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Crude-oil spill research project near Bemidji, Minnesota - Bibliography, 1984-1994

The U.S. Geological Survey began a research project at the site of a crude-oil spill near Bemidji, Minnesota in 1983. The project is part of the U.S. Geological Survey's Toxic Substances Hydrology Program. The objectives of research at the site are to obtain an understanding of the mobilization, transport, and fate of petroleum derivatives in the shallow subsurface and to use this understanding to develop predictive models of contaminant behavior. This report presents a bibliography of scientific papers that have been published from 1984 to early 1994. Research results have been published in scientific journals, conference proceedings, U.S. Geological Survey Reports, and academic theses.

Open-File Report

Proterozoic geochronological links between the Farewell, Kilbuck, and Arctic Alaska terranes

New U-Pb igneous and detrital zircon ages reveal that despite being separated by younger orogens, three of Alaska’s terranes that contain Precambrian rocks—Farewell, Kilbuck, and Arctic Alaska—are related. The Farewell and Kilbuck terranes can be linked by felsic magmatism at ca. 850 Ma and by abundant detrital zircons in the Farewell that overlap the ca. 2010–2085 Ma age range of granitoids in the Kilbuck. The Farewell and Arctic Alaska terranes have already been linked via correlative Neoproterozoic to Devonian carbonate platform deposits that share nearly identical faunas of mixed Siberian and Laurentian affinity. New igneous ages strengthen these ties. Specifically, 988, 979, and 979 Ma metafelsites in the Farewell terrane are close in age to a 971 Ma granitic orthogneiss in the Arctic Alaska terrane. Likewise, 852, 850, 845, and 837 Ma granitic orthogneisses, metafelsite, and rhyolite in the Farewell terrane are similar to the reported 874 to 848 Ma age range of metarhyolites in the Arctic Alaska terrane. The Kilbuck and Arctic Alaska terranes have been previously linked on the basis of provenance: detrital zircons from the Carboniferous Nuka Formation in the Arctic Alaska terrane range from 2013 to 2078 Ma, overlapping the age of Kilbuck granitoids. A new 849 Ma age of a Kilbuck granitoid strengthens the proposed connection. Among the other new results from Kilbuck terrane is a 2085 Ma zircon from a granitoid that now stands as the oldest tightly dated rock in Alaska. We conclude that the Kilbuck, Farewell, and Arctic Alaska terranes were not independent entities with unique geologic histories but instead are related pieces of the circum-Arctic tectonic puzzle.

Alaska

Explorers from space

The statement that a new era in exploration is opening will almost surely bring to mind the venturing of man into space and the ever more imminent exploration of the moon. The reference here, however, is to exploration of earth itself and to the unique capabilities for study of the earth that space technology will provide. Demands for water, minerals, energy, food, and for working, living and recreational space are outrunning our ability to meet them by traditional methods. In order to satisfy these demands, it is necessary now, just as it has been in the past, to look to the activities, the instruments, and the technologies that in part create the pressures for aid in meeting them. Studies being made at the U.S. Geological Survey and elsewhere of the potential applications of remote sensors in space to earth resources research indicate that now, at last, it will be possible to approach solutions on a regional or global basis. This paper discusses the plans for an Earth Resources Observational Satellites Program which will be designed for that purpose.

Journal of Geological Education

Geochemical recognition of a captured back-arc basin metabasaltic complex, southwestern Oregon

An extensive fault-bounded amphibolite terrane of Late Jurassic ( ) metamorphic age occurring in the northeastern Klamath Mountains of southern Oregon has been recognized as the remnants of an ancient back-arc basin. In spite of thorough metamorphic recrystallization under amphibolite-facies conditions, the amphibolite locally displays relict igneous textures which suggest that the protoliths included basaltic dikes or sills, shallow diabase intrusions, and gabbros. The major- and minor-element chemistry of the amphibolite indicates that some alteration of original compositions has occurred. Nevertheless, certain elements (e.g. Zr, Ti, Y, Hf, P, Th, Ta, and the REE) were probably immobile and retain their original igneous abundances. Chondrite-normalized REE patterns are similar to those of mid-ocean ridge basalt (MORB): concave-downward and flat or slightly LREE-depleted, with abundances about six to 30 times chondritic values. Patterns are slightly LREE-enriched and HREE-depleted relative to average MORB. Most samples plot in or near MORB fields in tectonomagmatic discrimination diagrams, but relative enrichment in Th and the LREE suggest the involvement of subduction-related fluids in magma genesis. In this regard, the amphibolite is very similar to some back-arc basin basalts. The geochemical data, together with the present-day geologic context, indicate that the tectonic setting of eruption/intrusion was probably within a back-arc basin that existed inboard (east) of a pre-Nevadan volcanic arc. The basalt (now amphibolite) and the overlying sediments (now the May Creek Schist) were metamorphosed and deformed during accretion to North America during the Late Jurassic Nevadan orogeny.

Journal of Geology

Pedimentation versus debris-flow origin of plateau-side desert terraces in southern Utah

Plateau-side terraces in arid areas around the world are commonly described as pediment remnants, although, in many cases, they may have been formed by debris-flow deposition. Pediments do exist in the area of the Aquarius and Kaiparowits Plateaus of southern Utah; however, many alluvial terraces that were classified by previous workers as pediments are actually formed of thick deposits of sediment released into valleys by episodic landslide events. Pedimentation may have implications of base level stability and aridity that are very different from the implications of landsliding, so that the identification of pediments where none exist, as has occurred for some places in the Aquarius and Kaiparowits areas, may result in erroneous interpretations of geologic history. Although both pediment and debris-flow depositional terraces have smooth, alluvium-covered upper surfaces, the two can be distinguished by the shape of the underlying bedrock surface and the process of formation. The distinction is that pedimentation produces smooth relief through erosion whereas wet debris flow produces smooth relief through deposition, although transitional phases exist. Most terraces on the flanks of the Aquarius and Kaiparowits Plateaus reflect periods of valley filling when wet debris flows rapidly deposited large quantities of sediment. The sources of the wet debris-flow sediment were large lobes of landslide debris that carried down sediment from high on the plateau sides. The relation of younger terraces to landsliding is clear, because the terrace surfaces are graded to the toes of slide lobes, but the origin of older terraces is less obvious, because older lobes of slide debris have generally been removed by erosion.

Journal of Geology

Organic geochemical studies of the transformation of gymnospermous xylem during peatification and coalification to subbituminous coal

Organic geochemical investigations of peatified and coalified xylem from gymnosperms have provided useful information on the organic transformational processes collectively known as coalification. The combined use of solid-state 13 C nuclear magnetic resonance (NMR) and pyrolysis/gas chromatography/mass spectrometry (py/gc/ms) has allowed us to examine the organic composition of peatified and coalified xylem on both a bulk (average) compositional basis and on a detailed molecular basis. We conclude from our studies that coalification of gymnospermous xylem involves the following processes1. (1) early selective removal of cellulosic materials so that lignin, a primary constituent of xylem, is transformed to macromolecular aromatic components in coal;2. (2) modification of gymnospermous lignin by demethylation to form catechol-like structures, and by condensation reactions to induce a high level of cross-linking at an early stage of coalification; and (3) dehydroxylation during increasing coalification to subbituminous coal, the resultant xylem becomes more phenolic in character as the catechol-like structures decrease.

International Journal of Coal Geology

Geospatial resources for the geologic community: The USGS National Map

Geospatial data are a key component of investigating, interpreting, and communicating the geological sciences. Locating geospatial data can be time-consuming, which detracts from time spent on a study because these data are not obviously placed in central locations or are served from many disparate databases. The National Map of the US Geological Survey is a publicly available resource for accessing the geospatial base map data needs of the geological community from a central location. The National Map data are available through a viewer and download platform providing access to eight primary data themes, plus the US Topo and scanned historical topographic maps. The eight themes are elevation, orthoimagery, hydrography, geographic names, boundaries, transportation, structures, and land cover, and they are being offered for download as predefined tiles in formats supported by leading geographic information system software. Data tiles are periodically refreshed to capture the most current content and are an efficient method for disseminating and receiving geospatial information. Elevation data, for example, are offered as a download from the National Map as 1° × 1° tiles for the 10- and 30- m products and as 15′ × 15′ tiles for the higher-resolution 3-m product. Vector data sets with smaller file sizes are offered at several tile sizes and formats. Partial tiles are not a download option—any prestaged data that intersect the requesting bounding box will be, in their entirety, part of the download order. While there are many options for accessing geospatial data via the Web, the National Map represents authoritative sources of data that are documented and can be referenced for citation and inclusion in scientific publications. Therefore, National Map products and services should be part of a geologist’s first stop for geospatial information and data.

Journal of Geology

River terrace evidence of tectonic processes in the eastern North American plate interior, South Anna River, Virginia

We show that long-recognized seismicity in the central Virginia seismic zone of the eastern North American intraplate setting arises primarily from tectonic processes predicted by new, fully coupled plate tectonic geodynamic models. The study leverages much new geophysical and geologic data following the 2011 Mineral, Virginia, earthquake that ruptured a steeply dipping, northwest-verging reverse fault traversed by the South Anna River. The data are primarily assembled from a flight of six fluvial terrace geomorphic markers identified and correlated on texture, relative weathering, and numeric ages including one terrestrial cosmogenic nuclide (TCN) profile and 30 luminescence dates. Terrace thickness, stratigraphic age models, and incision rates downstream and upstream of the 2011 rupture are different. Long-term river incision rates of ∼25–30 m/My are superimposed on regional TCN-determined erosion rates of ∼8.5 m/My; however, there are at least 10 m of tectonically driven incision in the epicentral region at rates of ∼30–94 m/My. The inferred deformation resembles a hanging wall anticline above a blind reverse fault with a diffuse overlying carapace of minor brittle faults, an interpretation supported by seismology as well as bedrock and saprolite mapped across the epicentral region. These results are further supported by channel metrics that show nonuniform channel steepness ( k sn ) and a predicted steady-state channel elevation different from the actual channel elevation across the epicentral region. If all of the observed deformation is a consequence of the fault that ruptured in 2011, the recurrence interval of Mineral-sized events would be ∼5.5 ky.

Virginia

Defining the hafnium isotopic signature of the Appalachian orogen through analysis of detrital zircons from modern fluvial sediments

Fluvial sediments are the product of erosion, weathering, and transport of bedrock within a well-defined catchment area, and their constituent grains may therefore record valuable information about the lithological and geochemical properties of geologic units within the upstream drainage. Analysis of U-Pb ages and Lu/Hf isotopic values in detrital zircon grains from major rivers in the eastern USA characterizes these parameters within broad areas of the Appalachian orogen. In this study, five modern fluvial sediment samples, collected across ~1500 km and representing 216,000 km2 of total catchment area, reveal that the relative proportions of Mesoproterozoic to Paleozoic U-Pb crystallization ages vary widely across the former Laurentian margin. However, εHft values in the same samples are largely consistent regardless of their geographic location. Mesoproterozoic (Grenville orogen) zircons display a more limited range of εHft values (approximately 0 to +10 εHft units) compared to the more negative, more variable values (-15 to +10) found in grains from the Paleozoic orogenies. When compared to other published modern detrital samples from the Gulf Coastal Plain, Appalachian samples show more similarity to each other and to the Pleistocene of Florida than to those from the Mississippi River mouth, likely because the latter also sources sediments from the Cordillera of western North America. More negative εHft values in Paleozoic zircons may be genetically related to older Mesoproterozoic grains, as they are compatible with the continued isotopic evolution of Lu/Hf derived from the mantle between 1.2 and 2.0 Ga. Hafnium geochemistry in detrital grains may therefore have some utility in discerning sediment provenance between the Appalachians and other regions, and may also provide useful information regarding the nature of crustal generation through time.

Journal of Geology

Physical geology and eruptive history of the Matahina Ignimbrite, Taupo Volcanic Zone, North Island, New Zealand

The Matahina Ignimbrite is a 280 ka ash‐flow sheet that erupted from Haroharo Caldera in the Okataina Volcanic Centre, northern Taupo Volcanic Zone, North Island, New Zealand. The ignimbrite underlies a 2000 km 2 area mainly east of the caldera, ranges in thickness from 5 to 200 m, and has a outflow volume of c. 120 km 3 , equivalent to c. 75 km 3 of magma. It is a multiple‐flow, compound cooling unit consisting of a basal tephra (fallout) member and three ash‐flow members, designated lower, middle , and upper , that record three eruptive pulses separated by brief time intervals, estimated from cooling and compaction noddling to range from 20 to 60 days. Distribution of coarse lithic clasts, together with local interbedded co‐ignimbrite lag breccias and tephra layers east of the Puhipuhi Easin, confirm Haroharo Caldera as the eruptive source. Over most of its extent on the Kaingaroa Plateau, the outflow s leet thickens eastward away from its source and attains its greatest thickness in the elongate, north‐trending, fault‐a ngle trough formed between the gently east sloping surface of the plateau and the western front of the Ikawhenua Fange. Difference in thickness of the ignimbrite across the fault bounding the west front of the Ikawhenua Range suggests that during the short time interval between emplacement of the lower and middle ash‐flow members, a major tectonic event caused at least 10 m displacement on the fault locally. Circumstantial evidence supporting this early syneruptive tectonic event is found along the Bay of Plenty coast where penecontemporaneous liquefaction structures, possibly seismically induced, occur in the distal subaqueous facies of the lower ash‐flow member. The presence of such 1 quefaction structures in the Matahina and other coastal New Zealand ignimbrites suggests a possible close association between tectonism and major ignimbrite eruptions.

North Island, Taupo Volcanic Zone

Bedrock geology of DFDP-2B, central Alpine Fault, New Zealand

During the second phase of the Alpine Fault, Deep Fault Drilling Project (DFDP) in the Whataroa River, South Westland, New Zealand, bedrock was encountered in the DFDP-2B borehole from 238.5–893.2 m Measured Depth (MD). Continuous sampling and meso- to microscale characterisation of whole rock cuttings established that, in sequence, the borehole sampled amphibolite facies, Torlesse Composite Terrane-derived schists, protomylonites and mylonites, terminating 200–400 m above an Alpine Fault Principal Slip Zone (PSZ) with a maximum dip of 62°. The most diagnostic structural features of increasing PSZ proximity were the occurrence of shear bands and reduction in mean quartz grain sizes. A change in composition to greater mica:quartz + feldspar, most markedly below c. 700 m MD, is inferred to result from either heterogeneous sampling or a change in lithology related to alteration. Major oxide variations suggest the fault-proximal Alpine Fault alteration zone, as previously defined in DFDP-1 core, was not sampled.

New Zealand Journal of Geology and Geophysics

Pleistocene Brawley and Ocotillo Formations: Evidence for initial strike-slip deformation along the San Felipe and San Jacinto fault zonez, Southern California

We examine the Pleistocene tectonic reorganization of the Pacific-North American plate boundary in the Salton Trough of southern California with an integrated approach that includes basin analysis, magnetostratigraphy, and geologic mapping of upper Pliocene to Pleistocene sedimentary rocks in the San Felipe Hills. These deposits preserve the earliest sedimentary record of movement on the San Felipe and San Jacinto fault zones that replaced and deactivated the late Cenozoic West Salton detachment fault. Sandstone and mudstone of the Brawley Formation accumulated between ???1.1 and ???0.6-0.5 Ma in a delta on the margin of an arid Pleistocene lake, which received sediment from alluvial fans of the Ocotillo Formation to the west-southwest. Our analysis indicates that the Ocotillo and Brawley formations prograded abruptly to the east-northeast across a former mud-dominated perennial lake (Borrego Formation) at ???1.1 Ma in response to initiation of the dextral-oblique San Felipe fault zone. The ???25-km-long San Felipe anticline initiated at about the same time and produced an intrabasinal basement-cored high within the San Felipe-Borrego basin that is recorded by progressive unconformities on its north and south limbs. A disconformity at the base of the Brawley Formation in the eastern San Felipe Hills probably records initiation and early blind slip at the southeast tip of the Clark strand of the San Jacinto fault zone. Our data are consistent with abrupt and nearly synchronous inception of the San Jacinto and San Felipe fault zones southwest of the southern San Andreas fault in the early Pleistocene during a pronounced southwestward broadening of the San Andreas fault zone. The current contractional geometry of the San Jacinto fault zone developed after ???0.5-0.6 Ma during a second, less significant change in structural style. ?? 2007 by The University of Chicago. All rights reserved.

Journal of Geology

Sediment fluxes from California Coastal Rivers: the influences of climate, geology, and topography

The influences of geologic and climatic factors on erosion and sedimentation processes in rivers draining the western flank of the California Coast Range are assessed. Annual suspended, bedload, and total sediment fluxes were determined for 16 river basins that have hydrologic records covering all or most of the period from 1950 to 2006 and have been relatively unaffected by flow storage, regulation, and depletion, which alter the downstream movement of water and sediment. The occurrence of relatively large annual sediment fluxes are strongly influenced by the El Nino–Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO). The frequency of relatively large annual sediment fluxes decreases from north to south during La Nina phases and increases from north to south during El Nino phases. The influence of ENSO is modulated over a period of decades by the PDO, such that relatively large annual sediment fluxes are more frequent during a La Nina phase in conjunction with a cool PDO and during an El Nino phase in conjunction with a warm PDO. Values of mean annual sediment flux, , were regressed against basin and climatic characteristics. Basin area, bedrock erodibility, basin relief, and precipitation explain 87% of the variation in from the 16 river basins. Bedrock erodibility is the most significant characteristic influencing . Basin relief is a superior predictor of compared with basin slope. is nearly proportional to basin area and increases with increasing precipitation. For a given percentage change, basin relief has a 2.3-fold greater effect on than a similar change in precipitation. The estimated natural from all California coastal rivers for the period 1950–2006 would have been approximately 85 million tons without flow storage, regulation, and depletion; the actual has been approximately 50 million tons, because of the effects of flow storage, regulation, and depletion.

California

Detecting snow avalanche activity using infrasound: Hooker Valley, New Zealand

Snow avalanches pose considerable hazards to people and infrastructure in alpine environments. Traditional avalanche monitoring relies on meteorological data and visual observations, which can be limited in scope and timeliness. Infrasound offers a promising complementary monitoring tool by detecting the low-frequency sound waves generated by avalanches. Here, we present infrasound and camera observations during a 50-day field campaign in the Hooker Valley of Aoraki/Mount Cook National Park, New Zealand. Our study detected seven avalanches with the cameras, whereas the infrasound system identified only one of these events, which was the largest and occurred under conditions that likely favoured infrasound propagation. The infrasound system recorded numerous other events not captured by the cameras, indicating the benefit of further investigation to determine their sources. These findings highlight the potential of infrasound technology for detecting avalanches and providing broad spatial coverage, capturing events in areas not monitored by cameras, while also showcasing limitations in infrasound capabilities. The limited detection of smaller avalanches underscores the opportunity for further research to enhance detection capabilities and understand environmental influences such as snow cover and wind noise. Overall, this study emphasises the utility of multidisciplinary monitoring techniques to improve avalanche detection in alpine environments.

Hooker Valley

Dust deposited on snow cover in the San Juan Mountains, Colorado, 2011-2016: Compositional variability bearing on snow-melt effects

Light-absorbing particles in atmospheric dust deposited on snow cover (dust-on-snow, DOS) diminish albedo and accelerate the timing and rate of snow melt. Identification of these particles and their effects are relevant to snow-radiation modeling and thus water-resource management. Laboratory-measured reflectance of DOS samples from the San Juan Mountains (USA) were compared with DOS mass loading, particle sizes, iron mineralogy, carbonaceous matter type and content, and chemical compositions. Samples were collected each spring for water years 2011-2016, when individual dust layers had merged into one (all layers merged) at the snow surface. Average reflectance values of the six samples were 0.2153 (sd, 0.0331) across the visible wavelength region (0.4-0.7 µm) and 0.3570 (sd, 0.0498) over the full-measurement range (0.4-2.50 µm). Reflectance values correlated inversely to concentrations of ferric oxide, organic carbon (1.4-10 wt. %), magnetite (0.05-0.13 wt. %), and silt (PM63-3.9; median grain sizes averaged 21.4 µm) but lacked correspondence to total iron and PM10 contents. Measurements of reflectance and Mössbauer spectra and magnetic properties indicated that microcrystalline hematite and nano-size goethite were primarily responsible for diminished visible reflectance. Positive correlations between organic carbon and metals attributed to fossil-fuel combustion, with observations from electron microscopy, indicated that some carbonaceous matter occurred as black carbon. Magnetite was a surrogate for related light-absorbing minerals, dark rock particles, and contaminants. Similar analyses of DOS from other areas would help evaluate the influences of varied dust sources, wind-storm patterns, and anthropogenic inputs on snow melt and water resources in and beyond the Colorado River basin.

Colorado

Remanent magnetization and susceptibility of late Cenozoic rocks from New Zealand

Measurements of magnetic remanence and susceptibility were made on 176 samples of volcanic rocks from 22 late Cenozoic formations from the North Island. Intensities of remanence, susceptibilities, and Q ratios are highly variable in both the ignimbrites and andesites and their ranges overlap, indicating that the magnetic anomalies produced by ignimbrite bodies would be difficult to distinguish from those produced by andesite flows. An analysis of the directions of magnetization of the ignimbrites indicates that groups of petrologically distinct ignimbrites probably formed during the same volcanic episode.

North Island

Evaporite encrustations and sulphide oxidation products from the southern Antarctic peninsula.

White evaporite encrustations collected from 66 sites scattered over 30 000km2 of S.Antarctic Peninsula are dominantly gypsum and calcite, and subordinate aragonite and thenardite. Natrojarosite occurs as locally developed yellow surface stains on c30% of the white encrustations examined. Water, which forms by the melting of snow blown into cracks in highly fractured rocks by ground blizzards, dissolves soluble ions from minerals in these rocks as it percolates into them. The white encrustations appear to be deposited when this water later rises to the surface by capillary action and evaporates.-from Author Antarctica chemical weathering evaporites sulphide oxidation.

New Zealand Journal of Geology and Geophysics

A paleomagnetic investigation of rocks from the Ohio Range and the Dry Valleys, Transantarctic Mountains, Antarctica

Two well-defined virtual geomagnetic poles (VGPs) for East Antarctica were obtained from the Middle Jurassic Ferrar Dolerite, sampled from a thick sill on Mt Schopf in the Ohio Range, and from a horizontal sheet intruding Paleozoic granitic rocks at Mt Cerberus in the Dry Valleys. The VGP from the sill at Mt Schopf lies at lat. 58°.0S, long. 129°.0W (dm=13°, dp=12°), and the VGP from Mt Cerberus lies at lat. 57°.8S, long. 135°.7W (dm=6°, dp=6°). Rocks from both localities have normal polarity magnetisations. These data, together with 15 other acceptable pole positions reported in the literature, define a Middle Jurassic paleomagnetic pole at 52°.7S, 139°.6W (α 95 =4°.4), which is not significantly different from previously reported mean Middle Jurassic paleomagnetic poles from East Antarctica. Paleomagnetic investigations in the Ohio Range of mafic inclusions in Ordovician granitic and sedimentary rocks of Devonian and Permian ages found that the rocks are magnetically unstable and are unreliable for determining a paleomagnetic pole.

New Zealand Journal of Geology and Geophysics