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At least 901 records · Page 50Linked to original sources

Processes controlling the episodic streamwater transport of atrazine and other agrichemicals in an agricultural watershed

Episodic streamwater transport of atrazine (a common agricultural herbicide) and nutrients has been observed throughout agricultural watersheds in the United States and poses a serious threat to the quality of its water resources. Catchment-scale atrazine and nutrient transport processes after agricultural application are still poorly understood, and predicting episodic streamwater composition remains an elusive goal. We instrumented a 1.2-km 2 agricultural catchment near Harrisonburg, Virginia, and examined streamwater, overland flow, soil water, groundwater, and rainfall during the summer of 1998. Storm chemographs demonstrated different patterns for constituents derived primarily from weathering (silica and calcium), compared to constituents derived primarily from early spring land applications (nitrate, atrazine, DOC, potassium, chloride, and sulfate). During storms, the concentrations of silica and calcium decreased, the atrazine response was variable, and the concentrations of nitrate, DOC, potassium, chloride, and sulfate increased; the elevated nitrate signal lagged several hours behind the other elevated constituents. Graphical and statistical analyses indicated a relatively stable spring-fed baseflow was modified by a mixture of overland flow and soil water. A rapid, short-duration overland-flow pulse dominated the streamflow early in the event and contributed most of the potassium, DOC, chloride, suspended sediment, and atrazine. A longer-duration soil–water pulse dominated the streamflow later in the event and contributed the nitrate as well as additional potassium, DOC, sulfate, and atrazine. The contributions to the episodic streamflow were quantified using a flushing model in which overland-flow and soil–water concentrations decreased exponentially with time during an episode. Flushing time constants for the overland-flow and soil–water reservoirs were calculated on a storm-by-storm basis using separate tracers for each time-variable reservoir. Initial component concentrations were estimated through regression analyses. Mass-balance calculations were used for flow separations and to predict the observed streamwater composition. Model forecasts indicated that reduced fertilizer and pesticide application (rather than elimination of overland-flow or soil–water contributions) was necessary to improve the episodic streamwater composition. This study provides important additional understanding of the catchment-scale processes by which land-applied pesticides and nutrients can move through agricultural systems.

Virginia↗

Recent and projected precipitation and temperature changes in the Grand Canyon area with implications for groundwater resources

Groundwater is a critical resource in the Grand Canyon region, supplying nearly all water needs for residents and millions of visitors. Additionally, groundwater discharging at hundreds of spring locations in and near Grand Canyon supports important ecosystems in this mostly arid environment. The security of groundwater supplies is of critical importance for both people and ecosystems in the region and the potential for changes to groundwater systems from projected climate change is a cause for concern. In this study, we analyze recent historical and projected precipitation and temperature data for the Grand Canyon region. Projected climate scenarios are then used in Soil Water Balance groundwater infiltration simulations to understand the state-of-the-science on projected changes to groundwater resources in the area. Historical climate data from 1896 through 2019 indicate multi-decadal cyclical patterns in both precipitation and temperature for most of the time period. Since the 1970s, however, a significant rising trend in temperature is observed in the area. All 10-year periods since 1993 are characterized by both below average precipitation and above average temperature. Downscaled and bias-corrected precipitation and temperature output from 97 CMIP5 global climate models for the water-year 2020–2099 time period indicate projected precipitation patterns similar to recent historical (water-year 1951–2015) data. Projected temperature for the Grand Canyon area, however, is expected to rise by as much as 3.4 °C by the end of the century, relative to the recent historical average. Integrating the effects of projected precipitation and temperature changes on groundwater infiltration, simulation results indicate that > 76% of future decades will experience average potential groundwater infiltration less than that of the recent historical period.

Arizona, Utah↗

Exposed water ice discovered near the south pole of Mars

The Mars Odyssey Thermal Emission Imaging System (THEMIS) has discovered water ice exposed near the edge of Mars' southern perennial polar cap. The surface H2O ice was first observed by THEMIS as a region that was cooler than expected for dry soil at that latitude during the summer season. Diurnal and seasonal temperature trends derived from Mars Global Surveyor Thermal Emission Spectrometer observations indicate that there is H2O ice at the surface. Viking observations, and the few other relevant THEMIS observations, indicate that surface H2O ice may be widespread around and under the perennial CO2 cap.

Science↗

Regional nitrate and pesticide trends in ground water in the eastern San Joaquin Valley, California

Protection of ground water for present and future use requires monitoring and understanding of the mechanisms controlling long-term quality of ground water. In this study, spatial and temporal trends in concentrations of nitrate and pesticides in ground water in the eastern San Joaquin Valley, California, were evaluated to determine the long-term effects of agricultural and urban development on regional ground-water quality. Trends in concentrations of nitrate, the nematocide 1,2-dibromo-3-chloropropane, and the herbicide simazine during the last two decades are generally consistent with known nitrogen fertilizer and pesticide use and with the position of the well networks in the regional ground-water flow system. Concentrations of nitrate and pesticides are higher in the shallow part of the aquifer system where domestic wells are typically screened, whereas concentrations are lower in the deep part of the aquifer system where public-supply wells are typically screened. Attenuation processes do not seem to significantly affect concentrations. Historical data indicate that concentrations of nitrate have increased since the 1950s in the shallow and deep parts of the aquifer system. Concentrations of nitrate and detection of pesticides in the deep part of the aquifer system will likely increase as the proportion of highly affected water contributed to these wells increases with time. Because of the time of travel between the water table and the deep part of the aquifer system, current concentrations in public-supply wells likely reflect the effects of 40- to 50-yr-old management practices. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Conference Paper↗

The contribution of rice agriculture to methylmercury in surface waters: A review of data from the Sacramento Valley, California

Methylmercury (MeHg) is a bioaccumulative pollutant produced in and exported from flooded soils, including those used for rice ( Oriza sativa L.) production. Using unfiltered aqueous MeHg data from MeHg monitoring programs in the Sacramento River watershed from 1996 to 2007, we assessed the MeHg contribution from rice systems to the Sacramento River. Using a mixed-effects regression analysis, we compared MeHg concentrations in agricultural drainage water from rice-dominated regions (AgDrain) to MeHg concentrations in the Sacramento and Feather Rivers, both upstream and downstream of AgDrain inputs. We also calculated MeHg loads from AgDrains and the Sacramento and Feather Rivers. Seasonally, MeHg concentrations were higher during November through May than during June through October, but the differences varied by location. Relative to upstream, November through May AgDrain least-squares mean MeHg concentration (0.18 ng L −1 , range 0.15–0.23 ng L −1 ) was 2.3-fold higher, while June through October AgDrain mean concentration (0.097 ng L −1 , range 0.6–1.6 ng L −1 ) was not significantly different from upstream. June through October AgDrain MeHg loads contributed 10.7 to 14.8% of the total Sacramento River MeHg load. Missing flow data prevented calculation of the percent contribution of AgDrains in November through May. At sites where calculation was possible, November through May loads made up 70 to 90% of the total annual load. Elevated flow and MeHg concentration in November through May both contribute to the majority of the AgDrain MeHg load occurring during this period. Methylmercury reduction efforts should target elevated November through May MeHg concentrations in AgDrains. However, our findings suggest that the contribution and environmental impact of rice is an order of magnitude lower than previous studies in the California Yolo Bypass.

California↗

Development and calibration of a ground-water flow model for the Sparta Aquifer of southeastern Arkansas and north-central Louisiana and simulated response to withdrawals, 1998-2027

The Sparta aquifer, which consists of the Sparta Sand, in southeastern Arkansas and north-central Louisiana is a major water resource and provides water for municipal, industrial, and agricultural uses. In recent years, the demand in some areas has resulted in withdrawals from the Sparta aquifer that substantially exceed replenishment of the aquifer. Considerable drawdown has occurred in the potentiometric surface forming regional cones of depression as water is removed from storage by withdrawals. These cones of depression are centered beneath the Grand Prairie area and the cities of Pine Bluff and El Dorado in Arkansas, and Monroe in Louisiana. The rate of decline for hydraulic heads in the aquifer has been greater than 1 foot per year for more than a decade in much of southern Arkansas and northern Louisiana where hydraulic heads are now below the top of the Sparta Sand. Continued hydraulic-head declines have caused water users and managers alike to question the ability of the aquifer to supply water for the long term. Concern over protecting the Sparta aquifer as a sustainable resource has resulted in a continued, cooperative effort by the Arkansas Soil and Water Conservation Commission, U.S. Army Corps of Engineers, and the U.S. Geological Survey to develop, maintain, and utilize numerical ground-water flow models to manage and further analyze the ground-water system. The work presented in this report describes the development and calibration of a ground-water flow model representing the Sparta aquifer to simulate observed hydraulic heads, documents major differences in the current Sparta model compared to the previous Sparta model calibrated in the mid-1980's, and presents the results of three hypothetical future withdrawal scenarios. The current Sparta model-a regional scale, three-dimensional numerical ground-water flow model-was constructed and calibrated using available hydrogeologic, hydraulic, and water-use data from 1898 to 1997. Significant changes from the previous model include grid rediscretization of the aquifer, extension of the active model area northward beyond the Cane River Formation facies change, and representation of model boundaries. The current model was calibrated with the aid of parameter estimation, a nonlinear regression technique, combined with trial and error parameter adjustment using a total of 795 observations from 316 wells over 4 different years-1970, 1985, 1990, and 1997. The calibration data set provides broad spatial and temporal coverage of aquifer conditions. Analysis of the residual statistics, spatial distribution of residuals, simulated compared to observed hydrographs, and simulated compared to observed potentiometric surfaces were used to analyze the ability of the calibrated model to simulate aquifer conditions within acceptable error. The calibrated model has a root mean square error of 18 feet for all observations, an improvement of more than 12 feet from the previous model. The current Sparta model was used to predict the effects of three hypothetical withdrawal scenarios on hydraulic heads over the period 1998-2027 with one of those extended indefinitely until equilibrium conditions were attained, or steady state. In scenario 1a, withdrawals representing the time period from 1990 to 1997 was held constant for 30 years from 1998 to 2027. Hydraulic heads in the middle of the cone of depression centered on El Dorado decreased by 10 feet from the 1997 simulation to 222 feet below NGVD of 1929 in 2027. Hydraulic heads in the Pine Bluff cone of depression showed a greater decline from 61 feet below NGVD of 1929 to 78 feet below NGVD of 1929 in the center of the cone. With these same withdrawals extended to steady state (scenario 1b), hydraulic heads in the Pine Bluff cone of depression center declined an 2 Development and Calibration of a Ground-Water Flow Model for the Sparta Aquifer of Southeastern Arkansas and North-Central Louisiana and Simulated Response to Withdrawa

Water-Resources Investigations Report↗

Using Cl/Br ratios and other indicators to assess potential impacts on groundwater quality from septic systems: A review and examples from principal aquifers in the United States

A detailed review was made of chemical indicators used to identify impacts from septic tanks on groundwater quality. Potential impacts from septic tank leachate on groundwater quality were assessed using the mass ratio of chloride–bromide (Cl/Br), concentrations of selected chemical constituents, and ancillary information (land use, census data, well depth, soil characteristics) for wells in principal aquifers of the United States. Chemical data were evaluated from 1848 domestic wells in 19 aquifers, 121 public-supply wells in 6 aquifers, and associated monitoring wells in four aquifers and their overlying hydrogeologic units. Based on previously reported Cl/Br ratios, statistical comparisons between targeted wells (where Cl/Br ratios range from 400 to 1100 and Cl concentrations range from 20 to 100 mg/L) and non-targeted wells indicated that shallow targeted monitoring and domestic wells (<20 m depth below land surface) had a significantly ( p < 0.05) higher median percentage of houses with septic tanks (1990 census data) than non-targeted wells. Higher ( p = 0.08) median nitrate–N concentration (3.1 mg/L) in oxic (dissolved oxygen concentrations >0.5 mg/L) shallow groundwater from target domestic wells, relative to non-target wells (1.5 mg/L), corresponded to significantly higher potassium, boron, chloride, dissolved organic carbon, and sulfate concentrations, which may also indicate the influence of septic-tank effluent. Impacts on groundwater quality from septic systems were most evident for the Eastern Glacial Deposits aquifer and the Northern High Plains aquifer that were associated with the number of housing units using septic tanks, high permeability of overlying sediments, mostly oxic conditions, and shallow wells. Overall, little or no influence from septic systems were found for water samples from the deeper public-supply wells. The Cl/Br ratio is a useful first-level screening tool for assessing possible septic tank influence in water from shallow wells (<20 m) with the range of 400–1100. The use of this ratio would be enhanced with information on other chloride sources, temporal variability of chloride and bromide concentrations in shallow groundwater, knowledge of septic-system age and maintenance, and the use of multiple tracers (combination of additional chemical and microbiological indicators).

Journal of Hydrology↗

Resilience to fire and resistance to annual grass invasion in sagebrush ecosystems of US National Parks

Western North American sagebrush shrublands and steppe face accelerating risks from fire-driven feedback loops that transition these ecosystems into self-reinforcing states dominated by invasive annual grasses. In response, sagebrush conservation decision-making is increasingly done through the lens of resilience to fire and annual grass invasion resistance. Operationalizing resilience and resistance concepts requires place-based understanding of resilience and resistance variation among landscapes over time. Place-based insights allow for landscape prioritization in targeted areas of significance such as protected-area sagebrush ecosystems that exhibit inherently low resilience and are therefore at high risk of loss. We used a multi-scale approach to evaluate sagebrush resiliency and strategic planning across 1) the US National Park system, 2) a regional suite of five parks, and 3) for two specific park case studies. First, we summarized broad patterns of relative resilience to fire and resistance to annual grass invasion across all parks with sagebrush ecosystems. We found that national parks represented ~11% of US protected-area sagebrush ecosystems and reflected a similar low-resilience bias that occurs across the biome, broadly. Climate change is likely to shift both low- and high-resilience park sagebrush ecosystems towards moderate resiliency, creating new opportunities and constraints for park conservation. Approximately seventy park units include at least some sagebrush shrublands or steppe, but we identified 40 parks with substantial amounts (>20% of park area) that can be included in an agency-wide conservation strategy. Second, we examined detailed patterns of resilience and resistance, fire history and fire risk, cheatgrass ( Bromus tectorum ) invasion, and sagebrush shrub ( Artemisia spp.) persistence in five national park units in Columbia Basin and Snake River Plain sagebrush steppe, contextualized by the broader summary. In these five parks, fire frequency and size increased in recent decades. Cheatgrass invasion and sagebrush persistence correlated strongly with resilience, burn frequency (0–3 fires since ~1940), and burn probability, but with important variation, in part mediated by local-scale topography. Third, we used these insights to assemble strategic sagebrush ecosystem fire protection mapping scenarios in two additional parks – Lava Beds National Monument and Great Basin National Park. Readily available and periodically updated geospatial data including soil surveys, fire histories, vegetation inventories, and long-term monitoring support resiliency-based adaptive management through tactical planning of pre-fire protection, post-fire restoration, and triage. Our assessment establishes the precarious importance of the US national park system to sagebrush ecosystem conservation and an operational strategy for place-based and science-supported conservation.

Arizona, California, Colorado, Idaho, Montana, New↗

Development and implementation of a Bayesian-based aquifer vulnerability assessment in Florida

The Florida Aquifer Vulnerability Assessment (FAVA) was designed to provide a tool for environmental, regulatory, resource management, and planning professionals to facilitate protection of groundwater resources from surface sources of contamination. The FAVA project implements weights-of-evidence (WofE), a data-driven, Bayesian-probabilistic model to generate a series of maps reflecting relative aquifer vulnerability of Florida's principal aquifer systems. The vulnerability assessment process, from project design to map implementation is described herein in reference to the Floridan aquifer system (FAS). The WofE model calculates weighted relationships between hydrogeologic data layers that influence aquifer vulnerability and ambient groundwater parameters in wells that reflect relative degrees of vulnerability. Statewide model input data layers (evidential themes) include soil hydraulic conductivity, density of karst features, thickness of aquifer confinement, and hydraulic head difference between the FAS and the watertable. Wells with median dissolved nitrogen concentrations exceeding statistically established thresholds serve as training points in the WofE model. The resulting vulnerability map (response theme) reflects classified posterior probabilities based on spatial relationships between the evidential themes and training points. The response theme is subjected to extensive sensitivity and validation testing. Among the model validation techniques is calculation of a response theme based on a different water-quality indicator of relative recharge or vulnerability: dissolved oxygen. Successful implementation of the FAVA maps was facilitated by the overall project design, which included a needs assessment and iterative technical advisory committee input and review. Ongoing programs to protect Florida's springsheds have led to development of larger-scale WofE-based vulnerability assessments. Additional applications of the maps include land-use planning amendments and prioritization of land purchases to protect groundwater resources. ?? International Association for Mathematical Geology 2007.

Natural Resources Research↗

Pb-Sr isotopic and geochemical constraints on sources and processes of lead contamination in well waters and soil from former fruit orchards, Pennsylvania, USA: A legacy of anthropogenic activities

Isotopic discrimination can be an effective tool in establishing a direct link between sources of Pb contamination and the presence of anomalously high concentrations of Pb in waters, soils, and organisms. Residential wells supplying water containing up to 1600 ppb Pb to houses built on the former Mohr orchards commercial site, near Allentown, PA, were evaluated to discern anthropogenic from geogenic sources. Pb (n = 144) and Sr (n = 40) isotopic data and REE (n = 29) data were determined for waters from residential wells, test wells (drilled for this study), and surface waters from pond and creeks. Local soils, sediments, bedrock, Zn-Pb mineralization and coal were also analyzed (n = 94), together with locally used Pb-As pesticide (n = 5). Waters from residential and test wells show overlapping values of 206 Pb/ 207 Pb, 208 Pb/ 207 Pb and 87 Sr/ 86 Sr. Larger negative Ce anomalies (Ce/Ce*) distinguish residential wells from test wells. Results show that residential and test well waters, sediments from residential water filters in water tanks, and surface waters display broad linear trends in Pb isotope plots. Pb isotope data for soils, bedrock, and pesticides have contrasting ranges and overlapping trends. Contributions of Pb from soils to residential well waters are limited and implicated primarily in wells having shallow water-bearing zones and carrying high sediment contents. Pb isotope data for residential wells, test wells, and surface waters show substantial overlap with Pb data reflecting anthropogenic actions (e.g., burning fossil fuels, industrial and urban processing activities). Limited contributions of Pb from bedrock, soils, and pesticides are evident. High Pb concentrations in the residential waters are likely related to sediment build up in residential water tanks. Redox reactions, triggered by influx of groundwater via wells into the residential water systems and leading to subtle changes in pH, are implicated in precipitation of Fe oxyhydroxides, oxidative scavenging of Ce(IV), and desorption and release of Pb into the residential water systems. The Pb isotope features in the residences and the region are best interpreted as reflecting a legacy of industrial Pb present in underlying aquifers that currently supply the drinking water wells.

Pennsylvania↗

Water Budgets: Foundations for Effective Water-Resources and Environmental Management

INTRODUCTION Water budgets provide a means for evaluating availability and sustainability of a water supply. A water budget simply states that the rate of change in water stored in an area, such as a watershed, is balanced by the rate at which water flows into and out of the area. An understanding of water budgets and underlying hydrologic processes provides a foundation for effective water-resource and environmental planning and management. Observed changes in water budgets of an area over time can be used to assess the effects of climate variability and human activities on water resources. Comparison of water budgets from different areas allows the effects of factors such as geology, soils, vegetation, and land use on the hydrologic cycle to be quantified. Human activities affect the natural hydrologic cycle in many ways. Modifications of the land to accommodate agriculture, such as installation of drainage and irrigation systems, alter infiltration, runoff, evaporation, and plant transpiration rates. Buildings, roads, and parking lots in urban areas tend to increase runoff and decrease infiltration. Dams reduce flooding in many areas. Water budgets provide a basis for assessing how a natural or human-induced change in one part of the hydrologic cycle may affect other aspects of the cycle. This report provides an overview and qualitative description of water budgets as foundations for effective water-resources and environmental management of freshwater hydrologic systems. Perhaps of most interest to the hydrologic community, the concepts presented are also relevant to the fields of agriculture, atmospheric studies, meteorology, climatology, ecology, limnology, mining, water supply, flood control, reservoir management, wetland studies, pollution control, and other areas of science, society, and industry. The first part of the report describes water storage and movement in the atmosphere, on land surface, and in the subsurface, as well as water exchange among these compartments. Our ability to measure these phenomena and inherent uncertainties in measurement techniques also are discussed. The latter part of the report presents a number of case studies that illustrate how water-budget studies are conducted, documents how human activities affect water budgets, and describes how water budgets are used to address water and environmental issues.

Circular↗

The Loma Prieta, California, Earthquake of October 17, 1989: Performance of the built environment

Professional Paper 1552 focuses on the response of buildings, lifelines, highway systems, and earth structures to the earthquake. Losses to these systems totaled approximated $5.9 billion. The earthquake displaced many residents from their homes and severely disrupted transportation systems. Some significant findings were: * Approximately 16,000 housing units were uninhabitable after the earthquake including 13,000 in the San Francisco Bay region. Another 30,000-35,000 units were moderately damaged in the earthquake. Renters and low-income residents were particularly hard hit. * Failure of highway systems was the single largest cause of loss of life during the earthquake. Forty-two of the 63 earthquake fatalities died when the Cypress Viaduct in Oakland collapsed. The cost to repair and replace highways damaged by the earthquake was $2 billion, about half of which was to replace the Cypress Viaduct. * Major bridge failures were the result of antiquated designs and inadequate anticipation of seismic loading. * Twenty one kilometers (13 mi) of gas-distribution lines had to be replaced in several communities and more than 1,200 leaks and breaks in water mains and service connections had to be excavated and repaired. At least 5 electrical substations were badly damaged, overwhelming the designed redundancy of the electrical system. * Instruments in 28 buildings recorded their response to earthquake shaking that provided opportunities to understand how different types of buildings responded, the importance of site amplification, and how buildings interact with their foundation when shaken (soil structure interaction).

Professional Paper↗

Phosphorus component in AnnAGNPS

The USDA Annualized Agricultural Non-Point Source Pollution model (AnnAGNPS) has been developed to aid in evaluation of watershed response to agricultural management practices. Previous studies have demonstrated the capability of the model to simulate runoff and sediment, but not phosphorus (P). The main purpose of this article is to evaluate the performance of AnnAGNPS on P simulation using comparisons with measurements from the Deep Hollow watershed of the Mississippi Delta Management Systems Evaluation Area (MDMSEA) project. A sensitivity analysis was performed to identify input parameters whose impact is the greatest on P yields. Sensitivity analysis results indicate that the most sensitive variables of those selected are initial soil P contents, P application rate, and plant P uptake. AnnAGNPS simulations of dissolved P yield do not agree well with observed dissolved P yield (Nash-Sutcliffe coefficient of efficiency of 0.34, R2 of 0.51, and slope of 0.24); however, AnnAGNPS simulations of total P yield agree well with observed total P yield (Nash-Sutcliffe coefficient of efficiency of 0.85, R2 of 0.88, and slope of 0.83). The difference in dissolved P yield may be attributed to limitations in model simulation of P processes. Uncertainties in input parameter selections also affect the model's performance.

Transactions of the American Society of Agricultur↗

Simulation of net infiltration and potential recharge using a distributed-parameter watershed model of the Death Valley region, Nevada and California

This report presents the development and application of the distributed-parameter watershed model, INFILv3, for estimating the temporal and spatial distribution of net infiltration and potential recharge in the Death Valley region, Nevada and California. The estimates of net infiltration quantify the downward drainage of water across the lower boundary of the root zone and are used to indicate potential recharge under variable climate conditions and drainage basin characteristics. Spatial variability in recharge in the Death Valley region likely is high owing to large differences in precipitation, potential evapotranspiration, bedrock permeability, soil thickness, vegetation characteristics, and contributions to recharge along active stream channels. The quantity and spatial distribution of recharge representing the effects of variable climatic conditions and drainage basin characteristics on recharge are needed to reduce uncertainty in modeling ground-water flow. The U.S. Geological Survey, in cooperation with the Department of Energy, developed a regional saturated-zone ground-water flow model of the Death Valley regional ground-water flow system to help evaluate the current hydrogeologic system and the potential effects of natural or human-induced changes. Although previous estimates of recharge have been made for most areas of the Death Valley region, including the area defined by the boundary of the Death Valley regional ground-water flow system, the uncertainty of these estimates is high, and the spatial and temporal variability of the recharge in these basins has not been quantified. To estimate the magnitude and distribution of potential recharge in response to variable climate and spatially varying drainage basin characteristics, the INFILv3 model uses a daily water-balance model of the root zone with a primarily deterministic representation of the processes controlling net infiltration and potential recharge. The daily water balance includes precipitation (as either rain or snow), snow accumulation, sublimation, snowmelt, infiltration into the root zone, evapotranspiration, drainage, water content change throughout the root-zone profile (represented as a 6-layered system), runoff (defined as excess rainfall and snowmelt) and surface water run-on (defined as runoff that is routed downstream), and net infiltration (simulated as drainage from the bottom root-zone layer). Potential evapotranspiration is simulated using an hourly solar radiation model to simulate daily net radiation, and daily evapotranspiration is simulated as an empirical function of root zone water content and potential evapotranspiration. The model uses daily climate records of precipitation and air temperature from a regionally distributed network of 132 climate stations and a spatially distributed representation of drainage basin characteristics defined by topography, geology, soils, and vegetation to simulate daily net infiltration at all locations, including stream channels with intermittent streamflow in response to runoff from rain and snowmelt. The temporal distribution of daily, monthly, and annual net infiltration can be used to evaluate the potential effect of future climatic conditions on potential recharge. The INFILv3 model inputs representing drainage basin characteristics were developed using a geographic information system (GIS) to define a set of spatially distributed input parameters uniquely assigned to each grid cell of the INFILv3 model grid. The model grid, which was defined by a digital elevation model (DEM) of the Death Valley region, consists of 1,252,418 model grid cells with a uniform grid cell dimension of 278.5 meters in the north-south and east-west directions. The elevation values from the DEM were used with monthly regression models developed from the daily climate data to estimate the spatial distribution of daily precipitation and air temperature. The elevation values were also used to simulate atmosp

Water-Resources Investigations Report↗

Behaviorally-mediated trophic cascade attenuated by prey use of risky places at safe times

The mere threat of predation may incite behavioral changes in prey that lead to community-wide impacts on productivity, biodiversity, and nutrient cycling. The paucity of experimental manipulations, however, has contributed to controversy over the strength of this pathway in wide-ranging vertebrate systems. We investigated whether simulated gray wolf ( Canis lupus ) presence can induce behaviorally-mediated trophic cascades, specifically, whether the ‘fear’ of wolf olfactory cues alone can change deer foraging behavior in ways that affect plants and soils. Wolves were recently removed from the Cedar Creek Ecosystem Science Reserve (Minnesota, USA), such that consumptively mediated predator effects were negligible. At 32 experimental plots, we crossed two nested treatments: wolf urine application and herbivore exclosures. We deployed camera traps to quantify how white-tailed deer ( Odocoileus virginianus ) adjusted their spatiotemporal habitat use, foraging, and vigilance in response to wolf cues and how these behavioral changes affected plant productivity, plant communities, and soil nutrients. Weekly applications of wolf urine significantly altered deer behavior, but deer responses did not cascade to affect plant or soil properties. Deer substantially reduced crepuscular activity at wolf-simulated sites compared to control locations. As wolves in this area predominantly hunted during mornings and evenings, this response potentially allows deer to maximize landscape use by accessing dangerous areas when temporal threat is low. Our experiment suggests that prey may be sensitive to ‘dynamic’ predation risk that is structured across both space and time and, consequentially, prey use of risky areas during safe times may attenuate behaviorally-mediated trophic cascades at the predator–prey interface.

Minnesota↗

Deep subsurface drip irrigation using coal-bed sodic water: part I. water and solute movement

Water co-produced with coal-bed methane (CBM) in the semi-arid Powder River Basin of Wyoming and Montana commonly has relatively low salinity and high sodium adsorption ratios that can degrade soil permeability where used for irrigation. Nevertheless, a desire to derive beneficial use from the water and a need to dispose of large volumes of it have motivated the design of a deep subsurface drip irrigation (SDI) system capable of utilizing that water. Drip tubing is buried 92 cm deep and irrigates at a relatively constant rate year-round, while evapotranspiration by the alfalfa and grass crops grown is seasonal. We use field data from two sites and computer simulations of unsaturated flow to understand water and solute movements in the SDI fields. Combined irrigation and precipitation exceed potential evapotranspiration by 300-480 mm annually. Initially, excess water contributes to increased storage in the unsaturated zone, and then drainage causes cyclical rises in the water table beneath the fields. Native chloride and nitrate below 200 cm depth are leached by the drainage. Some CBM water moves upward from the drip tubing, drawn by drier conditions above. Chloride from CBM water accumulates there as root uptake removes the water. Year over year accumulations indicated by computer simulations illustrate that infiltration of precipitation water from the surface only partially leaches such accumulations away. Field data show that 7% and 27% of added chloride has accumulated above the drip tubing in an alfalfa and grass field, respectively, following 6 years of irrigation. Maximum chloride concentrations in the alfalfa field are around 45 cm depth but reach the surface in parts of the grass field, illustrating differences driven by crop physiology. Deep SDI offers a means of utilizing marginal quality irrigation waters and managing the accumulation of their associated solutes in the crop rooting zone.

Wyoming↗

Revision of Fontes & Garnier's model for the initial 14 C content of dissolved inorganic carbon used in groundwater dating

The widely applied model for groundwater dating using 14 C proposed by Fontes and Garnier (F&G) (Fontes and Garnier, 1979) estimates the initial 14 C content in waters from carbonate-rock aquifers affected by isotopic exchange. Usually, the model of F&G is applied in one of two ways: (1) using a single 13 C fractionation factor of gaseous CO 2 with respect to a solid carbonate mineral, εg/s, regardless of whether the carbon isotopic exchange is controlled by soil CO 2 in the unsaturated zone, or by solid carbonate mineral in the saturated zone; or (2) using different fractionation factors if the exchange process is dominated by soil CO 2 gas as opposed to solid carbonate mineral (typically calcite). An analysis of the F&G model shows an inadequate conceptualization, resulting in underestimation of the initial 14 C values ( 14 C 0 ) for groundwater systems that have undergone isotopic exchange. The degree to which the 14 C 0 is underestimated increases with the extent of isotopic exchange. Examples show that in extreme cases, the error in calculated adjusted initial 14 C values can be more than 20% modern carbon (pmc). A model is derived that revises the mass balance method of F&G by using a modified model conceptualization. The derivation yields a “global” model both for carbon isotopic exchange dominated by gaseous CO 2 in the unsaturated zone, and for carbon isotopic exchange dominated by solid carbonate mineral in the saturated zone. However, the revised model requires different parameters for exchange dominated by gaseous CO 2 as opposed to exchange dominated by solid carbonate minerals. The revised model for exchange dominated by gaseous CO 2 is shown to be identical to the model of Mook (Mook, 1976). For groundwater systems where exchange occurs both in the unsaturated zone and saturated zone, the revised model can still be used; however, 14 C 0 will be slightly underestimated. Finally, in carbonate systems undergoing complex geochemical reactions, such as oxidation of organic carbon, radiocarbon ages are best estimated by inverse geochemical modeling techniques.

Chemical Geology↗