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The atmospheres of Saturn and Titan in the near-infrared: First results of Cassini/Vims

The wide spectral coverage and extensive spatial, temporal, and phase-angle mapping capabilities of the Visual Infrared Mapping Spectrometer (VIMS) onboard the Cassini-Huygens Orbiter are producing fundamental new insights into the nature of the atmospheres of Saturn and Titan. For both bodies, VIMS maps over time and solar phase angles provide information for a multitude of atmospheric constituents and aerosol layers, providing new insights into atmospheric structure and dynamical and chemical processes. For Saturn, salient early results include evidence for phosphine depletion in relatively dark and less cloudy belts at temperate and mid-latitudes compared to the relatively bright and cloudier Equatorial Region, consistent with traditional theories of belts being regions of relative downwelling. Additional Saturn results include (1) the mapping of enhanced trace gas absorptions at the south pole, and (2) the first high phase-angle, high-spatial-resolution imagery of CH4 fluorescence. An additional fundamental new result is the first nighttime near-infrared mapping of Saturn, clearly showing discrete meteorological features relatively deep in the atmosphere beneath the planet's sunlit haze and cloud layers, thus revealing a new dynamical regime at depth where vertical dynamics is relatively more important than zonal dynamics in determining cloud morphology. Zonal wind measurements at deeper levels than previously available are achieved by tracking these features over multiple days, thereby providing measurements of zonal wind shears within Saturn's troposphere when compared to cloudtop movements measured in reflected sunlight. For Titan, initial results include (1) the first detection and mapping of thermal emission spectra of CO, CO2, and CH3D on Titan's nightside limb, (2) the mapping of CH4 fluorescence over the dayside bright limb, extending to ??? 750 km altitude, (3) wind measurements of ???0.5 ms-1, favoring prograde, from the movement of a persistent (multiple months) south polar cloud near 88??S latitude, and (4) the imaging of two transient mid-southern-latitude cloud features. ?? Springer Science+Business Media, Inc. 2006.

Earth, Moon and Planets

Steady- and non-steady-state carbonate-silicate controls on atmospheric CO2

Two contrasting hypotheses have recently been proposed for the past long-term relation between atmospheric CO 2 and the carbonate-silicate geochemical cycle. One approach (Berner, 1990) suggests that CO 2 levels have varied in a manner that has maintained chemical weathering and carbonate sedimentation at a steady state with respect to tectonically controlled decarbonation reactions. A second approach (Raymo et al. , 1988), applied specificlly to the late Cenozoic, suggests a decrease in CO 2 caused by an uplift-induced increase in chemical weathering, without regard to the rate of decarbonation. According to the steady-state (first) hypothesis, increased weathering and carbonate sedimentation are generally associated with increasing atmospheric CO 2 , whereas the uplift (second) hypothesis implies decreasing CO 2 under the same conditions. An ocean-atmosphere-sediment model has been used to assess the response of atmospheric CO 2 and carbonate sedimentation to global perturbations in chemical weathering and decarbonation reactions. Although this assessment is theoretical and cannot yet be related to the geologic record, the model simulations compare steady-state and non-steady-state carbonate-silicate cycle response. The e-fold response time of the ‘CO 2 -weathering’ feedback mechanism is between 300 and 400 ka. The response of carbonate sedimentation is much more rapid. These response times provide a measure of the strength of steady-state assumptions, and imply that certain systematic relations are sustained throughout steady-state and non-steady-state scenarios for the carbonate-silicate cycle. The simulations suggest that feedbacks can maintain the system near a steady state, but that non-steady-state effects may contribute to long-term trends. The steady-state and uplift hypotheses are not necessarily incompatible over time scales of a few million years.

Quaternary Science Reviews

Computer simulations of large asteroid impacts into oceanic and continental sites--Preliminary results on atmospheric, cratering and ejecta dynamics

Computer simulations have been completed that describe passage of a 10-km-diameter asteroid through the Earth's atmosphere and the subsequent cratering and ejecta dynamics caused by impact of the asteroid into both oceanic and continental sites. The asteroid was modeled as a spherical body moving vertically at 20 km/s with a kinetic energy of 2.6 × 10 30 ergs (6.2 × 10 7 Mt ). Detailed material modeling of the asteroid, ocean, crustal units, sedimentary unit, and mantle included effects of strength and fracturing, generic asteroid and rock properties, porosity, saturation, lithostatic stresses, and geothermal contributions, each selected to simulate impact and geologic conditions that were as realistic as possible. Calculation of the passage of the asteroid through a U.S. Standard Atmosphere showed development of a strong bow shock wave followed by a highly shock compressed and heated air mass. Rapid expansion of this shocked air created a large low-density region that also expanded away from the impact area. Shock temperatures in air reached ∼20, 000K near the surface of the uplifting crater rim and were as high as ∼2000K at more than 30 km range and 10 km altitude. Calculations to 30 s showed that the shock fronts in the air and in most of the expanding shocked air mass preceded the formation of the crater, ejecta, and rim uplift and did not interact with them. As cratering developed, uplifted rim and target material were ejected into the very low density, shock-heated air immediately above the forming crater, and complex interactions could be expected. Calculations of the impact events showed equally dramatic effects on the oceanic and continental targets through an interval of 120 s. Despite geologic differences in the targets, both cratering events developed comparable dynamic flow fields and by ∼29s had formed similar-sized transient craters ∼39km deep and ∼62km across. Transient-rim uplift of ocean and crust reached a maximum altitude of nearly 40 km at ∼30s and began to decay at velocities of 500 m/s to develop large-tsunami conditions. After ∼30s, strong gravitational rebound drove both craters toward broad flat-floored shapes. At 120 s, transient crater diameters were ∼80km (continental) and ∼105km (oceanic) and transient depths were ∼27km; crater floors consisting of melted and fragmented hot rock were rebounding rapidly upward. By 60 s, the continental crater had ejected ∼2 × 10 14 t, about twice the mass ejected from the oceanic crater. By 120 s, ∼70, 000km 3 (continental) and ∼90, 000km 3 (oceanic) target material were excavated (no mantle) and massive ejecta blankets were formed around the craters. We estimate that in excess of ∼70% of the ejecta would finally lie within ∼3 crater diameters of the impact, and the remaining ejecta (∼10 13 t), including the vaporized asteroid, would be ejected into the atmosphere to altitudes as high as the ionosphere. Effects of secondary volcanism and return of the ocean over hot oceanic crater floor could also be expected to contribute substantial material to the atmosphere.

International Journal of Impact Engineering

AVO-G2S: A modified, open-source Ground-to-Space atmospheric specification for infrasound modeling

To facilitate infrasound propagation studies, we present AVO-G2S, an open-source, Ground-to-Space model which provides temperature and wind specifications from the surface to an altitude of 225 km. This model provides a means of smoothly characterizing atmospheric conditions using multiple numerical weather prediction forecast and reanalysis products, along with upper-atmospheric empirical models. Regional atmospheric reconstructions only require a limited domain and can utilize high-resolution numerical weather prediction forecasts typically provided on a projected grid. The use of a projected grid allows for faster spectral transform libraries to be employed. The AVO-G2S software can also provide global reconstructions that rely on global numerical weather prediction products and spherical harmonic decompositions. AVO-G2S is inspired by a global Ground-to-Space model developed by the Naval Research Laboratory, and relies on their empirical descriptions of upper-atmospheric conditions. Alaska Volcano Observatory has implemented this model for near-real-time infrasound monitoring of volcanic eruptions and historical research projects.

Computers & Geosciences

Historical trends in occurrence and atmospheric inputs of halogenated volatile organic compounds in untreated ground water used as a source of drinking water

Analyses of samples of untreated ground water from 413 community-, non-community- (such as restaurants), and domestic-supply wells throughout the US were used to determine the frequency of detection of halogenated volatile organic compounds (VOCs) in drinking-water sources. The VOC data were compiled from archived chromatograms of samples analyzed originally for chlorofluorocarbons (CFCs) by purge-and-trap gas chromatography with an electron-capture detector (GC-ECD). Concentrations of the VOCs could not be ascertained because standards were not routinely analyzed for VOCs other than trichloromonofluoromethane (CFC-11), dichlorodifluoromethane (CFC-12) and 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113). Nevertheless, the peak areas associated with the elution times of other VOCs on the chromatograms can be classified qualitatively to assess concentrations at a detection limit on the order of parts per quadrillion. Three or more VOCs were detected in 100% (percent) of the chromatograms, and 77.2% of the samples contained 10 or more VOCs. The maximum number of VOCs detected in any sample was 24. Modeled ground-water residence times, determined from concentrations of CFC-12, were used to assess historical trends in the cumulative occurrence of all VOCs detected in this analysis, as well as the occurrence of individual VOCs, such as CFC-11, carbon tetrachloride (CCl 4 ), chloroform and tetrachloroethene (PCE). The detection frequency for all of the VOCs detected has remained relatively constant from approximately 1940 to 2000; however, the magnitude of the peak areas on the chromatograms for the VOCs in the water samples has increased from 1940 to 2000. For CFC-11, CCl 4 , chloroform and PCE, small peaks decrease from 1940 to 2000, and large peaks increase from 1940 to 2000. The increase in peak areas on the chromatograms from analyses of more recently recharged water is consistent with reported increases in atmospheric concentrations of the VOCs. Approximately 44% and 6.7% of the CCl 4 and PCE detections, respectively, in pre-1940 water, and 68% and 62% of the CCl 4 and PCE detections, respectively, in water recharged in 2000 exceed solubility equilibrium with average atmospheric concentrations. These exceedences can be attributed to local atmospheric enrichment or direct contaminant input to ground-water flow systems. The detection of VOCs at concentrations indicative of atmospheric sources in 100% of the samples indicates that untreated drinking water from ground-water sources in the US recharged within the past 60 years has been affected by anthropogenic activity. Additional inputs from a variety of sources such as spills, underground injections and leaking landfills or storage tanks increasingly are providing additional sources of contamination to ground water used as drinking-water sources.

Science of the Total Environment

Atmospheric mercury speciation in Yellowstone National Park

Atmospheric concentrations of elemental mercury (Hg 0 ), reactive gaseous Hg (RGM), and particulate Hg (pHg) concentrations were measured in Yellowstone National Park (YNP), U.S.A. using high resolution, real time atmospheric mercury analyzers (Tekran 2537A, 1130, and 1135). A survey of Hg 0 concentrations at various locations within YNP showed that concentrations generally reflect global background concentrations of 1.5–2.0 ng m − 3 , but a few specific locations associated with concentrated geothermal activity showed distinctly elevated Hg 0 concentrations (about 9.0 ng m − 3 ). At the site of intensive study located centrally in YNP (Canyon Village), Hg 0 concentrations did not exceed 2.5 ng m − 3 ; concentrations of RGM were generally below detection limits of 0.88 pg m − 3 and never exceeded 5 pg m − 3 . Concentrations of pHg ranged from below detection limits to close to 30 pg m −3 . RGM and pHg concentrations were not correlated with any criteria gases (SO 2 , NO x , O 3 ); however pHg was weakly correlated with the concentration of atmospheric particles. We investigated three likely sources of Hg at the intensive monitoring site: numerous geothermal features scattered throughout YNP, re-suspended soils, and wildfires near or in YNP. We examined relationships between the chemical properties of aerosols (as measured using real time, single particle mass spectrometry; aerosol time-of-flight mass spectrometer; ATOFMS) and concentrations of atmospheric pHg. Based on the presence of particles with distinct chemical signatures of the wildfires, and the absence of signatures associated with the other sources, we concluded that wildfires in the park were the main source of aerosols and associated pHg to our sampling site.

Science of the Total Environment

Additions of nutrients and major ions by the atmosphere and tributaries to nearshore waters of northwestern Lake Huron

Nutrient additions by the atmosphere and six tributaries to nearshore waters of northwestern Lake Huron were measured at weekly intervals from August 1975 to July 1976. The atmosphere contributed 43% of the nitrogen (N) and 10% of the phosphorus (P) that was added during the year. The 1975–76 atmospheric loading rate of total N to this area (11 kg/ha/yr) was one of the highest found to date in the United States. N was conserved more efficiently than P in the tributary drainage basins. Of the N and P that fell annually on the watersheds under study, 2 to 37% of the N and 31 to 84% of the P was carried with runoff to the lake. From a basin where ditching and clear-cutting occurred, water, P, silica (SiO 2 ), N, and sodium were lost at higher rates than from five other basins. Most of the N in bulk atmospheric samples (23%) and tributary waters (56%) was dissolved organic N, a form of N not often measured.

Michigan

Decreased atmospheric sulfur deposition across the southeastern U.S.: When will watersheds release stored sulfate?

Emissions of sulfur dioxide (SO 2 ) to the atmosphere lead to atmospheric deposition of sulfate (SO 4 2- ), which is the dominant strong acid anion causing acidification of surface waters and soils in the eastern United States (U.S.). Since passage of the Clean Air Act and its Amendments, atmospheric deposition of SO 2 in this region has declined by over 80%, but few corresponding decreases in stream-water SO 4 2- concentrations have been observed in unglaciated watersheds. We calculated SO 4 2- mass balances for 27 forested, unglaciated watersheds from Pennsylvania to Georgia, by using total atmospheric deposition (wet plus dry) as input. Many of these watersheds still retain SO 4 2- , unlike their counterparts in the northeastern U.S. and southern Canada. Our analysis showed that many of these watersheds should convert from retaining to releasing SO 4 2- over the next two decades. The specific years when the watersheds crossover from retaining to releasing SO 4 2- correspond to a general geographical pattern of later net watershed release from north to south. The single most important variable that explained the crossover year was the runoff ratio, defined as the ratio of annual mean stream discharge to precipitation. Percent clay content and mean soil depth were secondary factors in predicting crossover year. The conversion of watersheds from net SO 4 2- retention to release anticipates more widespread reductions in stream-water SO 4 2- concentrations in this region.

Environmental Science & Technology

African desert dust in the Caribbean atmosphere: Microbiology and public health

Air samples collected on St. John in the U.S. Virgin Islands were screened for the presence of viable bacteria and fungi to determine if the number of cultivatable microbes in the atmosphere differed between "clear atmospheric conditions" and "African dust-events." Results indicate that during "African dust-events," the numbers of cultivatable airborne microorganisms can be 2 to 3 times that found during "clear atmospheric conditions." Direct microbial counts of air samples using an epifluorescent microscopy assay demonstrated that during an "African dust-event," bacteria-like and virus-like particle counts were approximately one log greater than during "clear atmospheric conditions." Bacteria-like particles exhibiting autofluoresence, a trait of phototrophs, were only detected during an "African dust-event.".

Aerobiologia

Dust in the wind: long range transport of dust in the atmosphere and its implications for global public and ecosystem health

Movement of soil particles in atmospheres is a normal planetary process. Images of Martian dust devils (wind-spouts) and dust storms captured by NASA's Pathfinder have demonstrated the significant role that storm activity plays in creating the red atmospheric haze of Mars. On Earth, desert soils moving in the atmosphere are responsible for the orange hues in brilliant sunrises and sunsets. In severe dust storm events, millions of tons of soil may be moved across great expanses of land and ocean. An emerging scientific interest in the process of soil transport in the Earth's atmosphere is in the field of public and ecosystem health. This article will address the benefits and the potential hazards associated with exposure to particle fallout as clouds of desert dust traverse the globe.

Global Change and Human Health

Exploring Martian polar atmospheric circulation and surface interactions

The northern and southern seasonal polar caps of Mars are formed in the polar night, during their respective autumn and winter seasons, by the condensation of atmospheric CO 2 directly to the solid phase as ice, snow, and possibly frost. During spring and summer, the seasonal ice sublimes, returning CO 2 to the atmosphere. The caps advance and recede in response to seasonal variations in solar insolation, extending as far as 40° from the poles, and have been noted by telescopic observers since the 17th century Roughly 25% of the atmosphere, which is 95% CO 2 by volume, is cycled into and out of the seasonal caps. The CO 2 cycle dominates atmospheric circulation on Mars, and must be thoroughly understood in order to answer fundamental questions about climate history and the global distribution of near‐surface water.

Eos, Transactions, American Geophysical Union

Climatically driven loss of calcium in steppe soil as a sink for atmospheric carbon

During the last several thousand years the semi-arid, cold climate of the Russian steppe formed highly fertile soils rich in organic carbon and calcium (classified as Chernozems in the Russian system). Analysis of archived soil samples collected in Kemannaya Steppe Preserve in 1920, 1947, 1970, and fresh samples collected in 1998 indicated that the native steppe Chernozems, however, lost 17-28 kg m-2 of calcium in the form of carbonates in 1970-1998. Here we demonstrate that the loss of calcium was caused by fundamental shift in the steppe hydrologic balance. Previously unleached soils where precipitation was less than potential evapotranspiration are now being leached due to increased precipitation and, possibly, due to decreased actual evapotranspiration. Because this region receives low levels of acidic deposition, the dissolution of carbonates involves the consumption of atmospheric CO2. Our estimates indicate that this climatically driven terrestrial sink of atmospheric CO2 is ???2.1-7.4 g C m-2 a-1. In addition to the net sink of atmospheric carbon, leaching of pedogenic carbonates significantly amplified seasonal amplitude of CO2 exchange between atmosphere and steppe soil. Copyright 2008 by the American Geophysical Union.

Global Biogeochemical Cycles

Atmospheric bromine flux from the coastal Abu Dhabi sabkhat: A ground-water mass-balance investigation

A solute mass-balance study of ground water of the 3000 km2 coastal sabkhat (salt flats) of the Emirate of Abu Dhabi, United Arab Emirates, documents an annual bromide loss of approximately 255 metric tons (0.0032 Gmoles), or 85 kg/km2. This value is an order of magnitude greater than previously published direct measurements from the atmosphere over an evaporative environment of a salar in Bolivia. Laboratory evidence, consistent with published reports, suggests that this loss is by vapor transport to the atmosphere. If this bromine flux to the atmosphere is representative of the total earth area of active salt flats then it is a significant, and generally under recognized, input to the global atmospheric bromide flux.

Geophysical Research Letters

Coupled atmosphere-ocean-wave simulations of a storm event over the Gulf of Lion and Balearic Sea

The coastal areas of the North-Western Mediterranean Sea are one of the most challenging places for ocean forecasting. This region is exposed to severe storms events that are of short duration. During these events, significant air-sea interactions, strong winds and large sea-state can have catastrophic consequences in the coastal areas. To investigate these air-sea interactions and the oceanic response to such events, we implemented the Coupled Ocean-Atmosphere-Wave-Sediment Transport Modeling System simulating a severe storm in the Mediterranean Sea that occurred in May 2010. During this event, wind speed reached up to 25 m.s-1 inducing significant sea surface cooling (up to 2°C) over the Gulf of Lion (GoL) and along the storm track, and generating surface waves with a significant height of 6 m. It is shown that the event, associated with a cyclogenesis between the Balearic Islands and the GoL, is relatively well reproduced by the coupled system. A surface heat budget analysis showed that ocean vertical mixing was a major contributor to the cooling tendency along the storm track and in the GoL where turbulent heat fluxes also played an important role. Sensitivity experiments on the ocean-atmosphere coupling suggested that the coupled system is sensitive to the momentum flux parameterization as well as air-sea and air-wave coupling. Comparisons with available atmospheric and oceanic observations showed that the use of the fully coupled system provides the most skillful simulation, illustrating the benefit of using a fully coupled ocean-atmosphere-wave model for the assessment of these storm events.

Journal of Geophysical Research

Equilibrium responses of global net primary production and carbon storage to doubled atmospheric carbon dioxide: Sensitivity to changes in vegetation nitrogen concentration

We ran the terrestrial ecosystem model (TEM) for the globe at 0.5° resolution for atmospheric CO 2 concentrations of 340 and 680 parts per million by volume (ppmv) to evaluate global and regional responses of net primary production (NPP) and carbon storage to elevated CO 2 for their sensitivity to changes in vegetation nitrogen concentration. At 340 ppmv, TEM estimated global NPP of 49.0 10 15 g (Pg) C yr −1 and global total carbon storage of 1701.8 Pg C; the estimate of total carbon storage does not include the carbon content of inert soil organic matter. For the reference simulation in which doubled atmospheric CO 2 was accompanied with no change in vegetation nitrogen concentration, global NPP increased 4.1 Pg C yr −1 (8.3%), and global total carbon storage increased 114.2 Pg C. To examine sensitivity in the global responses of NPP and carbon storage to decreases in the nitrogen concentration of vegetation, we compared doubled CO 2 responses of the reference TEM to simulations in which the vegetation nitrogen concentration was reduced without influencing decomposition dynamics (“lower N” simulations) and to simulations in which reductions in vegetation nitrogen concentration influence decomposition dynamics (“lower N+D” simulations). We conducted three lower N simulations and three lower N+D simulations in which we reduced the nitrogen concentration of vegetation by 7.5, 15.0, and 22.5%. In the lower N simulations, the response of global NPP to doubled atmospheric CO 2 increased approximately 2 Pg C yr −1 for each incremental 7.5% reduction in vegetation nitrogen concentration, and vegetation carbon increased approximately an additional 40 Pg C, and soil carbon increased an additional 30 Pg C, for a total carbon storage increase of approximately 70 Pg C. In the lower N+D simulations, the responses of NPP and vegetation carbon storage were relatively insensitive to differences in the reduction of nitrogen concentration, but soil carbon storage showed a large change. The insensitivity of NPP in the N+D simulations occurred because potential enhancements in NPP associated with reduced vegetation nitrogen concentration were approximately offset by lower nitrogen availability associated with the decomposition dynamics of reduced litter nitrogen concentration. For each 7.5% reduction in vegetation nitrogen concentration, soil carbon increased approximately an additional 60 Pg C, while vegetation carbon storage increased by only approximately 5 Pg C. As the reduction in vegetation nitrogen concentration gets greater in the lower N+D simulations, more of the additional carbon storage tends to become concentrated in the north temperate-boreal region in comparison to the tropics. Other studies with TEM show that elevated CO 2 more than offsets the effects of climate change to cause increased carbon storage. The results of this study indicate that carbon storage would be enhanced by the influence of changes in plant nitrogen concentration on carbon assimilation and decomposition rates. Thus changes in vegetation nitrogen concentration may have important implications for the ability of the terrestrial biosphere to mitigate increases in the atmospheric concentration of CO 2 and climate changes associated with the increases.

Global Biogeochemical Cycles

The influence of north Pacific atmospheric circulation on streamflow in the west

The annual cycle and nonseasonal variability of streamflow over western North America and Hawaii is studied in terms of atmospheric forcing elements. This study uses several decades of monthly average streamflow beginning as early as the late 1800's over a network of 38 stations. In addition to a strong annual cycle in mean streamflow and its variance at most of the stations, there is also a distinct annual cycle in the autocorrelation of anomalies that is related to the interplay between the annual cycles of temperature and precipitation. Of particular importance to these lag effects is the well-known role of water stored as snow pack, which controls the delay between peak precipitation and peak flow and also introduces persistence into the nonseasonal streamflow anomalies, with time scales from 1 month to over 1 year. The degree to which streamflow is related to winter atmospheric circulation over the North Pacific and western North America is tested using correlations with time averaged, gridded sea level pressure (SLP), which begins in 1899. Streamflow fluctuations show significant large-scale correlations for the winter (December through February) mean SLP anomaly patterns over the North Pacific with maximum correlations ranging from 0.3 to about 0.6. For streams along the west coast corridor the circulation pattern associated with positive streamflow anomalies is low pressure centered off the coast to the west or northwest, indicative of increased winter storms and an anomalous westerly-to-southwesterly wind component. For streams in the interior positive streamflow anomalies are associated with a positive SLP anomaly stationed remotely over the central North Pacific, and with negative but generally weaker SLP anomalies locally. One important influence on streamflow variability is the strength of the Aleutian Low in winter. This is represented by the familiar Pacific-North America (PNA) index and also by an index defined herein the “CNP” (Central North Pacific). This index, beginning in 1899, is taken to be the average of the SLP anomaly south of the Aleutians and the western Gulf of Alaska. Correlations between PNA or CNP and regional anomalies reflect streamflow the alternations in strength and position of the mean North Pacific storm track entering North America as well as shifts in the trade winds over the subtropical North Pacific. Regions whose streamflow is best tuned to the PNA or CNP include coastal Alaska, the northwestern United States, and Hawaii; the latter two regions have the opposite sign anomaly as the former. The pattern of streamflow variations associated with El Niño is similar, but the El Niño signal also includes a tendency for greater than normal streamflow in the southwestern United States. These indices are significantly correlated with streamflow at one to two seasons in advance of the December–August period, which may allow modestly skillful forecasts. It is important to note that streamflow variability in some areas, such as British Columbia and California, does not respond consistently to these broad scale Pacific atmospheric circulation indices, but is related to regional atmospheric anomaly features over the eastern North Pacific. Spatially, streamflow anomalies are fairly well correlated over scales of several hundred kilometers. Inspection of the spatial anomalies of stream-flow in this study suggest an asymmetry in the spatial pattern of positive versus negative streamflow anomalies in the western United States: dry patterns have tended to be larger and more spatially coherent than wet patterns.

Pacific Ocean

The influence of formation material properties on the response of water levels in wells to Earth tides and atmospheric loading

The water level in an open well can change in response to deformation of the surrounding material, either because of applied strains (tidal or tectonic) or surface loading by atmospheric pressure changes. Under conditions of no vertical fluid flow and negligible well bore storage (static-confined conditions), the sensitivities to these effects depend on the elastic properties and porosity which characterize the surrounding medium. For a poroelastic medium, high sensitivity to applied areal strains occurs for low porosity, while high sensitivity to atmospheric loading occurs for high porosity; both increase with decreasing compressibility of the solid matrix. These material properties also influence vertical fluid flow induced by areally extensive deformation and can be used to define two types of hydraulic diffusivity which govern pressure diffusion, one for applied strain and one for surface loading. The hydraulic diffusivity which governs pressure diffusion in response to surface loading is slightly smaller than that which governs fluid flow in response to applied strain. Given the static-confined response of a water well to atmospheric loading and Earth tides, the in situ drained matrix compressibility and porosity (and hence the one-dimensional specific storage) can be estimated. Analysis of the static-confined response of five wells to atmospheric loading and Earth tides gives generally reasonable estimates for material properties.

Journal of Geophysical Research Solid Earth

Isotopic composition of atmospheric hydrogen and methane

IN a recent communication, Bishop and Taylor 1 express the opinion that the tritium concentration of free hydrogen in the atmosphere has been rising over the past ten years, with a doubling time of approximately 18 months. The authors suspect that artificial tritium was released into the atmosphere several years before the Castle test series in 1954, which is commonly assumed to have led to the first pronounced rise in the tritium concentration of terrestrial surface water. Bishop and Taylor's communication includes a diagram of the logarithms of all the experimentally determined tritium values in free atmospheric hydrogen plotted against time. The plot shows that the values follow a straight line that includes the first value obtained by Faltings and Harteck 2 on atmospheric hydrogen collected in 1948.

Nature