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U.S. Geological Survey core drilling on the Atlantic shelf

The first broad program of scientific shallow drilling on the U.S. Atlantic continental shelf has delineated rocks of Pleistocene to Late Cretaceous age, including phosphoritic Miocene strata, widespread Eocene carbonate deposits that serve as reflective seismic markers, and several regional unconformities. Two sites, off Maryland and New Jersey, showed light hydrocarbon gases having affinity to mature petroleum. Pore fluid studies showed that relatively fresh to brackish water occurs beneath much of the Atlantic continental shelf, whereas increases in salinity off Georgia and beneath the Florida-Hatteras slope suggest buried evaporitic strata. The sediment cores showed engineering properties that range from good foundation strength to a potential for severe loss of strength through interaction between sediments and man-made structures.

Science

A channel sampling strategy for measurement of mineral modal and chemical composition of drill cores: Application to lower oceanic crustal rocks from IODP Expedition 345 to the Hess Deep rift

We report a new sampling strategy for collecting representative samples of drill core. By splitting the core with a diamond saw into working and archive halves, the saw cuttings constitute a “channel” sample, the best subsample from which to obtain an average mineralogical and geochemical composition of a core. We apply this procedure to sampling core of the lower oceanic crust in the Hess Deep obtained during Expedition 345 of the Integrated Ocean Drilling Program (now International Ocean Discovery Program). Our results show that particles produced by sawing range from sand to clay sizes. Sand- and silt-sized cuttings can be sampled with a spatula, whereas clay-sized particles remained in suspension after 12 h and could be collected only by settling, aided by centrifuge. X-ray diffraction (XRD) analysis and Rietveld refinement show that phyllosilicates were fractionated into the clay-sized fraction. Thus, collection of both the sedimented fraction and the clay-sized suspended fraction (commonly > 15 wt % of the total) is necessary to capture the whole sample. The strong positive correlation between the recovered sample mass (in grams) and length of core cut demonstrates that this sampling protocol was uniform and systematic, with almost 1.4 g sediment produced per centimeter of core cut. We show that major-element concentrations of our channel samples compare favorably with the compositions of billet-sized samples analyzed aboard the JOIDES Resolution , but the results show that individual billet analyses are rarely representative of the whole core recovered. A final test of the validity of our methods comes from the strong positive correlation between the loss on ignition (LOI) values of our channel samples and the H 2 O contents calculated from the modal mineralogy obtained by X-ray diffraction and Rietveld refinement. This sampling procedure shows that grain-sized fractionation modifies both mineralogical and chemical compositions; nevertheless, this channel sampling method is a reliable method of obtaining representative samples of bulk cores. With the ever-increasing precision offered by modern analytical instrumentation, this sampling protocol allows the accuracy of the analytical results to keep pace.

Scientific Drilling

Effect of clay content and mineralogy on frictional sliding behavior of simulated gouges: binary and ternary mixtures of quartz, illite, and montmorillonite

We investigated the frictional sliding behavior of simulated quartz-clay gouges under stress conditions relevant to seismogenic depths. Conventional triaxial compression tests were conducted at 40 MPa effective normal stress on saturated saw cut samples containing binary and ternary mixtures of quartz, montmorillonite, and illite. In all cases, frictional strengths of mixtures fall between the end-members of pure quartz (strongest) and clay (weakest). The overall trend was a decrease in strength with increasing clay content. In the illite/quartz mixture the trend was nearly linear, while in the montmorillonite mixtures a sigmoidal trend with three strength regimes was noted. Microstructural observations were performed on the deformed samples to characterize the geometric attributes of shear localization within the gouge layers. Two micromechanical models were used to analyze the critical clay fractions for the two-regime transitions on the basis of clay porosity and packing of the quartz grains. The transition from regime 1 (high strength) to 2 (intermediate strength) is associated with the shift from a stress-supporting framework of quartz grains to a clay matrix embedded with disperse quartz grains, manifested by the development of P-foliation and reduction in Riedel shear angle. The transition from regime 2 (intermediate strength) to 3 (low strength) is attributed to the development of shear localization in the clay matrix, occurring only when the neighboring layers of quartz grains are separated by a critical clay thickness. Our mixture data relating strength degradation to clay content agree well with strengths of natural shear zone materials obtained from scientific deep drilling projects.

Journal of Geophysical Research B: Solid Earth

Proceedings of the ocean drilling program: New Jersey continental slope and rise

The Scientific Results volumes of the Proceedings of the Ocean Drilling Program contain specialty papers presenting the results of extensive research in various aspects of scientific ocean drilling. The authors of the papers published in this volume have enabled future investigators to gain ready access to the results of their research, and I acknowledge their contributions with thanks. Each paper submitted to a Scientific Results volume undergoes rigorous peer review by at least two specialists in the author's research field. A paper typically goes through at least one revision cycle before being accepted for publication. We seek to maintain a peer-review system comparable to those of the most highly regarded journals in the geological sciences. Each Scientific Results volume has an Editorial Review Board that is responsible for obtaining peer reviews of papers submitted to the volume. This board usually is made up of the two co-chief scientists for the cruise, the ODP staff scientist for the cruise, and one external specialist who is familiar with the geology of the area investigated. In addition, the volume has an ODP staff editor who assists with manuscripts that require English-language attention and who coordinates volume assembly. Scientific Results volumes may also contain short reports of useful data that are not ready for final interpretation. Papers of this type, which may be found together in a section in the back of the volume, are called Data Reports and include no interpretation of results. Data Report papers are read carefully by at least one specialist to make sure they are well organized, comprehensive, and discuss the techniques or procedures thoroughly. To acknowledge the contributions made by this volume's Editorial Review Board, the Board members are designated Editors of the volume and are so listed on the title page. Reviewers of manuscripts for this volume, whose efforts are so essential to the success of the publication, are listed in the front of the book, without attribution to a particular manuscript. On behalf of the Ocean Drilling Program, I extend sincere appreciation to members of the Editorial Review Boards and to the reviewers for giving their generous contribution of time and effort, which ensures that only papers of high scientific quality are published in the Proceedings .

Book

Historical methane hydrate project review

In 1995, U.S. Geological Survey made the first systematic assessment of the volume of natural gas stored in the hydrate accumulations of the United States. That study, along with numerous other studies, has shown that the amount of gas stored as methane hydrates in the world greatly exceeds the volume of known conventional gas resources. However, gas hydrates represent both a scientific and technical challenge and much remains to be learned about their characteristics and occurrence in nature. Methane hydrate research in recent years has mostly focused on: (1) documenting the geologic parameters that control the occurrence and stability of gas hydrates in nature, (2) assessing the volume of natural gas stored within various gas hydrate accumulations, (3) analyzing the production response and characteristics of methane hydrates, (4) identifying and predicting natural and induced environmental and climate impacts of natural gas hydrates, and (5) analyzing the effects of methane hydrate on drilling safety. Methane hydrates are naturally occurring crystalline substances composed of water and gas, in which a solid water-­‐lattice holds gas molecules in a cage-­‐like structure. The gas and water becomes a solid under specific temperature and pressure conditions within the Earth, called the hydrate stability zone. Other factors that control the presence of methane hydrate in nature include the source of the gas included within the hydrates, the physical and chemical controls on the migration of gas with a sedimentary basin containing methane hydrates, the availability of the water also included in the hydrate structure, and the presence of a suitable host sediment or “reservoir”. The geologic controls on the occurrence of gas hydrates have become collectively known as the “methane hydrate petroleum system”, which has become the focus of numerous hydrate research programs. Recognizing the importance of methane hydrate research and the need for a coordinated effort, the U.S. Congress enacted Public Law 106-­‐193, the Methane Hydrate Research and Development Act of 2000. This Act called for the Secretary of Energy to begin a methane hydrate research and development program in consultation with other U.S. federal agencies. At the same time a new methane hydrate research program had been launched in Japan by the Ministry of International Trade and Industry to develop plans for a methane hydrate exploratory drilling project in the Nankai Trough. Since this early start we have seen other countries including India, China, Canada, and the Republic of Korea establish large gas hydrate research and development programs. These national led efforts have also included the investment in a long list of important scientific research drilling expeditions and production test studies that have provided a wealth of information on the occurrence of methane hydrate in nature. The most notable expeditions and projects have including the following: -­‐Ocean Drilling Program Leg 164 (1995) -­‐Japan Nankai Trough Project (1999-­‐2000) -­‐Ocean Drilling Program Leg 204 (2004) -­‐Japan Tokai-­‐oki to Kumano-­‐nada Project (2004) -­‐Gulf of Mexico JIP Leg I (2005) -­‐Integrated Ocean Drilling Program Expedition 311 (2005) -­‐Malaysia Gumusut-­‐Kakap Project (2006) -­‐India NGHP Expedition 01 (2006) -­‐China GMGS Expedition 01 (2007) -­‐Republic of Korea UBGH Expedition 01 (2007) -­‐Gulf of Mexico JIP Leg II (2009) -­‐Republic of Korea UBGH Expedition 02 (2010) -­‐MH-­‐21 Nankai Trough Pre-­‐Production Expedition (2012-­‐2013) -­‐Mallik Gas Hydrate Testing Projects (1998/2002/2007-­‐2008) -­‐Alaska Mount Elbert Stratigraphic Test Well (2007) -­‐Alaska Iġnik Sikumi Methane Hydrate Production Test Well (2011-­‐2012) Research coring and seismic programs carried out by the Ocean Drilling Program (ODP) and Integrated Ocean Drilling Program (IODP), starting with the ODP Leg 164 drilling of the Blake Ridge in the Atlantic Ocean in 1995, have also contributed greatly to our understanding of the geologic controls on the formation, occurrence, and stability of gas hydrates in marine environments. For the most part methane hydrate research expeditions carried out by the ODP and IODP provided the foundation for our scientific understanding of gas hydrates. The methane hydrate research efforts under ODP-­‐IODP have mostly dealt with the assessment of the geologic controls on the occurrence of gas hydrate, with a specific goal to study the role methane hydrates may play in the global carbon cycle. Over the last 10 years, national led methane hydrate research programs, along with industry interest have led to the development and execution of major methane hydrate production field test programs. Two of the most important production field testing programs have been conducted at the Mallik site in the Mackenzie River Delta of Canada and in the Eileen methane hydrate accumulation on the North Slope of Alaska. Most recently we have also seen the completion of the world’s first marine methane hydrate production test in the Nankai Trough in the offshore of Japan. Industry interest in gas hydrates has also included important projects that have dealt with the assessment of geologic hazards associated with the presence of hydrates. The scientific drilling and associated coring, logging, and borehole monitoring technologies developed in the long list of methane hydrate related field studies are one of the most important developments and contributions associated with methane hydrate research and development activities. Methane hydrate drilling has been conducted from advanced scientific drilling platforms like the JOIDES Resolution and the D/V Chikyu, which feature highly advanced integrated core laboratories and borehole logging capabilities. Hydrate research drilling has also included the use of a wide array of industry, geotechnical and multi-­‐service ships. All of which have been effectively used to collect invaluable geologic and engineering data on the occurrence of methane hydrates throughout the world. Technologies designed specifically for the collection and analysis of undisturbed methane hydrate samples have included the development of a host of pressure core systems and associated specialty laboratory apparatus. The study and use of both wireline conveyed and logging-­‐while-­‐drilling technologies have also contributed greatly to our understanding of the in-­‐situ nature of hydrate-­‐bearing sediments. Recent developments in borehole instrumentation specifically designed to monitor changes associated with hydrates in nature through time or to evaluate the response of hydrate accumulations to production have also contributed greatly to our understanding of the complex nature and evolution of methane hydrate systems. Our understanding of how methane hydrates occur and behave in nature is still growing and evolving – we do not yet know if methane hydrates can be economically produced, nor do we know fully the role of hydrates as an agent of climate change or as a geologic hazard. But it is known for certain that scientific drilling has contributed greatly to our understanding of hydrates in nature and will continue to be a critical source of the information to advance our understanding of methane hydrates.

Report

Scientific results of the Second Gas Hydrate Drilling Expedition in the Ulleung Basin (UBGH2)

As a part of Korean National Gas Hydrate Program, the Second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2) was conducted from 9 July to 30 September, 2010 in the Ulleung Basin, East Sea, offshore Korea using the D/V Fugro Synergy. The UBGH2 was performed to understand the distribution of gas hydrates as required for a resource assessment and to find potential candidate sites suitable for a future offshore production test, especially targeting gas hydrate-bearing sand bodies in the basin. The UBGH2 sites were distributed across most of the basin and were selected to target mainly sand-rich turbidite deposits. The 84-day long expedition consisted of two phases. The first phase included logging-while-drilling/measurements-while-drilling (LWD/MWD) operations at 13 sites. During the second phase, sediment cores were collected from 18 holes at 10 of the 13 LWD/MWD sites. Wireline logging (WL) and vertical seismic profile (VSP) data were also acquired after coring operations at two of these 10 sites. In addition, seafloor visual observation, methane sensing, as well as push-coring and sampling using a Remotely Operated Vehicle (ROV) were conducted during both phases of the expedition. Recovered gas hydrates occurred either as pore-filling medium associated with discrete turbidite sand layers, or as fracture-filling veins and nodules in muddy sediments. Gas analyses indicated that the methane within the sampled gas hydrates is primarily of biogenic origin. This paper provides a summary of the operational and scientific results of the UBGH2 expedition as described in 24 papers that make up this special issue of the Journal of Marine and Petroleum Geology.

East Sea Of Korea;Ulleung Basin

Trans-Amazon Drilling Project (TADP): origins and evolution of the forests, climate, and hydrology of the South American tropics

This article presents the scientific rationale for an ambitious ICDP drilling project to continuously sample Late Cretaceous to modern sediment in four different sedimentary basins that transect the equatorial Amazon of Brazil, from the Andean foreland to the Atlantic Ocean. The goals of this project are to document the evolution of plant biodiversity in the Amazon forests and to relate biotic diversification to changes in the physical environment, including climate, tectonism, and the surface landscape. These goals require long sedimentary records from each of the major sedimentary basins across the heart of the Brazilian Amazon, which can only be obtained by drilling because of the scarcity of Cenozoic outcrops. The proposed drilling will provide the first long, nearly continuous regional records of the Cenozoic history of the forests, their plant diversity, and the associated changes in climate and environment. It also will address fundamental questions about landscape evolution, including the history of Andean uplift and erosion as recorded in Andean foreland basins and the development of west-to-east hydrologic continuity between the Andes, the Amazon lowlands, and the equatorial Atlantic. Because many modern rivers of the Amazon basin flow along the major axes of the old sedimentary basins, we plan to locate drill sites on the margin of large rivers and to access the targeted drill sites by navigation along these rivers.

Amazon region

Drilling the central crater of the Chesapeake Bay Impact Structure: A first look

The late Eocene Chesapeake Bay impact structure is a well‐preserved example of one of Earth's largest impact craters, and its continental‐shelf setting and relatively shallow burial make it an excellent target for study. Since the discovery of the structure over a decade ago [ Edwards et al., 2004; Poag et al., 2004], test drilling by U.S. federal and state agencies has been limited to the structure's annular trough (Figure 1). In May 2004, the U.S. Geological Survey (USGS) drilled the first scientific test hole into the central crater of the Chesapeake Bay impact structure in Cape Charies,Virginia (Figure 1). This partially cored test hole, the deepest to date, penetrated postimpact sediments and impact breccias to a total depth of 823 m.

Chesapeake Bay

Scientific objectives of the Gulf of Mexico gas hydrate JIP leg II drilling

The Gulf of Mexico Methane Hydrate Joint Industry Project (JIP) has been performing research on marine gas hydrates since 2001 and is sponsored by both the JIP members and the U.S. Department of Energy. In 2005, the JIP drilled the Atwater Valley and Keathley Canyon exploration blocks in the Gulf of Mexico to acquire downhole logs and recover cores in silt- and clay-dominated sediments interpreted to contain gas hydrate based on analysis of existing 3-D seismic data prior to drilling. The new 2007-2009 phase of logging and coring, which is described in this paper, will concentrate on gas hydrate-bearing sands in the Alaminos Canyon, Green Canyon, and Walker Ridge protraction areas. Locations were selected to target higher permeability, coarser-grained lithologies (e.g., sands) that have the potential for hosting high saturations of gas hydrate and to assist the U.S. Minerals Management Service with its assessment of gas hydrate resources in the Gulf of Mexico. This paper discusses the scientific objectives for drilling during the upcoming campaign and presents the results from analyzing existing seismic and well log data as part of the site selection process. Alaminos Canyon 818 has the most complete data set of the selected blocks, with both seismic data and comprehensive downhole log data consistent with the occurrence of gas hydrate-bearing sands. Preliminary analyses suggest that the Frio sandstone just above the base of the gas hydrate stability zone may have up to 80% of the available sediment pore space occupied by gas hydrate. The proposed sites in the Green Canyon and Walker Ridge areas are also interpreted to have gas hydrate-bearing sands near the base of the gas hydrate stability zone, but the choice of specific drill sites is not yet complete. The Green Canyon site coincides with a 4-way closure within a Pleistocene sand unit in an area of strong gas flux just south of the Sigsbee Escarpment. The Walker Ridge site is characterized by a sand-prone sedimentary section that rises stratigraphically across the base of the gas hydrate stability zone and that has seismic indicators of gas hydrate.

Conference Paper

Gas geochemistry of the Valles caldera region, New Mexico and comparisons with gases at Yellowstone, Long Valley and other geothermal systems

Noncondensible gases from hot springs, fumaroles, and deep wells within the Valles caldera geothermal system (210-300??C) consist of roughly 98.5 mo1% CO2, 0.5 mol% H2S, and 1 mol% other components. 3He/4He ratios indicate a deep magmatic source (R/Ra up to 6) whereas ??13C-CO2 values (-3 to -5???) do not discriminate between a mantle/magmatic source and a source from subjacent, hydrothermally altered Paleozoic carbonate rocks. Regional gases from sites within a 50-km radius beyond Valles caldera are relatively enriched in CO2 and He, but depleted in H2S compared to Valles gases. Regional gases have R/Ra values ???1.2 due to more interaction with the crust and/or less contribution from the mantle. Carbon sources for regional CO2 are varied. During 1982-1998, repeat analyses of gases from intracaldera sites at Sulphur Springs showed relatively constant CH4, H2, and H2S contents. The only exception was gas from Footbath Spring (1987-1993), which experienced increases in these three components during drilling and testing of scientific wells VC-2a and VC-2b. Present-day Valles gases contain substantially less N2 than fluid inclusion gases trapped in deep, early-stage, post-caldera vein minerals. This suggests that the long-lived Valles hydrothermal system (ca. 1 Myr) has depleted subsurface Paleozoic sedimentary rocks of nitrogen. When compared with gases from many other geothermal systems, Valles caldera gases are relatively enriched in He but depleted in CH4, N2 and Ar. In this respect, Valles gases resemble end-member hydrothermal and magmatic gases discharged at hot spots (Galapagos, Kilauea, and Yellowstone). Published by Elsevier Science B.V.

Journal of Volcanology and Geothermal Research