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Simulated effects of future water availability and protected species habitat in a perennial wetland, Santa Barbara County, California

This study evaluates the potential water availability in Barka Slough and the effects of changing hydrological conditions on the aquatic habitat of five protected species. Barka Slough is a historically perennial wetland at the downstream western end of the San Antonio Creek Valley watershed (SACVW). A previously published hydrologic model of the SACVW for 1948–2018 was extended to include 2019–2021 and then modified to simulate the future years of 2022–2051. Two models simulating the future years of 2022–2051 were constructed, each with different climate inputs: (1) a repeated historical climate and (2) a 2070-centered Drier Extreme Warming climate (2070 DEW). The model with the 2070 DEW climate had warmer temperatures and an increase in average annual precipitation driven by larger, albeit more infrequent, precipitation events than the model with the historical climate. Simulated groundwater pumpage resulted in cumulative groundwater storage depletion and groundwater-level decline in Barka Slough in both future models. The simulations indicate that Barka Slough may transition from a perennial to an ephemeral wetland. Streamflow, stream disconnection, and depth to groundwater are key habitat metrics for federally listed species in Barka Slough. Future seasonal conditions for each metric are more likely to affect federally listed species’ habitats under 2070 DEW climatic conditions. Future seasonal streamflow volume may negatively impact unarmored threespine stickleback ( Gasterosteus aculeatus williamsoni ) and tidewater goby ( Eucyclogobis newberryi) habitats. Future seasonal stream disconnection may negatively impact the unarmored threespine stickleback habitat. Future groundwater-level decline may negatively impact Gambel’s watercress ( Nasturtium gambelii ) and La Graciosa thistle ( Cirsium scariosum var. loncholepis ) habitats and could influence the ability to use Barka Slough as a restoration or reintroduction site for these species. Results from this study can be used to inform water management decisions to sustain future groundwater availability in the SACVW.

California

Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain

VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey's (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite . Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.

Texas

An evaluation of the effects of different deicing salt application rates on three watersheds in Essex County, New York

The U.S. Geological Survey, in cooperation with the New York State Department of Transportation, evaluated the effects of different deicing salt application rates on surface water, groundwater, and highway runoff quality near State highways in northern New York. Three reaches of State highways were tested with different deicing treatments between October 2019 and November 2022: a salt-sand mixture (Treatment A), a salt mixture applied at a lower rate (Treatment B), and a control mixture consistent with typical deicing salt amounts and application rates. Data on pavement conditions and the quality of surface water, highway runoff, and groundwater were collected. Surface electromagnetic data were also collected. Surface-water and groundwater quality downgradient from the State highways were compared with water quality at upgradient locations. The percentage of snow or ice coverage was used to evaluate the effectiveness of the salt applications. This report provides an overview of the transport of deicing salt. The Treatment B watershed had deicing mixture applied more frequently than other highway reaches, which caused it to have the highest annual total chloride application. Despite differences in chloride application, flow-weighted mean chloride concentrations in highway runoff were comparable across treatments. Chloride concentrations were elevated in surface water and groundwater downgradient from highways relative to chloride concentrations upgradient from highways. A chloride mass balance, calculated for one treatment watershed, indicated that groundwater affected by legacy deicing practices may be contributing additional chloride to surface water. Spatial patterns from electromagnetic surveys show a shallow saline plume alongside the highway in that area. Differences in winter severity and pavement-surface conditions drove deicing salt applications in the treatment areas. This study found that several factors affect chloride loads in the watersheds, including variable winter conditions, adaptive snow and ice management, legacy management practices, and area-specific aquifer and groundwater conditions.

New York

Transmissivity and water quality of water-producing zones in the intermediate aquifer system, Sarasota County, Florida

The intermediate aquifer system is an important water source in Sarasota County, Florida, because the quality of water in it is usually better than that in the underlying Upper Floridan aquifer. The intermediate aquifer system consists of a group of up to three water-producing zones separated by less-permeable units that restrict the vertical movement of ground water between zones. The diverse lithology, that makes up the intermediate aquifer system, reflects the variety of depositional environments that occurred during the late Oligocene and Miocene epochs. Slight changes in the depositional environment resulted in aquifer heterogeneity, creating both localized connection between water-producing zones and abrupt culmination of water-producing zones that are not well documented. Aquifer heterogeneity results in vertical and areal variability in hydraulic and water-quality properties. The uppermost water-producing zone is designated producing zone 1 but is not extensively used because of its limited production capability and limited areal extent. The second water-producing zone is designated producing zone 2, and most of the domestic- and irrigation-supply wells in the area are open to this zone. Additionally, producing zone 2 is utilized for public supply in southern coastal areas of Sarasota County. Producing zone 3 is the lowermost and most productive water-producing zone in the intermediate aquifer system. Public-supply well fields serving the cities of Sarasota and Venice, as well as the Plantation and Mabry Carlton Reserve well fields, utilize producing zone 3. Heads within the intermediate aquifer system generally increase with aquifer depth. However, localized head-gradient reversals occur in the study area, coinciding with sites of intense ground-water withdrawals. Heads in producing zones 1, 2, and 3 range from 1 to 23, 0.2 to 34, and 7 to 42 feet above sea level, respectively. Generally, an upward head gradient exists between producing zones 3 and 2. However, an upward head gradient between producing zones 2 and 1 does not consistently occur throughout Sarasota County, probably the result of greater ground-water withdrawals from producing zone 2 than from producing zone 1. The transmissivity of the intermediate aquifer system is spatially variable. Specific-capacity data from selected wells penetrating producing zones 2 and 3, were used to estimate transmissivity. Estimated transmissivity values for producing zones 2 and 3 range from about 100 to 26,000 feet squared per day and from about 1,300 to 6,200 feet squared per day, respectively. Because the capacity of specific water-producing zones is highly variable from site to site, estimating the performance of a specific water-producing zone as a water resource is difficult. Water samples collected during the study were analyzed for major-ion concentrations. Generally, bicarbonate type water from rock interaction occurs in northern Sarasota County; enriched calcium-magnesium-sulfate type water from deeper aquifers occurs in central Sarasota County; and sodium-chloride type water from saltwater mixing occurs in southern Sarasota County. In some areas of northern Sarasota County, the major-ion concentrations in water are lower in producing zone 2 than in producing zone 1. Major-ion concentrations in water are higher in producing zone 3 throughout the study area. A major objective of the study was to evaluate hydraulic and water-quality data to determine distinctions that could be used to characterize a particular producing zone. However, data indicate that both hydraulic and water-quality properties are highly variable within and between zones, and are more related to the degree of connection between and areal extent of water-producing zones than to aquifer depth and distance from the coast.

Florida

Hydrogeology, groundwater salinity distributions, and assessment of the effect of oil-production activities on groundwater in the Midway Valley area, western Kern County, San Joaquin Valley, California

This study seeks to determine the effects of oil field produced water disposal operations and well mechanical integrity issues on groundwater quality in oil fields in the southwest San Joaquin Valley, California. Whereas previous studies used groundwater wells to study shallow aquifers outside the oil fields, this study demonstrates that future approaches may use oil well geophysical logs to map groundwater head gradients, create salinity profiles and document changes in salinity over time in oil field areas with sparse groundwater well data and at depths greater than 330 m. We also incorporate an analysis of well histories to determine potential effects of compromised wellbore seals on changes in aquifer quality that cannot be explained by water disposal practices. Water quality in the aquifers is naturally brackish across most of the area, with better quality groundwater occurring in the eastern part. Geophysical logs are used to determine salinity variations within aquifers including the depth at which TDS exceeds 10,000 mg/L. This depth ranges from 366 m in the northwest to approximately 1,500 m in the southeast. Oil well porosity logs are used to determine water table elevations. These logs indicate the water table slopes south-southeast, showing the predominant groundwater flow direction is from oil field disposal areas toward better quality groundwater east of the oil fields. Geophysical logs show formation resistivity near some disposal facilities has decreased over time, indicating the salinity of the aquifer has increased due to disposal of saline produced water in injection wells and ponds. Oil well history analysis suggests that increased salinity over time in water-saturated sand intervals >1.5 km from disposal facilities may be caused by mechanical failures and/or incomplete borehole seals in poorly constructed or abandoned wellbores prevalent throughout the study area—particularly wells drilled prior to 1930.

California

Quality assurance and analysis of water levels in wells on Pahute Mesa and vicinity, Nevada Test Site, Nye County, Nevada

Periodic and continual water-level data from 1963 to 1998 were compiled and quality assured for 65 observation wells on Pahute Mesa and vicinity, Nye County, Nevada. As part of the quality assurance of all water levels, ancillary data pertinent to computing hydraulic heads in wells were compiled and analyzed. Quality-assured water levels that were not necessarily in error but which did not represent static heads in the regional aquifer system, or required some other qualification, were flagged. Water levels flagged include those recovering from recent pumping or well construction, water levels affected by nuclear tests, and measurements affected by borehole deviations. A cursory examination of about 30 wells with available water-level and down-hole temperature data indicate that water levels in most wells on Pahute Mesa would not be significantly affected by temperature if corrected to 95 degrees Fahrenheit. Wells with large corrections (greater than 10 feet) are those with long water columns (greater than 1,500 feet of water above the assumed point of inflow) in combination with mean water-column temperatures exceeding 105 degrees Fahrenheit. Water-level fluctuations in wells on Pahute Mesa are caused by several factors including infiltration of precipitation, barometric pressure, Earth tides, ground-water pumpage, and seismic events caused by tectonic activity and underground nuclear testing. No observed water-level fluctuations were attributed to a naturally occurring earthquake. The magnitude and duration of changes in water levels caused by nuclear tests are affected by the test size and the distance from a well to the test. Identifying water levels that might be affected by past nuclear tests is difficult because pre-testing water-level data are sparse. Hydrologically significant trends were found in 13 of 25 wells with multiple years of water-level record. The largest change in water levels (1,029 feet in 25 years) occurred in well U-19v PS 1D as a result of the Almendro nuclear test. Likely explanations for trends in most of the wells are either changes in precipitation patterns that affect recharge rates to the ground-water system, pumping effects from water-supply well U-20 WW, or a combination of these two factors.

Nevada

Ground-water quality atlas of Oakland County, Michigan

The U.S. Geological Survey (USGS), in cooperation with Oakland County Health Division (OCHD), collected 140 water samples from 38 wells in Oakland County during 1998 to better understand ground-water quality. OCHD had observed temporal variations in concentrations of various constituents, so two additional sets of samples were collected to evaluate potential short-term variability related to sample collection procedures and long-term seasonal variability. Replicate samples from 28 wells were analyzed in the Michigan Department of Environmental Quality (MDEQ) Drinking Water Laboratory to compare MDEQ’s analytical results to those obtained from the USGS National Water Quality Laboratory. Several additional databases describing population, land use, water supply, soils, geology, and flows of ground water and surface water are presented in the first part of the report to assist in interpreting the water-quality data. Maps created from these databases are provided in the first portion of the report as an extension of the study-area description. The U.S. Environmental Protection Agency (USEPA) has established Maximum Contaminant Levels (MCL) and Secondary Maximum Contaminant Levels (SMCL) for which samples were analyzed in this study. Water from the 38 wells sampled by the USGS did not exceed the SMCL or MCL for sulfate, fluoride, or nitrite. However, water from 26 wells exceeded the SMCL for iron, water from 12 wells exceeded the SMCL for manganese, and water from 12 wells exceeded the SMCL for dissolved solids. Water from two wells exceeded the MCL for nitrate, although nitrate concentrations in water from most wells was below the detection limit. Water from seven wells exceeded the SMCL for chloride, and water from all wells contained detectable concentrations of chloride. Water from five wells exceeded the MCL for arsenic, and most of the wells sampled contained detectable concentrations of arsenic. These five wells were identified from previous MDEQ analyses to have elevated arsenic concentrations, and were sampled to obtain additional chemistry information. Replicate samples were collected from 26 of the 38 wells for analysis at the MDEQ Drinking-Water Laboratory to compare the results with the USGS National Water Quality Laboratory. The results of the replicate analyses indicate close agreement between the laboratories, with mean differences for nitrate, chloride, and arsenic of 0.10 milligrams per liter (mg/L) as nitrogen, 6.8 mg/L, and 0.0008 mg/L, respectively between the USGS and MDEQ analyses. Potential health effects associated with ingesting nitrate, chloride, and arsenic are provided with the water-quality data, along with references for further information.

Michigan

Analysis of factors affecting plume remediation in a sole-source aquifer system, southeastern Nassau County, New York

Several plumes of dissolved, chlorinated solvents, including trichloroethylene, have been identified in a sole-source aquifer near the former Northrop Grumman Bethpage Facility and Naval Weapons Industrial Reserve Plant sites in southeastern Nassau County, New York. Past investigations have documented that the groundwater contamination originated from this industrial area and now extends to the south, in the direction of groundwater flow. The intermixed plumes are commonly referred to as the “Navy Grumman groundwater plume.” Detailed groundwater-flow modeling was needed for the New York State Department of Environmental Conservation (NYSDEC) to evaluate design options necessary for the construction, operation, optimization, maintenance, and monitoring of a groundwater extraction and treatment cleanup plan selected in a December 2019 Amended Record of Decision by the NYSDEC to comprehensively address these plumes. Consequently, the NYSDEC began a cooperative study with the U.S. Geological Survey in 2020 to better understand the local hydrogeologic framework using two independent approaches to characterize aquifer heterogeneity and update an existing regional groundwater-flow model to provide transient boundary conditions for new inset groundwater-flow models of the plume area. We developed these detailed inset models for the two independent aquifer characterizations using history-matching techniques coupled with a novel approach to risk-based management optimization of the remedial design. We also used the updated regional model to assess this optimized groundwater extraction and treatment design for potential saltwater intrusion. The ensembles of parameters resulting from history matching provided a platform with which to evaluate capture by water-supply and remedial wells using particle-tracking techniques. Using the ensemble to select a risk stance, we performed multiobjective optimization to identify various configurations of remedial pumping that are consistent with external constraints and that favor potentially competing objectives. Multiple solutions provide tradeoffs that NYSDEC can consider. In general, pumping redistribution may help to prevent further contamination migration downgradient. These and other study results are intended to support decisions for the remedial design focused on the local area encompassing the full extent of the Navy Grumman groundwater plume.

New York

Assessment of potential for natural attenuation of chlorinated ethenes and ethanes in ground water at a petrochemical reclamation site, Harris County, Texas

Redox conditions in the Numerous Sand Channels Zone beneath a petrochemical reclamation site in Harris County, Texas, range from sulfate reducing to methanogenic as indicated by the presence of methane in ground water and the range of molecular hydrogen concentrations. Assessment of the potential for reductive dechlorination using BIOCHLOR as a screening tool indicated conditions favoring anaerobic degradation of chlorinated organic compounds in the Numerous Sand Channels Zone. Evidence supporting reductive dechlorination includes apparently biogenic cis -1,2-dichloroethene; an increased ratio of 1,2-dichloroethane to 1,1,2-trichloroethane downgradient from the assumed contaminant source area; ethene and methane concentrations greater than background concentrations within the area of the contaminant plume; and a positive correlation of the ratio of ethene to vinyl chloride as a function of methane concentrations. The body of evidence presented in this report argues for hydrogenolysis of trichloroethene to cis -1,2-dichloroethene; of 1,1,2-trichloroethane to 1,2-dichloroethane; and of vinyl chloride to ethene within the Numerous Sand Channels Zone. Simulations using BIOCHLOR yielded apparent first-order decay constants for reductive dechlorination in the sequence tetrachloroethene trichloroethene cis -1,2-dichloroethene vinyl chloride ethene within the range of literature values reported for each compound and apparent first-order decay constants for reductive dechlorination in the sequence 1,1,2-trichloroethane 1,2-dichloroethane slightly greater than literature values reported for each compound along the upgradient segment of a simulated ground-water flowpath. Except for vinyl chloride, apparent rates of reductive dechlorination for all simulated species show a marked decrease along the downgradient segment of the simulated ground-water flowpath. Evidence for reductive dechlorination of chlorinated ethenes within the Numerous Sand Channels Zone indicates potential for natural attenuation of chlorinated ethenes. Reductive dechlorination of chlorinated ethanes apparently occurs to a lesser extent, indicating relatively less potential for natural attenuation of chlorinated ethanes. Additional data are needed on the concentrations and distribution of chlorinated ethenes and ethanes in individual fine sand intervals of the Numerous Sand Channels Zone. This information, combined with lower minimum reporting levels for future chloroethane analyses, might enable a more complete and quantitative assessment of the potential for natural attenuation at the site.

Texas

Land cover change within wetland complexes at Dixie Meadows, Churchill County, Nevada: 2015 – 2023

Dixie Meadows, Nevada, is a system of geothermal springs and seeps that feed a complex of marshes and wetland meadows that are located within lands managed by the Bureau of Land Management (BLM) and the Department of Defense (DOD). A previous U.S. Geological Survey report documented variability in satellite imagery-based land cover classifications for seven wetland complexes at near monthly time intervals between October 2015 and January 2022. This report presents additional data, extending analysis to November 2023. Land cover classifications between October 2015 and November 2023 demonstrated an association between vegetation cover characteristics and surface moisture, with Class 1 having dry, bare soil or sparse upland vegetation, Class 2 having moist, bare soil or sparse to small vegetation, Class 3 having dense green vegetation with potentially saturated soil conditions, Class 4 having a mix of shallow surface water, saturated soil, and dense green vegetation, and Class 5 having open surface water. Most of the wetland complexes occur close to spring outflows primarily within land managed by the DOD, though portions are also within BLM lands. The intervening and surrounding landscape outside of the wetland complexes assessed in this study are managed by the BLM. As a result, Class 1 land covers had the largest areal coverage for BLM managed lands. Classes 2 and 3 land covers were primarily mapped inside the wetland complexes and thus had the largest area coverage within DOD managed lands. Class 4 was almost exclusively mapped within the wetland complexes and thus was largely contained within DOD managed lands. Class 5 (open water) was exclusively mapped in and adjacent to a single wetland complex with catchment ponds on land managed by the BLM. The distribution of these land cover classes over the study period was seasonally and annually variable. Land cover areas of Classes 1 and 2 were larger during the spring months. Conversely, land cover areas of Classes 3 and 4 tended to be greatest during the summer or fall. These patterns might be influenced by differences in seasonal water sources and phenology.

Nevada

Investigation of land cover within wetland complexes at Dixie Meadows, Churchill County, Nevada, from October 2015 to January 2022

The U.S. Geological Survey investigated land cover at subannual time steps within six wetland areas in Dixie Valley, Churchill County, Nevada, from October 2015 to January 2022. As requested by the U.S. Fish and Wildlife Service, we used aerial photography and satellite remote sensing data to map surface water and other land cover types within the wetland complexes. We identified five land cover classes using the green normalized difference vegetation index (gNDVI) and its inverse relationship to the normalized difference water index (NDWI) within three U.S. Department of Agriculture National Agriculture Imagery Program aerial images (acquired in 2015, 2017, and 2019) and 110 European Space Agency Sentinel-2 satellite images (acquired 2015–2022). The relative wetness of soil conditions within each land cover class is estimated by comparison to previously published observations of relative conductivity measured by 79 field-based sensors within the wetlands from 2019 to 2021. We mapped the areal coverage of the five land cover classes for approximately 385 acres (1,559,000 square meters [m²]) comprising six individual wetland complexes as well as a larger 1,298- acre (5,254,000-m 2 ) area of interest inclusive of the wetland complexes and adjacent landscape. Land cover of open water (Class 5) primarily within ponds at one of the wetland complexes comprised 8,333 m 2 , on average, of the wetland complexes. Land cover of mixed shallow surface water, saturated soil, and vegetation (Class 4) comprised 111,723 m 2 on average of the wetland complexes. Land cover of dense green vegetation canopy cover (Class 3) that often (46 percent of observations) had underlying surface water or saturated soil conditions comprised 592,522 m 2 on average of the wetland complexes. The remaining areas of the wetland complexes not mapped as these three land cover types (Classes 2 and 1) had sparse vegetation or bare soil cover and commonly (greater than or equal to 67 percent of observations) had dry soil conditions. The investigation of land cover detailed in this report could inform future efforts to map land cover more precisely via higher resolution remote sensing or ground-based surveying or could be incorporated with other environmental monitoring data to characterize habitat and hydrology of the wetland complexes at Dixie Meadows.

Nevada

Potentiometric surface maps and groundwater-level hydrographs for confined aquifers of the New Jersey Coastal Plain, 2018

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection (NJDEP), prepared potentiometric surface maps for 10 confined aquifers of the New Jersey Coastal Plain physiographic province based on water-level measurements collected during late 2018 and early 2019 from 951 wells in New Jersey and parts of Pennsylvania and Delaware. Maps were prepared for the confined Cohansey aquifer, Rio Grande water-bearing zone, Atlantic City 800-foot sand, Piney Point aquifer, Vincentown aquifer, Wenonah-Mount Laurel aquifer, Englishtown aquifer system, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system. Potentiometric surface maps indicate regional cones of depression in the following aquifers and the counties in which they are centered: Atlantic City 800-foot sand in Atlantic County, the Piney Point aquifer in Cumberland County, the Wenonah-Mount Laurel aquifer and Englishtown aquifer system in Monmouth and Ocean Counties, the Wenonah-Mount Laurel aquifer in Camden and Gloucester County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Ocean County, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system in Camden County. Cones of depression with smaller areal extents were in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand centered in Cape May County, the Piney Point aquifer centered in Ocean County, the Wenonah-Mount Laurel aquifer in Salem and Burlington Counties, the Englishtown aquifer system in Camden County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth County, and the middle aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth, Ocean, and Salem Counties. No cone of depression was interpreted in the Vincentown aquifer. Long-term hydrographs are presented for 75 wells spanning each of the 10 confined aquifers, and contain a mix of discrete water-level measurements and daily mean water levels based on continuously recorded 15-minute data. Changes of water levels during 2014–19, as indicated by the hydrographs, were compared with those of previous periods to assess any departures from historical data. During 2014–19, water levels were stable and fluctuated within similar ranges as previous periods in the following aquifers and locations: all wells in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Vincentown aquifer, the Englishtown aquifer system, the Piney Point aquifer wells in Burlington and Ocean Counties, six of eight wells in the Wenonah-Mount Laurel aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system except those within NJDEP Critical Area II. Increasing water levels in 2014–19, ongoing since historical periods, were indicated in the following aquifers and locations: Atlantic County wells in the Piney Point aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system within NJDEP Critical Area II. Water levels in the Atlantic City 800-foot sand also increased during 2014–19 in wells in Atlantic County and northern Cape May County closer to the center of the cone of depression in that aquifer, which is a response unique to this period and absent from previous periods. During 2013–19, continued decreasing water levels, ongoing since previous periods, were indicated by hydrographs of Atlantic City 800-foot sand wells in southern Cape May County, Piney Point aquifer wells in Cumberland County where the regional cone of depression is located, and two wells in the Wenonah-Mount Laurel aquifer—070478, which in 2014–19 departed from previous periods, and 330020, which continued a gradual decrease throughout its period of record.

New Jersey

Hydrogeology, karst, and groundwater availability of Monroe County, West Virginia

Monroe County is in southeastern West Virginia, encompassing an area of 474 square miles. The area consists of karst and siliciclastic aquifers of Ordovician, Silurian, Devonian, and Mississippian age and is in parts of two physiographic provinces: the Valley and Ridge Province to the east of Peters Mountain, and the Appalachian Plateau Province to the west of Peters Mountain. This study was developed in response to inquiries from the Monroe County Commission requesting assessment of the water resources of the county to better understand the quantity of the county’s groundwater resources, for both current [2023] and future demand, and to provide information to support protection and management of the county’s valuable groundwater resources. Various products were developed for this study that provide knowledge with respect to water availability and contamination susceptibility of the karst aquifers within the county. U.S. Geological Survey (USGS) geologists conducted extensive geologic mapping in support of the project, producing (1) a countywide bedrock geologic map, (2) a countywide hydrogeologic map, and (3) a light detection and ranging (lidar)-derived countywide digital elevation model and associated sinkhole map. A significant part of this work was to map in detail the Greenbrier Group at the formation level, which prior to this study had only partially been completed. The report also includes (4) a description of the lithologic units identified as part of the geologic mapping process. U.S. Geological Survey hydrologists completed several additional products for the hydrology part of the effort, including development of (1) a countywide potentiometric surface (water-table) map, (2) a countywide base-flow stream assessment, (3) countywide water-budget estimates, (4) well log surveys for 15 wells to better understand subsurface controls on groundwater flow within the study area, (5) two groundwater tracer tests to better refine the groundwater divide from the northern and southern parts of the karst aquifer in Monroe County; and finally, based on all available data collected for the study including the potentiometric surface map, geologic map, current [2023] and legacy fluorometric groundwater tracer tests, and base-flow stream assessments, (6) groundwater-basin delineations were reassessed for principal groundwater basins within the Greenbrier aquifer. In Monroe County, four principal hydrogeologic settings produce large yields of water for residential, agricultural, and other uses. The most relied upon water-bearing zone with respect to current [2023] public water supply is from springs along Peters Mountain. These springs are derived from intervals of fractured sandstone and resultant alluvial deposits. Groundwater flows downslope through these permeable alluvial deposits and discharges at the contact with less permeable strata, such as the Reedsville Shale. The second most relied upon water-bearing zone in Monroe County is within the karstic Greenbrier Group aquifer, in which the basal Hillsdale Limestone overlies the less permeable Maccrady Shale. This geologic contact between the Hillsdale Limestone and Maccrady Shale is not only targeted as a source of water for agricultural supply but also is targeted as a source of water for residential supply. The third most relied upon water-bearing zone is composed of shallow perched aquifers within the Greenbrier Group. The discontinuous nature of these perched aquifers makes mapping their extent impossible, but they are related to permeable geologic strata, such as karstified limestones with solutionally enhanced permeability that overlies less permeable shale or chert bedrock. During geologic mapping of the county, several of these perched aquifers were documented in the Pickaway, Union, and Alderson Limestones. A fourth zone consists of springs from Ordovician carbonates at the base of Peters Mountain, which are influenced by sinking streams as well as upwelling along faults. In terms of water quantity, the most sustainable springs are those having deeper-sourced flows. Public supplies are a principal source of water used for residential and commercial supply in the region, accounting for 0.49 million gallons per day (Mgal/d) of fresh-water withdrawals (0.14 Mgal/d of groundwater and 0.35 Mgal/d of surface water) for residential and commercial use and serving 6,645 individuals (49.2 percent of the population). An estimated 6,861 people, (50.8 percent of the population) primarily rely on private wells or other unregulated sources, such as springs, and withdraw 0.55 Mgal/d of groundwater for their residential use. Public water supply in the region is primarily (71.4 percent) derived from springs and augmented by stream withdrawals (backup sources mainly during low-flow periods), with the remaining portion (28.6 percent) derived from groundwater withdrawals from wells. For rural residents, however, 100 percent of their withdrawals are derived from groundwater (wells or springs).

West Virginia

Escherichia coli monitoring and assessment in 2022 and 2023 after beach restoration at Lake St. Clair Metropark Beach, Macomb County, Michigan

Lake St. Clair Metropark Beach in Michigan has a history of closures because of elevated Escherichia coli ( E. coli ) concentrations in its recreational waters. To reduce closures, restoration projects were implemented in 2021 to deter waterfowl from congregating on the beach. In this study, the U.S. Geological Survey, in cooperation with the Michigan Department of the Environment, Great Lakes, and Energy and in collaboration with Huron-Clinton Metroparks and the Macomb County Health Department, monitored E. coli from 2022–23 in surface water, shallow groundwater, and sediment at Lake St. Clair Metropark Beach. Results were compared to data from a prerestoration (2018–19) study. A significant decrease in daily geometric mean E. coli concentrations in surface water was observed postrestoration, but the number of high concentration events increased. This resulted in more frequent beach closures postrestoration. Surface-sediment E. coli concentrations significantly decreased after restoration, and waterfowl populations generally decreased from 2021 to 2023, suggesting that the deterrence measures could be influencing E. coli concentrations in surface sediments and surface water. Groundwater E. coli concentrations were orders of magnitude higher than those in surface water and revealed no change correlated with restoration. Seepage measurements indicated that groundwater occasionally discharges into surface water, potentially providing a transport mechanism for E. coli to reach the lake. Continued monitoring and consideration of environmental factors could help to better understand the beach system.

Michigan

Map of topographic lineaments interpreted as recent surface ruptures along the Bennett Valley and Southern Maacama Fault Zones, Sonoma County, California

This study documents lidar-illuminated topographic lineaments interpreted as evidence of recent surface fault ruptures and surface ruptures related to distributed deformation along the Bennett Valley Fault Zone and the southernmost Maacama Fault Zone in the northern San Francisco Bay area (fig. 1, on map sheet). Together, these fault zones form a structural connection across a right stepover between the main Maacama Fault Zone and the Rodgers Creek Fault, overlapping principal strands of the San Andreas plate boundary system north of San Francisco Bay (figs. 1, 2, on map sheet) that accommodate about a quarter of the ~40 millimeters per year of regional dextral tectonic slip (Parsons and others, 2013). Although much of the Bennett Valley Fault Zone is seismically active (McLaughlin and others, 2012; Sowers and others, 2010), only the north end of the fault zone (the “Spring Valley strand,” indicated on southern map panel of map sheet and labeled “D” in figure 2, on map sheet) was previously known to have youthful geomorphic expression and to displace Holocene deposits (McLaughlin and others, 2008; Sowers and others, 2010; Sowers and others, 2016). Holocene activity along the length of the Bennett Valley Fault Zone and southernmost Maacama Fault Zone, with possible implications for rupture propagation, continuity, and slip transfer, had not been identified. However, fault splays that project eastward from the Rodgers Creek Fault have been mapped and hypothesized to accommodate slip transfer to the Bennett Valley Fault Zone (Hecker and Randolph Loar, 2018). The generally subtle and distributed nature of surface-rupture evidence along the Bennett Valley and southernmost Maacama Fault Zones, and extensive vegetation cover, had left recent faulting previously unmapped along most of the zone. The map presented here represents a new compilation of inferred surface-rupture features detected using high-resolution topographic lidar data from an airborne lidar survey of Sonoma County, California (OpenTopography, 2014). These data, which enable subtle topographic features to be discerned, indicate that recent (likely Holocene) surface ruptures extend throughout the Bennett Valley and southernmost Maacama Fault Zones. The rupture-lineament map was created using a GIS (geographic information system) framework and is included herein as an image map at a scale of 1:36,000 and as digital datasets (included as supplemental information to this report). The mapping is intended to lay the groundwork for future studies designed to better characterize how plate-boundary slip is accommodated on this important and complex system of faults.

California

Salinas Valley integrated hydrologic and reservoir operations models, Monterey and San Luis Obispo Counties, California

The area surrounding the Salinas Valley groundwater basin in Monterey and San Luis Obispo Counties of California is a highly productive agricultural area, contributes substantially to the local economy, and provides a substantial portion of vegetables and other agricultural commodities to the Nation. This region of California provides about half of the Nation’s lettuce, celery, broccoli, and spinach each year. Thus, this agricultural area provides substantial volumes of agricultural products not just for California but for the United States. Changes in population and increased agricultural development, which includes a shift toward more water-intensive crops, and climate variability, have put increasing demand on both surface-water and groundwater resources in the valley. This situation has resulted in water management challenges in the Salinas Valley that generally relate to the distribution of the water supply throughout the basin. Where and when the water is present in the surface and subsurface does not coincide with where and when the water is needed. Historically, to deal with the distribution issue, water has been used conjunctively in the valley. Conjunctive use is a water management strategy that coordinates surface-water and groundwater use to maximize water availability. Groundwater is used throughout the Salinas Valley to meet water demands when surface-water supplies are insufficient. The availability of surface water is constrained by climate. Precipitation and streamflow vary seasonally and year to year. Although there are two reservoirs in the Salinas Valley to capture and store water during wet periods, the only conveyance of reservoir water to coastal agricultural areas is the Salinas River. Increasing demand for groundwater and surface-water resources throughout the Salinas Valley has resulted in undesirable effects from unsustainable water use, such as surface-water depletion, groundwater-level declines, storage depletion in the principal aquifers, and seawater intrusion. To address these escalating issues, local communities, water management agencies, and groundwater sustainability agencies are evaluating how to sustainably manage both their surface-water and groundwater resources. To meet water demands and reduce the undesirable effects of unsustainable water use, continued conjunctive management of surface water and groundwater would ideally incorporate strategies to deal with increases in demand and climate variability. To evaluate the challenging water management issues in the Salinas Valley, the U.S. Geological Survey, Monterey County Water Resources Agency, and the Salinas Valley Basin Groundwater Sustainability Agency developed a comprehensive suite of models that represent the Salinas Valley hydrogeologic system called the Salinas Valley System Model. The geologic framework is known as the Salinas Valley Geologic Framework and was developed to characterize the subsurface using various topographic and geologic data sources, including information on hydrogeologic units, their surfaces and extents, geologic structures, lithology, and elevations from borehole data and cross sections, as well as details on faults and existing models. The surface-water model is called the Salinas Valley Watershed Model and simulates the Salinas River watershed. Monthly surface-water inflows into the integrated hydrologic model domain were simulated using the Salinas Valley Watershed Model. The historical model uses historical climate data, water and land use data, and reservoir releases to simulate agricultural operations, including landscape water demands, diversions, and reclaimed wastewater. The operational model adds an embedded reservoir operations framework to the simulation of the historical model that allows specified operational rules to simulate reservoir releases and changes in reservoir storage. The operational model assumes current reservoir operations and constant land use, which differs from historical conditions. Thus, the operational model is a hypothetical baseline model that can be used by local water managers to evaluate and quantify potential benefits of water supply projects. Together, the geologic framework, watershed, historical, and operational models form a tool that can be used to simulate irrigated agriculture and associated reservoir operations of the integrated hydrologic system of the Salinas Valley.

California

Reduction of red bed sedimentary rocks in connection with energy metal ore formation: A case study from the Sinbad seep, Mesa County, Colorado

The Paradox Basin’s Sinbad seep is a modern analog for ancient bleaching of red bed sediments by introduced alkaline, reducing brines. This bleaching, involving reductive alteration of former red beds, is essential ground preparation that enables the altered rocks to trap Cu, U, and V from later oxidized fluids, forming ore deposits. Study of Sinbad thus offers insights into these metallic mineralization processes in the Paradox and other sedimentary basins. The Sinbad seep occurs where shallow groundwater interacts with organic-rich petroleum source rocks, flows up a fault, and discharges into Salt Creek. Ratios of Na/Cl, Na/Br, and Cl/Br, plus high sulfate concentrations, indicate that the salinity of the seep water originated from dissolution of halite and gypsum during topographically driven flow of meteoric water across a diapir of the Pennsylvanian Paradox Formation, rather than from deep basinal brines. In contact with the organic-rich shales of the Paradox, these SO 4 -rich waters become reduced through bacterial reduction, producing H 2 S. The waters react with red beds of the Permian Cutler Formation, causing pervasive bleaching. The bleaching at Sinbad is characterized by iron-conservative reduction of ferric iron in diagenetic hematite and detrital ilmenite and magnetite to Fe sulfides. The ferrous iron is retained in these sulfides likely as sorbed Fe. Associated alteration includes precipitation of quartz and feldspar overgrowths, partial dissolution of detrital quartz and feldspar caused by pressure solution, formation of clay and authigenic rutile, and precipitation of carbonate and gypsum. The Fe sulfides rapidly degenerate to a mixture of jarosite and iron oxides on weathering at the surface. Among the major-oxide elements and most trace elements, there is no statistical difference between unbleached and bleached samples. The exceptions are uranium and sulfur, which are somewhat greater in bleached samples. Fission track radiography illuminates that uranium is preferentially concentrated in iron oxide cements, iron sorbed into detrital clasts, and finely disseminated iron oxide in illite cement in bleached samples. A leaching experiment suggests that uranium may be more easily available for mobilization from rocks that have undergone bleaching alteration, making them potential U sources. In addition, bleached rocks form effective traps for U, V, and some Cu mineralization.

Colorado

Geologic map of the Buckner 7.5-Minute quadrangle, Louisa County, Virginia

The Buckner 7.5-minute quadrangle straddles three terrane boundaries in the Piedmont Physiographic Province in central Virginia: the Chopawamsic terrane, the Elk Hill Complex, and the Goochland terrane. In much of the map area, the Elk Hill Complex separates the Chopawamsic and Goochland terranes. Rocks of the Chopawamsic terrane include Ordovician metavolcanic and metasedimentary rocks of the Chopawamsic Formation, Ordovician to Silurian granodiorite sheet intrusions, and Paleozoic mafic intrusions. Silurian to Devonian rocks of the Quantico Formation, mostly garnet-mica schist, crop out in the northwesternmost part of the map area, and are in unconformable contact with rocks of the Chopawamsic Formation on the southeastern limb of the Quantico synclinorium. The main map unit in the Elk Hill Complex is Neoproterozoic mica gneiss, which is in pre-metamorphic fault contact with rocks of the Chopawamsic Formation to the west. The main map unit of the Goochland terrane is the Maidens Gneiss. Except for Jurassic diabase dikes, all rocks on the Buckner 7.5-minute quadrangle were metamorphosed to amphibolite facies during the Alleghanian orogeny and preserve multiple compositional and phyllosilicate penetrative foliations. Evidence of amphibolite-facies metamorphism during the Taconic orogeny is preserved in rocks of the Elk Hill Complex. The entire width of the Maidens Gneiss on the Buckner 7.5-minute quadrangle is within the Spotsylvania high-strain zone and amphibolite-facies mylonitic textures are pervasive. Quartz veins and Jurassic diabase dikes crosscut all older rocks of the quadrangle. Multiple levels of terrace deposits are present along and near the major streams of the quadrangle. The lower terrace deposits are likely remnants of former positions of the Little River on the landscape, whereas higher deposits may be remnants of former deposits of the Atlantic Coastal Plain that covered this portion of the Piedmont Province. A linear cluster of aftershocks from the magnitude 5.8 earthquake that occurred near Mineral, Virginia, in 2011 defines the Fredericks Hall fault, which is at depth on the Buckner quadrangle. Most of the aftershocks occurred in the core of the Elk Creek antiform and have no relation to faults mapped at the surface. Several abandoned crushed stone and building stone quarries, as well as a mica prospect, exist in the quadrangle.

Virginia