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At least 865 records · Page 48Linked to original sources
USGS1991

Data standardization. The key to effective management

Effective management of the nation's water resources is dependent upon accurate and consistent hydrologic information. Before the emergence of environmental concerns in the 1960's, most hydrologic information was collected by the U.S. Geological Survey and other Federal agencies that used fairly consistent methods and equipment. In the past quarter century, however, increased environmental awareness has resulted in an expansion of hydrologic data collection not only by Federal agencies, but also by state and municipal governments, university investigators, and private consulting firms. The acceptance and use of standard methods of collecting and processing hydrologic data would contribute to cost savings and to greater credibility of flow information vital to responsible assessment and management of the nation's water resources. This paper traces the evolution of the requirements and uses of open-channel flow information in the U.S., and the sequence of efforts to standardize the methods used to obtain this information in the future. The variable nature of naturally flowing rivers results in continually changing hydraulic properties of their channels. Those persons responsible for measurement of water flowing in open channels (streamflow) must use a large amount of judgement in the selection of appropriate equipment and technique to obtain accurate flow information. Standardization of the methods used in the measurement of streamflow is essential to assure consistency of data, but must also allow considerable latitude for individual judgement to meet constantly changing field conditions.

Conference Paper↗
USGS1987

Application of microwave digestion to the analysis of peat

A microwave digestion technique for the dissolution of peat is described and compared with a dry ashing method and a nitric - perchloric - hydrofluoric acid wet digestion. Peat samples with different organic matter contents were used and Ca, Mg, Fe, AI, Na, K, Mn, Zn, Cu and Li were determined by atomic absoprtion spectrometry. The results obtained using the three dissolution techniques were in good agreement. The microwave method has the advantage of digesting the samples in less than 2 h and uses less acid than the conventional wet digestion method. Keeping the volume of the acid mixture as small as possible minimises contamination and leads to lower blank values.

The Analyst↗
USGS2020

Vapor-bubble growth in olivine-hosted melt inclusions

Melt inclusions record the depth of magmatic processes, magma degassing paths, and volatile budgets of magmas. Extracting this information is a major challenge. It requires determining melt volatile contents at the time of entrapment when working with melt inclusions that have suffered post-entrapment modifications. Several processes decrease internal melt inclusion pressure, resulting in nucleation and growth of a vapor bubble and, time permitting, diffusion of volatiles (especially CO2) into the vapor bubble. Methods exist that attempt to reconstruct the entrapped CO2 contents, but they are difficult to apply and yield inconsistent results. Here, we explore bubble growth, evaluate CO2 reconstruction approaches, and develop improved experimental and computational approaches. Piston-cylinder experiments were conducted on olivine-hosted melt inclusions from Seguam (Alaska, USA) and Fuego (Guatemala) volcanoes at the following conditions: 500-800 MPa, 1140-1200 °C for Seguam and 1110-1140 °C for Fuego, 4-8 wt% H2O in the KBr brine, and run durations of 10-120 minutes. Heated melt inclusions form well-defined S-CO2 trends that can be described by degassing models. CO2 contents are enriched by a factor of ~2.5, on average, relative to those of the glasses within unheated melt inclusions, whereas S contents of heated and unheated melt inclusion glasses overlap, indicating insignificant amounts of S partition into the vapor bubble. Low closure temperatures enable CO2 diffusion into vapor bubbles during quench upon eruption, while a higher closure temperature for S limits its loss to vapor bubbles. We evaluate the timescales of post-entrapment processes and use the results to develop a new computational model to restore entrapped CO2 contents: MIMiC (Melt Inclusion Modification Corrections). Heated melt inclusion data are used as a benchmark to evaluate of the results from MIMiC and other published methods of CO2 reconstruction. The methods perform variably well. Key advantages to our experimental rehomogenization technique are that it enables accurate measurements of CO2 contents and allows for large quantities of melt inclusions to be rehomogenized efficiently. Our new computational model produces more accurate results than other computational methods, has similar accuracy to the Raman method of CO2 reconstruction in cases where Raman can be applied (i.e., no C-bearing phases in bubble), and can be applied to the vast body of published melt inclusion data. To obtain the most robust data on bubble-bearing melt inclusions, we recommend taking both experimental- and MIMiC-based approaches.

American Mineralogist↗
USGS2023

Magnitude and frequency of floods on Kauaʻi, Oʻahu, Molokaʻi, Maui, and Hawaiʻi, State of Hawaiʻi, based on data through water year 2020

Accurate estimates of flood magnitude and frequency are needed to (1) optimize the design and location of infrastructure, including dams, culverts, bridges, industrial buildings, and highways, and (2) inform flood-zoning and flood-insurance studies. The U.S. Geological Survey (USGS), in cooperation with the State of Hawaiʻi Department of Transportation, estimated flood magnitudes for the 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probabilities (AEP) for unregulated streamgages in Kauaʻi, Oʻahu, Molokaʻi, Maui, and Hawaiʻi, State of Hawaiʻi, using data through water year 2020. Regression equations were developed to estimate flood magnitude and associated frequency at ungaged streams. This study improves upon a previous USGS flood-frequency report (Oki and others, 2010) by including more peak-flow data, implementing new statistical methods in flood-frequency analysis, and using updated techniques to estimate the regional-skewness coefficient (regional skew). Flood magnitude and frequency at 238 streamgages were estimated—following national guidelines established in Bulletin 17C (England and others, 2019)—by fitting annual peak-flow data to the Log-Pearson Type III distribution using the expected moments algorithm and the PeakFQ flood-frequency software. Potentially influential low outliers in the data were identified and removed using the Multiple Grubbs-Beck Test. An updated regional skew for Hawaiʻi was estimated using the Bayesian weighted least squares/Bayesian generalized least squares method. The updated regional skew employs a constant model for the five islands in the study area and has a value of −0.157 (mean square error of 0.212). Multiple linear regression techniques were used to develop regression equations that relate basin and climatic characteristics to peak flows at streamgages. The regression equations can be applied to estimate flood magnitude and frequency at ungaged sites. The study area was split into 10 regions—2 regions per island, generally following a leeward/windward division—containing from 9 to 49 streamgages each. The final regression equations for each region were determined with generalized least-squares analysis using the USGS weighted-multiple-linear regression (WREG) program. The standard error of prediction at the 1-percent AEP for the regression equations ranged from 18 to 164 percent; the pseudo coefficient of determination (pseudo-R2) at the 1-percent AEP ranged from 46 to 100 percent. The regression equations performed well for all regions except leeward Molokaʻi and southern Island of Hawaiʻi; for all other regions, the pseudo-R2 values ranged from about 75 to 100 percent. Compared to the regression equations developed by Oki and others (2010), the regression equations in this study generally showed modest improvements, although the magnitude of differences varied for each region. Peak-flow estimates at the 238 streamgages included in this study are improved by weighting the at-site statistics computed with PeakFQ and the predicted flows based on the regression equations. Results of this study—including the final peak-flow estimates at streamgages and the regional regression equations—are implemented in the USGS StreamStats web application (U.S. Geological Survey, 2023, StreamStats: https://streamstats.usgs.gov/ss/ ). StreamStats provides a consistent approach for obtaining peak-flow estimates at streamgages and for applying the regional regression equations for estimating peak flows at ungaged locations.

Hawaii↗
USGS2000

Techniques for identifying dust devils in mars pathfinder images

Image processing methods used to identify and enhance dust devil features imaged by IMP (Imager for Mars Pathfinder) are reviewed. Spectral differences, visible red minus visible blue, were used for initial dust devil searches, driven by the observation that Martian dust has high red and low blue reflectance. The Martian sky proved to be more heavily dust-laden than pre-Pathfinder predictions, based on analysis of images from the Hubble Space Telescope. As a result, these initial spectral difference methods failed to contrast dust devils with background dust haze. Imager artifacts (dust motes on the camera lens, flat-field effects caused by imperfections in the CCD, and projection onto a flat sensor plane by a convex lens) further impeded the ability to resolve subtle dust devil features. Consequently, reference images containing sky with a minimal horizon were first subtracted from each spectral filter image to remove camera artifacts and reduce the background dust haze signal. Once the sky-flat preprocessing step was completed, the red-minus-blue spectral difference scheme was attempted again. Dust devils then were successfully identified as bright plumes. False-color ratios using calibrated IMP images were found useful for visualizing dust plumes, verifying initial discoveries as vortex-like features. Enhancement of monochromatic (especially blue filter) images revealed dust devils as silhouettes against brighter background sky. Experiments with principal components transformation identified dust devils in raw, uncalibrated IMP images and further showed relative movement of dust devils across the Martian surface. A variety of methods therefore served qualitative and quantitative goals for dust plume identification and analysis in an environment where such features are obscure.

IEEE Transactions on Geoscience and Remote Sensing↗
USGS2007

An application of surface geophysical techniques to the study of watershed hydrology

The applicability of geophysical methods to experimental watershed research is demonstrated by a study of a 106-acre forested watershed in central Pennsylvania. Data from a shallow seismic refraction study and an electrical resistivity study of the watershed were used to determine the depth of soils, their volumes, depth to bedrock, configuration of the bedrock surface and delineation of the bedrock surface and delineation of the water table. With this information on the subsurface conditions, the hydrologic properties of the watershed were described in greater detail. This information will be of value in explaining the watershed's response to various watershed treatment practices that eventually will be used.

Pennsylvania↗
USGS1982

Techniques for estimating magnitude and frequency of floods in South Carolina

Methods are provided for estimating flood magnitudes at recurrence intervals of 2, 5, 10, 25, 50, and 100 years, for unregulated rural streams in South Carolina with drainage areas greater than 1.0 square mile. Multiple regression analyses were used to define the relation between flood discharge and basin and climatic variables. The analyses indicated that flood discharge is related to the drainage area and physiographic location of the basin. Accordingly, equations were developed for the Lower Coastal Plain, Inner Coastal Plain, Piedmont, and Blue Ridge provinces. The standard errors of estimate range from 31 to 56 percent. Station data used in the analyses are listed in the report. Individual relations of flood discharge and frequency to drainage area are given for some of the regulated major streams, including the Pee Dee, Catawba, Wateree, Broad, Saluda, Congaree, Santee, and Savannah Rivers. Storm tide-recurrence interval relations along the South Carolina coast indicate that the 500-year tide height can exceed 19 feet, National Geodetic Vertical Datum of 1929, at some locations. A compilation of flood records for gaging stations is included as supplemental data.

South Carolina↗
USGS2012

Evaluation of geophysical techniques for the detection of paleochannels in the Oakland area of eastern Nebraska as part of the Eastern Nebraska Water Resource Assessment

Over the winter and spring of 2009, the U.S. Geological Survey conducted a general assessment of the capabilities of several geophysical tools to delineate buried paleochannel aquifers in the glacial terrain of eastern Nebraska. Mapping these paleochannels is an important objective for the Eastern Nebraska Water Resources Assessment group. Previous attempts at mapping these channels included a helicopter electromagnetic survey flown over an area near the town of Oakland, Nebraska, in March 2007. This survey had limited success in imaging the paleochannels due to the restricted depth of investigation of the system in the clay-rich till overburden. The purpose of this study was to investigate whether other airborne electromagnetic or surface geophysical techniques, including audio-magnetotelluric, time-domain electromagnetic, gravity, and magnetic methods, could be used to image the paleochannels in the clay-rich tills of eastern Nebraska. This report releases the results of testing the ability of selected geophysical techniques to map aquifers in glacial deposits near the town of Oakland, Nebraska. Surface audio-magnetotelluric and time-domain electromagnetic methods achieved sufficient depth of penetration and indicated that the paleochannel was much more complex than the original geological model. Simulated and observed gravity anomalies indicate that imaging sand and gravel aquifers near Oakland, Nebraska, would be difficult due to the complex basement density contrasts. Interpretation of the magnetic data indicates no magnetic sources from geologic units above the bedrock surface. Based upon the analysis and interpretation of the four methods evaluated, we suggest a large-scale survey using a high-powered time-domain airborne system. This is the most efficient and cost-effective path forward for the Eastern Nebraska Water Assessment group to map paleochannels that lie beneath thick clay-rich glacial tills.

Nebraska↗
USGS2018

Estimating vegetation biomass and cover across large plots in shrub and grass dominated drylands using terrestrial lidar and machine learning

Terrestrial laser scanning (TLS) has been shown to enable an efficient, precise, and non-destructive inventory of vegetation structure at ranges up to hundreds of meters. We developed a method that leverages TLS collections with machine learning techniques to model and map canopy cover and biomass of several classes of short-stature vegetation across large plots. We collected high-definition TLS scans of 26 1-ha plots in desert grasslands and big sagebrush shrublands in southwest Idaho, USA. We used the Random Forests machine learning algorithm to develop decision tree models predicting the biomass and canopy cover of several vegetation classes from statistical descriptors of the aboveground heights of TLS points. Manual measurements of vegetation characteristics collected within each plot served as training and validation data. Models based on five or fewer TLS descriptors of vegetation heights were developed to predict the canopy cover fraction of shrubs (R 2 = 0.77, RMSE = 7%), annual grasses (R 2 = 0.70, RMSE = 21%), perennial grasses (R 2 = 0.36, RMSE = 12%), forbs (R 2 = 0.52, RMSE = 6%), bare earth or litter (R 2 = 0.49, RMSE = 19%), and the biomass of shrubs (R 2 = 0.71, RMSE = 175 g) and herbaceous vegetation (R 2 = 0.61, RMSE = 99 g) (all values reported are out-of-bag). Our models explained much of the variability between predictions and manual measurements, and yet we expect that future applications could produce even better results by reducing some of the methodological sources of error that we encountered. Our work demonstrates how TLS can be used efficiently to extend manual measurement of vegetation characteristics from small to large plots in grasslands and shrublands, with potential application to other similarly structured ecosystems. Our method shows that vegetation structural characteristics can be modeled without classifying and delineating individual plants, a challenging and time-consuming step common in previous methods applying TLS to vegetation inventory. Improving application of TLS to studies of shrub-steppe ecosystems will serve immediate management needs by enhancing vegetation inventories, environmental modeling studies, and the ability to train broader datasets collected from air and space.

Idaho↗
USGS1992

Tracking the movement of Hawaiian volcanoes; Global Positioning System (GPS) measurement

Most, if not all, volcanic eruptions are preceded by surface movements near the volcano. These ground movements are the response of the shallow crust to the accumulation of the magma or the buildup of magma pressure within a subterranean reservoir beneath the volcano. As the magma reservoir expands, the summit and the flanks of the volcano rise and spread apart. Measurements made at many volcanoes show that slow ground movement may precede an eruption by as many as several years. Sudden increases in the rate of ground movement often precede an eruption by a few hours or days. At some well-studied volcanoes, surface movements of at least several centimeters take place out to distances of about 10 km from the summit of the volcano. Widespread deformation of this type is relatively easy to monitor, because the necessary survey stations can be placed at favorable sites some distance from the summit of the volcano. Examples of deformation of this type include Kilauea and Mauna Loa in Hawaii, Krafla in Iceland, Long Valley in California, Camp Flegrei in Italy, and Sakurajima in Japan. In contrast, surface movement at some other volcanoes, usually volcanoes with steep slopes, is restricted to places within about 1 km of their summits. Examples of this class of volcanoes include Mount St. Helens in Washington, Etna in Italy, and Tangkuban Parahu in Indonesia. Local movement on remote, rugged volcanoes of this type is difficult to observe using conventional methods of measuring ground movement, which generally require a clear line-of-sight between points of interest. However, a revolutionary new technique, called the Global Positional System (GPS), provides a very efficient, alternative method of making such measurements. GPS, which uses satellites and ground-based receivers to accurately record slight crustal movements, is rapidly becoming the method of choice to measure deformation at volcanoes.

Hawaii↗
USGS2020

Comparison of underwater video with electrofishing and dive‐counts for stream fish abundance estimation

Advances in video technology enable new strategies for stream fish research. We compared juvenile (age‐0) and adult (age 1+) Brook Trout Salvelinus fontinalis abundance estimates from underwater video with backpack electrofishing and dive‐count methods across a series of stream pools in Shenandoah National Park, Virginia ( n = 41). Video methods estimated greater mean abundance of adult trout than 1‐pass electrofishing but were not different than 3‐pass electrofishing or dive‐count methods in this regard. In contrast, videos underestimated abundance of juvenile trout, and we suggest this is because predator avoidance‐behaviors by juvenile trout limit their use of microhabitat locations visible to cameras. Integrated abundance estimates from 2 cameras increased correspondence to comparison methods relative to single cameras, demonstrating the importance of an expanded field of view for video sampling in streams. Geomorphic features helped explain method‐wise differences: more adult trout were estimated with video than 3‐pass electrofishing as riffle crest depth and boulder composition increased, indicating habitat associations with trout escapement from electrofishing. Our results demonstrated that video techniques can provide a robust alternative or supplement to traditional methods for estimating adult trout abundance in stream pools.

Virgiinia↗
USGS2016

Multi-laboratory survey of qPCR enterococci analysis method performance in U.S. coastal and inland surface waters

Quantitative polymerase chain reaction (qPCR) has become a frequently used technique for quantifying enterococci in recreational surface waters, but there are several methodological options. Here we evaluated how three method permutations, type of mastermix, sample extract dilution and use of controls in results calculation, affect method reliability among multiple laboratories with respect to sample interference. Multiple samples from each of 22 sites representing an array of habitat types were analyzed using EPA Method 1611 and 1609 reagents with full strength and five-fold diluted extracts. The presence of interference was assessed three ways: using sample processing and PCR amplifications controls; consistency of results across extract dilutions; and relative recovery of target genes from spiked enterococci in water sample compared to control matrices with acceptable recovery defined as 50 to 200%. Method 1609, which is based on an environmental mastermix, was found to be superior to Method 1611, which is based on a universal mastermix. Method 1611 had over a 40% control assay failure rate with undiluted extracts and a 6% failure rate with diluted extracts. Method 1609 failed in only 11% and 3% of undiluted and diluted extracts analyses. Use of sample processing control assay results in the delta–delta Ct method for calculating relative target gene recoveries increased the number of acceptable recovery results. Delta–delta tended to bias recoveries from apparent partially inhibitory samples on the high side which could help in avoiding potential underestimates of enterococci — an important consideration in a public health context. Control assay and delta–delta recovery results were largely consistent across the range of habitats sampled, and among laboratories. The methodological option that best balanced acceptable estimated target gene recoveries with method sensitivity and avoidance of underestimated enterococci densities was Method 1609 without extract dilution and using the delta–delta calculation method. The applicability of this method can be extended by the analysis of diluted extracts to sites where interference is indicated but, particularly in these instances, should be confirmed by augmenting the control assays with analyses for target gene recoveries from spiked target organisms.

Journal of Microbiological Methods↗
USGS2008

Determination of the delta(18O/16O)of Water: RSIL Lab Code 489

The purpose of the technique described by the Reston Stable Isotope Laboratory (RSIL) lab code 489 is to present a method to determine the delta(180/160), abbreviated as delta-180, of water. This delta-18O measurement of water also is a component of National Water Quality Laboratory (NWQL in USGS) schedules 1142 and 1172. Water samples are loaded into glass sample containers on a vacuum manifold to equilibrate gaseous CO2 at constant temperature (25 deg C) with water samples. After loading water samples on the vacuum manifold, air is evacuated through capillary to avoid evaporation, and CO2 is added. The samples are shaken to increase the equilibration rate of water and CO2. When isotopic equilibrium has been attained, an aliquot of CO2 is extracted sequentially from each sample container, separated from water vapor by means of a dry ice trap, and introduced into a dual-inlet isotope-ratio mass spectrometer (DI-IRMS) for determination of the delta-18O value. There is oxygen isotopic fractionation between water and CO2, but it is constant at constant temperature. The DI-IRMS is a DuPont double-focusing mass spectrometer. It has a double collector. One ion beam passes through a slit in a forward collector and is collected in the rear collector. The other ion beams are collected in the front collector. The instrument is capable of measuring mass/charge (m/z) 44 and 45 or 44 and 46 by changing the ion-accelerating voltage under computer control. The ion beams from these m/z values are as follows: m/z 44=CO2=12C16O16O, m/z 45=CO2=13C16O16O primarily, and m/z 46 = CO2=12C16O18O primarily. The data acquisition and control software calculates delta-18O values.

Techniques and Methods↗
USGS2002

Discharge measurements using a broad-band acoustic Doppler current profiler

The measurement of unsteady or tidally affected flow has been a problem faced by hydrologists for many years. Dynamic discharge conditions impose an unreasonably short time constraint on conventional current-meter discharge-measurement methods, which typically last a minimum of 1 hour. Tidally affected discharge can change more than 100 percent during a 10-minute period. Over the years, the U.S. Geological Survey (USGS) has developed moving-boat discharge-measurement techniques that are much faster but less accurate than conventional methods. For a bibliography of conventional moving-boat publications, see Simpson and Oltmann (1993, page 17). The advent of the acoustic Doppler current profiler (ADCP) made possible the development of a discharge-measurement system capable of more accurately measuring unsteady or tidally affected flow. In most cases, an ADCP discharge-measurement system is dramatically faster than conventional discharge-measurement systems, and has comparable or better accuracy. In many cases, an ADCP discharge-measurement system is the only choice for use at a particular measurement site. ADCP systems are not yet ?turnkey;? they are still under development, and for proper operation, require a significant amount of operator training. Not only must the operator have a rudimentary knowledge of acoustic physics, but also a working knowledge of ADCP operation, the manufacturer's discharge-measurement software, and boating techniques and safety.

Open-File Report↗
USGS2008

Modified method for external attachment of transmitters to birds using two subcutaneous anchors

Of the transmitter attachment techniques for birds, the subcutaneous anchor provides a secure attachment that yields relatively few secondary effects. However, the use of subcutaneous anchors has been limited by transmitter size and retention time. Using a modified method of attachment that utilized two subcutaneous anchors, we deployed 69 GPS transmitters, plus 13 VHF transmitters that were similar in size and weight to GPS models, on Pacific Black Brant ( Branta bernicla nigricans ). Prior to our study, only harnesses were used for attaching GPS transmitters on birds, mainly because GPS transmitters are too large for other external attachment techniques and implantation in the body cavity attenuates the GPS signal. Thus, to increase the size capacity of anchor attachment and to avoid the well‐documented negative effects of harnesses on behavior and survival, we added a second anchor at the transmitter's posterior end. The double‐anchor attachment technique was quickly and easily accomplished in the field, requiring bird handling times of <10 min. Incidental recoveries of tagged Brant indicate a high degree of transmitter retention. Five recaptured birds (4–6 weeks after deployment) and eight killed by hunters (3–6 mo after deployment) retained their GPS transmitters. For studies involving the use of relatively large transmitters, the double‐anchor method appears to provide a viable alternative for external attachment.

Journal of Field Ornithology↗
USGS2005

Determination of total mercury in biological and geological samples

The analytical chemist is faced with several challenges when determining mercury in biological and geological materials. These challenges include widespread mercury contamination, both in the laboratory and the environment, possible losses of mercury during sample preparation and digestion, the wide range of mercury values commonly observed, ranging from the low nanogram per gram or per liter for background areas to hundreds of milligrams per kilogram in contaminated or ore-bearing areas, great matrix diversity, and sample heterogeneity1. These factors can be naturally occurring or anthropogenic, but must be addressed to provide a precise and accurate analysis. Although there are many instrumental methods available for the successful determination of mercury, no one technique will address all problems or all samples all of the time. The approach for the determination of mercury used at the U.S. Geological Survey, Crustal Imaging and Characterization Team, Denver Laboratories, utilizes a suite of complementary instrumental methods when approaching a study requiring mercury analyses. Typically, a study could require the analysis of waters, leachates or selective digestions of solids, vegetation, and biological materials such as tissue, bone, or shell, soils, rocks, sediments, coals, sludges, and(or) ashes. No one digestion or sample preparation method will be suitable for all of these matrices. The digestions typically employed at our laboratories include: (i) a closed-vessel microwave method using nitric acid and hydrogen peroxide, followed by digestion/dilution with a nitric acid/sodium dichromate solution, (ii) a robotic open test-tube digestion with nitric acid and sodium dichromate, (iii) a sealed Teflon? vessel with nitric acid and sodium dichromate, (iv) a sealed glass bottle with nitric acid and sodium dichromate, or (v) open test tube digestion with nitric and sulfuric acids and vanadium pentoxide. The common factor in all these digestions is that they are very oxidative to ensure the conversion of all mercury forms into Hg (II). Each method of digestion has its advantages and limitations. The method of detection used in our laboratories involves a combination of an in-house, custom, classic continuous-flow cold-vapor atomic absorption spectrometry (CVAAS), a commercially available, automated, flow-injection and a continuous flow cold-vapor atomic fluorescence spectrometry (CV-AFS) systems, and a relatively new, automated and integrated approach where solid or liquid samples are thermally decomposed under an oxygen atmosphere (a nitrogen atmosphere is used for coals) and the released mercury vapor trapped onto a gold gauze and then thermally released into an AAS system. Other less frequently used instrumental methods available for the determination of mercury include inductively coupled plasma ? optical emission spectrometry (ICP-OES), inductively couple plasma ? mass spectrometry (ICP-MS) (both solution nebulization and laser ablation), and instrumental neutron activation analysis (INAA). Results from two case studies involving the determination of mercury in the challenging matrices of biological materials will be presented. These will include fillet, liver and stomach-content samples from grayling for a baseline/background study in Alaska, and samples of meat tissue and shell material from Tanner crabs from Glacier Bay, Alaska. These studies show that the method of digestion is more important than a very sensitive detection limit for mercury.

Open-File Report↗
USGS1993

Estimation of hydraulic conductivity of a riverbed and aquifer system on the Susquehanna River in Broome County, New York

A three-dimensional finite-difference model of groundwater flow was used to estimate the hydraulic conductivity of riverbed and aquifer material in a 1-square-mile valley-fill aquifer system near a large river in which induced infiltration due to pumping cannot be measured directly. The aquifer consists of a 30- to 70-foot thickness of sand and gravel containing discontinuous layers of compact and silty sand and gravel. Horizontal hydraulic conductivity of the aquifer material, estimated through trial-and-error calibration of simulated water levels to drawdowns measured during an aquifer test, ranged from 500 to 10,000 feet per day; anisotropy (ratio of horizontal to vertical hydraulic conductivity) ranged from 125:1 to 250:1. The vertical hydraulic conductivity of the riverbed was estimated to be 0.1 to 0.5 foot per day, whereas permeameter tests on samples of silty sand and gravel layers from the riverbed yielded vertical hydraulic conductivity of 10 -3 foot per day. A sensitivity analysis indicated that a narrow range of anisotropy values gave the smallest residual error in simulated drawdowns. Residual error increased sharply when the maximum hydraulic conductivity value for the aquifer was lowered to less than 5,000 feet per day. Residual error also was large for large values of vertical hydraulic conductivity of the riverbed, but decreased to a constant amount for values less than 0.1 foot per day. Residual error was relatively insensitive to changes in the storage coefficient and specific yield. A nonlinear regression method that approximated the sensitivity matrix with a perturbation technique was applied to refine the estimates of these parameters and compute standard error of the estimates. The nonlinear regression indicated that the model was sensitive to hydraulic conductivity of the aquifer and anisotropy of the upper part of the aquifer but not to anisotropy of the lower part, and that vertical hydraulic conductivity of the riverbed was less than 0.5 foot per day. The regression method yielded aquifer hydraulic-conductivity values of 210 to 13,000 feet per day and an anisotropy ratio of 350:1 for the upper part of the aquifer; the standard error of these estimates was relatively small. In contrast, the standard errors of estimates of anisotropy in the lower part of the aquifer and the vertical hydraulic conductivity of the riverbed were extremely large.

New York↗
USGS2009

A nonlethal microsampling technique to monitor the effects of mercury on wild bird eggs

Methylmercury is the predominant chemical form of mercury reported in the eggs of wild birds, and the embryo is the most sensitive life stage to methylmercury toxicity. Protective guidelines have been based mainly on captive-breeding studies with chickens (Gallus gallus), mallards (Anas platyrhynchos), and ring-necked pheasants (Phasianus colchicus) or on field studies where whole eggs were collected and analyzed and the effects of the mercury were measured based on the reproductive success of the remaining eggs. However, both of these methods have limitations. As an alternative, we developed a technique that involves extracting a small sample of albumen from a live egg, sealing the egg, returning the egg to its nest to be naturally incubated by the parents, and then relating the hatching success of this microsampled egg to its mercury concentration. After first developing this technique in the laboratory using chicken and mallard eggs, we selected the laughing gull (Larus atricilla) and black-necked stilt (Himantopus mexicanus) as test subjects in the field. We found that 92% of the microsampled laughing gull eggs met our reproductive endpoint of survival to the beginning of hatching compared to 100% for the paired control eggs within the same nests. Microsampled black-necked stilt eggs exhibited 100% hatching success compared to 93% for the paired control eggs. Our results indicate that microsampling is an effective tool for nonlethally sampling mercury concentrations in eggs and, as such, can be used for monitoring sensitive species, as well as for improving studies that examine the effects of mercury on avian reproduction.

Environmental Toxicology and Chemistry↗