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At least 91 records · Page 5Linked to original sources

Embryotoxic effects of benzo[a]pyrene, chrysene and 7,12-dimethylbenz[a]-anthracene in petroleum hydrocarbon mixtures in mallard ducks

Studies with different avian species have revealed that surface applications of microliter amounts of some crude and fuel oils that coat less than 70% of the egg surface result in considerable reduction in hatching with teratogenicity and stunted growth. Other stUdies have shown that the embryo toxicity is dependent on the aromatic hydrocarbon content, further suggesting that the toxicity is due to causes other than asphyxia. In the present study the effects of three polycyclic aromatic hydrocarbons identified in petroleum were examined on mallard (Anas platyrhynchos) embryo development. Addition of benzo[a]pyrene (BaP), chrysene, or 7,7 2-dimethylbenz[ a]anthracene (DMBA) to a synthetic petroleum hydrocarbon mixture of known composition and relatively low embryotoxicity resulted in embryo toxicity that was enhanced or equal to that of crude oil when 10 :I was applied externally to eggs at 72 h of development. The order of ability to enhance embryo toxicity was DMBA > BaP > chrysene. The temporal pattern of embryonic death was similar to that reported after exposure to crude oil, with additional mortality occurring after outgrowth of the chorioallantois. Retarded growth, as reflected by embryonic body weight, crown-rump length, and bill length, was accompanied by teratogenicity. Abnormal embryos exhibited extreme stunting; eye, brain, and bill defects; and incomplete ossification. Gas chromatographic-mass spectral analysis of externally treated eggs showed the passage of aromatic hydrocarbons including chrysene through the shell and shell membranes to the developing embryos. These findings suggest that the presence of polycyclic aromatic hydrocarbons in petroleum, including BaP, chrysene, and DMBA, significantly enhances the overall embryotoxicity in avian species.

Journal of Toxicology and Environmental Health

Mineral facilities of Asia and the Pacific

This map displays over 1,500 records of mineral facilities throughout the continent of Asia and the countries of the Pacific Ocean. Each record represents one commodity and one facility type at a single geographic location. Facility types include mines, oil and gas fields, and plants, such as refineries, smelters, and mills. Common commodities of interest include aluminum, cement, coal, copper, gold, iron and steel, lead, nickel, petroleum, salt, silver, and zinc. Records include attributes, such as commodity, country, location, company name, facility type and capacity (if applicable), and latitude and longitude geographical coordinates (in both degrees-minutes-seconds and decimal degrees). The data shown on this map and in table 1 were compiled from multiple sources, including (1) the 2008 U.S. Geological Survey Minerals Yearbook (Asia and the Pacific volume), (2) minerals statistics and information from the U.S. Geological Survey Minerals Information Web site (http://minerals.usgs.gov/minerals/), and (3) data collected by U.S. Geological Survey minerals information country specialists. Other sources include statistical publications of individual countries, annual reports and press releases of operating companies, and trade journals. Due to the sensitivity of some energy commodity data, the quality of these data should be evaluated on a country-by-country basis. Additional information is available from the country specialists listed in table 2.

Open-File Report

Chemical characterization of gas- and oil-bearing shales by instrumental neutron activation analysis

The concentration of As, Ba, Ca, Co, Cr, Cs, Dy, Eu, Fe, Ga, Hf, K, La, Lu, Mn, Mo, Na, Ni, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, U, Yb, and Zn were determined by instrumental neutron activation analysis in block shale samples of the New Albany Group (Devonian-Mississippian) in the in the Illinois Basin. Uranium content of the samples was as high as 75 ppm and interfered in the determination of samarium, molybdenum, barium and cerium. In the determination of selenium a correction was made for interference from tantalum. U, As, Co, Mo, Ni and Sb as well as Cu, V and pyritic sulphur which were determined by other methods, were found to correlate positively with the organic carbon content of the samples. ?? 1982 Akade??miai Kiado??.

Journal of Radioanalytical Chemistry

Mineral facilities of Northern and Central Eurasia

This map displays almost 900 records of mineral facilities within the countries that formerly constituted the Union of Soviet Socialist Republics (USSR). Each record represents one commodity and one facility type at a single geographic location. Facility types include mines, oil and gas fields, and plants, such as refineries, smelters, and mills. Common commodities of interest include aluminum, cement, coal, copper, gold, iron and steel, lead, nickel, petroleum, salt, silver, and zinc. Records include attributes, such as commodity, country, location, company name, facility type and capacity (if applicable), and latitude and longitude geographical coordinates (in both degrees-minutes-seconds and decimal degrees). The data shown on this map and in table 1 were compiled from multiple sources, including (1) the most recently available data from the U.S. Geological Survey (USGS) Minerals Yearbook (Europe and Central Eurasia volume), (2) mineral statistics and information from the USGS Minerals Information Web site (http://minerals.usgs.gov/minerals/pubs/country/europe.html), and (3) data collected by the USGS minerals information country specialists from sources, such as statistical publications of individual countries, annual reports and press releases of operating companies, and trade journals. Data reflect the most recent published table of industry structure for each country at the time of this publication. Additional information is available from the country specialists listed in table 2

Open-File Report

Mineral facilities of Europe

This map displays over 1,700 records of mineral facilities within the countries of Europe and western Eurasia. Each record represents one commodity and one facility type at a single geographic location. Facility types include mines, oil and gas fields, and plants, such as refineries, smelters, and mills. Common commodities of interest include aluminum, cement, coal, copper, gold, iron and steel, lead, nickel, petroleum, salt, silver, and zinc. Records include attributes, such as commodity, country, location, company name, facility type and capacity (if applicable), and latitude and longitude geographical coordinates (in both degrees-minutes-seconds and decimal degrees). The data shown on this map and in table 1 were compiled from multiple sources, including (1) the most recently available data from the U.S. Geological Survey (USGS) Minerals Yearbook (Europe and Central Eurasia volume), (2) mineral statistics and information from the USGS Minerals Information Web site (http://minerals.usgs.gov/minerals/pubs/country/europe.html), and (3) data collected by the USGS minerals information country specialists from sources, such as statistical publications of individual countries, annual reports and press releases of operating companies, and trade journals. Data reflect the most recently published table of industry structure for each country at the time of this publication. Additional information is available from the country specialists listed in table 2.

Open-File Report

A synoptic examination of causes of land loss in southern Louisiana as related to the exploitation of subsurface geologic resources

During the last 80 years, Louisiana has been losing wetlands at an average rate of 62 km 2 /y (24 mi 2 /y) for an accumulated loss of approximately 4900 km 2 (1900 mi 2 ). The loss seems to be the combined result of natural and anthropogenic causes that are behind primarily land subsidence averaging about 10 mm/y (0.4 in/y) coinciding with a sea level rise now at 3 mm/y (0.1 in/y), both contributing to coastal inundation. Upon completing extensive review of often controversial and conflicting views only synoptically reported here, conclusions reached by applying Monte Carlo simulation include: (1) geodetic measurements are consistent with independently postulated causes of regional subsidence; (2) ranking of subsidence factors shows that the main contributor to the regional subsidence is adjustment to sediment load in the form of lithosphere flexure followed by normal faulting dipping basinward, which combined, account on average for 70% of the subsidence, with compaction accounting for another 23%; and (3) production of oil and gas plays a tertiary role. The literature supports the historical view that before experiencing engineering modifications across the catchment area, sedimentation from the Mississippi River system was able to build a prograding coastline by overcoming subsidence rates of similar magnitude with more generous sediment loads of coarser particle size. Sea level rise will become an increasingly dominant factor in land loss only if the acceleration predicted by simulation model scenarios materializes. Wetland losses most likely will continue for as long as there is no compensation to counterbalance the negative effects of land subsidence and sea level rise, with the latter determining the pace of future losses.

Louisiana

Gas shale/oil shale

The production of natural gas from shales continues to increase in North America, and shale gas exploration is on the rise in other parts of the world since the previous report by this committee was published by American Association of Petroleum Geologists, Energy Minerals Division (2009). For the United States, the volume of proved reserves of natural gas increased 11% from 2008 to 2009, the increase driven largely by shale gas development (Energy Information Administration 2010c). Furthermore, shales have increasingly become targets of exploration for oil and condensate as well as gas, which has served to greatly expand their significance as ‘‘unconventional’’ petroleum reservoirs. This report provides information about specific shales across North America and Europe from which gas (biogenic or thermogenic), oil, or natural gas liquids are produced or is actively being explored. The intent is to reflect the recently expanded mission of the Energy Minerals Division (EMD) Gas Shales Committee to serve as a single point of access to technical information on shales regardless of the type of hydrocarbon produced from them. The contents of this report were drawn largely from contributions by numerous members of the EMD Gas Shales Advisory Committee, with much of the data being available from public websites such as state or provincial geological surveys or other public institutions. Shales from which gas or oil is being produced in the United States are listed in alphabetical order by shale name. Information for Canada is presented by province, whereas for Europe, it is presented by country.

Natural Resources Research

Amino acids and gases in some springs and an oil field in California

Samples of water and gas were collected from six springs and two wells in the Upper Cretaceous Great Valley sequence and Franciscan Formation underlying the Coast Range of northern California and from four oil wells penetrating Tertiary sedimentary rocks in the Kettleman North Dome oil field. Comparison of the dissolved free amino acid compositions of the waters from the two locations show overlapping ranges with many more similarities than differences. The detection of nonprotein amino acids (sarcosine, β -amino n -butyric acid, and others) indicates the protein degradation is partly chemical rather than strictly biological. Other low molecular weight degradation products (methane, ethane, nonvolatile organic acids, and other organic chelating agents) were found. This may be one mechanism for the transportation of organic matter from the source rocks to the reservoir rocks of an oil deposit.

California

Methodology for estimating the prospective CO2 storage resource of residual oil zones at the national and regional scale

Residual oil zones (ROZs) are increasingly gaining interest as potential reservoirs for carbon dioxide (CO 2 ) storage. Here, we present a national- and regional-scale methodology for estimating prospective CO 2 storage resources in residual oil zones. This methodology uses a volumetric equation that accounts for CO 2 storage as a free phase in pore space and as a dissolved phase in oil and does not assume any oil production associated with CO 2 storage. Reservoir modeling and the CO 2 -SCREEN tool are used to demonstrate that CO 2 storage in residual oil zones will predominantly take place in the free phase (approximately 92–97%) with some storage as dissolution in oil (approximately 3–8 %). Based on this preliminary demonstration, the CO 2 storage efficiency for ROZs using this national- and regional-scale method ranges from 0.61 to 7.1 %. This range indicates ROZs have a similar efficiency potential for storing CO 2 as deep saline formations (0.51–5.4 %).

International Journal of Greenhouse Gas Control

Arsenic release to the environment from hydrocarbon production, storage, transportation, use and waste management

Arsenic (As) is a toxic trace element with many sources, including hydrocarbons such as oil, natural gas, oil sands, and oil- and gas-bearing shales. Arsenic from these hydrocarbon sources can be released to the environment through human activities of hydrocarbon production, storage, transportation and use. In addition, accidental release of hydrocarbons to aquifers with naturally occurring (geogenic) As can induce mobilization of As to groundwater through biogeochemical reactions triggered by hydrocarbon biodegradation. In this paper, we review the occurrence of As in different hydrocarbons and the release of As from these sources into the environment. We also examine the occurrence of As in wastes from hydrocarbon production, including produced water and sludge. Last, we discuss the potential for As release related to waste management, including accidental or intentional releases, and recycling and reuse of these wastes.

Journal of Hazardous Materials

Forest cover changes due to hydrocarbon extraction disturbance in central Pennsylvania (2004–2010)

The state of Pennsylvania has a long history of oil and gas extraction. In recent years with advances in technology such as hydraulic fracturing, hydrocarbon sources that were not profitable in the past are now being exploited. Here, we present an assessment of the cumulative impact of oil and gas extraction activities on the forests of 35 counties in Pennsylvania and their intersecting sub-watersheds between 2004 and 2010. The assessment categorizes counties and sub-watersheds based on the estimated amount of change to forest cover in the area. From the data collected we recognize that although forest cover has not been greatly impacted (with an average loss of percent forest coverage of 0.16% at the county level), landscape structure is affected. Increase in edge forest and decrease in interior forest is evident in many of the counties and sub-watersheds examined. These changes can have a detrimental effect on forest biodiversity and dynamics.

Pennsylvania

Sound and sturgeon: Bioacoustics and anthropogenic sound

Sturgeons are basal bony fishes, most species of which are considered threatened and/or endangered. Like all fishes, sturgeons use hearing to learn about their environment and perhaps communicate with conspecifics, as in mating. Thus, anything that impacts the ability of sturgeon to hear biologically important sounds could impact fitness and survival of individuals and populations. There is growing concern that the sounds produced by human activities (anthropogenic sound), such as from shipping, commercial barge navigation on rivers, offshore windfarms, and oil and gas exploration, could impact hearing by aquatic organisms. Thus, it is critical to understand how sturgeon hear, what they hear, and how they use sound. Such data are needed to set regulatory criteria for anthropogenic sound to protect these animals. However, very little is known about sturgeon behavioral responses to sound and their use of sound. To help understand the issues related to sturgeon and anthropogenic sound, this review first examines what is known about sturgeon bioacoustics. It then considers the potential effects of anthropogenic sound on sturgeon and, finally identifies areas of research that could substantially improve knowledge of sturgeon bioacoustics and effects of anthropogenic sound. Filling these gaps will help regulators establish appropriate protection for sturgeon.

The Journal of the Acoustical Society of America

Monitoring and modeling wetland chloride concentrations in relationship to oil and gas development

Extraction of oil and gas via unconventional methods is becoming an important aspect of energy production worldwide. Studying the effects of this development in countries where these technologies are being widely used may provide other countries, where development may be proposed, with some insight in terms of concerns associated with development. A fairly recent expansion of unconventional oil and gas development in North America provides such an opportunity. Rapid increases in energy development in North America have caught the attention of managers and scientists as a potential stressor for wildlife and their habitats. Of particular concern in the Northern Great Plains of the U.S. is the potential for chloride-rich produced water associated with unconventional oil and gas development to alter the water chemistry of wetlands. We describe a landscape scale modeling approach designed to examine the relationship between potential chloride contamination in wetlands and patterns of oil and gas development. We used a spatial Bayesian hierarchical modeling approach to assess multiple models explaining chloride concentrations in wetlands. These models included effects related to oil and gas wells (e.g. age of wells, number of wells) and surficial geology (e.g. glacial till, outwash). We found that the model containing the number of wells and the surficial geology surrounding a wetland best explained variation in chloride concentrations. Our spatial predictions showed regions of localized high chloride concentrations. Given the spatiotemporal variability of regional wetland water chemistry, we do not regard our results as predictions of contamination, but rather as a way to identify locations that may require more intensive sampling or further investigation. We suggest that an approach like the one outlined here could easily be extended to more of an adaptive monitoring approach to answer questions about chloride contamination risk that are of interest to managers.

Montana, North Dakota

Relative importance of physical and economic factors in Appalachian coalbed gas assessment

In the 1995 National Assessment of Oil and Gas Resources prepared by the U.S. Geological Survey, only 20% of the assessed technically recoverable Appalachian Province coalbed gas resources were economic. Physical and economic variables are examined to explain the disparity between economic and technically recoverable coalbed gas. The Anticline and Syncline plays of the Northern Appalachian Basin, which account for 77% of the assessed technically recoverable coalbed gas, are not economic. Analysis shows marginal reductions in costs or rate of return will not turn these plays into commercial successes. Physical parameters that determine ultimate well recoverability and the rate of gas recovery are primary reasons the Northern Appalachian Basin plays are non-commercial. If the application of new well stimulation technology could offset slow gas desorption rates, Appalachian Province economic gas could increase to more then 70% of the technically recoverable gas. Similarly, if operators are able to develop strategies to selectively drill plays by avoiding dry holes and non-commercial occurrences, the economic fraction of technically recoverable gas could increase to over half.In the 1995 National Assessment of Oil and Gas Resources prepared by the U.S. Geological Survey, only 20% of the assessed technically recoverable Appalachian Province coalbed gas resources were economic. Physical and economic variables are examined to explain the disparity between economic and technically recoverable coalbed gas. The Anticline and Syncline plays of the Northern Appalachian Basin, which account for 77% of the assessed technically recoverable coalbed gas, are not economic. Analysis shows marginal reductions in costs or rate of return will not turn these plays into commercial successes. Physical parameters that determine ultimate well recoverability and the rate of gas recovery are primary reasons the Northern Appalachian Basin plays are non-commercial. If the application of new well stimulation technology could offset slow gas desorption rates, Appalachian Province economic gas could increase to more then 70% of the technically recoverable gas. Similarly, if operators are able to develop strategies to selectively drill plays by avoiding dry holes and non-commercial occurrences, the economic fraction of technically recoverable gas could increase to over half.

International Journal of Coal Geology

Modeling the spatial and temporal dynamics of land-based polar bear denning in Alaska

Although polar bears ( Ursus maritimus ) of the Southern Beaufort Sea (SBS) subpopulation have commonly created maternal dens on sea ice in the past, maternal dens on land have become increasingly prevalent as sea ice declines. This trend creates conditions for increased human–bear interactions associated with local communities and industrial activity. Maternal denning is a vulnerable period in the polar bear life cycle, and den disturbance could lead to den abandonment, cub mortality, and negative population impacts. We used published long-term data to parameterize a Bayesian hierarchical model of annual land den abundance during 2000–2015, in 4 regions of northern Alaska, USA, with current or potential future oil and gas activity. We also estimated long-term (1982–2015) shifts in the spatial distribution of land dens within and among regions using kernel density estimation and assessed the influence of local and regional sea ice and snow conditions on den site selection using a random forest resource selection function. Our objectives were to quantify current den distribution and abundance, test for distributional shifts over time, and investigate if those shifts could be attributed to environmental variables related to den habitat. We estimated that between 2000 and 2015, the SBS contained a median 123 dens in a typical year, of which 68 occurred on land. The region between the Colville and Canning rivers, where most current oil and gas activity occurred, also contained the largest fraction of land dens. Overall, land dens were disproportionately concentrated on barrier islands and on land within 30 km of the coast. The probability of dens occurring on land varied from 1982–1999 to 2000–2015 in all regions, and the overall distribution of land dens shifted west between those periods. This regional-scale change in den distribution was predictable based on spatial and temporal heterogeneity in snow and sea ice conditions within 50 km of individual den locations. Land denning is likely to become increasingly common with continued sea ice loss, and our results and modeling framework could be used to design additional mitigation strategies for reducing the risk of incidental take due to den disturbance.

Alaska

Estimating the pressure-limited CO2 injection and storage capacity of the United States saline formations: Effect of the presence of hydrocarbon reservoirs

The U.S. Geological Survey (USGS) national assessment of carbon dioxide (CO 2 ) storage capacity evaluated 192 saline Storage Assessment Units (SAUs) in 33 U.S. onshore sedimentary basins that may be utilized for CO 2 storage (see USGS Circular 1386). Similar to many other available models, volumetric analysis was utilized to estimate the initial CO 2 injection and storage capacity of these SAUs based on aquifer characteristics and buoyant and residual trapping. The factor being almost always overlooked in most CO 2 storage capacity models is that many of the evaluated SAUs contain large numbers of both conventional and unconventional discovered and undiscovered oil and gas reservoirs. The hydrocarbon production and pressure distribution of the resident oil and gas reservoirs may be negatively influenced by the propagated CO 2 plume and pressure front resulting from a CO 2 injection and storage operation in the surrounding SAU. To have a more realistic and accurate estimation of CO 2 injection and storage capacity in saline formations, a model was previously developed that considers the CO 2 injectivity of a given formation, underground pressure build-up limitations imposed by the rock fracturing pressure and the presence of hydrocarbon reservoirs within these aquifers. The developed method estimates the pre–brine extraction, pressure-limited CO 2 injection and storage capacity of a saline formation by applying 3D numerical simulation only on the effective injection area (A eff ) surrounding each CO 2 injection well utilizing TOUGH2-ECO2N simulation software.

Sligo and Hosston Formations

Delayed dynamic triggering of disposal-induced earthquakes observed by a dense array in Northern Oklahoma

Recent increases in earthquake occurrence rates in Oklahoma have been linked to the injection of large volumes of saltwater, a byproduct of oil and gas extraction. Here we present a detailed study of remote earthquake triggering in an area of active injection‐induced seismicity in northern Oklahoma using data from the LArge‐n Seismic Survey in Oklahoma (LASSO) temporary array and nearby permanent broadband seismic stations. We estimate changes in earthquake rates and calculate the Coulomb failure stress changes on potential receiver faults due to passing teleseismic surface waves. A statistically significant increase in seismicity is observed ∼8 hr after the 16 April 2016 M w 7.8 Ecuador earthquake. The Coulomb stress changes associated with the Ecuador earthquake are on the order of ∼1 kPa. Physical mechanisms consistent with the observed dynamic stress threshold include failure driven by activation of aseismic slip or hydrological response of the fault system.

Oklahoma

Tomographic Rayleigh-wave group velocities in the Central Valley, California centered on the Sacramento/San Joaquin Delta

If shaking from a local or regional earthquake in the San Francisco Bay region were to rupture levees in the Sacramento/San Joaquin Delta then brackish water from San Francisco Bay would contaminate the water in the Delta: the source of fresh water for about half of California. As a prelude to a full shear-wave velocity model that can be used in computer simulations and further seismic hazard analysis, we report on the use of ambient noise tomography to build a fundamental-mode, Rayleigh-wave group velocity model for the region around the Sacramento/San Joaquin Delta in the western Central Valley, California. Recordings from the vertical component of about 31 stations were processed to compute the spatial distribution of Rayleigh wave group velocities. Complex coherency between pairs of stations were stacked over 8 months to more than a year. Dispersion curves were determined from 4 to about 18 seconds. We calculated average group velocities for each period and inverted for deviations from the average for a matrix of cells that covered the study area. Smoothing using the first difference is applied. Cells of the model were about 5.6 km in either dimension. Checkerboard tests of resolution, which is dependent on station density, suggest that the resolving ability of the array is reasonably good within the middle of the array with resolution between 0.2 and 0.4 degrees. Overall, low velocities in the middle of each image reflect the deeper sedimentary syncline in the Central Valley. In detail, the model shows several centers of low velocity that may be associated with gross geologic features such as faulting along the western margin of the Central Valley, oil and gas reservoirs, and large cross cutting features like the Stockton arch. At shorter periods around 5.5s, the model’s western boundary between low and high velocities closely follows regional fault geometry and the edge of a residual isostatic gravity low. In the eastern part of the valley, the boundaries of the low velocity zone and gravity anomaly are better aligned at longer periods (around 10.5s) suggesting that the eastern edge of the gravity low is associated with deeper structure. There is a strong correspondence between a low in gravity near the Kirby Hills fault and low velocities from the ambient noise tomography. At longer periods, higher velocities creep in from the east and narrow the overall dimension defined by the lower velocities. Overall, there is a strong correspondence between the shape and location of low velocities in the Rayleigh wave velocity images, and geological and geophysical features.

California