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Visible and near-infrared multispectral analysis of geochemically measured rock fragments at the Opportunity landing site in Meridiani Planum

We have used visible and near‐infrared Panoramic Camera (Pancam) spectral data acquired by the Opportunity rover to analyze 15 rock fragments at the Meridiani Planum landing site. These spectral results were then compared to geochemistry measurements made by the in situ instruments Mössbauer (MB) and Alpha Particle X‐ray Spectrometer (APXS) to determine the feasibility of mineralogic characterization from Pancam data. Our results suggest that dust and alteration rinds coat many rock fragments, which limits our ability to adequately measure the mineralogy of some rocks from Pancam spectra relative to the different field of view and penetration depths of MB and APXS. Viewing and lighting geometry, along with sampling size, also complicate the spectral characterization of the rocks. Rock fragments with the same geochemistry of sulfate‐rich outcrops have similar spectra, although the sulfate‐rich composition cannot be ascertained based upon Pancam spectra alone. FeNi meteorites have spectral characteristics, particularly ferric oxide coatings, that generally differentiate them from other rocks at the landing site. Stony meteorites and impact fragments with unknown compositions have a diverse range of spectral properties and are not well constrained nor diagnostic in Pancam data. Bounce Rock, with its unique basalt composition, is easily differentiated in the Pancam data from all other rock types at Meridiani Planum. Our Pancam analyses of small pebbles adjacent to these 15 rock fragments suggests that other rock types may exist at the landing site but have not yet been geochemically measured.

Journal of Geophysical Research E: Planets

Origin of magnetite and pyrrhotite in carbonaceous chondrites

CARBONACEOUS chondrites, although comprising only about 2% of known meteorites, are extremely interesting for scientific investigation. Their mineral constitution, and the correspondence between their bulk chemical composition and the solar abundance of condensable elements, indicate that minimum chemical fractionation and thermal alteration have occurred. The mineral phases observed in these primitive chondrites are sufficiently unique, with respect to other meteorite classes, to have elicited considerable speculation about the physical environment in which they formed 1–7 .

Nature

Diel biogeochemical processes and their effect on the aqueous chemistry of streams: A review

This review summarizes biogeochemical processes that operate on diel, or 24-h, time scales in streams and the changes in aqueous chemistry that are associated with these processes. Some biogeochemical processes, such as those producing diel cycles of dissolved O 2 and pH, were the first to be studied, whereas processes producing diel concentration cycles of a broader spectrum of chemical species including dissolved gases, dissolved inorganic and organic carbon, trace elements, nutrients, stable isotopes, and suspended particles have received attention only more recently. Diel biogeochemical cycles are interrelated because the cyclical variations produced by one biogeochemical process commonly affect another. Thus, understanding biogeochemical cycling is essential not only for guiding collection and interpretation of water-quality data but also for geochemical and ecological studies of streams. Expanded knowledge of diel biogeochemical cycling will improve understanding of how natural aquatic environments function and thus lead to better predictions of how stream ecosystems might react to changing conditions of contaminant loading, eutrophication, climate change, drought, industrialization, development, and other factors.

Chemical Geology

Formation of replicating saponite from a gel in the presence of oxalate: implications for the formation of clay minerals in carbonaceous chondrites and the origin of life

The potential role of clay minerals in the abiotic origin of life has been the subject of ongoing debate for the past several decades. At issue are the clay minerals found in a class of meteorites known as carbonaceous chondrites. These clay minerals are the product of aqueous alteration of anhydrous mineral phases, such as olivine and orthopyroxene, that are often present in the chondrules. Moreover, there is a strong correlation in the occurrence of clay minerals and the presence of polar organic molecules. It has been shown in laboratory experiments at low temperature and ambient pressure that polar organic molecules, such as the oxalate found in meteorites, can catalyze the crystallization of clay minerals. In this study, we show that oxalate is a robust catalyst in the crystallization of saponite, an Al- and Mg-rich, trioctahedral 2:1 layer silicate, from a silicate gel at 60°C and ambient pressure. High-resolution transmission electron microscopy analysis of the saponite treated with octadecylammonium (n(C)=18) cations revealed the presence of 2:1 layer structures that have variable interlayer charge. The crystallization of these differently charged 2:1 layer silicates most likely occurred independently. The fact that 2:1 layer silicates with variable charge formed in the same gel has implications for our understanding of the origin of life, as these 2:1 clay minerals most likely replicate by a mechanism of template-catalyzed polymerization and transmit the charge distribution from layer to layer. If polar organic molecules like oxalate can catalyze the formation of clay-mineral crystals, which in turn promote clay microenvironments and provide abundant adsorption sites for other organic molecules present in solution, the interaction among these adsorbed molecules could lead to the polymerization of more complex organic molecules like RNA from nucleotides on early Earth.

Astrobiology

Metallic spherules in tektites from Isabela, Philippine Islands

Iron-nickel spherules, as much as 0.5 mm in diameter, have been found completely embedded in some philippinites. The spherules consist mainly of kamacite with unidentified pink inclusions. The meteoritic origin of these spherules seems reasonable, suggesting that the tektites containing them were formed by asteroidal or meteoritic impact.

Isabela

Maskelynite: Formation by explosive shock

When high pressure (250 to 300 kilobars) was applied suddenly (shock-loading) to gabbro, the plagioclase was transformed to a noncrystalline phase (maskelynite) by a solid-state reaction at a low temperature, while the proxene remained crystalline. The shock-loaded gabbro resembles meteorites of the shergottite class; this suggests that the latter formed as a result of shock. The shock-loading of gabbro at 600 to 800 kilobars raised the temperature above the melting range of the plagioclase.

Science

Lunar metallic particle ("mini-moon"): An interpretation

A troilite-rich nickel-iron particle ("mini-moon") recovered from the moon may be a mound detached from a sphere of silicate glass. Erosion and pitting of the particle may have been caused by passage through a cloud of hot gas and particulate matter formed by meteorite impact on the lunar surface. This explanation is in contrast to the theory that the particle was meteoritically derived molten material that was furrowed during solidification after lunar impact, subsequently pitted by high-velocity particles, and then abraded and polished by drifting dust while on the lunar surface.

Science

Roadblocks on the kill curve: Testing the Raup hypothesis

The documented presence of two large (~100-km diameter), possibly coeval impact craters of late Eocene age, requires modification of the impact-kill curve proposed by David M. Raup. Though the estimated meteorite size for each crater alone is large enough to have produced considerable global environmental stress, no horizons of mass mortality or pulsed extinction are known to be associated with either crater or their ejecta deposits. Thus, either there is no fixed relationship between extinction magnitude and crater diameter, or a meteorite that would produce a crater of >100-km diameter is required to raise extinction rates significantly above a ~5% background level. Both impacts took place ~1-2 m.y. before the "Terminal Eocene Event" ( =early Oligocene pulsed extinction). Their collective long-term environmental effects, however, may have either delayed that extinction pulse or produced threshold conditions necessary for it to take place.

Palaios

Astronomical observations of volatiles on asteroids

We have long known that water and hydroxyl are important components in meteorites and asteroids. However, in the time since the publication of Asteroids III, evolution of astronomical instrumentation, laboratory capabilities, and theoretical models have led to great advances in our understanding of H 2 O/OH on small bodies, and spacecraft observations of the Moon and Vesta have important implications for our interpretations of the asteroidal population. We begin this chapter with the importance of water/OH in asteroids, after which we will discuss their spectral features throughout the visible and near-infrared. We continue with an overview of the findings in meteorites and asteroids, closing with a discussion of future opportunities, the results from which we can anticipate finding in Asteroids V. Because this topic is of broad importance to asteroids, we also point to relevant in-depth discussions elsewhere in this volume.

Book chapter

Astrogeologic studies, semiannual progress report, February 26, 1961 to August 24, 1961

This report is the second semiannual report on a geological program of research conducted by the Geological Survey on behalf of the National Aeronautics and Space Administration. This research is being carried out under the Branch of Astrogeology. The long-range objectives of this program are to determine and map the stratigraphy and structure of the Moon's crust, to develop basic information on processes that have led to the present condition of the Moon's surface, and to work out the sequence of events in the geologic history recorded in the Moon's stratigraphy and structure. The work includes three closely interrelated areas of study: (1) investigation of the chemistry, petrography, and physical properties of extraterrestrial materials that may have been derived from the Moon, such as tektites, certain types of meteorites, and extraterrestrial dust; (2) experimental and field investigations of the mechanics and phenomena of impact of high-speed objects and of cratering; and (3) geologic mapping of the Moon. Immediate objectives for the fiscal year 1961 have included the preparation of geologic maps for the nominal target area for the Ranger Project of the National Aeronautics and Space Administration. Field and laboratory work on craters was directed toward developing data and an adequate theory for the integrated effect of meteoroid bombardment of the lunar surface. Special attention has been given to phase changes and solid state changes produced in rock by meteorite impact. American and Philippine tektites were the principal materials of possible lunar origin to receive detailed petrographic and chemical analysis.

Open-File Report

Glaciers of Antarctica

Of all the world's continents Antarctica is the coldest, the highest, and the least known. It is one and a half times the size of the United States, and on it lies 91 percent (30,109,800 km 3 ) of the estimated volume of all the ice on Earth. Because so little is known about Antarctic glaciers compared with what is known about glaciers in populated countries, satellite imagery represents a great leap forward in the provision of basic data. From the coast of Antarctica to about 81?south latitude, there are 2,514 Landsat nominal scene centers (the fixed geographic position of the intersection of orbital paths and latitudinal rows). If there were cloud-free images for all these geographic centers, only about 520 Landsat images would be needed to provide complete coverage. Because of cloud cover, however, only about 70 percent of the Landsat imaging area, or 55 percent of the continent, is covered by good quality Landsat images. To date, only about 20 percent of Antarctica has been mapped at scales of 1:250,000 or larger, but these maps do include about half of the coastline. The area of Antarctica that could be planimetrically mapped at a scale of 1:250,000 would be tripled if the available Landsat images were used in image map production. This chapter contains brief descriptions and interpretations of features seen in 62 carefully selected Landsat images or image mosaics. Images were chosen on the basis of quality and interest; for this reason they are far from evenly spaced around the continent. Space limitations allow less than 15 percent of the Landsat imaging area of Antarctica to be shown in the illustrations reproduced in this chapter. Unfortunately, a wealth of glaciological and other features of compelling interest is present in the many hundreds of images that could not be included. To help show some important features beyond the limit of Landsat coverage, and as an aid to the interpretation of certain features seen in the images, 38 oblique aerial photographs have been included. Again, these represent only a small fraction of the large number of aerial photographs now available in various national collections. The chapter is divided into five geographic sections. The first is the Transantarctic Mountains in the Ross Sea area. Some very large outlet glaciers flow from the East Antarctic ice sheet through the Transantarctic Mountains to the Ross Ice Shelf. Byrd Glacier, one of the largest in the world, drains an area of more than 1,000,000 km 2 . Next, images from the Indian Ocean sector are discussed. These include the Lambert Glacier- Amery Ice Shelf system, so large that about 25 images must be mosaicked to cover its complex system of tributary glaciers. Shirase Glacier, a tidal outlet glacier in the sector, flows at a speed of 2.5 km a -l . About 200 km inland and 200 km west of Shirase Glacier lie the Queen Fabiola ("Yamato") Mountains, whose extensive exposures of `blue ice' lay claim to being the world's most important meteorite-collecting locality, with more than 4,700 meteorite fragments discovered since 1969. The Atlantic Ocean sector is fringed by ice shelves into which flow large ice streams like Jutulstraumen, Stancomb-Wills, Slessor, and Recovery Glaciers. Filchner and Ronne Ice Shelves together cover an area two-thirds the size of Texas. From the western margin of the Ronne Ice Shelf, the north-trending arc of the Antarctic Peninsula, with its fjord and alpine landscape and fringing ice shelves, stretches towards South America. The Pacific Ocean sector begins with the Ellsworth Mountains, which include the highest peaks (Vinson Massif at 4,897 m) in Antarctica. The area between the Ellsworth Mountains and the eastern margin of the Ross Ice Shelf is fringed with small ice shelves and some major outlet glaciers. One of these, Pine Island Glacier, was found from comparing 1973 and 1975 images to have an average ice-front velocity of 2.4 km a -1 . This part of Antarctica contains many dormant volcanoes; the summits of servers, such as Mount Takahe with its 8-km-wide summit caldera, protrude through the West Antarctic ice sheet.

Professional Paper

Chapter 9: Theory and processes relating to the lunar maria from the surveyor experiments

Prior to the Surveyor missions, there were three principal theories about the chemical constitution of the lunar maria: that the maria were (1) chondritic, (2) basaltic, or (3) silicic. Three types of materials recovered on Earth were suspected of coming from the maria: (1) chondritic meteorites, (2) basaltic achondrites, and (3) tektites. The Surveyor chemists have now spoken: Turkevich, Franzgrote, and Patterson find that, in Mare Tranquillitatis (ref. 9-1) and Sinus Medii (see ch. 7 of this report), the composition is basaltic. It is unmistakably too poor in magnesium to be like either kind of chondritic meteorite. It is too rich in the heavier elements, iron and calcium, to resemble terrestrial silicic rocks (the granitic kindred) or tektites.

Book chapter

A petrographical and geochemical study of quartzose nodules, country rocks, and dike rocks from the Upheaval Dome structure, Utah

Upheaval Dome, in Canyonlands National Park, Utah, USA, is a unique structure on the Colorado Plateau. It has earlier been interpreted as an impact structure or as a pinched-off salt diapir. Some subrounded quartzose fragments were found in a ring depression near the eastern margin of the structure and, based on vesicularity and apparent flow structure, the fragments were interpreted by early researchers as 'impactites.' Our petrographic studies show no indication of a high-temperature history and are in agreement with a slow, low-temperature formation of the quartz nodules. Compositionally, the lag deposit samples are almost pure SiO2. They show no chemical similarity to any of the possible target rocks (e.g., Navajo Sandstone), from which they should have formed by melting if they were impactites. Instead, the samples have relatively high contents of elements that indicate fluid interaction (e.g., hydrothermal growth), such as As, Sb, Ba, and U, and show positive Ce anomalies. Thus, we interpret the 'lag deposit samples' as normal low-temperature (hydrothermally-grown?) quartz that show no indication of being impact-derived. In addition, a petrographic and geochemical analysis of a series of dike samples yielded no evidence for shock metamorphism or a meteoritic component.

Utah

Hydrothermal alteration at the Lonar Lake impact structure, India: Implications for impact cratering on Mars

The 50,000 year old, 1.8 km diameter Lonar crater is one of only two known terrestrial craters to be emplaced in basaltic target rock (the 65 million year old Deccan Traps). The composition of the Lonar basalts is similar to martian basaltic meteorites, which establishes Lonar as an excellent analogue for similarly sized craters on the surface of Mars. Samples from cores drilled into the Lonar crater floor show that there are basaltic impact breccias that have been altered by post‐impact hydrothermal processes to produce an assemblage of secondary alteration minerals. Microprobe data and X‐ray diffraction analyses show that the alteration mineral assemblage consists primarily of saponite, with minor celadonite, and carbonate. Thermodynamic modeling and terrestrial volcanic analogues were used to demonstrate that these clay minerals formed at temperatures between 130°C and 200°C. By comparing the Lonar alteration assemblage with alteration at other terrestrial craters, we conclude that the Lonar crater represents a lower size limit for impact‐induced hydrothermal activity. Based on these results, we suggest that similarly sized craters on Mars have the potential to form hydrothermal systems, as long as liquid water was present on or near the martian surface. Furthermore, the Fe‐rich alteration minerals produced by post‐impact hydrothermal processes could contribute to the minor iron enrichment associated with the formation of the martian soil.

Lonar Lake; Mars

Bounce Rock-A shergottite-like basalt encountered at Meridiani Planum, Mars

The Opportunity rover of the Mars Exploration Rover mission encountered an isolated rock fragment with textural, mineralogical, and chemical properties similar to basaltic shergottites. This finding was confirmed by all rover instruments, and a comprehensive study of these results is reported here. Spectra from the miniature thermal emission spectrometer and the Panoramic Camera reveal a pyroxene-rich mineralogy, which is also evident in M??ssbauer spectra and in normative mineralogy derived from bulk chemistry measured by the alpha particle X-ray spectrometer. The correspondence of Bounce Rock's chemical composition with the composition of certain basaltic shergottites, especially Elephant Moraine (EET) 79001 lithology B and Queen Alexandra Range (QUE) 94201, is very close, with only Cl, Fe, and Ti exhibiting deviations. Chemical analyses further demonstrate characteristics typical of Mars such as the Fe/Mn ratio and P concentrations. Possible shock features support the idea that Bounce Rock was ejected from an impact crater, most likely in the Meridiani Planum region. Bopolu crater, 19.3km in diameter, located 75km to the southwest could be the source crater. To date, no other rocks of this composition have been encountered by any of the rovers on Mars. The finding of Bounce Rock by the Opportunity rover provides further direct evidence for an origin of basaltic shergottite meteorites from Mars.

Meteoritics and Planetary Science

Neutron absorption constraints on the composition of 4 Vesta

Global maps of the macroscopic thermal neutron absorption cross section of Vesta's regolith by the Gamma Ray and Neutron Detector (GRaND) on board the NASA Dawn spacecraft provide constraints on the abundance and distribution of Fe, Ca, Al, Mg, and other rock-forming elements. From a circular, polar low-altitude mapping orbit, GRaND sampled the regolith to decimeter depths with a spatial resolution of about 300 km. At this spatial scale, the variation in neutron absorption is about seven times lower than that of the Moon. The observed variation is consistent with the range of absorption for howardite whole-rock compositions, which further supports the connection between Vesta and the howardite, eucrite, and diogenite meteorites. We find a strong correlation between neutron absorption and the percentage of eucritic materials in howardites and polymict breccias, which enables petrologic mapping of Vesta's surface. The distribution of basaltic eucrite and diogenite determined from neutron absorption measurements is qualitatively similar to that indicated by visible and near infrared spectroscopy. The Rheasilvia basin and ejecta blanket has relatively low absorption, consistent with Mg-rich orthopyroxene. Based on a combination of Fe and neutron absorption measurements, olivine-rich lithologies are not detected on the spatial scales sampled by GRaND. The sensitivity of GRaND to the presence of mantle material is described and implications for the absence of an olivine signature are discussed. High absorption values found in Vesta's “dark” hemisphere, where exogenic hydrogen has accumulated, indicate that this region is richer in basaltic eucrite, representative of Vesta's ancient upper crust.

Meteoritics and Planetary Science

Chesapeake Bay impact structure: Morphology, crater fill, and relevance for impact structures on Mars

The late Eocene Chesapeake Bay impact structure (CBIS) on the Atlantic margin of Virginia is one of the largest and best-preserved "wet-target" craters on Earth. It provides an accessible analog for studying impact processes in layered and wet targets on volatile-rich planets. The CBIS formed in a layered target of water, weak clastic sediments, and hard crystalline rock. The buried structure consists of a deep, filled central crater, 38 km in width, surrounded by a shallower brim known as the annular trough. The annular trough formed partly by collapse of weak sediments, which expanded the structure to ???85 km in diameter. Such extensive collapse, in addition to excavation processes, can explain the "inverted sombrero" morphology observed at some craters in layered targets. The distribution of crater-fill materials i n the CBIS is related to the morphology. Suevitic breccia, including pre-resurge fallback deposits, is found in the central crater. Impact-modified sediments, formed by fluidization and collapse of water-saturated sand and silt-clay, occur in the annular trough. Allogenic sediment-clast breccia, interpreted as ocean-resurge deposits, overlies the other impactites and covers the entire crater beneath a blanket of postimpact sediments. The formation of chaotic terrains on Mars is attributed to collapse due to the release of volatiles from thick layered deposits. Some flat-floored rimless depressions with chaotic infill in these terrains are impact craters that expanded by collapse farther than expected for similar-sized complex craters in solid targets. Studies of crater materials in the CBIS provide insights into processes of crater expansion on Mars and their links to volatiles. ?? The Meteoritical Society, 2006.

Meteoritics and Planetary Science

Galileo Photometry of Asteroid 951 Gaspra

Galileo images of Gaspra make it possible for the first time to determine a main-belt asteroid's photometric properties accurately by providing surface-resolved coverage over a wide range of incidence and emission angles and by extending the phase angle coverage to phases not observable from Earth. We combine Earth-based telescopic photometry over phase angles 2° ≤ α ≤ 25° with Galileo whole-disk and disk-resolved data at 33° ≤ α ≤ 51° to derive average global photometric properties in terms of Hapke's photometric model. The microscopic texture and particle phase-function behavior of Gaspra's surface are remarkably like those of other airless rocky bodies such as the Moon. The macroscopic surface roughness parameter, θ̄ = 29°, is slightly larger than that reported for typical lunar materials. The particle single scattering albedo, ώ 0 = 0.36 ± 0.07, is significantly larger than for lunar materials, and the opposition surge amplitude, B 0 = 1.63 ± 0.07, is correspondingly smaller. We determine a visual geometric albedo p v = 0.22 ± 0.06 for Gaspra, in close agreement with p v = 0.22 ± 0.03 estimated from Earth-based observations. Gaspra's phase integral is 0.47, and the bolometric Bond albedo is estimated to be 0.12 ± 0.03. An albedo map derived by correcting Galileo images with our average global photometric function reveals subdued albedo contrasts of ±10% or less over Gaspra's northern hemisphere. Several independent classification algorithms confirm the subtle spectral heterogeneity reported earlier (S. Mottola, M. DiMartino, M. Gonano-Beurer, H. Hoffman, and G. Neukum, 1993, Asteroids, Comets, Meteors, pp. 421-424; M. J. S. Belton et al ., 1992, Science 257, 1647-1652). Whole-disk colors (0.41 ≤ λ ≤ 0.99 μm) vary systematically with longitude by about ±5%, but color differences as large as 30% occur locally. Colors vary continuously between end-member materials whose areal distribution correlates with regional topography. Infrared: violet (0.99:0.41-μm) color ratios on Gaspra are strongly correlated with local elevation, being largest at lower elevations and smaller at higher elevations. No correlation was detected between elevation and the green:violet (0.56:0.41-μm) color ratio. Bright materials with a strong 1-μm absorption occur primarily in association with craters along ridges, while darker materials with 30% weaker 1-μm signatures occur downslope. The variations of color and albedo cannot be easily explained by grain-size effects alone or by differences in photometric geometry. The trends observed are consistent with those revealed by laboratory studies of the effects of comminution, glass formation, and segregation of metal from silicate components in chondritic meteorites and also in some silicate mixtures. The relative importance of these various processes on Gaspra remains to be determined.

Icarus