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Heat capacities and thermodynamic functions for beryl, Be3Al2Si6O18, phenakite, Be2SiO4, euclase, BeAlSiO4(OH), bertrandite, Be4Si2O7(OH)2, and chrysoberyl, BeAl2O4.

The heat capacities of beryl, phenakite, euclase and bertrandite have been measured between approx 5 and 800 K by combined quasi-adiabatic cryogenic calorimetry and differential scanning calorimetry. The heat capacities of chrysoberyl have been measured from 340 to 800 K. The resulting data have been combined with solution and phase-equilibrium experimental data and simultaneously adjusted using the programme PHAS20 to provide an internally consistent set of thermodynamic properties for several important beryllium phases. The experimental heat capacities and tables of derived thermodynamic properties are presented.-J.A.Z.

American Mineralogist↗

SEAFLOOR EXPLORATION AND CHARACTERIZATION: PREREQUISITE TO OCEAN SPACE UTILIZATION.

A historical survey of US bathymetric mapping is presented up through the major mapping project begun in response to the 1983, establishment of an Exclusive Economic Zone (EEZ), 200 nautical miles seaward. The EEZ extends sovereign rights for the purposes of exploring, exploiting, conserving, and managing natural resources in the coastal ocean. This new area is approximately 3. 4 million square nautical miles or about 1. 3 times the total US land area. To characterize the resources within it, the US National Oceanic and Atmospheric Administration (NOAA) and the US Geological Survey (USGS) are undertaking systematic mapping programs of the EEZ. NOAA's effort includes detailed bathymetric mapping of the seabed. The USGS is using a wide-swath side-scan sonar system to map the EEZ seafloor on a reconaissance scale.

Conference Paper↗

National aerial photography program as a geographic information system resource

The National Aerial Photography Program (NAPP) is jointly funded by Federal agencies and States that choose to participate in a 50-50 cost sharing cooperative arrangement. The NAPP is designed to acquire black-and-white (B&W) or color infrared (CIR) photography at a scale of 1:40,000. The status of NAPP flying, now going into the first year of its second 5-year cycle, is reviewed to inform the user community of NAPP's coverage. The resolution, geometric quality and flight parameters are used to estimate the system's cartographic potential to produce orthophotoquads, digital elevation models, topographic maps and digital information to meet national map accuracy standards at 1:12,000 and 1:24,000-scale and serve as a geographic information system resource. Also, a technique is presented to compute the optimum scanning spot size (15 ??m) and storage required for converting the B&W or CIR photography to digital, machine-readable pixel form. The resulting digital NAPP data are suitable for a wide variety of new applications, including use in geographic information systems.

Conference Paper↗

Spatial resolution requirements for automated cartographic road extraction

Ground resolution requirements for detection and extraction of road locations in a digitized large-scale photographic database were investigated. A color infrared photograph of Sunnyvale, California was scanned, registered to a map grid, and spatially degraded to 1- to 5-metre resolution pixels. Road locations in each data set were extracted using a combination of image processing and CAD programs. These locations were compared to a photointerpretation of road locations to determine a preferred pixel size for the extraction method. Based on road pixel omission error computations, a 3-metre pixel resolution appears to be the best choice for this extraction method. -Authors

Photogrammetric Engineering and Remote Sensing↗

Heat capacities and thermodynamic properties of annite (aluminous iron biotite)

The heat capacities have been measured between 7 and 650 K by quasi-adiabatic calorimetry and differential scanning calorimetry. At 298.15 K and 1 bar, the calorimetric entropy for our sample is 354.9??0.7 J/(mol.K). A minimum configurational entropy of 18.7 J/(mol.K) for full disorder of Al/Si in the tetrahedral sites should be added to the calorimetric entropy for third-law calculations. The heat capacity equation [Cp in units of J/mol.K)] Cp0 = 583.586 + 0.075246T - 3420.60T-0.5 - (4.4551 ?? 106)T-2 fits the experimental and estimated heat capacities for our sample (valid range 250 to 1000 K) with an average deviation of 0.37%. -from Authors

American Mineralogist↗

Hydrothermal and metamorphic berthierine from the Kidd Creek volcanogenic massive sulfide deposit, Timmins, Ontario

Berthierine, a 7 A?? Fe-Al member of the serpentine group, occurs in the footwall stringer zone of the Archean Kidd Creek massive sulfide deposit, associated with quartz, muscovite, chlorite, pyrite, sphalerite, chalcopyrite, and local tourmaline, cassiterite, and halloysite. Petrographic and scanning electron microscopic (SEM) studies reveal different types of berthierine occurrences, including interlayers within the rims on deformed chlorite, intergrowths with muscovite and halloysite, and discrete coarse grains. This is the first reported occurrence of berthierine from volcanogenic massive sulfide deposits. Textural relations suggest that most of the berthierine formed as a primary hydrothermal mineral at relatively high temperatures (~350??C) in the footwall stringer zone, probably by the replacement of a pre-existing aluminous phase such as muscovite or chlorite. However, the intergrowth textures observed by SEM and TEM suggest that some of the berthierine originated by syn- or post-metamorphic replacement of chlorite. -from Authors

Canadian Mineralogist↗

Film cameras or digital sensors? The challenge ahead for aerial imaging

Cartographic aerial cameras continue to play the key role in producing quality products for the aerial photography business, and specifically for the National Aerial Photography Program (NAPP). One NAPP photograph taken with cameras capable of 39 lp/mm system resolution can contain the equivalent of 432 million pixels at 11 ??m spot size, and the cost is less than $75 per photograph to scan and output the pixels on a magnetic storage medium. On the digital side, solid state charge coupled device linear and area arrays can yield quality resolution (7 to 12 ??m detector size) and a broader dynamic range. If linear arrays are to compete with film cameras, they will require precise attitude and positioning of the aircraft so that the lines of pixels can be unscrambled and put into a suitable homogeneous scene that is acceptable to an interpreter. Area arrays need to be much larger than currently available to image scenes competitive in size with film cameras. Analysis of the relative advantages and disadvantages of the two systems show that the analog approach is more economical at present. However, as arrays become larger, attitude sensors become more refined, global positioning system coordinate readouts become commonplace, and storage capacity becomes more affordable, the digital camera may emerge as the imaging system for the future. Several technical challenges must be overcome if digital sensors are to advance to where they can support mapping, charting, and geographic information system applications.

Photogrammetric Engineering and Remote Sensing↗

Heat capacities and thermodynamic properties of braunite (Mn7 SiO12) and rhodonite (MnSiO3)

The heat capacities, C0P, of synthetic rhodonite and braunite have been measured by adiabatic calorimetry from 6 to ~350 K. The heat capacity of braunite was also measured to ~900 K by differential scanning calorimetry. Brunite exhibits a ??-peak in C0P in the temperature region 93.4-94.2 K. Rhodonite did not show the expected peak in C0P characteristic of the co-operative ordering of the Mn2+ spins at temperatures above 6 K. A revised petrogenetic grid for the system Mn-Si-O-C at 2000 bars is presented and is consistent with both thermochemical values and occurrence of natural assemblages. -from Authors

American Mineralogist↗

Geologic sources of asbestos in Seattle's tolt reservoir

Water from Seattle's South Fork Tolt Reservoir contains chrysotile and amphibole asbestos fibers, derived from natural sources. Using optical petrographic techniques, X-ray diffraction, and scanning electron microscopy, we identified the geologic source of these asbestiform minerals within the watershed. No asbestos was found in the bedrock underlying the watershed, while both chrysotile and amphibole fibers were found in sediments transported by Puget-lobe glacial processes. These materials, widely distributed throughout the lower watershed, would be difficult to separate from the reservoir sediments. The probable source of this asbestos is in pods of ultramafic rock occurring north of the watershed. Because asbestos is contained in widespread Pugetlobe glacial materials, it may be naturally distributed in other watersheds in the Puget Sound area.

Northwest Science↗

Heat capacity and thermodynamic properties for coesite and jadeite, reexamination of the quartz-coesite equilibrium boundary

The heat capacities of synthetic coesite and jadeite were measured between about 15 and 850 K by adiabatic and differential scanning calorimetry. The experimental data were smoothed and estimates were made of heat capacities to 1800 K. The following equations represent our estimate of the heat capacities of coesite and jadeite between 298.15 and 1800 K: [see original article for formula]. Tables of thermodynamic values for coesite and jadeite to 1800 K are presented. The entropies of coesite and jadeite are 40.38 ?? 0.12 and 136.5 ?? 0.32 J/(mol.K), respectively, at 298.15 K. The entropy for coesite derived here confirms the value published earlier by Holm et al. (1967). We have derived an equation to describe the quartz-coesite boundary over the temperature range of 600 to 1500 K, P(GPa) = 1.76 + 0.001T(K). Our results are in agreement with the enthalpy of transition reported by Akaogi and Navrotsky (1984) and yield -907.6 ?? 1.4 kJ/mol for the enthalpy of formation of coesite from the elements at 298.15 K and 1 bar, in agreement with the value recommended by CODATA (Khodakovsky et al. 1995). Several sources of uncertainty remain unacceptably high, including: the heat capacities of coesite at temperatures above about 1000 K; the heat capacities and volumetric properties of ?? quartz at higher pressures and at temperatures above 844 K; the pressure corrections for the piston cylinder apparatus used to determine the quartz-coesite equilibrium boundary.

American Mineralogist↗

Microscopic character of marine sediment containing disseminated gas hydrate. Examples from the Blake Ridge and the Middle America Trench

The presence of disseminated gas hydrate was inferred based on pore fluid geochemistry and downhole logging data, but was rarely observed at Ocean Drilling Program (ODP) Leg 164 (Blake Ridge), and Leg 170 (Middle America Trench, offshore from Costa Rica) drilling sites. Gas hydrate nucleation is likely to occur first in larger voids rather than in constricted pore space, where capillary forces depress the temperature-pressure stability field for gas hydrate formation. Traditional macroscopic descriptions of sediment fail to detect the microscopic character of primary and secondary porosity in sediment hosting disseminated gas hydrate. Light transmission and scanning electron microscopy of sediments within and below the depth of gas hydrate occurrences reveal at least four general types of primary and secondary porosity: (1) microfossils (diatoms, foraminifera, and spicules) void of infilling sediment, but commonly containing small masses of pyrite framboids; (2) infauna burrows filled with unconsolidated sand and or microfossil debris; (3) irregularly shaped pods of nonconsolidated framboidial pyrite; and (4) nonlithified volcanic ash.

Conference Paper↗

Attenuation-difference radar tomography: Results of a multiple-plane experiment at the U.S. Geological Survey Fractured-Rock Research Site, Mirror Lake, New Hampshire

Attenuation-difference, borehole-radar tomography was used to monitor a series of sodium chloride tracer injection tests conducted within the FSE, wellfield at the U.S. Geological Survey Fractured-Rock Hydrology Research Site in Grafton County, New Hampshire, USA. Borehole-radar tomography surveys were conducted using the sequential-scanning and injection method in three boreholes that form a triangular prism of adjoining tomographic image planes. Results indicate that time-lapse tomography methods provide high-resolution images of tracer distribution in permeable zones.

New Hampshire↗

An application of LIDAR to analyses of El Nino erosion in the Netarts littoral cell, Oregon

El Nin??o produces coastal and beach erosion along the West Coast of the USA by elevating mean water levels so that tides are significantly higher than predicted, and by altering the paths of storms that generate large waves. In the past it has been difficult to adequately document the erosion impacts since they are so widespread. This difficulty has been solved through the application of LIDAR, which uses a scanning laser mounted in a small aircraft to rapidly and accurately survey beach elevations. This study uses LIDAR to document the beach changes and shoreline erosion that occurred during the 1997-98 El Nin??o within the Netarts Littoral Cell on the Oregon coast, a 14-km long "pocket beach" between large rocky headlands. The LIDAR surveys demonstrate that sand generally migrated northward within the cell due to the southwest approach of the El Nin??o storm waves, but there was a complex pattern of beach-elevation change due to the superposition of eroded rip-current embayments. The greatest beach erosion occurred near the south end of the cell, where it impacted Cape Lookout State Park, and to the north of the inlet to Netarts Bay where it threatened The Capes, a development of condominiums located on a high bluff. In both cases the LIDAR data proved to be extremely useful in quantifying the erosion, and in providing a better understanding of the erosion processes that occur during an El Nin??o.

Journal of Coastal Research↗

Estimation of shoreline position and change using airborne topographic lidar data

A method has been developed for estimating shoreline position from airborne scanning laser data. This technique allows rapid estimation of objective, GPS-based shoreline positions over hundreds of kilometers of coast, essential for the assessment of large-scale coastal behavior. Shoreline position, defined as the cross-shore position of a vertical shoreline datum, is found by fitting a function to cross-shore profiles of laser altimetry data located in a vertical range around the datum and then evaluating the function at the specified datum. Error bars on horizontal position are directly calculated as the 95% confidence interval on the mean value based on the Student's t distribution of the errors of the regression. The technique was tested using lidar data collected with NASA's Airborne Topographic Mapper (ATM) in September 1997 on the Outer Banks of North Carolina. Estimated lidar-based shoreline position was compared to shoreline position as measured by a ground-based GPS vehicle survey system. The two methods agreed closely with a root mean square difference of 2.9 m. The mean 95% confidence interval for shoreline position was ?? 1.4 m. The technique has been applied to a study of shoreline change on Assateague Island, Maryland/Virginia, where three ATM data sets were used to assess the statistics of large-scale shoreline change caused by a major 'northeaster' winter storm. The accuracy of both the lidar system and the technique described provides measures of shoreline position and change that are ideal for studying storm-scale variability over large spatial scales.

Maryland, North Carolina, Virginia↗

Morphological variation in glochidia shells of six species of Elliptio from Gulf of Mexico and Atlantic Coast drainages in the southeastern United States

The genus Elliptio, with 36 currently recognized species, is the largest genus in the family Unionidae in North America. The genus is represented by two species, Elliptio crassidens and E. dilatata, in the Interior Basin and 34 species in drainages of the eastern Gulf of Mexico and Atlantic Coast. The paucity and variation of conchological characters in the genus Elliptio makes it extremely difficult to define species and determine relationships. We examined glochidia from six species of Elliptio in an effort to determine if there are useful characteristics for species level identification and/or characters for identification of species groups. Elliptio species were selected to represent different morphological groups from four drainages in the southeastern United States. The glochidia from E. crassidens, E. dariensis, E. hopetonensis, E. icterina, E. shepardiana, and E. mcmichaeli were qualitatively compared, using scanning electron microscopy, with each other and with descriptions of these and other Elliptio glochidia described in the literature. Two groups were identified. The crassidens group, including E. crassidens, E. dariensis, and E. mcmichaeli, had subtriangular glochidia with a triangular styliform hook extending from the ventral margin of the valve and rough exterior valve sculpturing. Adults of this group had wrinkled or corrugated sculpturing on the posterior slope of the shell. The complanata group, including E. hopetonensis, E. icterina, and E. shepardiana, had subelliptical glochidia with a broad flange extending the entire ventral margin and loose-looped exterior valve sculpturing. Adults of this group lack sculpturing on the posterior slope of the shell. Differences in glochidial morphometrics were found, however, additional work is needed to determine if they are reliable for species level identification.

Proceedings of the Biological Society of Washingto↗

Evaluation of airborne topographic lidar for quantifying beach changes

A scanning airborne topographic lidar was evaluated for its ability to quantify beach topography and changes during the Sandy Duck experiment in 1997 along the North Carolina coast. Elevation estimates, acquired with NASA's Airborne Topographic Mapper (ATM), were compared to elevations measured with three types of ground-based measurements - 1) differential GPS equipped all-terrain vehicle (ATV) that surveyed a 3-km reach of beach from the shoreline to the dune, 2) GPS antenna mounted on a stadia rod used to intensely survey a different 100 m reach of beach, and 3) a second GPS-equipped ATV that surveyed a 70-km-long transect along the coast. Over 40,000 individual intercomparisons between ATM and ground surveys were calculated. RMS vertical differences associated with the ATM when compared to ground measurements ranged from 13 to 19 cm. Considering all of the intercomparisons together, RMS ??? 15 cm. This RMS error represents a total error for individual elevation estimates including uncertainties associated with random and mean errors. The latter was the largest source of error and was attributed to drift in differential GPS. The ??? 15 cm vertical accuracy of the ATM is adequate to resolve beach-change signals typical of the impact of storms. For example, ATM surveys of Assateague Island (spanning the border of MD and VA) prior to and immediately following a severe northeaster showed vertical beach changes in places greater than 2 m, much greater than expected errors associated with the ATM. A major asset of airborne lidar is the high spatial data density. Measurements of elevation are acquired every few m2 over regional scales of hundreds of kilometers. Hence, many scales of beach morphology and change can be resolved, from beach cusps tens of meters in wavelength to entire coastal cells comprising tens to hundreds of kilometers of coast. Topographic lidars similar to the ATM are becoming increasingly available from commercial vendors and should, in the future, be widely used in beach surveying.

Journal of Coastal Research↗

Sand volume and distribution on the paraglacial inner continental shelf of the northwestern Gulf of Maine

In an extensive program of side-scan sonar and seismic reflection profiling, bottom sampling and vibracoring, we have mapped the western Gulf of Maine between Canada and Massachusetts, from the shoreline to the 100 m isobath. The purpose of the program was, in part, to locate and evaluate sand resources on the inner shelf. Surficial sand occurs on only 7% of this formerly glaciated region, and most is located seaward of southern Maine's large beaches in Wells Embayment, Saco Bay, and off Cape Small. Sand deposits occur 1) at the lowstand position of sea level, between 50 and 60 m depth, 2) on parts of the inner shelf between 50 m and the shoreface, and 3) in the shoreface. A paleodelta of the region's largest river, the Kennebec, occurs off Cape Small. Elsewhere, the lowstand deposits are thinner (<3 m) and form a mantle over notches cut into glacial sediment. Inner shelf deposits are found as thin (<1 m) layers unconformably overlying glacial sediment. These are widespread in Wells and Cape Small, but are confined to rock valleys by high-relief bedrock in Saco Bay. In Wells Embayment, numerous moraines were eroded during lower stands of sea level, but still possess >5 m of relief on the inner shelf and contain large quantities of material. The shoreface contains the greatest concentration of sand in each of the regions. A wedge-shaped deposit of sand overlies estuarine muddy sands in each area and is inferred to have formed during a slowdown in the rate of sea-level rise between 7.5 and 9.5 ka. The volume of shoreface sand varies from less than 60 million cubic meters in Saco Bay to more than 300 million cubic meters off Cape Small, and is loosely correlated with the erosional state of adjacent beaches.

Journal of Coastal Research↗

Fault trends on the seaward slope of the Aleutian Trench: Implications for a laterally changing stress field tied to a westward increase in oblique convergence

Normal faults along the seaward trench slope (STS) commonly strike parallel to the trench in response to bending of the oceanic plate into the subduction zone. This is not the circumstance for the Aleutian Trench, where the direction of convergence gradually changes westward, from normal to transform motion. GLORIA side-scan sonar images document that the Aleutian STS is dominated by faults striking oblique to the trench, west of 179??E and east of 172??W. These images also show a pattern of east-west trending seafloor faults that are aligned parallel to the spreading fabric defined by magnetic anomalies. The stress-strain field along the STS is divided into two domains west and east, respectively, of 179??E. Over the western domain, STS faults and nodal planes of earthquakes are oriented oblique (9??-46??) to the trench axis and (69??-90??) to the magnetic fabric. West of 179??E, STS fault strikes change by 36?? from the E-W trend of STS where the trench-parallel slip gets larger than its orthogonal component of convergence. This rotation indicates that horizontal stresses along the western domain of the STS are deflected by the increasing obliquity in convergence. An analytical model supports the idea that strikes of STS faults result from a superposition of stresses associated with the dextral shear couple of the oblique convergence and stresses caused by plate bending. For the eastern domain, most nodal planes of earthquakes strike parallel to the outer rise, indicating bending as the prevailing mechanism causing normal faulting. East of 172??W, STS faults strike parallel to the magnetic fabric but oblique (10??-26??) to the axis of the trench. On the basis of a Coulomb failure criterion the trench-oblique strikes probably result from reactivation of crustal faults generated by spreading. Copyright 2003 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗