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At least 91 records · Page 5Linked to original sources

A molecular investigation of soil organic carbon composition across a subalpine catchment

The dynamics of soil organic carbon (SOC) storage and turnover are a critical component of the global carbon cycle. Mechanistic models seeking to represent these complex dynamics require detailed SOC compositions, which are currently difficult to characterize quantitatively. Here, we address this challenge by using a novel approach that combines Fourier transform infrared spectroscopy (FT-IR) and bulk carbon X-ray absorption spectroscopy (XAS) to determine the abundance of SOC functional groups, using elemental analysis (EA) to constrain the total amount of SOC. We used this SOC functional group abundance (SOC-fga) method to compare variability in SOC compositions as a function of depth across a subalpine watershed (East River, Colorado, USA) and found a large degree of variability in SOC functional group abundances between sites at different elevations. Soils at a lower elevation are predominantly composed of polysaccharides, while soils at a higher elevation have more substantial portions of carbonyl, phenolic, or aromatic carbon. We discuss the potential drivers of differences in SOC composition between these sites, including vegetation inputs, internal processing and losses, and elevation-driven environmental factors. Although numerical models would facilitate the understanding and evaluation of the observed SOC distributions, quantitative and meaningful measurements of SOC molecular compositions are required to guide such models. Comparison among commonly used characterization techniques on shared reference materials is a critical next step for advancing our understanding of the complex processes controlling SOC compositions.

Soil Systems

Reversal of forest soil acidification in the northeastern United States and eastern Canada: Site and soil factors contributing to recovery

As acidic deposition has decreased across Eastern North America, forest soils at some sites are beginning to show reversal of soil acidification. However, the degree of recovery appears to vary and is not fully explained by deposition declines alone. To assess if other site and soil factors can help to explain degree of recovery from acid deposition, soil resampling chemistry data (8- to 24-year time interval) from 23 sites in the United States and Canada, located across 25° longitude from Eastern Maine to Western Ontario, were explored. Site and soil factors included recovery years, sulfate (SO 4 2− ) deposition history, SO 4 2− reduction rate, C horizon pH and exchangeable calcium (Ca), O and B horizon pH, base saturation, and exchangeable Ca and aluminum (Al) at the time of the initial sampling. We found that O and B horizons that were initially acidified to a greater degree showed greater recovery and B horizon recovery was further associated with an increase in recovery years and lower initial SO 4 2− deposition. Forest soils that seemingly have low buffering capacity and a reduced potential for recovery have the resilience to recover from the effects of previous high levels of acidic deposition. This suggests, that predictions of where forest soils acidification reversal will occur across the landscape should be refined to acknowledge the importance of upper soil profile horizon chemistry rather than the more traditional approach using only parent material characteristics.

Soil Systems

Have sustained acidic deposition decreases led to increased calcium availability in recovering watersheds of the Adirondack region of New York, USA?

Soil calcium depletion has been strongly linked to acidic deposition in eastern North America and recent studies have begun to document the recovery of soils in response to large decreases in acidic deposition. However, increased calcium availability has not yet been seen in the B horizon, where calcium depletion has been most acute, but mineral weathering is critically important for resupplying ecosystem calcium. This study provides new data in seven watersheds in the Adirondack region (New York, USA), where acidic deposition impacts on soils and surface waters have been substantial and recovery remains slow. Initial sampling in 1997–1998 and 2003–2004 was repeated in 2009–2010, 2014, 2016 and 2017. Exchangeable calcium concentrations increased by an average of 43% in the Oe horizon of three watersheds where this horizon was sampled (10.7–15.3 cmol c kg −1 ). Changes in calcium were not seen in the individual watersheds of the Oa and B horizons, but as a group, a significant increase in calcium was measured in the upper B horizon. Liming of a calcium-depleted watershed also tripled calcium concentration in the upper B horizon in 5 years. However, stream calcium in unlimed watersheds decreased over the study period. Small increases in B-horizon calcium may be underway

New York

Infrared heater system for warming tropical forest understory plants and soils

The response of tropical forests to global warming is one of the largest uncertainties in predicting the future carbon balance of Earth. To determine the likely effects of elevated temperatures on tropical forest understory plants and soils, as well as other ecosystems, an infrared (IR) heater system was developed to provide in situ warming for the Tropical Responses to Altered Climate Experiment (TRACE) in the Luquillo Experimental Forest in Puerto Rico. Three replicate heated 4-m- diameter plots were warmed to maintain a 4°C increase in understory vegetation compared to three unheated control plots, as sensed by IR thermometers. The equipment was larger than any used previously and was subjected to challenges different from those of many temperate ecosystem warming systems, including frequent power surges and outages, high humidity, heavy rains, hurricanes, saturated clayey soils, and steep slopes. The system was able to maintain the target 4.0°C increase in hourly average vegetation temperatures to within ± 0.1°C. The vegetation was heterogeneous and on a 21° slope, which decreased uniformity of the warming treatment on the plots; yet, the green leaves were fairly uniformly warmed, and there was little difference among 0–10 cm depth soil temperatures at the plot centers, edges, and midway between. Soil temperatures at the 40–50 cm depth increased about 3°C compared to the controls after a month of warming. As expected, the soil in the heated plots dried faster than that of the control plots, but the average soil moisture remained adequate for the plants. The TRACE heating system produced an adequately uniform warming precisely controlled down to at least 50-cm soil depth, thereby creating a treatment that allows for assessing mechanistic responses of tropical plants and soil to warming, with applicability to other ecosystems. No physical obstacles to scaling the approach to taller vegetation (i.e., trees) and larger plots were observed.

Puerto Rico

Adaptive management for soil ecosystem services

Ecosystem services provided by soil include regulation of the atmosphere and climate, primary (including agricultural) production, waste processing, decomposition, nutrient conservation, water purification, erosion control, medical resources, pest control, and disease mitigation. The simultaneous production of these multiple services arises from complex interactions among diverse aboveground and belowground communities across multiple scales. When a system is mismanaged, non-linear and persistent losses in ecosystem services can arise. Adaptive management is an approach to management designed to reduce uncertainty as management proceeds. By developing alternative hypotheses, testing these hypotheses and adjusting management in response to outcomes, managers can probe dynamic mechanistic relationships among aboveground and belowground soil system components. In doing so, soil ecosystem services can be preserved and critical ecological thresholds avoided. Here, we present an adaptive management framework designed to reduce uncertainty surrounding the soil system, even when soil ecosystem services production is not the explicit management objective, so that managers can reach their management goals without undermining soil multifunctionality or contributing to an irreversible loss of soil ecosystem services.

Journal of Environmental Management

Comparison between two statistically based methods, and two physically based models developed to compute daily mean streamflow at ungaged locations in the Cedar River Basin, Iowa

A variety of individuals from water resource managers to recreational users need streamflow information for planning and decisionmaking at locations where there are no streamgages. To address this problem, two statistically based methods, the Flow Duration Curve Transfer method and the Flow Anywhere method, were developed for statewide application and the two physically based models, the Precipitation Runoff Modeling-System and the Soil and Water Assessment Tool, were only developed for application for the Cedar River Basin. Observed and estimated streamflows for the two methods and models were compared for goodness of fit at 13 streamgages modeled in the Cedar River Basin by using the Nash-Sutcliffe and the percent-bias efficiency values. Based on median and mean Nash-Sutcliffe values for the 13 streamgages the Precipitation Runoff Modeling-System and Soil and Water Assessment Tool models appear to have performed similarly and better than Flow Duration Curve Transfer and Flow Anywhere methods. Based on median and mean percent bias values, the Soil and Water Assessment Tool model appears to have generally overestimated daily mean streamflows, whereas the Precipitation Runoff Modeling-System model and statistical methods appear to have underestimated daily mean streamflows. The Flow Duration Curve Transfer method produced the lowest median and mean percent bias values and appears to perform better than the other models.

Iowa

Alternate wetting and drying decreases methylmercury in flooded rice (Oryza sativa) systems

In flooded soils, including those found in rice ( Oryza sativa L.) fields, microbes convert inorganic Hg to more toxic methylmercury (MeHg). Methylmercury is accumulated in rice grain, potentially affecting health. Methylmercury in rice field surface water can bioaccumulate in wildlife. We evaluated how introducing aerobic periods into an otherwise continuously flooded rice growing season affects MeHg dynamics. Conventional continuously flooded (CF) rice field water management was compared with alternate wetting and drying, where irrigation was stopped twice during the growing season, allowing soil to dry to 35% volumetric moisture content, at which point plots were reflooded (AWD-35). Methylmercury studies began at harvest in Year 3 and throughout Year 4 of a 4-yr replicated field experiment. Bulk soil, water, and plant samples were analyzed for MeHg and total Hg (THg), and iron (Fe) speciation was measured in soil samples. Rice grain yield over 4 yr did not differ between treatments. Soil chemistry responded quickly to AWD-35 dry-downs, showing significant oxidation of Fe(II) accompanied by a significant reduction of MeHg concentration (76% reduction at harvest) compared with CF. Surface water MeHg decreased by 68 and 39% in the growing and fallow seasons, respectively, suggesting that the effects of AWD-35 management can last through to the fallow season. The AWD-35 treatment reduced rice grain MeHg and THg by 60 and 32%, respectively. These results suggest that the more aerobic conditions caused by AWD-35 limited the activity of Hg(II)-methylating microbes and may be an effective way to reduce MeHg concentrations in rice ecosystems.

Soil Science Society of America Journal

A framework for understanding the effects of subsurface agricultural drainage on downstream flows

Understanding controls on streamflow volume and magnitude is important to water resource management applications, such as critical water and transportation structure design and floodplain mapping. Changes in land use and agricultural practices, such as subsurface agricultural drainage, may be contributing to changes in streamflow characteristics. Subsurface agricultural drainage, also known as tile drainage, is the practice of installing drains in the subsurface of agricultural fields to improve productivity. Because of the complex interactions between subsurface drainage systems, precipitation, local soil conditions, and land management practices, it is difficult to determine how subsurface agricultural drainage affects downstream flow. Previously developed subsurface agricultural drainage conceptual models under dry, saturated, and winter conditions are summarized, and current literature on the effects of subsurface agricultural drainage on downstream flows, focusing on peak flow, non-event flow, and total flow to develop frameworks for discussing these systems is compiled. The effects that subsurface drainage has on hydrologic systems are expected to vary by site and are seasonally based on system design, soil type, moisture conditions, precipitation characteristics, and land conditions. Subsurface drainage can affect the magnitude of peak flow by converting surface runoff from a storm event to subsurface runoff. By increasing hydrologic connectivity of a catchment, subsurface drainage can increase non-event flow or the flow between two storm events, typically dependent on lateral flow through the subsurface and groundwater. Theoretically, by diverting water from groundwater recharge or by reducing water available for evapotranspiration, subsurface drainage may increase the total volume of flow. Precipitation changes may increase infiltration, excess overland flow, and flood risk regardless of the presence or absence of subsurface drainage.

Illinois, Iowa, Michigan, Minnesota, Missouri, Mon

Evaluation of conceptual models of natural organic matter (humus) from a consideration of the chemical and biochemical processes of humification

Natural organic matter (NOM) has been studied for more than 200 years because of its importance in enhancing soil fertility, soil structure, and water-holding capacity and as a carbon sink in the global carbon cycle. Two different types of models have been proposed for NOM: (1) the humic polymer models and (2) the molecular aggregate models. In the humic polymer models, NOM molecules are depicted as large (humic) polymers that have unique chemical structures that are different from those of the precursor plant degradation products. In the molecular aggregate models, NOM is depicted as being composed of molecular aggregates (supramolecular aggregates) of plant degradation products held together by non-covalent bonds. The preponderance of evidence favors the supramolecular aggregate models. These models were developed by studying the properties of NOM extracted from soils and natural waters, and as such, they provide only a very generalized picture of the structure of NOM aggregates in soils and natural waters prior to extraction. A compartmental model, in which the structure of the NOM in each of the compartments is treated separately, should provide a more accurate representation of NOM in soil and sediment systems. The proposed NOM compartments are: (1) partially degraded plant tissue, (2) biomass from microorganisms, (3) organic coatings on mineral grains, (4) pyrolytic carbon, (5) organic precipitates, and (6) dissolved organic matter (DOM) in interstitial water. Within each of these compartments there are NOM supramolecular aggregates that will be dissolved by the solvent systems that are used by researchers for extraction of NOM from soils and sediments. In natural water systems DOM may be considered as existing in two subcompartments: (1) truly dissolved DOM and (2) colloidal DOM.

Scientific Investigations Report

Soil moisture product validation good practices protocol, version 1.0

The Global Climate Observing System (GCOS) included soil moisture in the list of Essential Climate Variables (ECVs) to express its important role in Earth’s water, energy and carbon cycle. Soil moisture has a major impact on agriculture, land surface hydrology, weather, and climate forecasting. This document is a community-based effort to provide recommendations on good practices for the validation of global to regional soil moisture products. Definitions are given and metrics to adequately describe the quality of soil moisture products are presented. Spaceborne active and passive microwave sensors are listed with their characteristics, and the typical soil moisture retrieval methods are explained, including dielectric mixing models and optical methods. Spatial scaling, root zone soil moisture estimation, and operational implementations are addressed, as these issues continue to gain more and more importance. Standard and advanced in situ measurement techniques are described as well as sensor calibration, spatial representativity, sampling strategies, and the benefit of airborne campaigns.The community has agreed upon the utilization of the International Soil Moisture Network (ISMN) as the main online repository for in situ soil moisture measurements. Different validation methods such as ground-based validation, satellite product intercomparison, and time series analyses are presented. We provide strategies to evaluate the long-term quality of soil moisture products, and give advice on how to handle typical temporal and spatial-scale mismatches and how to effectively report validation results. Moreover, the benefit of blind tests is discussed to gain objective validation results. We encourage data providers, scientists and practitioners to use this Soil Moisture Product Validation Good Practices Protocol to provide, analyze, and improve high quality Earth Observation results.

Report

Biological soil crusts (biocrusts) as a model system in community, landscape and ecosystem ecology

Model systems have had a profound influence on the development of ecological theory and general principles. Compared to alternatives, the most effective models share some combination of the following characteristics: simpler, smaller, faster, general, idiosyncratic or manipulable. We argue that biological soil crusts (biocrusts) have unique combinations of these features that should be more widely exploited in community, landscape and ecosystem ecology. In community ecology, biocrusts are elucidating the importance of biodiversity and spatial pattern for maintaining ecosystem multifunctionality due to their manipulability in experiments. Due to idiosyncrasies in their modes of facilitation and competition, biocrusts have led to new models on the interplay between environmental stress and biotic interactions and on the maintenance of biodiversity by competitive processes. Biocrusts are perhaps one of the best examples of micro-landscapes—real landscapes that are small in size. Although they exhibit varying patch heterogeneity, aggregation, connectivity and fragmentation, like macro-landscapes, they are also compatible with well-replicated experiments (unlike macro-landscapes). In ecosystem ecology, a number of studies are imposing small-scale, low cost manipulations of global change or state factors in biocrust micro-landscapes. The versatility of biocrusts to inform such disparate lines of inquiry suggests that they are an especially useful model system that can enable researchers to see ecological principles more clearly and quickly.

Biodiversity and Conservation

Integrating magnetotellurics, soil gas geochemistry and structural analysis to identify hidden, high enthalpy, extensional geothermal systems

We applied magnetotellurics (MT), diagnostic structural affiliations, soil gas flux, and fluid geochemistry to assist in identifying hidden, high-enthalpy geothermal systems in extensional regimes of the U.S. Great Basin. We are specifically looking for high-angle, low-resistivity zones and dilatant geologic structures that can carry fluids from magmatic or high-grade metamorphic conditions in the deep crust upward to exploitable depths, and to verify the nature of the deep sources through soil gas and fluid compositions. The project was motivated by prior MT transect coverage of western and central Nevada centered upon the Dixie Valley producing geothermal system where such favorable indicators were first recognized. The high-angle MT structures are taken to be fluidized fault zones connecting deep magmatic/metamorphic activity with the geothermal system, but the concept required verification by testing at other systems. The project was set up with a two-phased organization. Phase I was carried out at the McGinness Hills system, central Nevada, where Ormat Inc flagship power facility is located and a considerable amount of pre-existing data were available. Resistivity models along MT transects also showed a strong low-resistivity upwelling originating from interpreted deep crustal magmatic underplating. Controlling structures on production as indicated by Ormat data and our new mapping were favorable to dilatancy, comprising an accommodation zone between major normal faults of opposing dip. A 3D MT survey and inversion confirmed the existence of the steep low-resistivity zone dipping ESE toward the deep crust and placed N-S bounds upon the feature. In cooperation with Ormat personnel, we sampled well fluids from production intervals for He isotope composition. Elevated 3He was verified through mass spectrometry analysis confirming a magmatic connection with the producing system. High CO2 soil gas flux including possibly metamorphic 13C and 14C component was measured over the area of dilatant structures. Hence, the triad of indicators posed above was confirmed in Phase I. Subsequently, Phase II of the project proceeded in the greenfield Kumiva-Blackrock Desert district of northwestern Nevada to see if a new system could be identified. Transect MT data also showed a low-resistivity upwelling originating from interpreted deep crustal magmatic underplating. An MT survey of 131 sites was imaged through 3D inversion using an in-house, DOE-supported finite element algorithm. Low resistivity upwellings that warranted follow up study occur under the flanks of the Seven Troughs Range, under Kumiva Playa immediately west of the Blue Wing Mountains, and under northern Granite Springs Valley. Structural assessment of the project area by Co-I J. Faulds at UNR provided numerous favorable Quaternary fault settings, which were correlated to the MT upwelling structures. Soil CO2 gas flux anomalies generally were not large but did show correlation with resistivity upwelling structure and favorable geological structures. Isotope analyses showed presence of possible inorganic/metamorphic 13C but 14C concentrations did not exceed background values. We view the initial concept of a confluence of low-resistivity upwelling, favorably dilatant 3D geological structure, and elevated soil gas flux including 13C component to be supported by the further evidence of this project although the indicators in the Phase II study were more diffuse. Mass balance calculations based upon 3He R/Ra values indicates that the proportion of magmatic fluids in a producing system is fairly low, 10-15% by volume. We suggest that the diagnostic MT geophysical structures denote zones of concentrated extensional deformation that increases permeability, potentially enabling a circulating upper crustal geothermal system, while at the same time connecting telltale deep component signatures to the upper crust. The northern Granite Springs Valley structure is receiving followup stu

Nevada

Yellowstone Volcano Observatory 2019 annual report

The Yellowstone Volcano Observatory (YVO) monitors volcanic and hydrothermal activity associated with the Yellowstone magmatic system, conducts research into magmatic processes occurring beneath Yellowstone Caldera, and issues timely warnings and guidance related to potential future geologic hazards. This report summarizes the activities and findings of YVO during the year 2019, focusing on the Yellowstone volcanic system. Highlights of YVO research and related activities during 2019 included deploying a portable seismic array near Steamboat Geyser in Norris Geyser Basin that recorded signals from seven major water eruptions; deploying a semipermanent Global Positioning System array; surveying soil carbon dioxide flux and temperature and operating an eddy covariance system to make continuous measurements; collecting and analyzing water samples from Shoshone Geyser Basin, the outlets of Shoshone and Lewis Lakes, Cinder Pool in Norris Geyser Basin, and several locations along Obsidian Creek; exploring and documenting a new thermal area near Tern Lake that was discovered in 2018; measuring specific conductance along major rivers to determine the chloride flux and total heat output of the Yellowstone hydrothermal system; conducting an inventory of hydrothermal features in Norris Geyser Basin and Upper Geyser Basin as part of a park-wide project that began in 2018; and sampling of tree rings and silica sinter deposits in the Upper Geyser Basin to better understand hydrothermal activity over time. Continuing the pattern that started in 2018, Steamboat Geyser, in Norris Geyser Basin, erupted 48 times in 2019—a new record for a calendar year! Overall, however, noteworthy geyser activity in Yellowstone National Park was much reduced relative to the previous year. Thermal features on Geyser Hill in the Upper Geyser Basin had returned to their normal activity styles after Ear Spring’s September 2018 eruption and did not show any significant changes in 2019. Giant Geyser, also in the Upper Geyser Basin, did not experience any eruptions after March 2019. Seismicity was reduced relative to previous years, and deformation of Norris Geyser Basin, which started as uplift in 2015 and paused in late 2018, shifted to subsidence in late 2019. Overall subsidence of the caldera floor, ongoing since late 2015 or early 2016, continued at rates of a few centimeters (1–2 inches) per year.

Wyoming

Ecosystem health in mineralized terrane — Data from podiform chromite (Chinese Camp mining district, California), quartz alunite (Castle Peak and Masonic mining districts, Nevada/California), and Mo/Cu porphyry (Battle Mountain mining district, Nevada) deposits

The myriad definitions of soil/ecosystem quality or health are often driven by ecosystem and management concerns, and they typically focus on the ability of the soil to provide functions relating to biological productivity and/or environmental quality. A variety of attempts have been made to create indices that quantify the complexities of soil quality and provide a means of evaluating the impact of various natural and anthropogenic disturbances. Though not without their limitations, indices can improve our understanding of the controls behind ecosystem processes and allow for the distillation of information to help link scientific and management communities. In terrestrial systems, indices were initially developed and modified for agroecosystems; however, the number of studies implementing such indices in nonagricultural systems is growing. Soil quality indices (SQIs) are typically composed of biological (and sometimes physical and chemical) parameters that attempt to reduce the complexity of a system into a metric of a soil’s ability to carry out one or more functions. The indicators utilized in SQIs can be as varied as the studies themselves, reflecting the complexity of the soil and ecosystems in which they function. Regardless, effective soil quality indicators should correlate well with soil or ecosystem processes, integrate those properties and processes, and be relevant to management practices. Commonly applied biological indicators include measures associated with soil microbial activity or function (for example, carbon and nitrogen mineralization, respiration, microbial biomass, enzyme activity. Cost, accessibility, ease of interpretation, and presence of existing data often dictate indicator selection given the number of available measures. We employed a large number of soil biological, chemical, and physical measures, along with measures of vegetation cover, density, and productivity, in order to test the utility and sensitivity of these measures within various mineralized terranes. We were also interested in examining these relations in the context of determining appropriate reference conditions with which to compare reclamation efforts. The purpose of this report is to present the data used to develop indices of soil and ecosystem quality associated with mineralized terranes (areas enriched in metal-bearing minerals), specifically podiform chromite, quartz alunite, and Mo/Cu porphyry systems. Within each of these mineralized terranes, a nearby unmineralized counterpart was chosen for comparison. The data consist of soil biological, chemical, and physical parameters, along with vegetation measurements for each of the sites described below. Synthesis of these data and index development will be the subject of future publications.

California

Review of revised Klamath River Total Maximum Daily Load models from Link River Dam to Keno Dam, Oregon

Flow and water-quality models are being used to support the development of Total Maximum Daily Load (TMDL) plans for the Klamath River downstream of Upper Klamath Lake (UKL) in south-central Oregon. For riverine reaches, the RMA-2 and RMA-11 models were used, whereas the CE-QUAL-W2 model was used to simulate pooled reaches. The U.S. Geological Survey (USGS) was asked to review the most upstream of these models, from Link River Dam at the outlet of UKL downstream through the first pooled reach of the Klamath River from Lake Ewauna to Keno Dam. Previous versions of these models were reviewed in 2009 by USGS. Since that time, important revisions were made to correct several problems and address other issues. This review documents an assessment of the revised models, with emphasis on the model revisions and any remaining issues. The primary focus of this review is the 19.7-mile Lake Ewauna to Keno Dam reach of the Klamath River that was simulated with the CE-QUAL-W2 model. Water spends far more time in the Lake Ewauna to Keno Dam reach than in the 1-mile Link River reach that connects UKL to the Klamath River, and most of the critical reactions affecting water quality upstream of Keno Dam occur in that pooled reach. This model review includes assessments of years 2000 and 2002 current conditions scenarios, which were used to calibrate the model, as well as a natural conditions scenario that was used as the reference condition for the TMDL and was based on the 2000 flow conditions. The natural conditions scenario included the removal of Keno Dam, restoration of the Keno reef (a shallow spot that was removed when the dam was built), removal of all point-source inputs, and derivation of upstream boundary water-quality inputs from a previously developed UKL TMDL model. This review examined the details of the models, including model algorithms, parameter values, and boundary conditions; the review did not assess the draft Klamath River TMDL or the TMDL allocations. Attention to the details of a model is one of the best ways to identify potential problems, correct them if possible, and begin to assess the magnitude of potential model errors and uncertainty. Model users need to determine the level of acceptable uncertainty associated with their objectives, identify all sources of potential uncertainty (model uncertainty, data uncertainty, etc.), and assess their approach and results accordingly. In the draft Klamath River TMDL, the Oregon Department of Environmental Quality identified the upstream boundary conditions as the largest source of uncertainty for both the current and natural conditions scenarios, not the model algorithms or choice of model parameters. We agree that the upstream boundary conditions are one of the largest, if not the largest, source of model uncertainty; therefore, the derivation of upstream boundary conditions may be more important to the TMDL than some other model-related issues identified in this review. The revised models contain a number of changes, some of which were done to solve small problems and are largely inconsequential to model results, but others of which are important and affect model predictions of instream concentrations. A consistent version of the model is now applied to all scenarios, and an error in the source code was corrected that had inadvertently discarded 20 percent of the incoming solar radiation in the original model. The baseline light-extinction coefficient for water was decreased and set to a consistent and defensible value across all models of reservoir reaches. Inconsistencies among the values of certain parameters in the original models, such as the ammonia nitrification rate and the decomposition rates of organic matter, have been eliminated, although the reasoning behind the final selections was not documented. The dependence of the rate of sediment oxygen demand (SOD) on temperature was modified such that the SOD rate was substantially decreased at temperatures less than 20°C, causing the model to predict higher dissolved oxygen (DO) concentrations in spring, autumn, and winter. Although that change to the temperature dependence function was done to make the function more similar to the model’s default, this change was not accompanied by any documentation of recalibration or sensitivity exercises. The maximum SOD rate for the 2002 current conditions scenario was decreased from 3.0 grams per square meter per day (g/m 2 /d) in the original model to 2.0 g/m 2 /d in the revised model, a considerable adjustment that appears to have been needed to offset effects of a change to another variable (O2LIM) that would have resulted in a substantial increase in the effective SOD rate for 2002. A 50-percent decrease in the SOD rate over a 2-year period, however, is not likely to be mirrored by field measurements, so this change may be compensating for some process that is not represented correctly in the DO budget for the current conditions scenarios. Several important changes were made to the natural conditions scenario. First, the elevation of the Keno reef was corrected; the elevation specified in the original model was 1 foot too high, which affected the volume of the pooled reach and the travel time through it. The most important changes to this scenario were to the upstream boundary inputs of organic matter and algae, which affect incoming fluxes of nitrogen and phosphorus. Algal biomass inputs were increased by approximately 60 percent during summer because of a change in the way those inputs were derived from results of the UKL TMDL model. Non-algal organic matter inputs were decreased, particularly in summer to correct a problem attributed to double-counting of phosphorus in the original inputs. The distribution of non-algal organic matter was changed from 20 percent dissolved in the original model to 90 percent dissolved in the revised model in response to review comments and published data. The overall sum of algal biomass and non-living organic matter was decreased, which resulted in lower inputs of total phosphorus and nitrogen. Total phosphorus inputs were less than 0.03 mg/L, and although the inputs were derived from selected results of the UKL TMDL model, these concentrations seem too low to be representative of a historically eutrophic system surrounded by extensive wetlands, peat soils, and a groundwater system high in phosphorus. The draft TMDL states that the upstream boundary conditions are the greatest source of uncertainty, greater than any uncertainty associated with the models. Efforts to improve existing models of algal growth and nutrient cycling in UKL, therefore, would provide a substantial benefit to downstream modeling efforts on the Klamath River. Although many improvements were made in revising the Klamath River TMDL models, some issues and uncertainties remain. Several errors in the model source code remain, but do not affect model results for this application as long as certain options and rates are not changed; future users of these models should be aware of these issues. Although the distribution of dissolved and particulate organic matter was modified for the natural conditions scenario, that distribution was not changed for the current conditions scenarios. Recent data on that distribution and the likely rates of organic matter decomposition could be used to improve these models in the future. Nitrate predictions at Keno (Highway 66) still are too high for the current conditions scenarios; future efforts should re-evaluate the model’s denitrification rates and the release rate of ammonia from anoxic sediments. Possibly the most important of the remaining issues are tied to the two-state (healthy/unhealthy) hypothesis for the algae population that was coded into the model. Some of the rates and conversion functions could be refined to make them more acceptable; currently, the published literature does not support the concept of moderately low dissolved-oxygen concentrations as a stressor of algae in the ranges used by the model. More research is needed before these algorithms can be truly tested. The algorithms currently appear to help the model fit the patterns in the available data, and that is useful and perhaps sufficient for some purposes, but those algorithms are not truly predictive or reliable for certain purposes until they can be tested through well-designed experiments and research. In summary, the TMDL models used to simulate Link and Klamath Rivers from Link River Dam to Keno Dam were revised to fix several problems and address various issues. The resulting models are an improvement over those that were reviewed by USGS in 2009, and represent a useful advance in the simulation of a complex system that is difficult to model. However, several issues remain that cause increased uncertainty in the model results. Depending on the objectives of the modeling, now or in the future, these remaining issues could be more or less important. For the Klamath River TMDL, the upstream boundary conditions may be a larger source of uncertainty than the concerns with model algorithms and model parameters identified in this review. Efforts to re-evaluate the available models of algal growth and nutrient cycling in UKL would be highly beneficial to downstream modeling efforts in the Klamath River.

Oregon;California

Precipitation-runoff relations and water-quality characteristics at edge-of-field stations, Discovery Farms and Pioneer Farm, Wisconsin, 2003-8

A cooperative study between the U.S. Geological Survey, the University of Wisconsin (UW)-Madison Discovery Farms program (Discovery Farms), and the UW-Platteville Pioneer Farm program (Pioneer Farm) was developed to identify typical ranges and magnitudes, temporal distributions, and principal factors affecting concentrations and yields of sediment, nutrients, and other selected constituents in runoff from agricultural fields. Hydrologic and water-quality data were collected year-round at 23 edge-of-field monitoring stations on 5 privately owned Discovery Farms and on Pioneer Farm during water years 2003-8. The studied farms represented landscapes, soils, and farming systems typical of livestock farms throughout southern Wisconsin. Each farm employed a variety of soil, nutrient, and water-conservation practices to help minimize sediment and nutrient losses from fields and to improve crop productivity. This report summarizes the precipitation-runoff relations and water-quality characteristics measured in edge-of-field runoff for 26 "farm years" (aggregate years of averaged station data from all 6 farms for varying monitoring periods). A relatively wide range of constituents typically found in agricultural runoff were measured: suspended sediment, phosphorus (total, particulate, dissolved reactive, and total dissolved), and nitrogen (total, nitrate plus nitrite, organic, ammonium, total Kjeldahl and total Kjeldahl-dissolved), chloride, total solids, total suspended solids, total volatile suspended solids, and total dissolved solids. Mean annual precipitation was 32.8 inches for the study period, about 3 percent less than the 30-year mean. Overall mean annual runoff was 2.55 inches per year (about 8 percent of precipitation) and the distribution was nearly equal between periods of frozen ground (54 percent) and unfrozen ground (46 percent). Mean monthly runoff was highest during two periods: February to March and May to June. Ninety percent of annual runoff occurred between January and the end of June. Event mean concentrations of suspended sediment in runoff during unfrozen-ground periods were significantly higher (p<0.05) than those during frozen-ground periods. Mean annual suspended-sediment yields ranged from about 3 to nearly 5,000 pounds per acre (lb/acre), with a mean yield of 667 lb/acre. Ninety percent of suspended sediment was yielded in runoff during unfrozen-ground periods. May and June alone contributed more than 80 percent of the overall yield. Phosphorus concentrations and yields were also affected by the ground conditions at the time of runoff; however, unlike suspended sediment, phosphorus was usually available for transport in runoff regardless of ground condition. Mean annual total-phosphorus yields ranged from 0.03 to 7.0 lb/acre, with a mean yield of about 2.0 lb/acre. Nitrogen in runoff followed similar patterns to phosphorus in that concentrations were highest during unfrozen-ground periods, yields were highest during months of highest runoff, and speciation was affected by the ground conditions at the time of runoff. Mean annual total-nitrogen yields ranged from 0.11 to 19.2 lb/acre, and the mean was 7.2 lb/acre. Mean monthly total-nitrogen yields were strongly correlated with mean monthly total-phosphorus yields (r 2 = 0.92), indicating that the sources of nitrogen and phosphorus in runoff were likely similar. Analysis of runoff, concentration, and yield data on annual, monthly, and seasonal time scales, when combined with precipitation, soil moisture, soil temperature, and on-farm field-activity information, revealed conditions in which runoff was most likely. The analysis also revealed the effects that field conditions and the timing of field-management activities-most notably, manure applications and tillage-had on the quantity and quality of surface runoff from agricultural fields.

Scientific Investigations Report