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At least 883 records · Page 49Linked to original sources

Deformation by pressure solution and grain boundary sliding in a retrograde shear zone in southern New England, USA

Alleghanian phyllonites in a shear zone in southern New England were formed by the retrogression and hydration of a high-grade Acadian pelitic schist. The retrogression was locally incomplete, resulting in both heterogeneous mineralogy and mineral compositions, and in many arrested reaction textures. These features, documented by backscattered electron and element map imaging, and by 40 Ar/ 39 Ar dating, provide a record of the processes active as the schist was converted to a phyllonite. On the margins of the shear zone relic biotite and garnet grains survive but are partially replaced by chlorite. Relic high-grade muscovite flakes containing up to 35 % paragonite (pg) also persist but are entrained in swarms of pg-poor muscovite flakes producing folia with an anastomosing network of muscovite grains of variable composition. Single crystals of pg-rich muscovite are truncated by muscovite in successively younger cross-cutting folia that contain decreasing pg contents, falling to <5% pg in the youngest folia. In the core of the shear zone all high-grade minerals are destroyed, but recrystallization continues with earlier greenschist facies folia replaced by lower grade and pg-poorer muscovite in younger folia. Muscovite grains in truncated folia are commonly kinked and selective recrystallization of muscovite in kink bands to pg-poor-compositions demonstrates that strain energy helped drive recrystallization. The boundaries of these new pg-poor muscovite folia are sharp, and truncations indicate that grain boundary sliding (GBS) involved dissolution. GBS also enabled folding by flexural slip along muscovite grain boundaries. Fold amplitudes increased as chlorite dissolved from fold limbs precipitated in fold hinges producing crescent-shaped saddle-reef-like structures. Together these observations of truncation and replacement by dissolution and precipitation demonstrate that pressure solution and GBS facilitated both the formation of the phyllonitic shear zone and slip along it.

Connecticut↗

Petrology and geochronology of Mesoproterozoic basement of the Mount Rogers area of southwestern Virginia and northwestern North Carolina: Implications for the Precambrian tectonic evolution of the southern Blue Ridge province

Results from new geologic mapping, SHRIMP U-Pb geochronology, and petrologic studies indicate that Mesoproterozoic basement in the northern French Broad massif near Mount Rogers consists of multiple, mostly granitic plutons, map- and outcrop-scale xenoliths of pre-existing crustal rocks, and remnants of formerly overlying meta-sedimentary lithologies. Zircon and titanite ages demonstrate that these rocks collectively record nearly 350 m.y. of tectonic evolution including periods of igneous intrusion at ca . 1190 to 1130 Ma (Early Magmatic Suite) and ca . 1075 to 1030 Ma (Late Magmatic Suite) and three episodes of regional metamorphism at ca . 1170 to 1140, 1070 to 1020, and 1000 to 970 Ma. The existence of ca . 1.3 Ga age crust is indicated by (1) orthogranofels of ca . 1.32 Ga age in a map-scale xenolith, (2) inherited zircons of ca . 1.33 to 1.29 Ga age in Early Magmatic Suite plutons, and (3) ca . 1.36 to 1.30 Ga age detrital zircons in meta-sedimentary lithologies. Mineral assemblages developed in amphibolites and granofelses indicate that metamorphism during both Mesoproterozoic episodes occurred at upper amphibolite- to lower granulite-facies conditions. Syn-orogenic Early Magmatic Suite plutons emplaced at ca . 1190 to 1145 Ma are characterized by high-K, variably magnesian, dominantly calc-alkalic compositions, and have trace-element characteristics indicative of continental-arc magmatic origin involving melting of thick continental crust. In contrast, ca . 1140 Ma age quartz syenite displays A-type features indicating derivation from depleted crustal sources with increased mantle input during waning stages of regional contraction. Plutons of the compositionally bimodal Late Magmatic Suite include (1) ca . 1060 Ma meta-granite with geochemical characteristics transitional between silicic rocks of arc systems and post-collisional granites of A-type lineage, and (2) ca . 1055 Ma monzodioritic rocks with A-type compositional characteristics that likely reflect derivation from fertile, mafic sources in the lower crust. Collectively, these data suggest that Mesoproterozoic rocks of the study area preserve evidence of multiple orogenic episodes that likely involved continental-arc development and deformation at ca . 1150 Ma followed by crustal thickening at ca . 1060 Ma. Field relations and geochronologic data indicate that regional uplift and sedimentation occurred at ca . 1100 Ma between the two episodes of overlapping magmatism and orogenesis. The nature and timing of Mesoproterozoic events recorded in basement rocks of the study area illustrate significant differences in the lithologic assemblages and geologic history preserved by Mesoproterozoic basement of the adjacent Shenandoah and French Broad massifs, suggesting that the Blue Ridge massifs occupied different locations within the regional Grenville-age orogen until about 1070 Ma when the effects of Ottawan-age tectonics began to affect both areas. The near ubiquity of Ottawan-age orogenic activity recorded in Mesoproterozoic rocks of the Blue Ridge, other Appalachian inliers such as the New Jersey Highlands, and the Grenville province of Canada, including the Adirondacks, suggests that these formerly disparate terranes were amalgamated to form a common, regional orogen by this time.

North Carolina, Virginia↗

New Idria serpentinite protrusion, Diablo Range, California: From upper mantle to the surface

The New Idria serpentinite body in the Coast Ranges of California is a diapir that resulted from the interaction of the migrating Mendocino trench-ridge-transform fault triple junction, transpression, metasomatic fluids, and previously subducted oceanic crust and mantle. Northward propagation of the San Andreas fault progressively eliminated the original subduction zone, allowing seawater to penetrate into the formerly subducting abyssal peridotite mantle, triggering serpentinization. The associated physical changes in density, volume, and strength yielded an expanding, buoyantly rising serpentinite protrusion, facilitated by transpression along the San Andreas fault. Sedimentary facies and intrusion of minor cross cutting syenite and alkali basalt dikes indicate that the serpentinization-driven diapir buoyantly rose and widely breached the surface by ca. 14 Ma, attending migration of the Mendocino Triple Junction past the latitude of New Idria.

California↗

Paleocene-Eocene dinoflagellate biostratigraphy in the central Delaware coastal plain

Dinoflagellate cyst palynology and lithostratigraphy from three continuously cored boreholes (Blackbird, Smyrna, and Woodland Beach), supplemented by calcareous nannofossil biostratigraphic data, were used to refine the age and correlation of three Paleocene-Eocene formations in northern Delaware: the Vincentown, Manasquan, and Shark River. Lithologic logs reveal significant facies changes in the upper Paleocene Vincentown Formation over a short distance (*9 km) southeastward, transitioning from very permeable glauconite-quartz-shell-rich sands that form the regionally important Rancocas/Aquia aquifer to much less permeable muddy sands and sandy muds. These lithologic changes represent a shift from nearshore, clear, warm-water, carbonate-rich sand shoals to mud-dominated deeper-water, offshore shelfal environments. Dinocyst assemblages including Areoligera gippingensis, Cribroperidinium giuseppei, and Stenodinium meckelfeldensis confirm the Paleogene ages and track these paleoceanographic changes from shallow coastal settings updip to neritic or outer marine settings downdip. The Vincentown Formation is unconformably overlain by the lower Eocene Manasquan Formation, which consists predominantly of silt and clay with relatively consistent lithology across the study area, representing general neritic or open marine conditions. Lithology, dinoflagellate cyst assemblages, and calcareous nannofossil data indicate that the Marlboro Clay and its record of the onset of the Paleocene-Eocene Thermal Maximum (PETM) global warming event is absent from the Paleocene-Eocene transition at these sites, with an unconformity marking the boundary between the Vincentown and Manasquan formations. The youngest unit examined, the Eocene Shark River Formation, unconformably overlies the Manasquan Formation and consists of interbedded clayey silts and sands, with dinoflagellate assemblages suggesting a return to coastal or inner neritic settings. Calcareous nannofossil zones recognized from the Woodland Beach core corroborate the depositional ages determined using dinoflagellates throughout the sequence, confirming the chronostratigraphic framework for these important coastal plain units.

Delaware↗

Leg 188 synthesis: Transitions in the glacial history of the Prydz Bay region, East Antarctica, from ODP drilling

Drilling during Leg 119 (1988) and Leg 188 (2000; Sites 1165–1167) of the Ocean Drilling Program (ODP) provides direct evidence for long- and short-term changes in Cenozoic paleoenvironments in the Prydz Bay region. Cores from across the continental margin reveal that in preglacial times the present shelf was an alluvial plain system with austral conifer woodland in the Late Cretaceous that changed to cooler Nothofagus rainforest scrub by the middle to late Eocene (Site 1166). Earliest recovered evidence of nearby mountain glaciation is seen in late Eocene–age grain textures in fluvial sands. In the late Eocene to early Oligocene, Prydz Bay permanently shifted from being a fluvio-deltaic complex to an exclusively marine continental shelf environment. This transition is marked by a marine flooding surface later covered by overcompacted glacial sediments that denote the first advance of the ice sheet onto the shelf. Cores do not exist for the early Oligocene to early Miocene, and seismic data are used to infer the transition from a shallow to normal depth prograding continental shelf with submarine canyons on the slope and channel/levees on the rise. Cores from the continental rise at Site 1165 show long-term (millions of years) early Miocene and younger decreases in sedimentation rates as well as short-term (Milankovitch periods) cyclicity between principally biogenic and terrigenous sediment supply—resulting from the cyclic presence of onshore glaciers and changes in ocean circulation. Middle Miocene transitions include rapid decreases in sedimentation rates, increased ice-rafted debris, shifts in clays and other minerals, and regional erosion of the slope and rise. These transitions may reflect enhanced glacial erosion and reduced glacial meltwater from progressively colder ice. At this time, seismic data show that depocenters began to shift from the outer continental rise to the base of the continental slope coincident with the initial stages of the glacial erosion and overdeepening of the continental shelf. During the late Miocene to early Pliocene there was a transition to greater subglacial activity on the shelf and more pronounced cyclic facies variations on the continental rise. At this time, severe glacial morphologies initiated on the shelf with the erosion of Prydz Channel and other troughs by fast-moving ice and the deposition of overcompacted glacial diamictons by slow-moving ice on adjacent banks. The Prydz trough-mouth fan also began to form with alternating deposition of debris flows (ice at shelf edge) and muddy units (reduced ice) (Site 1167). The fan also records a transition during the late Pleistocene for times younger than 780 k.y. when short-term glacial variations continued but ice reached the shelf edge only a few times. Both short-term and long-term transitions characterize the Cenozoic evolution of the Prydz Bay region from the Cretaceous nonglacial to late Neogene full-glacial paleoenvironments. These transitions are known only from ODP cores, and further insights will require additional drilling.

Prydz Bay region↗

Consolidation, triaxial shear-strength, and index-property characteristics of organic-rich sediment from the Peru continental margin: Results from Leg 112

Sites 679, 680, and 681 of the Ocean Drilling Program were drilled along an east-west transect across an organic-rich, diatomaceous, coastal upwelling facies that occurs as a shelf/slope lens along the Peru continental margin. Seven 60-cm-long, unsplit core sections from these sites were tested for consolidation, triaxial shear strength, and geotechnical index properties. The testing showed that the sediment has unusually high water content, Atterberg limits, degree of overconsolidation, compressibility, and shear strength. The sediment has unusually low density and grain specific gravity. Atterberg limits, grain specific gravity, compressibility, and apparent excess maximum past stress increase linearly with organic-carbon content, which also correlates positively with diatom content. Overconsolidation measured in these tests is probably not a result of sediment erosion or slumping, but rather the result of diagenesis or interparticle bonding by organic matter. High shear strengths were measured throughout, but particularly high relative shear strengths (as indicated by friction angles and degrees of dilatancy during shear) occur near 20 mbsf. This "crustlike" behavior is probably produced by early diagenesis (perhaps including dolotomization) within the upper 20 m, and is complemented by interlocking of diatoms.

Proceedings of the Ocean Drilling Program: Scienti↗

Off-platform Silurian sequences in the Ambler River quadrangle: A section in Geologic studies in Alaska by the U.S. Geological Survey during 1987

Lithofacies changes in coeval upper Paleozoic rocks have been used to unravel the tectonic history of northern Alaska (for example, Mayfield and others, 1983). Conodont biostratigraphy and detailed petrologic studies are now revealing facies differences in lower Paleozoic rocks that can also be used to constrain their tectono-sedimentary framework (Dumoulin and Harris, 1987). A basic element of basin analysis is the discrimination of shallow-water shelf and platform sequences from deeper water slope and basinal deposits. This report documents several new localities of deeper water, off-platform Silurian deposits in the Ambler River quadrangle and briefly outlines some of their paleogeographic implications.

Alaska↗

Stromatolite- and coated-grain-bearing carbonate rocks of the western Brooks Range: A section in Geologic studies in Alaska by the U.S. Geological Survey during 1987

Carbonate rocks characterized by locally abundant stromatolites and coated grains have been found at several localities in the Baird Mountains and Ambler River quadrangles (fig. 1). These rocks are part of a belt of metasedimentary and metaigneous rocks that constitutes the southwestern flank of the Brooks Range; all are included in the parautochthon (Schwatka sequence) of Mayfield and others (1983). The rocks have been deformed and metamorphosed to blueschist and greenschist facies, but primary textures and sedimentary structures are locally well preserved.

Alaska↗

Carboniferous and older carbonate rocks: Lithofacies, extent, and reservoir quality: Chapter CC in The oil and gas resource potential of the Arctic National Wildlife Refuge 1002 area, Alaska

Carboniferous and older carbonate rocks are potential hydrocarbon reservoir facies for four plays in the 1002 area of the Arctic National Wildlife Refuge. These rocks include several units in the pre-Carboniferous basement and the Carboniferous Lisburne Group. Data from exploratory wells west of the 1002 area, outcrops south of the 1002 area, seismic lines, and well logs are synthesized herein to infer carbonate lithofacies, extent, and reservoir character beneath the northeastern Arctic coastal plain. A chiefly shallow-water basement carbonate succession of Late Proterozoic through Early Devonian age (Katakturuk Dolomite, Nanook Limestone, and Mount Copleston Limestone) is interpreted to be present beneath much of the south-central 1002 area; it reaches 3,700 m thick in outcrop and is the primary reservoir for the Deformed Franklinian Play. A more heterogeneous lithologic assemblage of uncertain age forms basement in the northwestern part of the 1002 area; well data define three subunits that contain carbonate intervals 5- 50 m thick. These strata are prospective reservoirs for the Undeformed Franklinian Play and could also be reservoirs for the Niguanak- Aurora Play. Regional lithologic correlations suggest a Cambrian-Late Proterozoic(?) age for subunits one and two, and a slightly younger, later Cambrian-Silurian age for subunit three. Seismic and well data indicate that subunit one overlies subunit two and is overlain by subunit three. The Mississippian and Pennsylvanian Lisburne Group, a predominantly carbonate platform succession as much as 1 km thick, is projected beneath the southernmost part of the 1002 area and is a potential reservoir for the Ellesmerian Thrust-belt and Niguanak-Aurora Plays. Carbonate rocks in the 1002 area probably retain little primary porosity but may have locally well developed secondary porosity. Measured reservoir parameters in basement carbonate strata are low (porosity generally ≤ 5%; permeability ≤ 0.2 md) but drill-stem tests found locally reasonable flow rates (4,220-4,800 bpd) and, in the Flaxman Island area, recovered gas and condensate from these rocks. The Lisburne Group has produced up to 50,000 bbl of oil/ day from the Lisburne field at Prudhoe Bay. Reservoir parameters of the Lisburne in northeastern Alaska range from low (porosities ≤ 5% in most limestones) to good (porosities average 6.5-10% in some dolostones). Reservoir quality in Carboniferous and older carbonate strata in the 1002 area should be greatest where these rocks are highly fractured and (or) truncated by the Lower Cretaceous Unconformity.

Alaska↗

Heavy mineral zonation of Cretaceous and Tertiary rocks of the central area of northern Alaska

This report presents the general conclusions pertaining to the correlation of Cretaceous and Tertiary rocks in test wells and outcrops in the central area of northern Alaska (fig. 1) by means of heavy minerals. Approximately 1.000 drill and outcrop samples have been studied. In order to relate the materiel here presented to the regional geologic picture of the central area, the restored facies cross-sections A-A' and B-B' of T.G. Payne 1/ are used as a basis for the graphic presentation of the heavy mineral zonation. Section C-C' of Payne is not used because most of it lies outside the area treated in this report and because of new geological and geophysical interpretations in the Barrow area as the result of recent exploration. Instead, the heavy mineral zonation along a somewhat different section C-C' (see fig. 1) is discussed but not illustrated.

Alaska↗

Review and photogeologic evaluation of some selected anticlines in the Maybe Creek area

The following report presents in tabulated form the location, structure, and stratigraphy of various anticlines in the Maybe Creek area which are presently considered to be reasonably favorable drilling sites, References to mere complete sources of information for each anticline are listed. The accompanying diagram (Fig. 1) presents a generalized stratigraphic picture of the section that would be penetrated by a hole located on the crest of each of these structures. The zonal thicknesses, as shown in this diagram, are average figures and they probably vary from anticline to anticline within this area as they do elsewhere on the North Slope. The thickness of postulated favorable sands and also the stratigraphic horizon reached by each of the proposed 1,500-foot holes may be further affected by the postulated prezone F unconformity. It seems probable that zone E is essentially absent at Umiat. At the Weasel Creek anticline a total of approximately 1,700 feet of zone E sediments appear to be present. This is probably the complete zone E section. Thus the thickness of zone E sediments m4y vary considerably from place to place within the area west of Umiat covered by this report, and these possible variations are not shown in the diagram (Fig. 1). Interpretations of depth and thickness of favorable sands are based on the facies studies of T. G. Payne1/. Discussions presented are limited to Nanushuk Group rocks and no reference is made nor inference intended as to possible favorable stratigaphic or structural conditions in the older sedimentary rocks.

Alaska↗

Significance of tourmaline-rich rocks in the Grenville Complex of St. Lawrence County, New York

Feldspathic quartzite and metapelite of Middle Proterozic age north of Gouverneur, N.Y., contain abundant dravite-uvite (magnesian tourmaline). These rocks, more than 1,000 feet thick, are regionally metamorphosed to the upper amphibolite facies, are pyritic, and locally contain porphyroblastic scapolite. The rocks are underlain by talctremolite schist and a thick sequence of calcitic and dolomitic marble, and are overlain by quartz, calc-silicate carbonate rock, and a pyroxene scapolite unit. All rocks are part of the metasedimentary Grenville Complex. Individual tourmaline-rich layers in the quartzite are as thick as 3 cm and contain as much as 50 percent finegrained, brownish-green dravite. Subjacent talc schist contains fine-grained amber dravite, and silicated marble locally contains brown porphyroblasts of uvite. Gneissic granite, pegmatite, and migmatitic segregations cutting the tourmaline-bearing quartzite, gneisses, and schists are rich in black schorl. Tourmalines from the tourmaline-rich quartzite and other metasedimentary and metaigneous rocks were analyzed by means of an electron microprobe. The compositions of tourmalines in the North Gouverneur area are clearly a function of the bulk composition of the rock. Tourmaline compositions in the quartzite have a wide range in FeO/(Fe+MgO) ratios, from 0.15 to 0.58, which are distinct from the ratios for tourmalines in granitic and pegmatitic rocks that range from 0.55 to 0.75. Tourmalines in the area have Na2O contents that range from 0.85 to 4.25 weight percent. Aluminum in all tourmalines ranges widely from about 25 to 37 weight percent AI 2O3 . The most heterogeneous tourmaline compositions are in the quartzites, although most compositions cluster in the dravite-uvite solid solution series. Substitutions involving Na, Ca, Mg, Fe, and Al result in the following compositional schemes: Na+Fe = Al+vacancy, and Na = Ca. Such coupled substitutions probably represent valid constraints for tourmalines from North Gouverneur. The abundance of magnesian tourmaline in the metasedimentary rocks of the North Gouverneur area is comparable to that of tourmaline-rich rocks associated with sedimenthosted massive sulfide deposits for example, Sullivan Mine, British Columbia. A recently described large lead-zinc deposit at Dugald River, Australia, is associated with tourmaline- and scapolite-bearing rocks similar in many respects to those north of Gouverneur. Compared with known tourmaline compositions in the Sullivan Mine area, tourmalines from North Gouverneur have comparable FeO and MgO values. We suggest that other tourmaline components such as a low TiO2 content, variable Na/(Na + Ca + K) ratios, and the antipathetic correlation of Na and Ca might also be useful in discriminating tourmalines associated with ore deposits. Ore bodies at the nearby Balmat-Edwards mining district are in marbles associated with rocks of evaporitic origin. The boron- and scapolite-rich rocks under consideration in this study possibly also are related to an evaporite-producing environment. Similar rocks that have an evaporite origin are associated with stratabound sulfide deposits at many places.

Bulletin↗

Geologic framework of the Alaska Peninsula, southwest Alaska, and the Alaska Peninsula terrane

The Alaska Peninsula is composed of the late Paleozoic to Quaternary sedimentary, igneous, and minor metamorphic rocks that record the history of a number of magmatic arcs. These magmatic arcs include an unnamed Late Triassic(?) and Early Jurassic island arc, the early Cenozoic Meshik arc, and the late Cenozoic Aleutian arc. Also found on the Alaska Peninsula is one of the most complete nonmetamorphosed, fossiliferous, marine Jurassic sedimentary sections known. As much as 8,500 m of section of Mesozoic sedimentary rocks record the growth and erosion of the Early Jurassic island arc. A thinner, but still thick (as much as 5,400 m), sequence of Tertiary sedimentary rocks that are predominantly continental overlies the Mesozoic section. A brief regression in early Tertiary time on the Alaska Peninsula and granodiorite plutonism in the Shumagin, Semidi, and Sanak Islands was followed by deposition of fluvial and minor marine clastic strata. This was followed by deposition of transgressive marine clastic strata and initiation of the Meshik arc, shown by an areally extensive outpouring of volcanic and volcaniclastic rocks and debris between late Eocene and earliest Miocene time. Late Miocene time was marked by another brief transgression and northwest- to southeast-directed compression, followed by renewed volcanism and plutonism which initiated the modern Aleutian magmatic arc. Extensive glacial and glaciomarine deposits of late Pleistocene age create an extensive lowland physiographic province on the northwest side of the Alaska Peninsula and join isolated mountain masses to the Alaska Peninsula on the southwest. Multiple active volcanoes and volcanic peaks dominate the skyline of the Alaska Peninsula and represent the continuation of magmatic activity that has formed the Aleutian arc since late Miocene time. The Alaska Peninsula has had a long and involved history since Paleozoic time. We propose that the Paleozoic and Mesozoic rocks that constitute much of the Alaska Peninsula be called the Alaska Peninsula terrane. Using the concept of subterranes, we divide the terrane into two distinct but tectonically related subterranes: the Chignik and Iliamna subterranes, which share a limited common geologic history. The Iliamna subterrane has served at most times as a source area for the Chignik subterrane; however, some rock units are in common across the subterranes. The Iliamna and Chignik subterranes are in part separated by the Bruin Bay fault system. The Iliamna subterrane is composed of moderately deformed early Mesozoic marine sedimentary and volcanic rocks and schist, gneiss, and marble of Paleozoic(?) and Mesozoic age, and plutonic rocks of the Alaska-Aleutian Range batholith. Characteristic of the Chignik subterrane are little-deformed, shallow-marine to continental clastic sedimentary rocks ranging in age from Permian to latest Cretaceous. However, deep-marine, volcaniclastic, and calcareous rocks form important components of the older rocks in the subterrane. The two subterranes of the Alaska Peninsula terrane are characterized by radically different structural and metamorphic styles. The nonplutonic rocks of the Iliamna subterrane are characterized by metamorphism up to amphibolite-facies grade and intense folding. In the Chignik subterrane, the structural style is dominated by large, open, en echelon anticlinal structures, normal faulting, and thrust and high-angle reverse faults that have minor displacement in a northwest to southeast direction. In the Outer Shumagin and Sanak Islands, rocks assigned to the Chugach terrane are characterized structurally by tight, generally northeast-trending folds. Dips in these rocks tend to be steep, rarely less than 35&deg;, and overturned beds are locally common. The boundaries separating the Alaska Peninsula terrane from other terranes are commonly indistinct or poorly defined. A few boundaries have been defined at major faults, although the extensions of these faults are speculative through some areas. The west side of the Alaska Peninsula terrane is overlapped by Tertiary sedimentary and volcanic rocks and Quaternary deposits.

Alaska↗

Geology of the Harpers Ferry Quadrangle, Virginia, Maryland, and West Virginia

The Harpers Ferry quadrangle covers a portion of the northeast-plunging Blue Ridge-South Mountain anticlinorium, a west-verging allochthonous fold complex of the late Paleozoic Alleghanian orogeny. The core of the anticlinorium consists of high-grade paragneisses and granitic gneisses that are related to the Grenville orogeny. These rocks are intruded by Late Proterozoic metadiabase and metarhyolite dikes and are unconformably overlain by Late Proterozoic metasedimentary rocks of the Swift Run Formation and metavolcanic rocks of the Catoctin Formation, which accumulated during continental rifting of Laurentia (native North America) that resulted in the opening of the Iapetus Ocean. Lower Cambrian metasedimentary rocks of the Loudoun, Weverton, Harpers, and Antietam Formations and carbonate rocks of the Tomstown Formation were deposited in the rift-to-drift transition as the early Paleozoic passive continental margin evolved. The Short Hill fault is an early Paleozoic normal fault that was contractionally reactivated as a thrust fault and folded in the late Paleozoic. The Keedysville detachment is a folded thrust fault at the contact of the Antietam and Tomstown Formations. Late Paleozoic shear zones and thrust faults are common. These rocks were deformed and metamorphosed to greenschist-facies during the formation of the anticlinorium. The Alleghanian deformation was accompanied by a main fold phase and a regional penetrative axial plane cleavage, which was followed by a minor fold phase with crenulation cleavage. Early Jurassic diabase dikes transected the anticlinorium during Mesozoic continental rifting that resulted in the opening of the Atlantic Ocean. Cenozoic deposits that overlie the bedrock include bedrock landslides, terraces, colluvium, and alluvium.

Bulletin↗

Geologic, geochemical, and isotopic studies of a carbonate- and siliciclastic-hosted Pb-Zn deposit at Lion Hill, Vermont

Zn-, Pb-, Cu-, and Fe-bearing rocks of the Lion Hill area in western Vermont formed during the Early Cambrian by syngenetic sedimentary-exhalative and diagenetic replacement processes. Sphalerite, galena, chalcopyrite, pyrite, and, locally, magnetite form stratabound and broadly stratiform lenticular zones, -300 meters long and 25-50 meters thick, which are uneconomic at the present time. The lenses are structurally disrupted and metamorphosed to greenschist facies, probably due to the Taconic orogeny. Textural evidence suggests that mineralizing fluids permeated the sediments prior to lithification and that a dilatant fracture zone, possibly a feeder zone, contains some of the discordant veins at Lion Hill. The veins may have formed when the sediments were in a plastic, semiconsolidated state. The association of layered iron formation containing base-metal sulfide minerals provides possible lithologic evidence for syngenetic mineralization by submarine exhalative activity. Sand bars and tidal channels present in the sedimentary section could have acted as permeable pathways for movement of mineralizing fluids. The complex interlayering in the sedimentary sequence of carbonate and siliciclastic rock types having widely varying permeabilities created numerous fluid traps. Homogenization temperatures of primary and secondary inclusions in vein sphalerite range from 152&deg;C to 196&deg;C; salinities range from 11.5 to 14.0 equivalent weight percent NaCl. &delta; 34 S values of sulfides from Lion Hill vary from -25.9 to +10.0 per mil, and fall within the expected range for sulfide produced from bacteriogenic reduction of sulfate with &delta; 34 S values of 25 to 30 per mil. In addition, some pyrite probably formed from sulfate in trapped pore fluid that resulted in heavier isotopic values characteristic of more closed-system behavior. Three sphalerite samples that have heavier sulfur isotopic values may reflect a change in the source of sulfur during a later episode of mineralization, perhaps a change to a deep-seated source. Lead isotopic compositions of galenas from mineralized zones at Lion Hill range from 18.351 to 18.632 for 206 Pb/ 204 Pb, from 15.546 to 15.618 for 207 Pb/ 204 Pb, and from 38.126 to 38.496 for 208 Pb/ 204 Pb. The lead isotopic compositions of galena from Lion Hill and fluid inclusion and sulfur isotopic values for the Lion Hill sulfides are more like those of Pb-Zn-Ag deposits of Ireland than those of MVT or Appalachian-type Zn deposits. The prospect of an Irish-type sedimentary-exhalative origin for stratabound Pb-Zn deposits of the Paleozoic shelf of North America is of considerable importance to understanding the timing of mineralization relative to platform evolution and for evaluating the mineral resource potential of the region. Our study of the Lion Hill deposit indicates a potential for Irish-type Pb-Zn deposits in platform rocks of western Vermont; however, at Lion Hill they contain enrichments of Pb, Zn, and Cu rather than a Pb, Zn, and Ag association.

Vermont↗

Petroleum geology and resources of the North Caspian Basin, Kazakhstan and Russia

The North Caspian basin is a petroleum-rich but lightly explored basin located in Kazakhstan and Russia. It occupies the shallow northern portion of the Caspian Sea and a large plain to the north of the sea between the Volga and Ural Rivers and farther east to the Mugodzhary Highland, which is the southern continuation of the Ural foldbelt. The basin is bounded by the Paleozoic carbonate platform of the Volga-Ural province to the north and west and by the Ural, South Emba, and Karpinsky Hercynian foldbelts to the east and south. The basin was originated by pre-Late Devonian rifting and subsequent spreading that opened the oceanic crust, but the precise time of these tectonic events is not known. The sedimentary succession of the basin is more than 20 km thick in the central areas. The drilled Upper Devonian to Tertiary part of this succession includes a prominent thick Kungurian (uppermost Lower Permian) salt formation that separates strata into the subsalt and suprasalt sequences and played an important role in the formation of oil and gas fields. Shallow-shelf carbonate formations that contain various reefs and alternate with clastic wedges compose the subsalt sequence on the 1 basin margins. Basinward, these rocks grade into deep-water anoxic black shales and turbidites. The Kungurian salt formation is strongly deformed into domes and intervening depressions. The most active halokinesis occurred during Late Permian?Triassic time, but growth of salt domes continued later and some of them are exposed on the present-day surface. The suprasalt sequence is mostly composed of clastic rocks that are several kilometers thick in depressions between salt domes. A single total petroleum system is defined in the North Caspian basin. Discovered reserves are about 19.7 billion barrels of oil and natural gas liquids and 157 trillion cubic feet of gas. Much of the reserves are concentrated in the supergiant Tengiz, Karachaganak, and Astrakhan fields. A recent new oil discovery on the Kashagan structure offshore in the Caspian Sea is probably also of the supergiant status. Major oil and gas reserves are located in carbonate reservoirs in reefs and structural traps of the subsalt sequence. Substantially smaller reserves are located in numerous fields in the suprasalt sequence. These suprasalt fields are largely in shallow Jurassic and Cretaceous clastic reservoirs in salt dome-related traps. Petroleum source rocks are poorly identified by geochemical methods. However, geologic data indicate that the principal source rocks are Upper Devonian to Lower Permian deep-water black-shale facies stratigraphically correlative to shallow-shelf carbonate platforms on the basin margins. The main stage of hydrocarbon generation was probably in Late Permian and Triassic time, during deposition of thick orogenic clastics. Generated hydrocarbons migrated laterally into adjacent subsalt reservoirs and vertically, through depressions between Kungurian salt domes where the salt is thin or absent, into suprasalt clastic reservoirs. Six assessment units have been identified in the North Caspian basin. Four of them include Paleozoic subsalt rocks of the basin margins, and a fifth unit, which encompasses the entire total petroleum system area, includes the suprasalt sequence. All five of these assessment units are underexplored and have significant potential for new discoveries. Most undiscovered petroleum resources are expected in Paleozoic subsalt carbonate rocks. The assessment unit in subsalt rocks with the greatest undiscovered potential occupies the south basin margin. Petroleum potential of suprasalt rocks is lower; however, discoveries of many small to medium size fields are expected. The sixth identified assessment unit embraces subsalt rocks of the central basin areas. The top of subsalt rocks in these areas occurs at depths ranging from 7 to 10 kilometers and has not been reached by wells. Undiscovered resources of this unit did not rec

Bulletin↗

Petroleum geology and resources of the North Ustyurt Basin, Kazakhstan and Uzbekistan

The triangular-shaped North Ustyurt basin is located between the Caspian Sea and the Aral Lake in Kazakhstan and Uzbekistan and extends offshore both on the west and east. Along all its sides, the basin is bounded by the late Paleozoic and Triassic foldbelts that are partially overlain by Jurassic and younger rocks. The basin formed on a cratonic microcontinental block that was accreted northward to the Russian craton in Visean or Early Permian time. Continental collision and deformation along the southern and eastern basin margins occurred in Early Permian time. In Late Triassic time, the basin was subjected to strong compression that resulted in intrabasinal thrusting and faulting. Jurassic-Tertiary, mostly clastic rocks several hundred meters to 5 km thick overlie an older sequence of Devonian?Middle Carboniferous carbonates, Upper Precambrian massifs and deformed Caledonian foldbelts. The Carboniferous?Lower Permian clastics, carbonates, and volca-basement is at depths from 5.5 km on the highest uplifts to 11 nics, and Upper Permian?Triassic continental clastic rocks, pri-km in the deepest depressions. marily red beds. Paleogeographic conditions of sedimentation, Three total petroleum systems are identified in the basin. the distribution of rock types, and the thicknesses of pre-Triassic Combined volumes of discovered hydrocarbons in these sysstratigraphic units are poorly known because the rocks have been tems are nearly 2.4 billion barrels of oil and 2.4 trillion cubic penetrated by only a few wells in the western and eastern basin feet of gas. Almost all of the oil reserves are in the Buzachi Arch areas. The basement probably is heterogeneous; it includes and Surrounding Areas Composite Total Petroleum System in 2 Petroleum Geology, Resources?North Ustyurt Basin, Kazakhstan and Uzbekistan the western part of the basin. Oil pools are in shallow Jurassic and Neocomian sandstone reservoirs, in structural traps. Source rocks are absent in the total petroleum system area; therefore, the oil could have migrated from the adjacent North Caspian basin. The North Ustyurt Jurassic Total Petroleum System encompasses the rest of the basin area and includes Jurassic and younger rocks. Several oil and gas fields have been discovered in this total petroleum system. Oil accumulations are in Jurassic clastic reservoirs, in structural traps at depths of 2.5?3 km. Source rocks for the oil are lacustrine beds and coals in the continental Jurassic sequence. Gas fields are in shallow Eocene sandstones in the northern part of the total petroleum system. The origin of the gas is unknown. The North Ustyurt Paleozoic Total Petroleum System stratigraphically underlies the North Ustyurt Jurassic system and occupies the same geographic area. The total petroleum system is almost unexplored. Two commercial flows of gas and several oil and gas shows have been tested in Carboniferous shelf carbonates in the eastern part of the total petroleum system. Source rocks probably are adjacent Carboniferous deep-water facies interpreted from seismic data. The western extent of the total petroleum system is conjectural. Almost all exploration drilling in the North Ustyurt basin has been limited to Jurassic and younger targets. The underlying Paleozoic-Triassic sequence is poorly known and completely unexplored. No wells have been drilled in offshore parts of the basin. Each of three total petroleum systems was assessed as a single assessment unit. Undiscovered resources of the basin are small to moderate. Most of the undiscovered oil probably will be discovered in Jurassic and Neocomian stratigraphic and structural traps on the Buzachi arch, especially on its undrilled off-shore extension. Most of the gas discoveries are expected to be in Paleozoic carbonate reservoirs in the eastern part of the basin.

Bulletin↗

Petroleum geology and total petroleum systems of the Widyan Basin and Interior Platform of Saudi Arabia and Iraq

Two total petroleum systems are associated with the Widyan Basin - Interior Platform Province in northern Saudi Arabia and western Iraq. In the Paleozoic Qusaiba/Akkas/Abba/ Mudawwara Total Petroleum System, which consists of one assessment unit - the Horst/Graben-Related Oil and Gas Assessment Unit - high-gravity, low-sulfur crude oil, as well as natural gas, occurs in horst/graben-related traps that formed prior to, during, and after Hercynian deformation (Carboniferous). The source of oil and gas is from organic-rich marine shale at the base of the Silurian sedimentary sequence (Qusaiba, Akkas, Mudawwara, and Abba Formations) that was deposited under dysoxic to anoxic conditions in an intra-shelf basin located north of the Central Arabian Arch. Onset of oil generation in Iraq began about 250 million years ago (Ma) and in eastern Saudi Arabia about 160 Ma, reaching peak generation, expulsion, migration, and entrapment during the Jurassic Period. In Saudi Arabia, petroleum migrated into fluvial and eolian quartzose sandstones of the Carboniferous-Early Permian Unayzah Formation that overlies the Hercynian unconformity, filling in rifts and half-grabens to thicknesses ranging to more than 400 meters. Combined stratigraphic-structural traps exist where the Unayzah Formation is the reservoir, as is the case in central Saudi Arabia. Oil and gas are sealed in those reservoirs by overlying tight carbonate- evaporite strata, and by subunconformity pinchouts of Pre-Unayzah clastic reservoir units against impermeable facies. In Iraq, reservoirs are sandstones of the Ordovician Upper Khabour and Silurian Akkas Formations. Over most of the Southwestern Desert of Iraq, Lower Silurian shale is a seal for hydrocarbons in the underlying Ordovician Khabour Formation. The Jurassic Gotnia/Barsarin/Sargelu/Najmah Total Petroleum System has two assessment units: the Platform Horst/Graben- Related Oil Assessment Unit and the Basinal Oil and Gas Assessment Unit. All reservoirs are in the Upper Jurassic Najmah Limestone and Gotnia Formation in Iraq, and the correlative Arab Formation in Saudi Arabia, occurring as lenses of marine bar or shelf-margin calcarenites, calcarenitic limestone, and dolomite. These strata grade eastward into organic-rich source rocks that were deposited under anoxic and dysoxic conditions in three restricted intra-shelf basins - from north to south, the Gotnia, Arabian, and Southern Arabian Gulf Basins. Maturation of the Upper Jurassic source-rock formations (Sargelu and Naokelekan Formations in Iraq) began around 90 Ma; peak generation took place from 85 to 13 Ma. With time, the oil migrated updip and was trapped in calcarenite lenses. Later, oil remigrated and was trapped in anticlines that began to form in Early Cretaceous time. Younger Jurassic shale and anhydrite seal rocks are distributed throughout the total petroleum system. The Widyan Basin-Interior Platform Province (2023) ranks 17th in the world, exclusive of the United States, with 62.5 billion barrels of oil equivalent of total petroleum endowment (cumulative production plus remaining petroleum plus estimated mean undiscovered volumes). Mean estimates of undiscovered petroleum for the province, which includes both Paleozoic and Jurassic petroleum systems as well as portions of three additional total petroleum systems from adjacent provinces, are 21.22 billion barrels of oil, 94.75 trillion cubic feet of gas (15.8 billion barrels of oil equivalent), and 6.85 billion barrels of natural gas liquids. The Paleozoic total petroleum system is dominantly gas prone, whereas the volumetrically larger Jurassic total petroleum system is oil prone - resulting in the characterization of the province as an oil province. The discovery maturity for the province is a relatively low 31 percent, meaning that much of the province petroleum potential lies in the future.

Arabian Peninsula↗