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Critical mineral inventory of select IOA-IOCG deposits, southwestern USA

Critical minerals are necessary for modern technology and strategic purposes. Their increasing importance requires finding new and nontraditional resources. Samples of ore, altered, and unaltered host rock were collected from 26 iron mines and prospects in California, Nevada, and Utah to assess the potential of these deposits to host economic quantities of different critical minerals. Geochemical analyses were conducted by 61 element ICP-OES-MS sodium peroxide fusion and major elements determined by WDXRF. These deposits concentrated many critical minerals beyond what is found in average upper crustal abundances, such as Sb, As, Bi, Co, Ga, Mg, Mn, Ni, Nb, Pd, REE, Sc, Te, Sn, Ti, W, V, and Zn. However, most of these are not concentrated enough in the ore to be considered as economic resources. Those critical minerals that are enriched enough in some of these deposits to possibly be considered as by-product commodities are Ni, REE, V, and potentially Co and Ga. These enrichments were not uniform, with REE more likely to be enriched in IOA deposits, whereas Co, Ga, Ni, and V could be found enriched in either IOA or IOCG deposits.

California, Nevada, Utah

From critical minerals to food security, the benefits of data collaboration

The volume of data in the public geoscience sphere is rapidly and continually expanding. At Geoscience Australia (GA) we saw an over 500% increase in data points within our relational databases between 2018 and 2024, over the life of the Exploring for the Future (EFTF) program. With the Resourcing Australia’s Prosperity initiative, a continued increase in data quantity will be seen for the next 10 to 35 years. At the same time, a broadening audience for geoscience data is increasing the desire to enhance the diversity of delivery streams. This ranges from data-dense highly technical outputs for geoscience specialists to curated interpretive products for people who are non-geoscientists. Development of these curated outputs has contributed to our awareness of the need for data to be collected and compiled in a way that ensures its reuse, with a focus on quality metadata and data provenance.

Conference Paper

Subaerially exposed Iceberg Lake sediments: An exceptional record of historical subaqueous earthquake disturbance at the eastern edge of the Alaskan-Aleutian subduction zone

Paleoseismic records are limited in the Yakutat Terrane (eastern edge of the Alaskan-Aleutian subduction zone) due to the extensive ice cover that hinders traditional methods such as trenching of the faults, but lacustrine sediments offer an alternative archive. We investigated lakebed sediments exposed after recent outburst floods (1999 CE) at Iceberg Lake, a glacier-dammed basin whose stratigraphy was revealed after the lake drained and partially eroded. We logged outcrops across the basin and sampled their sediments. Between annually laminated background deposits, we identified sediment gravity flow beds and in-situ soft-sediment deformation structures (convolutions, sand blows, and fractures) interpreted to be earthquake-induced. Our age model links some of the uppermost depositional and deformational events to the 1958, 1964 and 1979 CE earthquakes. These results demonstrate that Iceberg Lake was a sensitive recorder of seismic shaking and its sediments hold strong potential for producing a paleoseismic record for the northern Yakutat Terrane.

Alaska

Mine waste as a potential source of critical minerals and other commodities: Examples from the Four Corners states, USA

The growing demand for critical minerals and other mineral resources has raised concerns about possible supplies of these essential commodities. Mine waste is a potential source of these essential commodities. We compiled a geospatial database of publicly available data of the largest non-fuel mine waste features (>200,000 m 2 in areal extent) in the Four Corners states of the United States, where most of those features are from porphyry Cu deposits. The combined volume of those large porphyry Cu mine waste features is approximately 17 cubic kilometers, 60% of which is ore-related material such as tailings. Using publicly available data on density, grade, and previous recovery values, we estimate the contained endowments of Ag, As, Au, Bi, Cu, Mo, Re, S, Sb, Se, Te, and W. These estimates indicate endowments within ore-related mine wastes are collectively comparable to endowments of giant to supergiant deposits. If fully recovered, these commodities could meet current global demand from less than 1 year (Sb) to more than 200 years (Re), underscoring the enormous untapped resource potential of mine waste.

Arizona, Colorado, New Mexico, Utah

Stable isotope composition and geochemistry of calcite and dolomite in the Mountain Pass carbonatite: A lens into petrogenesis

Carbonatites host most of the global rare earth element (REE) deposits. The petrogenesis of these rocks, including magmatic and post-magmatic processes, are poorly understood but critical in forming and upgrading these deposits. The Mountain Pass carbonatite, which hosts the only active REE mine in North America, is lithologically variable but consistently contains >50% calcite and/or dolomite. Multiple generations of carbonates are evident, suggesting bulk analysis of carbonate minerals would generate a mixed isotopic and geochemical signature. In-situ stable carbon and oxygen isotopes, combined with geochemical analysis and petrography, distinguish carbonate generations, trace the source region of the carbonatite magma, and link carbonate genesis to REE mineralization throughout the intrusion. Primary carbon and oxygen isotope values outside the accepted mantle range may suggest a subduction-related carbon and oxygen source in the mantle. Deformation textures in primary calcite indicate syn- or post-crystallization ductile flow. Carbonates with secondary textures and heavy δ 13 C and δ 18 O values are associated with ore mineralization, suggesting fluid mobilization was important in concentrating REE and upgrading of the Mountain Pass deposit.

California

Utilizing downhole datasets for modelling the aeromagnetic signature of the Iron Creek Co-Cu deposit in the Idaho Cobalt Belt

The Idaho Cobalt Belt in east-central Idaho is host to some of the largest domestic Co resources, including the informal Iron Creek deposit. The two main ore zones of this deposit, the Iron Creek and the Ruby, are hosted in greenschist-grade interbedded argillite/siltstone and quartz-rich units of the Mesoproterozoic Apple Creek Formation of Lemhi Group. The primary ore mineral is cobalt-bearing pyrite, which occurs with pyrrhotite, chalcopyrite, and magnetite. This study integrates mineralogical and core-scale geophysical measurements with regional-scale aeromagnetic surveys. The high magnetite content within the Ruby zone produces elevated magnetic susceptibility, but the relatively limited spatial footprint of the ore zone would produce a small-scale anomaly that may be overlooked in regional surveys. The low magnetite content in the Iron Creek zone results in low magnetic susceptibility, creating a relatively low amplitude geophysical response. By characterizing the magnetic properties and mineralogy of these ore zones, this study enhances the interpretation of aeromagnetic data, enabling the identification of small or faint anomalies as potential Co targets. These findings improve can improve exploration strategies, both within the Idaho Cobalt Belt as well as for similar deposit types globally.

Idaho

Synergy between geology and geophysics in graphite mineral resource assessment

Graphite is designated as a critical mineral by the U.S. Government due to its essential role in modern technology and its vulnerability to supply chain disruption. To evaluate domestic graphite resources, the U.S. Geological Survey (USGS) conducted two airborne electromagnetic (AEM) surveys as part of the Earth Mapping Resources Initiative (Earth MRI) over prospective areas in the southern Appalachians of Alabama and the Seward Peninsula of Alaska. These surveys aimed to refine areas of interest by revealing subsurface electrical resistivity patterns indicative of graphite-bearing rocks. The results of the AEM surveys were integrated with existing geological knowledge and supplemented by field observations to assess the likelihood of undiscovered resources in these regions. This multidisciplinary approach combined geophysical techniques with traditional geological methods, enhancing the understanding of graphite potential in areas that may have been previously overlooked. The findings from this initiative are expected to contribute significantly to the ongoing efforts to secure a reliable domestic supply of graphite, thereby reducing import reliance and supporting national interests in mineral resource management.

Conference Paper

Preventing overfitting when using tree-based methods for mapping hydrothermal favorability

Ensemble tree-based algorithms are robust tools for estimating sparsely distributed resources with non-linear dependencies (e.g., hydrothermal systems). These algorithms naturally accommodate the threshold conditions necessary to enable and support hydrothermal systems (e.g., having sufficient heat and permeability) and are simpler than many other non-linear machine learning strategies (e.g., artificial neural networks), which is an advantage when working with few labeled examples from which to learn. In previous work, we used eXtreme Gradient Boosting (XGBoost) to produce regional prediction and uncertainty maps of hydrothermal favorability; however, recent studies suggest that, even when properly applied, XGBoost has some risk of overfitting when there are few labeled examples from which to learn. To evaluate overfitting when constructing hydrothermal favorability maps with tree-based methods, we compare XGBoost with Extremely Randomized Trees (ExtraTrees), another ensemble tree-based algorithm that has the potential to underfit when using few labeled examples. We hold all other modeling parameters constant, resulting in two contrasting favorability maps of conventional geothermal resources for the Great Basin. Our results indicate that ExtraTrees demonstrably reduces overfitting compared with XGBoost. After considering overall performance, we conclude that ExtraTrees provides a more suitable modeling approach than XGBoost for the purposes of conventional hydrothermal resource assessments.

Conference Paper

Origin of the high Pd/Pt ratio of the J-M Reef, Stillwater Complex Montana USA

The J-M Reef of the Stillwater Complex exhibits a high and consistent Pd/Pt ratio (~3.8). This ratio results from the equilibration of an immiscible sulfide liquid with a relatively high Pd/Pt silicate melt rather than an unusually Pd- and Pt-enriched parental melt. Numerical modeling suggests that the original silicate melt contained typical mantle-derived concentrations of Pd and Pt (~10–20 ppb Pd/Pt ~1). The partitioning of Pt and Pd between sulfide liquid and silicate melt alone cannot explain the consistently high Pd/Pt ratio across variable melt-to-sulfide mass ratios (R factors). Instead Pt-depletion caused by the early fractionation of Pt-alloy from S-undersaturated silicate magma likely established the high Pd/Pt signature. High Pd/Pt ratios can form through batch equilibration of sulfide liquid with silicate melt if partition coefficients are extremely high (>10⁶). Alternatively Pd enrichment may result from sulfide upgrading within the resident footwall mush under smaller partition coefficients (10⁴–10⁶) in this model the instantaneous R factors remain low (R ≈ 100–700). This limits the impact of Pt and Pd partitioning on sulfide composition and helps explain the Pd-enriched character of the J-M Reef.

Montana

Deformation mechanisms in quartz veins and shear zones elucidate the origin of gold mineralization at Pogo, Alaska

Pogo is a quartz vein hosted, ca. 8 Moz gold deposit. Although it has similarities to orogenic and magmatic-hydrothermal deposits, its origin remains enigmatic. Observations from surface exposures, underground workings, and drill core provide new constraints on quartz vein origins with implications for mineralization. Abundant, largely barren metamorphic segregation quartz veins are found throughout interior Alaska and share characteristics with mineralized quartz veins at Pogo. Pogo quartz veins show crystal plastic deformation fabrics consistent with greenschist to amphibolite facies metamorphism and a lack of internal shear. In contrast, gold in Pogo quartz veins occurs in brittle microfaults and fractures with sulphides such as arsenopyrite and pyrrhotite. Major and minor cataclastic shear zones also exist at Pogo. Cataclastic shear zones commonly cut the mineralized quartz veins and porphyroclasts are dominated by quartz with the same plastic deformation fabrics found in the major Pogo quartz veins. The porphyroclasts, and the carbonaceous clay-rich matrix they sit in, also contain gold indicating that the shear zones postdate quartz and earliest gold deposition. These observations suggest that competency contrasts between the quartz veins and their phyllosilicate-rich host rocks controlled transient permeability formed by late, preferential brittle deformation events localizing sulphide ± gold deposition.

Alaska

Comparing magmatism and hydrothermal alteration using magnetic modelling and stable isotopes at the Clementine porphyry copper prospect, Montana, USA

Recent mapping of the underexplored Clementine prospect in southwestern Montana has revealed evidence of hydrothermal alteration and mineralized breccia vein gossan interpreted to represent the upper expression of a Cretaceous, sediment-hosted copper porphyry system. The prospect is at the nexus of several Cretaceous granites, including the pre-mineralization Butte Granite and Big Hole Canyon plutons and local pre- to post-mineralization granite intrusions. Here, 3D magnetic inversions and stable isotope data are used to evaluate the spatial and genetic relationship of mineralization and Cretaceous magmatism. Magnetic inversions reveal a zone of high magnetic susceptibility beneath the prospect that is related to an exposure of unaltered, likely post-mineralization granite. The granite appears to connect to the Big Hole Canyon pluton at depth, suggesting it is a late-stage differentiate of the cooling, pre-mineralization pluton that may have been one of several potential heat sources for the mineral system at Clementine. This is supported by carbon isotope values of graphite that indicate organic material in shale of the Cretaceous Kootenai Formation was subject to metamorphism. Preliminary light hydrogen isotope values of actinolite hydrothermal orbs suggest formation following magmatic outgassing during thermal advection from an underlying intrusion.

Montana

Paleoproterozoic vein graphite mineralization caused by decarbonation in the Ruby Range, Montana, USA

Hydrothermal graphite veins are a possible source for modern battery materials and require better understanding of their carbon source(s) and absolute timing to develop mapable criteria for exploration models. We present new observations of graphite vein and alteration paragenesis and U-Pb LA-ICP-MS titanite age data from the Ruby prospect, Montana, USA, that constrain mineralization timing and source. The graphite veins cut high-temperature metamorphic rocks of the lower Christensen Range suite and are associated with intense diopside (Di0.69Hd0.27Jo0.04) alteration of marble. The oldest titanite ages in fresh marble and partially altered calc-silicate gneiss are ca. 2,500 – 2,450 Ma, show elevated REE values, and Eu/Eu* <1.5, consistent with growth during early regional metamorphism. Titanite in diopside-graphite alteration, interpreted as part of the hydrothermal vein-forming episode, cluster around 1,750 Ma, are characterized by lower REE values, and show Eu/Eu* >2; suggesting a low fO 2 fluid generated from metamorphism during the Big Sky orogeny. Our paragenetic observations and titanite ages indicate graphite vein formation via skarnoid decarbonation reactions in marble late in regional orogenesis. Granulite-facies, carbonate-bearing, supracrustal rock terranes are thus favorable for hydrothermal graphite vein deposits.

Montana

Summary of results from monitoring the Geysers with continuous passive seismic and repeat magnetotelluric measurements (2021-2023)

Understanding temporal variations in a geothermal field can support operators in decision making that pertains to optimizing production and mitigating hazards. Between 2021 and 2023, The Geysers geothermal field in northern California was monitored with an array of continuous passive seismic sensors and annual repeat magnetotelluric (MT) measurements. Each of these data sets were analyzed and modelled separately to understand the data, sensitivity, and any observable changes. Then, the data were inverted jointly using a crossgradient method to further constrain temporal changes in geophysical properties within the geothermal field. Multiple permutations of annual datasets were used as inputs to the joint inversion. Results demonstrate seismic data constrain smooth inversion of the MT data, and the MT data provide supplementary information about the location of temporal fluid changes. Estimating relative changes in steam saturation for various time intervals of the joint models shows compartmentalized changes in the field, and good spatial correlation with the location of injection wells. These results demonstrate that collecting both passive seismic and MT measurements then modeling them jointly provide complementary information and a relatively inexpensive method for monitoring temporal changes in an active geothermal field that provides results to support operators.

California

Fingerprinting magmatic REE deposit sources with zircon petrochronology

Carbonatites and associated alkaline silicate rocks are of considerable economic interest due to their enrichments in rare earth elements. The petrogenesis and source(s) of these complexes, however, are poorly understood. Models propose either mantle plume-derived carbon-rich melts or a mantle source enriched by subduction-related metasomatism. We use zircon trace elements to fingerprint carbonatite-alkaline complex sources, focusing on the economically significant 1.4 Ga Mountain Pass intrusive suite (MPIS). Autocrystic zircon from MPIS alkaline silicate rocks are enriched in Th and U relative to Nb suggesting a subduction influenced, oxidized source region. Lower Sc/Yb, higher Ti concentrations, and the absence of Eu anomalies in autocrystic zircon suggest derivation from a less hydrous, hotter, and deeper mantle source relative to arc-related 1.8–1.6 Ga inherited zircon. These data are best explained by syn- to post-collisional Mesoproterozoic reactivation of a subduction-metasomatized mantle source. The source and tectonic setting of the MPIS contrasts with Mesoproterozoic Gifford Creek and Bayan Obo carbonatites which exhibit plume-like compositions and are associated with rifts, suggesting different sources and tectonic settings for these economically significant deposits. We demonstrate that zircon petrochronology is a robust method for distinguishing carbonatite sources and can inform more targeted exploration strategies for critical mineral resources.

Conference Paper

USGS addresses needs for lithium calibration and quality control materials for pLIBS analysis

Lithium (Li) is a globally important commodity used for energy storage, national defense, human health, and advanced technologies. Lithium resource development requires identifying deposits with elevated concentrations and optimal mineralogy, typically associated with select clays and pegmatites. Lithium is a light, highly reactive alkali metal with low atomic mass that is difficult to detect and quantify using conventional portable geochemical techniques such as X-ray fluorescence (XRF). However, portable laser-induced breakdown spectroscopy (pLIBS) is a powerful analytical technique for lithium exploration due to its ability to analyze solids quickly with minimal preparation. The expanded utility of pLIBS is hampered by the lack of matrix-matched calibration and quality control (QC) materials. The United States Geological Survey (USGS) has developed in-house lithium calibration and QC materials for lithium in clay and pegmatite matrices to address this limitation. We present the workflow and implementation of a custom-built matrix specific calibration on a SciAps Z-300 pLIBS, using proprietary Profile Builder software. The implementation of the custom calibration and quality control standards enables us to collect semiquantitative results directly from the pLIBS while in the field. Ultimately, this calibration has improved confidence in sample selection and collection in the field, providing more efficient site characterization.

Conference Paper

The new self-anchored suspension (SAS) San Francisco Bay Bridge- Its response to a small earthquake

This paper presents a summary of previously published work (Celebi 2023) related to the new Self-Anchored Suspension (SAS) bridge that went into service within the last decade as a replacement for the older truss bridge spanning between Yerba Buena Island and Oakland, California, within the San Francisco Bay Area. During the October 19, 1989 M6.9 Loma Prieta earthquake, which occurred ~100 km south of the Bay Bridge, a section of the upper deck of the truss bridge fell onto the lower deck – thus closing this important lifeline between San Francisco and Oakland. The SAS is unique, self-anchored, and suspended by a single tower that is pivotal in trafficking the cable and hanger system to support the decks. The SAS bridge is extensively instrumented by the California Geological Survey’s Strong Motion Instrumentation Program (CSMIP). There are approximately 85 channels of accelerometers in the seismic monitoring system that recorded the October 14, 2019 Mw4.6 Pleasant Hill earthquake. The data allow a complex but identifiable coupled response of the deck, tower, and cable system. Both acceleration and displacement time-history data are used to extract significant frequencies using system identification methods, including spectral analyses. Results are compared to those from finite-element-model (FEM) analyses carried out during the design and analysis process of the bridge in 2002 (Nader et al. 2002). There are differences between FEM analyses results and those from the low amplitude shaking caused by a seismic event. An apparent frequency (period) of the SAS bridge is assessed (approximately 5.2 seconds). In a plot of deck length versus period, there is an almost linear relationship with periods of other regular suspension bridges, such as the Golden Gate Bridge and the Carquinez Bridge, both in the San Francisco Bay.

California

New developments at the Center for Engineering Strong-Motion Data (CESMD)

The Center for Engineering Strong-Motion Data (CESMD), an internationally utilized joint center of the U.S. Geological Survey (USGS) and the California Geological Survey (CGS), provides a single access point for earthquake strong-motion records and station metadata from the CGS California Strong-Motion Instrumentation Program (CSMIP), the USGS National Strong-Motion Project (NSMP), the USGS Advanced National Seismic System, and other affiliates. The CESMD has been continuously improving its webtools to facilitate the access of strong-motion data and metadata for use in post-earthquake response and for scientific and engineering research applications. The Center provides raw and processed strong-motion data via the Engineering Data Center (EDC) and the Virtual Data Center (VDC) web portals. This paper focuses on the strong-motion products provided by the EDC where more than 48,000 records with peak ground accelerations greater than 0.1% g from over 2400 earthquakes are currently hosted. and on the ongoing efforts to develop data access tools and applications. The new developments and ongoing efforts in the EDC include: 1) enhancements to the CESMD webservices to facilitate access to station metadata, earthquake information, and strong motion records 2) new features to the interactive map interface, improving the visualization and access to earthquake, station, and record information, 3) efforts to develop a new web application tool for data format conversion from a number of data formats, 4) efforts to unify varying waveform data formats into a consistent format, 5) ongoing efforts to compile seismic station site geology, measured or inferred Vs30 values, shear-wave profiles, NEHRP site class, and available structural instrument deployment schematics, and 6) a special studies pages for research topic-specific ground motion datasets that offer uniform processing of records from a variety of sources.

Conference Paper

Combining scanning electron microscopy, X-ray diffraction, and X-ray fluorescence to characterize shear zones at the Pogo gold deposit, Alaska

This study employs a multi-method analytical approach to characterize the mineralogical, geochemical, and textural properties of fault rocks from the Pogo gold mine in the Yukon-Tanana Upland, central Alaska. Specifically, we examine cataclasites, to document the structural and geochemical evolution of shear zones and their associations with gold mineralization. To investigate the shear zone, we integrate portable X-ray fluorescence (pXRF), scanning electron microscopy-based automated mineralogy (SEM-AM), X-ray diffraction (XRD), and high-resolution micro-X-ray fluorescence (micro-XRF) mapping. These methods collectively provide insights into bulk and trace element chemistry, mineralogical composition, and deformation-related textures across multiple scales. Handheld pXRF enables rapid geochemical screening, guiding SEM-AM and XRD analyses to ensure consistent mineralogical interpretation. X-ray diffraction identifies and quantifies crystalline phases, while SEM-AM produces high-resolution mineral maps, revealing mineral abundances, grain-scale textures, and gold associations. Micro-XRF mapping further refines our understanding by showing visual trace element distributions at sub-millimetre resolution. By integrating these techniques, we improve our understanding of the nature and geochemistry of Pogo shear zones, their role in gold mineralization, and support metallurgical processing strategies. This approach enhances exploration models and resource characterization for structurally complex gold deposits.

Alaska