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A new basaltic glass microanalytical reference material for multiple techniques

The U.S. Geological Survey (USGS) has been producing reference materials since the 1950s. Over 50 materials have been developed to cover bulk rock, sediment, and soils for the geological community. These materials are used globally in geochemistry, environmental, and analytical laboratories that perform bulk chemistry and/or microanalysis for instrument calibration and quality assurance testing. To answer the growing demand for higher spatial resolution and sensitivity, there is a need to create a new generation of microanalytical reference materials suitable for a variety of techniques, such as scanning electron microscopy/X-ray spectrometry (SEM/EDS), electron probe microanalysis (EPMA), laser ablation inductively coupled mass spectrometry (LA-ICP-MS), and secondary ion mass spectrometry (SIMS). As such, the microanalytical reference material (MRM) needs to be stable under the beam, be homogeneous at scales of better than 10–25 micrometers for the major to ultra-trace element level, and contain all of the analytes (elements or isotopes) of interest. Previous development of basaltic glasses intended for LA-ICP-MS has resulted in a synthetic basaltic matrix series of glasses (USGS GS-series) and a natural basalt series of glasses (BCR-1G, BHVO-2G, and NKT-1G). These materials have been useful for the LA-ICP-MS community but were not originally intended for use by the electron or ion beam community. A material developed from start to finish with intended use in multiple microanalytical instruments would be useful for inter-laboratory and inter-instrument platform comparisons. This article summarizes the experiments undertaken to produce a basalt glass reference material suitable for distribution as a multiple-technique round robin material. The goal of the analytical work presented here is to demonstrate that the elemental homogeneity of the new glass is acceptable for its use as a reference material. Because the round robin exercise is still underway, only nominal compositional ranges for each element are given in the article.

Microscopy Today↗

Analysis of different sensor performances in impervious surface mapping

The U.S. Geological Survey (USGS) has developed the National Land Cover Database (NLCD) to provide consistent land cover and land cover change products for the nation since 2001. As one of products in the NLCD, the percent impervious surface area (ISA), which was estimated with Landsat imagery, represents the fraction of human-made impervious area in a 30-m grid and has been used to quantify urban land cover types and extents for the United States. However, it is still a challenge to clearly determine urban land cover intensity and extents using remote sensing data with spatial and spectral resolutions similar to Landsat in part because of highly heterogeneous features of urban land cover. Most urban areas, especially in low intensity development areas, exhibit sub-pixel characteristics that mix impervious surface with other land covers (e.g., grass and trees) in the 30-m resolution satellite imagery. Furthermore, the influence of highly heterogeneous features in many urban areas and how they alter the spectral signature of urban landscapes has not yet been fully studied. Recent advances in remote sensing technology have provided multiple spectral and spatial resolution data from several satellites including WorldView (WV), Sentinel-2, and the Landsat Operational Land Imager (OLI). Remote sensing images having different spectral bands and high spatial resolution provide the potential to derive detailed information on the nature and properties of different surface materials on the urban ground. This study focuses on performance of mapping impervious surface using data collected from WorldView-3, Sentinel-2, and Landsat OLI. We compared ISA results estimated from these sensors and evaluated benefits and limitations of radiometric and spatial resolutions for mapping impervious surface in a study area on the Eastern corridor between Washington, D.C., and Baltimore, where developed impervious surface containing both residential housings, office buildings, and roads, in the United States. The impact of different band combinations in Sentinel-2 imagery on mapping urban impervious surface and urban land cover was also evaluated.

Conference Paper↗

Triaxial testing of Lopez Fault gouge at 150 MPa mean effective stress

Triaxial compression experiments were performed on samples of natural granular fault gouge from the Lopez Fault in Southern California. This material consists primarily of quartz and has a self-similar grain size distribution thought to result from natural cataclasis. The experiments were performed at a constant mean effective stress of 150 MPa, to expose the volumetric strains associated with shear failure. The failure strength is parameterized by the coefficient of internal friction ??, based on the Mohr-Coulomb failure criterion. Samples of remoulded Lopez gouge have internal friction ??=0.6??0.02. In experiments where the ends of the sample are constrained to remain axially aligned, suppressing strain localisation, the sample compacts before failure and dilates persistently after failure. In experiments where one end of the sample is free to move laterally, the strain localises to a single oblique fault at around the point of failure; some dilation occurs but does not persist. A comparison of these experiments suggests that dilation is confined to the region of shear localisation in a sample. Overconsolidated samples have slightly larger failure strengths than normally consolidated samples, and smaller axial strains are required to cause failure. A large amount of dilation occurs after failure in heavily overconsolidated samples, suggesting that dilation is occurring throughout the sample. Undisturbed samples of Lopez gouge, cored from the outcrop, have internal friction in the range ??=0.4-0.6; the upper end of this range corresponds to the value established for remoulded Lopez gouge. Some kind of natural heterogeneity within the undisturbed samples is probably responsible for their low, variable strength. In samples of simulated gouge, with a more uniform grain size, active cataclasis during axial loading leads to large amounts of compaction. Larger axial strains are required to cause failure in simulated gouge, but the failure strength is similar to that of natural Lopez gouge. Use of the Mohr-Coulomb failure criterion to interpret the results from this study, and other recent studies on intact rock and granular gouge, leads to values of ?? that depend on the loading configuration and the intact or granular state of the sample. Conceptual models are advanced to account for these descrepancies. The consequences for strain-weakening of natural faults are also discussed. ?? 1994 Birkha??user Verlag.

Pure and Applied Geophysics PAGEOPH↗

Drivers of U.S. mineral demand

Introduction: The word 'demand' has different meanings for different people. To some, it means their 'wants and needs,' to others it is what they consume. Yet, when considering economics, demand refers to the specific amounts of goods or services that individuals will purchase at various prices. Demand is measured over a given time period. It is determined by a number of factors including income, tastes, and the price of complementary and substitute goods. In this paper, the term consumption is used fairly synonymously with the term demand. Most mineral commodities, like iron ore, copper, zinc, and gravel, are intermediate goods, which means that they are used in the production of other goods, called final goods. Demand for intermediate goods is called derived demand because such demand is derived from the demand for final goods. When demand increases for a commodity, generally the price rises. With everything else held constant, this increases the profits for those who provide this commodity. Normally, this would increase profits of existing producers and attract new producers to the market. When demand for a commodity decreases, generally the price falls. Normally, this would cause profits to fall and, as a consequence, the least efficient firms may be forced from the industry. Demand changes for specific materials as final goods or production techniques are reengineered while maintaining or improving product performance, for example, the use of aluminum in the place of copper in long distance electrical transmission lines or plastic replacing steel in automobile bumpers. Substitution contributes to efficient material usage by utilizing cheaper or technically superior materials. In this way, it may also alleviate materials scarcity. If a material becomes relatively scarce (and thus more expensive), a more abundant (and less expensive) material generally replaces it (Wagner and others, 2003, p. 91).

Open-File Report↗

Pumping tests in non-uniform aquifers - The linear strip case

Many pumping tests are performed in geologic settings that can be conceptualized as a linear infinite strip of one material embedded in a matrix of differing flow properties. A semi-analytical solution is presented to aid the analysis of drawdown data obtained from pumping tests performed in settings that can be represented by such a conceptual model. Integral transform techniques are employed to obtain a solution in transform space that can be numerically inverted to real space. Examination of the numerically transformed solution reveals several interesting features of flow in this configuration. If the transmissivity of the strip is much higher than that of the matrix, linear and bilinear flow are the primary flow regimes during a pumping test. If the contrast between matrix and strip properties is not as extreme, then radial flow should be the primary flow mechanism. Sensitivity analysis is employed to develop insight into the controls on drawdown in this conceptual model and to demonstrate the importance of temporal and spatial placement of observations. Changes in drawdown are sensitive to the transmissivity of the strip for a limited time duration. After that time, only the total drawdown remains a function of strip transmissivity. In the case of storativity, both the total drawdown and changes in drawdown are sensitive to the storativity of the strip for a time of quite limited duration. After that time, essentially no information can be gained about the storage properties of the strip from drawdown data. An example analysis is performed using data previously presented in the literature to demonstrate the viability of the semi-analytical solution and to illustrate a general procedure for analysis of drawdown data in complex geologic settings. This example reinforces the importance of observation well placement and the time of data collection in constraining parameter correlation, a major source of the uncertainty that arises in the parameter estimation procedure.

Journal of Hydrology↗

Preliminary geologic map of the eastern Willapa Hills, Cowlitz, Lewis, and Wahkiakum Counties, Washington

This digital map database and the PDF derived from the database were created from the analog geologic map: Wells, R.E. (1981), “Geologic map of the eastern Willapa Hills, Cowlitz, Lewis, and Wahkiakum Counties, Washington.” The geodatabase replicates the geologic mapping of the 1981 report with minor exceptions along water boundaries and also along the north and south map boundaries. Slight adjustments to contacts along water boundaries were made to correct differences between the topographic base map used in the 1981 compilation (analog USGS 15-minute series quadrangle maps at 1:62,500 scale) and the base map used for this digital compilation (scanned USGS 7.5-minute series quadrangle maps at 1:24,000 scale). These minor adjustments, however, did not materially alter the geologic map. No new field mapping was performed to create this digital map database, and no attempt was made to fit geologic contacts to the new 1:24,000 topographic base, except as noted above. We corrected typographical errors, formatting errors, and attribution errors (for example, the name change of Goble Volcanics to Grays River Volcanics following current State of Washington usage; Walsh and others, 1987). We also updated selected references, substituted published papers for abstracts, and cited published radiometric ages for the volcanic and plutonic rocks. The reader is referred to Magill and others (1982), Wells and Coe (1985), Walsh and others (1987), Moothart (1993), Payne (1998), Kleibacker (2001), McCutcheon (2003), Wells and others (2009), Chan and others (2012), and Wells and others (in press) for subsequent interpretations of the Willapa Hills geology.

Washington↗

Capture of environmental DNA (eDNA) from water samples by flocculation

The analysis of environmental DNA (eDNA) has become a widely used approach to problem solving in species management. The detection of cryptic species including invasive and (or) species at risk is the goal, typically accomplished by testing water and sediment for the presence of characteristic DNA signatures. Reliable and efficient procedures for the capture of eDNA are required, especially those that can be performed easily in the field by personnel with limited training and citizen scientists. The capture of eDNA using membrane filtration is widely used currently. This approach has inherent issues that include the choice of filter material and porosity, filter fouling, and time required on site for the process to be performed. Flocculation offers an alternative that can be easily implemented and applied to sampling regimes that strive to cover broad territories in limited time.

JOVE Journal Of Visualized Experiments↗

Assessment of relative accuracy in the determination of organic matter concentrations in aquatic systems

Accurate determinations of total (TOC), dissolved (DOC) and particulate (POC) organic carbon concentrations are critical for understanding the geochemical, environmental, and ecological roles of aquatic organic matter. Of particular significance for the drinking water industry, TOC measurements are the basis for compliance with US EPA regulations. The results of an interlaboratory comparison designed to identify problems associated with the determination of organic matter concentrations in drinking water supplies are presented. The study involved 31 laboratories and a variety of commercially available analytical instruments. All participating laboratories performed well on samples of potassium hydrogen phthalate (KHP), a compound commonly used as a standard in carbon analysis. However, problems associated with the oxidation of difficult to oxidize compounds, such as dodecylbenzene sulfonic acid and caffeine, were noted. Humic substances posed fewer problems for analysts. Particulate organic matter (POM) in the form of polystyrene beads, freeze-dried bacteria and pulverized leaf material were the most difficult for all analysts, with a wide range of performances reported. The POM results indicate that the methods surveyed in this study are inappropriate for the accurate determination of POC and TOC concentration. Finally, several analysts had difficulty in efficiently separating inorganic carbon from KHP solutions, thereby biasing DOC results.

Journal of Environmental Monitoring↗

Byproduct metals and rare-earth elements used in the production of light-emitting diodes—Overview of principal sources of supply and material requirements for selected markets

The use of light-emitting diodes (LEDs) is expanding because of environmental issues and the efficiency and cost savings achieved compared with use of traditional incandescent lighting. The longer life and reduced power consumption of some LEDs have led to annual energy savings, reduced maintenance costs, and lower emissions of carbon dioxide, sulfur dioxide, and nitrogen oxides from powerplants because of the resulting decrease in energy consumption required for lighting applications when LEDs are used to replace less-energy-efficient sources. Metals such as arsenic, gallium, indium, and the rare-earth elements (REEs) cerium, europium, gadolinium, lanthanum, terbium, and yttrium are important mineral materials used in LED semiconductor technology. Most of the world's supply of these materials is produced as byproducts from the production of aluminum, copper, lead, and zinc. Most of the rare earths required for LED production in 2011 came from China, and most LED production facilities were located in Asia. The LED manufacturing process is complex and is undergoing much change with the growth of the industry and the changes in demand patterns of associated commodities. In many respects, the continued growth of the LED industry, particularly in the general lighting sector, is tied to its ability to increase LED efficiency and color uniformity while decreasing the costs of producing, purchasing, and operating LEDs. Research is supported by governments of China, the European Union, Japan, the Republic of Korea, and the United States. Because of the volume of ongoing research in this sector, it is likely that the material requirements of future LEDs may be quite different than LEDs currently (2011) in use as industry attempts to cut costs by reducing material requirements of expensive heavy rare-earth phosphors and increasing the sizes of wafers for economies of scale. Improved LED performance will allow customers to reduce the number of LEDs in automotive, electronic, and lighting applications, which could reduce the overall demand for material components. Non-Chinese sources for rare earths are being developed, and some of these new sources are likely to be operational in time to meet increasing demand for rare earths from the LED sector. Because most LED component production and manufacturing occurs in Asia and many LED producers have established supply contracts with Chinese producers of rare earths, a significant amount of the metallic gallium, indium, and the rare earths used for LED production will likely continue to come from Chinese sources at least for the next 5 years; however, a greater amount of these materials are now being processed in Japan, the Republic of Korea, and Taiwan. As non-Chinese sources of rare earths come into production, these new mines are likely to be sources of light REEs, but China will likely remain the leading source of supply for the heavy REEs suitable for use as LED dopants and phosphors at least for the next few years. Increased research in the development of phosphors that use smaller amounts of or different REEs is intended to reduce dependence on rare earths from China. Supply disruption of rare earths and other specialty metals could take place if China's specialty metal exports are redirected to domestic markets. The cost of recovery is high and the lifespan for LEDs is comparatively long; thus, the LED waste volume was low in 2010, and few LEDs were recycled. The minute metal content of LEDs leads to a high cost for recovery, so recycling of LEDs outside of electronic waste is unlikely in the near term, although some LED producers are evaluating recycling options. Recycling of metals from LEDs in electronic waste is possible if the costs of recovering metals are justified by demand and metal prices.

Scientific Investigations Report↗

Evaluation of larval sea lamprey Petromyzon marinus growth in the laboratory: Influence of temperature and diet

Conservation aquaculture provides a means for promoting environmental stewardship, useful both in the context of restoring native species and limiting the production of invasive species. Aquaculture of lampreys is a relatively recent endeavor aimed primarily at producing animals to support the restoration of declining native populations. However, in the Laurentian Great Lakes, where sea lamprey Petromyzon marinus are invasive, the ability to acquire a reliable source of certain life stages would be a significant benefit to those controlling their populations and studying the species. Here, we apply methodologies developed for Pacific lamprey Entosphenus tridentatus restoration to investigate the feasibility of rearing larval sea lamprey under laboratory conditions. In two experiments lasting 3 and 9 months, we tested the effects of different dietary sources and water temperature (ambient and controlled) on the survival and growth of wild-caught larvae. Rearing conditions had no effect on mortality, as larval survival was 100% in both experiments. Growth was significantly affected by water temperature, with the highest average daily growth rates observed at 22 and 15°C (0.14 mm day −1 ) and lowest at 8°C (0.06 mm day −1 ). Diets of yeast alone (0.19 and 0.21 g L −1 ) performed better than those comprising a mixture of yeast and other material when fed 3 times weekly (rice flour, wheat flour, fish meal; 0.19 and 0.32 g L −1 ). Averaged across the three constant temperatures (8, 15, and 22°C), larvae fed on yeast grew 0.13 mm day −1 and 0.01 g day −1 , whereas on yeast + fish meal, they grew 0.09 mm day −1 and 0.01 g day −1 . At ambient temperature (4–20°C), larvae fed on yeast grew 0.15 mm day −1 and 0.01 g day −1 , whereas those fed on yeast + wheat flour grew 0.13 mm day −1 and 0.008 g day −1 and those fed on yeast + rice flour grew 0.12 mm day −1 and 0.009 g day −1 . An experimental duration of 90 days was sufficient to detect significant changes to larval sea lamprey growth stemming from temperature variation. Overall, rearing of sea lamprey in captivity appears feasible at low density (31–32 g m −2 and 17–25 larvae m −2 ), but uncertainties remain regarding the most appropriate means of providing adequate feed for these fish in high-density conditions.

Aquaculture Research↗

Shift in Global Tantalum Mine Production, 2000–2014

Introduction Tantalum has a unique set of properties that make it useful in a number of diverse applications. The ability of the metal to store and release electrical energy makes it ideally suited for use in certain types of capacitors that are widely used in modern electronics. Approximately 60 percent of global tantalum consumption is in the electronics industry. The ductility and corrosion resistance of the metal lends itself to application in the chemical processing industry, and its high melting point and high strength retention at elevated temperatures make it an important component of super alloys used in aircraft engines. As a major industrialized nation, the United States is a leading consumer of tantalum and tantalum-containing products. Domestic deposits typically are of low grade, and no tantalum has been recovered from mining activities in the United States since 1959. Consequently, the United States is nearly completely reliant on imports to meet its domestic consumption of tantalum for economic and national security needs. The recovery of tantalum from mine production is economically viable in only a few countries. Although developed countries dominated tantalum mine production in the early 2000s, production today is dominated by countries in the Great Lakes Region of Africa. There is concern that the sales of minerals, including columbite-tantalite or “coltan,” a mineral from which tantalum is derived, have helped finance rebel groups accused of violating human rights as part of the continuing armed conflict in the Democratic Republic of the Congo (DRC) and neighboring countries. These accusations have prompted the passage of legislation in the United States to curb the procurement of these mineral commodities, referred to as “conflict minerals,” from the DRC. Specifically, section 1502 of the 2010 Dodd-Frank Wall Street Reform and Consumer Protection Act (Public Law 111–203, 124 Stat. 2213–2218) requires companies that source tantalum, tin, tungsten, and gold (3TG) to perform due diligence on their supply chains to determine if the materials they use originate from the DRC or adjoining countries (defined as sharing a border with the DRC). The DRC, Rwanda, and surrounding countries are not globally significant sources of tin, tungsten, or gold, accounting for only about 2 percent of the mined world supply for each of these elements. The region has, however, evolved to become the world’s largest producer of mined tantalum. A further complication of the production of tantalum stems from the opacity of the tantalum market. Unlike most base and precious metals, tantalum concentrates are not publicly traded through commodities exchanges but are bought and sold through networks of dealers and on contract between producers and consumers, some of whom may not provide accurate statistical data concerning the amounts, origins, and destination of the concentrates. Some price data can be found in trade journals or in other publications; however, there are no recognized official set exchange prices for either concentrate or tantalum metal. Because price is determined by negotiation between buyer and seller, published prices for concentrate are probably not representative of global prices paid for concentrate. The development of a mine-to-market supply-chain analysis is complicated and difficult because many of the industry participants that produce, trade, and consume tantalum do not publish statistical information, contracts are long term between miners and buyers, and much of the industry is vertically integrated. As a result of these and other considerations, tantalum is considered by many to be a “critical” commodity. This fact sheet identifies and addresses the major geographic shifts in the source of mine production of tantalum which have occurred over the past 15 years, some of the factors that drove this shift, and some of the related consequences. One of the activities of the U.S. Geological Survey National Minerals Information Center (USGS-NMIC) is to analyze global supply chains and characterize major components of mineral and material flows from ore extraction through processing to first tier products. These analyses support the core mission of the USGS-NMIC as the Federal entity responsible for the collection, analysis, and dissemination of objective, unbiased, factual information on minerals essential to the U.S. economy and national security.

Fact Sheet↗

Geologic and seismic investigations for relocation of Route 138 in Brockton, Mass., prospective cut, stations 169 to 180

This work was done to obtain geologic and seismic data that would aid in establishing grade for a segment of Route 138 between stations 169 and 180, and that would also be of value in estimating the nature and quantities of subsurface materials to be estimating the nature and quantities of subsurface materials to be excavated from the proposed cut. The work was performed in August 1952, as part of a cooperative program pf the Massachusetts Department of Public Works and the United States Geological Survey.

Massachusetts↗

Geotechnical engineering for ocean waste disposal. An introduction

As members of multidisciplinary teams, geotechnical engineers apply quantitative knowledge about the behavior of earth materials toward designing systems for disposing of wastes in the oceans and monitoring waste disposal sites. In dredge material disposal, geotechnical engineers assist in selecting disposal equipment, predict stable characteristics of dredge mounds, design mound caps, and predict erodibility of the material. In canister disposal, geotechnical engineers assist in specifying canister configurations, predict penetration depths into the seafloor, and predict and monitor canister performance following emplacement. With sewage outfalls, geotechnical engineers design foundation and anchor elements, estimate scour potential around the outfalls, and determine the stability of deposits made up of discharged material. With landfills, geotechnical engineers evaluate the stability and erodibility of margins and estimate settlement and cracking of the landfill mass. Geotechnical engineers also consider the influence that pollutants have on the engineering behavior of marine sediment and the extent to which changes in behavior affect the performance of structures founded on the sediment. In each of these roles, careful application of geotechnical engineering principles can contribute toward more efficient and environmentally safe waste disposal operations.

Conference Paper↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Extraction of nitroaromatic compounds from water by polystyrene divinylbenzene cartridge and determination by high-performance liquid chromatography

Organic explosives are determined in samples of ground water and surface water with emphasis on identifying and quantifying trinitrotoluene (TNT) metabolites. Water samples are filtered to remove suspended particulate material and passed through a polystyrene divinylbenzene-packed cartridge by a vacuum-extraction system. The target analytes subsequently are eluted with acetonitrile. A high-performance liquid chromatograph (HPLC) equipped with a photodiode-array detector is used for sample analysis. Analytes are separated on an octadecylsilane column using a methanol, water, and acetonitrile gradient elution. The compounds 2,4- and 2,6-dinitrotoluene are separated through an independent, isocratic elution. Method detection limits, on the basis of a 1-liter sample size, range from 0.11 to 0.32 microgram per liter. Recoveries averaged from 71 to 101 percent for 13 analytes in one set of HPLC-grade water fortified at about 1 microgram per liter. The method is limited to use by analysts experienced in handling explosive materials. (USGS)

Open-File Report↗

Volcanic plume height measured by seismic waves based on a mechanical model

In August 2008 an unmonitored, largely unstudied Aleutian volcano, Kasatochi, erupted catastrophically. Here we use seismic data to infer the height of large eruptive columns such as those of Kasatochi based on a combination of existing fluid and solid mechanical models. In so doing, we propose a connection between a common, observable, short-period seismic wave amplitude to the physics of an eruptive column. To construct a combined model, we estimate the mass ejection rate of material from the vent on the basis of the plume height, assuming that the height is controlled by thermal buoyancy for a continuous plume. Using the estimated mass ejection rate, we then derive the equivalent vertical force on the Earth through a momentum balance. Finally, we calculate the far-field surface waves resulting from the vertical force. The model performs well for recent eruptions of Kasatochi and Augustine volcanoes if v , the velocity of material exiting the vent, is 120-230 m s -1 . The consistency between the seismically inferred and measured plume heights indicates that in these cases the far-field ~1 s seismic energy radiated by fluctuating flow in the volcanic jet during the eruption is a useful indicator of overall mass ejection rates. Thus, use of the model holds promise for characterizing eruptions and evaluating ash hazards to aircraft in real time on the basis of far-field short-period seismic data. This study emphasizes the need for better measurements of eruptive plume heights and a more detailed understanding of the full spectrum of seismic energy radiated coeruptively.

Journal of Geophysical Research B: Solid Earth↗

The nature of bacteria pathogenic to fish

A review is made of the progress in research on bacteria which are pathogenic to fish, with particular emphasis on those investigations performed during the past decade. The report includes a critical review of material published; the comments and suggestions are designed to stimulate the initiation of new research projects.

Transactions of the American Fisheries Society↗

Geophysical and hydrologic analysis of an earthen dam site in southern Westchester County, New York

Ninety percent of the drinking water for New York City passes through the Hillview Reservoir facility in the City of Yonkers, Westchester County, New York. In the past, several seeps located downslope from the reservoir have flowed out from the side of the steepest slope at the southern end of the earthen embankment. One seep that has been flowing continuously was discovered during an inspection of the embankment in 1999. Efforts were made in 2001 to locate the potential sources of the continuous flowing seep. In 2005, the U.S. Geological Survey, in cooperation with the New York City Department of Environmental Protection, began a cooperative study to investigate the relevant hydrogeologic framework to characterize the local groundwater-flow system and to determine possible sources of the seeps. The two agencies used hydrologic and surface geophysical techniques to assess the earthen embankment of the Hillview Reservoir. Between April 1, 2005 and March 1, 2008, water levels were measured manually each month at 46 wells surrounding the reservoir, and flow was measured monthly at three of the five seeps on the embankment. Water levels were measured hourly in the East Basin of the reservoir, at 24 of 46 wells, and discharge was measured hourly at two of the five seeps. Slug tests were performed at 16 wells to determine the hydraulic conductivity of the geologic material surrounding the screened zone. Estimated hydraulic conductivities for 25 wells on the southern embankment ranged from 0.0063 to 1.2 feet per day and averaged 0.17 foot per day. The two-dimensional resistivity surveys indicate a subsurface mound of electrically conductive material (low-resistivity zone) beneath the terrace area (top of dam) surrounding the reservoir with a distinct elevation increase closer to the crest. Two-dimensional shear wave velocity surveys indicate a similar structure of the high shear wave velocity materials (high-velocity zone), increasing in elevation toward the crest and decreasing toward the reservoir and toward the northern part of the study area. Water-quality samples collected from 12 wells, downtake chamber 1 of the reservoir, and two seeps detected the presence of arsenic, toluene, and two trihalomethanes. Water-quality samples collected at the two seeps detected fluoride, indicating a connection with reservoir water. Shallow wells on the southern embankment exhibited the largest seasonal water-level fluctuations ranging between 6 feet and 12 feet. The embankment is constructed from reworked low-permeability glacial deposits at the site. Water-level responses in observation wells within the embankment indicate that there is a shallow (approximately the upper 45 feet of the embankment) and a deep water-bearing unit within the embankment with a large downward vertical gradient between the shallow and deep water-bearing units. Precipitation strongly affected water levels in shallow wells, whereas the basin appears to be the main control on water levels in the deep wells. Seeps on the embankment slope appear to be caused by above-average precipitation that increases water levels in the shallow water-bearing unit, but does not easily recharge the deep water-bearing unit. Based on the data that have been analyzed, source water to the seeps appears to be primarily groundwater and, to a lesser extent, water from the East Basin of the reservoir.

New York↗

Stratification of a cityscape using census and land use variables for inventory of building materials

A cityscape (or any landscape) can be stratified into environmental units using multiple variables of information. For the purposes of sampling building materials, census and land use variables were used to identify similar strata. In the Metropolitan Statistical Area of a cityscape, the census tract is the smallest unit for which census data are summarized and digitized boundaries are available. For purposes of this analysis, census data on total population, total number of housing units, and number of singleunit dwellings were aggregated into variables of persons per square kilometer and proportion of housing units in single-unit dwellings. The level 2 categories of the U.S. Geological Survey's land use and land cover data base were aggregated into variables of proportion of residential land with buildings, proportion of nonresidential land with buildings, and proportion of open land. The cityscape was stratified, from these variables, into environmental strata of Urban Central Business District, Urban Livelihood Industrial Commercial, Urban Multi-Family Residential, Urban Single Family Residential, Non-Urban Suburbanizing, and Non-Urban Rural. The New England region was chosen as a region with commonality of building materials, and a procedure developed for trial classification of census tracts into one of the strata. Final stratification was performed by discriminant analysis using the trial classification and prior probabilities as weights. The procedure was applied to several cities, and the results analyzed by correlation analysis from a field sample of building materials. The methodology developed for stratification of a cityscape using multiple variables has application to many other types of environmental studies, including forest inventory, hydrologic unit management, waste disposal, transportation studies, and other urban studies. Multivariate analysis techniques have recently been used for urban stratification in England. ?? 1987 Annals of Regional Science.

The Annals of Regional Science↗