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Preliminary geologic map of the Cook Inlet region, Alaska-Including parts of the Talkeetna, Talkeetna Mountains, Tyonek, Anchorage, Lake Clark, Kenai, Seward, Iliamna, Seldovia, Mount Katmai, and Afognak 1:250,000-scale quadrangles

The growth in the use of Geographic Information Systems (GIS) has highlighted the need for digital geologic maps that have been attributed with information about age and lithology. Such maps can be conveniently used to generate derivative maps for manifold special purposes such as mineral-resource assessment, metallogenic studies, tectonic studies, and environmental research. This report is part of a series of integrated geologic map databases that cover the entire United States. Three national-scale geologic maps that portray most or all of the United States already exist; for the conterminous U.S., King and Beikman (1974a,b) compiled a map at a scale of 1:2,500,000, Beikman (1980) compiled a map for Alaska at 1:2,500,000 scale, and for the entire U.S., Reed and others (2005a,b) compiled a map at a scale of 1:5,000,000. A digital version of the King and Beikman map was published by Schruben and others (1994). Reed and Bush (2004) produced a digital version of the Reed and others (2005a) map for the conterminous U.S. The present series of maps is intended to provide the next step in increased detail. State geologic maps that range in scale from 1:100,000 to 1:1,000,000 are available for most of the country, and digital versions of these state maps are the basis of this product. The digital geologic maps presented here are in a standardized format as ARC/INFO export files and as ArcView shape files. The files named __geol contain geologic polygons and line (contact) attributes; files named __fold contain fold axes; files named __lin contain lineaments; and files named __dike contain dikes as lines. Data tables that relate the map units to detailed lithologic and age information accompany these GIS files. The map is delivered as a set 1:250,000-scale quadrangle files. To the best of our ability, these quadrangle files are edge-matched with respect to geology. When the maps are merged, the combined attribute tables can be used directly with the merged maps to make derivative maps.

Alaska

Acute and chronic sensitivity of white sturgeon ( Acipenser transmontanus ) and rainbow trout ( Oncorhynchus mykiss ) to cadmium, copper, lead, or zinc in laboratory water-only exposures

White sturgeon (Acipenser transmontanus) are experiencing poor recruitment in the trans boundary reach of the upper Columbia River in eastern Washington State. Limited toxicity data indicated that early life stages of white sturgeon are sensitive to metals. In acute 4-day (d) exposures with larval white sturgeon, previous studies have reported that the 4-day median lethal concentrations (LC50) based on biotic ligand model (BLM) normalization for copper were below the U.S. Environmental Protection Agency national recommended acute water-quality criterion. In previously published chronic 66-d exposures starting with newly fertilized eggs of white sturgeon, 20-percent lethal effect concentrations (LC20s) for copper, cadmium, or zinc generally were within a factor of two of the chronic values of the most sensitive fish species in the databases of the U.S. Environmental Protection Agency water-quality criteria (WQC) for the three metals. However, there were some uncertainties in the chronic exposures previously performed with white sturgeon, including (1) low control survival (37 percent), (2) more control fish tested in each replicate compared to other treatments, (3) limited replication of treatments (n=2), (4) lack of reported growth data (such as dry weight), and (5) wide dilution factors for exposure concentrations (6- to 8-fold dilutions). The U.S. Environmental Protection Agency concluded that additional studies are needed to generate more toxicity data to better define lethal and sublethal toxicity thresholds for metals for white sturgeon. The objective of the study was to further evaluate the acute and chronic toxicity of cadmium, copper, lead, or zinc to early life stages of white sturgeon in water-only exposures. Toxicity tests also were performed with commonly tested rainbow trout (Oncorhynchus mykiss) under similar test conditions to determine the relative sensitivity between white sturgeon and rainbow trout to these metals. Toxicity data generated from this study were used to evaluate the sensitivity of early life stages of white sturgeon and rainbow trout relative to data published for other test organisms. Toxicity data generated from this study also were used to evaluate the level of protection of U.S. Environmental Protection Agency WQC or Washington State water-quality standards (WQS) for copper, zinc, cadmium, or lead to white sturgeon inhabiting the upper Columbia River. Chapter A of this report summarizes the results of acute toxicity tests performed for 4 d with white sturgeon and rainbow trout exposed to copper, cadmium, or zinc. Chapter B of this report summarizes the results of chronic toxicity tests performed for as many as 53 days with white sturgeon or rainbow trout exposed to copper, cadmium, zinc, or lead. Appendixes to the report are available at http://pubs.usgs.gov/sir/2013/5204 . Supporting documentation for chapter A toxicity testing is provided in appendix 1. Supporting documentation for chapter B toxicity testing is provided in Appendix 2. Supporting documentation on analysis of water chemistry for chapter A and chapter B is provided in appendix 3 and 4. The rationale for applying corrections to measured copper and zinc values in water samples from some of the toxicity tests performed in chapter A is provided in appendix 5. A summary of dissolved organic carbon measurement variability and implications for biotic ligand model normalization for toxicity data summarized in chapter A and chapter B are provided in appendix 6. An evaluation of an interlaboratory comparison of analyses for dissolved organic carbon in water from the U.S. Geological Survey Columbia Environmental Research Center and University of Saskatchewan is provided in appendix 7. Finally, appendix 8 provides a summary of retesting of white sturgeon in 2012 to determine if improved survival of sturgeon would affect copper effect concentrations in 24-d copper exposures started with newly hatched larvae, and to evaluate the effect of light intensity or temperature on the response of newly hatched larvae during a 25-d study.

Scientific Investigations Report

Storage capacity of the Fena Valley Reservoir, Guam, Mariana Islands, 2014

The Fena Valley Reservoir is in southern Guam and is the primary source of water for the U.S. Naval Base Guam and nearby village residents. Since the construction of the Fena Dam in 1951, sediment has accumulated in the reservoir and reduced its storage capacity. The reservoir was surveyed previously in 1973, 1979, and 1990 to estimate the loss in storage capacity. To determine the current storage capacity, the U.S. Geological Survey, in cooperation with the U.S. Department of Defense Strategic Environmental Research and Development Program, surveyed the bathymetry of the reservoir in February 2014. The bathymetric survey was accomplished by making depth soundings using a boat-mounted, acoustic Doppler current profiler. Location during bathymetric data collection was determined using a single-base Global Navigation Satellite System-Real Time Kinematic survey. Vertical profiles of conductivity, temperature, and depth were collected periodically. The conductivity, temperature, and depth profiles were used to spatially and temporally adjust the sound-speed calculations used to determine depth from the soundings. Approximately 108 kilometers of transects with a total of about 380,000 depth soundings were surveyed. In addition, approximately 2,100 topographic survey points in shallow, wadable areas near the Imong River Delta were defined by using a Global Navigation Satellite System receiver attached to a fixed-length survey rod. Depth soundings and topographic survey points were compiled and interpolated to generate a digital-elevation model of the reservoir. Data extracted from the digital-elevation model were then tabulated to determine total reservoir capacity and create reservoir stage–surface area and stage–storage capacity tables. Analyses of the bathymetric data indicate that the reservoir currently has 6,915 acre-feet of storage capacity. The engineering drawings of record show that the total reservoir capacity in 1951 was estimated to be 8,365 acre-feet. Thus, between 1951 and 2014, the total storage capacity decreased by 1,450 acre-feet (a loss of 17 percent of the original total storage capacity). The remaining live-storage capacity, or the volume of storage above the lowest-level reservoir outlet elevation, was calculated to be 5,511 acre-feet in 2014, indicating a decrease of 372 acre-feet (or 6 percent) of the original 5,883 acre-feet of live-storage capacity. The remaining dead-storage capacity, or volume of storage below the lowest-level outlet, was 1,404 acre-feet in 2014, indicating a decrease of 1,078 acre-feet (or 43 percent) of the original 2,482 acre-feet of dead-storage capacity.

Scientific Investigations Report

Fena Valley Reservoir watershed and water-balance model updates and expansion of watershed modeling to southern Guam

In 2014, the U.S. Geological Survey, in cooperation with the U.S. Department of Defense’s Strategic Environmental Research and Development Program, initiated a project to evaluate the potential impacts of projected climate-change on Department of Defense installations that rely on Guam’s water resources. A major task of that project was to develop a watershed model of southern Guam and a water-balance model for the Fena Valley Reservoir. The southern Guam watershed model provides a physically based tool to estimate surface-water availability in southern Guam. The U.S. Geological Survey’s Precipitation Runoff Modeling System, PRMS-IV, was used to construct the watershed model. The PRMS-IV code simulates different parts of the hydrologic cycle based on a set of user-defined modules. The southern Guam watershed model was constructed by updating a watershed model for the Fena Valley watersheds, and expanding the modeled area to include all of southern Guam. The Fena Valley watershed model was combined with a previously developed, but recently updated and recalibrated Fena Valley Reservoir water-balance model. Two important surface-water resources for the U.S. Navy and the citizens of Guam were modeled in this study; the extended model now includes the Ugum River watershed and improves upon the previous model of the Fena Valley watersheds. Surface water from the Ugum River watershed is diverted and treated for drinking water, and the Fena Valley watersheds feed the largest surface-water reservoir on Guam. The southern Guam watershed model performed “very good,” according to the criteria of Moriasi and others (2007), in the Ugum River watershed above Talofofo Falls with monthly Nash-Sutcliffe efficiency statistic values of 0.97 for the calibration period and 0.93 for the verification period (a value of 1.0 represents perfect model fit). In the Fena Valley watershed, monthly simulated streamflow volumes from the watershed model compared reasonably well with the measured values for the gaging stations on the Almagosa, Maulap, and Imong Rivers—tributaries to the Fena Valley Reservoir—with Nash-Sutcliffe efficiency values of 0.87 or higher. The southern Guam watershed model simulated the total volume of the critical dry season (January to May) streamflow for the entire simulation period within –0.54 percent at the Almagosa River, within 6.39 percent at the Maulap River, and within 6.06 percent at the Imong River. The recalibrated water-balance model of the Fena Valley Reservoir generally simulated monthly reservoir storage volume with reasonable accuracy. For the calibration and verification periods, errors in end-of-month reservoir-storage volume ranged from 6.04 percent (284.6 acre-feet or 92.7 million gallons) to –5.70 percent (–240.8 acre-feet or –78.5 million gallons). Monthly simulation bias ranged from –0.48 percent for the calibration period to 0.87 percent for the verification period; relative error ranged from –0.60 to 0.88 percent for the calibration and verification periods, respectively. The small bias indicated that the model did not consistently overestimate or underestimate reservoir storage volume. In the entirety of southern Guam, the watershed model has a “satisfactory” to “very good” rating when simulating monthly mean streamflow for all but one of the gaged watersheds during the verification period. The southern Guam watershed model uses a more sophisticated climate-distribution scheme than the older model to make use of the sparse climate data, as well as includes updated land-cover parameters and the capability to simulate closed depression areas. The new Fena Valley Reservoir water-balance model is useful as an updated tool to forecast short-term changes in the surface-water resources of Guam. Furthermore, the now spatially complete southern Guam watershed model can be used to evaluate changes in streamflow and recharge owing to climate or land-cover changes. These are substantial improvements to the previous models of the Fena Valley watershed and Reservoir. Datasets associated with this report are available as a U.S. Geological Survey data release (Rosa and Hay, 2017; DOI:10.5066/F7HH6HV4).

Scientific Investigations Report

Hydrologic Resources of Guam

Introduction The U.S. Territory of Guam, which lies in the western Pacific Ocean near latitude 13?28'N and longitude 144?45'E, is the largest (211 mi2) and southernmost of the islands in the Mariana chain. Ground water supplies about 80 percent of the drinking water for the island's 150,000 residents and nearly one million visitors per year. In northern Guam, water is obtained from wells that tap the upper part of a fresh ground-water lens in an aquifer composed mainly of limestone. About 180 wells, nearly all in the north, withdraw about 35 Mgal/d of water with chloride concentrations ranging from 6 to 585 mg/L. In southern Guam, the main source of freshwater is from surface water that runs off the weathered volcanic rocks that are exposed over much of the area. About 9.9 Mgal/d of freshwater is obtained using surface reservoirs. The island's freshwater resources are adequate to meet current (2003) needs, but future demands will eventually be higher. To better understand the hydrology of the island, the U.S. Geological Survey (USGS) entered into a cooperative study with the Water and Environmental Research Institute of the Western Pacific (WERI) at the University of Guam. The objective of the study was to provide a better understanding of the water resources of the island through analysis of data collected by the USGS on Guam. This report provides a description of the general hydrologic principles of the island's ground-water systems, as well as of the rainfall and geology of Guam. Hydrologic data described in the report include water levels, chloride concentrations, and pumpage from ground-water wells and streamflow data from southern Guam.

Water-Resources Investigations Report

Reassessing particulate organic carbon dynamics in the highly disturbed San Francisco Bay Estuary

Environmental research has been shifting toward a new normal in which a primary focus is to capture change that may be accelerating. In this study, we collected particulate samples in the northern San Francisco Bay Estuary (SFBE) in the fall of 2011 through the spring of 2012 in order to assess vascular plant contributions across both time and space and to compare our findings with a similar set of samples from 1990 to 1992. Across the ∼20-year span, we detected (1) decreasing C:N a ratios (averages ± SD of 12.5 ± 2.5 vs. 8.8 ± 1.4, significant t -test with p < 0.0001); (2) distinct shifts in chlorophyll vs. salinity, with higher chlorophyll concentrations shifting toward freshwater; and (3) greater relative proportions of vascular plant carbon that also appears less degraded (as indicated by lignin measurements) shifting from freshwater toward higher salinities. Lignin compositional data (syringyl:vanillyl and cinnamyl:vanillyl) suggest that increased lignin content in the more saline samples could be derived from wetland materials, while a two-endmember mixing model indicates that a significant portion of the particulate organic carbon (POC) in the western sites (50–60% as an upper bound, 13–15% as a lower bound) could be wetland-derived. This has potential implications for the lower food web, given recent work that demonstrates selective feeding by copepods on wetland detrital material in the northern SFBE. The latter has ramifications for proposed wetland restoration within the SFBE and Sacramento River/San Joaquin River Delta system, namely, that restored wetlands could confer important benefits toward the food web. Equally important is to prioritize continued monitoring of particulate organic matter cycling in the SFBE system to make sure that changing conditions are accounted for in any management decision.

California

LANDSAT M. S. S. IMAGE MOSAIC OF TUNISIA.

The Landsat mosaic of Tunisia funded by USAID for the Remote Sensing Laboratory, Soils Division, Ministry of Agriculture, Tunisia, was completed by the USGS in September 1983. It is a mixed mosaic associating digital corrections and enhancements to manual mosaicking and corresponding to the Tunisian request for high resolution and the limited available funds. The scenes were processed by the Environmental Research Institute of Michigan, resampling the data geodesically corrected to fit the Universal Transverse Mercator projection using control points from topographic maps at 1:50,000 and 1:100,000 scales available in the U. S. The mosaicking was done in the Eastern Mapping Center under the supervision of the Graphic Arts System Section. The three black and white mosaics were made at the 1:1,000,000 scale and various products generated. They included color film positives at 1:2,000,000 and 1:4,000,000 scales reproducible in the Remote Sensing Laboratory in Tunis and corresponding color prints as well as tricolor prints at various scales from 1:500,000 to 1:2,000,000.

Conference Paper

Earthquake history of the United States

This publication is a history of the prominent earthquakes in the United States from historical times through 1970. It supersedes all previous editions with the same or similar titles (see page ii) and, in addition to updating earthquake listings through 1970, contains several additions and corrections to previous issues. It also brings together under a common cover earthquake data previously listed in two separate reports: Earthquake History of the United States, Part I, Stronger Earthquakes of the United States (Exclusive of California and Western Nevada) and Earthquake History of the United States, Part II, Stronger Earthquakes of California and Western Nevada . Another addition to this publication is the inclusion of a section describing earthquakes in the Puerto Rico region. For the purpose of listing and describing earthquakes, the United States has been divided into nine regions: (1) Northeastern Region, which includes New England and New York activity and observations of the principal earthquakes of eastern Canada; (2) Eastern Region, including the central Appalachian seismic region activity and the area near Charleston, S.C.; (3) Central Region, which consists of the area between the region just described and the Rocky Mountains; (4) Western Mountain Region, which includes all remaining states except those on the Pacific coast; (5) Washington and Oregon; (6) Alaska; (7) Hawaii; (8) Puerto Rico; and (9) California and Western Nevada. This arrangement has been made chiefly with reference to the natural seismic divisions. It also is a convenient arrangement because there are only three states where there is an important division of earthquake activity: In Tennessee, there are quite distinct areas at opposite ends of the state that fall into different regions. Only central and eastern Nevada are included in the Western Mountain Region, as the activity of the western part is closely associated with that of California. Some earthquake activity has occurred in the part of Texas located in the Western Mountain Region. The map facing page 1 shows locations of all earthquakes in the regions that follow. A small map showing the area covered by each region immediately precedes the résumé of each chapter (except for the Alaska, Puerto Rico, and Hawaii regions). The seismic risk map below was developed in January 1969 for the conterminous United States by Dr. S. T. Algermissen of NOAA's Environmental Research Laboratories. Subject to revision as continuing research warrants, it is an updated edition of a map divides the United States into four zones: Zone 0, areas with no reasonable expectancy of earthquake damage; Zone 1, expected minor damage; Zone 2, expected moderate damage; and Zone 3, major destructive earthquakes may occur.

Publication

Managing biological diversity

Biological diversity is the variety of life and accompanying ecological processes (Off. Technol. Assess. 1987, Wilcove and Samson 1987, Keystone 1991). Conservation of biological diversity is a major environmental issue (Wilson 1988, Counc. Environ. Quality 1991). The health and future of the earth's ecological systems (Lubchenco et al. 1991), global climate change (Botkin 1990), and an ever-increasing rate in loss of species, communities, and ecological systems (Myers 1990) are among issues drawing biological diversity to the mainstream of conservation worldwide (Int. Union Conserv. Nat. and Nat. Resour. [IUCN] et al. 1991). The legal mandate for conserving biological diversity is now in place (Carlson 1988, Doremus 1991). More than 19 federal laws govern the use of biological resources in the United States (Rein 1991). The proposed National Biological Diversity Conservation and Environmental Research Act (H.R. 585 and S.58) notes the need for a national biological diversity policy, would create a national center for biological diversity research, and recommends a federal interagency strategy for ecosystem conservation. There are, however, hard choices ahead for the conservation of biological diversity, and biologists are grappling with how to set priorities in research and management (Roberts 1988). We sense disillusion among field biologists and managers relative to how to operationally approach the seemingly overwhelming charge of conserving biological diversity. Biologists also need to respond to critics like Hunt (1991) who suggest a tree farm has more biological diversity than an equal area of old-growth forest. At present, science has played only a minor role in the conservation of biological diversity (Weston 1992) with no unified approach available to evaluate strategies and programs that address the quality and quantity of biological diversity (Murphy 1990, Erwin 1992). Although actions to conserve biological diversity need to be clearly defined by viewing issues across biological, spatial, and temporal scales (Knopf and Smith 1992), natural resource managers find much conflicting information in the literature on strategies and programs for the conservation of biological diversity (Ehrlich 1992). Moreover, recommendations provided in much of the published information available for planning or decisions not only can be debated but may prove counterproductive if implemented. Current operational efforts beg for clearer focus on fundamental concepts central to daily decisions that impact native biological diversity. Recognizing that many biologists would provide different council and at the risk of oversimplification, we offer the following 4 topical issues as fundamental guidance to wise conservation action. These recommendations are based on our collective experiences working within conservation agencies since our original, collaborative essay (Samson and Knopf 1982). They are offered as initial, rather than authoritative, steps to better align research and management decisions with what we perceive as the critical issues in conserving biological diversity at the landscape and ecosystem levels of resolution.

Wildlife Society Bulletin

The Global Land-Cover Characteristics Database: The users' perspective

A unique global land-cover characteristics database developed by the U.S. Geological Survey has been available to users since mid-1997. Access to the data is through the internet under the EROS (Earth Resources Observation Systems) Data Center's home page (http://edcwww.cr.usgs.gov/landdaac/glcc/glcc.html). Since the release of the database, the data have been incorporated into various environmental research and modeling applications, including mapping global biodiversity, mesoscale climate simulations, carbon cycle modeling, and estimating habitat destruction. Since the early stages of the project, user feedback has provided a means to understand data utility in applications, garner suggestions for data improvements, and gain insights into the technical challenges faced by users. Synthesis of user feedback provided a means to generate a user profile and derive a list of applications-critical criteria for land-cover data. User suggestions have lead to revisions in the database, including label changes, alternative classification schemes, and additional projections for the data.

Photogrammetric Engineering and Remote Sensing

Basic alumina flash chromatographic separation of bulk ortho-PCBs from on-ortho-PCBs, PBDEs, PCDFs, PCDDs, PCDTs, OCPs, and PCTs

Comprising nearly 100 congeners in environmental samples, PCBs are often still prevalent in concentrations exceeding 1 μg/g. To effectively measure PCBs, they are isolated as a group from other persistent organic pollutants using silica gel, Florisil, or alumina column chromatography for analysis by GC/MS or dual capillary column GC/ECD. When organochlorine pesticides (OCPs) and polybrominated diphenyl ethers (PBDEs) are also targeted, PCBs are often split into two chromatographic eluates. In contrast to the major ortho-substituted PCB congeners, much lower concentrations occur for congeners of polychlorinated- dibenzo- p -dioxins (PCDDs), dibenzofurans (PCDFs), dibenzothiophenes (PCDTs), naphthalenes (PCNs), and dioxin-like non- ortho -PCBs 1 . Such co-planar compounds are usually separated from the bulk PCBs using a carbon LC 2 or reusable porous graphitic carbon HPLC column 3 eluted forward ( o -PCBs, mono- o -PCBs, then non- o -PCBs) before reversal with toluene (PCDFs and PCDDs) and additional separation with basic alumina to remove PCNs, polychlorinated diphenyl ethers (PCDEs), and residual lipid for PCDF/PCDD GC/HRMS analysis. Recently, smaller particle-size normal phase adsorbents including active basic alumina have become available along with custom-made glass columns for use in low pressure flash chromatography. With low gas pressure (< 1-2 bar) and particles 32-63 μm, flash chromatography is a rapid, inexpensive technique with enhanced resolution compared to gravity column chromatography 4 . However, few environmental researchers use the technique, but basic alumina is in the automated PowerPrep LC system for PCDFs, PCDDs, PCBs and PBDEs 5 . A flash LC column is quickly dry-packed, gives improved flow performance, and has sufficient resistance to gravity flow without a shutoff valve. Contamination from lab air, dust, and sample carryover is minimized by using high purity nitrogen, much smaller eluate volumes and blown down in tubes with high purity nitrogen. The disposable adsorbent is used only once with an inert, nonleachable, reusable and cleanable glass column with glass joints and disposable glass fiber. We evaluated basic alumina flash chromatography initially for PCBs, because Loos et al. 6 had separated 13 selected o -PCB congeners from three non- o -PCBs (77, 126, and 169) and then from PCDFs and PCDDs with eluants of 150- 200 mL each from a large 25-g basic alumina (Super 1 active) column. Because the elution properties of other PCB congeners were unknown in addition to some PBDEs, PCDTs, and other compounds, we chose to evaluate basic alumina flash chromatography comprehensively. We optimized the separation of all bulk o-PCBs from all non- o- PCBs, tested other pollutants (PBDEs, PCDTs, PCDFs and PCDDs) under similar elution conditions, and finally applied the chromatographic technique to samples known or suspected to contain complex mixtures of these.

Organohalogen Compounds

Freshwater availability in Guam with projected changes in climate

Guam receives 85 to 116 inches of rain a year, two-thirds of which has historically fallen during the wet season. On average, three tropical storms and one typhoon pass within 80 nautical miles of Guam each year, generally during the rainy season. Both drought and flooding can impact freshwater supply and the associated infrastructure. Department of Defense (DoD) installations and non-military populations on Guam share freshwater resources, which will be impacted by changes in demographics, freshwater demand, and climate. This DoD Strategic Environmental Research and Development Program (SERDP) funded study evaluated potential climate impacts on freshwater supplies in Guam, and identified methods of increasing the water distribution system’s resilience.

Cooperator Report

Characterization of soils and rock at an active oil production site: Effects of brine and hydrocarbon contamination

An active oil production site (Osage-Skiatook petroleum environmental research Site B) in Osage County, Oklahoma is under study to determine the impacts on soils and rock of brine and hydrocarbon spills. The goals of the soil and rock characterization are to 1) document and identify the type, degree, and areal extent of brine and hydrocarbon releases, 2) understand controls on the movement and retention of brine and hydrocarbons, and 3) determine the role of solid phases, such as clay and iron-bearing minerals, in natural mitigation. The types and amounts of clay minerals and oxidizers (particularly iron) are important because of the capacity of clay minerals to exchange cations that are dissolved in brines and the capacity of reactive ferric iron species to oxidize hydrocarbons. Characterization of soils and rock includes visual and microscopic description, X-ray diffraction of bulk and clay fraction samples, separation of size fractions, determination of cation exchange capacity, bulk chemical composition, and selective extraction of iron species. Results suggest that much of the brine and hydrocarbon contamination occurs in the shallow subsurface (< 240 cm) where the soil profile varies from dark brown topsoil to reddish orange sand to greenish-gray clay. A layer of iron-stained colluvium that is present in the shallow subsurface consists of pebbles and coarse sand and forms an important conduit for fluid movement. Unusually high percentages (as much as 97 % of total iron) of reduced iron may record the passage of hydrocarbon-rich ground water. Clay minerals are abundant in some samples and are dominated by kaolinite, mixed layer illite-smectite, and smectite. The correlation of grain size and clay mineral content with soil leachate results will be discussed and high percentages of sodium on exchange sites in clay are expected in areas of past spills of produced water.

Oklahoma

Lake Tahoe clarity and associated conditions, 2022

Lake Tahoe’s clarity remains a key indicator of overall ecosystem status, and scientific understanding about factors affecting lake clarity continues to evolve. The purpose of this briefing memorandum is to summarize the status of clarity metrics and drivers of change discussed in the 2022 TSAC Data Synthesis and Analysis report. Consistent with the Lake Tahoe Total Maximum Daily Load analyses, the concentrations of fine particles remain important to lake clarity. These include fine sediment particles from the watershed as well as small phytoplankton cells produced within the lake. This year, in addition to the analysis of Secchi depth clarity response to fine particle and small phytoplankton concentrations, we reviewed available data on fine sediment particles from streams and urban runoff. Information summarized here is discussed further in the Tahoe Science Advisory Council (TSAC) Data Synthesis and Analysis reports (2022, 2021), the TSAC Lake Tahoe Seasonal and Long-Term Clarity Trend Analysis report (2020), and in annual State of the Lake reports produced by UC Davis Tahoe Environmental Research Center.

California, Nevada

Great Lakes lake trout thiamine monitoring program annual report

The U.S. Geological Survey’s Great Lakes Science Center (GLSC), Eastern Ecological Science Center, and Columbia Environmental Research Center (CERC), and the State University of New York (SUNY) Brockport have conducted in collaboration with partner agencies a cooperative program to monitor thiamine concentrations in lake trout eggs since the late 1990s. In 2021, egg thiamine concentrations were highly variable at each sampling site. No eggs samples with thiamine concentrations less than the 4 nmol/g threshold recommended for successful lake trout reproduction were collected in Lakes Superior, Huron, Erie, and Champlain. In contrast, every site in Lakes Michigan and Ontario and Cayuga Lake had some lake trout eggs below 4 nmol/g. Time series of mean lake trout egg thiamine concentrations showed high temporal and spatial variability within the Great Lakes region.

Great Lakes

Great Lakes lake trout (Salvelinus namaycush) thiamine monitoring program annual report

Thiamine deficiency in lake trout eggs has been identified to induce early life-stage mortality in the Great Lakes in the 1960s through the 1990s and potentially affecting lake trout recruitment. As a results, the U.S. Geological Survey’s Great Lakes Science Center (GLSC), Eastern Ecological Science Center, and Columbia Environmental Research Center (CERC), and the State University of New York (SUNY) Brockport, in collaboration with partner agencies, have conducted a cooperative program to monitor thiamine concentrations in lake trout Salvelinus namaycush eggs since the late 1990s. In 2023, egg thiamine concentrations were highly variable at each sampling site. No egg samples with thiamine concentrations less than the 4 nmol/g threshold recommended for successful lake trout reproduction were collected in Lakes Superior or Huron. In contrast, 3 to 52% of the lake trout collected at sites in Lakes Michigan, Huron, Ontario and Champlain, and Cayuga Lake had eggs below 4 nmol/g. Time series of mean lake trout egg thiamine concentrations showed high temporal and spatial variability within the Great Lakes region.

Cayuga Lake, Lake Champlain, Lake Erie, Lake Huron

Great Lakes lake trout (Salvelinus namaycush) thiamine monitoring program annual report

Thiamine deficiency in lake trout ( Salvelinus namaycush ) eggs has been linked to early life-stage mortality in the Great Lakes from the 1960s through the 1990s, potentially affecting lake trout recruitment. In response, the U.S. Geological Survey’s Great Lakes Science Center (GLSC), Eastern Ecological Science Center (EESC), and Columbia Environmental Research Center (CERC), and the State University of New York (SUNY) Brockport, in collaboration with partner agencies, initiated a cooperative monitoring program in the late 1990s to assess thiamine concentrations in lake trout eggs. In 2024, egg thiamine concentrations continued to show high variability across sampling sites. No samples with thiamine concentrations below the 4 nmol/g threshold recommended for successful reproduction were observed in Lakes Superior or Huron. In contrast, between 11% and 88% of lake trout sampled from sites in Lakes Michigan, Ontario, Champlain, and the Finger Lakes had egg thiamine concentrations below this critical threshold. Time series data revealed substantial temporal and spatial variation in mean lake trout egg thiamine concentrations across the Great Lakes region.

Finger Lakes, Great Lakes, Lake Champlain

Toward sustainable environmental quality: Priority research questions for North America

Anticipating, identifying, and prioritizing strategic needs represent essential activities by research organizations. Decided benefits emerge when these pursuits engage globally important environment and health goals, including the United Nations Sustainable Development Goals. To this end, horizon scanning efforts can facilitate identification of specific research needs to address grand challenges. We report and discuss 40 priority research questions following engagement of scientists and engineers in North America. These timely questions identify the importance of stimulating innovation and developing new methods, tools, and concepts in environmental chemistry and toxicology to improve assessment and management of chemical contaminants and other diverse environmental stressors. Grand challenges to achieving sustainable management of the environment are becoming increasingly complex and structured by global megatrends, which collectively challenge existing sustainable environmental quality efforts. Transdisciplinary, systems‐based approaches will be required to define and avoid adverse biological effects across temporal and spatial gradients. Similarly, coordinated research activities among organizations within and among countries are necessary to address the priority research needs reported here. Acquiring answers to these 40 research questions will not be trivial, but doing so promises to advance sustainable environmental quality in the 21st century.

Environmental Toxicology and Chemistry