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USGS2021

Soils and paleosols

Soils are naturally occurring bodies that form in the interface between the geosphere, biosphere, hydrosphere , and atmosphere. They are the medium for much of the Earth's plant and animal growth. Soil morphology and how it evolves are functions of the soil-forming factors of climate, organisms, relief, parent material, and time. The expression of soil morphology takes the form of layers, called horizons, that differ in their color, particle size distribution, structure, chemistry, and organic matter content from the parent material. A fundamental soil mapping unit in the USA is the soil order and 12 soil orders have been defined on the basis of soil morphology, physical and chemical properties, and climate. Soil geography in the USA is explained by an examination of how these 12 soil orders are found in particular climates, under specific vegetation communities, how they develop from compositionally distinct parent materials, or how they are a result of the age of soil parent material. Paleosols are ancient soils, those that formed in the past. Three types of paleosols are recognized, buried soils (those covered by a younger sediment or rock), exhumed paleosols (formerly buried soils that are now exposed at the surface due to erosion of overlying materials), and relict paleosols (soils that occur at the land surface, but which formed in an environment, such as a climate or biome, very different from that at the present time). Paleosols can help define geologic contacts and can aid in elucidating past climates or vegetation regimes. Although there are rich geologic records of paleosols in the Quaternary, there is an increasing recognition of the importance of all these features in the longer, pre-Quaternary geologic record.

Book chapter↗

USGS2016

Notes on the origin of copromacrinite based on nitrogen functionalities and δ13C and δ15N determined on samples from the Peach Orchard coal bed, southern Magoffin County, Kentucky

This paper represents the first attempt to show, by means other than just petrographic ones, that one type of macrinite, herein designated copromacrinite, may result from macrofauna feces. For that purpose a combination of coal petrography, X-ray photoelectron spectroscopy, and elemental-analysis continuous-flow isotope ratio mass spectrometry methods were used to determine nitrogen functionalities and δ 13 C and δ 15 N compositions in 1) vitrinite-rich, 2) fusinite + semifusinite-rich, and 3) macrinite-rich (with a possible coprolitic origin) samples of the high volatile A bituminous Peach Orchard coal (Bolsovian; Middle Pennsylvanian) from Magoffin County, Kentucky. There were no significant differences between pyridinic-N and quaternary-N abundance in the three samples, however, pyrrolic-N was higher (~ 54%) in the macrinite-rich sample than in the other two samples (~ 38%). The data suggest that pyridinic-N and quaternary-N are independent of maceral group composition and that pyrrolic-N is dependent on maceral composition (fusinite + semifusinite versus macrinite). δ 13 C values obtained for bulk and demineralized coal of the vitrinite- and fusinite + semifusinite-rich samples are similar with δ 13 C values of − 24.80 ± 0.01&permil; VPDB and − 24.61 ± 0.09&permil; VPDB for bulk samples and − 24.81 ± 0.07&permil; VPDB and − 24.52 ± 0.04&permil; VPDB for demineralized samples. These values are within the expected range for vitrinite-rich samples and the slightly higher δ 13 C value of the fusinite + semifusinite-rich sample is expected as δ 13 C values for inertinite are higher than for vitrinite. However, there was a significant shift to a lower δ 13 C value (− 26.80 ± 0.01&permil; VPDB for the bulk sample value) for the macrinite-rich sample. Because the samples are basically isorank, and δ 13 C (and δ 15 N) shifts do not occur during maturation until anthracite rank, the difference may be related to the presence or composition of the macrinite within the sample which lacks heat-effect indicators, such as devolatilization vacuoles and distorted pores. δ 15 N values are also similar for bulk and demineralized coal of the vitrinite- and fusinite + semifusinite-rich samples, and the bulk values were heavier in this samples (3.07 ± 0.03&permil; Air and 2.92 ± 0.10&permil; Air, respectively), and much lighter (− 2.83 ± 0.09&permil; Air) for the macrinite-rich sample. The study of Peach Orchard coal samples using reflected-light microscopy, isotopic composition, and nitrogen-forms analyses revealed that the macrinite-rich sample contains macrinite with coprolitic features (e.g. oxidation rind, mix of undigested palynomorphs, frequent and randomly located funginite, agglutination pulp of semifusinite reflectance, internal lack of bedding fabric, and suggestion of structures resulting from intestines and stomach walls), more pyrrolic-N (~ 16%), and lower δ 13 C (~ 2&permil; VPDB) and δ 15 N (~ 4&permil; Air) values than the vitrinite and semifusinite + fusinite rich samples. These findings suggest that the maceral macrinite has multiple origins based on petrography and measurable chemical differences between the macrinite, vitrinite, and semifusinite + fusinite fractions within the coal. Assuming that copromacrinite observed is an excretion then the anomalies observed may result from the symbiotic relations between the macrofauna (e.g. cockroaches) and microbiota during the digestive processes, and the nitrogen balance mechanisms inside macrofauna body.

Kentucky↗

USGS2007

Massive edifice failure at Aleutian arc volcanoes

Along the 450-km-long stretch of the Aleutian volcanic arc from Great Sitkin to Kiska Islands, edifice failure and submarine debris-avalanche deposition have occurred at seven of ten Quaternary volcanic centers. Reconnaissance geologic studies have identified subaerial evidence for large-scale prehistoric collapse events at five of the centers (Great Sitkin, Kanaga, Tanaga, Gareloi, and Segula). Side-scan sonar data collected in the 1980s by GLORIA surveys reveal a hummocky seafloor fabric north of several islands, notably Great Sitkin, Kanaga, Bobrof, Gareloi, Segula, and Kiska, suggestive of landslide debris. Simrad EM300 multibeam sonar data, acquired in 2005, show that these areas consist of discrete large blocks strewn across the seafloor, supporting the landslide interpretation from the GLORIA data. A debris-avalanche deposit north of Kiska Island (177.6° E, 52.1° N) was fully mapped by EM300 multibeam revealing a hummocky surface that extends 40 km from the north flank of the volcano and covers an area of ∼ 380 km 2 . A 24-channel seismic reflection profile across the longitudinal axis of the deposit reveals a several hundred-meter-thick chaotic unit that appears to have incised into well-bedded sediment, with only a few tens of meters of surface relief. Edifice failures include thin-skinned, narrow, Stromboli-style collapse as well as Bezymianny-style collapse accompanied by an explosive eruption, but many of the events appear to have been deep-seated, removing much of an edifice and depositing huge amounts of debris on the sea floor. Based on the absence of large pyroclastic sheets on the islands, this latter type of collapse was not accompanied by large eruptions, and may have been driven by gravity failure instead of magmatic injection. Young volcanoes in the central and western portions of the arc (177° E to 175° W) are located atop the northern edge of the ∼ 4000-m-high Aleutian ridge. The position of the Quaternary stratocones relative to the edge of the Aleutian ridge appears to strongly control their likelihood for, and direction of, past collapse. The ridge's steep drop to the north greatly increases potential runout length for slides that originate at the island chain.

Earth and Planetary Science Letters↗

USGS2022

The role of preexisting upper plate strike-slip faults during long-lived (ca. 30 Myr) oblique flat slab subduction, southern Alaska

Upper plates of subduction zones commonly respond to flat slab subduction by structural reactivation, magmatic arc disruption, and foreland basin inversion. However, the role of active strike-slip faults in focusing convergent deformation and magmatism in response to oblique flat slab subduction remains less clear. Here, we present new detrital apatite fission-track (dAFT) ages from 12 modern catchments in the eastern Alaska Range, Alaska, USA, to reveal how the dextral Denali fault system has facilitated bedrock exhumation and topographic growth during ca. 30 Ma-to-present oblique flat slab subduction of the Yakutat oceanic plateau. Additionally, a 940 ka ( 40 Ar/ 39 Ar whole rock) basalt flow is spatially associated with Cenozoic structures, locally reset AFT ages and provides the first evidence for Quaternary volcanism along the southern flank of the eastern Alaska Range. We integrate our new data with other thermochronologic, geochronologic, and regional geologic datasets to show that (1) most high topography regions in southern Alaska have undergone rapid bedrock cooling and exhumation since ca. 30 Ma; (2) elevated terrain and young cooling are spatially associated with long-lived active strike-slip fault systems; (3) topographic growth associated with strike-slip fault deformation led to local inversion of basin systems and drainage reorganization; (4) the onset of oblique oceanic plateau subduction is coeval with a southward shift in arc magmatism from one region of active strike-slip faulting to another above the northeastern edge of the flat slab; and (5) Quaternary volcanism marks the revival of magmatism in the eastern Alaska Range above the geophysically imaged northeastern edge of the flat slab. Our analysis of the post-30 Ma geologic evolution of southern Alaska demonstrates that strike-slip fault systems that were active at the time of slab flattening evolved into transpression zones that focused bedrock cooling, rock exhumation, and topographic growth.

Alaska↗

USGS2012

Tectonic influences on the preservation of marine terraces: Old and new evidence from Santa Catalina Island, California

The California Channel Islands contain some of the best geologic records of past climate and sea-level changes, recorded in uplifted, fossil-bearing marine terrace deposits. Among the eight California Channel Islands and the nearby Palos Verdes Hills, only Santa Catalina Island does not exhibit prominent emergent marine terraces, though the same terrace-forming processes that acted on the other Channel Islands must also have occurred on Santa Catalina. We re-evaluated previous researchers' field evidence and examined new topographic, bathymetric, and stream-profile data in order to find possible explanations for the lack of obvious marine terrace landforms or deposits on the island today. The most likely explanation is associated with the island's unresolved tectonic history, with evidence for both recent uplift and subsidence being offered by different researchers. Bathymetric and seismic reflection data indicate the presence of submerged terrace-like landforms from a few meters below present sea level to depths far exceeding that of the lowest glacial lowstand, suggesting that the Catalina Island block may have subsided, submerging marine terraces that would have formed in the late Quaternary. Similar submerged marine terrace landforms exist offshore of all of the other California Channel Islands, including some at anomalously great depths, but late Quaternary uplift is well documented on those islands. Therefore, such submarine features must be more thoroughly investigated and adequately explained before they can be accepted as definitive evidence of subsidence. Nevertheless, the striking similarity of the terrace-like features around Santa Catalina Island to those surrounding the other, uplifting, Channel Islands prompted us to investigate other lines of evidence of tectonic activity, such as stream profile data. Recent uplift is suggested by disequilibrium stream profiles on the western side of the island, including nickpoints and profile convexities. Rapid uplift is also indicated by the island's highly dissected, steep topography and abundant landslides. A likely cause of uplift is a restraining bend in the offshore Catalina strike-slip fault. Our analysis suggests that Santa Catalina Island has recently experienced, and may still be experiencing, relatively rapid uplift, causing intense landscape rejuvenation that removed nearly all traces of marine terraces by erosion. A similar research approach, incorporating submarine as well as subaerial geomorphic data, could be applied to many tectonically active coastlines in which a marine terrace record appears to be missing.

California↗

USGS2024

Two-million-year eruptive history of Laguna del Maule volcanic field

The Laguna del Maule (LdM) volcanic field, which surrounds the 54-km 2 lake of that name, covers ∼500 km 2 of mountainous glaciated terrain with Quaternary lavas and tuffs that extend 40 km westward from the Argentine frontier and 30 km north-south from the Río Campanario to Laguna Fea. Complementing recent investigations of postglacial volcanism and the ongoing geophysical unrest around the lake, we here review the longer eruptive history that spanned the entire Quaternary.

Journal of South American Earth Sciences↗

USGS2023

Precaldera mafic magmatism at Long Valley, California: Magma-tectonic siting and incubation of the Great Rhyolite System

The iconic volcanic center at Long Valley has released ∼820 km 3 of rhyolite in at least 110 eruptions. From 2.2 Ma until 0.23 Ma, products were exclusively rhyolitic, and ∼ 700 km 3 were high-silica rhyolite severely depleted in Sr, Ba, and Eu. The rhyolitic interval was preceded by an interval from 3.9 to 2.6 Ma with numerous basalt-andesite-dacite eruptions accompanied by no rhyolite at all. We have now mapped the circumcaldera products of this interval, defined 107 eruptive units, characterized them all chemically and petrographically, and dated many by 40 Ar/ 39 Ar. Here we display and describe them by sector around the caldera, interpret the nature of the transcrustal magma system that eventuated in the 35-km-wide Long Valley granite-rhyolite pluton, and analyze regional tectonic factors that did or did not contribute to siting the system. Nine Miocene (12–6 Ma) eruptive units close to Long Valley were followed by a Pliocene flare-up that released >300 mafic eruptions in a SW–NE swath 170 km long, centered across the later site of Long Valley. The basalts and their fractionates are intraplate alkalic products dominated by a continental lithosphere that had long been fluxed by Mesozoic subduction. Tertiary arc volcanism had not impinged on the area of Long Valley. Volumes estimated for the 107 Neogene precaldera eruptive units (only 40 of which exceeded 0.1 km 3 ) total ∼ 27 km 3 ± 50%—only ∼3% of the subsequent volume of rhyolite erupted. Such a volume of high-silica rhyolite with ultra-low Sr and Eu is not a product of partial melting but requires as proximate parent a leucogranitic crystal mush that is itself the upper level of a long-lived plutonic reservoir that extends to the lower crust. The 27 km 3 of Neogene magma that erupted was a small contingent of the mantle-derived basaltic flux needed to energize (and contribute its fractionated melt to) a 30-km-deep compositionally graded crustal column, which culminated in ∼10,000 km 3 of granitoid mush from which 820 km 3 of Quaternary high-silica rhyolitic melt escaped and erupted. Pliocene basaltic eruptions ceased at ∼2.6 Ma, probably because the basaltic flux intensified sufficiently to render the mushy upper crust impenetrable. The 2.6–2.2 Ma quiescent interval represented culmination of thermal activation of the plutonic column and refinement of its leucogranitic mushy upper layer, from which extreme melts escaped for the next 2 Myr. The Pliocene mafic swath crosses the Sierran rangefront fault zone coincident with a left-stepping extensional reentrant that also began developing at ∼3 Ma. Moreover, Long Valley overlies a dextral offset in the initial Sr-isotope 0.706 line, which may reflect the rifted or attenuated edge of Proterozoic crust and mantle lithosphere. Concatenation of these three influences may account for siting of intensified edge-focused magmatism that produced the great Quaternary pluton.

California↗

USGS2020

Seismic stratigraphic framework of the continental shelf offshore Delmarva, U.S.A.: Implications for Mid-Atlantic Bight evolution since the Pliocene

Understanding how past coastal systems have evolved is critical to predicting future coastal change. Using over 12,000 trackline kilometers of recently collected, co-located multi-channel boomer, sparker and chirp seismic reflection profile data integrated with previously collected borehole and vibracore data, we define the upper (< 115 m below mean lower low water) seismic stratigraphic framework offshore of the Delmarva Peninsula, USA. Twelve seismic units and 11 regionally extensive unconformities (U1-U11) were mapped over 5900 km 2 of North America's Mid-Atlantic continental shelf. We interpret U3, U7, U9, U11 as transgressive ravinement surfaces, while U1,2,4,5,6,8,10 are subaerial unconformities illustrating distinct periods of lower sea-level. Based on areal distribution, stratigraphic relationships and dating results (Carbon 14 and amino acid racemization estimates) from earlier vibracore and borehole studies, we interpret the infilled channels as late Neogene and Quaternary courses of the Susquehanna, Potomac, Rappahannock, York, James rivers and tributaries, and a broad flood plain. These findings indicate that the region's geologic framework is more complex than previously thought and that Pleistocene paleochannels are abundant in the Mid-Atlantic. This study synthesizes and correlates the findings of other Atlantic Margin studies and establishes a large-scale Quaternary framework that enables more detailed stratigraphic analysis in the future. Such work has implications for inner continental shelf systems tract evolution, the relationship between antecedent geology and modern coastal systems, assessments of eustacy, glacial isostatic adjustment, and other processes and forcings that play a role in passive margin evolution.

Delaware, Maryland, Virginia↗

USGS2006

Introduction to ‘Antarctic climate evolution: View from the margin’

This special issue on “Antarctic Climate Evolution—view from the margin” presents results from modelling studies and reports on geoscience data aimed at improving our understanding of the behaviour of the Antarctic ice sheet and the climate of the region. This research field is of interest because of the sensitivity of the polar regions to global warming, and because of the influence of the Antarctic ice sheet on global sea level and climate through most if not all of the Cenozoic Era. The Antarctic ice sheet both responds to and forces changes on global climate and sea level. We need to be aware of the scale and frequency of these changes if we are to understand past patterns of environmental change elsewhere on earth. It was only three decades ago that we discovered from strata drilled in shelf basins on the Antarctic margin that the Antarctic ice sheet had a history that predated the Quaternary ice ages by over 20 million years ( Hayes et al., 1975 ). Later that year the first interpretation of Antarctic glacial history through the Cenozoic Era from oxygen isotopes, recorded in foraminifera from deep-sea sediment cores, was published ( Shackleton and Kennett, 1975 ). Revisions with a more extensive database have modified the story a little ( Miller et al., 1987 , Zachos et al., 2001 ), and there have been recent attempts to resolve the temperature–ice volume ambiguity ( Lear et al., 2000 ). However, reports on strata drilled on the Antarctic margin have unambiguously shown the character of this huge ice sheet, which was oscillating in the Oligocene ( Barrett et al., 1987 , Barrett, 1999 ) with a period and magnitude comparable with the Northern Hemisphere ice sheets of the Quaternary ( Naish et al., 2001a , Naish et al., 2001b ). In this issue we present further research on the history of the Antarctic ice sheet from Oligocene to recent times, most of them from the Antarctic margin, but with some on the nature of the deep-sea isotope record, and others using recently developed modeling techniques to investigate the influence of atmosphere, ocean and biosphere on past Antarctic climate. This special issue is the third in three years on the theme of Antarctic Climate Evolution. The first followed a workshop in Erice, Sicily, in 2001 to report on results from ANTOSTRAT, a SCAR-sponsored project for gathering and analysing circum-Antarctic seismic data for planning and promoting offshore drilling for climate history. The introduction to that issue (Florindo et al., 2003) provides a review of the recent history of circum-Antarctic drilling by the Ocean Drilling Program (Legs 113, 114, 119, 120, 177, 178, 188 and 189) and the Cape Roberts Project. For a more comprehensive review of earlier drilling in the Ross Sea region (Deep Sea Drilling Project Leg 28, Dry Valley Drilling Project, McMurdo Sound Sediment and Tectonic Studies, Cenozoic Investigations in the western Ross Sea) see Hambrey and Barrett (1993). The first of these issues (Florindo et al., 2003) featured a global plate reconstruction of the Southern Hemisphere through Cenozoic time with emphasis on evolution of Cenozoic seaways (Lawver and Gahagan, 2003) along with a study of the inception and early evolution of the EAIS using a new coupled global climate (GCM)–dynamic ice sheet model (DeConto and Pollard, 2003b), as well as data from recent drilling around the margin covering time period from Cretaceous to the present. A second special issue on the same theme (Florindo et al., 2005) also featured a mix of modelling and data papers with a focus on the Eocene–Oligocene boundary and the initiation of ice sheet growth, including a pioneering attempt to evaluate the relative influence of fluvial versus glacial processes in shaping the landscape of the Prydz Bay sector of Antarctica (Jamieson et al., 2005). The remainder of the issue comprised further papers on seismic stratigraphy and reports from drilling around the margin. The papers to be found in this special issue, like the previous two, maintain the mix of modelling- and data-oriented papers that reflect the range of this research.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

USGS2015

Uranium-series ages of fossil corals from Mallorca, Spain: The "Neotyrrhenian" high stand of the Mediterranean Sea revisited

The emergent marine deposits of the Mediterranean basin have been recognized as an important record of Quaternary sea level history for more than a century. Previous workers identified what have been interpreted to be two separate high stands of sea in the late Quaternary, namely the “Eutyrrhenian” (thought to be ~ 120 ka) and the “Neotyrrhenian” (thought to be either ~ 100 ka or ~ 80 ka). On Mallorca, Spain, both of these named deposits lie close to present sea level, implying paleo-sea levels slightly above present during both marine isotope stages (MIS) 5.5/5e and either 5.3/5c or 5.1/5a. If these interpretations are correct, they conflict, at least in part, with sea level records from far-field localities. We analyzed corals from the Neotyrrhenian beds on Mallorca, which gave U-series ages from ~ 126 ka to ~ 118 ka. These ages are consistent with previously published amino acid data that show that the Neotyrrhenian and Eutyrrhenian deposits are not significantly different in age. A fossil molluscan fauna from the Neotyrrhenian deposits on Mallorca has a warm-water paleozoogeographic aspect, with nine southward-ranging species and four extralimital southern species. When compared with sea surface temperatures obtained from planktonic foraminifera and alkenones from ODP core 977 in the nearby Alboran Sea, the only time period that shows comparable warmth is MIS 5.5/5e, consistent with the U-series ages of corals from the Neotyrrhenian deposits. We propose that the Neotyrrhenian deposits are a beachrock facies of the same age as the Eutyrrhenian deposits. This interpretation is consistent with the differences in physical sedimentology of the two deposits, explains the U-series and amino acid data indicating the same age, is consistent with the very slight elevation difference of the Neotyrrhenian and Eutyrrhenian beds, and explains the similar, though not identical paleozoogeographic aspects of their fossil faunas.

Mallorca↗

USGS2017

Oxygen stable isotopic disparities among sympatric small land snail species from northwest Minnesota, USA

The oxygen isotopic composition (δ 18 O) of land snail shells can be a valuable paleoenvironmental archive if the climatic parameters that influence the isotopic system are fully understood. Previous calibration studies have examined a limited number of species or individuals, and most have focused on larger (> 10 mm) taxa, which do not represent the dominant shell material in the Quaternary fossil record. In this study, we evaluate the δ 18 O values of small land snails (< 10 mm), which are common in modern settings and are often preserved in a wide array of Quaternary geologic and archeologic deposits. Our primary goal was to determine if coexisting species record equivalent isotopic information in their shells, regardless of differences in their ecology, dietary habits, behavior, and/or body size. We collected and analyzed 265 individuals of 11 species from 12 sites in northwest Minnesota (USA), which exhibits extremely abundant and diverse terrestrial malacofauna in North America. We did not observe significant correlations between shell δ 18 O values and the type of ecosystem (forest/grassland) or hydrologic setting (upland/lowland). However, the majority of species differed significantly in shell δ 18 O values. Larger taxa ( Catinella , Succinea , Discus ) consistently yielded higher δ 18 O values than smaller taxa ( Euconulus , Gastrocopta , Hawaiia , Vallonia ), by up to ~ 3‰. These isotopic offsets among sympatric taxa could be attributed to a number of physical, behavioral, and/or evolutionary traits, including the ability of larger species to tolerate drier conditions better than their smaller counterparts, differences in their preferred microhabitats or phylogentic non-independence. Regardless of the reason, our results imply that researchers should not combine isotopic data from different types of land snails without first investigating modern specimens to determine if it is appropriate. Moreover, our data suggest that combining instrumental climate data, a snail flux-balance model, and shell δ 18 O values can help us to better understand the ecology of land snails.

Minnesota↗

USGS1997

Shallow seismic reflection profiles and geological structure in the Benton Hills, southeast Missouri

During late May and early June of 1993, we conducted two shallow, high-resolution seismic reflection surveys (Mini-Sosie method) across the southern escarpment of the Benton Hills segment of Crowleys Ridge. The reflection profiles imaged numerous post-late Cretaceous faults and folds. We believe these faults may represent a significant earthquake source zone. The stratigraphy of the Benton Hills consists of a thin, less than about 130 m, sequence of mostly unconsolidated Cretaceous, Tertiary and Quaternary sediments which unconformably overlie a much thicker section of Paleozoic carbonate rocks. The survey did not resolve reflectors within the upper 75-100 ms of two-way travel time (about 60-100 m), which would include all of the Tertiary and Quaternary and most of the Cretaceous. However, the Paleozoic-Cretaceous unconformity (Pz) produced an excellent reflection, and, locally a shallower reflector within the Cretaceous (K) was resolved. No coherent reflections below about 200 ms of two-way travel time were identified. Numerous faults and folds, which clearly offset the Paleozoic-Cretaceous unconformity reflector, were imaged on both seismic reflection profiles. Many structures imaged by the reflection data are coincident with the surface mapped locations of faults within the Cretaceous and Tertiary succession. Two locations show important structures that are clearly complex fault zones. The English Hill fault zone, striking N30??-35??E, is present along Line 1 and is important because earlier workers indicated it has Pleistocene Loess faulted against Eocene sands. The Commerce fault zone striking N50??E, overlies a major regional basement geophysical lineament, and is present on both seismic lines at the southern margin of the escarpment. The fault zones imaged by these surveys are 30 km from the area of intense microseismicity in the New Madrid seismic zone (NMSZ). If these are northeast and north-northeast oriented fault zones like those at Thebes Gap they are favorably oriented in the modern stress field to be reactivated as right-lateral strike slip faults. Currently, earthquake hazards assessments are most dependent upon historical seismicity, and there are little geological data available to evaluate the earthquake potential of fault zones outside of the NMSZ. We anticipate that future studies will provide evidence that seismicity has migrated between fault zones well beyond the middle Mississippi Valley. The potential earthquake hazards represented by faults outside the NMSZ may be significant.

Missouri↗

USGS2004

Distribution of potentially hazardous trace elements in coals from Shanxi province, China

Shanxi province, located in the center of China, is the biggest coal base of China. There are five coal-forming periods in Shanxi province: Late Carboniferous (Taiyuan Formation), Early Permian (Shanxi Formation), Middle Jurassic (Datong Formation), Tertiary (Taxigou Formation), and Quaternary. Hundred and ten coal samples and a peat sample from Shanxi province were collected and the contents of 20 potentially hazardous trace elements (PHTEs) (As, B, Ba, Cd, Cl, Co, Cr, Cu, F, Hg, Mn, Mo, Ni, Pb, Sb, Se, Th, U, V and Zn) in these samples were determined by instrumental neutron activation analysis, atomic absorption spectrometry, cold-vapor atomic absorption spectrometry, ion chromatography spectrometry, and wet chemical analysis. The result shows that the brown coals are enriched in As, Ba, Cd, Cr, Cu, F and Zn compared with the bituminous coals and anthracite, whereas the bituminous coals are enriched in B, Cl, Hg, and the anthracite is enriched in Cl, Hg, U and V. A comparison with world averages and crustal abundances (Clarke values) shows that the Quaternary peat is highly enriched in As and Mo, Tertiary brown coals are highly enriched in Cd, Middle Jurassic coals, Early Permian coals and Late Carboniferous coals are enriched in Hg. According to the coal ranks, the bituminous coals are highly enriched in Hg, whereas Cd, F and Th show low enrichments, and the anthracite is also highly enriched in Hg and low enrichment in Th. The concentrations of Cd, F, Hg and Th in Shanxi coals are more than world arithmetic means of concentrations for the corresponding elements. Comparing with the United States coals, Shanxi coals show higher concentrations of Cd, Hg, Pb, Se and Th. Most of Shanxi coals contain lower concentrations of PHTEs. ?? 2004 Elsevier Ltd. All rights reserved.

Fuel↗

USGS1981

Speciation of aryloxyethoxyethyl benzyl dimethyl ammonium salts by glass capillary gas chromatography and high-performance liquid chromatography

Using glass capillary gas chromatography (GC) and ion-pair reversed-phase high-performance liquid chromatography (HPLC), a pair of structurally similar microbicides, benzyl diisobutylphenoxyethoxyethyl dimethyl ammonium chloride and its cresoxy-analogue, were effectively resolved and accurately quantified with a high degree of selectivity and specificity. Optimization of conditions in the chromatographic systems to attain desirable baseline separations of the components of interest is described. The minimum detectable quantities as determined are in the neighborhood of 10 ng for the quaternary ammonium salts by HPLC-UV detection, 0.1 ng for the cyanamide derivatives of the salts by GC-alkaline flame-ionization detection and 1–2 pg for the trichloroethyl carbamate derivatives of the salts by GC-electron-capture detection. In conjunction with cation-exchange chromatography for sample enrichment and purification, the glass capillary GC and ion-pair reversed-phase HPLC methods presented here are particularly suitable to separate and simultaneously analyze for the aryloxyethoxyethyl benzyl dimethyl ammonium compounds concerned in environmental samples. It appears that these chromatographic techniques possess potential applicability to the separation and quantification of other classes of quaternary ammonium compounds with closely related structures that are not separable by other methods.

Journal of Chromatography↗

USGS1997

Shallow subsurface geology of the continental shelf, Gulf of the Farallones, California, and its relationship to surficial seafloor characteristics

The Gulf of the Farallones is located on a continental margin that is tectonically active and has experienced eustatic fluctuations of sea level throughout the Quaternary. Bathymetry of the Gulf suggests that it is different from the average continental shelf off California in that instead of a seafloor that slopes gently seaward from the shoreline to the shelf edge (dominantly west to southwest), much of the Gulf shelf slopes to the northwest, a direction that is subparallel to that of the adjacent mainland shoreline. Isobaths are oblique to shore-normal for much of the Gulf shelf as opposed to the more typical shore-parallel isobaths. This northwest trend is parallel to that of the offshore granitic outcrops, the Farallon Island ridge and Cordell Bank. 3.5 kHz shallow subsurface profiles show a regional unconformity (basal unconformity of this study) that truncates bedrock and typically is overlain by a very thin veneer (1-2 m or less) of acoustically transparent unconsolidated sediment. In places, the basal unconformity appears to be coincident with the seafloor. Where the basal unconformity is within 1-2 m of the seafloor, side-scan sonar reveals that either bedrock pierces the seafloor or numerous linear depressions dissect the shelf seafloor. Side-scan sonar shows that the central part of the study area is characterized by numerous linear depressions that are on the order of 1-3 m deep, several meters to 5 km in length, and from 250 m to 2 km in width. The only Holocene unconsolidated sediment in excess of 1-2 m that has accumulated on the Gulf shelf is located where the bedrock surface is topographically depressed. The topographic lows are situated south of the Point Reyes headland and southwest of the Golden Gate. The sediment deposits that overlie these lows attain thicknesses up to 15-20 m; however, their average thickness is less than 10 m. Structure contours on the basal unconformity surface, essentially the top of the bedrock platform, also show that it is topographically high at its southern end and low at its northern end; the slope of the platform is therefore to the northwest. The seafloor mimics the attitude of the bedrock platform owing to the lack of appreciable sediment cover and hence also slopes northwest. This accounts for the oblique to shore-normal orientation of isobaths in the Gulf and the northwestward slope of the seafloor. The results of this investigation suggest that eustatic sea level fluctuations in conjunction with local tectonics had a profound effect on the deposition, erosion, and preservation of sediment on the Gulf shelf throughout the Quaternary and that the shallow subsurface greatly influences many aspects of the present surficial morphology.

Marine Geology↗

USGS1999

Interaction of tectonic and depositional processes that control the evolution of the Iberian Gulf of Cadiz margin

This study provides an integrated view of the growth patterns and factors that controlled the evolution of the Gulf of Cadiz continental margin based on studies of the tectonic, sedimentologic and oceanographic history of the area. Seven sedimentary regimes are identified, but there are more extensive descriptions of the late Cenozoic regimes because of the larger data base. The regimes of the Mesozoic passive margin include carbonate platforms, which become mixed calcareous-terrigenous deposits during the Late Cretaceous-early Tertiary. The Oligocene and Early Miocene terrigenous regimes developed, in contrast, over the active and transcurrent margins near the African-Iberian plate boundary. The top of the Gulf of Cadiz olistostrome, emplaced in the Late Miocene, is used as a key horizon to define the 'post-orogenic' depositional regimes. The Late Miocene progradational margin regime is characterized by a large terrigenous sediment supply to the margin and coincides with the closing of the Miocene Atlantic-Mediterranean gateways. The terrigenous drift depositional regime of the Early Pliocene resulted from the occurrence of high eustatic sea level and the characteristics of the Mediterranean outflow currents that developed after the opening of the Strait of Gibraltar. The Late Pliocene and Quaternary regimes are dominated by sequences of deposits related to cycles of high and low sea levels. Deposition of shelf-margin deltas and slope wedges correlate with regressive and low sea level regimes caused by eustasy and subsidence. During the highstand regimes of the Holocene, inner shelf prograding deltas and deep-water sediment drifts were developed under the influence of the Atlantic inflow and Mediterranean outflow currents, respectively. A modern human cultural regime began 2000 years ago with the Roman occupation of Iberia; human cultural effects on sedimentary regimes may have equalled natural factors such as climate change. Interplay of tectonic and oceanographic controls dominated the evolution of the Cadiz margin during the Cenozoic. Depositional sequences formed where the tectonic setting provided the accommodation space and the shape of the deposits has been greatly influenced by the strong unidirectional Atlantic inflow currents on the shelf and Mediterranean outflow currents on the slope. The entire cycle of the inflow and outflow deposition along the margin has been controlled first by the tectonic evolution of the Betic and Rif gateways, which become closed during the Late Miocene, and after the Messinian by the opening of the Strait of Gibraltar. Strong current development during eustatic sea level highstands of the Pliocene and Quaternary has controlled deposition because of maximum sill depths at Gibraltar for water circulation. Lowstand sea levels slowed circulation and resulted in mud drapes over the slope and regressive stratigraphic sequences over the shelf. More recently, the human industrial revolution has caused heavy metal contamination of sediment and water over the Cadiz margin. Human activity also has affected sedimentation rates because of deforestation that caused increased depositional rates near undammed rivers and decreased rates where rivers have been dammed. Future research efforts will need to focus on: (1) the effect of increased Mediterranean outflow caused by river damming plus global warming and the increased outflow as a potential trigger for new ice ages; (2) assessments of geologic hazards for planning man-made shoreline structures, developing offshore petroleum resources and maintaining undersea communications cables; and (3) confirmation of the general geologic history of the Cadiz margin.

Marine Geology↗

USGS1997

The use of multifrequency and polarimetric SIR-C/X-SAR data in geologic studies of Bir Safsaf, Egypt

Bir Safsaf, within the hyperarid 'core' of the Sahara in the Western Desert of Egypt, was recognized following the SIR-A and SIR-B missions in the 1980s as one of the key localities in northeast Africa, where penetration of dry sand by radar signals delineates previously unknown, sand-buried paleodrainage valleys ('radar-rivers') of middle Tertiary to Quaternary age. The Bir Safsaf area was targeted as a focal point for further research in sand penetration and geologic mapping using the multifrequency and polarimetric SIR-C/X-SAR sensors. Analysis of the SIR-C/X-SAR data from Bir Safsaf provides important new information on the roles of multiple SAR frequency and polarimetry in portraying specific types of geologic units, materials, and structures mostly hidden from view on the ground and on Landsat TM images by a relatively thin, but extensive blanket of blow sand. Basement rock units (granitoids and gneisses) and the fractures associated with them at Bir Safsaf are shown here for the first time to be clearly delineated using C- and L-band SAR images. The detectability of most geologic features is dependent primarily on radar frequency, as shown for wind erosion patterns in bedrock at X-band (3 cm wavelength), and for geologic units and sand and clay-filled fractures in weathered crystal-line basement rocks at C-band (6 cm) and L-band (24 cm). By contrast, Quaternary paleodrainage channels are detectable at all three radar frequencies owing, among other things, to an usually thin cover of blow sand. The SIR-C/X-SAR data investigated to date enable us to make specific recommendations about the utility of certain radar sensor configurations for geologic and paleoenvironmental reconnaissance in desert regions.Analysis of the shuttle imaging radar-C/X-synthetic aperture radar (SIR-C/X-SAR) data from Bir Safsaf provides important new information on the roles of multiple SAR frequency and polarimetry in portraying specific types of geologic units, materials, and structures mostly hidden from view on the ground and on Landsat images by a relatively thin, but extensive blanket of blow sand. Basement rock units and associated fractures at the Bir Safsaf are clearly delineated using C- and L-band SAR images. The detectability of most geologic features depend primarily on radar frequency. The SIR-C/X-SAR data also provide recommendations about the utility of certain radar configurations for geologic and paleoenvironmental reconnaissance in deserts.

Remote Sensing of Environment↗

USGS1999

An example of neotectonism in a continental interior - Thebes Gap, Midcontinent, United States

Some of the most intense neotectonic activity known in the continental interior of North America has been recently discovered on a fault zone in the Thebes Gap area, Missouri and Illinois. This faulting almost assuredly was accompanied by large earthquakes. The zone is located approximately 30 km north of the New Madrid seismic zone and consists of complex north-northeast- to northeast-striking, steeply dipping faults that have had a long-lived history of reactivation throughout most of the Phanerozoic. Geophysical studies by others suggest that the faults are rooted in the deeply buried Late Proterozoic and Early Cambrian Reelfoot rift system. Quaternary deposits are cut by at least four episodes of faulting, two of which occurred during the Holocene. The overall style of neotectonic deformation is interpreted as right-lateral strike-slip faulting. At many locations, however, near-surface displacements have stepped from one fault strand to another and produced normal and oblique-slip faults in areas of transtension and high-angle reverse faults, thrust faults, and folds in areas of transpression. There is evidence of reactivation of some near-surface fault segments during the great 1811-1812 New Madrid earthquakes. Quaternary faulting at Thebes Gap demonstrates that there are additional seismic-source zones in the Midcontinent, U.S., other than New Madrid, and that even in the absence of plate-margin orogenesis, intense neotectonic activity does occur over long time periods along crustal weakenesses in continental interiors.

Tectonophysics↗