canyon yielded some evidence that the population represented a distinct species. To enable effective conservation, we clarify the group's taxonomy and characterize the genetic diversity of A. cremnophylax and A. humillimus . Methods We used AFLPs to genotype most species in sect. Humillimi , focusing on the two endangered forms. We examined patterns of genetic diversity using complementary analytical approaches. Key Results Our results demonstrate that North Rim populations group with A. c . var. cremnophylax . We found low levels of genetic diversity at certain localities and strong differentiation among populations. Astragalus humillimus , which has suffered recent and severe population declines, exhibits weak differentiation among and low diversity within populations. Conclusions Our results clarify the taxonomy of sect. Humillimi and define the boundaries of A. c . var. cremnophylax , which is shown to inhabit both rims of the Grand Canyon. This clarification, and detailed analysis of genetic variation within both endangered taxa, may advance ongoing efforts to conserve these taxa. Our results suggest that range‐wide genetic analysis of A. humillimus may inform recovery strategies for this taxon.

American Journal of Botany↗

The travel-time ellipse: An approximate zone of transport

A zone of transport for a well is defined as the area in the horizontal plane bounded by a contour of equal ground-water travel time to the well. For short distances and ground-water travel times near a well, the potentiometric surface may be simulated analytically as that for a fully penetrating well in a uniform flow field. The zone of transport for this configuration is nearly elliptical. A simple method is derived to calculate a travel-time ellipse that approximates the zone of transport for a well in a uniform flow field. The travel-time ellipse was nearly congruent with the exact solution for the theoretical zone of transport for ground-water travel times of at least 10 years and for aquifer property values appropriate for southeastern Minnesota. For distances and travel times approaching infinity, however, the ellipse becomes slightly wider at its midpoint and narrower near its upgradient boundary than the theoretical zone of transport. The travel-time ellipse also may be used to simulate the plume area surrounding an injection well. However, the travel-time ellipse is an approximation that does not account for the effect of dispersion in enlarging the true area of an injection plume or zone of transport; hence, caution is advised in the use and interpretation of this simple construction.

Journal of Hydrology↗

Rhyolitic and basaltic reference materials for TC/EA analysis: Investigation of water extraction and D/H ratios

Increasingly, water and D/H ratios of silicic and basaltic glasses are used to investigate magmatic degassing and secondary hydration, as well as for study these parameters in the mantle and crustal magmas. The advent of the High Temperature Conversion Element Analyzer (TC/EA) continuous flow mass spectrometry made the determination of hydrogen isotopes relatively quick and precise (±0.04 wt% H 2 O and 1–3‰ δ 2 H). Many labs around the world have such systems, thus there is a need to develop both silicic and basaltic volcanic glass reference materials (RMs) that can be used for interlaboratory comparison by bulk and microanalytical methods. Here, we report results of such investigation run against solid RMs (USGS micas) and water RMs (including VSMOW) in three different labs and describe analytical protocols. We report on the effects of glass size fraction, the mass of aliquots measured, and yield dependency for two glasses: UOR (drill cutting of IDDP-1 rhyolite, Iceland) and UOB (an E -MORB basalt from the East Pacific Rise). Proposed RM values are: UOB rhyolitic glass ( n = 31): H 2 O = 1.84 ± 0.06 wt% (1 s.d.), and δ 2 H = −115.5 ± 2.6‰ (1 s.d.). UOB basaltic glass ( n = 60): H 2 O = 0.37 ± 0.03 wt% (1 s.d.), and δ 2 H = −82.1 ± 5.7‰ (1 s.d.). Glass reference materials are available in 100 mg quantities from the Stable Isotope Laboratory at the University of Oregon for a nominal fee.

Chemical Geology↗

The absence of lithium isotope fractionation during basalt differentiation: New measurements by multicollector sector ICP-MS

We report measurements of the isotopic composition of lithium in basalts using a multicollector magnetic sector plasma-source mass spectrometer (MC-ICP-MS). This is the first application of this analytical technique to Li isotope determination. External precision of multiple replicate and duplicate measurements for a variety of sample types averages ±1.1‰ (2σ population). The method allows for the rapid (∼8 min/sample) analysis of small samples (∼40 ng Li) relative to commonly used thermal ionization methods. The technique has been applied to a suite of samples from Kilauea Iki lava lake, Hawaii. The samples range from olivine-rich cumulitic lava to SiO 2 − and K 2 O-enriched differentiated liquids, and have δ 7 Li (per mil deviation of sample 7 Li/ 6 Li relative to the L-SVEC standard) of +3.0 to +4.8. The data indicate a lack of per mil-level Li isotope fractionation as a result of crystal–liquid fractionation at temperatures greater than 1050°C. This conclusion has been tacitly assumed but never demonstrated, and is important to the interpretation of Li isotope results from such geochemically complex environments as island arcs.

Hawai'i↗

The comparison of usage and availability measurements for evaluating resource preference

Modern ecological research often involves the comparison of the usage of habitat types or food items to the availability of those resources to the animal. Widely used methods of determining preference from measurements of usage and availability depend critically on the array of components that the researcher, often with a degree of arbitrariness, deems available to the animal. This paper proposes a new method, based on ranks of components by usage and by availability. A virtue of the rank procedure is that it provides comparable results whether a questionable component is included or excluded from consideration. Statistical tests of significance are given for the method. The paper also offers a hierarchical ordering of selection processes. This hierarchy resolves certain inconsistencies among studies of selection and is compatible with the analytic technique offered in this paper.

Ecology↗

Hydrologic and landscape database for the Cache and White River National Wildlife Refuges and contributing watersheds in Arkansas, Missouri, and Oklahoma

A hydrologic and landscape database was developed by the U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, for the Cache River and White River National Wildlife Refuges and their contributing watersheds in Arkansas, Missouri, and Oklahoma. The database is composed of a set of ASCII files, Microsoft Access® files, Microsoft Excel® files, an Environmental Systems Research Institute (ESRI) ArcGIS® geodatabase, ESRI ArcGRID® raster datasets, and an ESRI ArcReader® published map. The database was developed as an assessment and evaluation tool to use in examining refuge-specific hydrologic patterns and trends as related to water availability for refuge ecosystems, habitats, and target species; and includes hydrologic time-series data, statistics, and hydroecological metrics that can be used to assess refuge hydrologic conditions and the availability of aquatic and riparian habitat. Landscape data that describe the refuge physiographic setting and the locations of hydrologic-data collection stations are also included in the database. Categories of landscape data include land cover, soil hydrologic characteristics, physiographic features, geographic and hydrographic boundaries, hydrographic features, regional runoff estimates, and gaging-station locations. The database geographic extent covers three hydrologic subregions—the Lower Mississippi–St Francis (0802), the Upper White (1101), and the Lower Arkansas (1111)—within which human activities, climatic variation, and hydrologic processes can potentially affect the hydrologic regime of the refuges and adjacent areas. Database construction has been automated to facilitate periodic updates with new data. The database report (1) serves as a user guide for the database, (2) describes the data-collection, data-reduction, and data-analysis methods used to construct the database, (3) provides a statistical and graphical description of the database, and (4) provides detailed information on the development of analytical techniques designed to assess water availability for ecological needs.

Arkansas;Missouri;Oklahoma↗

Landbird trends in national parks of the North Coast and Cascades Network, 2005-12

National parks in the North Coast and Cascades Network (NCCN) can fulfill vital roles as refuges for bird species dependent on late-successional forest conditions and as reference sites for assessing the effects of land-use and land-cover changes on bird populations throughout the larger Pacific Northwest region. Additionally, long-term monitoring of landbirds throughout the NCCN provides information that can inform decisions about important management issues in the parks, including visitor impacts, fire management, and the effects of introduced species. In 2005, the NCCN began implementing a network-wide Landbird Monitoring Project as part of the NPS Inventory and Monitoring Program. In this report, we discuss 8-year trends (2005–12) of bird populations in the NCCN, based on a sampling framework of point counts established in three large wilderness parks (Mount Rainier, North Cascades, and Olympic National Parks), 7-year trends at Lewis and Clark National Historical Park (sampled in 2006, 2008, 2010, and 2012), and 5-year trends at San Juan Islands National Historical Park (sampled in 2007, 2009, and 2011). Our analysis encompasses a fairly short time span for this long-term monitoring program. The first 2 years of the time series (2005 and 2006) were implemented as part of a limited pilot study that included only a small subset of the transects. The subsequent 6 years (2007–12) represent just a single cycle through 5 years of alternating panels of transects in the large parks, with the first of five alternating panels revisited for the first time in 2012. Of 204 transects that comprise the six sampling panels in the large parks, only 68 (one-third) have thus been eligible for revisit surveys (34 during every year after 2005, and an additional 34 only in 2012) and can contribute to our current trend estimates. We therefore initiated the current analysis with a primary goal of testing our analytical procedures rather than detecting trends that might be strong enough to drive conservation or management decisions in the parks or elsewhere. We expect that aggregated trend detection results may change substantially over the next several years, as the number of transects with revisit histories triples and the spatial dispersion of transects contributing to trend estimates also improves greatly. In the meantime, caution should be exercised in interpreting the importance of trends, as individual years can have very large influences on the direction and magnitude of trends in a time series of such limited duration (and limited numbers of repeat visits at the small parks). Nevertheless, we estimated trends for 43 species at Mount Rainier National Park, 53 species at North Cascades National Park Complex, and 41 species at Olympic National Park. Of 137 park-species combinations (including combined-park analyses), we found 16 significant decreases (12 percent) and five significant increases (4 percent). We identify several limitations of the current analytical framework for trend assessment but suggest that the overall sampling design is strong and amenable to analysis by more recently developed model-based methods. These could provide a more flexible framework for examining trends and other population parameters of interest, as well as testing hypotheses that relate the distribution and abundance of species to environmental covariates. A model-based approach would allow for modeling various components of the detection process and analyzing observations (detection process), population state (occupancy, population size, density), and change (trend, local extinction and colonization rates turnover) simultaneously. Finally, we also evaluate operational aspects of NCCN Landbird Monitoring Project, and conclude that our robust, multi-party partnership is successfully implementing the project as it was envisioned.

British Columbia;Oregon;Washington↗

An interactive code (NETPATH) for modeling NET geochemical reactions along a flow PATH, version 2.0

NETPATH is an interactive Fortran 77 computer program used to interpret net geochemical mass-balance reactions between an initial and final water along a hydrologic flow path. Alternatively, NETPATH computes the mixing proportions of two to five initial waters and net geochemical reactions that can account for the observed composition of a final water. The program utilizes previously defined chemical and isotopic data for waters from a hydrochemical system. For a set of mineral and (or) gas phases hypothesized to be the reactive phases in the system, NETPATH calculates the mass transfers in every possible combination of the selected phases that accounts for the observed changes in the selected chemical and (or) isotopic compositions observed along the flow path. The calculations are of use in interpreting geochemical reactions, mixing proportions, evaporation and (or) dilution of waters, and mineral mass transfer in the chemical and isotopic evolution of natural and environmental waters. Rayleigh distillation calculations are applied to each mass-balance model that satisfies the constraints to predict carbon, sulfur, nitrogen, and strontium isotopic compositions at the end point, including radiocarbon dating. DB is an interactive Fortran 77 computer program used to enter analytical data into NETPATH, and calculate the distribution of species in aqueous solution. This report describes the types of problems that can be solved, the methods used to solve problems, and the features available in the program to facilitate these solutions. Examples are presented to demonstrate most of the applications and features of NETPATH. The codes DB and NETPATH can be executed in the UNIX or DOS1 environment. This report replaces U.S. Geological Survey Water-Resources Investigations Report 91-4078, by Plummer and others, which described the original release of NETPATH, version 1.0 (dated December, 1991), and documents revisions and enhancements that are included in version 2.0. 1 The use of trade, brand or product names in this report is for identification purposes only and does not constitute endorsement by the U.S. Geological Survey.

Water-Resources Investigations Report↗

Sagebrush ecosystem conservation and management: Ecoregional assessment tools and models for the Wyoming Basins

The Wyoming Basins are one of the remaining strongholds of the sagebrush ecosystem. However, like most sagebrush habitats, threats to this region are numerous. This book adds to current knowledge about the regional status of the sagebrush ecosystem, the distribution of habitats, the threats to the ecosystem, and the influence of threats and habitat conditions on occurrence and abundance of sagebrush associated fauna and flora in the Wyoming Basins. Comprehensive methods are outlined for use in data collection and monitoring of wildlife and plant populations. Field and spatial data are integrated into a spatially explicit analytical framework to develop models of species occurrence and abundance for the egion. This book provides significant new information on distributions, abundances, and habitat relationships for a number of species of conservation concern that depend on sagebrush in the region. The tools and models presented in this book increase our understanding of impacts from land uses and can contribute to the development of comprehensive management and conservation strategies.

Wyoming↗

Determination of 2-isovaleryl-1,3-indandione with 2,4-dinitrophenylhydrazine. Rodenticide Analysis.

At present, three 2-alkyl-1,3-indandiones (PMP, pival, and diphacinon) are widely used as rodenticides. Because analytical procedures now in use are empirical and do not furnish adequate or positive means for distinguishing among these closely related compounds, studies were undertaken to develop a sensitive and specific method for the determination of PMP. The relation between KCN and the 2,4-dinitrophenylhydrazone of PMP was investigated and shown to be sensitive and specific. A deeply colored solution is produced with an absorption maximum at 540 mu. This solution obeys Beer?s law over a wide range. The molar absorptivity for the developed color was calculated to be 3.0 X 104. This reaction can be used also as a spot test to detect as little as 1 ug. of PMP.

Analytical Chemistry↗

Surface complexation studied via combined grazing-incidence EXAFS and surface diffraction: Arsenate on hematite (0001) and (10-12)

X-ray diffraction [crystal-truncation-rod (CTR)] studies of the surface structure of moisture-equilibrated hematite reveal sites for complexation not present on the bulk oxygen-terminated surface, and impose constraints on the types of inner-sphere sorption topologies. We have used this improved model of the hematite surface to analyze grazing-incidence EXAFS results for arsenate sorption on the c (0001) and r (10–12) surfaces measured in two electric vector polarizations. This work shows that the reconfiguration of the surface under moist conditions is responsible for an increased adsorption density of arsenate complexes on the (0001) surface relative to predicted ideal termination, and an abundance of “edge-sharing” bidentate complexes on both studied surfaces. We consider possible limitations on combining the methods due to differing surface sensitivities, and discuss further analysis possibilities using both methods.

Analytical and Bioanalytical Chemistry↗

Perchlorate isotope forensics

Perchlorate has been detected recently in a variety of soils, waters, plants, and food products at levels that may be detrimental to human health. These discoveries have generated considerable interest in perchlorate source identification. In this study, comprehensive stable isotope analyses ( 37 Cl/ 35 Cl and 18 O/ 17 O/ 16 O) of perchlorate from known synthetic and natural sources reveal systematic differences in isotopic characteristics that are related to the formation mechanisms. In addition, isotopic analyses of perchlorate extracted from groundwater and surface water demonstrate the feasibility of identifying perchlorate sources in contaminated environments on the basis of this technique. Both natural and synthetic sources of perchlorate have been identified in water samples from some perchlorate occurrences in the United States by the isotopic method.

Analytical Chemistry↗

Volumetric determination of uranium: Titanous sulfate as reductant before oxidimetric titration

Need for a more rapid volumetric method for the routine determination of uranium in uranium-rich materials has led to the development of a method that uses titanous sulfate as a reductant before oxidimetric titration. Separation of the hydrogen sulfide group is not necessary. Interfering elements precipitated by cupferron are removed by automatic filtrations made simultaneously rather than by the longer chloroform extraction method. Uranium is reduced from VI to IV by addition of an excess of titanous sulfate solution, cupric ion serving as an indicator by forming red metallic copper when reduction is complete. The copper is reoxidized by addition of mercuric perchlorate. The reduced uranium is then determined by addition of excess ferric sulfate and titration with ceric sulfate. The method has proved to be rapid, accurate, and economical.

Analytical Chemistry↗

Quantitative radiochemical methods for determination of the sources of natural radioactivity

Study of the state of equilibrium of any natural radioactive source requires determination of several key nuclides or groups of nuclides to find their contribution to the total amount of radioactivity. Alpha activity measured by scintillation counting is used for determination of protactinium-231, thorium-232, thorium-230, and radium-226. The chemical procedures for the separations of the specific elements are described, as well as the measurement techniques used to determine the abundances of the individual isotopes. To correct for deviations in the ore standards, an independent means of evaluating the efficiencies of the individual separations and measurements is used. The development of these methods of radiochemical analysis facilitates detailed investigation of the major sources of natural radioactivity.

Analytical Chemistry↗