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The question of recharge to the deep thermal reservoir underlying the geysers and hot springs of Yellowstone National Park: Chapter H in Integrated geoscience studies in Integrated geoscience studies in the Greater Yellowstone Area—Volcanic, tectonic, and hydrothermal processes in the Yellowstone geoecosystem

The extraordinary number, size, and unspoiled beauty of the geysers and hot springs of Yellowstone National Park (the Park) make them a national treasure. The hydrology of these special features and their relation to cold waters of the Yellowstone area are poorly known. In the absence of deep drill holes, such information is available only indirectly from isotope studies. The δD-δ18O values of precipitation and cold surface-water and ground-water samples are close to the global meteoric water line (Craig, 1961). δD values of monthly samples of rain and snow collected from 1978 to 1981 at two stations in the Park show strong seasonal variations, with average values for winter months close to those for cold waters near the collection sites. δD values of more than 300 samples from cold springs, cold streams, and rivers collected during the fall from 1967 to 1992 show consistent north-south and east-west patterns throughout and outside of the Park, although values at a given site vary by as much as 8 ‰ from year to year. These data, along with hot-spring data (Truesdell and others, 1977; Pearson and Truesdell, 1978), show that ascending Yellowstone thermal waters are modified isotopically and chemically by a variety of boiling and mixing processes in shallow reservoirs. Near geyser basins, shallow recharge waters from nearby rhyolite plateaus dilute the ascending deep thermal waters, particularly at basin margins, and mix and boil in reservoirs that commonly are interconnected. Deep recharge appears to derive from a major deep thermal-reservoir fluid that supplies steam and hot water to all geyser basins on the west side of the Park and perhaps in the entire Yellowstone caldera. This water (T ≥350°C; δD = –149±1 ‰) is isotopically lighter than all but the farthest north, highest altitude cold springs and streams and a sinter-producing warm spring (δD = –153 ‰) north of the Park. Derivation of this deep fluid solely from present-day recharge is problematical. The designation of source areas depends on assumptions about the age of the deep water, which in turn depend on assumptions about the nature of the deep thermal system. Modeling, based on published chloride-flux studies of thermal waters, suggests that for a 0.5- to 4-km-deep reservoir the residence time of most of the thermal water could be less than 1,900 years, for a piston-flow model, to more than 10,000 years, for a well-mixed model. For the piston-flow model, the deep system quickly reaches the isotopic composition of the recharge in response to climate change. For this model, stable-isotope data and geologic considerations suggest that the most likely area of recharge for the deep thermal water is in the northwestern part of the Park, in the Gallatin Range, where major north-south faults connect with the caldera. This possible recharge area for the deep thermal water is at least 20 km, and possibly as much as 70 km, from outflow in the thermal areas, indicating the presence of a hydrothermal system as large as those postulated to have operated around large, ancient igneous intrusions. For this model, the volume of isotopically light water infiltrating in the Gallatin Range during our sampling period is too small to balance the present outflow of deep water. This shortfall suggests that some recharge possibly occurred during a cooler time characterized by greater winter precipitation, such as during the Little Ice Age in the 15th century. However, this scenario requires exceptionally fast flow rates of recharge into the deep system. For the well-mixed model, the composition of the deep reservoir changes slowly in response to climate change, and a significant component of the deep thermal water could have recharged during Pleistocene glaciation. The latter interpretation is consistent with the recent discovery of warm waters in wells and springs in southern Idaho that have δD values 10–20 ‰ lower than the winter snow for their present-day high-level recharge. These waters have been interpreted to be Pleistocene in age (Smith and others, 2002). The well-mixed model permits a significant component of recharge water for the deep system to have δD values less negative than –150 ‰ and consequently for the deep system recharge to be closer to the caldera at a number of possible localities in the Park.

Idaho, Montana, Wyoming↗

Water quality and landscape processes of four watersheds in eastern Puerto Rico

Humid tropical regions occupy about a quarter of Earth's land surface, yet they contribute a substantially higher fraction of the water, solutes, and sediment discharged to the world's oceans. Nearly half of Earth's population lives in the tropics, and development stresses can potentially harm soil resources, water quality, and water supply and in addition increase landslide and flood hazards. Owing to Puerto Rico's steep topography, low water storage capacity, and dependence on trade-wind precipitation, the island's people, ecosystems, and water supply are vulnerable to extreme weather such as hurricanes, floods, and droughts. Eastern Puerto Rico offers a natural laboratory for separating geologic and land-cover influences from regional- and global-scale influences because of its various bedrock types and the changing land cover surrounding intact, mature forest of the Luquillo Experimental Forest. Accordingly, a multiyear assessment of hydrological and biogeochemical processes was designed to develop an understanding of the effects of these differences on local climate, streamflow, water quality, and ecosystems, and to form the basis for a long-term and event-based program of climate and hydrologic monitoring. Because infrequent, large storms play a major role in this landscape, we focused on high-runoff events, sampling 263 storms, including all major hurricanes from 1991 through 2005. The largest storms have profound geomorphic consequences, such as landslides, debris flows, deep gullying on deforested lands, excavation and suspension of sediment in stream channels, and delivery of a substantial fraction of annual stream sediment load. Large storms sometimes entrain ocean foam and spray causing high concentrations of seasalt-derived constituents in stream waters during the storm. Past deforestation and agricultural activities in the Cayaguás and Canóvanas watersheds accelerated erosion and soil loss, and this material continues to be remobilized during large storms. Nearly 5,000 routine and event samples were analyzed for parameters that allow determination of denudation rates based on suspended and dissolved loads; 860 of these samples were analyzed for a comprehensive suite of chemical constituents. The rivers studied are generally similar in water-quality characteristics, and windward or leeward aspect appears to exert a stronger influence on water quality than geology or land cover. Of samples analyzed for comprehensive chemistry and for sediment, 543 were collected at runoff rates greater than 1 millimeter per hour, 256 at rates exceeding 10 millimeters per hour, and 3 at rates exceeding 90 millimeters per hour. Streams have rarely been sampled during events with such high runoff rates. Rates of physical and chemical weathering are especially high, and physical denudation rates, forested watersheds included, are considerably greater than is expected for a steady-state system. The elevated physical erosion drives an increased particulate organic carbon flux, one that is large, important to the carbon cycle, and sustainable, because soil-carbon regeneration is rapid. The 15-year Water, Energy, and Biogeochemical Budget dataset, which includes discharge, field parameters, suspended sediment, major cations and anions, and nutrients, is available from the U.S. Geological Survey's National Water Information System (http://waterdata.usgs.gov/nwis). The dataset provides a baseline for characterizing future environmental change and will improve our understanding of the interdependencies of land, water, and biological resources and their responses to changes in climate and land use. Because eastern Puerto Rico resembles many tropical regions in terms of geology and patterns of development, implications from this study are transferable to other tropical regions facing deforestation, rapid land-use change, and climate change.

Professional Paper↗

Determining three-dimensional hydrologic processes in the eastern Snake River Plain aquifer using geochemical mass-balance modeling, Idaho National Laboratory, eastern Idaho, with contributions by Treinen, K.C.

Waste constituents discharged to the eastern Snake River Plain aquifer at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) pose risks to the water quality of the aquifer. To understand these risks, the U.S. Geological Survey, in cooperation with the DOE, used geochemical mass-balance modeling to identify three-dimensional hydrologic processes in that portion of the aquifer underlying the southwestern part of the INL that affect the movement of groundwater and waste constituents. Modeling was performed using water chemistry of 74 water samples collected from 30 wells. Fifty-four of the water samples were collected from 11 wells equipped with multilevel monitoring systems with vertically discrete sampling zones that encompass the upper 750 feet of the aquifer. Water samples from these multilevel wells were collected during 2007‒13, a period when conditions in the aquifer were approximately steady-state because there was little or no recharge from the Big Lost River. The primary source of water in groundwater at the multilevel wells during 2007‒13 was the Big Lost River. Other sources of water include groundwater from the Little Lost River valley, precipitation, and wastewater. Horizontal groundwater-flow directions appear to be similar in both the shallow and deep parts of the aquifer, and surface-water sources of water in most deep groundwater shows that groundwater moves downward. Surface-water sources of water in deep groundwater noticeably decrease within and below the Matuyama flow and associated sedimentary interbeds, which indicates that these units are semi-impermeable and retard the downward movement of groundwater.

Idaho↗

Evaluation of hydrologic processes in the eastern Snake River Plain aquifer using uranium and strontium isotopes, Idaho National Laboratory, eastern Idaho

Waste constituents discharged to the eastern Snake River Plain aquifer at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) pose risks to the water quality of the aquifer. To understand these risks, the U.S. Geological Survey, in cooperation with the DOE, is conducting geochemical studies to better understand the hydrologic processes at the INL that affect the movement of groundwater and waste constituents. In this study, we used natural uranium ( 234 U/ 238 U) and strontium ( 87 Sr/ 86 Sr) isotope ratios of surface water and groundwater to identify the sources of water, the mixing of different source waters, and the flow directions in the shallow part (upper 250 feet) of the aquifer at the INL. Samples were collected from 17 sites at and near the INL that represent the source-water contributions to the aquifer. These source-water sites included surface water, regional groundwater, and springs. Groundwater samples from 63 sites were collected at and near the INL. For all sites, sample collection dates ranged from 1979 to 2019, but groundwater samples collected at the INL are representative of wet climate cycles when the Big Lost River (BLR) was flowing onto the INL. The 234 U/ 238 U activity ratios and 87 Sr/ 86 Sr from groundwater at the INL were plotted on graphs within ternary mixing webs in which the three end members of the mixing web represented specific sources of recharge. The large number of sources of recharge required numerous mixing webs, representing various geographic locations at the INL, so that each mixing web represented an area with just three sources of recharge. Considerations for determining the sources of recharge to groundwater sites included chemical signatures in addition to 234 U/ 238 U and 87 Sr/ 86 Sr, hydrologic context, and geographic location. The mixing webs were used to estimate the percentage of recharge from specific sources to groundwater at wells. The results of this study identified groundwater from the Lemhi Range as a source of recharge to the INL, which was a previously unsuspected source of recharge. The estimated spatial distribution of recharge from the BLR and groundwater from the Lost River Range also decreased and increased, respectively, relative to the spatial distribution estimated from an earlier study. Upwelling geothermal water was identified at only one well, which indicates that the upward movement of deep groundwater to the shallow part of the aquifer is largely nonexistent. Mixing between surface water and groundwater, different groundwater recharge sources, or both is ubiquitous at the INL. Mixing of water fully explains the distribution of 234 U/ 238 U and 87 Sr/ 86 Sr in groundwater at the INL and thus renders unnecessary the hypothesis that fast and slow flow zones at the INL are required to explain the distribution of 234 U/ 238 U and 87 Sr/ 86 Sr.

Idaho↗

Channel and hillslope processes in a semiarid area, New Mexico

Ephemeral washes having drainage areas from a few acres to 5 square miles are shown by actual measurement to be accumulating sediment on the streambed. This aggradation is not apparent to the eye but is clearly shown in 7 years of annual remeasurement. A similar aggradation was in progress in the same area some 3000 years ago as evidenced by an alluvial terrace later dissected by the present channel system. At that time as well as at present, aggradation occurred even in tributary areas draining a few acres. Colluvial accumulations merge with channel deposits and blanket the valleys and tributary basins even up to a few hundred feet of the drainage divides. The present study concerned the amounts of sediment produced by different erosion processes in various physiographic positions in the drainage basins. Measurements show that by far the largest sediment source is sheet erosion operating on the small percentage of basin area near the basin divides. Mass movement, gully head extension, and channel enlargement are presently small contributors of sediment compared with sheet erosion on unrilled slopes. As in previous studies, not all of the erosion products could be accounted for by accumulations on colluvial slopes and on beds of channels. The discrepancies are attributed primarily to sediment carried completely out of the basins studied and presumably deposited somewhere downstream. Aggradation of alluvial valleys of 5 square miles area and smaller both in the present epicycle, and in prehistorical but post-glacial times in this locality, cannot be attributed to gullying or rill extension in the headwater tributaries but to sheet erosion of the most upstream margins of the basins. Studies of rainfall characteristics of the 7 years of measurement compared with previous years in the 100-year record do not provide a clear-out difference which would account for the presently observed aggradation of channels. Longer period of measurement of erosion and sedimentation will be necessary to identify what precipitation parameters govern whether the channels aggrade or degrade.

Professional Paper↗

Nutrient enrichment, phytoplankton algal growth, and estimated rates of instream metabolic processes in the Quinebaug River Basin, Connecticut, 2000-2001

A consistent and pervasive pattern of nutrient enrichment was substantiated by water-quality sampling in the Quinebaug River and its tributaries in eastern Connecticut during water years 2000 and 2001. Median total nitrogen and total phosphorus concentrations exceeded the U.S. Environmental Protection Agency?s recently recommended regional ambient water-qual-ity criteria for streams (0.71 and 0.031 milligrams per liter, respectively). Maximum total phosphorus concentrations exceeded 0.1 milligrams per liter at nearly half the sampled locations in the Quinebaug River Basin. Elevated total nitrogen and total phosphorus concentrations were measured at all stations on the mainstem of the Quinebaug River, the French River, and the Little River. Nutrient enrichment was related to municipal wastewater point sources at the sites on the mainstem of the Quinebaug River and French River, and to agricultural nonpoint nutrient sources in the Little River Basin. Nutrient enrichment and favorable physical factors have resulted in excessive, nuisance algal blooms during summer months, particularly in the numerous impoundments in the Quinebaug River system. Phytoplankton algal density as high as 85,000 cells per milliliter was measured during such nuisance blooms in water years 2000 and 2001. Different hydrologic conditions during the summers of 2000 and 2001 produced very different seston algal populations. Larger amounts of precipitation sustained higher streamflows in the summer of 2000 (than in 2001), which resulted in lower total algal abundance and inhibited the typical algal succession from diatoms to cyanobacteria. Despite this, nearly half of all seston chlorophyll-a concentrations measured during this study exceeded the recommended regional ambient stream-water-quality criterion (3.75 micrograms per liter), and seston chlorophyll-a concentrations as large as 42 micrograms per liter were observed in wastewa-ter-receiving reaches of the Quinebaug River. Estimates of primary productivity and respiration obtained from diel dissolved oxygen monitoring and from light- and dark-bottle dissolved oxygen measurements demonstrated that instream metabolic processes are consistent with a seston-algae dominant system. The highest estimated maximum primary productivity rate was 1.72 grams of oxygen per cubic meter per hour at the Quinebaug River at Jewett City during September 2001. The observed extremes in diel dissolved oxygen concentrations (less than 5 milligrams per liter) and pH (greater than 9) may periodically stress aquatic organisms in the Quinebaug River Basin.

Scientific Investigations Report↗

Hydrogeology, Chemical Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska

In 2001, the U.S. Geological Survey, as part of the National Water Quality Assessment (NAWQA) Program, initiated a topical study of Transport of Anthropogenic and Natural Contaminants (TANC) to PSW (public-supply wells). Local-scale and regional-scale TANC study areas were delineated within selected NAWQA study units for intensive study of processes effecting transport of contaminants to PSWs. This report describes results from a local-scale TANC study area at York, Nebraska, within the High Plains aquifer, including the hydrogeology and geochemistry of a 108-square-kilometer study area that contains the zone of contribution to a PSW selected for study (study PSW), and describes factors controlling the transport of selected anthropogenic and natural contaminants to PSWs. Within the local-scale TANC study area, the High Plains aquifer is approximately 75 m (meter) thick, and includes an unconfined aquifer, an upper confining unit, an upper confined aquifer, and a lower confining unit with lower confined sand lenses (units below the upper confining unit are referred to as confined aquifers) in unconsolidated alluvial and glacial deposits overlain by loess and underlain by Cretaceous shale. From northwest to southeast, land use in the local-scale TANC study area changes from predominantly irrigated agricultural land to residential and commercial land in the small community of York (population approximately 8,100). For the purposes of comparing water chemistry, wells were classified by degree of aquifer confinement (unconfined and confined), depth in the unconfined aquifer (shallow and deep), land use (urban and agricultural), and extent of mixing in wells in the confined aquifer with water from the unconfined aquifer (mixed and unmixed). Oxygen (delta 18O) and hydrogen (delta D) stable isotopic values indicated a clear isotopic contrast between shallow wells in the unconfined aquifer (hereinafter, unconfined shallow wells) and most monitoring wells in the confined aquifers (hereinafter, confined unmixed wells). Delta 18O and delta D values for a minority of wells in the confined aquifers were intermediate between those for the unconfined shallow wells and those for the confined unmixed wells. These intermediate values were consistent with mixing of water from unconfined and confined aquifers (hereinafter, confined mixed wells). Oxidation-reduction conditions were primarily oxic in the unconfined aquifer and variably reducing in the confined aquifers. Trace amounts of volatile organic compounds (VOC), particularly tetrachloroethylene (PCE) and trichloroethylene (TCE), were widely detected in unconfined shallow urban wells and indicated the presence of young urban recharge waters in most confined mixed wells. The presence of degradation products of agricultural pesticides (acetochlor and alachlor) in some confined mixed wells suggests that some fraction of the water in these wells also was the result of recharge in agricultural areas. In the unconfined aquifer, age-tracer data (chlorofluorocarbon and sulfur hexafluoride data, and tritium to helium-3 ratios) fit a piston-flow model, with apparent recharge ages ranging from 7 to 48 years and generally increasing with depth. Age-tracer data for the confined aquifers were consistent with mixing of 'old' water, not containing modern tracers recharged in the last 60 years, and exponentially-mixed 'young' water with modern tracers. Confined unmixed wells contained less than (<) 3 percent (%) young water mixed with a much larger fraction greater than or equal to (>=) 97% of old water. Confined mixed wells contained >30% young water and mean ages ranged from 12 to 14 years. Median concentrations of nitrate (as nitrogen, hereinafter, nitrate-N) were 17.3 and 16.0 mg/L (milligram per liter) in unconfined shallow urban and agricultural wells, respectively, indicating a range of likely nitrate sources. Septic systems are most numerous near the edge of the urban area and appear to be

Scientific Investigations Report↗

DayCent-Chem simulations of ecological and biogeochemical processes of eight mountain ecosystems in the United States

Atmospheric deposition of nitrogen (N) and sulfur (S) cause complex responses in ecosystems, from fertilization to forest ecosystem decline, freshwater eutrophication to acidification, loss of soil base cations, and alterations of disturbance regimes. DayCent-Chem, an ecosystem simulation model that combines ecosystem nutrient cycling and plant dynamics with aqueous geochemical equilibrium calculations, was developed to address ecosystem responses to combined atmospheric N and S deposition. It is unique among geochemically-based models in its dynamic biological cycling of N and its daily timestep for investigating ecosystem and surface water chemical response to episodic events. The model was applied to eight mountainous watersheds in the United States. The sites represent a gradient of N deposition across locales, from relatively pristine to N-saturated, and a variety of ecosystem types and climates. Overall, the model performed best in predicting stream chemistry for snowmelt-dominated sites. It was more difficult to predict daily stream chemistry for watersheds with deep soils, high amounts of atmospheric deposition, and a large degree of spatial heterogeneity. DayCent-Chem did well in representing plant and soil carbon and nitrogen pools and fluxes. Modeled stream nitrate (NO 3 - ) and ammonium (NH 4 + ) concentrations compared well with measurements at all sites, with few exceptions. Simulated daily stream sulfate (SO 4 2- ) concentrations compared well to measured values for sites where SO 4 2- deposition has been low and where SO 4 2- adsorption/desorption reactions did not seem to be important. The concentrations of base cations and silica in streams are highly dependent on the geochemistry and weathering rates of minerals in each catchment, yet these were rarely, if ever, known. Thus, DayCent-Chem could not accurately predict weathering products for some catchments. Additionally, few data were available for exchangeable soil cations or the magnitude of base cation deposition as a result of dry and fog inputs. The uncertainties related to weathering reactions, deposition, soil cation exchange capacity, and groundwater contributions influenced how well the simulated acid neutralizing capacity (ANC) and pH estimates compared to observed values. Daily discharge was well represented by the model for most sites. The chapters of this report describe the parameterization for each site and summarize model results for ecosystem variables, stream discharge, and stream chemistry. This intersite comparison exercise provided insight about important and possibly not well understood processes.

Scientific Investigations Report↗

Sand resources, regional geology, and coastal processes of the Chandeleur Islands Coastal System: An evaluation of the Breton National Wildlife Refuge

Breton National Wildlife Refuge, the Chandeleur Islands chain in Louisiana, provides habitat and nesting areas for wildlife and is an initial barrier protecting New Orleans from storms. The U.S. Geological Survey (USGS) in partnership with the University of New Orleans Pontchartrain Institute for Environmental Sciences undertook an intensive study that included (1) an analysis of island change based on historical maps and remotely sensed shoreline and topographic data; (2) a series of lidar surveys at 3- to 4-month intervals after Hurricane Katrina to determine barrier island recovery potential; (3) a discussion of sea level rise and effects on the islands; (4) an analysis of sea floor evolution and sediment dynamics in the refuge over the past 150 years; (5) an assessment of the local sediment transport and sediment resource availability based on the bathymetric and subbottom data; (6) a carefully selected core collection effort to groundtruth the geophysical data and more fully characterize the sediments composing the islands and surrounds; (7) an additional survey of the St. Bernard Shoals to assess their potential as a sand resource; and (8) a modeling study to numerically simulate the potential response of the islands to the low-intensity, intermediate, and extreme events likely to affect the refuge over the next 50 years. Results indicate that the islands have become fragmented and greatly diminished in subaerial extent over time: the southern islands retreating landward as they reorganize into subaerial features, the northern islands remaining in place. Breton Island, because maintenance of the Mississippi River-Gulf Outlet (MRGO) outer bar channel requires dredging, is deprived of sand sufficient to sustain itself. Regional sediment transport trends indicate that large storms are extremely effective in transporting sand and controlling the shoreline development and barrier island geometry. Sand is transported north and south from a divergent zone near Monkey Bayou at the southern end of the Chandeleur Islands. Numerical simulation of waves and sediment transport supports the geophysical results and indicates that vast areas of the lower shoreface are affected and are undergoing erosion during storm events, that there is little or no fair weather mechanism to rework material into the littoral system, and that as a result, there is a net loss of sediment from the system. Lidar surveys revealed that the island chain immediately after Hurricane Katrina lost about 84 percent of its area and about 92 percent of its prestorm volume. Marsh platforms that supported the islands’ sand prior to the storm were reduced in width by more than one-half. Repeated lidar surveys document that in places the shoreline has retreated about 100 m under the relatively low-energy waves since Hurricanes Katrina and Rita; however, this retreat is nonuniform. Recent high-resolution geophysical surveys of the sea floor and subsurface within 5–6 km of the Chandeleur Islands during 2006 and 2007 show that, in addition to the sand that is rebuilding portions of the island chain, a large volume of sand is contained in Hewes Point, in an extensive subtidal spit platform that has formed at the northern end of the Chandeleur Islands. Hewes Point appears to be the depositional terminus of the alongshore transport system. In the southern Chandeleurs, sand is being deposited in a broad tabular deposit near Breton Island called the southern offshore sand sheet. These two depocenters account for approximately 70 percent of the estimated sediment volume located in potential borrow sites. An additional large potential source of sand for restoration lies in the St. Bernard Shoals, which are estimated to contain approximately 200 × 10 6 m 3 of sand. Successful restoration planning for the Breton National Wildlife Refuge should mimic the natural processes of early stages of barrier island evolution including lateral transport to the flanks of the island chain from a centralized sand source that will ultimately enhance the ability of the islands to naturally build backbarrier marsh, dunes, and a continuous sandy shoreline. Barrier island sediment nourishment should be executed with the understanding that gulf shoreline erosion is inevitable but that island area can be maintained and enhanced during retreat (thus significantly prolonging the life of the island chain) with strategic sand placement.

Louisiana↗

Processes of Terrace Formation on the Piedmont of the Santa Cruz River Valley During Quaternary Time, Green Valley-Tubac Area, Southeastern Arizona

In this report we describe a series of stepped Quaternary terraces on some piedmont tributaries of the Santa Cruz River valley in southeastern Arizona. These terraces began to form in early Pleistocene time, after major basin-and-range faulting ceased, with lateral planation of basin fill and deposition of thin fans of alluvium. At the end of this cycle of erosion and deposition, tributaries of the Santa Cruz River began the process of dissection and terrace formation that continues to the present. Vertical cutting alternated with periods of equilibrium, during which streams cut laterally and left thin deposits of channel fill. The distribution of terraces was mapped and compiled with adjacent mapping to produce a regional picture of piedmont stream history in the middle part of the Santa Cruz River valley. For selected tributaries, the thickness of terrace fill was measured, particle size and lithology of gravel were determined, and sedimentary features were photographed and described. Mapping of terrace stratigraphy revealed that on two tributaries, Madera Canyon Wash and Montosa Canyon Wash, stream piracy has played an important role in piedmont landscape development. On two other tributaries, Cottonwood Canyon Wash and Josephine Canyon Wash, rapid downcutting preempted piracy. Two types of terraces are recognized: erosional and depositional. Gravel in thin erosional terraces has Trask sorting coefficients and sedimentary structures typical of streamflood deposits, replete with bar-and-swale surface topography on young terraces. Erosional-terrace fill represents the channel fill of the stream that cuts the terrace; the thickness of the fill indicates the depth of channel scour. In contrast to erosional terraces, depositional terraces show evidence of repeated deposition and net aggradation, as indicated by their thickness (as much as 20+ m) and weakly bedded structure. Depositional terraces are common below mountain-front canyon mouths where streams drop their load in response to abrupt flattening of gradients and expansion of channel banks, and they extend down the piedmont along Josephine Canyon Wash. Gravel in depositional terraces also has sorting coefficients typical of streamflood deposits. Sedimentary features in both types of terraces are consistent with deposition by flash floods in ephemeral streams, suggesting the climate was arid. Bedding and clast armor are weakly developed, clast clusters and imbrication are common, and crossbedding is generally absent. Debris-flow deposits, even near the mountain front, are surprisingly rare. On the tectonically stable piedmont of southeastern Arizona, stream piracy and climate change are the most likely agents of terrace formation. Both piracy and climate change can cause rapid changes in discharge and sediment supply, which initiate cycles of incision, lateral cutting, and aggradation. Increased stream discharge initiates downcutting, but increased sediment supply interrupts downcutting and causes streams to cut laterally and aggrade. At times, on Madera Canyon Wash and Montosa Canyon Wash, stream piracy affected stream discharge and sediment supply, but on Cottonwood Canyon Wash and Josephine Canyon Wash, only climate change could have initiated terrace cutting. Terraces probably formed during extended arid intervals when sparse vegetation and flashy stream discharge combined to increase sediment supply. In most cases, sediment supply was sufficient to promote lateral cutting but not long-term aggradation. Thus, most streams formed erosional terraces. The middle Pleistocene Josephine Canyon Wash formed a depositional terrace because it had a source of abundant unconsolidated sediment.

Scientific Investigations Report↗

Digital signal processing and interpretation of full waveform sonic log for well BP-3-USGS, Great Sand Dunes National Park and Preserve, Alamosa County, Colorado

Along the Great Sand Dunes National Park and Preserve boundary (fig. 1), 10 monitoring wells were drilled by the National Park Service in order to monitor water flow in an unconfined aquifer spanning the park boundary. Adjacent to the National Park Service monitoring well named Boundary Piezometer Well No. 3, or BP-3, the U.S. Geological Survey (USGS) drilled the BP-3-USGS well. This well was drilled from September 14 through 17, 2009, to a total depth of 99.4 meters (m) in order to acquire additional subsurface information. The BP-3-USGS well is located at lat 37 degrees 43'18.06' and long -105 degrees 43'39.30' at a surface elevation of 2,301 m. Approximately 23 m of core was recovered beginning at a depth of 18 m. Drill cuttings were also recovered. The wireline geophysical logs acquired in the well include natural gamma ray, borehole caliper, temperature, full waveform sonic, density, neutron, resistivity, and induction logs. The BP-3-USGS well is now plugged and abandoned. This report details the full waveform digital signal processing methodology and the formation compressional-wave velocities determined for the BP-3-USGS well. These velocity results are compared to several velocities that are commonly encountered in the subsurface. The density log is also discussed in context of these formation velocities.

Scientific Investigations Report↗

Vegetation of the Elwha River estuary: Chapter 8 in Coastal habitats of the Elwha River, Washington--biological and physical patterns and processes prior to dam removal

The Elwha River estuary supports one of the most diverse coastal wetland complexes yet described in the Salish Sea region, in terms of vegetation types and plant species richness. Using a combination of aerial imagery and vegetation plot sampling, we identified 6 primary vegetation types and 121 plant species in a 39.7 ha area. Most of the estuary is dominated by woody vegetation types, with mixed riparian forest being the most abundant (20 ha), followed by riparian shrub (6.3 ha) and willow-alder forest (3.9 ha). The shrub-emergent marsh transition vegetation type was fourth most abundant (2.2 ha), followed by minor amounts of dunegrass (1.75 ha) and emergent marsh (0.2 ha). This chapter documents the abundance, distribution, and floristics of these six vegetation types, including plant species richness, life form, species origin (native or introduced), and species wetland indicator status. These data will serve as a baseline to which future changes can be compared, following the impending removal of Glines Canyon and Elwha Dams upstream on the Elwha River. Dam removals may alter many of the processes, materials, and biotic interactions that influence the estuary plant communities, including hydrology, salinity, sediment and wood transport, nutrients, and plant-microbe interactions.

Washington↗

Streamflow and water-quality conditions including geologic sources and processes affecting selenium loading in the Toll Gate Creek watershed, Aurora, Arapahoe County, Colorado, 2007

Toll Gate Creek is a perennial stream draining a suburban area in Aurora, Colorado, where selenium concentrations have consistently exceeded the State of Colorado aquatic-life standard for selenium of 4.6 micrograms per liter since the early 2000s. In cooperation with the City of Aurora, Colorado, Utilities Department, a synoptic water-quality study was performed along an 18-kilometer reach of Toll Gate Creek extending from downstream from Quincy Reservoir to the confluence with Sand Creek to develop a detailed understanding of streamflow and concentrations and loads of selenium in Toll Gate Creek. Streamflow and surface-water quality were characterized for summer low-flow conditions (July–August 2007) using four spatially overlapping synoptic-sampling subreaches. Mass-balance methods were applied to the synoptic-sampling and tracer-injection results to estimate streamflow and develop spatial profiles of concentration and load for selenium and other chemical constituents in Toll Gate Creek surface water. Concurrent groundwater sampling determined concentrations of selenium and other chemical constituents in groundwater in areas surrounding the Toll Gate Creek study reaches. Multivariate principal-component analysis was used to group samples and to suggest common sources for dissolved selenium and major ions. Hydrogen and oxygen stable-isotope ratios, groundwater-age interpretations, and chemical analysis of water-soluble paste extractions from core samples are presented, and interpretation of the hydrologic and geochemical data support conclusions regarding geologic sources of selenium and the processes affecting selenium loading in the Toll Gate Creek watershed.

Colorado↗

Arsenic in New Jersey Coastal Plain streams, sediments, and shallow groundwater: effects from different geologic sources and anthropogenic inputs on biogeochemical and physical mobilization processes

Arsenic (As) concentrations in New Jersey Coastal Plain streams generally exceed the State Surface Water Quality Standard (0.017 micrograms per liter (&micro;g/L)), but concentrations seldom exceed 1 &micro;g/L in filtered stream-water samples, regardless of geologic contributions or anthropogenic inputs. Nevertheless, As concentrations in unfiltered stream water indicate substantial variation because of particle inputs from soils and sediments with differing As contents, and because of discharges from groundwater of widely varying chemistry. In the Inner Coastal Plain, streams draining to lower reaches of the Delaware River traverse As-rich glauconitic sediments of marine origin in which As contents typically are about 20 milligrams per kilogram (mg/kg) or greater. In some of these sedimentary units, As concentrations exceed the New Jersey drinking-water maximum contaminant level (5 &micro;g/L) in shallow groundwater that discharges to streams. Microbes, fueled by organic carbon beneath the streambed, reduce iron (Fe) and As, releasing As and Fe into solution in the shallow groundwater from geologic materials that likely include (in addition to glauconite) other phyllosilicates, apatite, and siderite. When the groundwater discharges to the stream, the dissolved Fe and As are oxidized, the Fe precipitates as a hydroxide, and the As sorbs or co-precipitates with the Fe. Because of the oxidation/precipitation process, dissolved As concentrations measured in filtered stream waters of the Inner Coastal Plain are about 1 &micro;g/L, but the total As concentrations (and loads) are greater, substantially amplified by As-bearing suspended sediment in stormflows. In the Outer Coastal Plain, streams draining to the Atlantic Ocean traverse quartz-rich sediments of mainly deltaic origin where the As content generally is low (<8 mg/kg). In unfiltered and filtered water samples, As concentrations typically are less than 1 &micro;g/L in the acidic stream water and groundwater of the Outer Coastal Plain, but are greater in waters from urban areas. Despite the generally small geologic contributions to Outer Coastal Plain groundwater, where wastewater inputs were indicated, concentrations of As in unfiltered shallow groundwater discharging to small urban streams exceeded the maximum contaminant level. With a history of agriculture in the New Jersey Coastal Plain, anthropogenic inputs of As, such as residues from former pesticide applications in soils, can amplify any geogenic As in runoff. Such inputs contribute to an increased total As load to a stream at high stages of flow. As a result of yet another anthropogenic influence, microbes that reduce and mobilize As beneath the streambeds are stimulated by inputs of dissolved organic carbon (DOC). Although DOC is naturally occurring, anthropogenic contributions from wastewater inputs may deliver increased levels of DOC to subsurface soils and ultimately groundwater. Arsenic concentrations may increase with the increases in pH of groundwater and stream water in developed areas receiving wastewater inputs, as As mobilization caused by pH-controlled sorption and desorption reactions are likely to occur in waters of neutral or alkaline pH (for example, Nimick and others, 1998; Barringer and others, 2007b). Because of the difference in As content of the geologic materials in the two sub-provinces of the Coastal Plain, the amount of As that is mobile in groundwater and stream water is, potentially, substantially greater in the Inner Coastal Plain than in the Outer Coastal Plain. In turn, streams within the Inner and Outer Coastal Plain can receive substantially more As in groundwater discharge from developed areas than from environments where DOC appears to be of natural origin.

New Jersey↗

Assessment of the quality of groundwater and the Little Wind River in the area of a former uranium processing facility on the Wind River Reservation, Wyoming, 1987 through 2010

In 2010, the U.S Geological Survey (USGS), in cooperation with the Wind River Environmental Quality Commission (WREQC), began an assessment of the effectiveness of the existing monitoring network at the Riverton, Wyoming, Uranium Mill Tailings Remedial Action (UMTRA) site. The USGS used existing data supplied by the U.S. Department of Energy (DOE). The study was to determine (1) seasonal variations in the direction of groundwater flow in the area of the former uranium processing facility toward the Little Wind River, (2) the extent of contaminated groundwater among the aquifers and between the aquifers and the Little Wind River, (3) whether current monitoring is adequate to establish the effectiveness of natural attenuation for the contaminants of concern, and (4) the influence of groundwater discharged from the sulfuric-acid plant on water quality in the Little Wind River.

Wyoming↗

Field trip guide to Mount St. Helens, Washington—Recent and ancient volcaniclastic processes and deposits

This field guide explores volcanic effusions, sediments, and landforms at Mount St. Helens in Washington. A detailed synopsis outlines the eruptive history of Mount St. Helens from about 300,000 years ago through 1980 and beyond. The five days in the field include about 28 stops and 12 potential stops. Exposures in valleys surrounding Mount St. Helens reveal records of diverse Pleistocene and Holocene processes including debris avalanche, lahar, huge water wave on a nearby lake, pyroclastic density currents (surge and flow), tephra fall, lava flow, the growth of domes, and Pleistocene glaciation. Many of the stops explore effects of the several catastrophes that constituted the 18 May 1980 eruption and made Mount St. Helens famous.

Washington↗

A process to estimate net infiltration using a site-scale water-budget approach, Rainier Mesa, Nevada National Security Site, Nevada, 2002–05

This report documents a process used to estimate net infiltration from precipitation, evapotranspiration (ET), and soil data acquired at two sites on Rainier Mesa. Rainier Mesa is a groundwater recharge area within the Nevada National Security Site where recharged water flows through bedrock fractures to a deep (450 meters) water table. The U.S. Geological Survey operated two ET stations on Rainier Mesa from 2002 to 2005 at sites characterized by pinyon-juniper and scrub-brush vegetative cover. Precipitation and ET data were corrected to remove measurement biases and gap-filled to develop continuous datasets. Net infiltration (percolation below the root zone) and changes in root-zone water storage were estimated using a monthly water-balance model. Site-scale water-budget results indicate that the heavily-fractured welded-tuff bedrock underlying thin (<40 centimeters) topsoil is a critical water source for vegetation during dry periods. Annual precipitation during the study period ranged from fourth lowest (182 millimeters [mm]) to second highest (708 mm) on record (record = 55 years). Annual ET exceeded precipitation during dry years, indicating that the fractured-bedrock reservoir capacity is sufficient to meet atmospheric-evaporative demands and to sustain vegetation through extended dry periods. Net infiltration (82 mm) was simulated during the wet year after the reservoir was rapidly filled to capacity. These results support previous conclusions that preferential fracture flow was induced, resulting in an episodic recharge pulse that was detected in nearby monitoring wells. The occurrence of net infiltration only during the wet year is consistent with detections of water-level rises in nearby monitoring wells that occur only following wet years.

Nevada↗

Modern landscape processes affecting archaeological sites along the Colorado River corridor downstream of Glen Canyon Dam, Glen Canyon National Recreation Area, Arizona

The landscape of the Colorado River through Glen Canyon National Recreation Area formed over many thousands of years and was modified substantially after the completion of Glen Canyon Dam in 1963. Changes to river flow, sediment supply, channel base level, lateral extent of sedimentary terraces, and vegetation in the post-dam era have modified the river-corridor landscape and have altered the effects of geologic processes that continue to shape the landscape and its cultural resources. The Glen Canyon reach of the Colorado River downstream of Glen Canyon Dam hosts many archaeological sites that are prone to erosion in this changing landscape. This study uses field evaluations from 2016 and aerial photographs from 1952, 1973, 1984, and 1996 to characterize changes in potential windblown sand supply and drainage configuration that have occurred over more than six decades at 54 archaeological sites in Glen Canyon and uppermost Marble Canyon. To assess landscape change at these sites, we use two complementary geomorphic classification systems. The first evaluates the potential for aeolian (windblown) transport of river-derived sand from the active river channel to higher elevation archaeological sites. The second identifies whether rills, gullies, or arroyos (that is, overland drainages that erode the ground surface) exist at the archaeological sites as well as the geomorphic surface, and therefore the relative base level, to which those flow paths drain. Results of these assessments are intended to aid in the management of irreplaceable archaeological resources by the National Park Service and stakeholders of the Glen Canyon Dam Adaptive Management Program.

Arizona↗