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At least 91 records · Page 5Linked to original sources

Platinum-group element abundance and distribution in chromite deposits of the Acoje Block, Zambales Ophiolite Complex, Philippines

Platinum-group elements (PGE) occur in ore-grade concentration in some of the chromite deposits related to the ultramafic section of the Acoje Block of the Zambales Ophiolite Complex. The deposits are of three types: Type 1 - associated with cumulate peridotites at the base of the crust; Type 2 - in dunite pods from the top 1 km of mantle harzburgite; and Type 3 - like Type 2, but in deeper levels of the harzburgite. Most of the deposites have chromite compositions that are high in Cr with Cr/(Cr + Al) (expressed as chromium index, Cr#) > 0.6; high-Al (Cr# < 0.6) chromite deposits are relatively rare, occurring as interspersed orebodies in regions of Types 2 and 3. Sulfide-bearing Type 1 high-Cr deposits are PGE-enriched; the high-Al deposits have lowest Ir and Pd. Among the PGEs, Ir ranges from <20 to 550 ppb, Rh from <100 to 1100 ppb, Rh from 0.7 to 760 ppb, Pt from <1.0 to 5960 ppb and Pd from <0.5 to 8350 ppb. Chondrite-normalized (CN) PGE patterns are diverse, and include those with both negative slope (Ir > Pd, thought to be characteristic of PGE-barren deposits) and positive slope (Ir < Pd, characteristic of PGE-rich deposits). Iridium, Ru and Os commonly occur as micron-size laurite (sulfide) inclusions in unfractured chromite. Laurite and native Os are also found as inclusions in interstitial sulfides. Platinum and Pd occur as alloy inclusions (and possibly as solid solution) in interstitial Ni-Cu sulfides and as tellurobismuthides in serpentine and altered sulfides.

Journal of Geochemical Exploration↗

Eruptive history of Mount Mazama and Crater Lake Caldera, Cascade Range, U.S.A.

New investigations of the geology of Crater Lake National Park necessitate a reinterpretation of the eruptive history of Mount Mazama and of the formation of Crater Lake caldera. Mount Mazama consisted of a glaciated complex of overlapping shields and stratovolcanoes, each of which was probably active for a comparatively short interval. All the Mazama magmas apparently evolved within thermally and compositionally zoned crustal magma reservoirs, which reached their maximum volume and degree of differentiation in the climactic magma chamber ∼ 7000 yr B.P. The history displayed in the caldera walls begins with construction of the andesitic Phantom Cone ∼ 400,000 yr B.P. Subsequently, at least 6 major centers erupted combinations of mafic andesite, andesite, or dacite before initiation of the Wisconsin Glaciation ∼ 75,000 yr B.P. Eruption of andesitic and dacitic lavas from 5 or more discrete centers, as well as an episode of dacitic pyroclastic activity, occurred until ∼ 50,000 yr B.P.; by that time, intermediate lava had been erupted at several short-lived vents. Concurrently, and probably during much of the Pleistocene, basaltic to mafic andesitic monogenetic vents built cinder cones and erupted local lava flows low on the flanks of Mount Mazama. Basaltic magma from one of these vents, Forgotten Crater, intercepted the margin of the zoned intermediate to silicic magmatic system and caused eruption of commingled andesitic and dacitic lava along a radial trend sometime between ∼ 22,000 and ∼ 30,000 yr B.P. Dacitic deposits between 22,000 and 50,000 yr old appear to record emplacement of domes high on the south slope. A line of silicic domes that may be between 22,000 and 30,000 yr old, northeast of and radial to the caldera, and a single dome on the north wall were probably fed by the same developing magma chamber as the dacitic lavas of the Forgotten Crater complex. The dacitic Palisade flow on the northeast wall is ∼ 25,000 yr old. These relatively silicic lavas commonly contain traces of hornblende and record early stages in the development of the climatic magma chamber. Some 15,000 to 40,000 yr were apparently needed for development of the climactic magma chamber, which had begun to leak rhyodacitic magma by 7015 ± 45 yr B.P. Four rhyodacitic lava flows and associated tephras were emplaced from an arcuate array of vents north of the summit of Mount Mazama, during a period of ∼ 200 yr before the climactic eruption. The climactic eruption began 6845 ± 50 yr B.P. with voluminous airfall deposition from a high column, perhaps because ejection of ∼ 4−12 km 3 of magma to form the lava flows and tephras depressurized the top of the system to the point where vesiculation at depth could sustain a Plinian column. Ejecta of this phase issued from a single vent north of the main Mazama edifice but within the area in which the caldera later formed. The Wineglass Welded Tuff of Williams (1942) is the proximal featheredge of thicker ash-flow deposits downslope to the north, northeast, and east of Mount Mazama and was deposited during the single-vent phase, after collapse of the high column, by ash flows that followed topographic depressions. Approximately 30 km 3 of rhyodacitic magma were expelled before collapse of the roof of the magma chamber and inception of caldera formation ended the single-vent phase. Ash flows of the ensuing ring-vent phase erupted from multiple vents as the caldera collapsed. These ash flows surmounted virtually all topographic barriers, caused significant erosion, and produced voluminous deposits zoned from rhyodacite to mafic andesite. The entire climactic eruption and caldera formation were over before the youngest rhyodacitic lava flow had cooled completely, because all the climactic deposits are cut by fumaroles that originated within the underlying lava, and part of the flow oozed down the caldera wall. A total of ∼ 51−59 km 3 of magma was ejected in the precursory and climactic eruptions, and ∼ 40−52 km 3 of Mount Mazama was lost by caldera formation. The spectacular compositional zonation shown by the climactic ejecta — rhyodacite followed by subordinate andesite and mafic andesite — reflects partial emptying of a zoned system, halted when the crystal-rich magma became too viscous for explosive fragmentation. This zonation was probably brought about by convective separation of low-density, evolved magma from underlying mafic magma. Confinement of postclimactic eruptive activity to the caldera attests to continuing existence of the Mazama magmatic system.

Mount Mazama, Crater Lake, Cascade Range↗

Lithic breccia and ignimbrite erupted during the collapse of Crater Lake Caldera, Oregon

The climactic eruption of Mount Mazama (6845 y.B.P.) vented a total of ∼50 km 3 of compositionally zoned rhyodacitic to basaltic magma from: (a) a single vent as a Plinian pumice fall deposit and the overlying Wineglass Welded Tuff, and (b) ring vents as ignimbrite and coignimbrite lithic breccia accompanying the collapse of Crater Lake caldera. New field and grain-size data for the ring-vent products are presented in this report. The coarse-grained, poorly bedded, clast-supported lithic breccia extends as far as 18 km from the caldera center. Like the associated ignimbrite, the breccia is compositionally zoned both radially and vertically, and silicic, mixed, and mafic types can be recognized, based on the proportion of rhyodacitic pumice. Matrix fractions in silicic breccias are depleted of fines and are lithic- and crystal-enriched relative to silicic ignimbrite due to vigorous gas sorting during emplacement. Ignimbrite occurs as a proximal veneer deposit overlying the breccia, a medial (∼ 8 to ∼ 25 km from the caldera center), compositionally zoned valley fill as much as > 110 m thick, and an unzoned distal (⪖ 20 km) facies which extends as far as 55 km from the caldera. Breccia within ∼ 9 km of the caldera center is interpreted as a coignimbrite lag breccia formed within the deflation zone of the collapsing ring-vent eruption columns. Expanded pyroclastic flows of the deflation zone were probably vertically graded in both size and concentration of blocks, as recently postulated for some turbidity currents. An inflection in the rate of falloff of lithic-clast size within the lithic breccia at ∼ 9 km may mark the outer edge of the deflation zone or may be an artifact of incomplete exposure. The onset of ring-vent activity at Mt. Mazama was accompanied by a marked increase in eruptive discharge. Pyroclastic flows were emplaced as a semicontinuous stream, as few ignimbrite flow-unit boundaries are evident. As eruption from the ring vents progressed, flow-runout distance and the extent of breccia deposition decreased due to (a) greater internal flow friction, and (b) decreasing eruption column heights. Effect (b) probably resulted from a progressive decrease in magmatic gas content and discharge rate. Waning discharge may have been promoted by the tapping of more viscous, crystal-rich magma, collapse of conduit walls, and declining caldera collapse rate.

Oregon↗

Deformation of the Wineglass Welded Tuff and the timing of caldera collapse at Crater Lake, Oregon

Four types of deformation occur in the Wineglass Welded Tuff on the northeast caldera rim of Crater Lake: (a) vertical tension fractures; (b) ooze-outs of fiamme: (c) squeeze-outs of fiamme; and (d) horizontal pull-apart structures. The three types of plastic deformation (b-d) developed in the lower part of the Wineglass Welded Tuff where degree of welding and density are maximum. Deformation originated from concentric normal faulting and landsliding as the caldera collapsed. The degree of deformation of the Wineglass Welded Tuff increases toward the northeast part of the caldera, where plastic deformation occurred more easily because of a higher emplacement temperature probably due to proximity to the vent. The probable glass transition temperature of the Wineglass Welded Tuff suggests that its emplacement temperature was ???750??C where the tuff is densely welded. Calculation of the conductive cooling history of the Wineglass Welded Tuff and the preclimactic Cleetwood (lava) flow under assumptions of a initially isothermal sheet and uniform properties suggests that (a) caldera collapse occurred a maximum of 9 days after emplacement of the Wineglass Welded Tuff, and that (b) the period between effusion of the Cleetwood (lava) flow and onset of the climactic eruption was <100 years. If cooling is controlled more by precipitation during quiescent periods than by conduction, these intervals must be shorter than the calculated times.

Oregon↗

An experiment to detect and locate lightning associated with eruptions of Redoubt Volcano

A commercially-available lightning-detection system was temporarily deployed near Cook Inlet, Alaska in an attempt to remotely monitor volcanogenic lightning associated with eruptions of Redoubt Volcano. The system became operational on February 14, 1990; lightning was detected in 11 and located in 9 of the 13 subsequent eruptions. The lightning was generated by ash clouds rising from pyroclastic density currents produced by collapse of a lava dome emplaced near Redoubt's summit. Lightning discharge (flash) location was controlled by topography, which channeled the density currents, and by wind direction. In individual eruptions, early flashes tended to have a negative polarity (negative charge is lowered to ground) while late flashes tended to have a positive polarity (positive charge is lowered to ground), perhaps because the charge-separation process caused coarse, rapid-settling particles to be negatively charged and fine, slow-settling particles to be positively charged. Results indicate that lightning detection and location is a useful adjunct to seismic volcano monitoring, particularly when poor weather or darkness prevents visual observation. The simultaneity of seismicity and lightning near a volcano provides the virtual certainty that an ash cloud is present. This information is crucial for aircraft safety and to warn threatened communities of impending tephra falls. The Alaska Volcano Observatory has now deployed a permanent lightning-detection network around Cook Inlet.

Journal of Volcanology and Geothermal Research↗

Mount St. Augustine volcano fumarole wall rock alteration: Mineralogy, zoning, composition and numerical models of its formation process

Intensely altered wall rock was collected from high-temperature (640 °C) and low-temperature (375 °C) vents at Augustine volcano in July 1989. The high-temperature altered rock exhibits distinct mineral zoning differentiated by color bands. In order of decreasing temperature, the color bands and their mineral assemblages are: (a) white to grey (tridymite-anhydrite); (b) pink to red (tridymite-hematite-Fe hydroxide-molysite (FeCl 3 ) with minor amounts of anhydrite and halite); and (c) dark green to green (anhydrite-halite-sylvite-tridymite with minor amounts of molysite, soda and potash alum, and other sodium and potassium sulfates). The alteration products around the low-temperature vents are dominantly cristobalite and amorphous silica with minor potash and soda alum, aphthitalite, alunogen and anhydrite. Compared to fresh 1986 Augustine lava, the altered rocks exhibit enrichments in silica, base metals, halogens and sulfur and show very strong depletions in Al in all alteration zones and in iron, alkali and alkaline earth elements in some of the alteration zones. To help understand the origins of the mineral assemblages in altered Augustine rocks, we applied the thermochemical modeling program, GASWORKS, in calculations of: (a) reaction of the 1987 and 1989 gases with wall rock at 640 and 375 °C; (b) cooling of the 1987 gas from 870 to 100 °C with and without mineral fractionation; (c) cooling of the 1989 gas from 757 to 100 °C with and without mineral fractionation; and (d) mixing of the 1987 and 1989 gases with air. The 640 °C gas-rock reaction produces an assemblage consisting of silicates (tridymite, albite, diopside, sanidine and andalusite), oxides (magnetite and hercynite) and sulfides (bornite, chalcocite, molybdenite and sphalerite). The 375 °C gas-rock reaction produces dominantly silicates (quartz, albite, andalusite, microcline, cordierite, anorthite and tremolite) and subordinate amounts of sulfides (pyrite, chalcocite and wurtzite), oxides (magnetite), sulfates (anhydrite) and halides (halite). The cooling calculations produce: (a) anhydrite, halite, sylvite; (b) Cu, Mo, Fe and Zn sulfides; (c) Mg fluoride at high temperature (> 370 °C); (d) chlorides, fluorides and sulfates of Mn, Fe, Zn, Cu and Al at intermediate temperature (170–370 °C); and (e) hydrated sulfates, liquid sulfur, crystalline sulfur, hydrated sulfuric acid and water at low temperature (< 170°C). The volcanic gas-air mixing calculation produces major amounts of Na and K sulfates, minor amounts of hematite and trace amounts (< 1%) of anhydrite at log gas/air (Ig/a) ratios > 0.41 (> 628°C). This is followed by precipitation of sulfates of Fe, Cu. Pb. Zn and Al at Ig/a ratios between 0.31 and -0.4 (>628-178°C). At a lg/r ratio of ≤ -0.4 (178°C). anhydrous sulfates are replaced by their hydrated forms and hygroscopic sulfuric acid forms. At these low g/a ratios. hydrated sulfuric acid becomes the dominant phase in the system. Comparison of the thermochemical modeling results with the natural samples suggests that the alteration assemblages include: (1) minerals that precipitate from direct cooling of the volcanic gas; (2) phases that form by volcanic gases mixing with air: and (3) phases that form by volcanic gas-air-rock reaction. A complex interplay of the three processes produces the observed mineral zoning. Another implication of the numerical simulation results is that most of the observed incrustation and sublimate minerals apparently formed below 700°C.

Journal of Volcanology and Geothermal Research↗

Aquatic photolysis: photolytic redox reactions between goethite and adsorbed organic acids in aqueous solutions

Photolysis of mono and di-carboxylic acids that are adsorbed onto the surface of the iron oxyhydroxide (goethite) results in an oxidation of the organic material and a reduction from Fe(III) to Fe(II) in the iron complex. There is a subsequent release of Fe2+ ions into solution. At constant light flux and constant solution light absorption, the factors responsible for the degree of photolytic reaction include: the number of lattice sites that are bonded by the organic acid; the rate of acid readsorption to the surface during photolysis; the conformation and structure of the organic acid; the degree of oxidation of the organic acid; the presence or absence of an ??-hydroxy group on the acid, the number of carbons in the di-acid chain and the conformation of the di-acid. The ability to liberate Fe(III) at pH 6.5 from the geothite lattice is described by the lyotropic series: tartrate>citrate> oxalate > glycolate > maleate > succinate > formate > fumarate > malonate > glutarate > benzoate = butanoate = control. Although a larger amount of iron is liberated, the series is almost the same at pH 5.5 except that oxalate > citrate and succinate > maleate. A set of rate equations are given that describe the release of iron from the goethite lattice. It was observed that the pH of the solution increases during photolysis if the solutions are not buffered. There is evidence to suggest the primary mechanism for all these reactions is an electron transfer from the organic ligand to the Fe(III) in the complex. Of all the iron-oxyhydroxide materials, crystalline goethite is the least soluble in water; yet, this study indicates that in an aqueous suspension, iron can be liberated from the goethite lattice. Further, it has been shown that photolysis can occur in a multiphase system at the sediment- water interface which results in an oxidation of the organic species and release of Fe2+ to solution where it becomes available for further reaction. ?? 1993.

Journal of Photochemistry and Photobiology A: Chem↗

Evaluation of coal mine drainage and associated precipitates for radium and rare earth element concentrations

Coal mine drainage (CMD) and associated metal-rich precipitates have recently been proposed as unconventional sources of rare earth elements (REEs). However, the potential occurrence of radium (Ra), a known carcinogen, with the REE-bearing phases has not been investigated. We hypothesized that Ra may occur in solids that are precipitated from CMD as a “radiobarite” solid solution ((Ba,Sr,Ra)SO 4 ) and/or adsorbed with hydrous metal oxides. REEs have been documented to sorb or co-precipitate with iron (Fe), manganese (Mn), and aluminum (Al) oxyhydroxide in CMD solids. Likewise, Ra has been documented to sorb to hydrous Fe and Mn oxides especially where sulfate (SO 4 ) and/or barium (Ba) concentrations are insufficient to precipitate radiobarite. Thus, we conducted the first-ever survey of Ra concentrations in corresponding CMD water and solid samples in the United States. Samples were analyzed from 4 untreated and 9 treated CMD sites in both the bituminous and anthracite coal regions of Pennsylvania across a range of pH and SO 4 concentrations. The dissolved Ra in CMD was relatively low (<0.5 Bq/L), consistent with radiobarite solubility; however, CMD solids were largely composed of amorphous Fe, Al, and Mn oxyhydroxide and silicate minerals. Ra was associated with Mn-enriched CMD solids, upwards of 875 Bq/kg. Total REE + yttrium (Y) content in the CMD solids was enriched upwards of 3600 mg/kg and was significantly correlated with Al content. These preliminary results suggest that REE extraction may target Al-rich solids to avoid Ra in Mn-rich solids.

Pennsylvania↗

Interannual to multidecadal climate forcings on groundwater resources of the U.S. West Coast

Study region The U.S. West Coast, including the Pacific Northwest and California Coastal Basins aquifer systems. Study focus Groundwater response to interannual to multidecadal climate variability has important implications for security within the water–energy–food nexus. Here we use Singular Spectrum Analysis to quantify the teleconnections between AMO, PDO, ENSO, and PNA and precipitation and groundwater level fluctuations. The computer program DAMP was used to provide insight on the influence of soil texture, depth to water, and mean and period of a surface infiltration flux on the damping of climate signals in the vadose zone. New hydrological insights for the region We find that PDO, ENSO, and PNA have significant influence on precipitation and groundwater fluctuations across a north-south gradient of the West Coast, but the lower frequency climate modes (PDO) have a greater influence on hydrologic patterns than higher frequency climate modes (ENSO and PNA). Low frequency signals tend to be preserved better in groundwater fluctuations than high frequency signals, which is a function of the degree of damping of surface variable fluxes related to soil texture, depth to water, mean and period of the infiltration flux. The teleconnection patterns that exist in surface hydrologic processes are not necessarily the same as those preserved in subsurface processes, which are affected by damping of some climate variability signals within infiltrating water.

California, Oregon, Washington↗

Observations of nearshore groundwater discharge: Kahekili Beach Park submarine springs, Maui, Hawaii

Study region The study region encompasses the nearshore, coastal waters off west Maui, Hawaii. Here abundant groundwater—that carries with it a strong land-based fingerprint—discharges into the coastal waters and over a coral reef. Study focus Coastal groundwater discharge is a ubiquitous hydrologic feature that has been shown to impact nearshore ecosystems and material budgets. A unique combined geochemical tracer and oceanographic time-series study addressed rates and oceanic forcings of submarine groundwater discharge at a submarine spring site off west Maui, Hawaii. New hydrological insights for the region Estimates of submarine groundwater discharge were derived for a primary vent site and surrounding coastal waters off west Maui, Hawaii using an excess 222 Rn ( t 1/2 = 3.8 d) mass balance model. Such estimates were complemented with a novel thoron ( 220 Rn, t 1/2 = 56 s) groundwater discharge tracer application, as well as oceanographic time series and thermal infrared imagery analyses. In combination, this suite of techniques provides new insight into the connectivity of the coastal aquifer with the near-shore ocean and examines the physical drivers of submarine groundwater discharge. Lastly, submarine groundwater discharge derived constituent concentrations were tabulated and compared to surrounding seawater concentrations. Such work has implications for the management of coastal aquifers and downstream nearshore ecosystems that respond to sustained constituent loadings via this submarine route.

Hawaii↗

Leveraging airborne imaging spectroscopy and multispectral satellite imagery to map glacial sediment plumes in Kachemak Bay, Alaska

Study Region Kachemak Bay is a fjord-type estuary in the northern Gulf of Alaska. Water quality and habitat characteristics are strongly influenced by freshwater and sediment input from multiple glacierized catchments. Study Focus We present a new method combining imaging spectroscopy from an airborne survey with Landsat and Sentinel-2 imagery to map water surface turbidity originating from glacial runoff based on spectral abundance. We compare the spectral characteristics of turbid glacial water to clear water and generate a high resolution reference map of glacial turbidity in Kachemak Bay. This informs the subsequent analysis of a homogenized, Rayleigh corrected time series of Landsat and Sentinel-2 images and seasonal patterns of turbidity. New Hydrological Insights for the Region Our results provide the most comprehensive data set on water surface turbidity in Kachemak Bay to date and improve understanding of spatial and seasonal variability of glacial turbidity in a data sparse region. July and August have the largest plumes with median sizes around 150 km 2 "> 2 , or around a quarter of Kachemak Bay. Plume sizes typically decrease with decreasing glacier runoff in September and October. We show that imaging spectroscopy aids assessments of turbid water in glacial marine catchments across scales. Leveraging high resolution spectral information allows for water color analyses that are customized to local conditions and catchment characteristics as well as scalable to wider regions.

Alaska↗

Geologic, hydrologic, and geochemical interpretations of mineral deposits as analogs for understanding transport of environmental contaminants

Base- and precious-metal mineral deposits comprise anomalous concentrations of metals and associated elements, which may be useful subjects for study as analogs for migration of environmental contaminants. In the geologic past, hydrothermal mineral deposits formed at the intersection of favorable geologic, hydrologic and geochemical gradients. In the present, weathering of these sulfide-rich deposits occurs as a result of the interplay between rates of oxygen supply versus rates of ground or surface-water flow. Transport and spatial dispersion of elements from a mineral deposit occurs as a function of competing rates of water flow versus rates of attenuation mechanisms such as adsorption, dilution, or (co)precipitation. In this paper we present several case studies from mineralized and altered sedimentary and crystalline aquifers in the western United States to illustrate the geologic control of ground-water flow and solute transport, and to demonstrate how this combined approach leads to a more complete understanding of the systems under study as well as facilitating some capability to predict major flow directions in aquifers.

Journal of Geochemical Exploration↗

Changing climate drives future streamflow declines and challenges in meeting water demand across the southwestern United States

Society and the environment in the arid southwestern United States depend on reliable water availability, yet current water use outpaces supply. Water demand is projected to grow in the future and climate change is expected to reduce supply. To adapt, water managers need robust estimates of future regional water supply to support management decisions. To address this need, we estimate future streamflow in seven water resource regions in the southwestern U.S. using a new SPAtially Referenced Regressions On Watershed attributes (SPARROW) streamflow model. We present streamflow projections corresponding to input data from seven climate models and two greenhouse gas Representative Concentration Pathways (RCP4.5 and 8.5) for three, thirty-year intervals centered on the 2030s, 2050s, and 2080s, and for a historical thirty year interval centered on the 1990s. Across water resource regions, about half of the RCP4.5 models (51%) and two thirds of the RCP8.5 models (67%) indicate decreases in streamflow in the 2080s relative to the historical period. Models project maximum decreases in streamflow of 36–80% in all water resource regions for all periods and RCPs relative to historical streamflow, and maximum streamflow decreases of up to 20–45% in the 2080s at sites along the Colorado River used for measuring compliance with interstate and international water agreements. Headwaters are projected to experience the greatest declines, with substantial downstream implications. Among these estimates, the streamflows from models forced with RCP8.5 tend to be lower than those forced with RCP4.5. Not all climate models, times, and RCPs project widespread streamflow declines. The most ubiquitous streamflow increases are projected to occur in the 2030s under RCP4.5. Later time periods and enhanced greenhouse gas forcings indicate smaller regions of streamflow increase and lower accumulated streamflows, suggesting that limiting or reducing greenhouse gas concentrations could support future water availability. Although some possible streamflow increases are promising, the modest and spatially limited increases in streamflow projected for later time periods are still unlikely to be sufficient to meet the projected water demand. These results inform the likelihood of future water agreement compliance, and support developing strategies to balance water supply and demand.

Arizona, California, Colorado Idaho, Nevada, New M↗

The behavior of rare earth elements in naturally and anthropogenically acidified waters

In this paper, the behavior of rare earth elements (REE) in a watershed impacted by acid-mine drainage (Fisher Creek, Montana) is compared to that in a volcanically acidified watershed (Rio Agrio and Lake Caviahue, Argentina). The REE behave conservatively in acidic waters with pH values less than approximately 5.5. However, above pH 5.5, REE concentrations are controlled by adsorption onto or co-precipitation with a variety of Fe or Al oxyhydroxides. The heavy REE partition to a greater extent into the solid phase than the light REE as pH rises above 6. Concentrations of REE exhibit diel (24-h) cycling in waters that were initially acidic, but have become neutralized downstream. In Fisher Creek, at the most downstream sampling station investigated (pH 6.8), concentrations of dissolved REE were 190–840% higher in the early morning versus the late afternoon. This cycling can be related to temperature-dependent, cyclic adsorption–desorption of REE onto hydrous ferric or aluminum oxide or both. Similar but gentler diel cycling of the REE was found at Rio Agrio. The existence of such cycling has important ramifications for the study of REE in natural waters.

Journal of Alloys and Compounds↗

Integrating stations from the North America Gravity Database into a local GPS-based land gravity survey

The ability to augment local gravity surveys with additional gravity stations from easily accessible national databases can greatly increase the areal coverage and spatial resolution of a survey. It is, however, necessary to integrate such data seamlessly with the local survey. One challenge to overcome in integrating data from national databases is that these data are typically of unknown quality. This study presents a procedure for the evaluation and seamless integration of gravity data of unknown quality from a national database with data from a local Global Positioning System (GPS)-based survey. The starting components include the latitude, longitude, elevation and observed gravity at each station location. Interpolated surfaces of the complete Bouguer anomaly are used as a means of quality control and comparison. The result is an integrated dataset of varying quality with many stations having GPS accuracy and other reliable stations of unknown origin, yielding a wider coverage and greater spatial resolution than either survey alone.

Missouri↗

Roles of saltcedar (Tamarix spp.) and capillary rise in salinizing a non-flooding terrace on a flow-regulated desert river

Tamarix spp. (saltcedar) secretes salts and has been considered to be a major factor contributing to the salinization of river terraces in western US riparian zones. However, salinization can also occur from the capillary rise of salts from the aquifer into the vadose zone. We investigated the roles of saltcedar and physical factors in salinizing the soil profile of a non-flooding terrace at sites on the Cibola National Wildlife Refuge on the Lower Colorado River, USA. We placed salt traps under and between saltcedar shrubs and estimated the annual deposition rate of salts from saltcedar. These were then compared to the quantities and distribution on of salts in the soil profile. Dense stands of saltcedar deposited 0.159 kg m −2 yr −1 of salts to the soil surface. If this rate was constant since seasonal flooding ceased in 1938 and all of the salts were retained in the soil profile, they could account for 11.4 kg m −2 of salt, about 30% of total salts in the profile today. Eliminating saltcedar would not necessarily reduce salts, because vegetation reduces the upward migration of salts in bulk flow from the aquifer. The densest saltcedar stand had the lowest salt levels in the vadose zone in this study.

California↗

A comparison of estimates of basin-scale soil-moisture evapotranspiration and estimates of riparian groundwater evapotranspiration with implications for water budgets in the Verde Valley, Central Arizona, USA

Population growth in the Verde Valley in Arizona has led to efforts to better understand water availability in the watershed. Evapotranspiration (ET) is a substantial component of the water budget and a critical factor in estimating groundwater recharge in the area. In this study, four estimates of ET are compared and discussed with applications to the Verde Valley. Higher potential ET (PET) rates from the soil-water balance (SWB) recharge model resulted in an average annual ET volume about 17% greater than for ET from the basin characteristics (BCM) recharge model. Annual BCM PET volume, however, was greater by about a factor of 2 or more than SWB actual ET (AET) estimates, which are used in the SWB model to estimate groundwater recharge. ET also was estimated using a method that combines MODIS-EVI remote sensing data and geospatial information and by the MODFLOW-EVT ET package as part of a regional groundwater-flow model that includes the study area. Annual ET volumes were about same for upper-bound MODIS-EVI ET for perennial streams as for the MODFLOW ET estimates, with the small differences between the two methods having minimal impact on annual or longer groundwater budgets for the study area.

Arizona↗

Foraging behavior of Raramuri Criollo vs. Angus cattle grazing California Chaparral and Colorado Plateau shrublands

Selecting livestock genetics adapted to arid environments, such as Criollo cattle, is one of several strategies recommended for decreasing the vulnerability to climate change of ranching in the southwestern USA. Our objective was to determine whether desirable foraging traits of Criollo cattle previously documented in the Chihuahuan Desert, held true in two of the most climate-vulnerable ecosystems of the Southwest. We conducted a study at Rancho Corta Madera (RCM) in southern California and Dugout Ranch (DR) in southeast Utah. Twenty mature cows, 10 Raramuri Criollo and 10 Red or Black Angus, were monitored with GPS collars during multiple seasons between 2018 and 2021. Geolocation data were used to compute daily distance traveled (km*d −1 ), movement velocity (m*min −1 ), path sinuosity (SI), time spent grazing, resting, or traveling (h*d −1 ), and area of the pasture explored (ha*d −1 ) as well as to calculate selection of vegetation cover types ( E , Ivlev's Electivity Index) by cows of each breed. The effects of breed, season, year, and pasture on each of these metrics were modeled with repeated measures analyses of variance. At both ranches, statistically detectable differences (P ≤ 0.05) between breeds were observed for most behavior metrics during the dormant season. Conversely, few breed differences were observed during the growing season. Criollo cattle exhibited greater relative preference for a number of shrub dominated vegetation types at both ranches, and similar relative selection of grassland dominated sites compared to Angus counterparts. At both ranches, Criollo cattle exhibited similar or less relative preference for riparian areas vs. Angus counterparts. Breed divergence vs. convergence of foraging behaviors during the dormant vs. growing seasons, previously observed in the Chihuahuan Desert, was documented at both sites. Positive system outcomes associated with foraging traits of Criollo cattle could be expected to occur more broadly across the Southwest.

Journal of Arid Environments↗