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Rank of coal beds of the Narragansett basin, Massachusetts and Rhode Island

Coal of the Narragansett basin generally has been considered to be anthracite and/or meta-anthracite. However, no single reliable method has been used to distinguish these two ranks in this basin. Three methods — chemical, X-ray, and petrographic — have been used with some degree of success on coal of the Narragansett basin, but too often the results are in conflict. Chemical methods have been limited by inadequate sampling on a coal-bed-by-coal-bed basis and by a lack of analyses made according to (American Society for Testing and Materials, 1974) standard specifications. In addition, when corrections are made by using the Parr formulas, as required by the ASTM (1974) procedures, the generally high to very high ash content of coal from the Narragansett basin causes the fixed-carbon content to appear higher than it actually is. X-ray methods using the degree of graphitization as a measure of rank are not reliable because some of the graphite is related to shearing and brecciation associated with folding and faulting. Petrographic methods using reflectance on vitrinite give results that are generally consistent with results from chemical determinations. However, it is not clear whether the mean maximum reflectance or mean bireflectance is a better indicator of similar rank of such high-rank coals that have been structurally deformed. Coal from the Cranston Mine, RI, is probably meta-anthracite and coal from the Portsmouth Mine is probably anthracite. These ranks are based on chemical,X-ray, and petrographic data and are supported by associated metamorphic mineral assemblages that indicate that the Cranston Mine is in a higher metamorphic zone than the zone containing the Porthmouth Mine. Interpretation of the rank of Mansfield, MA, coal on the basis of extant chemical data is difficult because it is an impure coal with an ash content of 33 to 50%. Reflectance data indicate that the Mansfield, Foxborough, and Plainville coals in the northern part of the Narragansett basin are meta-anthracite but this is in disagreement with the rank suggested by the low degree of metamorphism of the associated rocks.

International Journal of Coal Geology

Island history affects faunal composition: the treeshrews (Mammalia: Scandentia: Tupaiidae) from the Mentawai and Batu Islands, Indonesia

The Mentawai and Batu Island groups off the west coast of Sumatra have a complicated geological and biogeographical history. The Batu Islands have shared a connection with the Sumatran ‘mainland’ during periods of lowered sea level, whereas the Mentawai Islands, despite being a similar distance from Sumatra, have remained isolated from Sumatra, and probably from the Batu Islands as well. These contrasting historical relationships to Sumatra have influenced the compositions of the respective mammalian faunas of these island groups. Treeshrews (Scandentia, Tupaiidae) from these islands have, at various times in their history, been recognized as geographically circumscribed populations of a broadly distributed Tupaia glis, subspecies, or distinct species. We used multivariate analyses of measurements from the skull and hands to compare the island populations from Siberut (Mentawai Islands) and Tanahbala (Batu Islands) with the geographically adjacent species from the southern Mentawai Islands (T. chrysogaster) and Sumatra (T. ferruginea). Results from both the skull and manus of the Siberut population show that it is most similar to T. chrysogaster, whereas the Tanahbala population is more similar to T. ferruginea, confirming predictions based on island history. These results are further corroborated by mammae counts. Based on these lines of evidence, we include the Siberut population in T. chrysogaster and the Tanahbala population in T. ferruginea. Our conclusions expand the known distributions of both the Mentawai and Sumatran species. The larger geographical range of the endangered T. chrysogaster has conservation implications for this Mentawai endemic, so populations and habitat should be re-evaluated on each of the islands it inhabits. However, until such a re-evaluation is conducted, we recommend that the IUCN Red List status of this species be changed from ‘Endangered’ to ‘Data Deficient’.

Mentawai;Batu Islands

Hydrochemical analysis of groundwater using multivariate statistical methods - The Volta region, Ghana

Q and R-mode multivariate statistical analyses were applied to groundwater chemical data from boreholes and wells in the northern section of the Volta region Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area. The analyses revealed three zones in the groundwater flow system: recharge, intermediate and discharge regions. All three zones are clearly different with respect to all the major chemical parameters, with concentrations increasing from the perceived recharge areas through the intermediate regions to the discharge areas. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. This study finds that the ??D and ?? 18 O data from the area fall along the Global Meteoric Water Line (GMWL). An equation of regression derived for the relationship between ??D and ?? 18 O bears very close semblance to the equation which describes the GMWL. On the basis of this, groundwater in the study area is probably meteoric and fresh. The apparently low salinities and sodicities of the groundwater seem to support this interpretation. The suitability of groundwater for domestic and irrigation purposes is related to its source, which determines its constitution. A plot of the sodium adsorption ratio (SAR) and salinity (EC) data on a semilog axis, suggests that groundwater serves good irrigation quality in the area. Sixty percent (60%), 20% and 20% of the 67 data points used in this study fall within the medium salinity - low sodicity (C2-S1), low salinity -low sodicity (C1-S1) and high salinity - low sodicity (C3-S1) fields, which ascribe good irrigation quality to groundwater from this area. Salinities range from 28.1 to 1956 ??S/cm, whilst SAR values fall within the range 0-3. Extremely low sodicity waters of this kind, with salinities lower than 600 ??S/cm, have the tendency to affect the dispersive properties of irrigation soils when used for irrigation. About 50% of the groundwater in the study area fall within this category and need prior treatment before usage. ?? 2009 Korean Society of Civil Engineers and Springer-Verlag Berlin Heidelberg GmbH.

KSCE Journal of Civil Engineering

Structure and morphology of chars and activated carbons obtained from thermal treatment of coal and biomass origin materials, including their wastes: Results from the ICCP Microscopy of Carbon Materials Working Group

This paper describes the evaluation of petrographic textures in char and activated carbon derived from coal, coal by-products and biomass, formed during carbonization and activation processes. This work represents the results of interlaboratory exercises from 2016 to 2022 of the Microscopy of Carbon Materials Working Group in Commission III of the International Committee for Coal and Organic Petrology. The interlaboratory exercises were run on photomicrograph samples. For textural characterization of carbon materials, the existing American Society for Testing and Materials (ASTM) classification system for metallurgical coke was applied. Morphological differences were evaluated in 29 carbon material types, including 22 char samples, and 7 activated carbon (AC) samples obtained experimentally using conventional direct/indirect and microwave heating technologies. This approach gives an extended view on the identification of microporous carbons, and how a certain heat treatment develops a certain optical texture and structure in a raw material. The requested evaluation of carbon materials was related to their porosity, origin, extent, and characteristics, which are particular to each carbon material type. Because carbon matrices can form a wide range of optical textures during heat treatment it is important to demonstrate which carbon occurrences will have a crucial role in industrial applications dominated by adsorption phenomena. The interlaboratory exercises included 17 participants from 14 laboratories. Four sets of digital black and white and colour photomicrographs were distributed, which in total comprised 184 fields of different types of carbon material. The results were evaluated based on four levels: (i) optical texture (isotropic/anisotropic), (ii) optical type and size (punctiform, mosaic, fiber, ribbon, domain), iii) morphology (porous, non-porous/massive), and (iv) particle origin (precursor type). The statistical method applied to evaluate the results was based on “raw agreement indices”. Comparative analyses of the average values of the level of overall agreement showed homogeneity in the results, the mean value was 89%, with a minimum value of 87% and a maximum value of 91% for those who participated in at least three out of four exercises.

International Journal of Coal Geology

Upper Rio Grande Basin water-resource status and trends: Focus area study review and synthesis

The Upper Rio Grande Basin (URGB) is a critical international water resource under pressure from a myriad of climatic, ecological, infrastructural, water-use, and legal constraints. The objective of this study is to provide a comprehensive assessment of the spatial distribution and temporal trends of selected water-budget components (snow processes, evapotranspiration (ET), streamflow processes, and groundwater storage) using integrated analyses, such as watershed modeling and water availability and use data in the URGB over the past three decades. A spatially distributed snow evolution modeling system simulated snowpack processes over 34 years (1984–2017). It highlighted snow water equivalent declines from -35 to -77 mm/decade with widespread variability across elevation zones and land cover types. Gridded actual ET data from the SSEBop model were developed and tested for the URGB and demonstrated that all land-cover types had significant decreasing trends (1986-2015) ranging from -14 to -80 mm/decade. Conductivity-mass-balance (CMB) hydrograph separation results found that baseflow forms a large component of total streamflow, ranging from 29 to 69% (49% average) of total streamflow at 17 URGB sites upstream of Albuquerque, NM. Three of 4 graphical hydrograph separation methods in the U.S. Geological Survey Groundwater Toolbox were found to be inappropriate for estimating baseflow in the URGB; the most promising method, baseflow index (BFI) Standard, was optimized using CMB data and tested at three URGB sites, with resulting overestimation of 0 to 47%. Simulated changes in groundwater storage were extracted from historical and recent groundwater-flow models of select alluvial basins (San Luis, Española, Middle Rio Grande, and Tularosa-Hueco). In general, decreases in groundwater storage were observed from 1903 to 2013 except for the San Luis alluvial basin (Colorado), where periods of recovery are observed. The PRMS hydrologic model was successfully calibrated for 9 near-native subbasins (Nash-Sutcliffe efficiency 0.47 to 0.85) and parameters translated to the remaining subbasins; compared to simulated near-native flows (with minimal influence of reservoirs or diversions), observed Rio Grande streamgage flows demonstrated reductions of 40% or more for New Mexico and Texas areas of the basin. Significant decreasing trends (1980-2015) in precipitation, snowmelt rate, streamflow, and baseflow were observed at many of the 12 streamgage basins studied, which suggests that the decreasing trends for actual ET may be related to overall decreasing water availability in the basin, with negative implications for agricultural production and groundwater abstraction. Water security concerns arise from our findings of higher fraction precipitation as rain, slower snowmelt rates leading to decreasing streamflow production, and an increasing fraction of baseflow, all of which will affect the timing and magnitude of water available for human needs in the basin.

Upper Rio Grande Basin

Geophysical modeling of the northern Appalachian Brompton-Cameron, Central Maine, and Avalon terranes under the New Jersey Coastal Plain

A regional terrane map of the New Jersey Coastal Plain basement was constructed using seismic, drilling, gravity and magnetic data. The Brompton-Cameron and Central Maine terranes were coalesced as one volcanic island arc terrane before obducting onto Laurentian, Grenville age, continental crust in the Taconian orogeny [Rankin, D.W., 1994. Continental margin of the eastern United States: past and present. In: Speed, R.C., (Ed.), Phanerozoic Evolution of North American Continent-Ocean Transitions. DNAG Continent-Ocean Transect Volume. Geological Society of America, Boulder, Colorado, pp. 129-218]. Volcanic island-arc rocks of the Avalon terrane are in contact with Central Maine terrane rocks in southern Connecticut where the latter are overthrust onto the Brompton-Cameron terrane, which is thrust over Laurentian basement. Similarities of these allochthonous island arc terranes (Brompton-Cameron, Central Maine, Avalon) in lithology, fauna and age suggest that they are faulted segments of the margin of one major late Precambrian to early Paleozoic, high latitude peri-Gondwana island arc designated as "Avalonia", which collided with Laurentia in the early to middle Paleozoic. The Brompton Cameron, Central Maine, and Avalon terranes are projected as the basement under the eastern New Jersey Coastal Plain based on drill core samples of metamorphic rocks of active margin/magmatic arc origin. A seismic reflection profile across the New York Bight traces the gentle dipping (approximately 20 degrees) Cameron's Line Taconian suture southeast beneath allochthonous Avalon and other terranes to a 4 sec TWTT depth (approximately 9 km) where the Avalonian rocks are over Laurentian crust. Gentle up-plunge (approximately 5 degrees) projections to the southwest bring the Laurentian Grenville age basement and the drift-stage early Paleozoic cover rocks to windows in Burlington Co. at approximately 1 km depth and Cape May Co. at approximately 2 km depths. The antiformal Shellburne Falls and Chester domes and Chain Lakes-Pelham dome-Bronson Hill structural trends, and the synformal Connecticut Valley-Gaspe structural trend can be traced southwest into the New Jersey Coastal Plain basement. A Mesozoic rift basin, the "Sandy Hook basin", and associated eastern boundary fault is identified, based upon gravity modeling, in the vicinity of Sandy Hook, New Jersey. The thickness of the rift-basin sedimentary rocks contained within the "Sandy Hook basin" is approximately 4.7 km, with the basin extending offshore to the east of the New Jersey coast. Gravity modeling indicates a deep rift basin and the magnetic data indicates a shallow magnetic basement caused by magnetic diabase sills and/or basalt flows contained within the rift-basin sedimentary rocks. The igneous sills and/or flows may be the eastward continuation of the Watchung and Palisades bodies. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Geodynamics