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Geology of the Wadi Ash Shu'bah Quadrangle, Sheet 26 E, Kingdom of Saudi Arabia

The Wadi Ash Shu'bah quadrangle, located in the north-central part of the Arabian Shield, is underlain by nine Precambrian volcano-sedimentary formations and a wide compositional range of Precambrian intrusive rocks. Late Proterozoic to early Paleozoic rocks of the Jibalah Group crop out in the southwestern part of the quadrangle. Paleozoic and younger units are limited to the early Paleozoic Siq Sandstone that crops out in the northwestern part of the quadrangle and small outcrops of Cenozoic basalt and unconsolidated Quaternary sediments. The Hulayfah group, dated at older than 738 Ma, is the oldest volcano-sedimentary unit in the quadrangle and consists of metamorphosed basaltic to andesitic volcanic and subvolcanic rock, and interbedded limestone, sandstone, and silicic volcanic rock. The Maraghan formation is composed of strongly folded, fine-grained sedimentary rock that was deposited between 677 and 621 Ma. The Hadn and Hibshi formations are composed of rhyolitic to rhyodacitic volcanic rock and interbedded continental sedimentary rock that were deposited between 651 and 600 Ma, but are inferred to postdate the Maraghan formation because they are significantly less deformed. Andesitic flows and volcanic breccia in the southeast corner of the quadrangle are mapped as the Jurdhawiyah group; these rocks unconformably overlie the Maraghan formation. The Zarghat formation is a thick sequence of interbedded sedimentary rock and silicic volcanic rock, and unconformably overlies the Hadn formation. It is inferred to have been deposited between 600 and 580 Ma. The Precambrian igneous rocks are organized into four tentative magmatic episodes. Greenstone of the Hulayfah group and dioritic intrusive rocks represent the oldest episode, and are believed to have formed in an ensimatic magmatic arc environment. These rocks were intruded during a second magmatic episode by post-Hulayfah monzogranite and granodiorite. A still younger, post-Hadn magmatic episode is represented by alkali-feldspar granite and syenogranite. The most recent magmatic episode is represented by small diabase and gabbro intrusions that are inferred to have been emplaced during a period of crustal rifting coincident with the deposition of the Jibalah group. The magnesite deposit near the village of Zarghat is the most significant mineral deposit in the quadrangle. However, the Hulayfah group has the most potential for metallic deposits in the area as it contains numerous gossans and ancient mine workings.

Open-File Report↗

Geophysical-geological analysis of Fairfax County, Virginia

Aeromagnetic, aeroradioactivity, and gravity surveys of Fairfax County, Virginia, are interpreted with the aid of existing geologic data and local geophysical measurements. Highly magnetic metasedimentary rocks of the Peters Creek Schist and Sykesville Formation produce most of the magnetic anomalies of Fairfax County. In contrast, the granitoid rocks of the Occoquan pluton are relatively non-magnetic and are characterized by broad magnetic and gravity lows. Linear magnetic highs without corresponding gravity anomalies, plus samples from a test well, indicate that Peters Creek Schist underlies the east side of the Triassic-Jurassic Culpeper basin. The continuation of the Piney Branch mafic-ultramafic complex beneath the basin is indicated by a gravity high. Basement lithology beneath the Coastal Plain sediments is interpreted by the following anomaly combinations: Sykesville Formation - magnetic high with no gravity expression; Chopawamsic Formation -magnetic and corresponding gravity high; Occoquan granitoid rocks -magnetic and corresponding gravity low. Analysis of a detailed gravity profile across a diabase body near Herndon indicates that the intrusive is a sill which is partly discordant with the sedimentary rocks of the Culpeper basin. The limbs of the horseshoe-shaped exposure dip gently toward the center; the west limb, 500 m thick, dips 15° east and the east limb, 250 m thick, dips west 3° or less. A second gravity profile across a similar diabase body near Centreville suggests that part of its western limb consists of a narrow dike-like body projecting upwards from a 200 m-thick buried sill. Both of these bodies apparently have a spoon-shaped structure with a discordant northern edge which was probably controlled by faulting. Similarities between these intrusives apply also to the small Boyds diabase in Maryland. The three diabase bodies are aligned, have similar magnetic expressions, and abut the edge of the Culpeper basin, suggesting that they were intruded under similar structural settings at about the same time. The northward decrease in size of these intrusives may be a consequence of the inward-dipping shape and a greater degree of uplift and deeper erosion to the north. By this reasoning, the Boyds body represents only the basal remnant of a largely eroded structure with the Centreville body preserving more of the original form. A ground magnetometer survey and an aeroradioactivity survey indicate the presence of additional zones in the thermal metamorphic aureole in the sedimentary rocks around the large diabase bodies. A 150-300-m-wide inner magnetite-rich zone above and below the Herndon sill is inferred from anomalies on a detailed ground magnetic profile. Aeroradioactivity data show a rim of high values outside the geologically mapped aureole of both the Herndon and Centreville bodies. This suggests a subtle outer zone slightly enriched in thermally expelled radio-elements. Deep resistivity soundings in the Culpeper basin indicate that the sedimentary rocks may reach a thickness of about 3600 feet (1100 m) at the western edge of the county.

Virginia↗

Effects of Land-Use Changes and Ground-Water Withdrawals on Stream Base Flow, Pocono Creek Watershed, Monroe County, Pennsylvania

The Pocono Creek watershed drains 46.5 square miles in eastern Monroe County, Pa. Between 2000 and 2020, the population of Monroe County is expected to increase by 70 percent, which will result in substantial changes in land-use patterns. An evaluation of the effect of reduced recharge from land-use changes and additional ground-water withdrawals on stream base flow was done by the U.S. Geological Survey (USGS) in cooperation with the U.S. Environmental Protection Agency (USEPA) and the Delaware River Basin Commission as part of the USEPA?s Framework for Sustainable Watershed Management Initiative. Two models were used. A Soil and Water Assessment Tool (SWAT) model developed by the USEPA provided areal recharge values for 2000 land use and projected full buildout land use. The USGS MODFLOW-2000 ground-water-flow model was used to estimate the effect of reduced recharge from changes in land use and additional ground-water withdrawals on stream base flow. This report describes the ground-water-flow-model simulations. The Pocono Creek watershed is underlain by sedimentary rock of Devonian age, which is overlain by a veneer of glacial deposits. All water-supply wells are cased into and derive water from the bedrock. In the ground-water-flow model, the surficial geologic units were grouped into six categories: (1) moraine deposits, (2) stratified drift, (3) lake deposits, (4) outwash, (5) swamp deposits, and (6) undifferentiated deposits. The unconsolidated surficial deposits are not used as a source of water. The ground-water and surface-water systems are well connected in the Pocono Creek watershed. Base flow measured on October 13, 2004, at 27 sites for model calibration showed that streams gained water between all sites measured except in the lower reach of Pocono Creek. The ground-water-flow model included the entire Pocono Creek watershed. Horizontally, the modeled area was divided into a 53 by 155 cell grid with 6,060 active cells. Vertically, the modeled area was discretized into four layers. Layers 1 and 2 represented the unconsolidated surficial deposits where they are present and bedrock where the surficial deposits are absent. Layer 3 represented shallow bedrock and was 200 ft (feet) thick. Layer 4 represented deep bedrock and was 300 ft thick. A total of 873 cells representing streams were assigned to layer 1. Recharge rates for model calibration were provided by the USEPA SWAT model for 2000 land-use conditions. Recharge rates for 2000 for the 29 subwatersheds in the SWAT model ranged from 6.11 to 22.66 inches per year. Because the ground-water-flow model was calibrated to base-flow data collected on October 13, 2004, the 2000 recharge rates were multiplied by 1.18 so the volume of recharge was equal to the volume of streamflow measured at the mouth of Pocono Creek. During model calibration, adjustments were made to aquifer hydraulic conductivity and streambed conductance. Simulated base flows and hydraulic heads were compared to measured base flows and hydraulic heads using the root mean squared error (RMSE) between measured and simulated values. The RMSE of the calibrated model for base flow was 4.7 cubic feet per second for 27 locations, and the RMSE for hydraulic heads for 15 locations was 35 ft. The USEPA SWAT model was used to provide areal recharge values for 2000 and full buildout land-use conditions. The change in recharge ranged from an increase of 37.8 percent to a decrease of 60.8 percent. The ground-water-flow model was used to simulate base flow for 2000 and full buildout land-use conditions using steady-state simulations. The decrease in simulated base flow ranged from 3.8 to 63 percent at the streamflow-measurement sites. Simulated base flow at streamflow-gaging station Pocono Creek above Wigwam Run near Stroudsburg, Pa. (01441495), decreased 25 percent. This is in general agreement with the SWAT model, which estimated a 30.6-percent loss in base flow at the streamflow-gaging station.

Scientific Investigations Report↗

Geology and origin of the late Proterozoic Darb Zubaydah ophiolite, Kingdom of Saudi Arabia

The Late Proterozoic (830 ± 20 Ma) Darb Zubaydah ophiolite, north-central Arabian Shield, preserves a largely intact section consisting of ultramafic rocks, gabbro, diabase, granodiorite, and interbedded volcanic and sedimentary rocks. Formation of these rocks within or near an island arc is indicated by the absence of pelagic sediments and the abundance of pillow basalt, turbiditic sediments, lahar deposits, and basaltic to rhyolitic tuff. The oldest extrusive rocks, which range from tholeiites with MORB characteristics to calc-alkaline andesites and rhyolites, formed in a young, relatively un-evolved island are or in a back-arc basin sufficiently close to an arc to receive calc-alkaline lava flows and coarse-grained, arc-derived detritus. tus. Overlying turbidites and lahar deposits of the Kaffan sandstone point to the initiation of a rifting event. High-Ti basalts, which erupted above the Kaffan sandstone, and related diabase are interpreted to be magmatic products of incipient intra-arc rifting. Renewed arc volcanism produced calc-alkaline volcanic rocks that interfingered with the high-Ti basalt and later dominated the section as the volcanic apron of the arc prograded basinward. Extrusion of voluminous calc-alkaline tuff may have been contemporaneous with intrusion of granodiorite and gravity-driven landsliding.

Geological Society of America Bulletin↗

Geologic map of the Bailey 30' x 60' quadrangle, North-Central Colorado

The Bailey, Colo. 1:100,000-scale quadrangle lies within two physiographic and geologic provinces in central Colorado: 1) the Front Range and 2) South Park. Most of the Front Range is composed of Proterozoic rocks ranging in age from 1,790 Ma to 1,074 Ma. Along the eastern flanks and within the Denver Basin, sedimentary rocks ranging from Pennsylvanian to Cretaceous are deformed and steeply tilted to the east. Upper Cretaceous through Paleocene rocks were deposited in the foreland (that is, the Front Range eastern flank) and hinterland (that is, South Park) of this thrust and reverse fault system developed during the Late Cretaceous to Paleocene Laramide orogeny. Within South Park, rocks range in age from Pennsylvanian to Miocene with Quaternary deposits indicating tectonic subsidence of the basin. These rocks record five major geologic episodes: 1) the Paleozoic Anasazi uplift that formed the Ancestral Rockies, 2) the Late Cretaceous to Paleocene Laramide orogeny, 3) widespread Eocene to Oligocene volcanism, 4) Oligocene-Quaternary tectonics, and 5) Quaternary glacial episodes.

Colorado↗

Bedrock geologic map of the Eagle Lake quadrangle, Essex County, New York

The bedrock geology of the 7.5-minute Eagle Lake quadrangle, Essex County, New York, consists of deformed and metamorphosed Mesoproterozoic gneisses of the Adirondack Highlands unconformably overlain by weakly deformed lower Paleozoic sedimentary rocks of the Champlain Valley. The Mesoproterozoic rocks occur on the eastern edge of the Adirondack Highlands and represent an extension of the Grenville Province of Laurentia. Granulite facies Mesoproterozoic paragneiss, marble, and amphibolite hosted the emplacement of an anorthosite-mangerite-charnockite-granite (AMCG) suite, now exposed mostly as orthogneiss, at approximately 1.18–1.15 giga-annum (Ga, billion years before present). The earliest of four phases of deformation (D1) predated AMCG magmatism and is characterized by gneissosity, rarely preserved F1 isoclinal folds, and migmatite in the paragneiss host rocks. A sample of hornblende quartz syenite from the AMCG suite, collected from an abandoned railroad cut on Old Furnace Road, yielded a U-Pb zircon age of 1,149±10 million years before present. D2 deformation produced a composite penetrative gneissosity, migmatite, and isoclinal F2 folds. Towards the end of D2, felsic magmatism (including the regionally extensive Lyon Mountain Granite Gneiss, abbreviated “LMG”) spread by penetrative migration as semiconcordant alkali feldspar granite sheets subparallel to S2 into the previously deformed lithologies. The LMG crystallized at approximately 1.15 to 1.14 Ga and displays synkinematic F2 folds thus constraining the time of D2 deformation. Exhumation of the Marcy anorthosite began during D3 along a mylonitic extensional detachment, as a type of core complex. Protracted D3 produced F3 folds exhibited in regional domes and basins, such as the Hammondville antiform, reactivation of the S2 foliation, partial melting, metamorphism, metasomatism, iron ore remobilization, and intrusion of magnetite-bearing pegmatite both as layer-parallel sills and crosscutting dikes. D4 created NE- and NW-trending boudinage, local high-grade ductile shear zones, and crosscutting granitic pegmatite dikes. Kilometer (km)-scale lineaments readily observed in lidar data are Ediacaran mafic dikes and Phanerozoic brittle faults. Lower Paleozoic rocks are part of the Early Cambrian to Late Ordovician great American carbonate bank on the ancient margin of Laurentia. The Potsdam Sandstone preserves the Cambrian stratigraphy in outliers above the Great Unconformity. The Paleozoic rocks are weakly folded and block faulted. Parts of the quadrangle are covered by undifferentiated glacial deposits, but much of the quadrangle contains only a variably thick, veneer of unmapped glacial till over significant areas of exposed bedrock. The map also shows waste rock piles and locations of historical mining operations. This study was undertaken to improve our understanding of the bedrock geology in the Adirondack Highlands, establish a modern framework for 1:24,000-scale bedrock geologic mapping in the Adirondack Mountains, and provide a modern context for historical mines. This Scientific Investigations Map of the Eagle Lake 7.5-minute quadrangle consists of a map sheet, an explanatory pamphlet, and a geographic information system database that includes bedrock geologic units, faults, outcrops, and structural geologic information. The map sheet includes a bedrock geologic map, a correlation of map units, a description of map units, an explanation of map symbols, and two cross sections. The explanatory pamphlet includes a discussion of the geology.

New York↗

Geologic map of the Aeolis Dorsa Region, Mars

The Aeolis Dorsa region of Mars, located just north of the global dichotomy boundary, includes the Aeolis and Zephyria Plana, and a depositional basin between them. This interplana region consists of extensive networks of ridges—the eponymous Aeolis Dorsa—and is interpreted as having formed by topographic inversion of fluvial and alluvial deposits. To the south is a nearly 1-km-deep trough (Aeolis Chaos) and the southern highlands. These elements of the map area compose a landscape of extensive erosional and depositional sedimentary processes. The plana are pervasively abraded into yardangs, and the interplana area shows scattered yardangs superposed on the underlying terrain. The Aeolis Dorsa fluvial deposits are concentrated within and around the margins of the interplana region, exposed and (or) inverted by this pervasive aeolian abrasion. During this period of extensive erosion and deposition, impacts have also redistributed material. The geologic mapping of this region, conducted at 1:500,000 scale to enable depiction of the fine-scale fluvial features, divides the landscape into six unit groups. The highlands units group comprises three units, located in the southwestern map area. These units, having the highest elevation in the map area, consist of mesas surrounded by more gently sloping terrain. The transitional units group, located northeast of the highlands units, includes the Aeolis Chaos, denoted as a chaos terrain unit, and two transitional units, differentiated on the basis of surface texture and relative elevation. The plana units group comprises five units. The oldest unit consists of mesas similar to those of the highlands mesas unit but located about 200 kilometers north of the highlands in Aeolis Planum. Three other plana units, located on the Aeolis and Zephyria Plana, are differentiated on the basis of yardang texture, crosscutting relations, and relative elevations. They are interpreted as abraded sedimentary and (or) volcaniclastic deposits. The fifth plana unit, which crops out in the north corners of the map area, is at low elevation, has numerous small craters, and is interpreted as cratered lava plains. The interplana units group hosts a hummocky unit and a mounds unit, differentiated on the basis of texture and relief. In the Aeolis Dorsa units group, four units are mapped on the basis of dorsa morphology and adjacent textures. Stratigraphic relations indicate a decrease in discharge over time. The crater units group includes a crater unit, found throughout the map area although concentrated within the interplana region, and a crater fill unit that is found within several craters in this interplana region. Based on this mapping, the interpretation of the regional geologic record begins with emplacement of the highlands terrain during the Noachian Period. Emplacement was followed during the Early Hesperian by erosion and redistribution of this high-standing terrain to form the transitional units, and Aeolis Chaos formed after deposition of the other transitional units. The high-standing plana were emplaced and eroded repeatedly throughout the Hesperian and Early Amazonian time, and impact cratering occurred at decreasing crater sizes. The fluvial and alluvial activity that gave rise to the Aeolis Dorsa also extended throughout this time, leaving their diagnostic signature on this region.

Scientific Investigations Map↗

Computer simulations of large asteroid impacts into oceanic and continental sites--Preliminary results on atmospheric, cratering and ejecta dynamics

Computer simulations have been completed that describe passage of a 10-km-diameter asteroid through the Earth's atmosphere and the subsequent cratering and ejecta dynamics caused by impact of the asteroid into both oceanic and continental sites. The asteroid was modeled as a spherical body moving vertically at 20 km/s with a kinetic energy of 2.6 × 10 30 ergs (6.2 × 10 7 Mt ). Detailed material modeling of the asteroid, ocean, crustal units, sedimentary unit, and mantle included effects of strength and fracturing, generic asteroid and rock properties, porosity, saturation, lithostatic stresses, and geothermal contributions, each selected to simulate impact and geologic conditions that were as realistic as possible. Calculation of the passage of the asteroid through a U.S. Standard Atmosphere showed development of a strong bow shock wave followed by a highly shock compressed and heated air mass. Rapid expansion of this shocked air created a large low-density region that also expanded away from the impact area. Shock temperatures in air reached ∼20, 000K near the surface of the uplifting crater rim and were as high as ∼2000K at more than 30 km range and 10 km altitude. Calculations to 30 s showed that the shock fronts in the air and in most of the expanding shocked air mass preceded the formation of the crater, ejecta, and rim uplift and did not interact with them. As cratering developed, uplifted rim and target material were ejected into the very low density, shock-heated air immediately above the forming crater, and complex interactions could be expected. Calculations of the impact events showed equally dramatic effects on the oceanic and continental targets through an interval of 120 s. Despite geologic differences in the targets, both cratering events developed comparable dynamic flow fields and by ∼29s had formed similar-sized transient craters ∼39km deep and ∼62km across. Transient-rim uplift of ocean and crust reached a maximum altitude of nearly 40 km at ∼30s and began to decay at velocities of 500 m/s to develop large-tsunami conditions. After ∼30s, strong gravitational rebound drove both craters toward broad flat-floored shapes. At 120 s, transient crater diameters were ∼80km (continental) and ∼105km (oceanic) and transient depths were ∼27km; crater floors consisting of melted and fragmented hot rock were rebounding rapidly upward. By 60 s, the continental crater had ejected ∼2 × 10 14 t, about twice the mass ejected from the oceanic crater. By 120 s, ∼70, 000km 3 (continental) and ∼90, 000km 3 (oceanic) target material were excavated (no mantle) and massive ejecta blankets were formed around the craters. We estimate that in excess of ∼70% of the ejecta would finally lie within ∼3 crater diameters of the impact, and the remaining ejecta (∼10 13 t), including the vaporized asteroid, would be ejected into the atmosphere to altitudes as high as the ionosphere. Effects of secondary volcanism and return of the ocean over hot oceanic crater floor could also be expected to contribute substantial material to the atmosphere.

International Journal of Impact Engineering↗

Geometry of the neoproterozoic and paleozoic rift margin of western Laurentia: Implications for mineral deposit settings

The U.S. and Canadian Cordilleran miogeocline evolved during several phases of Cryogenian-Devonian intracontinental rifting that formed the western mangin of Laurentia. Recent field and dating studies across central Idaho and northern Nevada result in identification of two segments of the rift margin. Resulting interpretations of rift geometry in the northern U.S. Cordillera are compatible with interpretations of northwest- striking asymmetric extensional segments subdivided by northeast-striking transform and transfer segments. The new interpretation permits integration of miogeoclinal segments along the length of the western North American Cordillera. For the U.S. Cordillera, miogeoclinal segments include the St. Mary-Moyie transform, eastern Washington- eastern Idaho upper-plate margin, Snake River transfer, Nevada-Utah lower-plate margin, and Mina transfer. The rift is orthogonal to most older basement domains, but the location of the transform-transfer zones suggests control of them by basement domain boundaries. The zigzag geometry of reentrants and promontories along the rift is paralleled by salients and recesses in younger thrust belts and by segmentation of younger extensional domains. Likewise, transform transfer zones localized subsequent transcurrent structures and igneous activity. Sediment-hosted mineral deposits trace the same zigzag geometry along the margin. Sedimentary exhalative (sedex) Zn-Pb-Ag ??Au and barite mineral deposits formed in continental-slope rocks during the Late Devonian-Mississippian and to a lesser degree, during the Cambrian-Early Ordovician. Such deposits formed during episodes of renewed extension along miogeoclinal segments. Carbonate-hosted Mississippi Valley- type (MVT) Zn-Pb deposits formed in structurally reactivated continental shelf rocks during the Late Devonian-Mississippian and Mesozoic due to reactivation of preexisting structures. The distribution and abundance of sedex and MVT deposits are controlled by the polarity and kinematics of the rift segment. Locally, discrete mineral belts parallel secondary structures such as rotated crustal blocks at depth that produced sedimentary subbasins and conduits for hydrothermal fluids. Where the miogeocline was overprinted by Mesozoic and Cenozoic deformation and magmatism, igneous rock-related mineral deposits are common. ??2008 Geological Society of America.

Geosphere↗

Geologic map of the Kanab 30' x 60' quadrangle, Utah and Arizona

The 1:100,000-scale geologic map of the sparsely populated Kanab 30' x 60' quadrangle in southernmost Utah and a narrow strip in northernmost Arizona delineates 17 formations and numerous subdivisions of sedimentary rock units of Permian, Triassic, Jurassic, Cretaceous, and Tertiary ages; 12 Quaternary alluvial, eolian, and mass-wasting units; and Quaternary basaltic igneous rocks and vents.Units within the Straight Cliffs Formation are correlated with those of the Kaiparowits Plateau. Palynological edidence indicates that the Kaiparowits(?) Formation is older than the type formation in the Kaiparowits Plateau. Structures include parts of the Sevier, Kanab Creek, Johnson Canyon, and Paunsaugunt fault zones. Regional dip is generally northeast at very low angles. Coal beds are presentin the upper unit of the Straight Cliffs Formation, in the Tropic Shale, and in the Dakota Formation.

IMAP↗

Geology and mineral resources of central Antioquia Department (Zone IIA), Colombia

This report summarizes the geology of an area of some 6000 square kilometers in the northern part of the Central Cordillera of the Colombian Andes. The area, in north-central Department of Antioquia, was mapped between 1964 and 1968 as part of the Inventario Minero Nacional (IMN) project. Mineral resources are summarized within a larger area, designated as subzone ILK of IMN Zone If, which comprises almost 22,000 sq. kin, including the area mapped geologically by IMN and additional areas mapped by other agencies. The oldest formation is a micaceous paragneiss of early Paleozoic or possibly late Precambrian age. A thick geosynclinal sedimentary series accumulated during the Paleozoic Era and became regionally metamorphosed to greenschist (locally amphibolite) facies during the Permian or early Triassic; these schists and gneisses are designated collectively as the Valdivia Group. The Permian(?) orogenic episode included intrusion of concordant syntectonic plutons, mostly of tonalitic composition. Rocks of unequivocal Triassic or Jurassic age are not recognized. The Cretaceous is well represented by both igneous and sedimentary assemblages. Eugeosynclinal alpine ophiolites comprising submarine basalt flows and numerous intrusions of gabbro and serpentinite are prominent in the Lower Cretaceous, together with flysch composed of marine shale and lesser sandstone and conglomerate. The Upper Cretaceous is represented along the west border of the mapped area by submarine basalt flows and pyroclastic rocks, locally Interbedded with fine-grained clastic sedimentary beds, and lenses of dark laminated chert, at least part of which is radiolarian. The Late Cretaceous was marked by an orogenic event that profoundly folded and faulted all rocks and in the Central Cordillera caused low-grade metamorphism, the overprint of which is hardly observable in pre-Cretaceous rocks elsewhere. The Late Cretaceous orogeny culminated with discordant intrusion of the epizonal tonalitic Antioquian batholith. Displacement along the great Romeral wrench fault may have begun in the Cretaceous. Plutonism continued into the Cenozoic, exemplified by the hornblende-diorite Sabanalarga pluton. Intermontane basins were filled with molasse derived from the erosion of adjacent highlands; Tertiary sedimentation in marshy areas included organic carboniferous matter subsequently converted to lignite or subbituminous coal. The Sabanalarga fault system originated in the Late Tertiary; intermittent displacement continued on the older wrench faults such as the Romeral. Epeirogenic uplift, which probably began in the Pliocene and continued through the Pleistocene and Holocene, brought on renewed erosion which has sculptured the mountains into their present form. Mineral resources in subzone IIA are varied but not of outstanding importance. Gold and silver mining, significant in past centuries, is minor today. Ferruginous laterite on serpentinite once considered as a potential source of iron ore is not economically exploitable. IMN has explored nickeliferous laterite at the extreme northwest corner of subzone IIA; this is a potential resource, exploitable only after exhaustion of the larger and richer nickel laterite deposit at Cerro Matoso, farther to the north and outside the boundaries of Zone If. Known deposits of mercury, chromium, manganese, and copper are small, with limited economic potential. Nonmetallic resources include raw materials for cement, including portland cement. Saprolite clay is widely used in making common red brick and tile, still a dominant construction material in all but the most modern multistory buildings. Aggregate materials are varied and abundant. Kaolin of good quality near La Union is important as a ceramic raw mineral filler. Tertiary subbituminous coal beds are an important energy resource in western subzone IIA, and have a good potential for greater development. Deposits of sodic feldspar, talc, decorative stone, and silica a

Open-File Report↗

Reconnaissance geology of the Qufar Quadrangle, sheet 27/41 D, Kingdom of Saudi Arabia

The Qufar quadrangle, south of the city of Ha' il in the northern Arabian Shield is underlain by late Proterozoic granitic and dioritic rocks and two volcano-sedimentary sequences. Phanerozoic rocks include a few outcrops of the Cambrian and Ordovician Saq Sandstone and small remnants of Miocene basalt flows and plugs. The oldest rocks in the quadrangle comprise the Nuf formation, a layered sequence of submarine, tholeiitic metabasalt and meta-andesite, and interbedded metagraywacke and marble. The Nuf formation may correlate with rocks mapped as Halaban or Hulayfah group (approximately 780-720 Ma old) to the south of the quadrangle. Cogenetic subvolcanic rocks include gabbro and diorite. Voluminous plutonic rocks of approximately monzogranite composition intruded and dismembered the Nuf formation, gabbro, and diorite, which were simultaneously metamorphosed and internally deformed. Metamorphism of the Nuf formation was variable, but generally' upper greenstone-facies assemblages were produced. Following a period of extensive erosion, the Hadn formation, dacitic to rhyolitic ignimbrite and flow breccia, and interbedded subgraywacke, arkose, and minor conglomerate was deposited. The Hadn formation may be a continental equivalent of the Murdama group, which is mapped to the south of the quadrangle and is approximately 650 to 610 Ma old. Numerous plutons, predominantly monzogranite, but ranging from gabbro to alkali-feldspar granite, post-date the Hadn formation. Of these, the Malayhah granite is particularly noteworthy because it has a broad zone of cataclasis along the western and southern border. Country rock within several kilometers of the western contact is also highly sheared, predominantly along northerly trends. Locally, a melange of several rock types was produced. Contact metamorphism to garnet-amphibolite hornfels facies occurred at this time, and may be responsible for the formation of small sub-economic magnetite lenses interlayered with some of the marbles of the Nuf formation. In the northern part of the quadrangle, southeast dipping imbricate thrust faults probably closely post-date the emplacement of the Mulayhah granite. These thrusts were followed in time by predominantly northeast-trending high-angle faults. The last major plutonic event in the area is the intrusion of the alkalic granite complexes at Jabal Aja and Jabal Sal ma about 580 Ma ago. Of particular note is a per alkalic border facies of the Jabal Aja complex that is associated with pegmatites enriched in thorium, niobium, and rare-earth elements.

Open-File Report↗

Geology and assessment of undiscovered oil and gas resources of the Yukon Flats Basin Province, 2008

The hydrocarbon potential of the Yukon Flats Basin Province in Central Alaska was assessed in 2004 as part of an update to the National Oil and Gas Assessment. Three assessment units (AUs) were identified and assessed using a methodology somewhat different than that of the 2008 Circum-Arctic Resource Appraisal (CARA). An important difference in the methodology of the two assessments is that the 2004 assessment specified a minimum accumulation size of 0.5 million barrels of oil equivalent (MMBOE), whereas the 2008 CARA assessment specified a minimum size of 50 MMBOE. The 2004 assessment concluded that >95 percent of the estimated mean undiscovered oil and gas resources occur in a single AU, the Tertiary Sandstone AU. This is also the only AU of the three that extends north of the Arctic Circle. For the CARA project, the number of oil and gas accumulations in the 2004 assessment of the Tertiary Sandstone AU was re-evaluated in terms of the >50-MMBOE minimum accumulation size. By this analysis, and assuming the resource to be evenly distributed across the AU, 0.23 oil fields and 1.20 gas fields larger than 50 MMBOE are expected in the part of the AU north of the Arctic Circle. The geology suggests, however, that the area north of the Arctic Circle has a lower potential for oil and gas accumulations than the area to the south where the sedimentary section is thicker, larger volumes of hydrocarbons may have been generated, and potential structural traps are probably more abundant. Because of the low potential implied for the area of the AU north of the Arctic Circle, the Yukon Flats Tertiary Sandstone AU was not quantitatively assessed for the 2008 CARA.

Alaska↗

Predicted pH at the domestic and public supply drinking water depths, Central Valley, California

This scientific investigations map is a product of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) project modeling and mapping team. The prediction grids depicted in this map are of continuous pH and are intended to provide an understanding of groundwater-quality conditions at the domestic and public supply drinking water zones in the groundwater of the Central Valley of California. The chemical quality of groundwater and the fate of many contaminants is often influenced by pH in all aquifers. These grids are of interest to water-resource managers, water-quality researchers, and groundwater modelers concerned with the occurrence of natural and anthropogenic contaminants related to pH. In this work, the median well depth categorized as domestic supply was 30 meters below land surface, and the median well depth categorized as public supply is 100 meters below land surface. Prediction grids were created using prediction modeling methods, specifically boosted regression trees (BRT) with a Gaussian error distribution within a statistical learning framework within the computing framework of R ( http://www.r-project.org/ ). The statistical learning framework seeks to maximize the predictive performance of machine learning methods through model tuning by cross validation. The response variable was measured pH from 1,337 wells and was compiled from two sources: USGS National Water Information System (NWIS) database (all data are publicly available from the USGS: http://waterdata.usgs.gov/ca/nwis/nwis ) and the California State Water Resources Control Board Division of Drinking Water (SWRCB-DDW) database (water quality data are publicly available from the SWRCB: http://www.waterboards.ca.gov/gama/geotracker_gama.shtml ). Only wells with measured pH and well depth data were selected, and for wells with multiple records, only the most recent sample in the period 1993–2014 was used. A total of 1,003 wells (training dataset) were used to train the BRT model, and 334 wells (hold-out dataset) were used to validate the prediction model. The training r-squared was 0.70, and the root-mean-square error (RMSE) in standard pH units was 0.26. The hold-out r-squared was 0.43, and RMSE in standard pH units was 0.37. Predictor variables consisting of more than 60 variables from 7 sources were assembled to develop a model that incorporates regional-scale soil properties, soil chemistry, land use, aquifer textures, and aquifer hydrology. Previously developed Central Valley model outputs of textures (Central Valley Textural Model, CVTM; Faunt and others, 2010) and MODFLOW-simulated vertical water fluxes and predicted depth to water table (Central Valley Hydrologic Model, CVHM; Faunt, 2009) were used to represent aquifer textures and groundwater hydraulics, respectively. In this work, wells were attributed to predictor variable values in ArcGIS using a 500-meter buffer. Faunt, C.C., ed., 2009, Groundwater availability in the Central Valley aquifer, California: U.S. Geological Survey Professional Paper 1776, 225 p., accessed at https://pubs.usgs.gov/pp/1766/ . Faunt, C.C., Belitz, K., and Hanson, R.T., 2010, Development of a three-dimensional model of sedimentary texture in valley-fill deposits of Central Valley, California, USA: Hydrogeology Journal, v. 18, no. 3, p. 625–649, https://doi.org/10.1007/s10040-009-0539-7 .

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Geologic map of the source region of Shalbatana Vallis, Mars

Xanthe Terra is a high-standing cratered plain located southeast of Lunae Planum and south of Chryse Planitia in the western equatorial region of Mars. It contains landforms shaped by diverse geologic processes, including various scales of channels and valleys, chaotic terrains, delta fan deposits, and landslides. An extensive outflow channel system is located within Xanthe Terra and the surrounding circum-Chryse region, including Shalbatana and Ravi Valles, thought to have formed by catastrophic flooding during the Hesperian to Amazonian Periods. The study region within Xanthe Terra is defined by Mars Transverse Mercator (MTM) quadrangles 00042 and 00047 (2.5° to −2.5° N, 310° to 320° E) and includes Orson Welles crater (124.5 km diameter, the source region for Shalbatana Vallis), the southernmost portion of Shalbatana Vallis, Aromatum Chaos (the source region for Ravi Vallis), the westernmost portion of Ravi Vallis, and the source area of Nanedi Valles. The Mars Odyssey Thermal Emission Image System (THEMIS) IR daytime mosaic (100 m/pixel) was used as the primary base map. We constructed the geologic map of the source region of Shalbatana Vallis at 1:750,000 scale. We defined 16 geologic units in the map area, which we divided into the following groups: plains units, channel units, crater units, chaos units, flow units, and surficial units. Mapped linear features include ridge crests, scarp crests, channels, crests of crater rims, crests of buried or degraded crater rims, graben traces, grooves, troughs, and faults. Surface features include secondary crater chains and dark ejecta material. The geologic history of the map region can be summarized as follows. During the Noachian Period, ancient highland materials in the Xanthe Terra region, including lava and any ancient sedimentary units present, were reworked by impacts during the heavy bombardment. In particular, the impact that formed a basin that later underwent widespread resurfacing, likely as a combination of lava flows, reworked crater materials, and sedimentary deposits resulting in the flat-lying, smooth plains of Chryse Planitia. The Hesperian Period was characterized by the impact that formed Orson Welles crater and the subsequent formation of Shalbatana Vallis, as well as Aromatum Chaos and Ravi Vallis. During this period, depressions were filled with smooth material that was subsequently modified by collapse, subsidence, and flooding. Water filled and overflowed the tops of Orson Welles crater and other depressions. The Amazonian Period was characterized by ongoing collapse, as well as the formation of flow and surficial materials, including a lava flow that extends from Aromatum Chaos.

Scientific Investigations Map↗

An update of the distribution of selected radiochemical and chemical constituents in perched ground water, Idaho National Laboratory, Idaho, Emphasis 1999-2001

Radiochemical and chemical wastes generated at facilities at the Idaho National Laboratory (INL) were discharged since 1952 to infiltration ponds at the Reactor Technology Complex (RTC) (known as the Test Reactor Area [TRA] until 2005), and the Idaho Nuclear Technology and Engineering Center (INTEC) and buried at the Radioactive Waste Management Complex (RWMC). Disposal of wastewater to infiltration ponds and infiltration of surface water at waste burial sites resulted in formation of perched ground water in basalts and in sedimentary interbeds above the Snake River Plain aquifer. Perched ground water is an integral part of the pathway for waste-constituent migration to the aquifer. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains ground-water monitoring networks at the INL to determine hydrologic trends, and to monitor the movement of radiochemical and chemical constituents in wastewater discharged from facilities to both perched ground water and the aquifer. This report presents an analysis of water-quality and water-level data collected from wells completed in perched ground water at the INL during 1999-2001, and summarizes historical disposal data and water-level-and water-quality trends. At the RTC, tritium, strontium-90, cesium-137, dissolved chromium, chloride, sodium, and sulfate were monitored in shallow and deep perched ground water. In shallow perched ground water, no tritium was detected above the reporting level. In deep perched ground water, tritium concentrations generally decreased or varied randomly during 1999-2001. During October 2001, tritium concentrations ranged from less than the reporting level to 39.4?1.4 picocuries per milliliter (pCi/mL). Reportable concentrations of tritium during July-October 2001 were smaller than the reported concentrations measured during July-December 1998. Tritium concentrations in water from wells at the RTC were likely affected by: well's distance from the radioactive-waste infiltration ponds (commonly referred to as the warm-waste ponds); water depth below the ponds; the amount of tritium discharged to radioactive-waste infiltration ponds in the past; discontinued use of radioactive-waste infiltration ponds; radioactive decay; and dilution from disposal of nonradioactive water. During 1999-2001, the strontium-90 concentrations in two wells completed in shallow perched water near the RTC exceeded the reporting level. Strontium-90 concentrations in water from wells completed in deep perched ground water at the RTC varied randomly with time. During October 2001, concentrations in water from five wells exceeded the reporting level and ranged from 2.8?0.7 picocuries per liter (pCi/L) in well USGS 63 to 83.8?2.1 pCi/L in well USGS 54. No reportable concentrations of cesium-137, chromium-51, or cobalt-60 were present in water samples from any of the shallow or deep wells at the RTC during 1999-2001. Dissolved chromium was not detected in shallow perched ground water at the RTC during 1999-2001. Concentrations of dissolved chromium during July-October 2001 in deep perched ground water near the RTC ranged from 10 micrograms per liter (?g/L) in well USGS 61 to 82 ?g/L in well USGS 55. The largest concentrations were in water from wells north and west of the radioactive-waste infiltration ponds. During July-October 2001, dissolved sodium concentrations ranged from 7 milligrams per liter (mg/L) in well USGS 78 to 20 mg/L in all wells except well USGS 68 (413 mg/L). Dissolved chloride concentrations in shallow perched ground water ranged from 10 mg/L in wells CWP 1, 3, and 4 to 53 mg/L in well TRA A 13 during 1999-2001. Dissolved chloride concentrations in deep perched ground water ranged from 5 mg/L in well USGS 78 to 91 mg/L in well USGS 73. The maximum dissolved sulfate concentration in shallow perched ground water was 419 mg/L in well CWP 1 during July 2000. Concentrations of dissolved sulfate in water from wells USGS 54, 60

Scientific Investigations Report↗

Summary of the analyses for recovery factors

Introduction In order to determine the hydrocarbon potential of oil reservoirs within the U.S. sedimentary basins for which the carbon dioxide enhanced oil recovery (CO 2- EOR) process has been considered suitable, the CO 2 Prophet model was chosen by the U.S. Geological Survey (USGS) to be the primary source for estimating recovery-factor values for individual reservoirs. The choice was made because of the model’s reliability and the ease with which it can be used to assess a large number of reservoirs. The other two approaches—the empirical decline curve analysis (DCA) method and a review of published literature on CO 2 -EOR projects—were deployed to verify the results of the CO 2 Prophet model. This chapter discusses the results from CO 2 Prophet (chapter B, by Emil D. Attanasi, this report) and compares them with results from decline curve analysis (chapter C, by Hossein Jahediesfanjani) and those reported in the literature for selected reservoirs with adequate data for analyses (chapter D, by Ricardo A. Olea). To estimate the technically recoverable hydrocarbon potential for oil reservoirs where CO 2 -EOR has been applied, two of the three approaches—CO 2 Prophet modeling and DCA—do not include analysis of economic factors, while the third approach—review of published literature—implicitly includes economics. For selected reservoirs, DCA has provided estimates of the technically recoverable hydrocarbon volumes, which, in combination with calculated amounts of original oil in place (OOIP), helped establish incremental CO 2 -EOR recovery factors for individual reservoirs. The review of published technical papers and reports has provided substantial information on recovery factors for 70 CO 2 -EOR projects that are either commercially profitable or classified as pilot tests. When comparing the results, it is important to bear in mind the differences and limitations of these three approaches.

Scientific Investigations Report↗

Assessment of the petroleum, coal, and geothermal resources of the Economic Community of West African States (ECOWAS) region

Approximately 85 percent of the land area of the ECOWAS (Economic Community of West African States) region is covered by basement rocks (igneous and highly metamorphosed rocks) or relatively thin layers of Paleozoic, Upper Precambrian, and 'Continental Intercalaire? sedimentary rocks. These areas have little or no petroleum potential. Areas of the ECOWAS region that have potential for petroleum production or potential for increased petroleum production include the narrow belt of sedimentary rocks that stretches along the continental margin from Mauritania to Nigeria and the Niger Delta and the Benue depression. The Senegal Basin, located on the continental margin of Mauritania, Senegal, Gambia, Guinea Bissau, and Guinea, has been intensely explored by the oil industry and most of the larger structures onshore and on the shelf probably have been tested by drilling with little or no resulting commercial production. Unless basic ideas pertaining to the petroleum geology of the Senegal Basin are revised, future discoveries are expected to be limited to small fields overlooked by industry at a time when petroleum prices were low. On the continental shelf of Sierra Leone and the continental shelf of northeast and central Liberia, the sedimentary rocks are relatively thin, and industry has shown little interest in the area. On the continental rise of these countries, however, the sedimentary section, deposited in a complex fault-block system, increases in thickness. A renewal of industry interest in this deep-water area will probably follow further development of deep-water production technology. A recent oil discovery on the continental slope off the Ivory Coast is expected to spur further exploration offshore of southeastern Liberia, Ivory Coast, Ghana, Togo, and Benin. This relatively unexplored area in the Gulf of Guinea has good possibilities .for the discovery of giant oil fields. Nigeria's oil development from the Niger Delta may have peaked, as 13 of 14 giant oil fields were discovered prior to 1969 and the greatest number of fields were discovered in the period 1965 through 1967. Like delta regions in other parts of the world, individual oil fields of the Niger Delta are small to medium by world standards and future discoveries, therefore, are likely to reflect this reality. The natural gas resources of the Niger Delta, unlike its oil resources, are comparatively underdeveloped. Parts of the Benue depression in Nigeria and Niger could contain significant deposits of petroleum. The lower Benue depression, immediately north of the Niger Delta, has been extensively explored by drilling. Except for noncommercial discoveries of oil and gas and traces of oil and gas on the ground surface, the results of exploration in the lower Benue depression were negative. However, in the Lake Chad area of Chad and in southern Chad near the Central African Republic boundary, oil and gas discoveries were made just prior to the cessation of all drilling and exploration activity in early 1979. It is rumored that these discoveries may be large although little information is available. The relation between the two areas in Chad and their overall relation to the Benue depression is poorly understood; however, the possibility of thick sedimentary sections containing Cretaceous marine source rock and Tertiary reservoir beds-all contained within grabens in a highly faulted failed-arm system subjected to high heat flow--is attractive. Of the ECOWAS countries, only Nigeria and Niger produce coal commercially. Nigeria produces subbituminous coal from Paleocene-Maestrichtian and Maestrichtian (Late Cretaceous) age rocks of the Niger Delta region; reserves are estimated, on the basis of extensive drilling, to be 350 million tons (standard coal equivalent). In addition, lignite deposits of the Niger Delta appear to be large but have not been developed. Niger produces small amounts of coal used locally by uranium mine and mill operations from C

Open-File Report↗