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USGS1997

Nutrients and pesticides in ground water of the Ozark Plateaus in Arkansas, Kansas, Missouri, and Oklahoma

A total of 229 ground-water samples were collected from 215 sites as part of the Ozark Plateaus study unit of the National Water-Quality Assessment Program. These samples were collected from 1993 through 1995 using a network of springs and wells with three scale-dependent components. The first component, the study-unit survey, consisted of 99 randomly selected springs and domestic wells in the Springfield Plateau and Ozark aquifers. The second component, two land-use studies, consisted of 42 springs and domestic wells in a poultry-dominated agricultural area and 40 springs and domestic wells in a cattle-dominated agricultural area overlying the Springfield Plateau aquifer. The third component, the small-watershed study, consisted of 4 springs, 18 domestic wells, and 11 monitoring wells in a small basin within the poultry land-use study area. Samples were analyzed for major ions, nutrients, dissolved organic carbon, methylene blue active substances, tritium, and 88 pesticides and metabolites.The water-quality data from these samples were analyzed with descriptive and statistical methods. Nitrite plus nitrate, which was detected more often and in greater concentrations than any of the other nutrients, ranged from less than 0.05 to 25 milligrams per liter as nitrogen. Nitrite plus nitrate concentrations positively correlated to percent agricultural land use around each site. Median nitrite plus nitrate concentrations generally were greater in samples from springs than in samples from wells. Concentrations of nitrite, ammonia, and ammonia plus organic nitrogen were also affected by land use and also by concentrations of dissolved oxygen in the ground water. Concentrations of phosphorus and orthophosphate probably were affected by land use and also by phosphorus solubility. Pesticides were detected in 80 of 229 samples from 73 of 215 sites. A total of 20 pesticides were detected with a maximum of 5 pesticides detected in any 1 sample. The most commonly detected pesticides were tebuthiuron, atrazine, prometon, desethylatrazine, and simazine. Maximum concentrations ranged from 0.003 to 1.0 microgram per liter. The occurrence and distribution of pesticides were related to land use. Percent agricultural land use was greater for samples with pesticides detected than for samples with no pesticides detected. Pesticides were detected more often in samples from springs than in samples from wells. The occurrence of pesticides also was related to seasonality and chemical characteristics, such as solubility and persistence, of the compounds.

Arkansas, Kansas, Missouri, Oklahoma↗
USGS1998

Peak-discharge frequency and potential extreme peak discharge for natural streams in the Brazos River basin, Texas

The 2-, 5-, 10-, 25-, 50-, and 100-year peak discharges were estimated for 186 streamflow-gaging stations with at least 8 years of data for natural streams in and near the Brazos River Basin, Texas. Multiple regression equations were developed to estimate peak-discharge frequency for the 2-, 5-, 10-, 25-, 50-, and 100-year recurrence intervals for each of three hydrologic regions that compose the Brazos River Basin. The equations for each region are a function of significant basin characteristics (explanatory variables). The significant explanatory variables among six that were tested are the contributing drainage area and stream slope for regions 1 and 2 and the contributing drainage area for region 3. For the three sets of equations, the coefficient of determination ranges from 0.59 to 0.93, and the standard error ranges from 0.184 to 0.391 log units. A larger coefficient of determination and a lower standard error generally are associated with the equations for hydrologic regions 2 and 3. Statistics from the regression analysis allow computation of the prediction interval associated with a given significance level for a peak-discharge frequency estimate. The regression equations can be used to estimate peak discharges for sites at, near, or away from sites with streamflow-gaging stations. The potential extreme peak-discharge curves as related to contributing drainage area were estimated for each of the three hydrologic regions from measured extreme peaks of record at 186 sites with streamflow-gaging stations and from measured extreme peaks at 37 sites without streamflow-gaging stations in and near the Brazos River Basin. The potential extreme peak-discharge curves generally are similar for hydrologic regions 1 and 2, and the curve for region 3 consistently is below the curves for regions 1 and 2, which indicates smaller peak discharges.

Texas↗
USGS2026

Water use permits as of July 2024 and reported water use near the North Unit of Theodore Roosevelt National Park, North Dakota, 1980–2023

Starting in the early 2000s, increasing oil and gas development in western North Dakota created a need for additional water resources from surface-water and groundwater sources near the North Unit of Theodore Roosevelt National Park. To summarize the use of water in that area, the U.S. Geological Survey, in cooperation with the National Park Service, developed a map of surface-water and groundwater resources, aquifers, and water-use diversions, and plotted water-use trends from 1980 to 2023. Reported water used from permits in the map area has more than doubled since 2020, increasing from about 750 acre-feet in 2020 to about 2,300 acre-feet in 2022 and 2,000 acre-feet in 2023. Surface water provided the primary source of reported water used for the study period with an average of about 410 acre-feet per year from 1980 through 2017 and about 1,330 acre-feet per year from 2018 through 2023. After 2011, groundwater sourced from the Little Missouri River, Tobacco Garden Creek, Fox Hills, Fort Union, and Dakota aquifers became a larger portion of total annual reported water use from permits in the map area. From 1980 through 2015, water use for irrigation averaged 86 percent of the total annual reported surface-water and groundwater use in the map area. Starting in 2011, however, industrial uses became a proportionally larger total use of water, and in 2015, became the highest reported volume of water use in the map area. From 2011 to 2023, industrial use designated for water depots increased from 50 acre-feet to about 1,370 acre-feet, accounting for about 70 percent of total reported water use in the map area in 2023.

North Dakota↗
USGS1998

Water resources of Mellette and Todd counties, South Dakota

Mellette and Todd Counties are located in south-central South Dakota and have a combined area of 2,694 square miles. The White River and its tributaries, which include the Little White River, drain Mellette County and about one-half of Todd County. Tributaries to the Niobrara River, which include the Keya Paha River, drain the other one-half of Todd County. The average discharge of the Little White River is about 56 cubic feet per second as the river enters Todd County and is about 131 cubic feet per second as it discharges to the White River in northern Mellette County. The average discharge of the Keya Paha River just outside Todd County is about 39 cubic feet per second. The average annual runoff for Mellette and Todd Counties ranges from 0.94 to 2.36 inches based on records from nine streamflow-gaging stations in and near the counties. The average annual runoff is 1.62 inches, which compares with the average annual precipitation of about 19 inches. In Todd County, shallow wells completed in the alluvial, Ogallala, Arikaree, and White River aquifers generally can supply water that has low concentrations of dissolved solids, is fresh, and is soft to moderately hard. Ground water from shallow aquifers is limited in Mellette County; therefore, deep wells, often greater than 1,000 feet, are sometimes installed. The Pierre Shale often is used to supply rural domestic and stock wells in Mellette County even though well yields are low and the water has high dissolved solids, is moderately saline, and is very hard. Alluvial aquifers are present in both counties and store an estimated 1.6 million acre-feet of water. The water quality of the alluvial aquifers is dependent on the underlying deposits, and generally the water has low concentrations of dissolved solids, is fresh, and is soft to moderately hard where underlain by the Ogallala and Arikaree Formations; has moderate concentrations of dissolved solids, is slightly saline, and is hard where underlain by the White River Group; and has high concentrations of dissolved solids, is saline, and is very hard where underlain by the Pierre Shale. Also, yields often are lower where the alluvial aquifers are underlain by the Pierre Shale. The Ogallala aquifer is present in only Todd County, and the Arikaree aquifer is present throughout most of Todd County and southwestern and south-central Mellette County. The Ogallala aquifer contains an estimated 17 million acre-feet of water in storage, and the Arikaree aquifer contains an estimated 50 million acre-feet of water in storage. Both aquifers generally are suitable for irrigation, and yields from these aquifers are sometimes greater than 1,000 gallons per minute. Nitrate concentrations in 13 out of 92 water samples collected from the Ogallala aquifer exceeded the Primary Drinking Water Maximum Contaminant Level (MCL) of 10 milligrams per liter. In 11 out of 46 samples collected from the Arikaree aquifer, arsenic concentrations exceeded the MCL of 50 micrograms per liter. The White River aquifer, where present, is usually the shallowest source of ground water in Mellette County. The White River aquifer also is used in northern Todd County where the Ogallala and Arikaree aquifers are not present. The White River aquifer contains an estimated 50 million acre-feet of water in storage. Reported yields from the aquifer range from 1 to 30 gallons per minute, which generally is insufficient to support irrigation in most areas. However, yields are sufficient for livestock-watering and rural-domestic purposes. In both counties, the Pierre Shale is the shallowest bedrock aquifer and is exposed at the land surface throughout most of Mellette County. This aquifer is used primarily in Mellette County. Although the aquifer contains an estimated maximum of 1.5 million acre-feet of water in storage, it is not a viable source of ground water because the aquifer is relatively impermeable, yields are low, and water usually can be obtained from shallower sources, especially in Todd County. Reported yields from the Pierre Shale aquifer range from 1 to 8 gallons per minute. Because few test holes and wells penetrate below the Pierre Shale, little is known about the extent of the deeper bedrock aquifers. All wells completed in the Dakota Sandstone, Inyan Kara, and Minnelusa and Madison aquifers in the counties are used for stock-watering purposes. High concentrations of dissolved solids and hard water are characteristic of the water quality in the bedrock aquifers. Depths to the top of the deeper bedrock aquifers range from 1,270 feet to greater than 2,000 feet below land surface.

South Dakota↗
USGS1998

Technique for simulating peak-flow hydrographs in Maryland

The efficient design and management of many bridges, culverts, embankments, and flood-protection structures may require the estimation of time-of-inundation and (or) storage of floodwater relating to such structures. These estimates can be made on the basis of information derived from the peak-flow hydrograph. Average peak-flow hydrographs corresponding to a peak discharge of specific recurrence interval can be simulated for drainage basins having drainage areas less than 500 square miles in Maryland, using a direct technique of known accuracy. The technique uses dimensionless hydrographs in conjunction with estimates of basin lagtime and instantaneous peak flow. Ordinary least-squares regression analysis was used to develop an equation for estimating basin lagtime in Maryland. Drainage area, main channel slope, forest cover, and impervious area were determined to be the significant explanatory variables necessary to estimate average basin lagtime at the 95-percent confidence interval. Qualitative variables included in the equation adequately correct for geographic bias across the State. The average standard error of prediction associated with the equation is approximated as plus or minus (+/-) 37.6 percent. Volume correction factors may be applied to the basin lagtime on the basis of a comparison between actual and estimated hydrograph volumes prior to hydrograph simulation. Three dimensionless hydrographs were developed and tested using data collected during 278 significant rainfall-runoff events at 81 stream-gaging stations distributed throughout Maryland and Delaware. The data represent a range of drainage area sizes and basin conditions. The technique was verified by applying it to the simulation of 20 peak-flow events and comparing actual and simulated hydrograph widths at 50 and 75 percent of the observed peak-flow levels. The events chosen are considered extreme in that the average recurrence interval of the selected peak flows is 130 years. The average standard errors of prediction were +/- 61 and +/- 56 percent at the 50 and 75 percent of peak-flow hydrograph widths, respectively.

Maryland↗
USGS1997

Hydrologic and water-quality conditions in the Horse Creek basin, west-central Florida, October 1992-February 1995

A baseline study of the 241-square-mile Horse Creek basin was undertaken from October 1992 to February 1995 to assess the hydrologic and water-quality conditions of one of the last remaining undeveloped basins in west-central Florida. During the period of the study, much of the basin remained in a natural state, except for limited areas of cattle and citrus production and phosphate mining. Rainfall in 1993 and 1994 in the Horse Creek basin was 8 and 31 percent, respectively, above the 30-year long-term average. The lowest and highest maximum instantaneous peak discharge of the six daily discharge stations occurred at the Buzzard Roost Branch and the Horse Creek near Arcadia stations with 185 to 4,180 cubic feet per second, respectively. The Horse Creek near Arcadia station had the lowest number of no-flow days with zero days and the Brushy Creek station had the highest number with 113 days. During the study, the West Fork Horse Creek subbasin had the highest daily mean discharge per square mile with 30.6 cubic feet per second per square mile, and the largest runoff coefficient of 43.7 percent. The Buzzard Roost Branch subbasin had the lowest daily mean discharge per square mile with 5.05 cubic feet per second per square mile, and Brushy Creek and Brandy Branch shared the lowest runoff coefficient of 0.6 percent. Brandy Branch had the highest monthly mean runoff in both 1993 and 1994 with 11.48 and 19.28 inches, respectively. During the high-baseflow seepage run, seepage gains were 8.87 cubic feet per second along the 43-mile Horse Creek channel. However, during the low-baseflow seepage run, seepage losses were 0.88 cubic foot per second. Three methods were used to estimate average annual ground-water recharge in the Horse Creek basin: (1) well hydrograph, (2) chloride mass balance, and (3) streamflow hydrograph. Estimated average annual recharge using these three methods ranged from 3.6 to 8.7 inches. The high percentage of carbonate plus bicarbonate analyzed at the Carlton surficial aquifer well could indicate an upward ground-water flow from the underlying intermediate aquifer system. Based on constituent concentrations in water samples from the six daily discharge stations, concentrations generally are lower in the upper three subbasins, West Fork Horse Creek, Upper Horse Creek, and Brushy Creek than in the lower three subbasins. Typically, concentrations were highest for major ions at Buzzard Roost Branch and nutrients at Brushy Creek.

Florida↗
USGS1999

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee↗
USGS1999

Water quality of Rob Roy Reservoir and Lake Owen, Albany County, and Granite Springs and Crystal Lake Reservoirs, Laramie County, Wyoming, 1997-98

The water quality of four reservoirs was assessed during 1997 and 1998 as a cooperative project between the Cheyenne Board of Public Utilities and the U. S. Geological Survey. The four reservoirs, Rob Roy, Lake Owen, Granite Springs, and Crystal Lake, provide approximately 75 percent of the public water supply for Cheyenne, Wyoming. Samples of water and bottom sediment were collected and analyzed for selected physical, chemical, and biological characteristics to provide data about the reservoirs. Water flows between the reservoirs through a series of pipelines and stream channels. The reservoirs differ in physical characteristics such as elevation, volume, and depth. Profiles of temperature, dissolved oxygen, specific conductance, and pH were examined. Three of the four reservoirs exhibited stratification during the summer. The profiles indicate that stratification develops in all reservoirs except Lake Owen. Stratification developed in Rob Roy, Granite Springs, and Crystal Lake Reservoirs by mid-July in 1998 and continued until September, with the thickness of the epilimnion increasing during that time. Secchi disk readings indicated Rob Roy Reservoir had the clearest water of the four reservoirs studied. The composition of the phytoplankton community was different in the upper two reservoirs from that in the lower two reservoirs. Many of the species found in Rob Roy Reservoir and Lake Owen are associated with oligotrophic, nutrient-poor conditions. In contrast, many of the species found in Granite Springs and Crystal Lake Reservoirs are associated with mesotrophic or eutrophic conditions. The total number of taxa identified also increased downstream. The chemical water type in the reservoirs was similar, but dissolved-solids concentrations were greater in the downstream reservoirs. Water in all four reservoirs was a calcium-bicarbonate type. In the fall of 1997, Rob Roy Reservoir had the lowest dissolved-solids concentration (19 milligrams per liter), whereas Crystal Lake Reservoir had the highest concentration (63 milligrams per liter). Relatively little differences in the concentrations of major-ion species were noted between samples collected near the surface and near the bottom of the same reservoir. In contrast, iron and manganese concentrations generally were higher in samples collected near the bottom of a reservoir than in near-surface samples collected from the same reservoir. Composite bottom-sediment samples from all four reservoirs contained similar concentrations of bulk constituents such as aluminum, iron, phosphorus and titanium, but varied in concentrations of trace elements. Trace-element concentrations in Rob Roy Reservoir and Lake Owen were similar to the crustal average, whereas in Granite Springs and Crystal Lake Reservoirs the concentrations were similar to granitic rocks.

Wyoming↗
USGS2000

Water quality of the Quaternary and Ada-Vamoosa aquifers on the Osage Reservation, Osage County, Oklahoma, 1997

The project was to provide information on the quality of ground water from rural-domestic-water wells within the Osage Reservation and compare the water-quality to proximity to oil wells. About 38,500 oil wells have been drilled in the Reservation since drilling began in 1896. About 1,480 square miles or 64 percent of the Reservation is within a quarter mile of an oil well. The unconfined Quaternary sand aquifer covers about 315 square miles or about 14 percent of the Reservation and the confined Ada-Vamoosa sandstone aquifer covers about 800 square miles or about 35 percent of the Reservation. Fifty-eight percent of the Quaternary aquifer and 69 percent of the outcrop area of the Ada-Vamoosa aquifer are within a quarter mile of an oil well. One hundred twenty domestic ground-water wells were sampled from the Quaternary and Ada-Vamoosa aquifers. Forty-nine percent of the Reservation is underlain by the aquifers. Ground-water quality is good on most of the Reservation, but the use of domestic-water-supply wells tend to minimize water-quality problems. Existing water-supply wells commonly are located in areas that produce usable volumes of potable water. Several constituents in samples from the Ada-Vamoosa aquifer within a quarter mile of an oil well were significantly greater than from the aquifer not near oil wells. The constituents include specific conductance, dissolved solids, sodium, sulfate, chloride, bromide, and silica. These ions are probably derived from brine water. In the Ada-Vamoosa aquifer subgroups, 57 percent of the samples near oil wells and 24 percent of the samples not near oil wells had dissolved-solids concentrations greater than 500 milligrams per liter. The water quality in the Quaternary and Ada-Vamoosa aquifers is similar in areas where no oil wells have been drilled but is significantly different for several constituents. Median concentrations of major constituents from the Ada-Vamoosa aquifer not near oil wells were less than or equal to values from the Quaternary aquifer. Sixty-four percent of the water-quality samples from the Quaternary and 51 percent from the Ada-Vamoosa aquifers have dissolved-solids concentrations less than the secondary drinking water regulations of 500 milligrams per liter. Fifty-nine percent of the aquifer samples in the Quaternary aquifer subgroups not near oil wells and 70 percent of the samples near oil wells had dissolved solids less than 500 milligrams per liter. Areas in the Ada-Vamoosa aquifer near Hominy, Pershing, and Hula Lake have dissolved-solids concentrations greater than the secondary drinking water regulations. Water-quality samples from the Quaternary aquifer in these areas also have dissolved-solids concentrations greater than 500 milligrams per liter.

Oklahoma↗
USGS2000

Use of a ground-penetrating radar system to detect pre- and post-flood scour at selected bridge sites in New Hampshire, 1996-98

Ground-penetrating radar was used to measure the depth and extent of existing and infilled scour holes and previous scour surfaces at seven bridges in New Hampshire from April 1996 to November 1998. Ground-penetrating-radar survey techniques initially were used by the U.S. Geological Survey to study streambed scour at 30 bridges. Sixteen of the 30 bridges were re-surveyed where floods exceeded a 2-year recurrence interval. A 300-megahertz signal was used in the ground-penetrating radar system that penetrated through depths as great as 20 feet of water and as great as 32 feet of streambed materials. Existing scour-hole dimensions, infilled thickness, previous scour surfaces, and streambed materials were detected using ground-penetrating radar. Depths to riprap materials and pier footings were identified and verified with bridge plans. Post data-collection-processing techniques were applied to assist in the interpretation of the data, and the processed data were displayed and printed as line plots. Processing included distance normalization, migration, and filtering but processing was kept to a minimum and some interference from multiple reflections was left in the record. Of the 16 post-flood bridges, 22 ground-penetrating-radar cross sections at 7 bridges were compared and presented in this report. Existing scour holes were detected during 1996 (pre-flood) data collection in nine cross sections where scour depths ranged from 1 to 3 feet. New scour holes were detected during 1998 (post-flood) data collection in four cross sections where scour depths were as great as 4 feet deep. Infilled scour holes were detected in seven cross sections, where depths of infilling ranged from less than 1 to 4 feet. Depth of infilling by means of steel rod and hammer was difficult to verify in the field because of cobble and boulder streambeds or deep water. Previous scour surfaces in streambed materials were identified in 15 cross sections and the depths to these surfaces ranged from 1 to 10 feet below the streambed. Riprap materials or pier footings were identified in all cross sections. Calculated record depths generally agree with bridge plans. Pier footings were exposed at two bridges and steel pile was exposed at one bridge. Exposures were verified by field observations.

New Hampshire↗
USGS1993

Ground-water quality near an inactive landfill and sludge-spreading area, Tallahassee, Florida

Ground-water quality of a 120-acre area encompassing an inactive landfill southwest of Tallahassee, Florida, was assessed by installing and sampling 21 monitoring wells. Sludge from a municipal sewage-treatment plant was also applied to the land surface near the landfill site. Water samples were collected from the 21 monitoring wells from June 1987 through September 1990 and analyzed for concentrations of major ions, nitrogen species, trace metals, field measurements, and more than 140 organic constituents. Water quality in the Upper Floridan aquifer at the study site was compared to background water quality in other areas of Leon County. Ground-water quality of the study site was evaluated by the location of wells sampled in relation to the landfill and the sludge-spreading areas. Results of nonparametric statistical analysis indicated that potassium and nitrite plus nitrate as nitrogen concentrations in water samples from wells completed in the Upper Floridan aquifer at the study site were significantly different at the 5 percent probability level from those in samples from background wells completed in this aquifer in Leon County. Median potassium concentrations were 0.4 mg/L (milligrams per liter) in water from wells at the study site and 0.7 mg/L in water from background wells in Leon County. Median nitrite plus nitrate concentrations were 6.48 mg/L in water samples from wells at the study site and 0.51 mg/L in water samples from background wells. Graphical comparison of the water quality characteristics in water from six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and background Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, and dissolved solids concentrations and specific conductance values were highest within the landfill. Upgradient and downgradient well categories include wells in areas affected by sludge spreading. Localized reducing conditions were indicated in a downgradient area by median iron concentrations of 930 and 30 ug/L (micrograms per liter) in samples from wells only 5 feet apart. Nitrite plus nitrate concentrations were lowest in water from wells in the landfill compared to water from the other categories. Concentrations of most trace elements and organic compounds were mostly below detection limits, although State maximum contaminant levels of 1 ug/L for benzene and vinyl chloride and 3 ug/L for tetrachloroethene were exceeded in 14 samples. Concentrations of sodium, potassium, chloride, sulfate, nitrite plus nitrate, total organic and ammonia nitrogen, and ammonia nitrogen in ground water were statistically analyzed in areas affected by sludge-spreading and other areas. Only nitrite plus nitrate and chloride concentrations were significantly different between the two areas. Median nitrite plus nitrate and chloride concentrations in sludge-spreading areas were 6.9 mg/L and 2.9 mg/L, respectively, compared to 1.1 mg/L and 1.8 mg/L in other areas.

Florida↗
USGS1998

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma — Nutrients, bacteria, organic carbon, and suspended sediment in surface water, 1993-95

Nutrient, bacteria, organic carbon, and suspended- sediment samples were collected from 1993-95 at 43 surface-water-quality sampling sites within the Ozark Plateaus National Water- Quality Assessment Program study unit. Most surface-water-quality sites have small or medium drainage basins, near-homogenous land uses (primarily agricultural or forest), and are located predominantly in the Springfield and Salem Plateaus. The water-quality data were analyzed using selected descriptive and statistical methods to determine factors affecting occurrence in streams in the study unit. Nitrogen and phosphorus fertilizer use increased in the Ozark Plateaus study unit for the period 1965-85, but the application rates are well below the national median. Fertilizer use differed substantially among the major river basins and physiographic areas in the study unit. Livestock and poultry waste is a major source of nutrient loading in parts of the study unit. The quantity of nitrogen and phosphorus from livestock and poultry wastes differed substantially among the river basins of the study unit's sampling network. Eighty six municipal sewage-treatment plants in the study unit have effluents of 0.5 million gallons per day or more (for the years 1985-91). Statistically significant differences existed in surface-water quality that can be attributed to land use, physiography, and drainage basin size. Dissolved nitrite plus nitrate, total phosphorus, fecal coliform bacteria, and dissolved organic carbon concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. A large difference in dissolved nitrite plus nitrate concentrations occurred between streams draining basins with agricultural land use in the Springfield and Salem Plateaus. Streams draining both small and medium agricultural basins in the Springfield Plateau had much larger concentrations than their counterparts in the Salem Plateau. Drainage basin size was not a significant factor in affecting total phosphorus, fecal coliform bacteria, or dissolved organic carbon concentrations. Suspended-sediment concentrations generally were small and indicative of the clear water in streams in the Ozark Plateaus. A comparison of the dissolved nitrite plus nitrate, total phosphorus, and fecal coliform data collected at the fixed and synoptic sites indicates that generally the data for streams draining basins of similar physiography, land-use setting, and drainage basin size group together. Many of the variations are most likely the result of differences in percent agricultural land use between the sites being compared or are discharge related. The relation of dissolved nitrite plus nitrate, total phosphorus, and fecal coliform concentration to percent agricultural land use has a strong positive 2 Water-Quality Assessment-Nutrients, Bacteria, Organic Carbon, and Suspended Sediment in Surface Water, 1993-95 correlation, with percent agricultural land use accounting for between 42 and 60 percent of the variation in the observed concentrations.

Arkansas, Kansas, Missouri, Oklahoma↗
USGS1992

Nonpoint-source pollutant discharges of the three major tributaries to Reelfoot Lake, west Tennessee, October 1987-September 1989

An investigation of the concentration and loads of nitrogen, phosphorus, and suspended sediment in storm runoff to Reelfoot Lake, in western Tennessee, was conducted from October 1987 through September 1989. Concentrations of selected herbicides also were defined. Reelfoot Lake, with a surface area of about 15,500 acres, is the largest natural lake in Tennessee and an important recreation and fisheries resource. Previous studies showed that the lake is hypereutrophic, a condition caused by high concentrations of nutrients in water and sediments discharged from the three principal tributaries (South Reelfoot Creek, North Reelfoot Creek, and Running Slough) to the lake. Pesticides, including herbicides, have been detected in the lake's bottom sediments. Storm runoff contributed about 87percent of the total water discharge of the three main tributaries to Reelfoot Lake. South Reelfoot Creek contributed about 4.7 tons per acre per year of suspended sediment, while North Reelfoot Creek contributed about 1.9 tons per acre per year. Running Slough contributed only about 0.31 ton per acre per year of suspended sediment. Most of the suspended sediment was transported by storm runoff between October and March. About 80 percent of the annual streamflow of the three tributaries occurs during these months. The North Reelfoot Creek basin contributed 8.2 pounds per acre per year of total nitrogen and 2.4 pounds per acre per year of total phosphorus. South Reelfoot Creek basin contributed about 6.5 and 1.3 pounds per acre per year of total nitrogen and phosphorus, respectively, while Running Slough basin contributions were 3.4 and 0.86 pounds per acre per year, respectively. The differences in nutrient yields appear to result from more row-crop agriculture and the relatively steeply sloping agricultural land in the North Reelfoot Creek basin. Ninety-one percent of the total nitrogen load and 95 percent of the total phosphorus load in the three streams was transported by storm runoff. Significant differences in the mean concentrations of nutrients in runoff were defined between the active agricultural months (April through September) and the inactive months (October through March). Storm-runoff samples were analyzed for II selected triazine herbicides. Alachlor and atrazine were the most commonly detected herbicides. Thirty-two percent of the samples contained detectable levels of alachlor and 93 percent of the samples contained detectable levels of atrazine. Ninety percent of the samples collected during the active agricultural months contained detectable leveki of alachlor and all 29 samples contained detectable levels of atrazine. Sixteen samples exceeded lifetime health-advisory levels for atrazine in drinking water (3 micrograms per liter); two samples collected from the April IS, 1988, storm at North Reelfoot Creek and South Reelfoot Creek contained 42 and 57 micrograms per liter of atrazine, respectively. Concentrations of the other nine triazine herbicides were generally less than the level of detection (0.1 microgram per liter).

Tennessee↗
USGS1999

Comparison of two approaches for determining ground-water discharge and pumpage in the lower Arkansas River Basin, Colorado, 1997-98

In March 1994, the Colorado Division of Water Resources (CDWR) adopted “Rules Governing the Measurement of Tributary Ground Water Diversions Located in the Arkansas River Basin” (Office of the State Engineer, 1994); these initial rules were amended in February 1996 (Office of the State Engineer, 1996). The amended rules require users of wells that divert tributary ground water to annually report the water pumped monthly by each well. The rules allow a well owner to report the pumpage measured by a totalizing flowmeter (TFM) or pumpage determined from electrical power data and a power conversion coefficient (PCC) (Hurr and Litke, 1989). Opinions by representatives of the State of Kansas, presented before the Special Master hearing a court case [State of Kansas v. State of Colorado, No. 105 Original (1996)] concerning post-Compact well pumping, stated that the PCC approach does not provide the same level of accuracy and reliability as a TFM when used to determine pumpage. In 1997, the U.S. Geological Survey (USGS), in cooperation with the CDWR, began a 2-year study to compare ground-water pumpage estimates made using the TFM and the PCC approaches. The study area was along the Arkansas River between Pueblo, Colorado, and the Colorado-Kansas State line (fig. 1). The two approaches for estimating ground-water discharge and pumpage were compared for more than 100 wells completed in the alluvial aquifer of the Arkansas River Basin. The TFM approach uses an inline flowmeter to directly measure instantaneous discharge and the total volume of water pumped at a well. The PCC approach uses electrical power consumption records and a power conversion coefficient to estimate the pumpage at ground-water wells. This executive summary describes the results of the comparison of the two approaches. Specifically, (1) the differences in instantaneous discharge measured with three portable flowmeters and measured with an inline TFM are evaluated, and the statistical differences in paired instantaneous discharge between the two approaches are determined; (2) short- and long-term variations in the PCC’s are presented; (3) differences in pumpage between the two approaches are evaluated, and the statistical differences in pumpage between the two approaches are determined; (4) potential sources of discrepancy between pumpage estimates are discussed; and (5) differences in total network pumpage using the two approaches are presented. During the irrigation seasons of 1997 and 1998, instantaneous discharge and electrical power demand were measured at randomly selected wells to determine PCC’s. At more than 100 wells, the PCC’s determined during the 1998 season were applied to total electrical power consumption data that was recorded between the initial and final readings at each network well site in 1998 to estimate total ground-water pumpage. At each site, an inline TFM was installed in a full-flowing, acceptable test section of pipe on the discharge side of the pump where the measurement of discharge was made. Measurements of instantaneous ground-water discharge also were made using three different types of portable flowmeters. The average velocity multiplied by the cross-sectional area of the discharge pipe was used to compute the discharge in gallons per minute. Whenever possible, discharge measurements were made at each network site using all three types of portable flowmeters.

Colorado↗
USGS1998

Trace elements in streambed sediment and fish liver at selected sites in the Upper Colorado River Basin, Colorado 1995-96

Trace elements were analyzed in streambed-sediment samples collected from 16 sites and in fish-liver samples collected from 14 sites in the Upper Colorado River Basin in Colorado as part of the National Water-Quality Assessment program. Sites sampled represented agricultural, mining, mixed, and urban/recreation land uses and background conditions. The results for 15 trace elements in streambed-sediment and in fish-liver samples are presented in this report. Fourteen of the selected trace elements were detected in streambed-sediment samples collected at all sites. Twelve of the selected trace elements were detected in fish liver at more than 50 percent of the sites. Cadmium, copper, selenium, and zinc were selected for a more detailed analysis. Cadmium, copper, and zinc concentrations in streambed sediment were highest at mining land-use sites in the Southern Rocky Mountains physiographic province. Selenium concentrations in streambed sediment were highest at an agricultural land-use site in the Colorado Plateau physiographic province. The concentration of trace elements in streambed sediment generally increased as particle size decreased. Concentrations of trace elements in fish liver generally did not follow the same relation to land use as concentrations in streambed sediment; however, cadmium concentrations in fish liver were highest at a mining land-use site in the Southern Rocky Mountains physiographic province, and selenium concentrations in fish liver were highest at an agricultural land-use site in the Colorado Plateau physiographic province. Copper and zinc concentrations in fish liver were highest at mixed land-use sites. Comparison of streambed-sediment and fish-liver concentrations to two other similar NAWQA studies in the Rocky Mountain region generally indicated similar patterns in relation to land use for streambed sediment, but not for fish liver. Cadmium, copper, and zinc concentrations in streambed sediment were highest at sites affected by mining in all three study units. Selenium concentrations in streambed sediment did not indicate relations among the three study units when compared to land use. Cadmium in fish liver was highest at sites affected by mining in all three study units. Copper, selenium, and zinc in fish liver did not indicate relations among the three study units when compared to land use.

Colorado↗
USGS2025

Hydrogeology, water budget, and simulated groundwater availability in the Salt Fork Arkansas River and Chikaskia River alluvial aquifers, northern Oklahoma, 1980–2020

The 1973 Oklahoma Groundwater Law (Oklahoma Statute §82–1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s aquifers to determine the maximum annual yield for each groundwater basin. The U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, conducted an updated hydrologic investigation of the Salt Fork Arkansas River and Chikaskia River alluvial aquifers in northern Oklahoma for the study period spanning 1980–2020 and evaluated the simulated effects of potential groundwater withdrawals on groundwater flow and availability in the Salt Fork Arkansas River alluvial aquifer. A hydrogeologic framework and conceptual model were developed to guide the development of a numerical model. Three groundwater-availability scenarios were evaluated by using the calibrated numerical model, which was focused on the Salt Fork Arkansas River alluvial aquifer. These scenarios were used to (1) estimate equal-proportionate-share groundwater withdrawal rates, (2) quantify the potential effects of projected well withdrawals on groundwater storage over a 50-year period, and (3) simulate the potential effects of a hypothetical 10-year drought. The 20-, 40-, and 50-year equal-proportionate-share groundwater withdrawal rates for the Salt Fork Arkansas River alluvial aquifer under normal recharge conditions were about 0.63, 0.58, and 0.57 acre-foot per acre per year, respectively. Projected 50-year groundwater withdrawal scenarios were used to simulate the effects of modified well withdrawal rates. Because well withdrawals were less than 2 percent of the calibrated numerical-model water budget, changes to the well groundwater withdrawal rates had little effect on simulated Salt Fork Arkansas River base flows and groundwater storage in the Salt Fork Arkansas River alluvial aquifer. A hypothetical 10-year drought scenario was used to simulate the potential effects of a prolonged period of reduced recharge on groundwater storage. Groundwater storage at the end of the hypothetical drought period was 14.5 percent less than the groundwater storage of the calibrated numerical model without the simulated drought.

Oklahoma↗
USGS1998

Ground-water flow in the surficial aquifer system and potential movement of contaminants from selected waste-disposal sites at Naval Station Mayport, Florida

Ground-water flow through the surficial aquifer system at Naval Station Mayport near Jacksonville, Florida, was simulated with a two-layer finite-difference model as part of an investigation conducted by the U.S. Geological Survey. The model was calibrated to 229 water-level measurements from 181 wells during three synoptic surveys (July 17, 1995; July 31, 1996; and October 24, 1996). A quantifiable understanding of ground-water flow through the surficial aquifer was needed to evaluate remedial-action alternatives under consideration by the Naval Station Mayport to control the possible movement of contaminants from sites on the station. Multi-well aquifer tests, single-well tests, and slug tests were conducted to estimate the hydraulic properties of the surficial aquifer system, which was divided into three geohydrologic units�an S-zone and an I-zone separated by a marsh-muck confining unit. The recharge rate was estimated to range from 4 to 15 inches per year (95 percent confidence limits), based on a chloride-ratio method. Most of the simulations following model calibration were based on a recharge rate of 8 inches per year to unirrigated pervious areas. The advective displacement of saline pore water during the last 200 years was simulated using a particle-tracking routine, MODPATH, applied to calibrated steady-state and transient models of the Mayport peninsula. The surficial aquifer system at Naval Station Mayport has been modified greatly by natural and anthropogenic forces so that the freshwater flow system is expanding and saltwater is being flushed from the system. A new MODFLOW package (VAR1) was written to simulate the temporal variation of hydraulic properties caused by construction activities at Naval Station Mayport. The transiently simulated saltwater distribution after 200 years of displacement described the chloride distribution in the I-zone (determined from measurements made during 1993 and 1996) better than the steady-state simulation. The advective movement of contaminants from selected sites within the solid waste management units to discharge points was simulated using MODPATH. Most of the particles were discharged to the nearest surface-water feature after traveling less than 1,000 feet in the ground-water system. Most areas within 1,000 feet of a surface-water feature or storm sewer had traveltimes of less than 50 years, based on an effective porosity of 40 percent. Contributing areas, traveltimes, and pathlines were identified for 224 wells at Naval Station Mayport under steady-state and transient conditions by back-tracking a particle from the midpoint of the wetted screen of each well. Traveltimes to contributing areas that ranged between 15 and 50 years, estimated by the steady-state model, differed most from the transient traveltime estimates. Estimates of traveltimes and pathlines based on steady-state model results typically were 10 to 20 years more and about twice as long as corresponding estimates from the transient model. The models differed because the steady-state model simulated 1996 conditions when Naval Station Mayport had more impervious surfaces than at any earlier time. The expansion of the impervious surfaces increased the average distance between contributing areas and observation wells.

Florida↗
USGS2000

Stormflow chemistry in the Santa Ana River below Prado Dam and at the diversion downstream from Imperial Highway, southern California, 1995-98

The Santa Ana River drains about 2,670 square miles of the densely populated coastal area of southern California, near Los Angeles. Almost all the flow in the river, more than 200,000 acre-feet annually, is diverted into ponds where it infiltrates and recharges underlying aquifers. About 2 million people are dependent on these aquifers for water supply. Stormflow in the Santa Ana River is considered a source of "high-quality" water suitable for use as a source of ground-water recharge. To test this assumption, stormflow samples were collected at two locations--below Prado Dam and at the diversion point downstream from Imperial Highway--for 12 winter storms between 1995 and 1998. Nitrate concentrations decreased during stormflow from a median concentration of 7.8 milligrams per liter in base flow to concentrations less than 1 milligram per liter in some large storms. Concentrations of chemically reduced forms of nitrogen (nitrite, ammonia, and organic nitrogen) increased during stormflow and are the predominant forms of nitrogen in large stormflows. Dissolved organic carbon (DOC) concentrations increased from a median concentration of 4.6 milligrams per liter in base flow to more than 20 milligrams per liter in some stormflows. Concentrations of DOC were especially high during the first storm of the rainy season, and large increases in DOC concentrations were measured even as a result of small early season storms that did not cause large increases in streamflow. DOC present during early season stormflow had less ultraviolet absorbance at 254 nanometers (UV 254 ) per unit of carbon than did DOC from late season stormflows. DOC in water held in storage behind Prado Dam had the highest UV 254 absorbance per unit of carbon. Maximum pesticide concentrations in stormflow did not exceed U.S. Environmental Protection Agency Maximum Contaminant Levels. Most pesticide concentrations were less than 1 microgram per liter and less than the detection limits obtained using standard drinking water analyses. Increases in concentrations of pesticides such as diazinon, malathion, and chlorpyrifos in stormflow result from runoff from urban areas downstream from Prado Dam. In general, large late season stormflows have the most pesticide detections of all stormflows sampled. Concentrations of methyl tert-butyl ether (MTBE), a gasoline additive, during base flow were as high as 0.9 microgram per liter and concentrations decreased during stormflow. Like pesticides, the concentrations did not exceed the U.S. Environmental Protection Agency Maximum Contaminant Levels for MTBE.

California↗