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USGS1991

Geohydrology and ground-water resources of Philadelphia, Pennsylvania

The aquifers underlying the 134.6-square-mile city of Philadelphia are divided by the Fall Line into the unconsolidated aquifers (chiefly sand and gravel) of the Coastal Plain and the consolidated-rock aquifers (chiefly schist of the Wissahickon Formation) of the Piedmont. Ground water is present under confined and unconfined conditions. The principal units of the confined-aquifer system are the lower and middle sands of the Potomac-Raritan-Magothy aquifer system. The lower sand unit is the most productive aquifer in Philadelphia. The median yield of wells screened in the lower sand unit is 275 gal/min (gallons per minute), and yields of some wells are as high as 1,350 gal/min. The median specific capacity is 16 (gal/min)/ft (gallons per minute per foot of drawdown). The principal units of the unconsolidated unconfined-aquifer system are the upper sand unit of the Potomac-Raritan-Magothy aquifer system and the informally named Trenton gravel. The median yield of wells tapping these two undifferentiated units is 90 gal/min, and yields of some wells are as high as 1,370 gal/min. The median specific capacity is 12 (gal/min)/ft. The consolidated unconfined-aquifer system consists mainly of the Wissahickon Formation. The median yield of nondomestic wells that tap the Wissahickon Formation is 45 gal/min, and yields are as high as 350 gal/min. The median specific capacity is 0.5 (gal/min)/ft. Urbanization has considerably modified the hydrologic cycle in Philadelphia. Impervious surfaces have reduced recharge areas and evapotranspiration and have increased direct runoff. Leakage from the water-distribution system, which is supplied from the Delaware and Schuylkill Rivers, was about 60 to 72 Mgal/d (million gallons per day) in 1980. Groundwater infiltration to sewers is estimated to be as much as 135 Mgal/d when the water table is high. The potentiometric surface of the lower sand unit has been lowered substantially by pumping. By 1954, cones of depression were more than 50 ft (feet) below sea level at the U.S. Naval Base and more than 70 ft below sea level along the Delaware River northeast of the naval base. As a result of withdrawals, declining heads in the lower sand unit caused water to flow downward from the overlying unconsolidated deposits and the water table to decline below sea level along the Delaware River. Beginning in the mid1960's, ground-water withdrawals from the lower sand unit decreased, and, by 1979, water levels had risen 25 ft at the U.S. Naval Base and 45 ft farther north along the Delaware River. As of 1985, water levels in the lower sand unit were controlled largely by pumping in nearby parts of New Jersey. Urbanization also has caused substantial degradation of the quality of ground water in Philadelphia. By 1945, the quality of water in the unconfined aquifer system began to deteriorate as contaminants present at the land surface migrated down- ward. Withdrawal of water from the deeper confined aquifers caused a head decline that resulted in downward movement of contaminated water from the overlying unconfined aquifer system. Consequently, water in the confined aquifers deteriorated progressively in chemical quality so it resembles water in the unconfined aquifer system. The concentration of dissolved solids in water samples collected during 1979-80 ranged from 90 to 4,480 mg/L (milligrams per liter). The average concentration of 778 mg/L was 45 percent higher than that of samples collected during 1945-58. Water from the unconfined unconsolidated aquifers generally had the highest dissolved-solids concentration. The concentration of dissolved iron in water samples collected during 197980 ranged from 0 to 220 mg/L and exceeded 0.30 mg/L in 71 percent of the samples. The average concentration of 17 mg/L was nearly 30 percent higher than that of samples collected during 1945-58. Many wells have been abandoned because of elevated iron concentrations. The concentration of dissolved manganese in water

Water Supply Paper↗

USGS1993

Characterizing the hydrogeologic framework of the Death Valley region, Southern Nevada and California

Three-dimensional (3-D) hydrogeologic modeling of the complex geology of the Death Valley region requires the application of a number of Geoscientific Information System (GSIS) techniques. This study, funded by United States Department of Energy as a part of the Yucca Mountain Project, focuses on an area of approximately 100,000 square kilometers (three degrees of latitude by three degrees of longitude) and extends up to ten kilometers in depth. The geologic conditions are typical of the Basin and Range province; a variety of sedimentary and igneous intrusive and extrusive rocks have been subjected to both compressional and extensional deformation. GSIS techniques allow the synthesis of geologic, hydrologic and climatic information gathered from many sources, including satellite imagery and published maps and cross-sections. Construction of a 3-D hydrogeological model is possible with the combined use of software products available from several vendors, including traditional GIS products and sophisticated contouring, interpolation, visualization, and numerical modeling packages.

Conference Paper↗

USGS2015

National Park Service vegetation inventory program: Mississippi National River and Recreation Area, Minnesota

The Mississippi National River and Recreation Area (MISS) vegetation mapping project is an initiative of the National Park Service (NPS) Vegetation Inventory Program (VIP) to classify and map vegetation types of MISS. (Note: “MISS” is also referred to as “park” throughout this report.) The goals of the project are to adequately describe and map vegetation types of the park and to provide the NPS Natural Resource Inventory and Monitoring (I&M) Program, resource managers, and biological researchers with useful baseline vegetation information. The MISS vegetation mapping project was officially started in spring 2012, with a scoping meeting wherein partners discussed project objectives, goals, and methods. Major collaborators at this meeting included staff from the NPS MISS, the NPS Great Lakes Network (GLKN), NatureServe, and the USGS Upper Midwest Environmental Sciences Center. The Minnesota Department of Natural Resources (DNR) was also in attendance. Common to all NPS VIP projects, the three main components of the MISS vegetation mapping project are as follows: (1) vegetation classification, (2) vegetation mapping, and (3) map accuracy assessment (AA). In this report, each of these fundamental components is discussed in detail. With the completion of the MISS vegetation mapping project, all nine park units within the NPS GLKN have received vegetation classification and mapping products from the NPS and USGS vegetation programs. Voyageurs National Park and Isle Royale National Park were completed during 1996–2001 (as program pilot projects) and another six park units were completed during 2004–11, including the Apostle Islands National Lakeshore, Grand Portage National Monument, Indiana Dunes National Lakeshore, Pictured Rocks National Lakeshore, Saint Croix National Scenic Riverway, and Sleeping Bear Dunes National Lakeshore.

Natural Resource Report↗

USGS2001

Characterization of the Mississippian chat in south-central Kansas

To understand production from low resistivity-high porosity Mississippian chat reservoirs in south-central Kansas it is necessary to understand the nature of deposition and diagenesis, how tectonics is a factor, the lithofacies controls on petrophysical properties, and log response to these properties. The initial mudstones to sponge-spicule wacke-packstones were deposited in transgressive-regressive (T-R) cycles on a shelf to shelf margin setting, resulting in a series of shallowing-upward cycles. Sponge-spicule content appears to increase upward with increasing cycle thickness. After early silicification, inter- and post-Mississippian subaerial exposure resulted in further diagenesis, including sponge-spicule dissolution, vuggy porosity development in moldic-rich rocks, and autobrecciation. Meteoric water infiltration is limited in depth below the exposure surface and in distance downdip into unaltered, cherty Cowley Formation facies. Areas of thicker preserved chat and increased diagenesis can be correlated with structural lineaments and, in some areas, with recurrent basement block movement. Combination of folding or block fault movement prior to or during development of the basal Pennsylvanian unconformity, sponge-spicule concentration, and possibly thickness of overlying bioclastic wacke-grainstones resulted in variable reservoir properties and the creation of pods of production separated by nonproductive cherty dolomite mudstones. These events also resulted in alteration of the depositional cycles to produce a series of lithofacies that exhibit unique petrophysical properties. From bottom to top in a complete cycle seven lithofacies are present: (1) argillaceous dolomite mudstone, (2) argillaceous dolomite mudstone that has chert nodules, (3) clean dolomite mudstone that has nodular chert, (4) nodular to bedded chert, (5) autoclastic chert, (6) autoclastic chert that has clay infill, and (7) bioclastic wacke-grainstone. The uppermost cycle was terminated by another lithofacies, a chert conglomerate of Mississippian and/or Pennsylvanian age. The chert facies exhibit porosities ranging from 25 to 50% and permeabilities greater than 5 md. The (Begin page 86) cherty dolomite mudstones, argillaceous dolomite mudstones, and bioclastic wacke-grainstones exhibit nonreservoir properties. Reservoir production, numerical simulation, and whole core data indicate fracturing can be present in chat reservoirs and can enhance permeability by as much as an order of magnitude. Capillary pressure data indicate the presence of microporosity and can explain high water saturations and low resistivity observed in wire-line logs. Relative permeabilities to oil decrease rapidly for saturations greater than 60% and may be influenced by dual pore systems. Archie cementation exponents increase from 1.8 for mudstones to more than 2.5 in the cherts that have increasing sponge-spicule mold and vug content. Detailed modified Pickett plot analysis of logs reveals critical aspects of chat character and can provide reliable indices of reservoir properties and pay delineation. Models developed provide additional insight into the chat of south-central Kansas and understanding of the nature of controls on shallow-shelf chert reservoir properties.

Kansas↗

USGS1964

Ground water east of Jackson Lake, Grand Teton National Park, Wyoming

The project area, which lies east of and adjacent to Jackson Lake is on the downthrown eastern block of the Teton fault, a normal fault that trends northward along the west edge of Jackson Lake. Rocks of pre-Cretaceous age are deeply buried beneath this area. Sedimentary rocks of Cretaceous age and sedimentary and volcanic rocks of Tertiary age, which have an aggregate thickness of about 30,000 feet, are exposed in the northern and eastern parts of the area. Along most of the east side of Jackson Lake, unconsolidated glacial and interglacial deposits of Quaternary age overlie the rocks of Cretaceous and Tertiary age. The unconsolidated deposits were penetrated by test drilling to a depth of 206 feet, but the maximum thickness is probably much greater. Test wells were drilled in five localities to evaluate the deposits of Quaternary age as possible sources of ground water for National Park Service facilities. In the Pilgrim Creek valley, test wells were capable of yielding 200 gpm (gallons per minute); properly constructed production wells could obtain much greater yields. Test wells at Lizard Point and Jackson Lake Campgrounds yielded more than 100 gpm, and a test well near the confluence of the Buffalo Fork and Snake rivers yielded 30 gpm. A test hole drilled in the NW1/4 sec. 36, T. 46 N., R. 115 W., was dry at 200 feet. Unconsolidated deposits of Quaternary age are the most promising source of additional ground water. Because of the extreme range in grain size and sorting, these deposits vary greatly in permeability. Their saturated thickness ranges from 0 to more than 130 feet and changes seasonally; variations of as much as 36 feet were measured (1961-62) in the Pilgrim Creek valley. In most localities where deposits of Quaternary age are ,present, small to moderate ground-water supplies can be developed; larger ground-water supplies can be developed in parts of the Pilgrim Creek valley. One well taps the Bivouac Formation of Late Pliocene or Pleistocene age, but no other wells are known to tap rocks of possible pre-Quaternary age. The Harebell Formation and Bacon Ridge Sandstone of Late Cretaceous age and the Bivouac Formation offer the best possibilities for development of additional water supplies from the consolidated rocks. Chemical analyses of water samples from 11 wells in the deposits of Quaternary age and 1 well in the Bivouac Formation indicate that the water is of generally good quality for drinking and most other purposes. Water from one well tapping lacustrine(?) sand had a dissolved-solids content of 321 ppm (parts per million); all other samples had from 87 to 145 ppm.

Wyoming↗

USGS2004

Hyperspectral analysis of the ultramafic complex and adjacent lithologies at Mordor, NT, Australia

The Mordor Complex consists of a series of potassic ultramafic rocks which were intruded into Proterozoic felsic gneisses and amphibolite and are overlain by quartzite and unconsolidated deposits. In situ and laboratory 0.4 to 2.5 ??m reflectance spectra show Al-OH absorption features caused by absorption in muscovite, kaolinite, and illite/smectite in syenite, granitic gneiss, quartzite and unconsolidated sedimentary deposits, and Fe,Mg-OH features due to phlogopite, biotite, epidote, and hornblende in the mafic and ultramafic rocks. Ferrous-iron absorption positioned near 1.05 ??m is most intense in peridotite reflectance spectra. Ferric-iron absorption is intense in most of the felsic lithologies. HyMap data were recorded in 126 narrow bands from 0.43 to 2.5 ??m along a 7-km-wide swath with approximately 6-m spatial resolution. Correction of the data to spectral reflectance was accomplished by reference to in situ measurements of an extensive, alluvial plain. Spectral classes for matched filter processing were selected by using the pixel purity index procedure and analysis of in situ and laboratory spectra. Considering the spatial distribution of the resulting 14 classes, some classes were combined, which produced eight classes characterized by Al-OH absorption features, and three Fe,Mg-OH absorption-feature classes. Comparison of the distribution of these 11 spectral classes to a generalized lithologic map of the study area shows that the spectral distinction among the eight Al-OH classes is related to variations in primary lithology, weathering products, and vegetation density. Quartzite is represented in three classes, syenite corresponds to a single scattered class, quartz-muscovite-biotite schist defines a single very coherent class, and unconsolidated sediments are portrayed in four classes. The three mafic-ultramafic classes are distinguished on the basis of generally intense Fe,Mg-OH and ferrous-iron absorption features. A single class represents the main Mordor ultramafic mass. Epidote-bearing rocks define another class, which corresponds to biotite gneiss and, in the southern part of the area, to fracture zones. The third class, which exhibits Al-OH, as well as Fe,Mg-OH features, represents hornblende gneiss and other mafic gneisses. These results indicate the importance of analyzing the VNIR and SWIR spectral shape and albedo, as well as analyzing specific spectral features, for mapping lithologic units in this weathered terrain. ?? 2004 Elsevier Inc. All rights reserved.

Remote Sensing of Environment↗

USGS2008

Breeding phenology and reproductive success of the Brandt's Cormorant at three nearshore colonies in central California, 1997-2001

Brandt's Cormorant ( Phalacrocorax penicillatus ) breeding effort, phenology and success were studied in 1997-2001 at three colonies spanning approximately 200 km of the central California coast: Point Reyes (PR); Devil's Slide Rock and Mainland (DS); and Castle-Hurricane Colony Complex (CH). Breeding effort was reduced at all three colonies in the 1998 El Niño event. Mean clutch initiation dates differed significantly among colonies, with cormorants at the southernmost colony (CH) laying earliest, and those at the northernmost colony (PR) laying latest. Productivity at individual colonies varied greatly among years (range 0.7-2.5 fledglings per pair). Overall colony means were lowest (1.6 fledglings/pair) during the 1998 El Niño event and highest (2.5 fledglings/pair) in the 1999 La Niña event. Productivity at CH (1.7 fledglings/pair) was significantly lower than at PR (2.2 fledglings/pair), and interannual variation was greatest at CH. Late-nesting birds laid fewer eggs, hatched fewer chicks, and fledged fewer chicks per pair than early-nesters. The rapid rate of growth at some nearshore colonies in central California suggests immigration from elsewhere, most likely the large offshore colony at the South Farallon Islands. Variation in timing of breeding and reproductive success among colonies demonstrates a value in maintaining multiple study locations when assessing Brandt's Cormorant population parameters in the California Current System.

Waterbirds↗

USGS1997

Geologic age: using radioactive decay to determine geologic age

At the close of the 18th century, the haze of fantasy and mysticism that tended to obscure the true nature of the Earth was being swept away. Careful studies by scientists showed that rocks had diverse origins. Some rock layers, containing clearly identifiable fossil remains of fish and other forms of aquatic animal and plant life, originally formed in the ocean. Other layers, consisting of sand grains winnowed clean by the pounding surf, obviously formed as beach deposits that marked the shorelines of ancient seas. Certain layers are in the form of sand bars and gravel banks -- rock debris spread over the land by streams. Some rocks were once lava flows or beds of cinders and ash thrown out of ancient volcanoes; others are portions of large masses of once-molten rock that cooled very slowly far beneath the Earth's surface. Other rocks were so transformed by heat and pressure during the heaving and buckling of the Earth's crust in periods of mountain building that their original features were obliterated.

General Information Product↗

USGS1974

Geology and mineral deposits of Churchill County, Nevada

Churchill County, in west-central Nevada, is an area of varied topography and geology that has had a rather small total mineral production. The western part of the county is dominated by the broad low valley of the Carson Sink, which is underlain by deposits of Lake Lahontan. The bordering mountain ranges to the west and south are of low relief and underlain largely by Tertiary volcanic and sedimentary units. Pre-Tertiary rocks are extensively exposed east of the Carson Sink in the Stillwater Range, Clan Alpine Mountains, Augusta Mountains, and New Pass Mountains. The eastern valleys are underlain by Quaternary alluvial and lacustrine deposits contemporaneous with the western deposits of Lake Lahontan. The eastern mountain ranges are more rugged than the western ranges and have higher relief; the eastern valleys are generally narrower.

Nevada↗

USGS2015

Geochemical and mineralogical characteristics of REE in granite-derived regolith: a model for the Southeast United States

Rare earth element (REE) ion-adsorption clay deposits are of global economic importance because they currently supply a significant portion of the world’s annual production of both light (LREE) and heavy REE (HREE). There is considerable ambiguity regarding the origin of this deposit type: The main criteria include the presence of large, generally granitic, igneous suites; long periods of intense weathering with little subsequent erosion; and evidence for mobility of REE within the regolith. Granitic rocks of the southeastern United States have been subjected to a long history of chemical weathering, comparable to that of South China, an area which contains many REE clay deposits. Detailed comparisons of weathered bedrock-soil profiles for large masses of granitic rocks as exemplified by the Stewartsville, Striped Rock, and Liberty Hill plutons, USA, indicate that REE are mobile within many regolith profiles and locally can attain grades comparable to mined deposits of South China. Primary accessory mineralogy, modal content, and element redistribution as a result of weathering are identified as distinguishing factors in mobility-related enrichment of REE in the regolith profiles. Only limited geochemical separation of REE was observed within profiles, which suggests the importance of source rock composition and mineralogy in the initial distribution of extractable REE in the regolith. Retention of extractable HREE was favored over LREE, Th and U within most of the studied profiles.

Conference Paper↗

USGS1996

Alamo megabreccia: Record of a late devonian impact in southern Nevada

The Alamo breccia is probably the most voluminous known outcropping carbonate megabreccia. It occupies ~4000 km2 across 11 mountain ranges in southern Nevada, has an average thickness of ~70 m, and contains a volume of 250+ km3. The breccia is a single bed, of early Frasnian (early Late Devonian) age, that formed in the wake of a giant slide that deposited a lower chaotic debrite, containing clasts as large as 80 × 500 m, and an upper exquisitely graded turbidite. It is anomalously intercalated with cyclic shallow-water platform carbonates of the Guilmette Formation. The Alamo breccia is interpreted as a product of the Alamo event, a nearby marine impact of an extraterrestrial object, whereby impact-generated crustal shock waves and/or marine superwaves detached the upper ~60 m of platform along a horizontal surface. Loosened bedrock slid seaward across the platform, and some of it accumulated as the lower debrite. Rock-water exchange induced landward-propagated tsunami(s), whose uprush and/or backwash deposited the upper turbidite, partly above sea level. Evidence for impact includes shockedquartz grains, an iridium anomaly, and reworked conodonts, all found only within the breccia. Because the Alamo breccia is not known outside of Nevada, and because the early Frasnian time of the Alamo event is not noted for accelerated extinctions, being ~3 m.y. before the Frasnian-Famennian impact(s) and biotic crisis, the impact was probably only of moderate size.

Nevada↗

USGS2015

Mount St. Helens: Controlled-source audio-frequency magnetotelluric (CSAMT) data and inversions

This report describes a series of geoelectrical soundings carried out on and near Mount St. Helens volcano, Washington, in 2010–2011. These soundings used a controlled-source audio-frequency magnetotelluric (CSAMT) approach (Zonge and Hughes, 1991; Simpson and Bahr, 2005). We chose CSAMT for logistical reasons: It can be deployed by helicopter, has an effective depth of penetration of as much as 1 kilometer, and requires less wire than a Schlumberger sounding. This Data Series provides the edited data for these CSAMT soundings as well as several different types of 1-D inversions (where the signal data are converted to conductivity-versus-depth models). In addition, we include a map showing station locations on and around the volcano and the Pumice Plain to the north. The apparent conductivity (or its inverse, apparent resistivity) measured by a geoelectrical system is caused by several factors. The most important of these are water-filled rock porosity and the presence of water-filled fractures; however, rock type and minerals (for instance, sulfides and clay content) also contribute to apparent conductivity. In situations with little recharge (for instance, in arid regions), variations in ionic content of water occupying pore space and fractures sampled by the measurement system must also be factored in (Wynn, 2006). Variations in ionic content may also be present in hydrothermal fluids surrounding volcanoes in wet regions. In unusual cases, temperature may also affect apparent conductivity (Keller, 1989; Palacky, 1989). There is relatively little hydrothermal alteration (and thus fewer clay minerals that might add to the apparent conductivity) in the eruptive products of Mount St. Helens (Reid and others, 2010), so conductors observed in the Fischer, Occam, and Marquardt inversion results later in this report are thus believed to map zones with significant water content. Geoelectrical surveys thus have the potential to reveal subsurface regions with significant groundwater content, including perched and regional aquifers. Reid and others (2001) and Reid (2004) have suggested that groundwater involvement may figure in both the scale and the character of some if not all volcanic edifice collapse events. Ongoing research by the U.S. Geological Survey (USGS) and others aims to better understand the contribution of groundwater to both edifice pore pressure and rock alteration as well as its direct influence on eruption processes by violent interaction with magma (Schmincke, 1998).

Washington↗

USGS2021

Reconnaissance study of the major and trace element content of bauxite deposits in the Arkansas bauxite region, Saline and Pulaski Counties, central Arkansas

The Arkansas bauxite district, which comprises about 275 square miles (710 square kilometers) of central Arkansas, produced an order of magnitude more bauxite and alumina than the other bauxite districts in the United States combined. Bauxite was mined in the region continuously from 1898 to 1982. These bauxites are laterite deposits, formed from intensive in-place weathering of the exposed surface of the Granite Mountain pluton, a Late Cretaceous batholith composed mainly of nepheline syenite and lesser amounts of syenite. Nepheline syenite was the aluminum source for the bauxite and clay deposits that blanket the pluton. The early Eocene continental sedimentary rocks that contain and overlie the bauxite deposits indicate that central Arkansas had a warm tropical environment during bauxite formation. Bauxite ores are the principal sources of aluminum. Some of the global bauxite deposits have been found to contain co-occurring metals that have essential applications in modern technologies. For example, bauxite is the largest global source of gallium (Ga), used in semiconductors, which is recovered as a byproduct of processing bauxite to recover alumina. Other critical metal commodities within some bauxites that reportedly have potential for byproduct recovery include niobium (Nb), scandium (Sc), and rare earth elements (REEs). Currently (2021), the United States is wholly dependent on imports for its supplies of bauxite for processing to produce alumina. The United States is also dependent on foreign sources of gallium, niobium, and scandium, as well for most of its domestic requirements of REEs. For these reasons, samples were collected from Arkansas bauxite deposits, associated clays, mill residue wastes (respectively referred to as red muds and black sands), and the parent nepheline syenite to determine their elemental content, with a particular focus on gallium, niobium, scandium, and REEs. Each sample was analyzed for 60 elements; these data and the methods used are published as a U.S. Geological Survey data release. The results indicate that, of the critical metals in bauxites, gallium is a potential byproduct from the central Arkansas bauxite deposits. The highest gallium concentrations occur in the raw bauxite ore, with an average concentration of 76 parts per million (ppm). Gallium partitions with alumina (the product) rather than into mine waste residues. Results indicate an average niobium content of 662 ppm in the Arkansas bauxite ores. Niobium progressively increases in concentration from parent syenite (247 ppm) to clays (315 ppm) and further from bauxite (662 ppm) to processed residues (1,075 ppm). Low concentrations of scandium were found in all samples, averaging 10 ppm or less in the parent rock (syenite), bauxite, clays, and processing residues. Modest concentrations of the light and heavy REEs were found in samples of bauxite ores, bauxitic clays and interbedded clays, syenite, and the residues of ore. The highest REE values were found in processed residues, with average concentrations of 613 ppm total light REEs and 130 ppm total heavy REEs. These concentrations suggest that additional processing to recover REEs is unlikely to be economic in the foreseeable future.

Arkansas↗

USGS2001

The Sirte Basin province of Libya; Sirte-Zelten total petroleum system

The Sirte (Sirt) Basin province ranks 13th among the world?s petroleum provinces, having known reserves of 43.1 bil-lion barrels of oil equivalent (36.7 billion barrels of oil, 37.7 tril-lion cubic feet of gas, 0.1 billion barrels of natural gas liquids). It includes an area about the size of the Williston Basin of the north-ern United States and southern Canada (?490,000 square kilome-ters). The province contains one dominant total petroleum system, the Sirte-Zelten, based on geochemical data. The Upper Cretaceous Sirte Shale is the primary hydrocarbon source bed. Reservoirs range in rock type and age from fractured Precam-brian basement, clastic reservoirs in the Cambrian-Ordovician Gargaf sandstones, and Lower Cretaceous Nubian (Sarir) Sand-stone to Paleocene Zelten Formation and Eocene carbonates commonly in the form of bioherms. More than 23 large oil fields (>100 million barrels of oil equivalent) and 16 giant oil fields (>500 million barrels of oil equivalent) occur in the province. Abstract 1 Production from both clastic and carbonate onshore reservoirs is associated with well-defined horst blocks related to a triple junc-tion with three arms?an eastern Sarir arm, a northern Sirte arm, and a southwestern Tibesti arm. Stratigraphic traps in combina-tion with these horsts in the Sarir arm are shown as giant fields (for example, Messla and Sarir fields in the southeastern portion of the province). Significant potential is identified in areas marginal to the horsts, in the deeper grabens and in the offshore area. Four assessment units are defined in the Sirte Basin prov-ince, two reflecting established clastic and carbonate reservoir areas and two defined as hypothetical units. Of the latter, one is offshore in water depths greater than 200 meters, and the other is onshore where clastic units, mainly of Mesozoic age, may be res-ervoirs for laterally migrating hydrocarbons that were generated in the deep-graben areas. The Sirte Basin reflects significant rifting in the Early Cre-taceous and syn-rift sedimentary filling during Cretaceous through Eocene time, and post-rift deposition in the Oligocene and Miocene. Multiple reservoirs are charged largely by verti-cally migrating hydrocarbons along horst block faults from Upper Cretaceous source rocks that occupy structurally low posi-tions in the grabens. Evaporites in the middle Eocene, mostly post-rift, provide an excellent seal for the Sirte-Zelten hydrocarbon system. The offshore part of the Sirte Basin is complex, with subduction occurring to the northeast of the province boundary, which is drawn at the 2,000-meter isobath. Possible petroleum systems may be present in the deep offshore grabens on the Sirte Rise such as those involving Silurian and Eocene rocks; however, potential of these systems remains speculative and was not assessed.

Bulletin↗

USGS2015

Substantial contribution of biomethylation to aquifer arsenic cycling

Microbes play a prominent role in transforming arsenic to and from immobile forms in aquifers1. Much of this cycling involves inorganic forms of arsenic2, but microbes can also generate organic forms through methylation3, although this process is often considered insignificant in aquifers4, 5, 6, 7. Here we identify the presence of dimethylarsinate and other methylated arsenic species in an aquifer hosted in volcaniclastic sedimentary rocks. We find that dimethylarsinate is widespread in the aquifer and its concentration correlates strongly with arsenite concentration. We use laboratory incubation experiments and an aquifer injection test to show that aquifer microbes can produce dimethylarsinate at rates of about 0.1% of total dissolved arsenic per day, comparable to rates of dimethylarsinate production in surface environments. Based on these results, we estimate that globally, biomethylation in aquifers has the potential to transform 100 tons of inorganic arsenic to methylated arsenic species per year, compared with the 420–1,250 tons of inorganic arsenic that undergoes biomethylation in soils8. We therefore conclude that biomethylation could contribute significantly to aquifer arsenic cycling. Because biomethylation yields arsine and methylarsines, which are more volatile and prone to diffusion than other arsenic species, we further suggest that biomethylation may serve as a link between surface and subsurface arsenic cycling.

Nature Geoscience↗

USGS2024

Spawning habitat selection and egg deposition by reintroduced Lake Sturgeon in a tributary to Cayuga Lake, NY

In June 2017, we documented the first observed spawning event by a reintroduced population of Lake Sturgeon ( Acipenser fulvescens ) in Fall Creek, a tributary to Cayuga Lake, New York, USA. This is the first observed spawning encounter of adult Lake Sturgeon since the beginning of the multi-agency Lake Sturgeon restoration effort in Cayuga Lake initiated in 1995 by the New York State Department of Environmental Conservation. Lake Sturgeon egg deposition was found specifically on substrate mainly composed of gravel sized rocks with depths and flows that made up a unique microhabitat combination within the creek which is not typical of habitat identified in other Lake Sturgeon spawning habitat studies across the Great Lakes. An estimated 810,052 ± 24,386 eggs were deposited in the sampled area of Fall Creek. The identified, potentially productive spawning microhabitat type in Fall Creek is likely to be widespread in similar tributaries around Cayuga Lake as well as small tributaries to other Finger Lakes and Lake Ontario. Ongoing research is focused on the evaluation of the extent of Finger Lakes habitat similar to that identified in Fall Creek. This microhabitat evaluation of sturgeon spawning and the broad scale landscape knowledge of tributary habitats, should support subsequent management to restore Lake Sturgeon.

New York↗

USGS2001

Geologic Map of Part of the Uinkaret Volcanic Field, Mohave County, Northwestern Arizona

The geologic map of part of the Uinkaret Volcanic Field is one product of a cooperative project between the U.S. Geological Survey, the National Park Service, and the Bureau of Land Management to provide geologic information about this part of the Grand Canyon-Parashant Canyon National Monument of Arizona. The Uinkaret Volcanic Field is a unique part of western Grand Canyon where volcanic rocks have preserved the geomorphic development of the landscape. Most of the Grand Canyon, and parts of adjacent plateaus have already been mapped. This map completes one of the remaining areas where uniform quality geologic mapping was needed. A few dozen volcanoes and lava flows within the Grand Canyon are not included in the map area, but their geologic significance to Grand Canyon development is documented by Hamblin (1994) and mapped by Billingsley and Huntoon (1983) and Wenrich and others (1997). The geologic information in this report may be useful to resource managers of the Bureau of Land Management for range management, biological, archaeological, and flood control programs. The map area lies within the Shivwits, Uinkaret, and Kanab Plateaus, which are subplateaus of the Colorado Plateaus physiographic province (Billingsley and others, 1997), and is part of the Arizona Strip north of the Colorado River. The nearest settlement is Colorado City, Arizona, about 58 km (36 mi) north of the map area (fig. 1). Elevations range from about 2,447 m (8,029 ft) at Mount Trumbull, in the northwest quarter of the map area, to about 732 m (2,400 ft) in Cove Canyon, in the southeast quarter of the map area. Vehicle access is via the Toroweap and Mount Trumbull dirt roads (fig. 1). Unimproved dirt roads traverse other parts of the area except in designated wilderness. Extra fuel, two spare tires, and extra food and water are highly recommended for travelers in this remote area. The U.S. Bureau of Land Management, Arizona Strip Field Office, St. George, Utah manages most of the area. In addition, there are 12 sections belonging to the State of Arizona, about 12 sections are private land, and several sections are within the Grand Canyon National Park and Lake Mead National Recreational Area (U.S. Department of the Interior, 1993). The private land is in Potato Valley and Lake Valley, southwest and west of Mount Trumbull, and in Whitmore Canyon and Toroweap (Tuweap) Valley. Portions of the Sawmill Mountains, Mount Logan, and Mount Trumbull areas were originally established as part of the Dixie National Forest in 1904. In 1924, Dixie National Forest land became part of the Kaibab National Forest. Then on February 13, 1974, management of this part of the Kaibab National Forest was transferred to the Bureau of Land Management, Arizona Strip Field Office (personal commun. Becky Hammond, Bureau of Land Management, 1997). Mount Logan and part of the Sawmill Mountains are now designated as the Mount Logan Wilderness Area, and Mount Trumbull is designated as the Mount Trumbull Wilderness Area. Most of the map area is now part of the new Grand Canyon-Parashant Canyon National Monument established January 11, 2000. Lower elevations within Hells Hollow, Whitmore Canyon, Toroweap Valley, and Cove Canyon support a sparse growth of sagebrush, cactus, grass, and a variety of desert shrubs. Sagebrush, grass, cactus, cliffrose bush, pinion pine, and juniper trees thrive at elevations above 1,830 m (6,000 ft). Ponderosa pine and oak forests thrive at higher elevations in the Mount Trumbull and Mount Logan areas. Surface runoff within the map area drains south towards the Colorado River through Hells Hole, Hollow, Whitmore Canyon, Toroweap Valley, and Cove Canyon. Upper Toroweap Valley, upper Hells Hollow, and Whitmore Canyon are part of the physiographic area of Grand Canyon, but are not within Grand Canyon National Park (Billingsley and others, 1997). As of January 11, 2000, these areas are now part of the new Grand Canyon-Parashant

Miscellaneous Field Studies Map↗

USGS2017

Geologic assessment of undiscovered oil and gas resources—Lower Cretaceous Albian to Upper Cretaceous Cenomanian carbonate rocks of the Fredericksburg and Washita Groups, United States Gulf of Mexico Coastal Plain and State Waters

In 2010, the U.S. Geological Survey (USGS) assessed Lower Cretaceous Albian to Upper Cretaceous Cenomanian carbonate rocks of the Fredericksburg and Washita Groups and their equivalent units for technically recoverable, undiscovered hydrocarbon resources underlying onshore lands and State Waters of the Gulf Coast region of the United States. This assessment was based on a geologic model that incorporates the Upper Jurassic-Cretaceous-Tertiary Composite Total Petroleum System (TPS) of the Gulf of Mexico basin; the TPS was defined previously by the USGS assessment team in the assessment of undiscovered hydrocarbon resources in Tertiary strata of the Gulf Coast region in 2007. One conventional assessment unit (AU), which extends from south Texas to the Florida panhandle, was defined: the Fredericksburg-Buda Carbonate Platform-Reef Gas and Oil AU. The assessed stratigraphic interval includes the Edwards Limestone of the Fredericksburg Group and the Georgetown and Buda Limestones of the Washita Group. The following factors were evaluated to define the AU and estimate oil and gas resources: potential source rocks, hydrocarbon migration, reservoir porosity and permeability, traps and seals, structural features, paleoenvironments (back-reef lagoon, reef, and fore-reef environments), and the potential for water washing of hydrocarbons near outcrop areas. In Texas and Louisiana, the downdip boundary of the AU was defined as a line that extends 10 miles downdip of the Lower Cretaceous shelf margin to include potential reef-talus hydrocarbon reservoirs. In Mississippi, Alabama, and the panhandle area of Florida, where the Lower Cretaceous shelf margin extends offshore, the downdip boundary was defined by the offshore boundary of State Waters. Updip boundaries of the AU were drawn based on the updip extent of carbonate rocks within the assessed interval, the presence of basin-margin fault zones, and the presence of producing wells. Other factors evaluated were the middle Cenomanian sea-level fall and erosion that removed large portions of platform and platform-margin carbonate sediments in the Washita Group of central Louisiana. The production history of discovered reservoirs and well data within the AU were examined to estimate the number and size of undiscovered oil and gas reservoirs within the AU. Using the USGS National Oil and Gas Assessment resource assessment methodology, mean volumes of 40 million barrels of oil, 622 billion cubic feet of gas, and 14 million barrels of natural gas liquids are the estimated technically recoverable undiscovered resources for the Fredericksburg-Buda Carbonate Platform-Reef Gas and Oil AU.

Alabama, Arkansas, Florida, Louisiana, Mississippi↗