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Byproduct metals and rare-earth elements used in the production of light-emitting diodes—Overview of principal sources of supply and material requirements for selected markets

The use of light-emitting diodes (LEDs) is expanding because of environmental issues and the efficiency and cost savings achieved compared with use of traditional incandescent lighting. The longer life and reduced power consumption of some LEDs have led to annual energy savings, reduced maintenance costs, and lower emissions of carbon dioxide, sulfur dioxide, and nitrogen oxides from powerplants because of the resulting decrease in energy consumption required for lighting applications when LEDs are used to replace less-energy-efficient sources. Metals such as arsenic, gallium, indium, and the rare-earth elements (REEs) cerium, europium, gadolinium, lanthanum, terbium, and yttrium are important mineral materials used in LED semiconductor technology. Most of the world's supply of these materials is produced as byproducts from the production of aluminum, copper, lead, and zinc. Most of the rare earths required for LED production in 2011 came from China, and most LED production facilities were located in Asia. The LED manufacturing process is complex and is undergoing much change with the growth of the industry and the changes in demand patterns of associated commodities. In many respects, the continued growth of the LED industry, particularly in the general lighting sector, is tied to its ability to increase LED efficiency and color uniformity while decreasing the costs of producing, purchasing, and operating LEDs. Research is supported by governments of China, the European Union, Japan, the Republic of Korea, and the United States. Because of the volume of ongoing research in this sector, it is likely that the material requirements of future LEDs may be quite different than LEDs currently (2011) in use as industry attempts to cut costs by reducing material requirements of expensive heavy rare-earth phosphors and increasing the sizes of wafers for economies of scale. Improved LED performance will allow customers to reduce the number of LEDs in automotive, electronic, and lighting applications, which could reduce the overall demand for material components. Non-Chinese sources for rare earths are being developed, and some of these new sources are likely to be operational in time to meet increasing demand for rare earths from the LED sector. Because most LED component production and manufacturing occurs in Asia and many LED producers have established supply contracts with Chinese producers of rare earths, a significant amount of the metallic gallium, indium, and the rare earths used for LED production will likely continue to come from Chinese sources at least for the next 5 years; however, a greater amount of these materials are now being processed in Japan, the Republic of Korea, and Taiwan. As non-Chinese sources of rare earths come into production, these new mines are likely to be sources of light REEs, but China will likely remain the leading source of supply for the heavy REEs suitable for use as LED dopants and phosphors at least for the next few years. Increased research in the development of phosphors that use smaller amounts of or different REEs is intended to reduce dependence on rare earths from China. Supply disruption of rare earths and other specialty metals could take place if China's specialty metal exports are redirected to domestic markets. The cost of recovery is high and the lifespan for LEDs is comparatively long; thus, the LED waste volume was low in 2010, and few LEDs were recycled. The minute metal content of LEDs leads to a high cost for recovery, so recycling of LEDs outside of electronic waste is unlikely in the near term, although some LED producers are evaluating recycling options. Recycling of metals from LEDs in electronic waste is possible if the costs of recovering metals are justified by demand and metal prices.

Scientific Investigations Report

Evaluation of larval sea lamprey Petromyzon marinus growth in the laboratory: Influence of temperature and diet

Conservation aquaculture provides a means for promoting environmental stewardship, useful both in the context of restoring native species and limiting the production of invasive species. Aquaculture of lampreys is a relatively recent endeavor aimed primarily at producing animals to support the restoration of declining native populations. However, in the Laurentian Great Lakes, where sea lamprey Petromyzon marinus are invasive, the ability to acquire a reliable source of certain life stages would be a significant benefit to those controlling their populations and studying the species. Here, we apply methodologies developed for Pacific lamprey Entosphenus tridentatus restoration to investigate the feasibility of rearing larval sea lamprey under laboratory conditions. In two experiments lasting 3 and 9 months, we tested the effects of different dietary sources and water temperature (ambient and controlled) on the survival and growth of wild-caught larvae. Rearing conditions had no effect on mortality, as larval survival was 100% in both experiments. Growth was significantly affected by water temperature, with the highest average daily growth rates observed at 22 and 15°C (0.14 mm day −1 ) and lowest at 8°C (0.06 mm day −1 ). Diets of yeast alone (0.19 and 0.21 g L −1 ) performed better than those comprising a mixture of yeast and other material when fed 3 times weekly (rice flour, wheat flour, fish meal; 0.19 and 0.32 g L −1 ). Averaged across the three constant temperatures (8, 15, and 22°C), larvae fed on yeast grew 0.13 mm day −1 and 0.01 g day −1 , whereas on yeast + fish meal, they grew 0.09 mm day −1 and 0.01 g day −1 . At ambient temperature (4–20°C), larvae fed on yeast grew 0.15 mm day −1 and 0.01 g day −1 , whereas those fed on yeast + wheat flour grew 0.13 mm day −1 and 0.008 g day −1 and those fed on yeast + rice flour grew 0.12 mm day −1 and 0.009 g day −1 . An experimental duration of 90 days was sufficient to detect significant changes to larval sea lamprey growth stemming from temperature variation. Overall, rearing of sea lamprey in captivity appears feasible at low density (31–32 g m −2 and 17–25 larvae m −2 ), but uncertainties remain regarding the most appropriate means of providing adequate feed for these fish in high-density conditions.

Aquaculture Research

Shift in Global Tantalum Mine Production, 2000–2014

Introduction Tantalum has a unique set of properties that make it useful in a number of diverse applications. The ability of the metal to store and release electrical energy makes it ideally suited for use in certain types of capacitors that are widely used in modern electronics. Approximately 60 percent of global tantalum consumption is in the electronics industry. The ductility and corrosion resistance of the metal lends itself to application in the chemical processing industry, and its high melting point and high strength retention at elevated temperatures make it an important component of super alloys used in aircraft engines. As a major industrialized nation, the United States is a leading consumer of tantalum and tantalum-containing products. Domestic deposits typically are of low grade, and no tantalum has been recovered from mining activities in the United States since 1959. Consequently, the United States is nearly completely reliant on imports to meet its domestic consumption of tantalum for economic and national security needs. The recovery of tantalum from mine production is economically viable in only a few countries. Although developed countries dominated tantalum mine production in the early 2000s, production today is dominated by countries in the Great Lakes Region of Africa. There is concern that the sales of minerals, including columbite-tantalite or “coltan,” a mineral from which tantalum is derived, have helped finance rebel groups accused of violating human rights as part of the continuing armed conflict in the Democratic Republic of the Congo (DRC) and neighboring countries. These accusations have prompted the passage of legislation in the United States to curb the procurement of these mineral commodities, referred to as “conflict minerals,” from the DRC. Specifically, section 1502 of the 2010 Dodd-Frank Wall Street Reform and Consumer Protection Act (Public Law 111–203, 124 Stat. 2213–2218) requires companies that source tantalum, tin, tungsten, and gold (3TG) to perform due diligence on their supply chains to determine if the materials they use originate from the DRC or adjoining countries (defined as sharing a border with the DRC). The DRC, Rwanda, and surrounding countries are not globally significant sources of tin, tungsten, or gold, accounting for only about 2 percent of the mined world supply for each of these elements. The region has, however, evolved to become the world’s largest producer of mined tantalum. A further complication of the production of tantalum stems from the opacity of the tantalum market. Unlike most base and precious metals, tantalum concentrates are not publicly traded through commodities exchanges but are bought and sold through networks of dealers and on contract between producers and consumers, some of whom may not provide accurate statistical data concerning the amounts, origins, and destination of the concentrates. Some price data can be found in trade journals or in other publications; however, there are no recognized official set exchange prices for either concentrate or tantalum metal. Because price is determined by negotiation between buyer and seller, published prices for concentrate are probably not representative of global prices paid for concentrate. The development of a mine-to-market supply-chain analysis is complicated and difficult because many of the industry participants that produce, trade, and consume tantalum do not publish statistical information, contracts are long term between miners and buyers, and much of the industry is vertically integrated. As a result of these and other considerations, tantalum is considered by many to be a “critical” commodity. This fact sheet identifies and addresses the major geographic shifts in the source of mine production of tantalum which have occurred over the past 15 years, some of the factors that drove this shift, and some of the related consequences. One of the activities of the U.S. Geological Survey National Minerals Information Center (USGS-NMIC) is to analyze global supply chains and characterize major components of mineral and material flows from ore extraction through processing to first tier products. These analyses support the core mission of the USGS-NMIC as the Federal entity responsible for the collection, analysis, and dissemination of objective, unbiased, factual information on minerals essential to the U.S. economy and national security.

Fact Sheet

Geologic and seismic investigations for relocation of Route 138 in Brockton, Mass., prospective cut, stations 169 to 180

This work was done to obtain geologic and seismic data that would aid in establishing grade for a segment of Route 138 between stations 169 and 180, and that would also be of value in estimating the nature and quantities of subsurface materials to be estimating the nature and quantities of subsurface materials to be excavated from the proposed cut. The work was performed in August 1952, as part of a cooperative program pf the Massachusetts Department of Public Works and the United States Geological Survey.

Massachusetts

Geotechnical engineering for ocean waste disposal. An introduction

As members of multidisciplinary teams, geotechnical engineers apply quantitative knowledge about the behavior of earth materials toward designing systems for disposing of wastes in the oceans and monitoring waste disposal sites. In dredge material disposal, geotechnical engineers assist in selecting disposal equipment, predict stable characteristics of dredge mounds, design mound caps, and predict erodibility of the material. In canister disposal, geotechnical engineers assist in specifying canister configurations, predict penetration depths into the seafloor, and predict and monitor canister performance following emplacement. With sewage outfalls, geotechnical engineers design foundation and anchor elements, estimate scour potential around the outfalls, and determine the stability of deposits made up of discharged material. With landfills, geotechnical engineers evaluate the stability and erodibility of margins and estimate settlement and cracking of the landfill mass. Geotechnical engineers also consider the influence that pollutants have on the engineering behavior of marine sediment and the extent to which changes in behavior affect the performance of structures founded on the sediment. In each of these roles, careful application of geotechnical engineering principles can contribute toward more efficient and environmentally safe waste disposal operations.

Conference Paper

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Extraction of nitroaromatic compounds from water by polystyrene divinylbenzene cartridge and determination by high-performance liquid chromatography

Organic explosives are determined in samples of ground water and surface water with emphasis on identifying and quantifying trinitrotoluene (TNT) metabolites. Water samples are filtered to remove suspended particulate material and passed through a polystyrene divinylbenzene-packed cartridge by a vacuum-extraction system. The target analytes subsequently are eluted with acetonitrile. A high-performance liquid chromatograph (HPLC) equipped with a photodiode-array detector is used for sample analysis. Analytes are separated on an octadecylsilane column using a methanol, water, and acetonitrile gradient elution. The compounds 2,4- and 2,6-dinitrotoluene are separated through an independent, isocratic elution. Method detection limits, on the basis of a 1-liter sample size, range from 0.11 to 0.32 microgram per liter. Recoveries averaged from 71 to 101 percent for 13 analytes in one set of HPLC-grade water fortified at about 1 microgram per liter. The method is limited to use by analysts experienced in handling explosive materials. (USGS)

Open-File Report

Volcanic plume height measured by seismic waves based on a mechanical model

In August 2008 an unmonitored, largely unstudied Aleutian volcano, Kasatochi, erupted catastrophically. Here we use seismic data to infer the height of large eruptive columns such as those of Kasatochi based on a combination of existing fluid and solid mechanical models. In so doing, we propose a connection between a common, observable, short-period seismic wave amplitude to the physics of an eruptive column. To construct a combined model, we estimate the mass ejection rate of material from the vent on the basis of the plume height, assuming that the height is controlled by thermal buoyancy for a continuous plume. Using the estimated mass ejection rate, we then derive the equivalent vertical force on the Earth through a momentum balance. Finally, we calculate the far-field surface waves resulting from the vertical force. The model performs well for recent eruptions of Kasatochi and Augustine volcanoes if v , the velocity of material exiting the vent, is 120-230 m s -1 . The consistency between the seismically inferred and measured plume heights indicates that in these cases the far-field ~1 s seismic energy radiated by fluctuating flow in the volcanic jet during the eruption is a useful indicator of overall mass ejection rates. Thus, use of the model holds promise for characterizing eruptions and evaluating ash hazards to aircraft in real time on the basis of far-field short-period seismic data. This study emphasizes the need for better measurements of eruptive plume heights and a more detailed understanding of the full spectrum of seismic energy radiated coeruptively.

Journal of Geophysical Research B: Solid Earth

The nature of bacteria pathogenic to fish

A review is made of the progress in research on bacteria which are pathogenic to fish, with particular emphasis on those investigations performed during the past decade. The report includes a critical review of material published; the comments and suggestions are designed to stimulate the initiation of new research projects.

Transactions of the American Fisheries Society

Geophysical and hydrologic analysis of an earthen dam site in southern Westchester County, New York

Ninety percent of the drinking water for New York City passes through the Hillview Reservoir facility in the City of Yonkers, Westchester County, New York. In the past, several seeps located downslope from the reservoir have flowed out from the side of the steepest slope at the southern end of the earthen embankment. One seep that has been flowing continuously was discovered during an inspection of the embankment in 1999. Efforts were made in 2001 to locate the potential sources of the continuous flowing seep. In 2005, the U.S. Geological Survey, in cooperation with the New York City Department of Environmental Protection, began a cooperative study to investigate the relevant hydrogeologic framework to characterize the local groundwater-flow system and to determine possible sources of the seeps. The two agencies used hydrologic and surface geophysical techniques to assess the earthen embankment of the Hillview Reservoir. Between April 1, 2005 and March 1, 2008, water levels were measured manually each month at 46 wells surrounding the reservoir, and flow was measured monthly at three of the five seeps on the embankment. Water levels were measured hourly in the East Basin of the reservoir, at 24 of 46 wells, and discharge was measured hourly at two of the five seeps. Slug tests were performed at 16 wells to determine the hydraulic conductivity of the geologic material surrounding the screened zone. Estimated hydraulic conductivities for 25 wells on the southern embankment ranged from 0.0063 to 1.2 feet per day and averaged 0.17 foot per day. The two-dimensional resistivity surveys indicate a subsurface mound of electrically conductive material (low-resistivity zone) beneath the terrace area (top of dam) surrounding the reservoir with a distinct elevation increase closer to the crest. Two-dimensional shear wave velocity surveys indicate a similar structure of the high shear wave velocity materials (high-velocity zone), increasing in elevation toward the crest and decreasing toward the reservoir and toward the northern part of the study area. Water-quality samples collected from 12 wells, downtake chamber 1 of the reservoir, and two seeps detected the presence of arsenic, toluene, and two trihalomethanes. Water-quality samples collected at the two seeps detected fluoride, indicating a connection with reservoir water. Shallow wells on the southern embankment exhibited the largest seasonal water-level fluctuations ranging between 6 feet and 12 feet. The embankment is constructed from reworked low-permeability glacial deposits at the site. Water-level responses in observation wells within the embankment indicate that there is a shallow (approximately the upper 45 feet of the embankment) and a deep water-bearing unit within the embankment with a large downward vertical gradient between the shallow and deep water-bearing units. Precipitation strongly affected water levels in shallow wells, whereas the basin appears to be the main control on water levels in the deep wells. Seeps on the embankment slope appear to be caused by above-average precipitation that increases water levels in the shallow water-bearing unit, but does not easily recharge the deep water-bearing unit. Based on the data that have been analyzed, source water to the seeps appears to be primarily groundwater and, to a lesser extent, water from the East Basin of the reservoir.

New York

Stratification of a cityscape using census and land use variables for inventory of building materials

A cityscape (or any landscape) can be stratified into environmental units using multiple variables of information. For the purposes of sampling building materials, census and land use variables were used to identify similar strata. In the Metropolitan Statistical Area of a cityscape, the census tract is the smallest unit for which census data are summarized and digitized boundaries are available. For purposes of this analysis, census data on total population, total number of housing units, and number of singleunit dwellings were aggregated into variables of persons per square kilometer and proportion of housing units in single-unit dwellings. The level 2 categories of the U.S. Geological Survey's land use and land cover data base were aggregated into variables of proportion of residential land with buildings, proportion of nonresidential land with buildings, and proportion of open land. The cityscape was stratified, from these variables, into environmental strata of Urban Central Business District, Urban Livelihood Industrial Commercial, Urban Multi-Family Residential, Urban Single Family Residential, Non-Urban Suburbanizing, and Non-Urban Rural. The New England region was chosen as a region with commonality of building materials, and a procedure developed for trial classification of census tracts into one of the strata. Final stratification was performed by discriminant analysis using the trial classification and prior probabilities as weights. The procedure was applied to several cities, and the results analyzed by correlation analysis from a field sample of building materials. The methodology developed for stratification of a cityscape using multiple variables has application to many other types of environmental studies, including forest inventory, hydrologic unit management, waste disposal, transportation studies, and other urban studies. Multivariate analysis techniques have recently been used for urban stratification in England. ?? 1987 Annals of Regional Science.

The Annals of Regional Science

Quality assurance and quality control in light stable isotope laboratories: A case study of Rio Grande, Texas, water samples

New isotope laboratories can achieve the goal of reporting the same isotopic composition within analytical uncertainty for the same material analysed decades apart by (1) writing their own acceptance testing procedures and putting them into their mass spectrometric or laser-based isotope-ratio equipment procurement contract, (2) requiring a manufacturer to demonstrate acceptable performance using all sample ports provided with the instrumentation, (3) for each medium to be analysed, prepare two local reference materials substantially different in isotopic composition to encompass the range in isotopic composition expected in the laboratory and calibrated them with isotopic reference materials available from the International Atomic Energy Agency (IAEA) or the US National Institute of Standards and Technology (NIST), (4) using the optimum storage containers (for water samples, sealing in glass ampoules that are sterilised after sealing is satisfactory), (5) interspersing among sample unknowns local laboratory isotopic reference materials daily (internationally distributed isotopic reference materials can be ordered at three-year intervals, and can be used for elemental analyser analyses and other analyses that consume less than 1 mg of material) – this process applies to H, C, N, O, and S isotope ratios, (6) calculating isotopic compositions of unknowns by normalising isotopic data to that of local reference materials, which have been calibrated to internationally distributed isotopic reference materials, (7) reporting results on scales normalised to internationally distributed isotopic reference materials (where they are available) and providing to sample submitters the isotopic compositions of internationally distributed isotopic reference materials of the same substance had they been analysed with unknowns, (8) providing an audit trail in the laboratory for analytical results – this trail commonly will be in electronic format and might include a laboratory information management system, (9) making at regular intervals a complete backup of laboratory analytical data (both of samples logged into the laboratory and of mass spectrometric analyses), being sure to store one copy of this backup offsite, and (10) participating in interlaboratory comparison exercises sponsored by the IAEA and other agencies at regular intervals.

Isotopes in Environmental and Health Studies

Pysochron: A Python-based solution for calculating cosmogenic 26Al/10Be isochron burial ages

Cosmogenic 26 Al/ 10 Be isochron burial dating is a powerful tool for dating sediment burial over the past several million years. By measuring in-situ 26 Al and 10 Be in a suite of samples from the same depth in a buried deposit, it is possible to quantify the inventory of cosmogenic nuclides produced after burial, date the burial of shallow sediments, identify sediment reworking, and calculate paleo-erosion rates. While this approach has been used to date materials around the world for over a decade, few published codes exist for performing 26 Al/ 10 Be isochron calculations. The isochron calculation options that are available typically rely on numerous files and libraries, rendering modification and troubleshooting difficult. Moreover, the widespread use of proprietary programming languages – and their associated addon packages – can place an additional financial burden on an already costly endeavor. Pysochron ( https://code.usgs.gov/recon/pysochron ) provides a solution to these issues. In its base form, it exists as a single script that can be easily modified, upgraded, and shared. Because it was developed in an open-source environment, all required computational packages are available free of charge. A user-friendly interface allows rapid modification of calculation parameters, and an automated commentary on isochron results provides insights and recommendations. Pysochron has been validated with 40 published cosmogenic 26 Al/ 10 Be burial isochrons around the world, with burial ages ranging from ∼5 Ma to ∼180 ka. As such, it is a promising option for members of the cosmogenic nuclide community seeking a straightforward, cost-effective, and flexible solution to isochron burial dating challenges.

Quaternary Geochronology

Quality of water and bed material in streams of Logan Township, Gloucester County, New Jersey, 1984

The surface water and surficial-bed material at seven stations on three streams in Logan Township, Gloucester County, New Jersey, were sampled in the fall of 1984. Samples of water were analyzed for volatile organic compounds, trace metals, and organochlorine and organophosphorous compounds. Surficial-bed material was analyzed for extractable trace metals and organochlorine compounds. Water samples from two closely spaced sampling locations along Raccoon Creek contained elevated concentrations of methylene chloride (455 and 1800 micrograms/L, respectively), a volatile organic solvent. Bed-material samples taken from Little Timber and Birch Creeks contained elevated levels of trace metals and organochlorine compounds, including polychlorinated biphenyls (PCB's). Contaminant concentrations in bed-material samples taken from Raccoon Creek were much lower than those found previously by the U.S. Geological Survey in 1980. Only a trace of PCB 's was detected in any bed material sample taken from Racoon Creek. Gas chromatographic flame-ionization detector scans, performed on solvent extracts of all water and sediment samples, were useful in characterizing the presence or absence of organic contaminants in those samples. Changes in the character of organic contamination along the reaches of two streams were apparent when the fingerprints of chromatograms representing upstream sites were compared to those representing downstream sites. (Author 's abstract)

Water-Resources Investigations Report

Sediment dynamics in the Adriatic Sea investigated with coupled models

Several large research programs focused on the Adriatic Sea in winter 2002-2003, making it an exciting place for sediment dynamics modelers (Figure 1). Investigations of atmospheric forcing and oceanic response (including wave generation and propagation, water-mass formation, stratification, and circulation), suspended material, bottom boundary layer dynamics, bottom sediment, and small-scale stratigraphy were performed by European and North American researchers participating in several projects. The goal of EuroSTRATAFORM researchers is to improve our ability to understand and simulate the physical processes that deliver sediment to the marine environment and generate stratigraphic signatures. Scientists involved in the Po and Apennine Sediment Transport and Accumulation (PASTA) experiment benefited from other major research programs including ACE (Adriatic Circulation Experiment), DOLCE VITA (Dynamics of Localized Currents and Eddy Variability in the Adriatic), EACE (the Croatian East Adriatic Circulation Experiment project), WISE (West Istria Experiment), and ADRICOSM (Italian nowcasting and forecasting) studies.

Adriatic Sea

Southwest Washington littoral drift restoration—Beach and nearshore morphological monitoring

A morphological monitoring program has documented the placement and initial dispersal of beach nourishment material (280,000 m3) placed between the Mouth of the Columbia River (MCR) North Jetty and North Head, at the southern end of the Long Beach Peninsula in southwestern Washington State. A total of 21 topographic surveys and 8 nearshore bathymetric surveys were performed between July 11, 2010, and November 4, 2011. During placement, southerly alongshore transport resulted in movement of nourishment material to the south towards the MCR North Jetty. Moderate wave conditions (significant wave height around 4 m) following the completion of the nourishment resulted in cross-shore sediment transport, with most of the nourishment material transported into the nearshore bars. The nourishment acted as a buffer to the more severe erosion, including dune overtopping and retreat, that was observed at the northern end of the study area throughout the winter. One year after placement of the nourishment, onshore transport and beach recovery were most pronounced within the permit area and to the south toward the MCR North Jetty. This suggests that there is some long-term benefit of the nourishment for reducing erosion rates locally, although the enhanced recovery also could be due to natural gradients in alongshore transport causing net movement of the sediment from north to south. Measurements made during the morphological monitoring program documented the seasonal movement and decay of nearshore sand bars. Low-energy conditions in late summer resulted in onshore bar migration early in the monitoring program. Moderate wave conditions in the autumn resulted in offshore movement of the middle bar and continued onshore migration of the outer bar. High-energy wave conditions early in the winter resulted in strong cross-shore transport and creation of a 3-bar system along portions of the coast. More southerly wave events occurred later in the winter and early spring and coincided with the complete loss of the outer bar and net loss of sediment from the study area. These data suggest that bar decay may be an important mechanism for exporting sediment from Benson Beach north to the Long Beach Peninsula. The measurements presented in this report represent one component of a broader monitoring program designed to track the movement of nourishment material on the beach and shoreface at this location, including continuous video monitoring (Argus), in situu measurements of hydrodynamics, and a physical tracer experiment. Field data from the monitoring program will be used to test numerical models of hydrodynamics and sediment transport and to improve the capability of numerical models to support regional sediment management.

Washington

Bed-sediment grain-size and morphologic data from Suisun, Grizzly, and Honker Bays, CA, 1998-2002

The USGS Place Based Studies Program for San Francisco Bay investigates this sensitive estuarine system to aid in resource management. As part of the inter-disciplinary research program, the USGS collected side-scan sonar data and bed-sediment samples from north San Francisco Bay to characterize bed-sediment texture and investigate temporal trends in sedimentation. The study area is located in central California and consists of Suisun Bay, and Grizzly and Honker Bays, sub-embayments of Suisun Bay. During the study (1998-2002), the USGS collected three side-scan sonar data sets and approximately 300 sediment samples. The side-scan data revealed predominantly fine-grained material on the bayfloor. We also mapped five different bottom types from the data set, categorized as featureless, furrows, sand waves, machine-made, and miscellaneous. We performed detailed grain-size and statistical analyses on the sediment samples. Overall, we found that grain size ranged from clay to fine sand, with the coarsest material in the channels and finer material located in the shallow bays. Grain-size analyses revealed high spatial variability in size distributions in the channel areas. In contrast, the shallow regions exhibited low spatial variability and consistent sediment size over time.

California

Seismic hazard classifications and Vs30 in Connecticut using MASW and HVSR methods

Five new seismic hazard classifications for Hartford County, Connecticut (CT), were proposed by New England State Geologists (NESG) in an effort to improve the current USGS Seismic Hazard Map. These classes were derived from mapped surficial materials, but in situ information is required to verify this approach. Therefore, active and passive surface wave techniques were performed at thirty field sites to determine V S30 and compare the results to the NESG map. Passive data were processed using the Horizontal-to-Vertical Spectral Ratio (HVSR); active data were processed with the multi-channel analysis of surface waves (MASW) technique. The field investigation demonstrated that the surficial material-based system was not sufficient for 66% of the field sites and in-situ velocity information from at least two methods should be considered for improved classification. The geophysical work discussed here represents the first field de-rived V S30 values for Hartford County, CT.

Conference Paper

The effect of wet-dry weathering on the rate of bedrock river channel erosion by saltating gravel

Previous work has shown that the bedrock erosion rate E because of collisions of saltating bedload can be expressed by E = βq b (1- P c ), where q b is the sediment transport rate, P c is the extent of alluvial cover, and β is the abrasion coefficient. However, the dependence of the abrasion coefficient on the physical characteristics of the bedrock material is poorly known, and in particular, the effects of wet-dry weathering on the saltation-abrasion bedrock incision has not been specifically characterized. Observation suggests that the typical wet-dry cycling of exposed bedrock in river beds gives rise to cracks and voids that are likely to alter the incision rate of the material when subjected to impacts of moving sediment. In this study, flume experiments are performed to develop an understanding of how wet-dry cycling affects the rock tensile strength and the bedrock erosion rate. To represent the physical effects of weathering, boring cores taken from natural bedrock channel are exposed to artificial wet-dry cycles. The experimental results suggest the following: (1) the abrasion coefficient for fresh bedrock is estimated by β = 1.0 × 10 − 4 σ T − 2 ( d / k sb ) 0.5 , where σ T is the tensile strength, d is the diameter of colliding gravel, and k sb is the hydraulic roughness height of bedrock; (2) the tensile strength of the bedrock decreases exponentially as a result of repeated wet-dry cycles, σ T /σ T 0 = exp (- C T NW a 0 /σ T 0 ), where σ T 0 is the initial tensile strength, W a 0 is the initial normalized rate of water absorption., N is the number of wet-dry cycles, and C T is a constant; (3) the erosion rate of fresh bedrock depends on the inverse of the square of tensile strength, but the erosion rate of weathered bedrock depends on the − 1.5 power of tensile strength.

Geomorphology