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USGS environmental characterization of flood sediments left in the New Orleans area after Hurricanes Katrina and Rita, 2005 — Progress Report

Introduction: The flooding in the greater New Orleans area that resulted from Hurricanes Katrina and Rita in September, 2005, left behind accumulations of sediments up to many centimeters thick on streets, lawns, parking lots, and other flat surfaces. These flood sediment deposits have been the focus of extensive study by the US Environmental Protection Agency (EPA) and Louisiana Department of Environmental Quality (LDEQ) due to concerns that the sediments may contain elevated levels of heavy metals, organic contaminants, and microbes. The U.S. Geological Survey (USGS) is characterizing a limited number of flood sediment samples that were collected on September 15-16 and October 6-7, 2005, from the greater New Orleans area by personnel from the USGS Louisiana Water Science Center in Baton Rouge. Small samples (< 3 pints each) of wet to dry flood sediment were collected from 11 localities around downtown New Orleans on September 15, 2005, and two large samples (40 pints each) of wet flood sediment were collected from the Chalmette area on September 16. Twelve additional samples (8-10 pints each) were collected from New Orleans, Slidell, Rigolets, and Violet on October 6 and 7. The USGS characterization studies of these flood sediments are designed to produce data and interpretations regarding how the sediments and any contained contaminants may respond to environmental processes. This information will be of use to cleanup managers and DoI/USGS scientists assessing environmental impacts of the hurricanes and subsequent cleanup activities.

Louisiana

Groundwater conditions in Utah, spring of 2011

This is the forty-eighth in a series of annual reports that describe groundwater conditions in Utah. Reports in this series, published cooperatively by the U.S. Geological Survey and the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality, provide data to enable interested parties to maintain awareness of changing groundwater conditions. This report, like the others in the series, contains information on well construction, groundwater withdrawal from wells, water-level changes, precipitation, streamflow, and chemical quality of water. Information on well construction included in this report refers only to wells constructed for new appropriations of groundwater. Supplementary data are included in reports of this series only for those years or areas that are important to a discussion of changing groundwater conditions and for which applicable data are available. This report includes individual discussions of selected significant areas of groundwater development in the State for calendar year 2010. Most of the reported data were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Environmental Quality, Division of Water Quality. This report is also available online at http:// www.waterrights.utah.gov/techinfo/ and http://ut.water.usgs. gov/publications/GW2011.pdf. Groundwater conditions in Utah for calendar year 2009 are reported in Burden and others (2010) and available online at http://ut.water.usgs.gov/ publications/GW2010.pdf. Analytical results associated with water samples collected from each area of groundwater development were compared to State of Utah Maximum Contaminant Levels (MCLs) and secondary drinking-water standards of routinely measureable substances present in water supplies. The MCLs and secondary drinking-water standards can be accessed online at http://www.rules.utah.gov/publicat/code/r309/r309-200. htm#T5. The U.S. Environmental Protection Agency (EPA) drinking-water standards can be accessed at http://www.epa. gov/safewater/mcl.html#mcls. Maximum Contaminant Levels and secondary drinking-water standards were developed for public water systems and do not apply to the majority of wells sampled during this study.

Utah

Sources and haloacetic acid/trihalomethane formation potentials of aquatic humic substances in the Wakarusa River and Clinton Lake near Lawrence, Kansas

Gram quantities of aquatic humic substances (AHS) were extracted from the Wakarusa River−Clinton Lake Reservoir system, near Lawrence, KS, to support nuclear magnetic resonance (NMR) experimental studies, report concentrations of dissolved organic carbon (DOC) and AHS, define sources of the AHS, and determine if the AHS yield sufficient quantities of haloacetic acids (HAA5) and trihalomethanes (THM4) that exceed U.S. Environmental Protection Agency (EPA) Maximum Contaminant Levels (MCL) in drinking water. AHS from the Wakarusa River and Clinton Lake originated from riparian forest vegetation, reflected respective effects of soil organic matter and aquatic algal/bacterial sources, and bore evidence of biological degradation and photodegradation. AHS from the Wakarusa River showed the effect of terrestrial sources, whereas Clinton Lake humic acid also reflected aquatic algal/bacterial sources. Greater amounts of carbon attributable to tannin-derived chemical structures may correspond with higher HAA5 and THM4 yields for Clinton Lake fulvic acid. Prior to appreciable leaf-fall from deciduous trees, the combined (humic and fulvic acid) THM4 formation potentials for the Wakarusa River approached the proposed EPA THM4 Stage I MCL of 80 μg/L, and the combined THM4 formation potential for Clinton Lake slightly exceeded the proposed THM4 Stage II MCL of 40 μg/L. Finally, AHS from Clinton Lake could account for most (>70%) of the THM4 concentrations in finished water from the Clinton Lake Water Treatment Plant based on September 23, 1996, THM4 results.

Environmental Science & Technology

Structure and vulnerability of Pacific Northwest tidal wetlands – A summary of wetland climate change research by the Western Ecology Division, U.S. EPA

Climate change poses a serious threat to the tidal wetlands of the Pacific Northwest (PNW) region of the U.S. In response to this threat, scientists at the Western Ecology Division of the U.S. EPA at and the Western Fisheries Research Center of the U.S. Geological Survey, along with other partners, initiated a series of studies on the structure and vulnerability of tidal wetlands to climate change. One research thrust was to evaluate community structure of PNW marshes, experimentally assess the vulnerability of marsh plants to inundation and salinity stress (as would happen with sea level rise), and evaluate the utility of the National Wetland Inventory (NWI) classification system. Another research thrust was to develop tools that provide insights into possible impacts of climate change. This effort included enhancing the Sea Level Affecting Marshes Model (SLAMM) to predict the effects of sea level rise on submerged aquatic vegetation (Zostera marina) distributions, evaluating changes in river flow into coastal estuaries in response to precipitation changes, and synthesizing Pacific Coast estuary, watershed, and climate data in a downloadable tool. Because the research resulting from these efforts was published in multiple venues, we summarized them in this document. We anticipate that future research efforts by the U.S. EPA will continue with a focus on climate change impacts on a regional scale.

California, Oregon, Washington

Results of a workshop concerning impacts of various activities on the functions of bottomland hardwoods

Under Section 404 of the Clean Water Act, the U.S. Environmental Protection Agency (EPA) has regulatory responsibilities related to the discharge of dredged or fill material into the Nation’s waters. In addition to its advisory role in the U.S. Army Corps of Engineers' permit program, EPA has a number of specific authorities, including formulation of the Section 404(b)(1) guidelines, use of Section 404(c) to prohibit disposal at particular sites, and enforcement actions for unauthorized discharges. A number of recent court cases focus on the geographic scope of Section 404 jurisdiction in potential bottomland hardwood (BLH) wetlands and the nature of landclearing activities in these areas that require a permit under Section 404. Accordingly, EPA needs to establish the scientific basis for implementing its responsibilities under Section 404 in bottomland hardwoods. EPA is approaching this task through a series of workshops designed to provide current scientific information on bottomland hardwoods and to organize that information in a manner pertinent to key policy questions. The first two workshops in the series were originally conceived as technically oriented meetings that would provide the information necessary to develop policy options at the third workshop. More specifically, the first workshop was designed to examine a zonation concept as a means of characterizing different BLH communities and describing variations in their functions along a soil moisture gradient. The second workshop was perceived as an attempt to evaluate the impacts of various activities on those functions. However, one conclusion of the first workshop, which was held in December 1984 in St. Francisville, Louisiana, was that the zonation approach does not describe the variability in the functions performed by BLH ecosystems sufficiently well to allow its use as the sole basis for developing a regulatory framework. That is, factors other than zone were considered critical for an effective characterization of the structure and functions of bottomland hardwoods. The approach to the second workshop, the results of which are described in this report, was therefore modified in response to the conclusions from the first workshop. The focus of the second workshop remained an analysis of the impacts of various activities or the functions of BLH ecosystems. However, as a prerequisite to this analysis, participants were also asked to develop a list of characteristics that determine the extent to which BLH sites perform the important functions. The workshop was organized such that alternating plenary and workgroup sessions allowed ample time for communication while still maintaining a focus on the overall goal. In the initial session, various individuals gave presentations concerning methodologies for evaluating the functions performed by wetlands, factors influencing the conversion of BLH forests to other uses, and the impacts of conversion activities. These were followed by a series of case study presentations designed to familiarize participants with the kinds of issues that are dealt with in the Section 404 program. These presentations are cited in this report as (author, workshop presentation). At the conclusion of these presentations, participants were divided into six workgroups to examine the functions of BLH ecosystems in the areas of hydrology, water quality, fisheries, wildlife, ecosystem processes, and culture/recreation/economics. Each workgroup was asked to undertake the following tasks. 1. Developed a list of functions performed by BLH ecosystems from the perspective of the workgroup's expertise and area of responsibility. 2. Identify those activities (e.g., impoundment construction, conversion to soybean farming) that impact the major functions (e.g., sediment retention, detrital export) performed by BLH ecosystems. 3. Develop a list of characteristics that determine the extent to which a BLH site performs each function and describe the relationship of each characteristic to the function. Develop, with supporting evidence where possible, an analysis of the impact of each activity (Task 2) on each characteristic (Task 3) and on each function as a whole. Upon completion of Task 2, in an effort to provide some uniformity in the analysis by the various workgroups, EPA personnel and several participants met and compiled a complete list of all the activities identified as having significant impacts in bottomland hardwoods (Table 1). From this list the group derived a set of seven activities, and a number of specific actions associated with each, for analysis by the workgroups (Table 2). These activities were selected on the basis of their perceived importance in BLH ecosystems and their interest from the perspective of EPA. Each workgroup was also encourage to ass any activities of particular important from its perspective. The workgroup reports that follow document the results of discussion concerning the above tasks. The WORKSHOP SUMMARY attempts to summarize these workgroup results, discuss availability of information, and identify some problems that must be addressed prior to the third workshop in this series.

Report

Temporal chemical data for sediment, water, and biological samples from the Lava Cap Mine Superfund site, Nevada County, California— 2006–2008

The Lava Cap Mine is located about 6 km east of the city of Grass Valley, Nevada County, California, at an elevation of about 900 m. Gold was hosted in quartz-carbonate veins typical of the Sierran Gold Belt, but the gold grain size was smaller and the abundance of sulfide minerals higher than in typical deposits. The vein system was discovered in 1860, but production was sporadic until the 1930s when two smaller operations on the site were consolidated, a flotation mill was built, and a 100-foot deep adit was driven to facilitate drainage and removal of water from the mine workings, which extended to 366 m. Peak production at the Lava Cap occurred between 1934 and 1943, when about 90,000 tons of ore per year were processed. To facilitate removal of the gold and accessory sulfide minerals, the ore was crushed to a very fine sand or silt grain size for processing. Mining operations at Lava Cap ceased in June 1943 due to War Production Board Order L-208 and did not resume after the end of World War II. Two tailings retention structures were built at the Lava Cap Mine. The first was a log dam located about 0.4 km below the flotation mill on Little Clipper Creek, and the second, built in 1938, was a larger earth fill and rip-rap structure constructed about 2 km downstream, which formed the water body now called Lost Lake. The log dam failed during a storm that began on December 31, 1996, and continued into January 1997; an estimated 8,000-10,000 m 3 of tailings were released into Little Clipper Creek during this event. Most of the fine tailings were deposited in Lost Lake, dramatically increasing its turbidity and resulting in a temporary 1-1.5 m rise in lake level due to debris blocking the dam spillway. When the blockage was cleared, the lake level quickly lowered, leaving a "bathtub ring" of very fine tailings deposited substantially above the water line. The U.S. Environmental Protection Agency (EPA) initiated emergency action in late 1997 at the mine site to reduce the possibility of future movement of tailings, and began an assessment of the risks posed by physical and chemical hazards at the site. The EPA's assessment identified arsenic (As) as the primary hazard of concern. Three main exposure routes were identified: inhalation/ingestion of mine tailings, dermal absorption/ingestion of As in lake water from swimming, and ingestion of As-contaminated ground water or surface water. Lost Lake is a private lake which is completely surrounded by low-density residential development. Prior to the dam failure, the lake was used by the local residents for swimming and boating. An estimated 1,776 people reside within one mile of the lake, and almost all residents of the area use potable groundwater for domestic use. Risk factors for human exposure to As derived from mine wastes were high enough to merit placement of the mine site and surrounding area on the National Priority List (commonly called "Superfund"). The Lava Cap Mine Superfund site (LCMS) encompasses approximately 33 acres that include the mine site, the stretch of Little Clipper Creek between the mine and Lost Lake, the lake itself, and the area between the lake and the confluence of Little Clipper Creek with its parent stream, Clipper Creek. The area between the two creeks is named the "deposition area" due to the estimated 24 m thick layer of tailings that were laid down there during and after active mining. The lobate structure of Lost Lake is also due to deposition in this area. The deposition area and Lost Lake are together estimated to contain 382,277 m 3 of tailings. The primary goals of the EPA have been to minimize tailings movement downstream of Lost Lake and to ensure that residents in the area have drinking water that meets national water quality standards. EPA has officially decided to construct a public water supply line to deliver safe water to affected residences, since some residential wells in the area have As concentrations above the current drinking water standard (10 ppb). However, some deeper monitoring wells in the deposition area have As concentrations that are as much as 100 times the As drinking water standard (EPA, 2001). Fracture-dominated groundwater flowpaths complicate measurement of the rate and direction of groundwater flow in the area. Investigations of groundwater movement at the LCMS are planned by the EPA, but have not been undertaken at the time of this writing.

California

EPA method 1312 (synthetic precipitation leaching procedure); leachate chemistry data for solid mine waste composite samples from Silverton and Leadville, Colorado

The EPA Method 1312 Synthetic Precipitation Leaching Procedure (SPLP) leachate chemistry data for mine waste samples is presented. Four mine waste composite samples were collected from Silverton (YUK and MAY) and Leadville (SUN and VEN), Colorado and were extracted following the EPA Method 1312 procedure. Leachate pH values ranged from 2.68 to 3.37 and the samples were ranked by increasing pH: VEN < SUN < YUK < MAY. Specific conductivity values ranged from 203 µS to 1080 µS and the samples were ranked by increasing specific conductivity: MAY < YUK < SUN < VEN. For selected metal concentrations, no consistent pattern presented itself. MAY is the sample that typically has the lowest metal concentrations with the exception of nickel, zinc, and lead. The samples had SPLP leachate concentrations below the EPA Method 1311 Toxicity Characteristic Leaching Procedure (TCLP) regulatory levels.

Colorado

Hydrogeologic and water-quality characteristics of glacial-drift aquifers in Minnesota

Water in Minnesota 's glacial drift aquifers generally is of acceptable quality for most uses, including household supply, industrial use, and irrigation. The aquifers generally contain calcium magnesium bicarbonate-type waters, but other types are present also. Calcium magnesium sulfate-type waters are common in the confined drift aquifers in the southwestern and northwestern parts of the State. The elevated concentrations of sulfate, which exceed limits recommended for drinking water by the EPA, results mainly from solution of sulfate bearing minerals in rocks of Cretaceous age that have been reworked in deep glacial drift. Sodium and chloride-type waters are common in drift aquifers in northwestern Minnesota owing to the inflow of saline water from bedrock aquifers of Paleozoic age North Dakota. Cation exchange with clay minerals in the drift also is a source of sodium to these waters, particularly in the confined drift aquifers. Some of the water from these aquifers are unsuitable for irrigation because of elevated concentrations of sodium, and some are unsuitable for drinking because of elevated concentrations of chloride. Concentrations of nitrite plus nitrate (as N) locally exceed the EPA recommended limits for drinking water in central and northwestern Minnesota. Shallow, unconfined drift aquifers are particularly susceptible to nitrate contamination from land surface. Confined drift aquifers are much less susceptible because overlying till deposits retard downward movement of contaminants to the deeper aquifers. Nitrate contamination, which may cause methemoglobinemia in infants, is one of the more serious water quality concerns in Minnesota. Iron and manganese concentrations commonly exceed EPA 's recommendations for drinking water throughout the State, but these constituents affect aesthetic properties of water rather than health.

Minnesota

Agencies collaborate, develop a cyanobacteria assessment network

Cyanobacteria are a genetically diverse group of photosynthetic microorganisms that occupy a broad range of habitats on land and water all over the world. They release toxins that can cause lung and skin irritation, alter the taste and odor of potable water, and cause human and animal illness. Cyanobacteria blooms occur worldwide, and climate change may increase the frequency, duration, and extent of these bloom events. Rapid detection of potentially harmful blooms is essential to protect humans and animals from exposure. Information about potential for exposure, such as bloom duration, frequency, and extent, is especially critical for developing environmental management decisions during periods of limited resources and funding. The National Research Council (NRC) report Exposure Science in the 21st Century suggested that effectively assessing and mitigating exposures requires techniques for rapid measurement of a stressor, such as an algal bloom, across diverse geographic, temporal, and biologic scales (e.g., various bloom concentrations) and an enhanced infrastructure to address threats [ NRC , 2012]. The report specifically calls for approaches that use diverse information, such as satellite remote sensing, to identify and understand exposures that may pose a threat to ecosystems or human health. A collaborative effort integrates the work of the U.S. Environmental Protection Agency (EPA), NASA, the National Oceanic and Atmospheric Administration (NOAA), and the U.S. Geological Survey (USGS) to provide an approach for using satellite ocean color capabilities in U.S. fresh and brackish water quality management decisions. The overarching goal of this collaborative project is to detect and quantify cyanobacteria blooms using satellite data records in order to support the environmental management and public use of U.S. lakes and reservoirs. Satellite remote sensing tools may enable policy makers and environmental managers to assess the sustainability of watershed ecosystems and the services they provide, now and in the future. Satellite technology allows us to develop early-warning indicators of cyanobacteria blooms at the local scale while maintaining continuous national coverage.

Eos, Earth and Space Science News

Cruise report, RV ocean alert cruise A1-98-HW; January 30 through February 23, 1998, Honolulu to Honolulu, Hawaii

The major objective of cruise A1-98 was to map portions of the insular slopes of Oahu, Kauai, Maui, Molokai, and Hawaii and to survey in detail US Environmental Protection Agency (USEPA) ocean dumping sites using a Simrad EM300 high-resolution multibeam mapping system. The cruise was a jointly funded project between the US Army Corps of Engineers (USCOE), USEPA, and the US Geological Survey (USGS). The USACOE and EPA are interested in these areas because of a series of ocean dump sites off Oahu, Kauai, Maui, and Hawaii (Fig. 1) that require high-resolution base maps for site monitoring purposes. The USGS Coastal and Marine Geology Program has several on-going projects off Oahu and Maui that lack high-precision base maps for a variety of ongoing geological studies. The cruise was conducted under a Cooperative Agreement between the USGS and the Ocean Mapping Group, University of New Brunswick, Canada.

Hawai'i

Phytoplankton, taste-and-odor compounds, and cyanotoxin occurrence in four water-supply reservoirs in the Triangle area of North Carolina, April–October 2014

Prior to 2014, local utilities and State agencies monitored for cyanotoxins and taste-and-odor (T&O) compounds and reported occasional detections in three water-supply reservoirs in Wake County, North Carolina. Comparable data for cyanotoxins and T&O compounds were lacking for other water-supply reservoirs in the Triangle area of North Carolina. This report assesses whether cyanotoxins and T&O compounds occurred in four previously unmonitored North Carolina Triangle area water-supply reservoirs at levels that exceed existing North Carolina and U.S. Environmental Protection Agency recreational and drinking water health advisory, guidance, and criterion levels based on data collected during the peak phytoplankton growth period in 2014. Samples were collected from five sites across the study reservoirs (Cane Creek Reservoir, West Fork Eno River Reservoir, B. Everett Jordan Lake, and University Lake) between April and October 2014 and analyzed for physical characteristics, chemical constituents, phytoplankton communities, cyanotoxins, and T&O compounds. Lake stratification during the sampling period in 2014 could indicate that the deep zones of the water column, during stratified anoxic conditions, may serve as possible sources of nutrients and metals for algal growth and other biogeochemical processes. Differences in phytoplankton communities were attributed to variability in environmental conditions across the sites and sampling events. Differences generally were greater among sites than among sampling events for phytoplankton communities and environmental conditions. Phytoplankton community assemblages, within reservoirs, often were dominated by cyanobacteria that contained genera capable of producing T&O compounds and cyanotoxins during summer and fall months. The occurrence and associated biovolumes of potential producers of cyanotoxins and T&O compounds varied across the sites and sampling events. Of 20 samples collected during the study, the T&O compound geosmin and the cyanotoxin microcystin were present in 19 and 18 samples, respectively. While not harmful, the aesthetically displeasing geosmin concentrations periodically exceeded the human detection threshold of 15 nanograms per liter at most sites. The T&O compound 2-methylisoborneol (MIB) was detected in 11 of 20 samples, with concentrations below the human detection threshold of 15 nanograms per liter in all but one sample. The cyanotoxin anatoxin-a was detected in two of the samples. No other cyanotoxins were detected during the study. In general, results did not indicate the biovolume of any given phytoplankton genera in the study was correlated with increased concentrations of MIB, geosmin, or microcystin. Results from this study indicated that microcystin concentrations in the water-supply reservoirs in the Triangle area were below EPA-recommended recreational level of 8 micrograms per liter, but periodically exceeded the EPA finished-water 10-day health advisory level of 0.3 microgram per liter for bottle-fed infants and preschool-age children. This suggests longer term data collection may be necessary to better understand the magnitude and frequency of cyanotoxin concentrations in these four water-supply reservoirs, particularly those with an elevated risk of exceeding the EPA 10-day health advisory levels in the finished drinking water or those with a higher frequency of T&O compound occurrence.

North Carolina

Methodology used to produce an encoded 1:100,000-scale digital hydrographic data layer for the Pacific Northwest

The U.S. Geological Survey (USGS) has produced a River Reach File data layer for the Pacific Northwest for use in water-resource management applications. The Pacific Northwest (PNW) River Reach Files, a geo-referenced river reach data layer at 1:100,000-scale, are encoded with the U.S. Environmental Protection Agency"s (EPA) reach numbers. The encoding was a primary task of the River Reach project, because EPA"s reach identifiers are also an integral hydrologic component in a regional Northwest Environmental Data Base-an ongoing effort by Federal and State agencies to compile information on reach-specific resources on rivers in Oregon, Idaho, Washington, and western Montana. A unique conflation algorithm was developed by the USGS to transfer the EPA reach codes and other meaningful attributes from the 1:250,000-scale EPA TRACE graphic files to the PNW Reach Files. The PNW Reach Files also were designed so that reach-specific information upstream or downstream from a point in the stream network could be extracted from feature attribute tables or from a Geographic Information System. This report documents the methodology used to create this 1:100,000-scale hydrologic data layer.

Water-Resources Investigations Report

Simulation of Streamflow and Water Quality to Determine Fecal Coliform and Nitrate Concentrations and Loads in the Mad River Basin, Ohio

The Hydrological Simulation Program Fortran (HSPF) was used to simulate the concentrations and loads of fecal coliform and nitrate for streams in the Mad River Basin in west-central Ohio during the period 1999 through 2003. The Mad River Basin was divided into subbasins that were defined either by the 14-digit Hydrologic Unit (HU) boundaries or by streamflow-gaging-station locations used in the model. Model calibration and simulation processes required the formation of nine meteorologic zones to input meteorologic time-series data and water-quality data. Sources of fecal coliform and nitrate from wastewater-treatment discharges and combined sewer overflow discharges (CSOs) within the City of Springfield were point sources simulated in the model. Failing septic systems and cattle with direct access to streams were nonpoint sources included in the study but treated in the model as point sources. Other nonpoint sources were addressed by adjusting interflow and ground-water concentrations in the subsurface and maximum storage capacities and accumulation rates of the simulated constituents on the land surface for each meteorologic zone. Simulation results from the calibrated model show that several HUs exceeded the water-quality standard of 1,000 colony-forming units per 100 mL for fecal coliform based on the maximum 30-day geometric mean. Most HUs with high fecal coliform counts were within or downstream from the City of Springfield. No water-quality standard has been set for instream nitrate concentrations; however, the Ohio Environmental Protection Agency (Ohio EPA) considered a concentration of 5 mg/L or greater to be of concern. Simulation results indicate that several HUs in the agricultural areas of the basin exceeded this level. The calibrated model was modified to create scenarios that simulated loads of fecal coliform and nitrate that were either reduced or eliminated from selected sources. The revised models included the elimination of failing septic systems, elimination of direct access of cattle to streams, decrease in fecal coliform loads from the CSOs and selected wastewater-treatment facilities, and decrease in nitrate loads from land surfaces. The fecal coliform source-reduction model decreased the fecal coliform concentrations below a target concentration of 1,000 colonies per 100 milliliters for all HU outlets and decreased the load at the mouth of the Mad River by 73 percent. The nitrate source-reduction model decreased some HU mean concentrations to 5 milligrams per liter or less and decreased the load at the mouth of the Mad River by 52 percent. Other reduction scenarios may be run by Ohio EPA with the intent of identifying a management strategy that will attain a target concentration for the Mad River Basin.

Scientific Investigations Report

A study of porewater in water saturated sediments of levee banks and marshes in the lower Coeur d'Alene River valley, Idaho: Sampling, analytical methods, and results

This report contains information about the composition of interstitial porewater and solids from water saturated, metal contaminated levee banks at the river's edge and marshes in the lower Coeur d'Alene River valley. Data include pH, alkalinity, and concentrations of sulfate and metals (arsenic [As], cadmium [Cd], copper [Cu], iron [Fe], mercury [Hg], manganese [Mn], lead [Pb], antimony [Sb], and zinc [Zn]) in porewater and sulfur (S), carbon (C), and metal contents of associated solids. The results indicate that the pH of the porewater in all of the sediments is less than the pH of the Coeur d'Alene River. Dissolved concentrations of Mn and Fe are elevated in all of the porewater and levels of sulfate in porewater are below detection limits in almost all marsh sediments and in levee banks at the 2 sites furthest downstream. These observations suggest that levee bank and marsh sediments are suboxic or anoxic below the surface. Concentrations of dissolved Cd are greater in the Coeur d'Alene River than in porewater, while concentrations of As are greater in the porewater relative to the Coeur d'Alene River. Some concentrations of Cu, Pb, Sb, and Zn in porewater are lower, while others are higher, than dissolved concentrations in the Coeur d'Alene River. In addition, leaching experiments (i.e., Standard Elutriate Tests [SET]) were done in the laboratory to evaluate potential water quality impacts resulting from the addition of oxygen and water to these sediments. The intent of the experiments was to simulate how metal concentrations in water may be affected during dredging of contaminated sediments in the lower Coeur d'Alene River valley. The results indicate that there are releases of protons, sulfate, As, Mn, Pb, Sb, and Zn from the majority of levee bank and marsh sediments during leaching by Coeur d'Alene River water. At a water to sediment ratio of 4 to 1, most values of pH and dissolved concentrations of Cd, Fe, Pb, and Zn in the leaching solutions exceed the freshwater aquatic life standards for water of a hardness of 100 mg CaCOa/L. This work was funded by the U.S. EPA and was done to support their Remedial Investigation/Feasibility Study of the Coeur d'Alene and Spokane River basins.

Idaho

Water quality of the lower Columbia River Basin: Analysis of current and historical water-quality data through 1994

The lower Columbia River Basin includes the river basins draining into the Columbia River below Bonneville Dam&mdash;the largest of which is the Willamette River. This report presents the results of a study by the U.S. Geological Survey, done in cooperation with the Lower Columbia River Bi-State Water- Quality Program, to describe the water-quality conditions in the lower Columbia River Basin by interpreting historical data collected and data collected in 1994. Historical water-quality data spanning more than 50 years and comprising more than 200 parameters were collated for interpretation in this report. The U.S. Geological Survey, the Oregon Department of Environmental Quality, and the Washington Department of Ecology collected water-quality data at 10 sites in the lower Columbia River Basin from January to December of 1994. Water-quality constituents measured in 1994 were screened against U.S. Environmental Protection Agency (EPA) and State guidelines. Arsenic, a human carcinogen, was detected in 15 of 16 samples in the lower Columbia River, but was not detected in any of the sampled tributaries. All 15 arsenic detections had concentrations that exceeded both the EPA ambient water-quality criteria for the protection of human health and the EPA human-health advisories for drinking water. Chromium was detected at all four Columbia River sites&mdash;most frequently in the Columbia River at Hayden Island. None of the chromium concentrations detected, however, exceeded water-quality criteria or guidelines. Measurements of suspended trace-element concentrations (trace-element concentrations associated with the suspended-sediment fraction) showed that the suspended form is the dominant transport phase for aluminum, iron, and manganese, whereas the dissolved form is the dominant transport phase for arsenic, barium, chromium, and copper. On the basis of tributary loads during summer low-flow months, sources of suspended silver, nickel, aluminum, and antimony exist in the lower Columbia River Basin, whereas the sources of suspended zinc and arsenic exist outside of the lower basin. Twenty organic compounds were detected of the 47 compounds analyzed for this study. None of the organic compounds measured exceeded EPA&rsquo;s ambient water-quality criteria or drinking-water guidelines. The Willamette River at Portland had the largest number of detections, and all 20 compounds were detected at one time or another at that site. The largest concentrations of the agricultural pesticides, atrazine, metolachlor, and simazine were detected in the Willamette River, where they were detected in 93, 86, 93 percent, respectively, of the samples collected. The highest concentrations of atrazine in the Willamette River were associated with the spring application and fall runoff periods. Both historical and current data showed that the highest water temperatures in the lower Columbia River Basin are present during August. For water years 1977&ndash;81 in the Columbia River at Bradwood (river mile 38.9), 75 percent of the daily mean water temperatures during August exceeded 20 degrees Celsius, a &ldquo;special condition&rdquo; criterion for the State of Washington. The special condition criterion was exceeded at four sites on the lower Columbia River during July and August, 1994&mdash;a period coinciding with season-high air temperatures and low streamflow. Trend tests using data from 1974 to 1994 showed significant (r < 0.05) upward trends for water temperature at the Columbia River at Warrendale and the Willamette River at Portland. Concentrations of dissolved oxygen and total dissolved gas were above saturation levels during high stormflows in the lower Columbia River and the Willamette River during 1994. The high concentrations of total dissolved gas in the Columbia River exceeded Oregon and Washington State standards of 110 percent of saturation and were caused by spilling water at the Columbia River dams. Aquatic life in the lower Columbia River Basin was not subjected to low dissolved-oxygen concentrations. Comparison of dissolved-oxygen concentrations in the Willamette River from 1949&ndash;58 to 1972&ndash;94 showed a significant increase in dissolved-oxygen concentrations during the low-streamflow months of summer. Trend tests showed significant (r < 0.05) downward trends from 1973 to 1994 for three constituents at the Columbia River at Warrendale: phosphorus in unfiltered water, total dissolved solids, and specific conductance. These trends may be a consequence of more conservative agricultural practices in the area upstream from Warrendale.

Oregon

Assessment of the role of bottomland hardwoods in sediment and erosion control

Drainage and clearing of bottomland hardwoods have long been recognized by the U.S. Environmental Protection Agency (EPA) and the U.S. Fish and Wildlife Service (Service) as important impacts of Federal water projects in the lower Mississippi River Valley. More recently, the water quality impacts of such projects (e.g., increases in sediments, nutrients, and pesticides) have also become of concern. In 1984, in an effort to better define problems concerning wetland losses and water degradation, EPA initiated a cooperative project with the Western Energy and Land Use Team (now the National Ecology Research Center) of the Service. Three phases of the project were identified: 1. To collect existing literature and data; 2. To select, develop, and test the utility of methods to quantify the relationships between land use, cover types, soils, hydrology, and water quality (as represented by sediment); and 3. To apply selected methodologies to several sites within the Yazoo Basin of Mississippi to determine the, potential effectiveness of various management alternatives to reduce sediment yield, increase sediment deposition, and improve water quality. Methods development focused on linking a simulation of water and sediment movement to a computerized geographic information system. We had several objectives for the resulting model. We desired that it should: 1. Estimate the importance of bottomland and hardwoods as a cover type that performs the functions of erosion and sediment control, 2. Simulate effects of proportions of ' various cover types and their specific spatial configurations, 3. Be applicable to moderately large spatial areas with minimal site-specific calibration, 4. Simulate spatial patterns of sediment loss-gain over time, and 5. Represent both sediment detachment and transport. While it was recognized that impacts and management alternatives could be sorted roughly into landscape measures and channel measures, the decision was made to focus study efforts mainly on landscape measures. Landscape measures include altered drainage and flooding patterns, altered cover types (e.g., conversion of bottomland hardwoods to agricultural crops, reforestation of cropland to bottomland hardwoods, and creation of riparian buffer strips), altered cropping and tillage patterns, altered routing of water, and creation of buffer strips along wetlands and channel margins. Channel measures include vegetative bank stabilization, grade control structures, and regulation of channel water volume and velocity. During the first year of the study, EPA decided not to fund the third phase of the project. This required considerable rescoping of the project with the result that application of the sediment mobilization, routing, and deposition models to various management alternatives and portions of the Yazoo Basin was somewhat restricted. We believe, however, that this report will provide a good understanding of the various modes of sediment mobilization, transport, and deposition within the Yazoo Basin, as well as of the role of bottomland hardwoods. The model developed in this study could be applied to a variety of management or mitigation alternatives prior to implementation to determine their relative effectiveness. Policy, political, and socio-economic consequences of any proposed management/mitigation practice, however, must ultimately be taken into consideration by those charged with management of water resources within the Yazoo Basin before any practice is implemented. This study makes no effort to judge the feasibility of management alternatives in this regard.

Report

Second Integrated Hydro-Terrestrial Modeling (IHTM 2.0) workshop: USGCRP federal agency perspectives

U.S. federal leadership, mobilizing close interagency coordination across sectors, is key to tackling compound climate and human impacts on our nation’s water resources. Recognizing this need, federal agencies and academic collaborators conducted a series of workshops to advance Integrated Hydro-Terrestrial Modeling (IHTM). IHTM is focused on supporting a multiscale framework to accelerate research insights, better integrate operational and planning perspectives, and bridge national-to-regional capabilities to address major interdependent societal water challenges. This framework leverages the capabilities of different agencies and institutional partners across sectors to advance a shared vision for use-inspired modeling and open science. The IHTM conceptual framework has developed over several community workshops in recent years: ● In September 2019, a community coordinating group on IHTM hosted an interagency workshop (“IHTM 1.0”) with support from NSF, DOE, and USGS. The resulting report identified the need for agencies to invest resources in designing pilot use cases, setting the stage for an integrated national IHTM capability. ● In November 2020, the U.S. Global Change Research Program (USGCRP) held a virtual Coastal-IHTM (C-IHTM) workshop in collaboration with the MultiSector Dynamics Community of Practice, which engages researchers across universities and national labs. Building on IHTM 1.0, this workshop aimed to identify coastal modeling capabilities and appropriate coastal applications of the IHTM framework. The workshop report detailed needs for open science, geographical or topical use cases, integrated modeling frameworks, and linking communities of practice. ● From October 31 to November 2, 2023, USGCRP hosted a hybrid IHTM 2.0 community workshop that brought together 160 scientists and managers from nine federal departments/agencies (DHS-FEMA, DOC-NOAA, DoD-USACE, DOE, DOI [U.S. Bureau of Reclamation (USBR), USGS], EPA, NASA, NSF, USDA [ARS, FS, NRCS]) and 32 non-federal academic, non-profit, and private institutions and consortiums. The workshop was organized by a federal Interagency Steering Committee with representatives from DOE, USGS, NSF, NASA, and NOAA, as well as a Scientific Organizing Committee comprising experts from academia and additional federal agency technical experts. The IHTM 2.0 workshop focused on moving the IHTM 1.0 concepts to action by making advances in designing national and regional integrated modeling experiments in five geographic testbeds. These modeling testbeds seek to facilitate collaborative water resources research and assessment that responds to societal needs, extending from basic research to resource management operations, including the assessment of water quantity, quality, and use at national and regional scales. Ultimately, we envision that the IHTM testbeds will improve our ability to provide water resources assessment scenarios to decision-makers and the public. This document summarizes USGCRP and member agencies’ perspectives of the IHTM 2.0 workshop. Sections 2 and 3 build on the work of the IHTM 2.0 workshop Scientific Organizing Committee to outline the importance of IHTM, summarize the workshop, and propose near- and medium-term IHTM priorities. Section 4 presents select ongoing and potential interagency activities that could help realize the IHTM 2.0 vision and align with three of USGCRP’s strategic goals for this decade: Advancing Science, Informing Decisions, and Engaging the Nation. Finally, Section 5 summarizes this report and offers information about how to connect with USGCRP’s IHTM activities. USGCRP and its member agencies are well-positioned to coordinate federal efforts to enhance IHTM capabilities in the coming years.

Conference Paper

Interim report on the scientific investigations in the Animas River watershed, Colorado to facilitate remediation decisions by the U.S. Bureau of Land Management and the U.S. Forest Service, March 29, 2000 meeting, Denver, Colo.

INTRODUCTION The joint U.S. Department of the Interior and U.S. Department of Agriculture Abandoned Mine Lands Initiative (AMLI) was developed as a collaborative effort between the Federal land management agencies (FLMA, that is the U.S. Bureau of Land Management and the U.S. Forest Service) and the U.S. Geological Survey (USGS) in 1996. The stated goal of the AML Initiative was to develop a strategy for gathering and communicating the scientific information needed to develop effective and cost-efficient remediation of abandoned mines within the framework of a watershed. Four primary objectives of the AMLI are to: 1. Provide the scientific information needed (in the short-term) by the FLMAs to make decisions related to the design and implementation of cleanup actions, 2. Develop a multi-disciplined, multi-division approach that integrates geologic, hydrologic, geochemical and ecological information into a knowledge base for sound decision making, 3. Transfer technologies developed within the scientific programs of the USGS to the field and demonstrate their suitability to solve real, practical problems, and 4. Establish working relationships among involved members of land management and regulatory agencies within the framework of a watershed approach to the cleanup of abandoned mines. Long-term process-based research, including development of analytical tools, is recognized as being critical to the long-term success in remediating watersheds impacted by historical mining activities (AML 5-year plan, http://amli.usgs.gov/amli). In a meeting of Federal agencies (U.S. Bureau of Land Management [BLM], U.S. Bureau of Reclamation [BOR], U.S. National Park Service [NPS], U.S. Forest Service [USFS], the U.S. Environmental Protection Agency [EPA], the U.S. Fish and Wildlife Service [F&WS]), and State agencies (Colorado Division of Public Health and Environment, Colorado Division of Mines and Geology), several watersheds were examined within the state whose water quality was presumed to be impacted by historical mining activities. The Animas River watershed (fig. 1) was selected by the State and Federal agencies as one of two watersheds in the U.S. to be studied in detail by the USGS in the AML Initiative. Beginning in October 1997, each of the four Divisions of the USGS (Water Resources, Geologic, Biological Resources, and National Mapping) initiated a collaborative integrated science study of the watershed. Funds were provided from USGS base funding to each of the four Divisions in response to the priorities set by Congressional action and within the flexibility provided by the budgetary framework funding individual research programs. The AML Initiative provides for a five-year focused scientific effort in the two watersheds with final synthesis of the scientific results from each to be published in 2001. Publications are released on the AML web site on a regular basis (http://amli.usgs.gov/amli). On March 29, 2000, the USGS hosted a meeting for the BLM and USFS to discuss remediation options that were under consideration for the summer of 2000. The purpose of this report is to provide an overview of the scientific rational provided by the USGS to meet objective one above, and to summarize our preliminary interpretations of our data. Additional information from sites on private lands have been collected by the State of Colorado, EPA, and the ARSG. Unfortunately, these data have not been fully supplied to the USGS so our conclusions are based only upon our data. These interpretations provide science-based constraints on possible remediation options to be considered by the FLMA, the State, and local property owners in the Animas River watershed. The report is presented in outline format to facilitate discussion of remediation options at the March 29, 2000 meeting. Not all historical mining sites within the watershed are on public lands. This should not be construed to be a final report of the USGS

Denver