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220 records · Page 5Linked to original sources

Controls on water quality below a reclaimed surface coal mine, southeastern Montana

Coal mining and reclamation can have a profound influence on hydrogeologic systems, with clear consequences for groundwater quality, yet their long-term influence on downgradient water quality over time following reclamation is less well documented. Geochemical trends were evaluated in water quality downgradient of a fully reclaimed landscape at the former Big Sky Mine in the Rosebud Creek watershed (southeastern Montana, USA), over a 3-year period (2020–2022), including bond release in 2022. Within 6 km downgradient from the reclaimed area, sulfate concentrations decreased from approximately 3500 to 1800 mg l −1 within the Miller Coulee alluvial aquifer. Major ions, δ 34 S SO4 values, and residence time tracers suggest that the observed decreases in sulfate concentration result from a combination of dilution by mixed-age inflows and incomplete transit of the high salinity plume from the mine boundary. Both bedrock and alluvial aquifers of the Rosebud Creek corridor contained contributions of millennia-old regional groundwater, which may serve to mitigate mine-derived high salinity waters. Rosebud Creek, which traverses the outflow zone of Miller Coulee in the study area, exhibited high sulfate concentrations during low flows and consistent downgradient increases in sulfate concentration. The possibility of plume dynamics in Miller Coulee suggests that the greatest water quality impacts may not yet have reached Rosebud Creek.

Montana

Site-specific, extended ShakeMaps for earthquake engineering applications

The U.S. Geological Survey (USGS) routinely produces ShakeMaps of shaking intensity across the globe. Due to practical constraints, the number of response spectral periods was limited to three standard periods (0.3, 1.0, and 3.0 sec). We have recently developed the tools that are necessary to expand this functionality to include 22 periods (matching the current U.S. National Seismic Hazard Model periods) as well as the orientation-independent components (e.g., “RotD50”). We refer to ShakeMap products that include these extensions as “extended ShakeMaps.” The added level of complexity motivated us to also develop a user-friendly tool called the “ShakeMap Sampling Tool” (SST) that gives all the estimated shaking metrics for a specific location (or list of locations). Additionally, we develop a web application where users can input locations of interest and view/download the SST results. We further familiarize users with the concept of “Composite ShakeMaps.” For earthquakes sequences such as a mainshock and larger foreshocks and aftershocks, this provides a map of the maximum value of each shaking metric, which is useful for overall loss estimates, the full extent of ground failure triggering potential, and a better portrayal of the repeated shaking levels at a given point for a series of earthquakes. Such a site-specific shaking history facilitates earthquake forensics at building or infrastructure sites for which damage may be of concern, as described in the Disproportionate Damage Earthquake trigger specified in the IEBC (2018, Section 405.2.2) and in developing ATC-145 guidelines (Guidelines for Post-Earthquake Assessment, Repair, and Retrofit of Buildings). The composite ShakeMap can be combined with the SST for a variety of earthquake-hazard applications, such as systematically inferring triggering shaking estimates at specific sites of geotechnical interest for landsliding, liquefaction, and lateral-spreading hazards.

Kahramanmaraş

Temporal and spatial comparison of coal mine ventilation methane emissions and mitigation quantified using PRISMA satellite data and on-site measurements

Emission monitoring at the facility level (bottom-up, BU) is key for accurate reporting of coal mine methane (CMM) emissions. Recent advances in aerial and satellite observations (top-down, TD) indicate that these methods have the potential to support CMM emissions monitoring and reporting of, as well as track the effectiveness of, mitigation actions. That said, studies have shown discrepancies between BU and TD estimations. Performing TD monitoring with concurrent BU measurements at the same mines may help address the observed discrepancies and improve quantification methods to narrow the gap between BU and TD data. This paper presents a comparison of concurrent BU-TD methane emission fluxes monitored from two ventilation shafts at a southwestern Virginia, USA, longwall mine to complement the existing body of studies on satellite-based monitoring of coal mines by incorporating continuous ground-based monitoring with concurrent TD monitoring of methane emission fluxes to address the gap and provide valuable insights into temporal emission patterns. The shafts were monitored on multiple dates between 2020 and 2023. BU monitoring was performed at the exhaust fans, while TD quantifications used PRISMA hyperspectral satellite data and two different wind reanalysis datasets (i.e., GEOS-FP and ERA5). This mine also offered a unique opportunity for BU-TD comparisons before and after ventilation air methane (VAM) oxidizer operation, which was installed at one of the shafts in 2022. The results showed that TD-estimated mean fluxes were generally lower than BU data, which were attributed to quantification difficulties associated with the low albedo caused by heavy vegetation and the terrain of the area. However, despite the discrepancies in mean emissions, both the interquartile range and the data range of the distributions generally overlapped, and the estimates correctly showed the emission trends.

Virginia

From exploration to production: Understanding the development dynamics of lithium mining projects

Recently, there has been considerable recent controversy whether current and new lithium mines will be able to supply the rapidly growing needs of the electromobility transition. Mineral exploration projects are typically active for many years, and only some become operational mines. From exploration to production, the projects go through several stages of characterisation and evaluation. At each stage, decisions are made by companies and stakeholders to advance, continue or stop the project. This is a complex process, and even projects with very similar geological and technical characteristics may take very different trajectories, depending on external factors such as global market conditions and local regulatory environments. The present study investigates the dynamics of this process for lithium exploration projects. A global database of 397 lithium projects was compiled, covering their progression through major development stages between 2004 and 2022. Ordinal logistic regression was used for the statistical analysis of this data. Different explanatory variables were tested, including economic, geological, technical, and geographic factors, to identify the best predictors for project progress at each development stage. The results suggest an essential role for lithium carbonate prices, and a variable role for other factors at each stage. Critically, the already elapsed lead time and project economics, which are traditionally considered important for the prediction of the start-up of individual mines, do not appear to be relevant in all cases. The results provide important insights into the dynamics of lithium supply and may eventually allow more realistic forecasts to be made for future lithium market dynamics.

Resources Policy

Geophysical identification of potential groundwater – surface water interactions in the Bonita Peak Mining District, San Juan County, Colorado

This report includes the results and interpretation of geophysical investigations to aid in the location, identification, and conceptual site model (CSM) development of the near surface groundwater and surface water hydrology of the Upper Cement Creek and California Gulch of the Animas Rivers within the Bonita Peak Mining Districts (BPMD). Mine influenced water (MIW) from numerous mine adits within the BPMD has altered the geochemistry and ecology of these ground and surface waters. Many studies of varying scales have investigated the geology, hydrogeology, geochemistry, and aqueous chemistry of these adits and impacted areas. Field investigations using non-invasive geophysical methods were conducted in the summer of 2019 to aid in identifying potential groundwater inputs to these streams and further the CSM of the near surface within and along these streams. Two field deployments were completed in August and September of 2019. In August 2019, Phase 1 was completed using multifrequency electromagnetic induction (EMI) and thermal infrared imaging (TIR) to measure the bulk electrical conductivity, magnetic susceptibility, and the temperature response at known and suspected groundwater seeps into the Upper Cement Creek and California Gulch stretches of these alpine streams. Results and interpretation from Phase 1 were used to co-locate stretches of these streams for further detailed fiber optic distributed temperature system (FODTS) monitoring of the temperature dynamics for submeter identification of potential groundwater seeps during Phase 2. Phase 2 included additional EMI measurements, FODTS measurements, and repeated some Phase 1 measurements for improved data quality. All these data were used for the combined qualitative interpretation identifying seep locations. The data from both Phase 1 and Phase 2 are available in the USGS data release at: https://www.sciencebase.gov/catalog/item/5f18a30082cef313ed84879b. These data include detailed near-surface electrical conductivity and magnetic susceptibility mapping, discrete TIR imaging, and several kilometers of FODTS data. These data were georeferenced and used to identify potential groundwater seeps into these streams. The results indicate a complex near surface geophysical and hydrogeologic regime. Seeps are classified and spatially correlated to the EMI, TIR, and geochemical sampling results. This report is a thorough compilation of the geophysical field efforts in the summer of 2019, the data processing, and interpretations of these data. These data alone should not be used for final interpretations of the complex hydrogeology within these alpine systems. Rather, these data should be combined with other known data from various investigations to further refine the CSM and guide decisions for future investigations, watershed protective measures, and other site decisions. Geographical information system (GIS) layers of these results are available to project managers for such integration and combined interpretations.

Colorado

Geochemical processes related to mined, milled, or natural metal deposits in a rapidly changing global environment

The demand for metals and raw materials, such as nickel and copper, has been projected to expand in the coming decades, driven by the global energy transition, the need for green technologies, and expanding infrastructure. Consequently, the increasing extraction and production of mining waste can have adverse impacts on surrounding environments and human health. The aim of this thematic collection is to fill critical knowledge gaps in the present-day cycles of metal(loid)s from source to larger sinks, and the effect of environmental management, anthropogenic development, and climate change. Altogether, the studies have been conducted in different natural settings around the world and comprise investigations in laterites, a soil-medicinal plant system, watersheds, and banded iron formations, among others. The geochemical applications in tracing mineralization, its secondary products, and/or potential impact on the immediate environment are highly diverse with applied tools ranging from isotope tracers to major and trace element systematics. Particularly the use of rare earth elements, their patterns and anomalies are methods employed by several studies in this collection. We summarize the findings to offer a potential future direction for the use of geochemical tracing techniques in resource exploration in the context of climate change and environmental challenges.

Geochemistry: Exploration, Environment, Analysis

Utilization of stochastic ground motion simulations for scenario-based performance assessment of geo-structures

Probabilistic seismic performance assessments of engineered structures can be highly sensitive to the seismic input excitation and its variability. In the present study, the scenario-based performance assessment recommended by Federal Emergency Management Agency (FEMA) P-58 guidelines is adopted to estimate seismic fragility of concrete dams for various seismic hazard scenarios. Due to the scarcity of recorded ground motions and thereby their poor representation of uncertainties, stochastic ground motion simulation methods are utilized to obtain the required input excitations. Moreover, to understand the uncertainty in ground motion simulation models, two broadband stochastic simulation models are used to generate input excitations representing six seismic hazard scenarios defined by earthquake magnitude, source-to-site distance, and soil conditions. Optimal intensity measure parameters for each scenario are identified using a systematic procedure that considers criteria such as efficiency, practicality, proficiency, sufficiency, and hazard compatibility. Fragility curves and surfaces are derived using the cloud analysis technique, taking into account various damage measures and limit state functions. The study finds that the derived fragility curves are particularly sensitive to the selection of earthquake scenarios, the choice of records, and the methods used to calculate fragility curves, with less sensitivity observed to different engineering demand parameters. Given this sensitivity, particularly to ground motion selection, the study highlights the necessity of incorporating both model-to-model variability (epistemic uncertainty) and record-to-record variability (aleatory uncertainty), alongside the established material and modeling uncertainties, in the probabilistic seismic assessment.

Reliability Engineering and System Safety (RESS)

Metal-rich lacustrine sediments from legacy mining perpetuate copper exposure to aquatic-riparian food webs

Historic copper mining left a legacy of metal-rich tailings resulting in ecological impacts along and within Torch Lake, an area of concern in the Keweenaw Peninsula, Michigan, USA. Given the toxicity of copper to invertebrates, this study assessed the influence of this legacy on present day nearshore aquatic and terrestrial ecosystems. We measured the metal (Co, Cu, Ni, Zn, Cd) and metalloid (As) concentrations in sediment, pore water, surface water, larval and adult insects, and two riparian spider taxa collected from Torch Lake and a nearby reference lake. Overall, elevated metal and metalloid concentrations, particularly Cu, were measured in all sediment samples and some surface and pore water samples collected from Torch Lake. For instance, Cu concentrations in the Torch Lake sediment were ∼200% higher than the reference lake and all measured concentrations exceeded predicted effects concentrations by at least ninefold. Within larval insect tissues, we observed 160% higher Cu concentrations than measured in the reference lake, and Cu was the only measured element above predicted effects concentrations in Torch Lake. Adult insects collected at both lakes had similar metal concentrations irrespective of exposure levels. Yet we found 100% higher copper concentrations in Torch Lake riparian spiders, demonstrating elevated exposure risk to insectivores across the aquatic-terrestrial boundary. Our results highlight that other metals in the mixture may not be as concerning to adjacent riparian ecosystems, but copper remains a contaminant of concern in Torch Lake 60 years after mining ceased.

Michigan

Simulated ground motion dataset in the Azores Plateau, Portugal, on rock and soil sites

Building on a previously developed bedrock dataset, this study extends the Azores Plateau ground motion simulations to include soil-amplified records and introduces a comprehensive validation framework. Soil amplification is modeled using one-dimensional soil profiles. A stochastic source-based approach is employed to generate the dataset, incorporating randomization of input-model parameters to account for the aleatory uncertainty in seismic activity. The accuracy of the dataset is verified through a comprehensive validation framework, showing that the randomization effectively captures variance and inter-period correlation observed in records. This work provides a robust dataset for advancing seismic hazard and risk assessment in the Azores Plateau.

central and eastern Azores islands

Lithium from magma to mine in an early Yellowstone hotspot caldera

Renewable energy technologies rely on the extraction of metals not historically in high demand, such as lithium (Li), for which ore deposit models are incompletely understood. One of the world’s largest Li deposits is hosted in lake sediments of the 16.4 Ma McDermitt caldera, which formed during the early stages of Yellowstone hotspot volcanism in the western United States. Eruptive and posteruptive mobility of Li are major challenges in elucidating deposit formation. Melt inclusions preserved in quartz crystals provide a means to assess pre-eruptive magmatic Li contents. Concentrations of Li determined by ion microprobe for melt inclusions in a McDermitt rhyolite lava are 400−1350 ppm, compared to 20−70 ppm Li in matrix rhyolite glasses. Synthesis with melt inclusion data for eight additional calderas demonstrates a recurrence of Li-rich rhyolitic magmas (200−2000 ppm Li) in the western part of the Yellowstone hotspot track. However, unlike the multicyclic caldera complexes with overlapping fault networks that may have compromised Li retention, the McDermitt caldera remained a closed hydrologic system throughout its evolution. Modeling indicates 100 km 3 of resurgent magma could yield 25−150 Mt Li in a magmatic fluid and supports accumulation of Li-rich magmatic fluid in a closed intracaldera lake, followed by evaporative concentration and sequestration of Li within clay minerals to generate the McDermitt deposit.

Idaho, Nevada, Oregon, Wyoming

Aeromagnetic and magnetotelluric imaging of west-central Idaho and the Stibnite-Yellow Pine mining district: A regional to district perspective

Aeromagnetic and magnetotelluric (MT) data are used to better understand the geology and mineral resources near the Stibnite-Yellow Pine mining district in central Idaho. The reduced-to-pole (RTP) transformation of regional-scale aeromagnetic data shows that allochthonous island-arc rocks west of the Salmon River suture are significantly more magnetic than the Laurentian continental rocks east of the suture and that the granitoids of the Idaho batholith have moderate to low magnetization in both early, metaluminous, and late, peraluminous phases. Application of tilt derivative to aeromagnetic data highlights major crustal-scale structures. The 5-km upward continued magnetic data indicate island-arc rocks have deep magnetic sources. The 110-km-long MT profile images resistivity structure to depths around 30 km. At shallow depths, resistivity corresponds to mapped geologic units, with moderate resistivities underlying volcanic and roof-pendant metasedimentary rocks and moderate to high resistivities occurring beneath the Idaho batholith. Crustal-scale moderate resistivities beneath the suture image the results of tectonomagmatic processes that accompanied suturing and translating allochthonous terranes. Low resistivity values beneath and fringing the batholith are derived from metasedimentary rocks that may have served as a melt source and reductant during melt generation and provided metals during later ore formation. In the Stibnite-Yellow Pine mining district, a high-resolution aeromagnetic compilation is shown to correlate with mapped lithologies and mineral deposit-related structures. The RTP transform distinguishes magnetic and nonmagnetic granitoid phases of the Idaho batholith. The tilt derivative highlights metasedimentary rocks, some of which are favorable ore hosts. The Meadow Creek fault hosts the Stibnite and Hangar Flats deposits and is imaged as a magnetic low due to hydrothermal alteration. Reconstructions of magnetic anomaly offsets and orebodies indicate around 3 km of post-95 Ma dextral separation, with some or all of the offset inferred to postdate the main Au mineralization episode (61–66 Ma).

Idaho

Gas emissions from the Sulphur Bank Mercury Mine hydrothermal system, Clear Lake volcanic field, California

The Sulphur Bank Mercury Mine (SBMM) hydrothermal system offers insights into active degassing processes in the Clear Lake volcanic field (CLVF), a high-threat region based on its record of Holocene eruptions and proximity to populated areas. Here we present chemical and isotopic analyses of gas samples collected between 2015 and 2023, along with the first comprehensive CO 2 flux survey of the SBMM area conducted in 2023. Sampled gases are CO 2 - and CH 4 -rich (≥84 and 6 mol% in dry gas, respectively) with high mantle-derived helium contributions ( 3 He/ 4 He = 6.54–7.86 R C /R A ). Carbon isotopic compositions of CO 2 (δ 13 C = −10.0 to −9.5 ‰) and CH 4 (δ 13 C = −35.8 ‰) indicate mixed sources, with significant contributions from metamorphism of organic-rich Franciscan Complex rocks hosting the hydrothermal system. Modeling of gas compositions shows that scrubbing by interaction with air-saturated groundwater strongly influences observed compositional variability. From our CO₂ flux measurements, we estimate the deeply derived CO 2 emission rate from the SBMM hydrothermal area (0.2 km 2 ) at 240 t d −1 , comparable to many quiescently degassing volcanoes worldwide. We also provide a first-order estimate of CH 4 emissions at approximately 0.5 t d −1 . Our findings establish crucial baseline data for future volcanic monitoring efforts, enhancing detection capabilities for potential changes in this active hydrothermal system. This work contributes to the broader understanding of volatile contributions from volcanic and metamorphic sources to the global carbon budget, while highlighting the strong influence of bedrock geology on gas compositions in the CLVF.

California

Models no not provide proof: An example of model ambiguity and application of isotopic data in a mine pit lake

Geochemical and hydrologic models of pit lakes are commonly used in environmental regulatory decisions to predict future water quality and hydrologic conditions and to understand existing pit lakes. Models may be used to quantify sulfide oxidation, predict thermal/chemical stratification and mixing, and better understand connections between pit lakes and aquifers. One concern related to the hydrologic character of pit lakes is if they are terminal (a groundwater sink with no outflow) or flowthrough (both receiving groundwater inflow and discharging to groundwater). This question was pertinent to the Liberty pit lake, a small acidic pit lake formed in a former Cu deposit in south-central Nevada where potentiometric and geochemical data potentially indicate pit-lake outflow. Potential discharge to groundwater from the pit lake was evaluated using a water-balance model, but uncertainty in hydraulic parameters led to ambiguity in the hydrologic character. Stable isotopes of water were then sampled from the pit lake and adjacent groundwater wells, which unambiguously indicated the lack of an evaporative signature in downgradient groundwater because the groundwater did not plot on a hypothetical mixing line between evaporated pit lake water and observed meteoric recharge. This methodology provided a more effective and more data-driven approach for understanding pit-lake hydrology. Although predictive models are required to quantify reasonable bounds on future conditions, many models contain substantial uncertainty and are not well suited in some environments. Datasets that provide more clear lines of evidence could be collected from existing pit lakes whenever possible to inform water-rock interaction, limnological behavior, and connectivity to adjacent groundwater.

Nevada

Modeling byproduct and coproduct mine production and mineral substitution using multidimensional supply curves: Application to the Cu-Co-Ni system and beyond

Rapid demand growth is expected for many metals used in the energy transition. Many of these metals are byproducts of other commodities. Byproduct production’s price response is tied to host mineral economics, complicating its supply dynamics. Moreover, many of these metals are used in applications where the material properties desired are difficult to substitute; effectively, limiting how quickly demand can adapt to changes in commodity price. Previous work has demonstrated the interconnectivity of jointly produced mineral commodities from the supply side, where the copper–cobalt–nickel system was used and demand was assumed independent across commodities. Studies to understand byproduct-coproduct market interconnectivity on the demand side are limited, while studies on the interconnectivity of supply and demand simultaneously are even more so. We propose a modification to the multicommodity supply curve method to enable inter-commodity effects on demand simultaneous with supply. In batteries, high cobaltprices may push consumers to transition to high-nickel chemistries, causing the nickel demand surface to decrease with nickel price but increase with cobaltprice, creating a two-dimensional demand surface. Below cross-price elasticities of 0.05, inter-commodity effects were found to be negligible, potentially permitting exclusion of these effects for many commodities. This additional demand curve complexity introduces potential computation challenges alongside the capacity to model many interrelated commodity systems such as rare earth elements, ferroalloys, country-oriented subsidies or restrictions, and bifurcated sustainable metals markets. By presenting the work done on multicommodity supply surfaces to date and potential new directions, this work aims to catalyze the next round of innovative approaches to modeling jointly produced commodities.

Conference Paper

Review: The hydrogeology of critical mineral resources relevant to the energy transition

Attaining the goals of the international treaty on climate change (the Paris Agreement) will greatly increase the demand for the critical minerals required to implement clean-energy technologies. This poses both challenges and opportunities to the hydrogeologic community from several perspectives. Here, important insights that the hydrogeological sciences have to offer for mineral exploration, mineral production, and addressing environmental issues related to mining and mine decommissioning are summarized. This study focuses on copper, cobalt, lithium, and rare earths to represent the broad spectrum of critical minerals and illustrate their relevance by referring to projected demands and production rates. The current understanding of the hydrogeologic processes that form major deposits of these minerals are then summarized. Ore is defined as the naturally occurring material from which minerals of economic value can be extracted, where most ore deposits are the products of complex hydrogeologic couplings between fluid flow, heat transport, solute transport, chemical reactions, and mechanical deformation. Exploration models for the discovery of deeper, hidden deposits are potentially informed by hydrogeologic theory and hydrogeochemical processes. Hydrogeologic understanding and methods are also essential to production and recovery. Longstanding challenges are mine dewatering and (conversely) mine water supply, as well as mineral-extraction practices such as spoil heap leaching and in situ mining. New challenges arise from element extraction from subsurface brines. Finally, the quantity of water use and potential environmental impacts of mining on water quality are at the core of ‘social license’: the approval and acceptance of society to mining activities.

Hydrogeology Journal

Tracing metal sources and groundwater flow paths in the Upper Animas River watershed using rare earth elements and stable isotopes

Groundwater flow paths and processes that govern metal mobility and transport are difficult to characterize in mountainous bedrock watersheds. Despite the difficulty in holistic characterization, conceptual understanding of subsurface hydrologic and geochemical processes is key to developing remediation plans for locations affected by acid mine drainage, such as the Upper Animas River watershed in southwestern Colorado, USA. Stable isotopes of water and rare earth elements were utilized to evaluate groundwater flow and metal sources within this complex catchment. Stable isotope samples collected from draining mine adits and springs display systematic spatial variation wherein sample sites at higher elevations have greater seasonal variability than sites at lower elevations. The Upper Cement Creek watershed, where multiple draining mines are present, displays the lowest seasonal variation in stable isotopic signatures, potentially indicating the presence of a large, well-mixed volume of groundwater storage or interbasin groundwater flow. Rare earth elements display statistically significant variation between different alteration styles in the catchment. Overprinting of regional propylitic alteration is evident based on enrichment of middle rare earth elements in acidic springs and mines that are not spatially associated with surficial exposures of acid generating alteration styles. Europium anomaly and middle rare earth enrichment signatures from two flooded mine tunnels on opposite sides of a watershed divide indicate connections to the same subsurface flooded mine workings.

Colorado

Geotechnical description of four Mississippi Delta soil borings

The submerged portion of the Mississippi Delta complex forms an ideal natural laboratory to study the effects of rapid deposition. One of the most obvious of these effects is the mass movements of sediments. Slump and slide signatures, mudflow characteristics, and evidence for creep are all found in abundance on the delta platform. These types of features have been studied by Colemen and Wright (1974) with regard to form and by Garrison (1974) with regard to their spatial distribution. Assembling these authors' findings, it is clear that the entire offshore zone contiguous with the Mississippi River is a myriad of geological action. This situation is indeed stimulating to the sedimentologist, yet it represents a nightmare to the foundation engineer. Emplacing offshore structures in such an environment is a most difficult task, particularly since the high degree of local variability dictates that each case must be handled separately. It is under these circumstances that a marriage between geology and engineering is most fruitful, for determining the relationships between the sedimentological processes and the engineering properties is satisfying to parties from both disciplines. This, then, is the underlying objective of the Mississippi Delta research project. By investigating the instability in a geologic sense, it is hoped that many of the engineering problems will become more soluble and that extrapolation and prediction will become more realistic.

Mississippi Delta

Assessing environmental drivers of denitrification in restored riverine floodplains

Restoration of impaired floodplains is an increasingly prevalent strategy for alleviating water quality concerns and reducing downstream flooding at watershed scales. Floodplains temporarily store water and slow flow velocity to promote sedimentation during overbank flooding and remove inorganic nitrogen from floodwater and groundwater via denitrification. Evaluating the impacts of different restoration strategies on denitrification can inform more strategic investments into floodplain modifications that improve water quality outcomes. Our research investigates how denitrification rates in floodplains respond to environmental factors that are actionable from an engineering perspective through design and water resources management. We seasonally measured soil denitrification enzyme activity and various environmental characteristics in 4 floodplains with different restoration design and management approaches at the confluence of the Wabash and Tippecanoe Rivers in Indiana, United States. Our results showed that denitrification rates in an agricultural floodplain were significantly lower than in restored floodplains with native vegetation. Certain soil conditions characteristic of floodplain wetlands were associated with higher denitrification, particularly elevated total nitrogen, moisture, silt, and organic matter contents. Vegetation species composition was correlated with denitrification rates. This link may reflect the direct effects of vegetation on soil conditions, such as supplying labile organic carbon, or indirect effects, such as vegetation acting as an indicator of hydrologic regime and land use. Denitrification seasonally varied, peaking in winter when nitrate supply from rivers draining agricultural watersheds in the region is also high. Substrate limitation of soil denitrification enzyme activity was most significant during the summer when overbank flooding, which replenishes soil nitrogen stocks, rarely occurs. Our findings indicate that denitrification capacity will likely be maximized in riverine floodplains that are restored as wetlands with diverse native vegetation and enhanced hydrologic connectivity. Such restoration activities promote higher denitrification rates via elevated moisture, fine sediment deposition, and soil organic matter.

Tippecanoe River, Wabash River