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From data to interpretable models: Machine learning for soil moisture forecasting

Soil moisture is critical to agricultural business, ecosystem health, and certain hydrologically driven natural disasters. Monitoring data, though, is prone to instrumental noise, wide ranging extrema, and nonstationary response to rainfall where ground conditions change. Furthermore, existing soil moisture models generally forecast poorly for time periods greater than a few hours. To improve such forecasts, we introduce two data-driven models, the Naive Accumulative Representation (NAR) and the Additive Exponential Accumulative Representation (AEAR). Both of these models are rooted in deterministic, physically based hydrology, and we study their capabilities in forecasting soilmoisture over time periods longer than a fewhours. Learned model parameters represent the physically based unsaturated hydrological redistribution processes of gravity and suction. We validate our models using soil moisture and rainfall time series data collected from a steep gradient, post-wildfire site in southern California. Data analysis is complicated by rapid landscape change observed in steep, burned hillslopes in response to even small to moderate rain events. The proposed NAR and AEAR models are, in forecasting experiments, shown to be competitive with several established and state-of-the-art baselines. The AEAR model fits the data well for three distinct soil textures at variable depths below the ground surface (5, 15, and 30 cm). Similar robust results are demonstrated in controlled, laboratory-based experiments. Our AEAR model includes readily interpretable hydrologic parameters and provides more accurate forecasts than existing models for time horizons of 10–24 h. Such extended periods of warning for natural disasters, such as floods and landslides, provide actionable knowledge to reduce loss of life and property.

International Journal of Data Science and Analytic↗

Juvenile African clawed frogs (Xenopus laevis) express growth, metamorphosis, mortality, gene expression, and metabolic changes when exposed to thiamethoxam and clothianidin

Neonicotinoids (NEO) represent the main class of insecticides currently in use, with thiamethoxam (THX) and clothianidin (CLO) primarily applied agriculturally. With few comprehensive studies having been performed with non-target amphibians, the aim was to investigate potential biomarker responses along an adverse outcome pathway of NEO exposure, whereby data were collected on multiple biological hierarchies. Juvenile African clawed frogs, Xenopus laevis , were exposed to commercial formulations of THX and CLO at high (100 ppm) and low (20 ppm) concentrations of the active ingredient. Mortality, growth, development, liver metabolic enzyme activity, and gene expression endpoints were quantified. Tadpoles ( n > 1000) from NF 47 through tail resorption stage (NF 66) were exposed to NEO or to NEO-free media treatments. Liver cell reductase activity and cytotoxicity were quantified by flow cytometry. Compared to control reference gene expressions, levels of expression for NEO receptor subunits, cell structure, function, and decontamination processes were measured by RT-qPCR by using liver and brain. Mortality in THX high was 21.5% compared to the control (9.1%); the metabolic conversion of THX to CLO may explain these results. The NF 57 control tadpoles were heavier, longer, and more developed than the others. The progression of development from NF 57–66 was reduced by THX low, and weight gain was impaired. Liver reductases were highest in the control (84.1%), with low NEO exhibiting the greatest reductions; the greatest cytotoxicity was seen with THX high. More transcriptional activity was noted in brains than in livers. Results affirm the utility of a study approach that considers multiple complexities in ecotoxicological studies with non-target amphibians, underscoring the need for simultaneously considering NEO concentration-response relationships with both whole-organism and biomarker endpoints.

International Journal of Molecular Sciences↗

Effect of flood-induced chemical load on filtrate quality at bank filtration sites

Riparian municipal wells, that are located on riverbanks, are specifically designed to capture a portion of the river water through induced infiltration. Runoff from agricultural watersheds is found to carry enormous amounts of pesticides and nitrate. While the risk of contamination for a vast majority of sites with small-capacity vertical wells is low, potential exists for medium to large capacity collector wells to capture a fraction of the surface water contaminants during flood. Prior monitoring and current modeling results indicate that a small-capacity (peak pumpage 0.0315 m3/s) vertical bank filtration well may not be affected by river water nitrate and atrazine even during flood periods. For a medium capacity (0.0875-0.175 m3/s) hypothetical collector well at the same site, potential exists for a portion of the river water nitrate and atrazine to enter the well during flood periods. Various combinations of hydraulic conductivity of the riverbed or bank material were used. For nitrate, it was assumed either no denitrification occurred during the period of simulation or a half-life of 2 years. Equilibrium controlled sorption (organic carbon partition coefficient of 52 ml/g) and a half-life of between 7.5 and 15 weeks were considered for atrazine. Combinations of these parameters were used in various simulations. Peak concentrations of atrazine or nitrate in pumped water could vary from less than 1% to as high as 90% of that in the river. It was found that a combination of river stage, pumping rates, hydraulic properties of the riverbed and bank, and soil/pesticide properties could affect contaminant entry from river water to any of these wells. If the hydraulic conductivity of the bed and bank material were low, atrazine would not reach the pumping well with or without sorption and degradation. However, for moderately low permeable bank and bed materials, some atrazine from river water could enter a hypothetical collector well while pumping at 0.0875 m3/s. It was interesting to note that doubling the pumpage of this collector well would bring in more ground water from the aquifer (with no atrazine) and thus have a lower concentration of atrazine in the filtrate. For highly conductive banks, it is possible to find some atrazine at a vertical well for a sustained pumpage rate of 0.0125 m3/s if the effect of sorption is neglected. However, with equilibrium sorption, the concentration would be below the detection limit. On the other hand, if a collector well of capacity 0.0875 m3/s is used at the place of the vertical well with highly conductive banks, atrazine concentration in the filtrate would be about 80% of river water even assuming equilibrium sorption and a half-life of 7.5 weeks. Remediation of river water contamination of the aquifer using 'scavenger' wells between the river and the pumping well(s) was not a feasible option due to the contact of the aquifer with a highly conductive bank at the site. However, moving the existing pumping well(s) 100 m upstream would have negligible impact from the bank-stored water. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Hydrology↗