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Formation of cordierite-bearing lavas during anatexis in the lower crust beneath Lipari Island (Aeolian arc, Italy)

Cordierite-bearing lavas (CBL;~105 ka) erupted from the Mt. S. Angelo volcano at Lipari (Aeolian arc, Italy) are high-K andesites, displaying a range in the geochemical and isotopic compositions that reflect heterogeneity in the source and/or processes. CBL consist of megacrysts of Ca-plagioclase and clinopyroxene, euhedral crystals of cordierite and garnet, microphenocrysts of orthopyroxene and plagioclase, set in a heterogeneous rhyodacitic-rhyolitic groundmass containing abundant metamorphic and gabbroic xenoliths. New petrographic, chemical and isotopic data indicate formation of CBL by mixing of basaltic-andesitic magmas and high-K peraluminous rhyolitic magmas of anatectic origin and characterize partial melting processes in the lower continental crust of Lipari. Crustal anatectic melts generated through two main dehydration-melting peritectic reactions of metasedimentary rocks: (1) Biotite + Aluminosilicate + Quartz + Albite = Garnet + Cordierite + K-feldspar + Melt; (2) Biotite + Garnet + Quartz = Orthopyroxene + Cordierite + K-feldspar + Melt. Their position into the petrogenetic grid suggests that heating and consequent melting of metasedimentary rocks occurred at temperatures of 725 < T < 900°C and pressures of 0.4–0.45 GPa. Anatexis in the lower crust of Lipari was induced by protracted emplacement of basic magmas in the lower crust (~130 Ky). Crustal melting of the lower crust at 105 ka affected the volcano evolution, impeding frequent mafic-magma eruptions, and promoting magma stagnation and fractional crystallization processes.

Contributions to Mineralogy and Petrology

Zinc, copper, and lead geochemistry of oceanic igneous rocks - ridges, islands, and arcs

Variations in the abundances of Zn, Cu, and Pb are found to be useful in identifying tectonic regimes and separating oceanisland basalts into enriched- and depleted-source categories. The average Zn, Cu, and Pb contents of normal mid-ocean ridge basalts (N-MORB) are 84, 70, and 0.35 ppm, respectively. Differences in average Zn contents for various ridges reflect more the varying degrees of differentiation than variations of Zn content in the source rocks. At a Mg# of 70, or Mg# 70 , which is taken to represent primitive MORB, many MORB sequences converge at a Zn content of 58 ± 6 ppm, which is close to the value for primitive mantle (50 ppm) and ordinary chondrites (∼55 ppm). Values of 0.1 to 0.15 ppm Pb in MORB at Mg# 70 , best defined at the superfast-spreading Southern East Pacific Rise, are similar to estimates of Pb in the primitive mantle (0.12 to 0.18 ppm). They also are near the lower end of the range for ordinary chondrites. The very slow spreading Southwest Indian Ocean Ridge has a sequence with higher Pb contents, in addition to a more normal sequence, which has a visual best value of 0.4 ppm Pb at Mg# 70 . With the exception of the Walvis Ridge, Zn and Cu appear to be little affected by proximity to hotspots (i.e., E-MORB); however, Pb contents are higher and average about 0.6 ppm.

International Geology Review

Porphyry copper assessment of the Tethys region of western and southern Asia: Chapter V in Global mineral resource assessment

A probabilistic mineral resource assessment of undiscovered resources in porphyry copper deposits in the Tethys region of western and southern Asia was carried out as part of a global mineral resource assessment led by the U.S. Geological Survey (USGS). The purpose of the study was to delineate geographic areas as permissive tracts for the occurrence of porphyry copper deposits at a scale of 1:1,000,000 and to provide probabilistic estimates of amounts of copper likely to be contained in undiscovered porphyry copper deposits in those tracts. The team did the assessment using the USGS three-part form of mineral resource assessment, which is based on (1) mineral deposit and grade-tonnage models constructed from known deposits as analogs for undiscovered deposits, (2) delineation of permissive tracts based on geoscientific information, and (3) estimation of numbers of undiscovered deposits. The assessment area includes the Asian part of Turkey and Georgia, Armenia, Azerbaijan, Iran, western Pakistan, and southwestern Afghanistan. Selected tracts also extend marginally into southwesternmost Russia and northeasternmost Iraq. This region is located in the central part of the larger Tethyan Eurasian Metallogenic Belt, which extends from western Europe to eastern Asia. Mining in this part of the Tethyan Eurasian Metallogenic Belt has occurred for thousands of years; in 2011 the region produced 420,000 metric tons (t) of copper (2.6 percent of global production), 8,300 t of molybdenum (3 percent), and 29,600 kilograms of gold (1 percent). The assessment team defined 26 tracts permissive for Late Triassic to Holocene porphyry copper-molybdenum and porphyry copper-gold deposits. Permissive tracts range in extent from 2,960 to 194,000 square kilometers (km 2 ) and cover a total area of 924,000 km 2 . Younger tracts overlap older tracts in several areas. Three permissive tracts include sub-tracts in order to separate tract segments on the basis of geography, data quality, or likelihood of occurrence of undiscovered deposits. About 65 percent of all known porphyry sites occur in only five tracts, which also host most of the identified copper resources. In terms of tectonic setting, 58 percent of the permissive tracts are related to continental arcs; 19 percent to island arcs or back arcs; and 24 percent to postcollisional settings. Of the known porphyry copper deposits, subequal fractions are spread among these three settings. The spatial distribution of known porphyry deposits and prospects is also related to the level of erosion. Magmatic belts with numerous known porphyry sites exhibit subequal areas of coeval plutonic and volcanic units and lesser amounts of cover rocks. Belts with fewer known porphyry sites display either high or low volcanic-to-plutonic ratios and (or) greater cover, indicating crustal levels that are too shallow or too deep for exposure of porphyry deposits. Probabilistic estimates of numbers of undiscovered porphyry copper deposits were made for 18 of the 26 tracts. The undiscovered porphyry copper endowment for 8 tracts is discussed qualitatively. The assessment estimates that the Tethys region contains 47 undiscovered deposits within 1 kilometer of the surface. Probabilistic estimates of numbers of undiscovered deposits were combined with grade and tonnage models in a Monte Carlo simulation to estimate probable amounts of contained metal. The 47 undiscovered deposits are estimated to contain a mean of 180 million metric tons (Mt) of copper distributed among the 18 tracts for which probabilistic estimates were made, in addition to the 62 Mt of copper already identified in the 42 known porphyry deposits in the study area. Results of Monte Carlo simulations show that 80 percent of the estimated undiscovered porphyry copper resources in the Tethys region are located in four tracts or sub-tracts.

Scientific Investigations Report

Magmatism and Epithermal Gold-Silver Deposits of the Southern Ancestral Cascade Arc, Western Nevada and Eastern California

Many epithermal gold-silver deposits are temporally and spatially associated with late Oligocene to Pliocene magmatism of the southern ancestral Cascade arc in western Nevada and eastern California. These deposits, which include both quartz-adularia (low- and intermediate-sulfidation; Comstock Lode, Tonopah, Bodie) and quartz-alunite (high-sulfidation; Goldfield, Paradise Peak) types, were major producers of gold and silver. Ancestral Cascade arc magmatism preceded that of the modern High Cascades arc and reflects subduction of the Farallon plate beneath North America. Ancestral arc magmatism began about 45 Ma, continued until about 3 Ma, and extended from near the Canada-United States border in Washington southward to about 250 km southeast of Reno, Nevada. The ancestral arc was split into northern and southern segments across an inferred tear in the subducting slab between Mount Shasta and Lassen Peak in northern California. The southern segment extends between 42&deg;N in northern California and 37&deg;N in western Nevada and was active from about 30 to 3 Ma. It is bounded on the east by the northeast edge of the Walker Lane. Ancestral arc volcanism represents an abrupt change in composition and style of magmatism relative to that in central Nevada. Large volume, caldera-forming, silicic ignimbrites associated with the 37 to 19 Ma ignimbrite flareup are dominant in central Nevada, whereas volcanic centers of the ancestral arc in western Nevada consist of andesitic stratovolcanoes and dacitic to rhyolitic lava domes that mostly formed between 25 and 4 Ma. Both ancestral arc and ignimbrite flareup magmatism resulted from rollback of the shallowly dipping slab that began about 45 Ma in northeast Nevada and migrated south-southwest with time. Most southern segment ancestral arc rocks have oxidized, high potassium, calc-alkaline compositions with silica contents ranging continuously from about 55 to 77 wt%. Most lavas are porphyritic and contain coarse plagioclase &plusmn; hornblende, biotite, and pyroxene phenocrysts. Seven epithermal gold-silver deposits with >1 Moz gold production, several large elemental sulfur deposits, and many large areas (10s to >100 km2) of hydrothermally altered rocks are present in the southern ancestral arc, especially south of latitude 40&deg;N. These deposits are principally hosted by intermediate to silicic lava dome complexes; only a few deposits are associated with mafic- to intermediate-composition stratovolcanoes. Large deposits are most abundant and well developed in volcanic fields whose evolution spanned millions of years. Most deposits are hundreds of thousands to several million years younger than their host rocks, although some quartz-alunite deposits are essentially coeval with their host rocks. Variable composition and thickness of crustal basement is the primary control on mineralization along the length of the southern ancestral arc; most deposits and large alteration zones are localized in basement rock terranes with a strong continental affinity, either along the edge of the North American craton (Goldfield, Tonopah) or in an accreted terrane with continental affinities (Walker Lake terrane; Aurora, Bodie, Comstock Lode, Paradise Peak). Epithermal deposits and quartz-alunite alteration zones are scarce to absent in the northern part of the ancestral arc above an accreted island arc (Black Rock terrane) or unknown basement rocks (Modoc Plateau). Walker Lane structures and areas that underwent large magnitude extension during the Late Cenozoic (areas with Oligocene-early Miocene volcanic rocks dipping >40&deg;) do not provide regional control on mineralization. Instead, these features may have served as local-scale conduits for mineralizing fluids.

Eastern California and Western Nevada

Large-scale deformation related to the collision of the Aleutian Arc with Kamchatka

The far western Aleutian Island Arc is actively colliding with Kamchatka. Westward motion of the Aleutian Arc is brought about by the tangential relative motion of the Pacific plate transferred to major, right-lateral shear zones north and south of the arc. Early geologic mapping of Cape Kamchatka (a promontory of Kamchatka along strike with the Aleutian Arc) revealed many similarities to the geology of the Aleutian Islands. Later studies support the notion that Cape Kamchatka is the farthest west Aleutian &ldquo;island&rdquo; and that it has been accreted to Kamchatka by the process of arc-continent collision. Deformation associated with the collision onshore Kamchatka includes gravimetrically determined crustal thickening and formation of a narrow thrust belt of intensely deformed rocks directly west of Cape Kamchatka. The trend of the thrust faults is concave toward the collision zone, indicating a radial distribution of maximum horizontal compressive stress. Offshore, major crustal faults trend either oblique to the Kamchatka margin or parallel to major Aleutian shear zones. These offshore faults are complex, accommodating both strike-slip and thrust displacements as documented by focal mechanisms and seismic reflection data. Earthquake activity is much higher in the offshore region within a zone bounded to the north by the northernmost Aleutian shear zone and to the west by an apparent aseismic front. Analysis of focal mechanisms in the region indicate that the present-day arc-continent &ldquo;contact zone&rdquo; is located directly east of Cape Kamchatka. In modeling the dynamics of the collision zone using thin viscous sheet theory, the rheological parameters are only partially constrained to values of n (the effective power law exponent) &ge; 3 and Ar (the Argand number) &le; 30. These values are consistent with a forearc thermal profile of Kamchatka, previously determined from heat flow modeling. The thin viscous sheet modeling also indicates that onshore thrust faulting is a consequence, not only of compressive stresses resulting from the west directed collision, but also of sediment-induced coupling of the subducting Pacific plate.

Kamchatka Peninsula

Porphyry copper deposits in Puerto Rico and their relation to arc-trench tectonics

The study of porphyry copper deposits in islands arcs provides an opportunity to observe closely the direct relationship between tectonics and ore deposition, and to avoid such complications as multiple orogenies and contamination of magmas that are common to deposits on continental margins. Puerto Rico has proved to be an ideal laboratory to make these observations. In the west central part of the island 240 million tons of .7 to .8 percent copper ore has been proved up in three deposits (Lutjen, 1971). Although deep saprolite covers most of the mineralized area, two marginal deposits, Helecho and Sapo Alegre, are partly exposed by deep stream valleys. The U. S. Geological Survey, in cooperation with the Puerto Rico Department of Natural Resources is in the middle of a five year geologic and geochemical study of copper deposits in the island. Drill core was made available through the courtesy of Kennecott Copper Corporation, American Metals Climax Corporation and the Puerto Rico Mining Commission. I wish to acknowledge the help of the Puerto Rico Laboratory of Geology for the chemical work, and Richard Marvin and J. Thomas Nash of the USGS for geochronologic and fluid inclusion data, respectively. This report will briefly describe the porphyry copper deposits of Puerto Rico and their tectonic-chronologic position in the development of the Greater Antilles. By extrapolation from this data it will be suggested that these deposits and several others are related to a process of subduction zone deactivation.

Open-File Report

Geology of the Zambales ophiolite, Luzon, Philippines

The Zambales ophiolite of western Luzon, Philippines, exposes a typical succession of basalt flows, diabasic dikes, gabbro and tectonized harzburgite. The age established by limiting strata is late Eocene. Lack of evidence of thrust faulting and the general domal disposition of the lithologie units indicate that the ophiolitic rocks are exposed by uplift. Highly complex internal layered structures within the complex are related to processes developed during formation of the ophiolite and the Zambales ophiolite may be one of the least disturbed (by emplacement) ophiolitic masses known. The exposed mass trends north and the upper surface plunges at low angles (a few degrees) to the north and south. The chemistry and composition of the rocks in the northwest part of the Zambales area (Acoje block) is distinct from that in the southeastern segment (Coto block). The Acoje block, according to Evans (1983) and Hawkins and Evans (1983), resembles (on a chemical basis) arc-tholeiite series rocks from intra-island arcs and the rocks in the Coto block are typical back-arc basin rock series. The present writer believes that the ophiolite composes a single genetic unit and that the changes in composition are the result of changes that took place during the initial formation. The gabbro probably formed below a spreading center in an elongate, in cross section, V-shaped, magma chamber. The gabbro is estimated by the writer to be less than 2 km thick and may be less than 1 km in places. Numerous erosional windows through the gabbro in the northern and eastern side of the Zambales area show that the gabbro remaining in those areas is likely to be only a few hundred meters thick. Harzburgite is exposed to a depth of about 800 m in the Bagsit River area and this may be the deepest part of the ophiolite accessible for study on which there is any control on depth. A transitional zone, about 200 m thick lying between the gabbro and harzburgite, is composed of serpentinized dunite. Commonly the dunite contains disseminated sulfide minerals and at the Acoje Mines, platinum-group elements. A compositional layering within the gabbro is in places cumulate in the lower part of the unit but may have formed by nucleation higher up on the relatively steep sides of the magma chamber. A widespread gneissic banding in the gabbro forms large mappable structures which are many times more complex than is the disposition of the major rock units. These structures are believed to be the result of extensive slumping in the magma chamber. The structure produced by the cumulate layering merges with the gneissic banding, commonly without discernible change in attitude. This tectonic layered structure crosses the gabbro-peridotite boundary at any angle without seeming to disturb the original rock distribution. At greater depths below the boundary (ca. 800 m), the harzburgite contains low dipping banding, which probably reflects the result of differential movement within the mantle. Chromite occurs almost exclusively in a zone that generally lies no more than 200–300 m below the gabbro-peridotite boundary. Refractory-grade chromite is found in this zone below the olivine gabbro in the Goto block and as low-grade metallurgical grade chromite below norite in the Acoje block. At Acoje Mines the chromite is present in layers in dunite, which the writer interprets as being distributed in a zone along the gently dipping (ca. 25°) gabbro-peridotite boundary. The steeply dipping (ca. 60–80 ° ) individual layers lie en echelon along the boundary at an angle (ca. 50 ° ) to the contact. At Coto the chromite forms large discontinuous masses in the lowest dunite and in the uppermost harzburgite. Except for the chromite present as layers at Acoje, the regional tectonic layering crosses the chromite deposits without structural deviation. The chromite deposits and associated peridotite may be cumulate in origin, but have been modified to such an extent that cumulate textures are generally obliterated. The angle of repose of cumulate layers in the Acoje area and in the Coto block dip towards each other raising the possibility that the Zambales area may contain the relics of a spreading center. Initial emplacement of the Zambales ophiolite took place by uplift and the ultramafic portion was exposed to erosion in the earliest Miocene or late Oligocene. Submergence of some of the ophiolite followed the previous uplift and on the west side of the Zambales Range submergence of several kilometers is indicated. Final emergence appears to have taken place in Pliocene or Pleistocene time by block uplift and areas of greatest uplift closely conform to the present topographic surface.

Tectonophysics

Yachats Basalt: An upper Eocene differentiated volcanic sequence in the Oregon Coast Range

The name Yadials Basalt is proposed for a sequence of largely subacrial basalt flows and breccias and associated dikes of late Eocene age that arc exposed along the central Oregon coast. These volcanic rocks, which have a maximum thickness of 750 m, are underlain by marine siltstonc of late Eocene age and overlain by marine siltstone and basaltic sandstone, also of late Eocene age. The siltstone contains a foraminiferal fauna indicative of a moderately deepwatcr marine environment, indicating that local uplift preceded the extrusion of the flows and local subsidence followed. The Yachats Basalt varies widely in composition. Although the bulk of the extrusive rocks and dikes arc basalt, some grade in composition to basaltic andcsite and andcsite; a few dikes are rhyodacitic. Most of the rocks arc porphyritic with phcnocrysts of labradorite and less commonly augite and olivine. Typical flow rock contains 50 percent SiO 2 and are characterized by high alumina, alkali, titania, and phosphate content. The wide range in composition and porphyritic character of the Yachats Basalt and the abundance of multiple dikes suggest that the magma that produced these rocks was differentiated in the upper crust before extrusion. The Yachats Basalt, and correlative upper Eocene volcanic rocks in western Oregon and Washington, lie along a generally north-trending belt. The predominance of normal faulting in western Oregon and Washington and on the adjacent continental shelf during post mid-late Eocene time suggests that the volcanics were extruded along a zone of tensional rifting. They do not appear to be related to conventional plate models for continental margins that arc characterized by deep trenches flanked by island arcs.

Oregon

Gas hydrates on Alaskan marine margins

Gas hydrate distributions on the marine margins of the U.S. state of Alaska are more poorly known than those on other U.S. margins, where bottom simulating reflections have been systematically mapped on marine seismic data to support modern, quantitative assessments of gas-in-place in gas hydrates. The extent of bottom simulating reflections in the U.S. Beaufort Sea has been known since the late 1970s, and researchers have investigated the possibility that remnant gas hydrate persists in association with decaying subsea permafrost on both the U.S. and Canadian Beaufort continental shelves. In the Bering Sea, possible gas hydrate-related features have been widely mapped, revealing zones of free gas and concentrated gas hydrate within the hydrate stability zone in features called velocity amplitude anomalies (VAMPs). However, there are few reports on bottom simulating reflections along the more than 2500 km of the Aleutian arc and along the transform plate margin in southeast Alaska. Here we examine selected seismic profiles from southeast Alaska, along the Aleutian margin, and on the Bering continental slope, emphasizing surveys acquired with large airgun arrays, and review the results obtained from Bering Sea’s Aleutian Basin and from the U.S. Beaufort Sea. In the new analyses, we detect hydrate-related bottom simulating reflections in southeastern Alaska and the eastern and central parts of the Aleutian arc, but not in the western Aleutian arc or beneath the continental slope from the island arc north into the Aleutian Basin. In the Bering Sea, recognition of hydrate-related bottom simulating reflections is complicated by the widespread existence of a bottom simulating reflector associated with a diagenetic transition (opal CT). Our detection of continental slope hydrate-related bottom simulating reflections in southeast Alaska and the eastern and central Aleutian arcs expands the area of potential gas hydrate distribution on Alaskan margins and underscores the need for more systematic analysis of existing seismic data to inform quantitative evaluation of gas-in-place.

Alaska

Tectonic transition zone in the northeastern Caribbean

Seismic reflection data indicate that the Atlantic plate has been underthrust beneath the Caribbean plate east of the Lesser Antilles. The data further reveal that the transition from underthrust to strike-slip plate motion occurs near lat 19.3° N. and long 62° W. in alinement with the Anegada Trough. Oceanic basement and reflectors above basement have not been detected beneath the landward wall of the Puerto Rico Trench west of the transition zone. Southeast of the zone, the horizontal distance over which the reflectors and basement can be traced beneath the landward wall (outer part of the Lesser Antilles rise) systematically increases from a few kilometers in the north to as much as 37 km near lat 16.5° N. If a thrust fault emerges at the landward trench wall, the data suggest that a decollement exists between reflectors above basement and an overlying acoustically transparent zone. Gravity and seismic refraction data indicate a thick accumulation of low-density, low-velocity material beneath the Lesser Antilles rise, possibly sediments scraped off the underthrusting Atlantic plate, although massive slumping might cause a similar low-density configuration. The magmatic history of the Lesser Antilles arc suggests two periods of underthrusting, one in the Mesozoic or early Cenozoic and a second in the late Cenozoic. Although the magmatic history of the Lesser Antilles apparently began in the Mesozoic, its Cenozoic history is remarkably similar to the Cenozoic histories of circum-Pacific arcs. Magmatic histories in both areas suggest that island arc evolution in the Cenozoic may have worldwide synchroneity.

Journal of Research of the U.S. Geological Survey

Subduction erosion of the Jurassic Talkeetna-Bonanza arc and the Mesozoic accretionary tectonics of western North America

The Jurassic Talkeetna volcanic arc of south-central Alaska is an oceanic island arc that formed far from the North American margin. Geochronological, geochemical, and structural data indicate that the arc formed above a north-dipping subduction zone after ca. 201 Ma. Magmatism migrated northward into the region of the Talkeetna Mountains ca. 180 Ma. We interpret this magmatism as the product of removal of the original forearc while the arc was active, mainly by tectonic erosion. Rapid exhumation of the arc after ca. 160 Ma coincided with the sedimentation of the coarse clastic Naknek Formation. This exhumation event is interpreted to reffect collision of the Talkeetna arc with either the active margin of North America or the Wrangellia composite terrane to the north along a second north-dipping subduction zone. The juxtaposition of accreted trench sedimentary rocks (Chugach terrane) against the base of the Talkeetna arc sequence requires a change from a state of tectonic erosion to accretion, probably during the Late Jurassic (before 150 Ma), and definitely before the Early Cretaceous (ca. 125 Ma). The change from erosion to accretion probably reflects increasing sediment flux to the trench due to collision ca. 160 Ma. ?? 2005 Geological Society of America.

Geology

Arc-related porphyry molybdenum deposit model

This report provides a descriptive model for arc-related porphyry molybdenum deposits. Presented within are geological, geochemical, and mineralogical characteristics that differentiate this deposit type from porphyry copper and alkali-feldspar rhyolite-granite porphyry molybdenum deposits. The U.S. Geological Survey's effort to update existing mineral deposit models spurred this research, which is intended to supplement previously published models for this deposit type that help guide mineral-resource and mineral-environmental assessments. Arc-related porphyry molybdenum deposits are a substantial resource for molybdenum metal and may have anomalous concentrations of tungsten. The deposits contain low-grade ore (0.03-0.22 percent molybdenum) as molybdenite, but are large-tonnage, making them amenable to bulk mining open-pit techniques. The mineralizing system usually has fluorine contents of less than 0.1 percent. The cogenetic intrusion is a differentiated calc-alkaline granitoid, typically granodiorite to quartz monzonite in composition, with low rubidium and niobium, and moderate to high strontium concentrations. Metals and hydrothermal fluids are sourced from these intrusions, with an additional meteoric fluid component contributing to peripheral alteration but not adding more metal. The lithology of the surrounding country rocks is not important to the formation of these deposits, but a surrounding carbonate unit may be altered to skarn that contains economic mineralization. The creation of contact-metamorphosed hornfels adjacent to the intrusion is common. Formation of arc-related porphyry molybdenum deposits typically occurs within a continental arc environment related to arc-continent or continent-continent collision and subduction. Few deposits are found in an island arc setting. Most classified arc-related porphyry molybdenum deposits are located in the western cordillera of North America, notably in British Columbia and Alaska. Hydrothermal alteration provides a key component to the identification of a deposit. Alteration usually is zoned from a core of potassic plus/minus silicic alteration outwards through phyllic to propylitic alteration. Argillic alteration may be irregular in shape and will overprint earlier hydrothermal alteration. Exploration should be limited to magmatic arc belts that have been unroofed and eroded to levels of a few kilometers depth. Important geological vectors toward areas of higher grade mineralization include intensity of hydrothermal alteration, veining, and faulting. Anomalous levels of molybdenum, tungsten, copper, lead, or zinc in soils, tills, stream sediments, and drainage waters may indicate the presence of an arc-related porphyry molybdenum deposit. Geophysical exploration techniques have been met with minimal success because of the overall low concentration of associated sulfide and oxide minerals. Geoenvironmental concerns are generally low because of low volumes of sulfide minerals. Most deposits are marginally acid-generating to non-acid-generating with drainage waters being near-neutral pH because of the acid generating potential of pyrite being partially buffered by late-stage calcite-bearing veins. The low ore content results in a waste:ore ratio of nearly 1:1 and large tailings piles from the open-pit method of mining.

Scientific Investigations Report

Pillow basalts of the Angayucham terrane: Oceanic plateau and island crust accreted to the Brooks Range

The Angayucham Mountains (north margin of the Yukon-Koyukuk province) are made up of an imbricate stack of four to eight east-west trending, steeply dipping, fault slabs composed of Paleozoic (Devonian to Mississippean), Middle to Late Triassic, and Early Jurassic oceanic upper crustal rocks (pillow basalt, subordinate diabase, basaltic tuff, and radiolarian chert). Field relations and geochemical characteristics of the basaltic rocks suggest that the fault slabs were derived from an oceanic plateau or island setting and were emplaced onto the Brooks Range continental margin. The basalts are variably metamorphosed to prehnite-pumpellyite and low-greenschist facies. Major element analyses suggest that many are hypersthene-normative olivine tholeiites. Classification based on immobile trace elements confirms the tholeiitic character of most of the basalts but suggests that some had primary compositions transitional to alkali basalt. Although field and petrographic features of the basalts are similar, trace element characteristics allow definition of geographically distinct suites. A central outcrop belt along the crest of the mountains is made up of basalt with relatively flat rare earth element (REE) patterns. This belt is flanked to the north and south by LREE (light rare earth element)-enriched basalts. Radiolarian and conodont ages from interpillow and interlayered chert and limestone indicate that the central belt of basalts is Triassic in age, the southern belt is Jurassic in age, and the northern belt contains a mixture of Paleozoic and Mesozoic ages. Data for most of the basalts cluster in the “within-plate basalt” fields of trace element discriminant diagrams; none have trace-element characteristics of island arc basalt. The Triassic and Jurassic basalts are geochemically most akin to modern oceanic plateau and island basalts. Field evidence also favors an oceanic plateau or island setting. The great composite thickness of pillow basalt probably resulted from obduction faulting, but the lack of fault slabs of gabbro or peridotite suggests that obduction faults did not penetrate below oceanic layer 2, a likely occurrence if layer 2 were anomalously thick, as in the vicinity of an oceanic island. The presence of basaltic tuff interbeds indicates proximity to an explosive basaltic eruptive center. The juxtaposition of submarine basalts of differing chemical affinity and age, adjacent to higher-grade Paleozoic metamorphic rocks of the Brooks Range to the north, may be explained by obduction of internally complex (thickened) oceanic crust formed in an ocean plateau setting. Emplacement and rotation of thrust plates to steep attitudes occurred during accretion of the Brooks Range passive margin, probably beginning in the Late to Middle Jurassic.

Journal of Geophysical Research Solid Earth

Isostatic residual gravity and crustal geology of the United States

A new isostatic residual gravity map of the conterminous United States presents continent-wide gravity data in a form that can be readily used, with geologic information and other geophysical data, in studies of the composition and structure of the continental crust. This map was produced from the gridded gravity data on which the recently released Gravity Anomaly Map of the United States is based. About 1 million onland and 0.8 million offshore gravity observations interpolated to a 4- by 4-km grid serve as the basis for both maps. The Airy-Heiskanen model of isostatic compensation of topography applied to topographic and bathymetric data averaged over 5- by 5-min compartments was used to remove, to first order, the large, long-wavelength Bouguer gravity anomalies caused by deep density distributions that support topographic loads. The parameters used in the Airy-Heiskanen model were topographic density, 2.67 g/cm 3 ; sea-level crustal thickness, 30 km; and density contrast across the base of the model crust, 0.35 g/cm 3 . Many of the conspicuous short-wavelength anomalies (widths less than several hundred kilometers) on the isostatic residual gravity map correlate with mapped or near-surface geologic features, and primarily reflect shallow-density distributions rather than any departures from isostatic equilibrium. In general, gravity highs occur over (1) mafic igneous bodies emplaced in rift or magmatic arc settings or as isolated intrusions controlled by structures; (2) accreted slices of mafic oceanic, island-arc, or transitional crust; and (3) uplifted crystalline basement. Gravity lows are found over (1) thick bodies of felsic intrusive or extrusive rocks; (2) sedimentary deposits in extensional, convergent, or transform settings; and (3) depressed crystalline basement. Anomalies with widths as much as 1,000 km or more also appear to reflect crustal properties in many cases—several broad gravity highs are associated with crust having a high average seismic wave velocity, and comparable broad gravity lows occur over areas of low average seismic velocity. Alternative ways of viewing the isostatic residual gravity data provide additional information about density distributions in the crust. The first-vertical derivative map accentuates gravity anomalies over shallow, abrupt density changes at the expense of those resulting from deeper or more gradual density transitions. The maximum horizontal gradient map contains information about the locations of pronounced density boundaries. Two-dimensional spectral analysis of the gravity data provides a quantitative means for identifying dominant fabrics in the gravity field and for distinguishing various terranes from each other. Neither Bouguer nor isostatic residual gravity anomalies are particularly well suited for practical modeling of deep structure in conjunction with deep seismic information. However, a scheme in which the entire Earth outside the area of interest is approximated by laterally homogeneous layers and isostatically compensated topography, and in which the area of interest is modeled using the seismic constraints applied in a two-and-one-half-dimensional geometry, holds promise for exploiting useful features of both the Bouguer and isostatic residual gravity anomalies.

conterminous United States

Geology and origin of the late Proterozoic Darb Zubaydah ophiolite, Kingdom of Saudi Arabia

The Late Proterozoic (830 ± 20 Ma) Darb Zubaydah ophiolite, north-central Arabian Shield, preserves a largely intact section consisting of ultramafic rocks, gabbro, diabase, granodiorite, and interbedded volcanic and sedimentary rocks. Formation of these rocks within or near an island arc is indicated by the absence of pelagic sediments and the abundance of pillow basalt, turbiditic sediments, lahar deposits, and basaltic to rhyolitic tuff. The oldest extrusive rocks, which range from tholeiites with MORB characteristics to calc-alkaline andesites and rhyolites, formed in a young, relatively un-evolved island are or in a back-arc basin sufficiently close to an arc to receive calc-alkaline lava flows and coarse-grained, arc-derived detritus. tus. Overlying turbidites and lahar deposits of the Kaffan sandstone point to the initiation of a rifting event. High-Ti basalts, which erupted above the Kaffan sandstone, and related diabase are interpreted to be magmatic products of incipient intra-arc rifting. Renewed arc volcanism produced calc-alkaline volcanic rocks that interfingered with the high-Ti basalt and later dominated the section as the volcanic apron of the arc prograded basinward. Extrusion of voluminous calc-alkaline tuff may have been contemporaneous with intrusion of granodiorite and gravity-driven landsliding.

Geological Society of America Bulletin

Detrital U-Pb zircon dating of lower Ordovician syn-arc-continent collision conglomerates in the Irish Caledonides

The Early Ordovician Grampian Orogeny in the British Isles represents a classic example of collision between an oceanic island arc and a passive continental margin, starting around 480 Ma. The South Mayo Trough in western Ireland preserves a complete and well-dated sedimentary record of arc collision. We sampled sandstones and conglomerates from the Rosroe, Maumtrasna and Derryveeny Formations in order to assess erosion rates and patterns during and after arc collision. U–Pb dating of zircons reveals a provenance dominated by erosion from the upper levels of the Dalradian Supergroup (Southern Highland and Argyll Groups), with up to 20% influx from the colliding arc into the Rosroe Formation, but only 6% in the Maumtrasna Formation (~ 465 Ma). The dominant source regions lay to the northeast (e.g. in the vicinity of the Ox Mountains, 50 km distant, along strike). The older portions of the North Mayo Dalradian and its depositional basement (the Annagh Gneiss Complex) do not appear to have been important sources, while the Connemara Dalradian only plays a part after 460 Ma, when it supplies the Derryveeny Formation. By this time all erosion from the arc had effectively ceased and exhumation rates had slowed greatly. The Irish Grampian Orogeny parallels the modern Taiwan collision in showing little role for the colliding arc in the production of sediment. Negligible volumes of arc crust are lost because of erosion during accretion to the continental margin.

British Isles

Arc-continent collision and the formation of continental crust: A new geochemical and isotopic record from the Ordovician Tyrone Igneous Complex, Ireland

Collisions between oceanic island-arc terranes and passive continental margins are thought to have been important in the formation of continental crust throughout much of Earth's history. Magmatic evolution during this stage of the plate-tectonic cycle is evident in several areas of the Ordovician Grampian-Taconic orogen, as we demonstrate in the first detailed geochemical study of the Tyrone Igneous Complex, Ireland. New U-Pb zircon dating yields ages of 493 2 Ma from a primitive mafic intrusion, indicating intra-oceanic subduction in Tremadoc time, and 475 10 Ma from a light rare earth element (LREE)-enriched tonalite intrusion that incorporated Laurentian continental material by early Arenig time (Early Ordovician, Stage 2) during arc-continent collision. Notably, LREE enrichment in volcanism and silicic intrusions of the Tyrone Igneous Complex exceeds that of average Dalradian (Laurentian) continental material that would have been thrust under the colliding forearc and potentially recycled into arc magmatism. This implies that crystal fractionation, in addition to magmatic mixing and assimilation, was important to the formation of new crust in the Grampian-Taconic orogeny. Because similar super-enrichment of orogenic melts occurred elsewhere in the Caledonides in the British Isles and Newfoundland, the addition of new, highly enriched melt to this accreted arc terrane was apparently widespread spatially and temporally. Such super-enrichment of magmatism, especially if accompanied by loss of corresponding lower crustal residues, supports the theory that arc-continent collision plays an important role in altering bulk crustal composition toward typical values for ancient continental crust. ?? 2009 Geological Society of London.

Journal of the Geological Society

Strontium and oxygen isotopic variations in Mesozoic and Tertiary plutons of central Idaho

Regional variations in initial 87Sr/86Sr ratios (ri) of Mesozoic plutons in central Idaho locate the edge of Precambrian continental crust at the boundary between the late Paleozoic-Mesozoic accreted terranes and Precambrian sialic crust in western Idaho. The ri values increase abruptly but continuously from less than 0.704 in the accreted terranes to greater than 0.708 across a narrow, 5 to 15 km zone, characterized by elongate, lens-shaped, highly deformed plutons and schistose metasedimentary and metavolcanic units. The chemical and petrologic character of the plutons changes concomitantly from ocean-arc-type, diorite-tonalite-trondhjemite units to a weakly peraluminous, calcic to calcalkalic tonalite-granodiorite-granite suite (the Idaho batholith). Plutons in both suites yield Late Cretaceous ages, but Permian through Early Cretaceous bodies are confined to the accreted terranes and early Tertiary intrusions are restricted to areas underlain by Precambrian crust. The two major terranes were juxtaposed between 75 and 130 m.y. ago, probably between 80 and 95 m.y. Oxygen and strontium isotopic ratios and Rb and Sr concentrations of the plutonic rocks document a significant upper-crustal contribution to the magmas that intrude Precambrian crust. Magmas intruding the arc terranes were derived from the upper mantle/subducted oceanic lithosphere and may have been modified by anatexis of earlier island-arc volcanic and sedimentary units. Plutons near the edge of Precambrian sialic crust represent simple mixtures of the Precambrian wall-rocks with melts derived from the upper mantle or subducted oceanic lithosphere with ri of 0.7035. Rb/Sr varies linearly with ri, producing "pseudoisochrons" with apparent "ages" close to the age of the wall rocks. Measured ??18O values of the wall rocks are less than those required for the assimilated end-member by Sr-O covariation in the plutons, however, indicating that wall-rock ??18O was reduced significantly by exchange with circulating fluids. Metasedimentary rocks of the Belt Supergroup are similarly affected near the batholith, documenting a systematic depletion in 18O as much as 50 km from the margin of the batholith. Plutons of the Bitterroot lobe of the Idaho batholith are remote from the accreted terranes and represent mixtures of Precambrian wall-rocks with melts dominated by continental lower crust (ri>0.708) rather than mantle. "Pseudoisochrons" resulting from these data are actually mixing lines that yield apparent "ages" less than the true age of the wall rocks and meaningless "ri". Assimilation/ fractional-crystallization models permit only insignificant amounts of crystal fractionation during anatexis and mixing for the majority of plutons of the region. ?? 1985 Springer-Verlag.

Contributions to Mineralogy and Petrology