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Annotated bibliography of scientific research relevant to oil and gas reclamation best management practices in the western United States, published from 1969 through 2020

Integrating recent scientific knowledge into management decisions supports effective natural resource management and can lead to better resource outcomes. However, finding and accessing scientific knowledge can be time consuming and costly. To assist in this process, the U.S. Geological Survey has created a series of annotated bibliographies on topics of management concern for lands in the western United States (U.S.). Oil and gas development on public lands is a long-standing and substantial component of local and regional economies and has expanded in recent decades, particularly on public lands in the western U.S. This development is associated with extensive networks of pipelines, roads, and processing facilities, across which reclamation is Federally mandated following initial well pad development (“interim” reclamation) and once resource extraction is complete (“final” reclamation). Reclamation is critical for recovering ecological services to energy-affected lands, including vegetation productivity, wildlife habitat, water and air quality, and soil stability (for example, resistance to wind and water erosion). However, reclamation of oil and gas affected lands in the western U.S. has proved challenging due to an array of regulatory and environmental factors, such as minimally developed soils, short growing seasons, herbivory, high winds, invasive species, rugged terrain, and in particular, arid climates associated with low total precipitation, high evapotranspiration rates, and highly variable precipitation patterns. We compiled and summarized journal articles, government reports, technical reports, proceedings, and theses and dissertations relevant to oil and gas reclamation. We constrained our search to products published on or before December 31, 2020 but did not limit our search by a starting date; the earliest product resulting from this effort was published in March 1969. Second, we manually scanned the last 15 years (2005-2020) of tables of contents in journals, bibliographies, and proceedings of which we were aware would contain articles highly relevant to this bibliography. We carried out the search for these products through multiple means: (1) performing a structured search of two reference databases, (2) examining articles published since 2005 in highly relevant scientific journals and conference proceedings, and (3) reviewing additional material suggested by authors of products identified in steps 1 and 2. Our search was intentionally broad in order to identify as much relevant work as possible, much of which is professionally applied and tested within the industry of oil and gas reclamation, but which remains unpublished in scientific journals. We refined the initial list of products by removing: (1) duplicates, (2) products not written in English, (3) products that were not relevant to the arid ecosystems of western North America, (4) products that were not released as research, data products, or review articles in journals or as formal scientific reports, and (5) products with data which were not relevant to reclamation of oil and gas-affected lands, or for which the study did not present new data, findings, or syntheses relevant to reclamation of oil and gas-affected lands. We summarized each product using a consistent structure (background, objectives, methods, location, findings, and implications) and assigned standardized management topics to each. Management topics are intended to aid online searching within the bibliography and are described in more detail in the Methods Section of this report; they include what type of disturbance the product addresses (well pads, mining, pipelines), what aspect of oil and gas reclamation they pertain to (practices, standards, monitoring), what type of data are present in the product (for instance soil or vegetation recovery data), and an indication if the product were from a source other than a published, peer-reviewed outlet (such as dissertations or unpublished professional reports – these are identified as grey literature). The review process for this annotated bibliography included an initial internal colleague review of each summary, requesting input on each summary from an author of the original product, and a formal peer-review. Our initial searches resulted in 3,197 total products, of which 290 met our criteria for inclusion. “Reclamation Practices” is by far the management topic most addressed, followed by “Reclamation Monitoring,” for example, products assessing what and how monitoring methods are used to track and measure reclamation outcome. This document may be accessed at https://doi.org/10.3133/ofr20231068 or from the U.S. Geological Survey Publication Warehouse ( https://pubs.usgs.gov/ ). The 1-page product summaries herein will also be used to create a bibliography at https://apps.usgs.gov/science-for-resource-managers that includes links to each original product, where available, and in which subject matter will be searchable by topic, location, and year. The studies compiled and summarized here may inform planning and management actions that seek to reclaim landscapes across the western U.S. which have been affected by oil and gas development.

Open-File Report

Assessment of Data for Use in the Development of Nutrient Criteria for Massachusetts Rivers and Streams

The U.S. Geological Survey synthesized, reviewed, and assessed Massachusetts water-quality data for use in the development of either numerical nutrient criteria for rivers and streams or a science-based framework for interpreting narrative criterial for nutrients. Water-quality data collected from 65 Massachusetts locations were selected to represent a wide range, but not a statistical selection, of drainage basins and high-, intermediate-, and low-nutrient ecoregions. Additional sites were selected at some locations to provide data to compare open- and closed-canopy effects on periphyton chlorophyll a concentrations. Nutrient and chlorophyll a concentrations are the primary focus of this study. Data for turbidity, color, dissolved oxygen, specific conductance, pH, and measures of aquatic-plant density also were examined. Water-quality data were analyzed by categories of year, ecoregion, drainage-basin size, Massachusetts nutrient ecoregion, presence of upstream wastewater dischargers, and canopy openness. Graphs and statistical analyses were used to evaluate data. The U.S. Environmental Protection Agency recommends the 25th-percentile value of a water-quality constituent as the numerical nutrient criterion when using all available data for the constituent. In this study of Massachusetts waters, the 25th percentiles of median values at all sampling stations were: total phosphorus, 0.019 milligram per liter (mg/L); total nitrogen, 0.44 (mg/L); and turbidity, 1.2 nephelometric turbidity units (NTU). When the data are sorted by the two USEPA nutrient ecoregions in Massachusetts (VIII and XIV), the new values are: for Ecoregion VIII, total phosphorus, 0.009 (mg/L); total nitrogen, 0.289 (mg/L); and turbidity, 1.7 NTU; for Ecoregion XIV, total phosphorus, 0.028 (mg/L); total nitrogen, 0.583 (mg/L); and turbidity, 3.1 NTU. For the three Massachusetts lake-based nutrient ecoregions, the values are: high-nutrient ecoregion, total phosphorus, 0.030 (mg/L); total nitrogen, 0.642 (mg/L); and turbidity, 1.5 NTU; intermediate-nutrient ecoregion, total phosphorus, 0.016 (mg/L); total nitrogen, 0.419 (mg/L); and turbidity, 1.1 NTU; and low-nutrient ecoregion, total phosphorus, 0.011 (mg/L); total nitrogen, 0.289 (mg/L); and turbidity, 0.7 NTU. In general, median nutrient concentrations were found to be higher in the three following categories of analysis than in their complementary groups: sites in USEPA nutrient Ecoregion XIV, sites downstream from major National Pollutant Discharge Elimination System-permitted wastewater dischargers, and sites in the Massachusetts high-nutrient ecoregion. The largest drainage-basin size class had higher median nitrogen (total and dissolved) concentrations than the smallest, but total median phosphorus concentrations were not significantly different. Median chlorophyll a concentrations did not vary significantly among the categories analyzed. The effects of open and closed canopies on median chlorophyll a concentrations were greater within groups defined by the categories used in this study than between the groups; open-canopy sites generally had higher median chlorophyll a concentrations than closed-canopy sites. More than 40 percent of the sampling stations were located downstream from major wastewater dischargers, and these dischargers were disproportionately located in USEPA Ecoregion XIV and the Massachusetts high-nutrient ecoregion and thus may constitute the same effect on water quality. A number of expected relations among parameters analyzed did not materialize. chlorophyll a did not correlate well with any other parameters. No strong relations among the categories and nutrient concentrations or canopy openness were apparent. The occurrence of antecedent flows exceeding mean annual discharges by 300 percent within 28 days of sample collection did not correlate with decreases in chlorophyll a concentrations that might have resulted from scouring associated with increasing velocities. No rel

Scientific Investigations Report

Ground-water quality in Geauga County, Ohio — Review of previous studies, status in 1999, and comparison of 1986 and 1999 data

Most residents in Geauga County, Ohio, rely on ground water as their primary source of drinking water. With population growing at a steady rate, the possibility that human activity will affect ground-water quality becomes considerable. This report presents the results of a study by the U.S. Geological Survey (USGS), in cooperation with the Geauga County Planning Commission and Board of County Commissioners, to provide a brief synopsis of work previously done within the county, to assess the present (1999) ground-water quality, and to determine any changes in groundwater quality between 1986 and 1999. Previous studies of ground-water quality in the county have consistently reported that manganese and iron concentrations in ground water in Geauga County often exceed the U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Level (SMCL). Road salt and, less commonly, oil-field brines and volatile organic compounds (VOCs) have been found in ground water at isolated locations. Nitrate has not been detected above the USEPA Maximum Contaminant Level (MCL) of 10 milligrams per liter as N; however, nitrate has been found in some locations at levels that may indicate the effects of fertilizer application or effluent from septic systems. Between June 7 and July 1, 1999, USGS personnel collected a total of 31 water-quality samples from wells completed in glacial deposits, the Pottsville Formation, the Cuyahoga Group, and the Berea Sandstone. All samples were analyzed for VOCs, sulfide, dissolved organic carbon, major ions, trace elements, alkalinity, total coliforms, and Escherichia coli bacteria. Fourteen of the samples also were analyzed for tritium. Water-quality data were used to determine (1) suitability of water for drinking, (2) age of ground water, (3) stratigraphic variation in water quality, (4) controls on water quality, and (5) temporal variation in water quality. Water from 16 of the 31 samples exceeded the Geauga County General Health District’s standard of 0 colonies of total coliform bacteria per 100 milliliters of water. Esthetically based SMCLs were exceeded in the indicated number of wells for pH (8), sulfate (1), dissolved solids (3), iron (19), and manganese (18). Hydrogen sulfide was detected at or above the detection limit of 0.01 milligram per liter in 17 of the 31 water samples. A range of water types was found among and within the four principal stratigraphic units. The waters can be categorized in three groups based on predominant anion type: bicarbonatetype waters, chloride-type waters, and sulfatetype waters. Chloride-to-bromide ratio analyses indicate that water from 8 of the 31 wells is in some way affected by human activity. Five other samples were in a chloride-to-bromide ratio range that could indicate possible effects of human activity. Ground-water-quality data from the current study were compared to data collected in 1986. Statistical analyses of data from the 16 wells that were sampled in both years did not indicate any significant changes that could be attributed to human activity.

Ohio

Compilation and evaluation of data used to identify groundwater sources under the direct influence of surface water in Pennsylvania

A study was conducted to compile and evaluate data used to identify groundwater sources that are under the direct influence of surface water (GUDI) in Pennsylvania. In the early 1990s, the Pennsylvania Department of Environmental Protection (PADEP) implemented the Surface Water Identification Protocol (SWIP) for the identification of GUDI sources. Since the establishment of the SWIP, PADEP has classified more than 500 individual sources across Pennsylvania as GUDI, but Pennsylvania’s complex geology and physiography provide a challenge for a uniform method of GUDI determination. Components used in this study to compile and evaluate data associated with GUDI determination include: (1) a preliminary review of file information for 43 public water-supply wells, (2) quality control and addition of data to PADEP’s database for public water-supply systems to prepare data for analysis, and (3) exploratory evaluation of existing GUDI sources in the database with respect to hydrogeologic and source-construction characteristics that are currently utilized in the assessment methodology. Case files for 43 wells from PADEP’s Northcentral and Southcentral regions were reviewed to: (1) provide a better understanding of how the SWIP was applied in practice, (2) verify and compile missing data, and (3) find additional attributes not previously available that might explain a well’s categorization as GUDI. Review of file information showed that the SWIP outlined in PADEP technical guidance was usually followed, but for some sources, the GUDI determination was more complex and could not be easily summarized. Data compiled for study analyses provided by PADEP include source data derived from public water-supply system case files, a source-information database for public water-supply systems, and Microscopic Particulate Analysis (MPA) results and associated water-quality data for public water-supply system groundwater sources. Data from the Pennsylvania Drinking Water Information System (PADWIS) , which is PADEP’s database for public water-supply systems, were also used for this study. The PADWIS database originally included data for 12,147 groundwater sources (11,812 groundwater sources not under the direct influence of surface water (non-GUDI) wells and 335 GUDI wells). A subset (4,018 wells consisting of 3,842 non-GUDI wells and 175 GUDI wells) of the PADWIS database was created for an analysis and includes only community wells evaluated in accordance with the SWIP. MPA results for 631 community and noncommunity wells were compiled, along with associated water-quality data (alkalinity, chloride, Escherichia coli , fecal coliform, nitrate, pH, sodium, specific conductance, sulfate, total coliform, total dissolved solids, total residue, and turbidity) populated from the PADEP Bureau of Laboratories Sample Information System. Data compiled from sources other than PADEP include spatial data, both naturogenic (for example, average precipitation or distance to closest hydrologic feature) and anthropogenic (for example, percentage of developed or agricultural land cover within a specific vicinity of a public water-supply system well) data representing spatially derived variables. Comparison among wells in the PADWIS dataset subset using the nonparametric Kruskal-Wallis test showed that GUDI wells had significantly older median construction years, shallower depths, and static water levels closer to the land surface than non-GUDI wells and that carbonate aquifers had the highest percentages of wells designated as GUDI (12 percent; 57 wells). Further comparison of wells in the PADWIS database subset using the Spearman’s rho monotonic correlation test illustrated that public water-supply wells designated as GUDI largely occur in unconfined aquifers and have high average yield and shallow static water levels. Assessment of the MPA database subset using the Kruskal-Wallis test showed wells with MPA total risk-factor scores that exceeded zero had older median construction years and shallower casing depths than wells with MPA total risk-factor scores of zero and that carbonate aquifers had the highest percentages of wells with MPA total risk-factor scores exceeding zero (30 percent; 63 wells). Spearman’s rho correlations showed that wells completed in aquifers with depths to major water-bearing zones closer to the land-surface had higher total risk-factor scores resulting from MPA samples. Based on the results of the analyses described in this report, broad conclusions can be drawn regarding site-specific well characteristics as well as anthropogenic and naturogenic factors that could be responsible for a well being designated as GUDI, but the accuracy of these results is dependent on the quality of the data being analyzed. Ultimately, study results serve as an added resource for initial desktop screening of wells to determine if additional site-specific investigation is warranted and underscore the need for field evaluation.

Pennsylvania

Using biological responses to monitor freshwater post-spill conditions over 3 years in Blacktail Creek, North Dakota, USA

A pipeline carrying unconventional oil and gas (OG) wastewater spilled approximately 11 million liters of wastewater into Blacktail Creek, North Dakota, USA. Flow of the mix of stream water and wastewater down the channel resulted in storage of contaminants in the hyporheic zone and along the banks, providing a long-term source of wastewater constituents to the stream. A multi-level investigation was used to assess the potential effects of oil and brine spills on aquatic life. In this study, we used a combination of experiments using a native fish species, Fathead Minnow ( Pimephales promelas ), field sampling of the microbial community structure, and measures of estrogenicity. The fish investigation included in situ experiments and experiments with collected site water. Estrogenicity was measured in collected site water samples, and microbial community analyses were conducted on collected sediments. During the initial post-spill investigation, February 2015, performing in situ fish bioassays was impossible because of ice conditions. However, microbial community (e.g., the presence of members of the Halomonadaceae, a family that is indicative of elevated salinity) and estrogenicity differences were compared to reference sites and point to early biological effects of the spill. We noted water column effects on in situ fish survival 6 months post-spill during June 2015. At that time, total dissolved ammonium (sum of ammonium and ammonia, TAN) was 4.41 mg NH 4 /L with an associated NH 3 of 1.09 mg/L, a concentration greater than the water quality criteria established to protect aquatic life. Biological measurements in the sediment defined early and long-lasting effects of the spill on aquatic resources. The microbial community structure was affected during all sampling events. Therefore, sediment may act as a sink for constituents spilled and as such provide an indication of continued and cumulative effects post-spill. However, lack of later water column effects may reflect pulse hyporheic flow of ammonia from shallow ground water. Combining fish toxicological, microbial community structure and estrogenicity information provides a complete ecological investigation that defines potential influences of contaminants at organismal, population, and community levels. In general, in situ bioassays have implications for the individual survival and changes at the population level, microbial community structure defines potential changes at the community level, and estrogenicity measurements define changes at the individual and molecular level. By understanding effects at these various levels of biological organization, natural resource managers can interpret how a course of action, especially for remediation/restoration, might affect a larger group of organisms in the system. The current work also reviews potential effects of additional constituents defined during chemistry investigations on aquatic resources.

North Dakota

Water resources of Carbon County, Wyoming

Carbon County is located in the south-central part of Wyoming and is the third largest county in the State. A study to describe the physical and chemical characteristics of surface-water and ground-water resources in Carbon County was conducted by the U.S. Geological Survey in cooperation with the Wyoming State Engineer's Office. Evaluations of streamflow and stream-water quality were limited to analyses of historical data and descriptions of previous investigations. Surface-water data were not collected as part of the study. Forty-five ground-water-quality samples were collected as part of the study and the results from an additional 618 historical ground-water-quality samples were reviewed. Available hydrogeologic characteristics for various aquifers in hydrogeologic units throughout the county also are described. Flow characteristics of streams in Carbon County vary substantially depending on regional and local basin char-acteristics and anthropogenic factors. Precipitation in the county is variable with high mountainous areas receiving several times the annual precipitation of basin lowland areas. For this reason, streams with headwaters in mountainous areas generally are perennial, whereas most streams in the county with headwaters in basin lowland areas are ephemeral, flowing only as a result of regional or local rainfall or snowmelt runoff. Flow characteristics of most perennial streams are altered substantially by diversions and regulation. Water-quality characteristics of selected streams in and near Carbon County during water years 1966 through 1986 varied. Concentrations of dissolved constituents and suspended sediment were smallest at sites on streams with headwaters in mountainous areas because of resistant geologic units, large diluting streamflows, and increased vegetative cover compared to sites on streams with headwaters in basin lowlands. Both water-table and artesian conditions occur in aquifers within the county. Shallow ground water is available throughout the county, although much of it is only marginally suitable or is unsuitable for domestic and irrigation uses mainly because of high total dissolved solids (TDS) concentrations. Suitable ground water for livestock use is available in most areas of the county. Ground-water quality tends to deteriorate with increasing distance from recharge areas and with increasing depth below land surface. Ground water from depths greater than a few thousand feet tends to have TDS concentrations that make it moderately saline to briny. In some areas, even shallow ground water is moderately saline. Specific constituents in parts of some aquifers in the county occur in relatively high concentrations when compared to U.S. Environmental Protection Agency drinking-water standards; for example, relatively high concentrations of sulfate, chloride, fluoride, boron, iron, manganese, and radon were found in several aquifers. The estimated mean daily water use in Carbon County in 2000 was about 320 million gallons per day. Water used for irrigation accounted for about 98 percent of this total. About 98 percent of the total water used was supplied by surface water and about 2 percent by ground water. Excluding irrigation, ground water comprised about 78 percent of total water use in Carbon County. Although ground water is used to a much lesser extent than surface water, in many areas of the county it is the only available water source.

Scientific Investigations Report

Coastal wetlands of the northern Gulf of California: Inventory and conservation status

1. Above 28°N, the coastline of the northern Gulf of California is indented at frequent intervals by negative or inverse estuaries that are saltier at their backs than at their mouths due to the lack of freshwater inflow. These ‘esteros’ total over 215 000 ha in area and encompass mangrove marshes below 29°N and saltgrass ( Distichlis palmeri ) marshes north of 29°N. An additional 6000 ha of freshwater and brackish wetlands are found in the Colorado River delta where fresh water enters the intertidal zone. 2. The mangrove marshes in the Gulf of California have been afforded some degree of protected status in Mexico, but the northern saltgrass esteros do not have priority conservation status and are increasingly becoming development targets for resorts, vacation homes and aquaculture sites. 3. We conducted an inventory of the marshes using aerial photography and satellite images, and evaluated the extent and type of development on each marsh. We reviewed the available literature on the marshes to document their vegetation types and ecological functions in the adjacent marine and terrestrial ecosystems. 4. Over 95% of the mangrove marshes have been developed for shrimp farming. However, the farms are built adjacent to, rather than in, the marshes, and the mangrove stands are still mostly intact. 5. The majority of saltgrass marshes above the mangrove line are still relatively unspoiled. However, resort and vacation home development is taking place on land surrounding them. 6. We recommend a system of protected reserves incorporating the pristine wetlands, along with water quality management and buffer zones for the more developed esteros. The saltgrass marshes should be considered for conservation protection, similar to the protection given to the southern mangrove marshes whose value has already been recognized.

Gulf of California

Hydrological, morphometrical, and biological characteristics of the connecting rivers of the International Great Lakes: a review

The connecting channels of the Great Lakes are large rivers (1, 200-9, 900 m3 • s-1) with limited tributary drainage systems and relatively stable hydrology (about 2:1 ration of maximum to minimum flow). The rivers, from headwaters to outlet, are the St. Marys, St. Clair, Detroit, Niagara, and St. Lawrence. They share several characteristics with certain other large rivers: the fish stocks that historically congregated for spawning or feeding have been overfished, extensive channel modification have been made, and they have been used as a repository for domestic and industrial wastes and for hydroelectric energy generation. Levels of phosphorus, chlorophyll a, and particulate organic matter increase 3- to 5-fold from the St. Marys River to the St. Lawrence River. Biological communities dependent on nutrients in the water column, such as phytoplankton, periphyton, and zooplankton similarly increase progressively downstream through the system. The standing crop of emergent macrophytes is similar in all of the rivers, reflecting the relatively large nutrient pools in the sediments and atmosphere. Consequently, emergent macrophytes are an important source of organic matter (67% of total primary production) in the nutrient poor waters of the St. Marys River, whereas phytoplankton production dominates (76%) in the enriched St. Lawrence River. Submersed and emergent macrophytes and the associated periphyton are major producers of organic matter in the connecting channels. Another major source of organic matter (measured as ash free dry weight, AFDW) in the Detroit River is sewage, introduced at a rate of 26, 000 t per year. The production of benthos ranges from a low 5.4 g AFDW•m-2 in the Detroit River to a high of 15.5 g AFDW•m-2 in the St. Marys River. The rivers lack the organic transport from riparian sources upstream but receive large amounts of high quality phytoplankton and zooplankton from the Great Lakes.

Canadian Special Publication of Fisheries and Aqua

Water resources of Sweetwater County, Wyoming

Sweetwater County is located in the southwestern part of Wyoming and is the largest county in the State. A study to quantify the availability and describe the chemical quality of surface-water and ground-water resources in Sweetwater County was conducted by the U.S. Geological Survey in cooperation with the Wyoming State Engineer’s Office. Most of the county has an arid climate. For this reason a large amount of the flow in perennial streams within the county is derived from outside the county. Likewise, much of the ground-water recharge to aquifers within the county is from flows into the county, and occurs slowly. Surface-water data were not collected as part of the study. Evaluations of streamflow and stream-water quality were limited to analyses of historical data and descriptions of previous investigations. Forty-six new ground-water-quality samples were collected as part of the study and the results from an additional 782 historical ground-water-quality samples were reviewed. Available hydrogeologic characteristics for various aquifers throughout the county also are described. Flow characteristics of streams in Sweetwater County vary substantially depending on regional and local basin characteristics and anthropogenic factors. Because precipitation amounts in the county are small, most streams in the county are ephemeral, flowing only as a result of regional or local rainfall or snowmelt runoff. Flows in perennial streams in the county generally are a result of snowmelt runoff in the mountainous headwater areas to the north, west, and south of the county. Flow characteristics of most perennial streams are altered substantially by diversions and regulation. Water-quality characteristics of selected streams in and near Sweetwater County during water years 1974 through 1983 were variable. Concentrations of dissolved constituents, suspended sediment, and bacteria generally were smallest at sites on the Green River because of resistant geologic units, increased vegetative cover, large diluting streamflows, and large reservoirs. Concentrations of dissolved constituents, suspended sediment, and bacteria generally were largest at sites in the Big Sandy River and Bitter Creek Basins. Some nutrient concentrations and bacteria counts exceeded various State and Federal water-quality criteria. Historical and recent anthropogenic activities contributed to natural sources of many dissolved constituents and suspended sediment. Both water-table and artesian conditions occur in aquifers within the county. Shallow ground water is available throughout the county, although much of it is only marginally suitable or is unsuitable for domestic and irrigation uses mainly because of high total dissolved solids (TDS) concentrations. Suitable ground water for livestock use can be found in most areas of the county. Ground-water quality tends to deteriorate with increasing distance from recharge areas and with increasing depth below land surface. Ground water from depths of greater than a few thousand feet tends to have TDS concentrations that make it moderately saline to briny. In some areas even shallow ground water has moderately saline TDS concentrations. Specific constituents in parts of some aquifers in the county occur in relatively high concentrations when compared to U.S. Environmental Protection Agency drinking-water standards. Relatively high concentrations of sulfate, fluoride, boron, iron, and manganese were found in several aquifers. Many ground-water samples from the Battle Spring aquifer in the Great Divide Structural Basin had high radionuclide concentrations. The estimated mean daily water use in Sweetwater County in 2000 was 170.73 million gallons per day. Irrigation was the largest single use of water in the county with an estimated mean use of more than 92 million gallons per day. Surface water irrigation accounted for nearly 90 percent of the total irrigation water used in 2000. Although ground water is used to a much lesser extent than surface water, in many areas of the county it is the only source of water available.

Wyoming

Quality-assurance data for routine water quality analyses by the U. S. Geological Survey laboratory in Troy, New York; July 1993 through June 1995

A laboratory for analysis of low-ionic strength water has been developed at the U.S. Geological Survey (USGS) office in Troy, N.Y., to analyze samples collected by USGS projects in the Northeast. The laboratory's quality-assurance program is based on internal and interlaboratory quality-assurance samples and quality-control procedures developed to ensure proper sample collection, processing, and analysis. The quality-assurance/quality-control data are stored in the laboratory's SAS data-management system, which provides efficient review, compilation, and plotting of quality-assurance/quality-control data. This report presents and discusses samples analyzed from July 1993 through June 1995. Quality-control results for 18 analytical procedures were evaluated for bias and precision. Control charts show that data from seven of the analytical procedures were biased throughout the analysis period for either high-concentration or low-concentration samples but were within control limits; these procedures were: acid-neutralizing capacity, dissolved inorganic carbon, dissolved organic carbon (soil expulsions), chloride, magnesium, nitrate (colorimetric method), and pH. Three of the analytical procedures were occasionally biased but were within control limits; they were: calcium (high for high-concentration samples for May 1995), dissolved organic carbon (high for highconcentration samples from January through September 1994), and fluoride (high in samples for April and June 1994). No quality-control sample has been developed for the organic monomeric aluminum procedure. Results from the filter-blank and analytical-blank analyses indicate that all analytical procedures in which blanks were run were within control limits, although values for a few blanks were outside the control limits. Blanks were not analyzed for acid-neutralizing capacity, dissolved inorganic carbon, fluoride, nitrate (colorimetric method), or pH. Sampling and analysis precision are evaluated herein in terms of the coefficient of variation obtained for triplicate samples in 14 of the 18 procedures. Data-quality objectives were met by more than 90 percent of the samples analyzed in all procedures except total monomeric aluminum (85 percent of samples met objectives), total aluminum (70 percent of samples met objectives), and dissolved organic carbon (85 percent of samples met objectives). Triplicate samples were not analyzed for ammonium, fluoride, dissolved inorganic carbon, or nitrate (colorimetric method). Results of the USGS interlaboratory Standard Reference Sample Program indicated high data quality with a median result of 3.6 of a possible 4.0. Environment Canada's LRTAP interlaboratory study results indicated that more than 85 percent of the samples met data-quality objectives in 6 of the 12 analyses; exceptions were calcium, dissolved organic carbon, chloride, pH, potassium, and sodium. Data-quality objectives were not met for calcium samples in one LRTAP study, but 94 percent of samples analyzed were within control limits for the remaining studies. Data-quality objectives were not met by 35 percent of samples analyzed for dissolved organic carbon, but 94 percent of sample values were within 20 percent of the most probable value. Data-quality objectives were not met for 30 percent of samples analyzed for chloride, but 90 percent of sample values were within 20 percent of the most probable value. Measurements of samples with a pH above 6.0 were biased high in 54 percent of the samples, although 85 percent of the samples met data-quality objectives for pH measurements below 6.0. Data-quality objectives for potassium and sodium were not met in one study (only 33 percent of the samples analyzed met the objectives), although 85 percent of the sample values were within control limits for the other studies. Measured sodium values were above the upper control limit in all studies. Results from blind reference-sample analyses indicated that data

Open-File Report

Water-quality assessment of the Trinity River Basin, Texas - Review and analysis of available pesticide information, 1968-91

In 1991 the Trinity River Basin study unit was among the first 20 study units in which work began under full-scale program implementation of the National Water-Quality Assessment Program. A retrospective assessment was undertaken to review and analyze existing pesticide data and related environmental factors. Population and land-use data indicate human modifications to the landscape and hydrologic system of the study area during the period 1968–91. A variety of crops treated with pesticides were identified, with wheat and cotton accounting for the largest number of acres treated annually (541,250 and 519,870 acres, respectively). Agricultural-use estimates for the later period covered by this report (1988–90) indicate that 105 different pesticides were used and that 24 pesticides accounted for 75 percent of average agricultural use in the study area. Sorghum was treated by the largest number of the 24 mostused pesticides, and cotton was treated by the second largest number of those pesticides. Dimethoate and methyl parathion were the most heavily used of the organophosphate class pesticides. The herbicide 2,4–D was the most heavily used chlorophenoxy pesticide. Carbamate pesticides are used extensively in the study area, with carbaryl, carbofuran, methomyl, and thiodicarb accounting for the majority of the use of this class of pesticide. Miscellaneous pesticides included alachlor, arsenic acid, picloram, and glyphosate, among others. The data indicate that herbicide use generally is proportionally higher in the study area than in the Nation, and that insecticide use in the study area generally is proportionally lower than in the Nation. Eight different agencies collected the waterquality data used in this report. Samples were collected by all agencies at a combined total of 155 surface-water sites and 121 ground-water sites. The sampled media included water, bed sediment, and tissues of fish and other aquatic wildlife. Some 273 samples for analysis of the herbicide 2,4–D were collected as part of the city of Arlington’s data-collection program. The herbicide was detected in 74 percent of the samples, but none exceeded the Maximum Contamination Level for drinking water. Dallas Water Utilities collected pesticide samples during a storm in February 1977. Samples were collected at 17 sites with detections of some pesticides in over 50 percent of the samples. Diazinon was detected in 56 percent of samples and 2,4–D was found in 56 percent of samples. Texas Parks and Wildlife Department collected samples from fish tissue for analyses of organochlorine pesticides from 15 sites in the Dallas-Fort Worth area. Chlordane concentrations in some of the samples exceeded the Food and Drug Administration’s action level of 300 micrograms per kilogram. The Texas Water Commission collected ground-water samples in the study area during 1990 for the major types of pesticides and none were detected. No arsenic was detected in samples from 121 wells in or near the study area. Organochlorine and organophosphate samples were collected beginning in 1974 and ending in 1991. Concentrations of organochlorine pesticides in bed sediment decrease with increasing distance downstream from the Dallas-Fort Worth urban area. Pesticide samples collected by the U.S. Geological Survey indicated significant rank correlation between number of detects of chlordane and the percent of the contributing watershed classified as urban land use. Dieldrin in bed sediment samples, and lindane, diazinon, and malathion, in water samples, also were significantly correlated with urban land use. Chlordane and dieldrin were significantly correlated with distance downstream from the Dallas-Fort Worth urban area. Review of all available data showed that pesticides were detected to a substantial degree in various sample media over the time period covered by this report. The authors were able to locate little pesticide-sample data for ground water or for tributary streams because sampling efforts historically have been concentrated on the mainstem Trinity River.

Texas

Water-resources-related information for the Milwaukee Metropolitan Sewerage District planning area, Wisconsin, 1970-2002

The Milwaukee Metropolitan Sewerage District (MMSD) Corridor Study is a three-phase project designed to improve the understanding of water resources in the stream corridors of the MMSD planning area by initially compiling existing data and using the compiled information to develop 3-year baseline and long-term monitoring plans. This report is one of the products of Phase I of the Corridor Study. A literature review of surface-water-quality, surface water- quantity, and ecology studies conducted from 1970 through 2001 was completed and is summarized in this report. An inventory of Geographic Information System spatial coverages available for the MMSD planning area has been assembled. A database of water, sediment, and tissue (fish, shellfish, and others) chemistry, macroinvertebrates, fish, algae, habitat, geomorphic, and other physical and ecological data was compiled from data sets from MMSD, U.S. Geological Survey, Wisconsin Department of Natural Resources, and the U.S. Environmental Protection Agency. More than 2.7 million results are available in the MMSD Corridor Study database and the compilation of multiple datasets allows for retrieving data from a central database rather than from each of the source datasets. Data for 1970 through 2002 were collected for the 420-square-mile planning area by various agencies using different field data-collection and laboratory analysis methods. Chemical constituents and ecological components that are important to an urban setting and well represented in the database were selected for further investigation. Each constituent or component is described in this report with some or all of the following: a text summary, map of sampling locations, and in some cases median concentrations, statistical distributions of concentrations by subwatershed, table of summary statistics by subwatershed, and graphs of temporal and (or) seasonal trends. Physical data presented in the report include streamflow, stream stage, and precipitation data. Chemical indicators of water quality presented in the report include field measurements and miscellaneous constituents (pH, alkalinity, specific conductance, hardness, dissolved oxygen, biochemical oxygen demand, and chloride), sediment (total suspended solids and suspended sediment), nutrients (total nitrogen, nitrate, Kjeldahl nitrogen, total phosphorus, and dissolved phosphorus), trace elements (cadmium, mercury, copper, lead, arsenic, chromium, nickel, and zinc), pesticides (historically used pesticides and pesticides still in use), and polychlorinated biphenyls. Ecological indicators of water quality discussed in the report include community surveys of macroinvertebrates and fish, chlorophyll a concentrations, habitat assessments and channel-measurement data, and fecal coliform and E. coli bacterial counts. In addition to the compilation of the database, a major purpose of this investigation was to identify additional sampling that should be conducted under the baseline monitoring phase, which will be the second phase of the Corridor Study. Additional sampling may include: • Some subwatersheds, such as those in the headwaters. • Emerging contaminants such as pharmaceuticals and personal care products (PPCPs), human hormones, organic wastewater contaminants, and other constituents that result from human activity. • E. coli, which can serve as an indicator of health risk to swimmers and other recreational water users. • Pesticides in all media. • PCBs. • Trace elements in water, bed sediment, and tissues (fish, shellfish, and others). • Samples during winter months or during early snowmelt episodes to address constituents such as chloride and some nutrients that have seasonal variability and that may be affected by factors such as road deicing during the winter. • Samples for macroinvertebrate and fish-community data and habitat assessments. • Physical data such as stream-channel cross-section profiles, bridge-scour assessments, flood-plain maps, structures, and shoreline conditions.

Wisconsin

GIS Representation of Coal-Bearing Areas in Africa

The African continent contains approximately 5 percent of the world's proven recoverable reserves of coal (World Energy Council, 2007). Energy consumption in Africa is projected to grow at an annual rate of 2.3 percent from 2004 through 2030, while average consumption in first-world nations is expected to rise at 1.4 percent annually (Energy Information Administration, 2007). Coal reserves will undoubtedly continue to be part of Africa's energy portfolio as it grows in the future. A review of academic and industrial literature indicates that 27 nations in Africa contain coal-bearing rock. South Africa accounts for 96 percent of Africa's total proven recoverable coal reserves, ranking it sixth in the world. This report is a digital compilation of information on Africa's coal-bearing geology found in the literature and is intended to be used in small scale spatial investigations in a Geographic Information System (GIS) and as a visual aid for the discussion of Africa's coal resources. Many maps of African coal resources often include points for mine locations or regional scale polygons with generalized borders depicting basin edges. Point locations are detailed but provide no information regarding extent, and generalized polygons do not have sufficient detail. In this dataset, the polygons are representative of the actual coal-bearing lithology both in location and regional extent. Existing U.S. Geological Survey (USGS) digital geology datasets provide the majority of the base geologic polygons. Polygons for the coal-bearing localities were clipped from the base geology that represented the age and extent of the coal deposit as indicated in the literature. Where the 1:5,000,000-scale geology base layer's ages conflicted with those in the publications, polygons were generated directly from the regional African coal maps (1:500,000 scale, approximately) in the published material. In these cases, coal-bearing polygons were clipped to the literature's indicated coal extent, without regard to the underlying geology base or topographic constraints. Indication of the presence of African coal is based on multiple sources. However, the quality of the sources varies and there is often disagreement in the literature. This dataset includes the rank, age, and location of coal in Africa as well as the detailed source information responsible for each coal-bearing polygon. The dataset is not appropriate for use in resource assessments of any kind. Attributes necessary for tasks, such as number of coal seams, thickness of seams, and depth to coal are rarely provided in the literature and accordingly not represented in this data set. Small-scale investigations, representations and display uses are most appropriate for this product. This product is the first to show coal distribution as bounded by actual geologic contacts for the entire African continent. In addition to the spatial component of this dataset, complete references to source material are provided for each polygon, making this product a useful first step resource in African coal research. Greater detail regarding the creation of this dataset as well as the sources used is provided in the metadata file for the Africa_coal.shp file.

Open-File Report

A review of post-wildfire adaptations of surface-water-quality models: Synthesis, gaps, and opportunities

As wildfires increasingly affect water-supply watersheds, the demand for models to predict water-quality responses is increasing. This work reviews and synthesizes existing post-wildfire applications of water-quality models in the context of geographic and ecohydrological distribution, hydrologic and water-quality response process representation, model parameterization, model and input data scales, model calibration data availability, as well as calibration and performance evaluation approaches. Emphasis is placed on models that simulate water-quality output, rather than sediment and erosional response as the primary focus. Here, identified gaps and opportunities to advance the post-wildfire application of water-quality models include: 1. applying models in under-represented geographic and ecohydrologic regions, 2. simulating multiple streamflow generation mechanisms, including groundwater, with an emphasis on shifting dominant flow pathways as the landscape recovers following wildfire, 3. adding studies that include the simulation of metals, 4. incorporating more biogeochemical and in-stream processes to model applications, 5. applying finer spatial and temporal resolution of precipitation data input as well as finer spatial resolution hydrologic response units, 6. implementing fully distributed grid or element models or finer resolution response units to capture burn severity heterogeneity, 7. collecting enhanced water-quality data for model calibration and validation, 8. conducting model-intercomparison studies, and 9. developing model parameter value guidance in post-wildfire applications. These identified gaps and opportunities may assist users in deciding on key processes and approaches to consider in modeling post-wildfire water-quality conditions.

Science of the Total Environment

Accuracy assessment/validation methodology and results of 2010–11 land-cover/land-use data for Pools 13, 26, La Grange, and Open River South, Upper Mississippi River System

Introduction/Background The U.S. Geological Survey (USGS)-Upper Midwest Environmental Sciences Center (UMESC) was responsible for development of several land cover/land use (LCU) systemic datasets of the Upper Mississippi River System (UMRS). These efforts (1989 and 2000) were funded by the U.S. Army Corps of Engineers’ Upper Mississippi River Restoration Program (UMRR) Long Term Resource Monitoring (LTRM) element. Development of systemic datasets includes the acquisition, processing, and serving of high-resolution aerial photography and land cover/land use spatial datasets ( http://www.umesc.usgs.gov/data_library/land_cover_use/land_cover_use_data.html ). In 2008, the UMRR reached a collaborative agreement with the U.S. Fish and Wildlife Service-Region 3 to collect high-resolution digital imagery of the entire UMRS floodplain during 2010–11 for LTRM. The UMESC helped acquire, process, and serve this imagery, as well as produce and serve the 2010–11 LCU systemic dataset of the UMRS floodplain. Digital imagery for Pools 13, 26, La Grange, and Open River South was collected using an Applanix DSS 439 digital sensor system with a 40 millimeter lens and Color Infrared (CIR) filter. The imagery was collected at a resolution of 20 centimeters/pixel (8 inches/pixel) for Pool 13 and 40 centimeters/pixel (16 inches/pixel) for Pools 26, Open River South, and La Grange. All imagery was projected to Universal Transverse Mercator (UTM) Zone 15, North American Datum of 1983 (NAD 83). The General Wetland Vegetation Classification (GWVC) system used for mapping is hierarchical, and its 31 classes can be collapsed into broader categories using either a 15- or 7-class level. While the 1989 and 2000 LCU systemic datasets have not gone through a traditional thematic accuracy assessment (AA) in the past, nor have they undergone a validation analysis, the end products are of high quality. For each systemic dataset produced (1989, 2000, 2010–11), extensive field reconnaissance is performed before photointerpretation. The intent of this field reconnaissance is to learn, test, and verify image signatures as they relate to vegetation types. Questionable areas on the imagery are visited, and the plants or land features observed in the area are recorded for reference. This procedure verifies vegetation signatures on the imagery with those on the ground. In addition, once the photointerpretation is complete, the final LCU dataset undergoes extensive quality assurance/quality control to ensure the imagery is mapped correctly. Since the 2000 LCU systemic dataset was developed, there has been a growing interest in completing thematic AAs for the LTRM LCU spatial datasets. The objective of an AA is to measure the probability that a particular location has been assigned its correct vegetation class. An AA estimates thematic (map class) errors in the data, giving users information needed to determine data suitability for a particular application. At the same time, data producers are able to learn more about the nature of errors in the data. Thus, the two attributes of an AA are “producers’ accuracy,” which is the probability that an AA point has been mapped correctly (also referred to as an error of omission); and “users’ accuracy,” which is the probability that the map actually represents what was found on the ground (also referred to as error of commission). Producers’ and users’ accuracies can be obtained from the same set of data by using different analyses. Accuracy assessment is an extensive effort that requires seasonal field personnel and equipment, data entry, analyses, and post processing—tasks that are costly and time consuming. The geospatial team at the UMESC has suggested a validation process for understanding the accuracy of the spatial datasets, which will be tested on at least some areas of the UMRS. Validation is not a true verification of map-class type in the field; however, it can provide the user of the map with useful information that is similar to a field AA. Similar to an AA, validation involves generating random points based on the total area for each map class. However, instead of collecting field data, two or three individuals not involved with the photo-interpretative mapping separately review each of the points onscreen and record a best-fit vegetation type(s) for each site. Once the individual analyses are complete, results are joined together and a comparative analysis is performed. The objective of this initial analysis is to identify areas where the validation results were in agreement (matches) and areas where validation results were in disagreement (mismatches). The two or three individuals then perform an analysis, looking at each mismatched site, and agree upon a final validation class. (If two vegetation types at a specific site appear to be equally prevalent, the validation team is permitted to assign the site two best-fit vegetation types.) Following the validation team’s comparative analysis of vegetation assignments, the data are entered into a database and compared to the mappers’ vegetation assignments. Agreements and disagreements between the map and validation classes are identified, and a contingency table is produced. This document presents the AA processes/results for Pools 13 and La Grange, as well as the validation process/results for Pools 13 and 26 and Open River South.

Iowa, Illinois, Minnesota, Missouri, Wisconsin

Test and calibration of the Digital World-Wide Standardized Seismograph

During the past decade there has been steady progress in the modernization of the global seismograph network operated by the U.S. Geological Survey (USGS). The World-Wide Standardized Seismograph Network (WWSSN) has been augmented by new stations with advanced instrumentation, including the Seismic Research Observatories (SRO) and the modified High-Gain Long-Period (ASRO) stations. One goal in the modernization effort has been to improve signal resolution in the long-period band. A second goal has been to generate a global digital data base to support contemporary computer-based analysis and research. In 1976, a Panel on Seismograph Networks was established by the Committee on Seismology of the National Academy of Sciences to review progress in network seismology and recommend actions that would lead to an improved global data base for seismology. One recommendation in the Panel report (Engdahl, 1977) called for upgrading selected WWSSN stations by the installation of digital recorders. This was viewed as an economical way of expanding the digital network, which had proven itself to be a very promising new tool for earthquake and explosion research. Funds for the development and assembly of 15 digital recorders were provided to the USGS by the Defense Advanced Research Projects Agency and an ad Inoc panel of scientists was convened by the Committee on Seismology to advise the USGS on the selection of stations to be upgraded and on data recording requirements, A total of 19 digital World-Wide Standardized Seismograph (DWWSS) systems will be operational when all are installed. The additional systems were made available through purchase by the USGS and other organizations; for example, the University of Bergen purchased and installed a DWWSS-type recorder and agreed to furnish the USGS with the data. A list of operational and planned DWWSS network stations is given in Table 1.1. As one might expect, the digital recorder turned out to be somewhat more sophisticated than the original concept. It was decided to record three components of long-period data continuously, three components of intermediateperiod data in an event mode, and the vertical-component short-period data in and event mode (with the capability of adding short-period horizontal channels in the future). Special amplifiers were developed for use with the WWSS seismometers, and a 16-bit fixed-point analog-to-digital converter was chosen to provide increased resolution (as opposed to a 16-bit gain-ranged encoder). The microprocessor-based digital recording systems were developed and assembled at the USGS Albuquerque Seismological Laboratory (ASL) and ASL-based technicians began installation at WWSSN stations in 1980. The current and proposed locations of the DWWSSN stations, together with other stations in the Global Digital Seismograph Network (GDSN), are shown on the map in Figure 1.1. A system was operated at Albuquerque for about 18 months, serving as a test bed for evaluation studies. Although the network hardware has been available for some time, the installation of the DWWSSN has proceeded slowly. The National Science Foundation supported installation of six stations and the USGS is funding installation of most of the others; however, the network completion date is conjectural because of funding uncertainties. The DWWSSN stations are supported with supplies and technical assistance from ASL (subject to availability of funds). Data recorded on magnetic tapes are mailed to ASL where they are reviewed for quality, then merged with other GDSN station data on the network-day tapes. Hoffman (1980) provides a description of the network-day tape format. Zirbes and Buland (1981) have developed and published user software for reading and interpreting the day tapes. This report will serve several purposes. One is to provide nominal system transfer functions and calibration information that are needed in the analysis of DWWSSN data. A second purpose is to report on an evaluation of operating characteristics (calibration stability, noise levels, and linearity) that may limit the usefulness of the data and to determine if modifications may be needed to improve the data. It is not an exhaustive study in this respect. We continue to depend mostly on data user feedback to point out deficiencies and we solicit comments whenever anomalies are observed in the data.

Open-File Report

Identification and synthetic modeling of factors affecting American black duck populations

We reviewed the literature on factors potentially affecting the population status of American black ducks ( Anas rupribes ). Our review suggests that there is some support for the influence of 4 major, continental-scope factors in limiting or regulating black duck populations: 1) loss in the quantity or quality of breeding habitats; 2) loss in the quantity or quality of wintering habitats; 3) harvest, and 4) interactions (competition, hybridization) with mallards ( Anas platyrhychos ) during the breeding and/or wintering periods. These factors were used as the basis of an annual life cycle model in which reproduction rates and survival rates were modeled as functions of the above factors, with parameters of the model describing the strength of these relationships. Variation in the model parameter values allows for consideration of scientific uncertainty as to the degree each of these factors may be contributing to declines in black duck populations, and thus allows for the investigation of the possible effects of management (e.g., habitat improvement, harvest reductions) under different assumptions. We then used available, historical data on black duck populations (abundance, annual reproduction rates, and survival rates) and possible driving factors (trends in breeding and wintering habitats, harvest rates, and abundance of mallards) to estimate model parameters. Our estimated reproduction submodel included parameters describing negative density feedback of black ducks, positive influence of breeding habitat, and negative influence of mallard densities; our survival submodel included terms for positive influence of winter habitat on reproduction rates, and negative influences of black duck density (i.e., compensation to harvest mortality). Individual models within each group (reproduction, survival) involved various combinations of these factors, and each was given an information theoretic weight for use in subsequent prediction. The reproduction model with highest AIC weight (0.70) predicted black duck age ratios increasing as a function of decreasing mallard abundance and increasing acreage of breeding habitat; all models considered involved negative density dependence for black ducks. The survival model with highest AIC weight (0.51) predicted nonharvest survival increasing as a function of increasing acreage of wintering habitat and decreasing harvest rates (additive mortality); models involving compensatory mortality effects received ≈0.12 total weight, vs. 0.88 for additive models. We used the combined model, together with our historical data set, to perform a series of 1-year population forecasts, similar to those that might be performed under adaptive management. Initial model forecasts over-predicted observed breeding populations by ≈25%. Least-squares calibration reduced the bias to ≈0.5% under prediction. After calibration, model-averaged predictions over the 16 alternative models (4 reproduction × 4 survival, weighted by AIC model weights) explained 67% of the variation in annual breeding population abundance for black ducks, suggesting that it might have utility as a predictive tool in adaptive management. We investigated the effects of statistical uncertainty in parameter values on predicted population growth rates for the combined annual model, via sensitivity analyses. Parameter sensitivity varied in relation to the parameter values over the estimated confidence intervals, and in relation to harvest rates and mallard abundance. Forecasts of black duck abundance were extremely sensitive to variation in parameter values for the coefficients for breeding and wintering habitat effects. Model-averaged forecasts of black duck abundance were also sensitive to changes in harvest rate and mallard abundance, with rapid declines in black duck abundance predicted for a range of harvest rates and mallard abundance higher than current levels of either factor, but easily envisaged, particularly given current rates of growth for mallard populations. Because of concerns about sensitivity to habitat coefficients, and particularly in light of deficiencies in the historical data used to estimate these parameters, we developed a simplified model that excludes habitat effects. We also developed alternative models involving a calibration adjustment for reproduction rates, survival rates, or neither. Calibration of survival rates performed best (AIC weight 0.59, % BIAS = -0.280, R 2 =0.679), with reproduction calibration somewhat inferior (AIC weight 0.41, % BIAS = -0.267, R 2 =0.672); models without calibration received virtually no AIC weight and were discarded. We recommend that the simplified model set (4 biological models × 2 alternative calibration factors) be retained as the best working set of alternative models for research and management. Finally, we provide some preliminary guidance for the development of adaptive harvest management for black ducks, using our working set of models.

Book

Potential interaction of groundwater and surface water including autonomous underwater vehicle reconnaissance at Nolin River Lake, Kentucky, 2016

The U.S. Geological Survey collaborated with the U.S. Army Corps of Engineers, Louisville District, on a synoptic study of water quality at Nolin River Lake during August 2016. The purpose of the study was to develop a better understanding of the potential for interaction between groundwater and surface water at Nolin River Lake, Kentucky. Groundwater can have properties that are measurably different from those in adjacent surface water, and inflows and outflows can be an important component of water quality and quantity. An improved understanding of potential interaction of groundwater and surface water at Nolin River Lake may be used to refine lake-management strategies. This study (1) compiled and interpreted existing information to characterize the hydrogeological setting and implications for potential interaction of groundwater and surface water in the Nolin River Lake watershed; (2) collected transects of onsite water-quality parameters using an autonomous underwater vehicle (AUV) in areas with potential for interaction of groundwater and surface water, including five sites on Nolin River Lake and one site on the Nolin River; and (3) collected discrete water-quality and phytoplankton community data at the same six sites. A review of existing hydrogeologic information did not indicate the presence of karst features adjacent to or beneath Nolin River Lake that would facilitate groundwater interaction with the reservoir. Observations leading to this conclusion include (1) limestone that is adjacent to the shoreline and perhaps beneath the lake, is overlain with siliciclastic rocks and fine-grained sediment that inhibits infiltration and development of karst features that encourage rapid groundwater flow; (2) the geologic deposits surrounding the reservoir are described as having limited or no potential for development of karst features, some exceptions may exist in tributary valleys; (3) very few karst features were mapped within 1 mile of the reservoir or in the area currently occupied by the reservoir; and (4) faults that intersect the reservoir but may not possess hydraulic properties that cause the faults to be conduits for groundwater flow. Groundwater interaction with reservoir tributaries is likely more common in areas of the watershed upstream from Nolin River Lake where karst hydrogeology is prevalent. Results of water-quality surveys using an AUV from August 15 to 19, 2016, did not identify areas of anomalous values that might indicate groundwater inflows through preferential flow zones. Spatial distributions of water-quality parameters were generally uniform within each constant-depth layer. The constant-depth layers were selected to be above, within, and below the thermocline and ranged from the water surface to 25 feet. Surveys near the bottom of the reservoir that might have been more sensitive to groundwater inflows were not done because presurvey data were not available to indicate locations of obstacles that could ensnare the AUV. Water-quality data collected with the AUV did identify water-quality anomalies where stream tributaries were discharging to the reservoir. The discrete water-quality samples indicated uniformity among the five reservoir sites. The riverine site that is immediately upstream from Nolin River Lake, however, had some unique water-quality characteristics relative to sites on the reservoir. The highest concentrations of nitrate plus nitrite as nitrogen (0.145 milligrams per liter [mg/L]), total phosphorous (0.07 mg/L), chlorophyll a (36.1 micrograms per liter), and pheophytin a (10.2 micrograms per liter) were measured at the Nolin River Lake riverine site (site 2NRR20034). The concentrations of nutrients and chlorophyll a at the riverine site did exceed the 25th percentile of median concentrations measured by the U.S. Environmental Protection Agency (EPA) at other lakes and reservoirs in EPA level IV ecoregion 71a. Concentrations of most nutrients and chlorophyll a at the five reservoir sites also exceeded the 25th percentile of median concentrations in EPA level IV ecoregion 72h. The exception was the concentrations of total phosphorus as phosphorus at the reservoir sites that were at or below the 25th percentile of median concentrations measured by EPA (0.03 mg/L). Concentrations of orthophosphate as phosphorus were less than the method detection limit of 0.004 mg/L at all sites. The phytoplankton community in Nolin River Lake was almost exclusively (greater than 90 percent of total phytoplankton abundance) cyanobacteria, also known as blue-green algae. A species of Cylindrospermopsis dominated the cyanobacterial community at the five reservoir sites, while Chroococcus microscopicus was most abundant at the riverine site. Cyanobacterial cell densities ranged from 10,000 to 198,067,460 cells per liter in five areas in the reservoir and from 4,800 to 73,751,253 cells per liter at the riverine site. Multiple potential sources of water to Nolin River Lake include direct precipitation, overland flow, interflow, groundwater, and surface water. Understanding the exact contribution of each of these components to the water budget at Nolin River Lake may help the U.S. Army Corps of Engineers manage the water quality, water quantity, and biological communities in the reservoir. Additional hydrogeologic and water-quality data that builds on the results of this study may refine the inferences of this study; for example, deeper AUV surveys that target the largest fault zones might further the understanding of the potential for groundwater flow through those features. A complete understanding of the reservoir hydrology, however, may require the use of scientific methods intended for water bodies as large as Nolin River Lake, such as aerial infrared photography and imagery; water mass, chemical, and isotopic balance studies; geophysical measurements; and numerical simulations.

Kentucky