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USGS2010

Contamination of basaltic lava by seawater: Evidence found in a lava pillar from Axial Seamount, Juan de Fuca Ridge

A lava pillar formed during the 1998 eruption at Axial Seamount exhibits compositional and textural evidence for contamination by seawater under magmatic conditions. Glass immediately adjacent to anastomosing microfractures within 1 cm of the inner pillar wall is oxidized and significantly enriched in Na and Cl and depleted in Fe and K with respect to that in glassy selvages from the unaffected outer pillar wall. The affected glass contains up to 1 wt % Cl and is enriched by ∼2 wt % Na 2 O relative to unaffected glass, consistent with a nearly 1:1 (molar) incorporation of NaCl. Glass bordering the Cl‐enriched glass in the inner pillar wall is depleted in Na but enriched in K. The presence of tiny (<10 μ m) grains of Cu‐Fe sulfides and Fe sulfides as well as elemental Ni, Ag, and Au in the Na‐depleted, K‐enriched glass of the inner pillar wall implies significant reduction of this glass, presumably by hydrogen generated during seawater contamination and oxidation of lava adjacent to microfractures. We interpret the compositional anomalies we see in the glass of the interior pillar wall as caused by rapid incorporation of seawater into the still‐molten lava during pillar growth, probably on the time scale of seconds to minutes. Only one of seven examined lava pillars shows this effect, and we interpret that seawater has to be trapped in contact with molten lava (inside the lava pillar, in this case) to produce the effects we see. Thus, under the right conditions, seawater contamination of lavas during submarine eruptions is one means by which the oceanic crust can sequester Cl during its global flux cycle. However, since very few recent lava flows have been examined in similar detail, the global significance of this process in effecting Earth's Cl budget remains uncertain.

Geochemistry, Geophysics, Geosystems↗

USGS2010

Clockwise rotation and implications for northward drift of the western Transverse Ranges from paleomagnetism of the Piuma Member, Sespe Formation, near Malibu, California

New paleomagnetic results from mid-Tertiary sedimentary beds in the Santa Monica Mountains reinforce the evidence for large-scale rotation of the western Transverse Ranges, and anisotropy measurements indicate that compaction-induced inclination flattening may resolve a long-standing controversy regarding the original paleolatitude of the rotated block. Previously published paleomagnetic data indicate that post-Oligocene rotation amounts to 70°–110° clockwise, affecting the Channel Islands, Santa Monica Mountains, and Santa Ynez Mountains. The Sespe Formation near Malibu consists of a lower member dominated by nonmarine sandstone and conglomerate and an upper section, the Piuma Member, which consists of gray-red sandstone and mudstone interbedded with minor tuff and limestone beds. The Piuma Member has a paleomagnetic pole at 36.6°N, 326.7°E (A 95min = 5.0°, A 95max = 9.6°), obtained by thermal demagnetization of 34 oriented cores from Oligocene and early Miocene beds. After correcting for plunge of the geologic structure, the data are consistent with significant clockwise rotation (77° ± 7°) of the region relative to stable North America. Rotation of the western Transverse Ranges is generally viewed as a consequence of Pacific–North American plate interactions after 28 Ma, when east–west subduction gave way to northwest transform motion in southern California. Inclinations from the Piuma study indicate a paleolatitude anomaly of 11° ± 7° and are consistent with a mean northward drift that exceeds generally accepted San Andreas fault displacement by a factor of 3. However, sedimentary inclination error may accentuate the anomaly. Anisotropy of isothermal remanent magnetization indicates inclination flattening of approximately 8°, and correction for the effect reduces the paleolatitude anomaly to 5.3° ± 5.8°. Compaction may explain the inclination flattening in these sedimentary rocks, but the process does not adequately explain lower-than-expected inclinations found in previous studies of Miocene volcanic rocks of the western Transverse Ranges.

Geochemistry, Geophysics, Geosystems↗

USGS2010

Time-averaged paleomagnetic field at the equator: Complete data and results from the Galapagos Islands, Ecuador

We present here the complete paleomagnetic laboratory results from a collection of approximately 1500 oriented cores from all 16 of the Galapagos Islands, Ecuador, collected by Allan Cox in 1964–1965 but nearly all previously unpublished. The islands are located in the eastern Pacific Ocean within 1.4° of latitude from the equator and range in age from historically erupted to 3 Ma, mostly determined by published K-Ar and 3He isotopic dating. The number of sites collected on each island ranges from 1 to 28, for a total of 186. After combining duplicate site mean directions, 149 are used for an overall mean direction and 8 represent excursions and one reversal path. Divided by geomagnetic polarity chron, 110 site means are Brunhes or Jaramillo (normal polarity), 27 are Matuyama (reversed polarity), and 12 are Gauss (both polarities). We have completed the magnetic cleaning that was commenced in the late 1960s. Secondary (mostly viscous) magnetizations were nearly all removed by alternating field demagnetization at 10 mT. We have used the so-called blanket cleaning method, generally at 10 mT. All sites were in basalt flows and gave good paleomagnetic results; none was rejected in toto, and only a few core specimens were magnetically unsatisfactory. Nearly all sites had eight independently oriented cores, and within-site angular standard deviations of directions range from 1° to 8°. We used both Fisher and Bingham statistics to analyze the data and found that many of the direction populations are strongly elongate along the paleomagnetic meridian, while the corresponding virtual pole (VGP) populations are essentially circularly distributed. The paleomagnetic poles, calculated as the means of VGPs, are as follows: Brunhes and Jaramillo, north latitude = 86.9°, east longitude = 245.1°, and 95% confidence radius A 95 = 1.9°; Matuyama, latitude = 87.2°, longitude = 158.2°, and A 95 = 3.8°; Gauss, latitude = 83.0°, longitude = 204.7°, and A 95 = 7.0°. These paleomagnetic poles do not differ significantly from one another, but the Brunhes and Jaramillo combined pole is significantly near-sided with respect to the Galapagos, as is the overall mean pole, which is at latitude = 87.1° and longitude = 227.6°, with A 95 = 1.7°. Omitting the excursion and reversal path data, the overall angular standard deviation of VGPs is 11.7° with lower and upper 95% confidence limits of 10.8° and 12.7°, respectively, in good agreement with previously published values for near-equatorial sampling latitudes.

Galapagos Islands↗

USGS2010

Atmospheric mineral dust in dryland ecosystems: Applications of environmental magnetism

Magnetic properties of shallow (<10‐cm depth), fine‐grained surficial sediments contrast greatly with those of immediately underlying bedrock across much of the dry American Southwest. At 26 study sites in fine‐grained (<63 μ m) surficial sediments isolated from alluvial inputs, isothermal remanent magnetization (IRM; mean of 67 samples = 6.72 × 10 −3 Am 2 kg −1 ) is more than two orders of magnitude greater than that for underlying Paleozoic and Mesozoic sedimentary rocks. This contrast is mainly caused by the presence of silt‐size, titanium‐bearing magnetite particles in the surficial deposits and their absence in bedrock. Because of their size, composition, and isolated location, the magnetite particles represent a component of atmospheric dust likely deposited over the past few centuries. The positive correlation of sediment‐IRM values with amounts of potential plant nutrients reveals the importance of atmospheric dust to soil fertility over much of the American Southwest. Subsequent disturbance of landscapes, by domestic livestock grazing as an example, commonly results in wind erosion, which then depletes exposed surfaces of original aeolian magnetite and associated fine‐grained sediment. Declines in soil fertility and water‐holding capacity in these settings can be estimated in some field settings via decreases in magnetic susceptibility, relative to nearby undisturbed areas. Along gentle hillslope gradients of the Colorado Plateau, field measures for aeolian magnetite demonstrate that the redistribution of deposited atmospheric dust influences landscape‐level patterns in the distribution of invasive exotic plant species. Our results indicate that environmental magnetism has high potential for assessing the development and degradation of dry landscapes elsewhere.

Geochemistry, Geophysics, Geosystems↗

USGS2010

Low‐productivity Hawaiian volcanism between Kaua‘i and O‘ahu

The longest distance between subaerial shield volcanoes in the Hawaiian Islands is between the islands of Kaua‘i and O‘ahu, where a field of submarine volcanic cones formed astride the axis of the Hawaiian chain during a period of low magma productivity. The submarine volcanoes lie ∼25–30 km west of Ka‘ena Ridge that extends ∼80 km from western O‘ahu. These volcanoes were sampled by three Jason2 dives. The cones are flat topped, <400 m high and 0.4–2 km in diameter at water depths between ∼2700 and 4300 m, and consist predominantly of pillowed flows. Ar‐Ar and K‐Ar ages of 11 tholeiitic lavas are between 4.9 and 3.6 Ma. These ages overlap with shield volcanism on Kaua‘i (5.1–4.0 Ma) and Wai‘anae shield basalts (3.9–3.1 Ma) on O‘ahu. Young alkalic lavas (circa 0.37 Ma) sampled southwest of Ka‘ena Ridge are a form of offshore secondary volcanism. Half of the volcanic cones contain high‐SiO 2 basalts (51.0–53.5 wt % SiO 2 ). The trends of isotopic compositions of West Ka‘ena tholeiitic lavas diverge from the main Ko‘olau‐Kea shield binary mixing trend in isotope diagrams and extend to lower 208 Pb/ 204 Pb and 206 Pb/ 204 Pb than any Hawaiian tholeiitic lava. West Ka‘ena tholeiitic lavas have geochemical and isotopic characteristics similar to volcanoes of the Loa trend. Hence, our results show that the Loa‐type volcanism has persisted for at least 4.9 Myr, beginning prior to the development of the dual, subparallel chain of volcanoes. Several West Ka‘ena samples are similar to higher SiO 2 , Loa trend lavas of Ko‘olau Makapu‘u stage, Lāna‘i, and Kaho‘olawe; these lavas may have been derived from a pyroxenite source in the mantle. The high Ni contents of olivines in West Ka‘ena lavas also indicate contribution from pyroxenite‐derived melting. Average compositions of Hawaiian shield volcanoes show a clear relation between 206 Pb/ 204 Pb and SiO 2 within Loa trend volcanoes, which supports a prominent but variable influence of pyroxenite in the Hawaiian plume source. In addition, both Pb isotopes and volcano volume show a steady increase with time starting from a minimum west of Ka‘ena Ridge. The entrained mafic component in the Hawaiian plume is probably not controlling the increasing magma productivity in the Hawaiian Islands.

Hawaii↗

USGS2010

A rapid method for the measurement of sulfur hexafluoride (SF6), trifluoromethyl sulfur pentafluoride (SF5CF3), and Halon 1211 (CF2ClBr) in hydrologic tracer studies

A rapid headspace method for the simultaneous laboratory determination of intentionally introduced hydrologic tracers, sulfur hexafluoride (SF6), trifluoromethyl sulfur pentafluoride (SF5CF3), Halon 1211 (CF2ClBr), and other halocarbons in water and gases is described. The high sensitivity of the procedure allows for introduction of minimal tracer mass (a few grams) into hydrologic systems with a large dynamic range of analytical detection (dilutions to 1:108). Analysis times by gas chromatography with electron capture detector are less than 1 min for SF6; about 2 min for SF6 and SF5CF3; and 4 min for SF6, SF5CF3, and Halon 1211. Many samples can be rapidly collected, preserved in stoppered septum bottles, and analyzed at a later time in the laboratory. Examples are provided showing the effectiveness of the gas tracer test studies in varied hydrogeological settings.

Geochemistry, Geophysics, Geosystems↗

USGS2011

A multitracer approach for characterizing interactions between shallow groundwater and the hydrothermal system in the Norris Geyser Basin area, Yellowstone National Park

Multiple environmental tracers are used to investigate age distribution, evolution, and mixing in local‐ to regional‐scale groundwater circulation around the Norris Geyser Basin area in Yellowstone National Park. Springs ranging in temperature from 3°C to 90°C in the Norris Geyser Basin area were sampled for stable isotopes of hydrogen and oxygen, major and minor element chemistry, dissolved chlorofluorocarbons, and tritium. Groundwater near Norris Geyser Basin is comprised of two distinct systems: a shallow, cool water system and a deep, high‐temperature hydrothermal system. These two end‐member systems mix to create springs with intermediate temperature and composition. Using multiple tracers from a large number of springs, it is possible constrain the distribution of possible flow paths and refine conceptual models of groundwater circulation in and around a large, complex hydrothermal system.

Wyoming↗

USGS2011

Cooling rates and the depth of detachment faulting at oceanic core complexes: Evidence from zircon Pb/U and (U-Th)/He ages

Oceanic detachment faulting represents a distinct mode of seafloor spreading at slow spreading mid‐ocean ridges, but many questions persist about the thermal evolution and depth of faulting. We present new Pb/U and (U‐Th)/He zircon ages and combine them with magnetic anomaly ages to define the cooling histories of gabbroic crust exposed by oceanic detachment faults at three sites along the Mid‐Atlantic Ridge (Ocean Drilling Program (ODP) holes 1270D and 1275D near the 15°20′N Transform, and Atlantis Massif at 30°N). Closure temperatures for the Pb/U (∼800°C–850°C) and (U‐Th)/He (∼210°C) isotopic systems in zircon bracket acquisition of magnetic remanence, collectively providing a temperature‐time history during faulting. Results indicate cooling to ∼200°C in 0.3–0.5 Myr after zircon crystallization, recording time‐averaged cooling rates of ∼1000°C–2000°C/Myr. Assuming the footwalls were denuded along single continuous faults, differences in Pb/U and (U‐Th)/He zircon ages together with independently determined slip rates allow the distance between the ∼850°C and ∼200°C isotherms along the fault plane to be estimated. Calculated distances are 8.4 ± 4.2 km and 5.0 ± 2.1 km from holes 1275D and 1270D and 8.4 ± 1.4 km at Atlantis Massif. Estimating an initial subsurface fault dip of 50° and a depth of 1.5 km to the 200°C isotherm leads to the prediction that the ∼850°C isotherm lies ∼5–7 km below seafloor at the time of faulting. These depth estimates for active fault systems are consistent with depths of microseismicity observed beneath the hypothesized detachment fault at the TAG hydrothermal field and high‐temperature fault rocks recovered from many oceanic detachment faults.

Geochemistry, Geophysics, Geosystems↗

USGS2011

Modeling sulfate reduction in methane hydrate-bearing continental margin sediments: Does a sulfate-methane transition require anaerobic oxidation of methane?

The sulfate‐methane transition (SMT), a biogeochemical zone where sulfate and methane are metabolized, is commonly observed at shallow depths (1–30 mbsf) in methane‐bearing marine sediments. Two processes consume sulfate at and above the SMT, anaerobic oxidation of methane (AOM) and organoclastic sulfate reduction (OSR). Differentiating the relative contribution of each process is critical to estimate methane flux into the SMT, which, in turn, is necessary to predict deeper occurrences of gas hydrates in continental margin sediments. To evaluate the relative importance of these two sulfate reduction pathways, we developed a diagenetic model to compute the pore water concentrations of sulfate, methane, and dissolved inorganic carbon (DIC). By separately tracking DIC containing 12 C and 13 C, the model also computes δ 13 C‐DIC values. The model reproduces common observations from methane‐rich sediments: a well‐defined SMT with no methane above and no sulfate below and a δ 13 C‐DIC minimum at the SMT. The model also highlights the role of upward diffusing 13 C‐enriched DIC in contributing to the carbon isotope mass balance of DIC. A combination of OSR and AOM, each consuming similar amounts of sulfate, matches observations from Site U1325 (Integrated Ocean Drilling Program Expedition 311, northern Cascadia margin). Without AOM, methane diffuses above the SMT, which contradicts existing field data. The modeling results are generalized with a dimensional analysis to the range of SMT depths and sedimentation rates typical of continental margins. The modeling shows that AOM must be active to establish an SMT wherein methane is quantitatively consumed and the δ 13 C‐DIC minimum occurs. The presence of an SMT generally requires active AOM.

Geochemistry, Geophysics, Geosystems↗

USGS2011

Gravity lineaments of the Cocos Plate: Evidence for a thermal contraction crack origin

Lineaments in the gravity field with wavelengths of 100–200 km affect the south-central Pacific. Because they align with absolute plate motion, it has been proposed that they reflect small-scale convection cells beneath the lithosphere that become elongated by basal shear. Alternatively, it was suggested that they reflect channelized flow of low viscosity material following the base of the lithosphere toward the East Pacific Rise, or that they result from lithospheric-scale thermal contraction cracks. Here, we report about previously undetected gravity lineaments across the Cocos Plate. Similarly to the south-central Pacific lineaments, the Cocos lineaments affect a plate that is anomalously shallow, with seamounts aligning mostly within their troughs. However, the Cocos lineaments strike markedly oblique to absolute plate motion and follow instead trajectories that are perpendicular to seafloor isochrons, a characteristic best explained by the thermal contraction crack model. The presence of steep scarps at the base of seamounts and the seismic imaging of faults striking perpendicular to isochrons further support this interpretation. Assuming that the slow subsidence rates of the south-central Pacific and Cocos plates reflect a warmer upper mantle, we propose that the associated thinner elastic plates favor the formation of thermal contraction cracks. A thinner elastic plate may also explain the pattern of ridge propagation in both areas. At large ridge offsets with a history of steady migration, the propagating segments have been those cutting into the shallower flanks, consistent with the concept that a warmer, thinner plate is more easily cracked.

Geochemistry Geophysics Geosystems↗

USGS2011

Shallow lithological structure across the Dead Sea Transform derived from geophysical experiments

In the framework of the DEad SEa Rift Transect (DESERT) project a 150 km magnetotelluric profile consisting of 154 sites was carried out across the Dead Sea Transform. The resistivity model presented shows conductive structures in the western section of the study area terminating abruptly at the Arava Fault. For a more detailed analysis we performed a joint interpretation of the resistivity model with a P wave velocity model from a partially coincident seismic experiment. The technique used is a statistical correlation of resistivity and velocity values in parameter space. Regions of high probability of a coexisting pair of values for the two parameters are mapped back into the spatial domain, illustrating the geographical location of lithological classes. In this study, four regions of enhanced probability have been identified, and are remapped as four lithological classes. This technique confirms the Arava Fault marks the boundary of a highly conductive lithological class down to a depth of ∼3 km. That the fault acts as an impermeable barrier to fluid flow is unusual for large fault zone, which often exhibit a fault zone characterized by high conductivity and low seismic velocity. At greater depths it is possible to resolve the Precambrian basement into two classes characterized by vastly different resistivity values but similar seismic velocities. The boundary between these classes is approximately coincident with the Al Quweira Fault, with higher resistivities observed east of the fault. This is interpreted as evidence for the original deformation along the DST originally taking place at the Al Quweira Fault, before being shifted to the Arava Fault.

Dead Sea↗

USGS2012

Deep magmatic degassing versus scrubbing: Elevated CO2 emissions and C/S in the lead-up to the 2009 eruption of Redoubt Volcano, Alaska

We report CO 2, SO 2 , and H 2 S emission rates and C/S ratios during the five months leading up to the 2009 eruption of Redoubt Volcano, Alaska. CO 2 emission rates up to 9018 t/d and C/S ratios ≥30 measured in the months prior to the eruption were critical for fully informed forecasting efforts. Observations of ice-melt rates, meltwater discharge, and water chemistry suggest that surface waters represented drainage from surficial, perched reservoirs of condensed magmatic steam and glacial meltwater. These fluids scrubbed only a few hundred tonnes/day of SO 2 , not the >2100 t/d SO 2 expected from degassing of magma in the mid- to upper crust (3–6.5 km), where petrologic analysis shows the final magmatic equilibration occurred. All data are consistent with upflow of a CO 2 -rich magmatic gas for at least 5 months prior to eruption, and minimal scrubbing of SO 2 by near-surface groundwater. The high C/S ratios observed could reflect bulk degassing of mid-crustal magma followed by nearly complete loss of SO 2 in a deep magmatic-hydrothermal system. Alternatively, high C/S ratios could be attributed to decompressional degassing of low silica andesitic magma that intruded into the mid-crust in the 5 months prior to eruption, thereby mobilizing the pre-existing high silica andesite magma or mush in this region. The latter scenario is supported by several lines of evidence, including deep long-period earthquakes (−28 to −32 km) prior to and during the eruption, and far-field deformation following the onset of eruptive activity.

Alaska↗

USGS2012

Generation and evolution of hydrothermal fluids at Yellowstone: Insights from the Heart Lake Geyser Basin

We sampled fumaroles and hot springs from the Heart Lake Geyser Basin (HLGB), measured water and gas discharge, and estimated heat and mass flux from this geothermal area in 2009. The combined data set reveals that diverse fluids share an origin by mixing of deep solute-rich parent water with dilute heated meteoric water, accompanied by subsequent boiling. A variety of chemical and isotopic geothermometers are consistent with a parent water that equilibrates with rocks at 205°C ± 10°C and then undergoes 21% ± 2% adiabatic boiling. Measured diffuse CO 2 flux and fumarole compositions are consistent with an initial dissolved CO 2 concentration of 21 ± 7 mmol upon arrival at the caldera boundary and prior to southeast flow, boiling, and discharge along the Witch Creek drainage. The calculated advective flow from the basin is 78 ± 16 L s −1 of parent thermal water, corresponding to 68 ± 14 MW, or –1% of the estimated thermal flux from Yellowstone. Helium and carbon isotopes reveal minor addition of locally derived crustal, biogenic, and meteoric gases as this fluid boils and degasses, reducing the He isotope ratio (Rc/Ra) from 2.91 to 1.09. The HLGB is one of the few thermal areas at Yellowstone that approaches a closed system, where a series of progressively boiled waters can be sampled along with related steam and noncondensable gas. At other Yellowstone locations, steam and gas are found without associated neutral Cl waters (e.g., Hot Spring Basin) or Cl-rich waters emerge without significant associated steam and gas (Upper Geyser Basin).

Wyoming↗

USGS2012

Cenozoic tectono-thermal history of the Tordrillo Mountains, Alaska: Paleocene-Eocene ridge subduction, decreasing relief, and late Neogene faulting

Topographic development inboard of the continental margin is a predicted response to ridge subduction. New thermochronology results from the western Alaska Range document ridge subduction related orogenesis. K-feldspar thermochronology (KFAT) of bedrock samples from the Tordrillo Mountains in the western Alaska Range complement existing U-Pb, 40 Ar/ 39 Ar and AFT (apatite fission track) data to provide constraints on Paleocene pluton emplacement, and cooling as well as Late Eocene to Miocene vertical movements and exhumation along fault-bounded blocks. Based on the KFAT analysis we infer rapid exhumation-related cooling during the Eocene in the Tordrillo Mountains. Our KFAT cooling ages are coeval with deposition of clastic sediments in the Cook Inlet, Matanuska Valley and Tanana basins, which reflect high-energy depositional environments. The Tordrillo Mountains KFAT cooling ages are also the same as cooling ages in the Iliamna Lake region, the Kichatna Mountains of the western Alaska Range, and Mt. Logan in the Wrangell-St. Elias Mountains, thus rapid cooling at this time encompasses a broad region inboard of, and parallel to, the continental margin extending for several hundred kilometers. We infer these cooling events and deposition of clastic rocks are related to thermal effects that track the eastward passage of a slab window in Paleocene-Eocene time related to the subduction of the proposed Resurrection-Kula spreading ridge. In addition, we conclude that the reconstructed KFAT max negative age-elevation relationship is likely related to a long period of decreasing relief in the Tordrillo Mountains.

Alaska↗

USGS2012

Tracking lava flow emplacement on the east rift zone of Kilauea, Hawai’i with synthetic aperture radar (SAR) coherence

Lava flow mapping is both an essential component of volcano monitoring and a valuable tool for investigating lava flow behavior. Although maps are traditionally created through field surveys, remote sensing allows an extraordinary view of active lava flows while avoiding the difficulties of mapping on location. Synthetic aperture radar (SAR) imagery, in particular, can detect changes in a flow field by comparing two images collected at different times with SAR coherence. New lava flows radically alter the scattering properties of the surface, making the radar signal decorrelated in SAR coherence images. We describe a new technique, SAR Coherence Mapping (SCM), to map lava flows automatically from coherence images independent of look angle or satellite path. We use this approach to map lava flow emplacement during the Pu‘u ‘Ō‘ō-Kupaianaha eruption at Kīlauea, Hawai‘i. The resulting flow maps correspond well with field mapping and better resolve the internal structure of surface flows, as well as the locations of active flow paths. However, the SCM technique is only moderately successful at mapping flows that enter vegetation, which is also often decorrelated between successive SAR images. Along with measurements of planform morphology, we are able to show that the length of time a flow stays decorrelated after initial emplacement is linearly related to the flow thickness. Finally, we use interferograms obtained after flow surfaces become correlated to show that persistent decorrelation is caused by post-emplacement flow subsidence.

Hawai'i↗

USGS2012

Integrated geophysical and hydrothermal models of flank degassing and fluid flow at Masaya Volcano, Nicaragua

We investigate geologic controls on circulation in the shallow hydrothermal system of Masaya volcano, Nicaragua, and their relationship to surface diffuse degassing. On a local scale (~250 m), relatively impermeable normal faults dipping at ~60° control the flowpath of water vapor and other gases in the vadose zone. These shallow normal faults are identified by modeling of a NE-SW trending magnetic anomaly of up to 2300 nT that corresponds to a topographic offset. Elevated SP and CO2 to the NW of the faults and an absence of CO2 to the SE suggest that these faults are barriers to flow. TOUGH2 numerical models of fluid circulation show enhanced flow through the footwalls of the faults, and corresponding increased mass flow and temperature at the surface (diffuse degassing zones). On a larger scale, TOUGH2 modeling suggests that groundwater convection may be occurring in a 3-4 km radial fracture zone transecting the entire flank of the volcano. Hot water rising uniformly into the base of the model at 1 x 10-5 kg/m2s results in convection that focuses heat and fluid and can explain the three distinct diffuse degassing zones distributed along the fracture. Our data and models suggest that the unusually active surface degassing zones at Masaya volcano can result purely from uniform heat and fluid flux at depth that is complicated by groundwater convection and permeability variations in the upper few km. Therefore isolating the effects of subsurface geology is vital when trying to interpret diffuse degassing in light of volcanic activity.

Masaya Volcano↗

USGS2012

An apparent "vital effect" of calcification rate on the Sr/Ca temperature proxy in the reef coral Montipora capitata

Measuring the strontium to calcium ratio in coral skeletons reveals information on seawater temperatures during skeletal deposition, but studies have shown additional variables may affect the ratio. Here we measured Sr/Ca in the reef coral, Montipora capitata, grown in six mesocosms continuously supplied with seawater from the adjacent reef flat. Three mesocosms were ambient controls, and three had seawater chemistry simulating "ocean acidification" (OA). We found that Sr/Ca was not affected by the OA treatment, and neither was coral calcification for these small colonies (larger colonies did show an OA effect). The lack of OA effects allowed us to test the hypothesis that coral growth rate can affect Sr/Ca using the natural range in calcification rates of the corals grown at the same temperature. We found that Sr/Ca was inversely related to calcification rate (Sr/Ca = 9.39 - 0.00404 mmol/mol * mg day-1 cm-2, R2 = 0.32). Using a previously published calibration curve for this species, a 22 mg day-1 colony-1 increase in calcification rate introduced a 1°C warmer temperature estimate, with the 27 corals reporting "temperatures" ranging from 24.9 to 28.9, with mean 26.6 ± 0.9°C SD. Our results lend support to hypotheses invoking kinetic processes and growth rate to explain vital effects on Sr/Ca. However, uncertainty in the slope of the regression of Sr/Ca on calcification and a low R-squared value lead us to conclude that Sr/Ca could still be a useful proxy in this species given sufficient replication or by including growth rate in the calibration.

Geochemistry, Geophysics, Geosystems↗

USGS2012

Illumination of rheological mantle heterogeneity by the M7.2 2010 El Mayor-Cucapah earthquake

Major intracontinental strike-slip faults tend to mark boundaries between lithospheric blocks of contrasting mechanical properties along much of their length. Both crustal and mantle heterogeneities can form such boundaries, but the role of crustal versus mantle strength contrasts for localizing strain sufficiently to generate major faults remains unclear. Using the crustal velocity field observed through the Global Positioning System (GPS) in the epicentral area of the M7.2 2010 El Mayor-Cucapah earthquake, Baja California, we find that transient deformation observed after the event is anomalously small in areas of relatively high seismic velocity in the shallow upper mantle (∼50 km depth). This pattern is best explained with a laterally heterogeneous viscoelastic structure that mimics the seismic structure. The mantle of the Southern Colorado River Desert (SCRD) and Peninsular Ranges (PR), which bound the fault system to its east and west, respectively, have anomalously high viscosity and seismic velocity. We hypothesize that compared with the rest of the San Andreas fault (SAF) system to its north, the strike-slip fault system in northern Baja California is narrow because of the presence of the PR and SCRD high-viscosity regions which bound it.

Arizona, Baja California, California, Sonora↗