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At least 91 records · Page 5Linked to original sources

Nitrate reduction in sediments of lowland tropical streams draining swamp forest in Costa Rica: An ecosystem perspective

Nitrate reduction and denitrification were measured in swamp forest streams draining lowland rain forest on Costa Rica's Atlantic slope foothills using the C2H2-block assay and sediment-water nutrient fluxes. Denitrification assays using the C2H2-block technique indicated that the full suite of denitrifying enzymes were present in the sediment but that only a small fraction of the functional activity could be expressed without adding NO3/-. Under optimal conditions, denitrification enzyme activity averaged 15 nmoles cm-3 sediment h-1. Areal NO3/- reduction rates measured from NO3/- loss in the overlying water of sediment- water flux chambers ranged from 65 to 470 umoles m-2 h-1. Oxygen loss rates accompanying NO3/-depletion averaged 750 umoles m-2 h-1. Corrected for denitrification of NO3/- oxidized from NH4/+ in the sediment, gross NO3/- reduction rates increase by 130 umoles m-2 h-1, indicating nitrification may be the predominant source of NO3/- for NO3/- reduction in swamp forest stream sediments. Under field conditions approximately 80% of the increase in inorganic N mass along a 1250-m reach of the Salto River was in the form of NO3/- with the balance NH4/+. Scrutiny of potential inorganic N sources suggested that mineralized N released from the streambed was a major source of the inorganic N increase. Despite significant NO3/- reduction potential, swamp forest stream sediments appear to be a source of inorganic N to downstream communities.

Biogeochemistry↗

Experimental studies in stream-aquifer interaction along the Arkansas River in Central Kansas - Field testing and analysis

During the last several years, streamflows of a number of Kansas streams have been reduced as a result of groundwater declines. In order to better understand and quantify stream-aquifer interrelationships, an eight-day comprehensive stream-aquifer pumping test, followed by recovery monitoring, was conducted along the Arkansas River near Great Bend, Kansas. In addition to water level monitoring in numerous observation wells, streamflow data, streambed hydraulic gradients, neutron probe-based water content of dewatered sediments, water chemistry and other data were collected. The alluvial aquifer is shown to be highly transmissive ( T = 1803 m 2 d −1 ) with the pumping stress (9538 m 3 d −1 ) having a radius of influence larger than 1.77 km, impacting both the aquifer levels and the streamflow in the nearby Arkansas River. Drawdown and recharge boundary effects were observed in all observation wells, including those on the opposite side of the river. The alluvial aquifer did not exhibit a water table behavior and responded as a leaky confined aquifer. A semiconfining clay layer less than 3 m thick and an additional recharge source from a nearby stream-alluvial system were the probable causes of the observed phenomena. Actual streamflow depletion is shown to be appreciably less than the computed depletion based on analytical solutions.

Kansas↗

PFAS exposure suppresses leaf litter decomposition in a stream ecosystem

Decomposition of organic matter is critical to the biogeochemical cycling of carbon and nutrients in all ecosystems. In streams, decomposition can be influenced by anthropogenic impacts, including contaminants. Per- and polyfluoroalkyl substances (PFAS) are resistant to degradation and widespread in freshwater ecosystems, yet little is known about their influence on organic matter processing in streams. We paired an observational field study of a PFAS-impacted stream via food processing wastewater with a 28-day laboratory experiment to investigate PFAS effects on leaf litter processing using multiple lines of evidence. Leaf litter decomposition rates and microbial respiration were significantly lower downstream of the PFAS point-source compared to the paired upstream site. We hypothesized that PFAS suppressed microbial activity thereby resulting in slower decomposition rates. To investigate further and better isolate PFAS, we dosed aquatic mesocosms containing leaf packs with differing concentrations of perfluorooctane sulfonate (PFOS). Over the 28-day incubation, decomposition rates did not differ, but we observed lower respiration rates on day 28 and higher dissolved organic carbon (DOC) in PFOS-dosed mesocosms, suggesting that PFAS may suppress microbial activity and inhibit carbon processing. These results underscore that concerns regarding PFAS contamination extend beyond organismal toxicity to ecosystem-level effects. Further research is needed to understand the scale, implications, and mechanisms responsible for these changes.

Upper Mississippi River Basin↗

Growth and secondary production of aquatic insects along a gradient of Zn contamination in Rocky Mountain streams

Secondary production estimates from several Rocky Mountain streams were used to test hypotheses about the effects of chronic metal contamination on insect populations and ecosystem processes. Quantitative samples of chemistry, habitat, and benthic insects were collected monthly during the ice-free period (May–November) from five 2 nd - to 3 rd -order streams that varied primarily in Zn contamination. Secondary production was estimated for the 19 dominant taxa using increment-summation, size-frequency, and P/B methods. Uncertainty was estimated by bootstrapping estimates of mean abundance, biomass, and cohort production intervals. Secondary production of metal-sensitive Heptageniidae ( Rhithrogena robusta , Cinygmula spp., and Epeorus longimanus ) was lower in lightly to moderately contaminated streams than in reference streams. Experiments were done to determine whether herbivore growth was influenced by food quality in contaminated streams. Growth estimates from field and microcosm experiments revealed that low mayfly production in contaminated streams was caused mostly by reduced population abundances. Production of predatory stoneflies was also lower in contaminated streams than reference streams. Estimates of the trophic basis of production revealed that, although the relative contribution to community production from various food sources was similar among streams, total production attributable to algae and animal prey declined in contaminated streams. Much of the reduction in herbivory in contaminated streams was the result of lower production of heptageniids, especially R. robusta . Assemblage and taxon-specific estimates of secondary production were sensitive to variation in metal contamination and indicated that relatively low metal concentrations may have ecosystem-wide consequences for energy flow.

Journal of the North American Benthological Societ↗

Time of travel of solutes in selected reaches of Ohio streams, 1973 and 1975

The basic field data for time-of-travel measurements on six streams in Ohio are presented. In general, additional data on stream cross sections, tributary inflows, and chemical analyses for mainstream and tributary flows are given. Insufficient data were obtained to establish time-distance or time-discharge relationships.

Ohio↗

FLOwPER user guide—For collection of FLOw PERmanence field observations

The accurate mapping of streams and their streamflow conditions in terms of presence or absence of surface water is important to both understanding physical, chemical, and biological processes in streams and to managing land, water, and ecological resources. This document describes a field form, FLOwPER (FLOw PERmanence), available within a mobile application (app), for standardized data collection of the presence or absence of surface flow in streams. The FLOwPER Database is a publicly available geodataset that can be used for research and management applications. This document provides instructions on how to (1) access and download the FLOwPER field form within the mobile app service, (2) use and complete a FLOwPER field form, and (3) view and download data from the FLOwPER Database.

Open-File Report↗

Identifying sources of aeolian mineral dust: Present and past

Aeolian mineral dust is an important component of the Earth’s environmental systems, playing roles in the planetary radiation balance, as a source of fertilizer for biota in both terrestrial and marine realms and as an archive for understanding atmospheric circulation and paleoclimate in the geologic past. Crucial to understanding all of these roles of dust is the identification of dust sources. Here we review the methods used to identify dust sources active at present and in the past. Contemporary dust sources, produced by both glaciogenic and non-glaciogenic processes, can be readily identified by the use of Earth-orbiting satellites. These data show that present dust sources are concentrated in a global dust belt that encompasses large topographic basins in low-latitude arid and semiarid regions. Geomorphic studies indicate that specific point sources for dust in this zone include dry or ephemeral lakes, intermittent stream courses, dune fields, and some bedrock surfaces. Back-trajectory analyses are also used to identify dust sources, through modeling of wind fields and the movement of air parcels over periods of several days. Identification of dust sources from the past requires novel approaches that are part of the geologic toolbox of provenance studies. Identification of most dust sources of the past requires the use of physical, mineralogical, geochemical, and isotopic analyses of dust deposits. Physical properties include systematic spatial changes in dust deposit thickness and particle size away from a source. Mineralogy and geochemistry can pinpoint dust sources by clay mineral ratios and Sc-Th-La abundances, respectively. The most commonly used isotopic methods utilize isotopes of Nd, Sr, and Pb and have been applied extensively in dust archives of deep-sea cores, ice cores, and loess. All these methods have shown that dust sources have changed over time, with far more abundant dust supplies existing during glacial periods. Greater dust supplies in glacial periods are likely due to greater production of glaciogenic dust particles from expanded ice sheets and mountain glaciers, but could also include dust inputs from exposed continental and insular shelves now submerged. Future dust sources are difficult to assess, but will likely differ from those of the present because of global warming. Global warming could bring about shifts in dust sources by changes in degree or type of vegetation cover, changes in wind strength, and increases or decreases in the size of water bodies. A major uncertainty in assessing dust sources of the future is related to changes inhuman land use, which could affect land surface cover, particularly due to increased agricultural endeavors and water usage.

Book chapter↗

Agricultural chemical concentrations and loads in rivers draining the Central Valley, California: Before, during, and after an extended drought

Drought or near drought conditions persisted in California from 2012 through 2016, followed by a high precipitation year in 2017. Long-term water quality monitoring of two key river stations, the Sacramento River at Freeport and the San Joaquin River near Vernalis, located within the largely agricultural Central Valley, allow for an examination of pesticide concentrations and mass loading. Daily models were constructed using an estimation procedure that links mean daily streamflow with pesticide concentration monitoring and time. There were 13 different pesticides and three degradation products modeled, including herbicides, fungicides, and insecticides. Not all pesticides were detected at each river site. There were eight pesticides modeled for the Sacramento River and fourteen for the San Joaquin River. Collectively, there were 16 models for these two sites that showed decreasing trends, 5 with increasing, and 1 with no trend. Mass loads of the modeled compounds increased in 2017 because of the high river discharge. Most pesticides had measured or modeled concentrations that were below acute and chronic toxicity benchmarks. One exception was the neonicotinoid insecticide imidacloprid, which had an increasing trend in concentration with levels that exceeded chronic toxicity thresholds for invertebrates, especially after 2015. The use of some pesticides decreased during this period of time which partly explains the decreasing concentration trends. However, some pesticides had increased useage but with decreasing river concentration. The preponderance of negative trends in concentration of most pesticides suggested that lack of rainfall during the drought resulted in less transport from treated fields to the streams.

California↗

Acoustic Doppler current profiler applications used in rivers and estuaries by the U.S. Geological Survey

The U.S. Geological Survey (USGS) has collected streamflow information for the Nation's streams since 1889. Streamflow information is used to predict floods, manage and allocate water resources, design engineering structures, compute water-quality loads, and operate water-control structures. The current (2007) size of the USGS streamgaging network is over 7,400 streamgages nationwide. The USGS has progressively improved the streamgaging program by incorporating new technologies and techniques that streamline data collection while increasing the quality of the streamflow data that are collected. The single greatest change in streamflow measurement technology during the last 100 years has been the development and application of high frequency acoustic instruments for measuring streamflow. One such instrument, the acoustic Doppler current profiler (ADCP), is rapidly replacing traditional mechanical current meters for streamflow measurement (Muste and others, 2007). For more information on how an ADCP works see Simpson (2001) or visit http://hydroacoustics.usgs.gov/. The USGS has used ADCPs attached to manned or tethered boats since the mid-1990s to measure streamflow in a wide variety of conditions (fig. 1). Recent analyses have shown that ADCP streamflow measurements can be made with similar or greater accuracy, efficiency, and resolution than measurements made using conventional current-meter methods (Oberg and Mueller, 2007). ADCPs also have the ability to measure streamflow in streams where traditional current-meter measurements previously were very difficult or costly to obtain, such as streams affected by backwater or tides. In addition to streamflow measurements, the USGS also uses ADCPs for other hydrologic measurements and applications, such as computing continuous records of streamflow for tidally or backwater affected streams, measuring velocity fields with high spatial and temporal resolution, and estimating suspended-sediment concentrations. An overview of these applications is provided in the fact sheet.

Fact Sheet↗

Design of a sediment-monitoring gaging network on ephemeral tributaries of the Colorado River in Glen, Marble, and Grand Canyons, Arizona

Management of sediment in rivers downstream from dams requires knowledge of both the sediment supply and downstream sediment transport. In some dam-regulated rivers, the amount of sediment supplied by easily measured major tributaries may overwhelm the amount of sediment supplied by the more difficult to measure lesser tributaries. In this first class of rivers, managers need only know the amount of sediment supplied by these major tributaries. However, in other regulated rivers, the cumulative amount of sediment supplied by the lesser tributaries may approach the total supplied by the major tributaries. The Colorado River downstream from Glen Canyon has been hypothesized to be one such river. If this is correct, then management of sediment in the Colorado River in the part of Glen Canyon National Recreation Area downstream from the dam and in Grand Canyon National Park may require knowledge of the sediment supply from all tributaries. Although two major tributaries, the Paria and Little Colorado Rivers, are well documented as the largest two suppliers of sediment to the Colorado River downstream from Glen Canyon Dam, the contributions of sediment supplied by the ephemeral lesser tributaries of the Colorado River in the lowermost Glen Canyon, and Marble and Grand Canyons are much less constrained. Previous studies have estimated amounts of sediment supplied by these tributaries ranging from very little to almost as much as the amount supplied by the Paria River. Because none of these previous studies relied on direct measurement of sediment transport in any of the ephemeral tributaries in Glen, Marble, or Grand Canyons, there may be significant errors in the magnitudes of sediment supplies estimated during these studies. To reduce the uncertainty in the sediment supply by better constraining the sediment yield of the ephemeral lesser tributaries, the U.S. Geological Survey Grand Canyon Monitoring and Research Center established eight sediment-monitoring gaging stations beginning in 2000 on the larger of the previously ungaged tributaries of the Colorado River downstream from Glen Canyon Dam. The sediment-monitoring gaging stations consist of a downward-looking stage sensor and passive suspended-sediment samplers. Two stations are equipped with automatic pump samplers to collect suspended-sediment samples during flood events. Directly measuring discharge and collecting suspended-sediment samples in these remote ephemeral streams during significant sediment-transporting events is nearly impossible; most significant run-off events are short-duration events (lasting minutes to hours) associated with summer thunderstorms. As the remote locations and short duration of these floods make it prohibitively expensive, if not impossible, to directly measure the discharge of water or collect traditional depth-integrated suspended-sediment samples, a method of calculating sediment loads was developed that includes documentation of stream stages by field instrumentation, modeling of discharges associated with these stages, and automatic suspended-sediment measurements. The approach developed is as follows (1) survey and model flood high-water marks using a two-dimensional hydrodynamic model, (2) create a stage-discharge relation for each site by combining the modeled flood flows with the measured stage record, (3) calculate the discharge record for each site using the stage-discharge relation and the measured stage record, and (4) calculate the instantaneous and cumulative sediment loads using the discharge record and suspended-sediment concentrations measured from samples collected with passive US U-59 samplers and ISCO TM pump samplers. This paper presents the design of the gaging network and briefly describes the methods used to calculate discharge and sediment loads. The design and methods herein can easily be used at other remote locations where discharge and sediment loads are required.

Arizona↗

Solute transport and modeling of water quality in a small stream

An injection of chloride, sodium, and stable strontium was made at a constant rate for 3 hours into Uvas Creek, Santa Clara County, Calif., to determine the mass transport processes in a small stream. Five observation points were selected within a 610-metre reach of the stream below the injection site. Water samples were collected at the observation points during and immediately after the injection. A mathematical model of the stream was obtained by solving analytically and optimally the one-dimensional mass transport equation of the solutes in the stream. Comparison of field results with a simplified mathematical model indicates the dominance of convection in the behavior of sodium and chloride. The concentration of chloride and sodium can be closely simulated by the model. However, strontium cannot be well represented by the simplified model, which contains a first-order decay-type sink.

California↗

Peak flow regression equations For small, ungaged streams in Maine: Comparing map-based to field-based variables

Regression equations to estimate peak streamflows with 1- to 500-year recurrence intervals (annual exceedance probabilities from 99 to 0.2 percent, respectively) were developed for small, ungaged streams in Maine. Equations presented here are the best available equations for estimating peak flows at ungaged basins in Maine with drainage areas from 0.3 to 12 square miles (mi 2 ). Previously developed equations continue to be the best available equations for estimating peak flows for basin areas greater than 12 mi 2 . New equations presented here are based on streamflow records at 40 U.S. Geological Survey streamgages with a minimum of 10 years of recorded peak flows between 1963 and 2012. Ordinary least-squares regression techniques were used to determine the best explanatory variables for the regression equations. Traditional map-based explanatory variables were compared to variables requiring field measurements. Two field-based variables—culvert rust lines and bankfull channel widths—either were not commonly found or did not explain enough of the variability in the peak flows to warrant inclusion in the equations. The best explanatory variables were drainage area and percent basin wetlands; values for these variables were determined with a geographic information system. Generalized least-squares regression was used with these two variables to determine the equation coefficients and estimates of accuracy for the final equations.

Maine↗

Water quality of groundwater and stream base flow in the Marcellus Shale Gas Field of the Monongahela River Basin, West Virginia, 2011-12

The Marcellus Shale gas field underlies portions of New York, Pennsylvania, Ohio, Virginia, Maryland, Tennessee, and West Virginia. Development of hydraulic fracturing and horizontal drilling technology led to extensive development of gas from the Marcellus Shale beginning about 2007. The need to identify and monitor changes in water-quality conditions related to development of the Marcellus Shale gas field prompted the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection, Division of Water and Waste Management, to document water quality for comparison with water quality in samples collected at a future date. The identification of change in water-quality conditions over time is more difficult if baseline water-quality conditions have not been documented. U.S. Geological Survey personnel sampled groundwater and surface water in West Virginia’s Monongahela River Basin during 2011–12. A groundwater survey, in which 39 wells and 2 springs were sampled, was conducted during June through September 2011. A base-flow survey was conducted during July through October 2012; 50 stream sites were sampled under base-flow conditions in this survey. Because additives to hydraulic fracturing fluids are variable and decrease in flowback water over a relatively short time, water-quality analyses for this study focused on documenting the water-quality characteristics typical of water from shallow aquifers; water derived from contact with the Marcellus Shale (flowback from hydraulic fracturing or formation water); and water with constituents from conventional oil and gas development, sewage effluent, and coal-mine drainage. All samples were analyzed for field properties (water temperature, pH, specific conductance, dissolved oxygen, and turbidity), major ions, trace elements, naturally occurring radioactive materials, and stable isotopes. In addition to documenting baseline water-quality conditions for an area of shale-gas development, these data were examined for patterns in water quality. Groundwater and base-flow survey data were compared to historical data from the Monongahela River Basin in West Virginia. Additionally, groundwater- and base-flow survey samples were grouped by Marcellus Shale gas production in the subbasin in which that sampling site was located. The comparisons of data collected as part of this study with historical data identified few differences. No significant difference was found in a comparison of groundwater survey data and historical data. Base-flow survey samples differed significantly from historical data for pH, chloride, and strontium, all of which had higher concentrations in the base-flow survey samples. Differences in pH are likely related to changes in mining regulation beginning in 1977. Concentrations of chloride and strontium elevated above background concentrations may be related to saline groundwater; saline water is within 300 feet of the land surface in parts of the study area. In the comparison of base-flow survey samples grouped by shale-gas-production setting, significant differences were found for fluoride and barium. Concentrations of fluoride and barium were higher in stream subbasins with active Marcellus Shale production than in subbasins not near active Marcellus Shale production. Elevated fluoride and barium are associated with deep brines. Generally, naturally occurring radioactive materials were not found in elevated concentrations in either groundwater or base-flow samples. Only 3 samples, 2 from the groundwater survey and one from the base-flow survey, exceeded the U.S. Environmental Protection Agency maximum contaminant level for radium isotopes of 5.0 picocurie per liter for either a single isotope or a combined value of radium-226 and radium-228. Stable isotope composition indicates broad similarity among surface water, shallow groundwater, and precipitation in the region. Neither shallow groundwater nor surface water showed a marked similarity with the deep brines associated with shale gas. In most of the groundwater survey samples, 38 of 41 samples, dissolved gas profiles were similar to those previously found in samples from shallow, domestic wells in the region. This study provides a baseline of water-quality conditions in the Monongahela River Basin in West Virginia during the early phases of development of the Marcellus Shale gas field. Although not all inclusive, the results of this study provide a set of reliable water-quality data against which future data sets can be compared and the effects of shale-gas development may be determined.

West Virginia↗

Field study and simulation of diurnal temperature effects on infiltration and variably saturated flow beneath an ephemeral stream

Two experiments were performed to investigate flow beneath an ephemeral stream and to estimate streambed infiltration rates. Discharge and stream-area measurements were used to determine infiltration rates. Stream and subsurface temperatures were used to interpret subsurface flow through variably saturated sediments beneath the stream. Spatial variations in subsurface temperatures suggest that flow beneath the streambed is dependent on the orientation of the stream in the canyon and the layering of the sediments. Streamflow and infiltration rates vary diurnally: Streamflow is lowest in late afternoon when stream temperature is greatest and highest in early morning when stream temperature is least. The lower afternoon Streamflow is attributed to increased infiltration rates; evapotranspiration is insufficient to account for the decreased Streamflow. The increased infiltration rates are attributed to viscosity effects on hydraulic conductivity from increased stream temperatures. The first set of field data was used to calibrate a two-dimensional variably saturated flow model that includes heat transport. The model was calibrated to (1) temperature fluctuations in the subsurface and (2) infiltration rates determined from measured Streamflow losses. The second set of field data was to evaluate the ability to predict infiltration rates on the basis of temperature measurements alone. Results indicate that the variably saturated subsurface flow depends on downcanyon layering of the sediments. They also support the field observations in indicating that diurnal changes in infiltration can be explained by temperature dependence of hydraulic conductivity. Over the range of temperatures and flows monitored, diurnal stream temperature changes can be used to estimate streambed infiltration rates. It is often impractical to maintain equipment for determining infiltration rates by traditional means; however, once a model is calibrated using both infiltration and temperature data, only relatively inexpensive temperature monitoring can later yield infiltration rates that are within the correct order of magnitude.

Water Resources Research↗

Environmental contamination in the oil fields of western Pennsylvania

The effects on freshwater wildlife of chronic exposure to oil field discharges are not well known. Collections of wastewater, aquatic invertebrates, fish, salamanders, and small mammals were made in several streams in the oil fields of western Pennsylvania during 1980-81. Estimates of the petroleum content of two wastewater discharges were high (21.9 and 8.4 ppm) and one was low (0.3 ppm). Water conductivity was inversely related to aquatic invertebrate biomass. Hydrocarbons accumulated in significantly greater amounts in crayfish, fish, and small mammals from collection sites with oil extraction activity than from sites without oil extraction activity. Estimates of total petroleum in invertebrates, trout, and suckers averaged between 200 and 280 ppm for oil extraction sites and between 8 and 80 ppm for sites without oil extraction activity: Oil extraction activity did not affect metal accumulation by fish. Oil and wastewater discharges in oil fields disrupt community composition and can cause an overall reduction in stream productivity.

Oil and Petrochemical Pollution↗

Sonic depth sounder for laboratory and field use

The laboratory investigation of roughness in alluvial channels has led to the development of a special electronic device capable of mapping the streambed configuration under dynamic conditions. This electronic device employs an ultrasonic pulse-echo principle, similar to that of a fathometer, that utilizes microsecond techniques to give high accuracy in shallow depths. This instrument is known as the sonic depth sounder and was designed to cover a depth range of 0 to 4 feet with an accuracy of ? 0.5 percent. The sonic depth sounder is capable of operation at frequencies of 500, 1,000 and 2,000 kilocycles. The ultrasonic beam generated at the transducer is designed to give a minimum-diameter interrogating signal over the extended depth range. The information obtained from a sonic depth sounder is recorded on a strip-chart recorder. This permanent record allows an analysis to be made of the streambed configuration under different dynamic conditions. The model 1024 sonic depth sounder was designed principally as a research instrument to meet laboratory needs. As such, it is somewhat limited in its application as a field instrument on large streams and rivers. The principles employed in this instrument, however, have many potentials for field applications such as the indirect measurement of bed load when the bed roughness is ripples and (or) dunes, depth measurement, determination of bed configuration, and determination of depth of scour around bridge piers and abutments. For field application a modification of the present system into a battery-operated lightweight instrument designed to operate at a depth range of 0 to 30 feet is possible and desirable.

Circular↗

Changes in dissolved organic material determine exposure of stream benthic communities to UV-B radiation and heavy metals: Implications for climate change

Changes in regional climate in the Rocky Mountains over the next 100 years are expected to have significant effects on biogeochemical cycles and hydrological processes. In particular, decreased discharge and lower stream depth during summer when ultraviolet radiation (UVR) is the highest combined with greater photo-oxidation of dissolved organic materials (DOM) will significantly increase exposure of benthic communities to UVR. Communities in many Rocky Mountain streams are simultaneously exposed to elevated metals from abandoned mines, the toxicity and bioavailability of which are also determined by DOM. We integrated field surveys of 19 streams (21 sites) along a gradient of metal contamination with microcosm and field experiments conducted in Colorado, USA, and New Zealand to investigate the influence of DOM on bioavailability of heavy metals and exposure of benthic communities to UVR. Spatial and seasonal variation in DOM were closely related to stream discharge and significantly influenced heavy metal uptake in benthic organisms. Qualitative and quantitative changes in DOM resulting from exposure to sunlight increased UV-B (290-320nm) penetration and toxicity of heavy metals. Results of microcosm experiments showed that benthic communities from a metal-polluted stream were tolerant of metals, but were more sensitive to UV-B than communities from a reference stream. We speculate that the greater sensitivity of these communities to UV-B resulted from costs associated with metal tolerance. Exclusion of UVR from 12 separate Colorado streams and from outdoor stream microcosms in New Zealand increased the abundance of benthic organisms (mayflies, stoneflies, and caddisflies) by 18% and 54%, respectively. Our findings demonstrate the importance of considering changes in regional climate and UV-B exposure when assessing the effects of local anthropogenic stressors. ?? Journal compilation ?? 2008 Blackwell Publishing.

Global Change Biology↗

Ground-water flow directions and estimation of aquifer hydraulic properties in the lower Great Miami River Buried Valley aquifer system, Hamilton Area, Ohio

The Great Miami River Buried Valley Aquifer System is one of the most productive sources of potable water in the Midwest, yielding as much as 3,000 gallons per minute to wells. Many water-supply wells tapping this aquifer system are purposely placed near rivers to take advantage of induced infiltration from the rivers. The City of Hamilton's North Well Field consists of 10 wells near the Great Miami River, all completed in the lower Great Miami River Buried Valley Aquifer System. A well-drilling program and a multiple-well aquifer test were done to investigate ground-water flow directions and to estimate aquifer hydraulic properties in the lower part of the Great Miami River Buried Valley Aquifer System. Descriptions of lithology from 10 well borings indicate varying amounts and thickness of clay or till, and therefore, varying levels of potential aquifer confinement. Borings also indicate that the aquifer properties can change dramatically over relatively short distances. Grain-size analyses indicate an average bulk hydraulic conductivity value of aquifer materials of 240 feet per day; the geometric mean of hydraulic conductivity values of aquifer material was 89 feet per day. Median grain sizes of aquifer material and clay units were 1.3 millimeters and 0.1 millimeters, respectively. Water levels in the Hamilton North Well Field are affected by stream stage in the Great Miami River and barometric pressure. Bank storage in response to stream stage is evident. Results from a multiple-well aquifer test at the well field indicate, as do the lithologic descriptions, that the aquifer is semiconfined in some areas and unconfined in others. Transmissivity and storage coefficient of the semiconfined part of the aquifer were 50,000 feet squared per day and 5x10-4, respectively. The average hydraulic conductivity (450 feet per day) based on the aquifer test is reasonable for glacial outwash but is higher than calculated from grain-size analyses, implying a scale effect. Although the part of the lower Great Miami River Buried Valley Aquifer System where the Hamilton North Well Field is located is semiconfined, unconfined, or locally confined and not directly connected to the Great Miami River, the discontinuity of the clay/till layers beneath the river indicates that other, deeper parts of the aquifer system may be directly connected to the Great Miami River.

Scientific Investigations Report↗