Search USGS⌕ Search

SEARCH · Search USGS

Results for “Soil Science”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 865 records · Page 48Linked to original sources

Spatial and temporal variation in dissolved organic matter in urban streams in metropolitan Boston, Massachusetts (USA)

Urban riverine systems are heterogeneous, and the substantial variability in impervious cover, riparian cover, wetlands, and wastewater and stormwater infrastructure affect sources and transport of dissolved organic matter (DOM), of which dissolved organic C (DOC) is a substantial component. An understanding of the quantity, bioavailability, and timing of DOM inputs (a key energy source for food webs and a component of nutrient cycling) to streams within cities can help to better evaluate drivers of DOM variability. We sampled 100 stream sites in the greater Boston (Massachusetts, USA) area spanning a range of land cover, riparian vegetation, stream size, housing and infrastructure age, and sociodemographic characteristics. Water samples collected during 4 seasonal synoptic events in 2021 and 2022 were analyzed for DOC concentration and DOM characteristics (using fluorescence excitation–emission matrices and absorbance spectra). Temporally, we observed more-autochthonous DOM and lower DOC concentrations in the summer, possibly due to low precipitation and streamflow disconnecting streams from humic wetland and soil C sources. Consistent with other studies, we observed that more-urbanized streams had DOM that was less humic and more autotrophic. Higher wetland cover was associated with more-humic, higher-molecular-weight DOM and was the strongest predictor of DOM characteristics, suggesting that managers should consider the impacts of development on DOM, stream ecological functions, and CO 2 emissions. Interestingly, except during the very dry summer, sites downstream of combined sewer outfalls showed distinctly higher concentrations of protein-like DOM, suggesting the influence of sewage overflows and highlighting the potential for monitoring wastewater contamination using protein-like DOM. Although sociodemographic variables were not strong predictors of DOM composition, we observed a possible association between lower-income areas with less canopy cover and more-autochthonous DOM and between areas with older housing, more canopy cover, and more-humic DOM. These patterns suggest that equitable repair of wastewater infrastructure and restoration of riparian vegetation is needed.

Massachusetts↗

Improved automated detection of subpixel-scale inundation – Revised Dynamic Surface Water Extent (DSWE) partial surface water tests

In order to produce useful hydrologic and aquatic habitat data from the Landsat system, the U.S. Geological Survey has developed the “Dynamic Surface Water Extent” (DSWE) Landsat Science Product. DSWE will provide long-term, high-temporal resolution data on variations in inundation extent. The model used to generate DSWE is composed of five decision-rule based tests that do not require scene-based training. To allow its general application, required inputs are limited to the Landsat at-surface reflectance product and a digital elevation model. Unlike other Landsat-based water products, DSWE includes pixels that are only partially covered by water to increase inundation dynamics information content. Previously published DSWE model development included one wetland-focused test developed through visual inspection of field-collected Everglades spectra. A comparison of that test’s output against Everglades Depth Estimation Network (EDEN) in situ data confirmed the expectation that omission errors were a prime source of inaccuracy in vegetated environments. Further evaluation exposed a tendency toward commission error in coniferous forests. Improvements to the subpixel level “partial surface water” (PSW) component of DSWE was the focus of this research. Spectral mixture models were created from a variety of laboratory and image-derived endmembers. Based on the mixture modeling, a more “aggressive” PSW rule improved accuracy in herbaceous wetlands and reduced errors of commission elsewhere, while a second “conservative” test provides an alternative when commission errors must be minimized. Replication of the EDEN-based experiments using the revised PSW tests yielded a statistically significant increase in mean overall agreement (4%, p = 0.01, n = 50) and a statistically significant decrease (11%, p = 0.009, n = 50) in mean errors of omission. Because the developed spectral mixture models included image-derived vegetation endmembers and laboratory spectra for soil groups found across the US, simulations suggest where the revised DSWE PSW tests perform as they do in the Everglades and where they may prove problematic. Visual comparison of DSWE outputs with an unusual variety of coincidently collected images for locations spread throughout the US support conclusions drawn from Everglades quantitative analyses and highlight DSWE PSW component strengths and weaknesses.

Remote Sensing↗

Belowground carbon balance and carbon accumulation rate in the successional series of monsoon evergreen broad-leaved forest

The balance, accumulation rate and temporal dynamics of belowground carbon in the successional series of monsoon evergreen broadleaved forest are obtained in this paper, based on long-term observations to the soil organic matter, input and standing biomass of litter and coarse woody debris, and dissolved organic carbon carried in the hydrological process of subtropical climax forest ecosystem—monsoon evergreen broad-leaved forest, and its two successional forests of natural restoration—coniferous and broad-leaved mixed forest and Pinus massoniana forest, as well as data of root biomass obtained once every five years and respiration measurement of soil, litter and coarse woody debris respiration for 1 year. The major results include: the belowground carbon pools of monsoon evergreen broad-leaved forest, coniferous and broad-leaved mixed forest, and Pinus massoniana forest are 23191 ± 2538 g · m −2 , 16889 ± 1936 g · m −2 and 12680 ± 1854 g · m −2 , respectively, in 2002. Mean annual carbon accumulation rates of the three forest types during the 24a from 1978 to 2002 are 383 ± 97 g · m −2 · a −1 , 193 ± 85 g · m −2 · a −1 and 213 ± 86 g · m −2 · a −1 , respectively. The belowground carbon pools in the three forest types keep increasing during the observation period, suggesting that belowground carbon pools are carbon sinks to the atmosphere. There are seasonal variations, namely, they are strong carbon sources from April to June, weak carbon sources from July to September; while they are strong carbon sinks from October to November, weak carbon sinks from December to March.

Science in China, Series D: Earth Sciences↗

Microbial-sized, carboxylate-modified microspheres as surrogate tracers in a variety of subsurface environments: An overview

Since 1986, fluorescent carboxylate-modified polystyrene/latex microspheres (FCM) have been co-injected into aquifers along with conservative tracers and viruses, bacteria, and (or) protozoa. Use of FCM has resulted in new information about subsurface transport behaviors of microorganisms in fractured crystalline rock, karst limestone, soils, and granular aquifers. FCM have been used as surrogates for oocysts of the pathogenic protist Cryptosporidium parvum in karst limestone and granular drinking-water aquifers. The advantages of FCM in subsurface transport studies are that they are safe in tracer applications, negatively charged, easy to detect, chemically inert, and available in wide range of sizes. The limitations of FCM are that the quantities needed for some field transport studies can be prohibitively expensive and that their surface characteristics may not match the microorganisms of interest. These limitations may be ameliorated, in part by using chemically modified FCM so that their surface characteristics are a better match to that of the organisms. Also, more sensitive methods of detection may allow using smaller quantities of FCM. To assess how the transport behaviors of FCM and pathogens might compare at the field scale, it is helpful to conduct side-by-side comparisons of their transport behaviors using the geologic media and site-specific conditions that characterize the field site.

Procedia Earth and Planetary Science↗

Wildfire risk and hazardous fuel reduction treatments along the US-Mexico border: A review of the science (1985-2019)

The ecosystems along the border between the United States and Mexico are at increasing risk to wildfire due to interactions among climate, land-use, and fuel loads. A wide range of fuel treatments have been implemented to mitigate wildfire and its threats to valued resources, yet we have little information about treatment effectiveness. To fill critical knowledge gaps, we reviewed wildfire risk and fuel treatment studies that were conducted near the US-Mexico border and published in the peer-reviewed literature between 1986 and 2019. The number of studies has grown during this time in warm desert to forest ecosystems on primarily federal lands. The most common study topics included fire effects on native species, the role of invasive species and woody encroachment on wildfire risk, historical fire regimes, and remote sensing and modeling to study wildfire risk across the landscape. A majority of fuel treatment studies focused on prescribed burns, and fuel treatments collectively had mixed effects on mitigating future wildfire risk and threats to ecosystems depending on vegetation and fire characteristics. The diversity of ecosystems and land ownership along the US-Mexico border present unique challenges for understanding and managing wildfire risk, and also create opportunities for collaboration and cross-site studies to promote knowledge across broad environmental gradients.

Arizona, California, New Mexico, Texas↗

Soil diversity and hydration as observed by ChemCam at Gale crater, Mars

The ChemCam instrument, which provides insight into martian soil chemistry at the submillimeter scale, identified two principal soil types along the Curiosity rover traverse: a fine-grained mafic type and a locally derived, coarse-grained felsic type. The mafic soil component is representative of widespread martian soils and is similar in composition to the martian dust. It possesses a ubiquitous hydrogen signature in ChemCam spectra, corresponding to the hydration of the amorphous phases found in the soil by the CheMin instrument. This hydration likely accounts for an important fraction of the global hydration of the surface seen by previous orbital measurements. ChemCam analyses did not reveal any significant exchange of water vapor between the regolith and the atmosphere. These observations provide constraints on the nature of the amorphous phases and their hydration.

Science↗

Improvement of the R-SWAT-FME framework to support multiple variables and multi-objective functions

Application of numerical models is a common practice in the environmental field for investigation and prediction of natural and anthropogenic processes. However, process knowledge, parameter identifiability, sensitivity, and uncertainty analyses are still a challenge for large and complex mathematical models such as the hydrological/water quality model, Soil and Water Assessment Tool (SWAT). In this study, the previously developed R program language-SWAT-Flexible Modeling Environment (R-SWAT-FME) was improved to support multiple model variables and objectives at multiple time steps (i.e., daily, monthly, and annually). This expansion is significant because there is usually more than one variable (e.g., water, nutrients, and pesticides) of interest for environmental models like SWAT. To further facilitate its easy use, we also simplified its application requirements without compromising its merits, such as the user-friendly interface. To evaluate the performance of the improved framework, we used a case study focusing on both streamflow and nitrate nitrogen in the Upper Iowa River Basin (above Marengo) in the United States. Results indicated that the R-SWAT-FME performs well and is comparable to the built-in auto-calibration tool in multi-objective model calibration. Overall, the enhanced R-SWAT-FME can be useful for the SWAT community, and the methods we used can also be valuable for wrapping potential R packages with other environmental models.

Science of the Total Environment↗

Sediment sources and sealed-pavement area drive polycyclic aromatic hydrocarbon and metal occurrence in urban streams

Metals and polycyclic aromatic hydrocarbons (PAHs) are common pollutants in urban streambed sediment, yet their occurrence is highly variable and difficult to predict. To investigate sources of PAHs and metals to streambed sediment, we sampled pavement dust, soil, and streambed sediment in 10 urban watersheds in three regions of the United States and applied a fallout-radionuclide-based sediment-source analysis to quantify the pavement dust contribution to stream sediment (%dust). We also mapped the area of sealcoated pavement in each watershed (%sealed) to investigate the role of coal-tar pavement sealant (CTS) as a PAH source. Median total and carbon-normalized total PAH concentrations were significantly higher in streambed sediment in the Northeast (54.3 mg/kg and 2.71 mg/gOC) and Southeast (5.37 mg/kg and 1.36 mg/gOC), where CTS is commonly used, than in the Northwest (2.11 mg/kg and 0.071 mg/gOC), where CTS is rarely used. Generalized additive models indicated that %sealed and in some cases %dust significantly affected total PAH concentrations in streambed sediments. The %dust was a significant variable for common urban metals: Cu, Pb, and Zn. These findings advance our quantitative understanding of the role of pavement dust as a source and a vector of contaminants to urban streams.

Georgia, New York, North Carolina, Oregon, Virgini↗

Nuclear methods applied to uranium geochemistry

Stable and radioactive daughter products produced from nuclear disintegrations of uranium have proved useful in fundamental studies of the geochemistry of uranium in igneous rock and sedimentary environments and in ore deposits. Information gained from geochemical studies of uranium migration has been used to develop models for attempts to date archeological, geological, and oceanographic environments represented by samples of bone, wood, charcoal, continental and marine carbonates, marine sediments, and glacially derived soils. Recent improvements of nuclear instrumentation and techniques allowed accurate measurements of natural radioactive isotopes, and it is now believed that radioactive equilibrium between the long-lived isotopes of the two uranium decay series is more the exception than the rule in nature. It was assumed that the 234U and 238U isotopes were in equilibrium until Thurber confirmed that considerable separation between 234U daughter and 238U parent exists in nature. It now has been documented that the 234U content may range from 60% deficient to 500% in excess relative to 238U. An excess of 15% of 234U isotope in sea water is well documented. A summary of previous work has shown that geochemical fractionation of the radioactive nuclides in 238U and 235U decay series takes place in the hydrologic environment, resulting in depletion of 230Th and 231Pa with respect to their parents, 238U, 234U, and 235U, in water and a complementary enrichment of these daughter nuclides in some sediments. Subsequent assimilation of Uranium, essentially free of radioactive daughters, occurs in some specific types of deposits such as carbonates and phosphates.

IEEE Transactions on Nuclear Science↗

The United States National Climate Assessment - Alaska Technical Regional Report

The Alaskan landscape is changing, both in terms of effects of human activities as a consequence of increased population, social and economic development and their effects on the local and broad landscape; and those effects that accompany naturally occurring hazards such as volcanic eruptions, earthquakes, and tsunamis. Some of the most prevalent changes, however, are those resulting from a changing climate, with both near term and potential upcoming effects expected to continue into the future. Alaska's average annual statewide temperatures have increased by nearly 4°F from 1949 to 2005, with significant spatial variability due to the large latitudinal and longitudinal expanse of the State. Increases in mean annual temperature have been greatest in the interior region, and smallest in the State's southwest coastal regions. In general, however, trends point toward increases in both minimum temperatures, and in fewer extreme cold days. Trends in precipitation are somewhat similar to those in temperature, but with more variability. On the whole, Alaska saw a 10-percent increase in precipitation from 1949 to 2005, with the greatest increases recorded in winter. The National Climate Assessment has designated two well-established scenarios developed by the Intergovernmental Panel on Climate Change (Nakicenovic and others, 2001) as a minimum set that technical and author teams considered as context in preparing portions of this assessment. These two scenarios are referred to as the Special Report on Emissions Scenarios A2 and B1 scenarios, which assume either a continuation of recent trends in fossil fuel use (A2) or a vigorous global effort to reduce fossil fuel use (B1). Temperature increases from 4 to 22°F are predicted (to 2070-2099) depending on which emissions scenario (A2 or B1) is used with the least warming in southeast Alaska and the greatest in the northwest. Concomitant with temperature changes, by the end of the 21st century the growing season is expected to lengthen by 15-25 days in some areas of Alaska, with much of that corresponding with earlier spring snow melt. Future projections of precipitation (30-80 years) over Alaska show an increase across the State, with the largest changes in the northwest and smallest in the southeast. Because of increasing temperatures and growing season length, however, increased precipitation may not correspond with increased water availability, due to temperature related increased evapotranspiration. The extent of snow cover in the Northern Hemisphere has decreased by about 10 percent since the late 1960s, with stronger trends noted since the late 1980s. Alaska has experienced similar trends, with a strong decrease in snow cover extent occurring in May. When averaged across the State, the disappearance of snow in the spring has occurred from 4 to 6 days earlier per decade, and snow return in fall has occurred approximately 2 days later per decade. This change appears to be driven by climate warming rather than a decrease in winter precipitation, with average winter temperatures also increasing by about 2.5°F. The extent of sea ice has been declining, as has been widely published in both national and scientific media outlets, and is projected to continue to decline during this century. The observed decline in annual sea ice minimum extent (September) has occurred more rapidly than was predicted by climate models and has been accompanied by decreases in ice thickness and in the presence of multi-year ice. This decrease was first documented by satellite imagery in the late 1970s for the Bering and Chukchi Seas, and is projected to continue, with the potential for the disappearance of summer sea ice by mid- to late century. A new phenomenon that was not reported in previous assessments is ocean acidification. Uptake of carbon dioxide (CO2) by oceans has a significant effect on marine biogeochemistry by reducing seawater pH. Ocean acidification is of particular concern in Alaska, because cold sea water absorbs CO2 more rapidly than warm water, and a decrease in sea ice extent has allowed increased sea surface exposure and more uptake of CO2 into these northern waters. Ocean acidification will likely affect the ability of organisms to produce and maintain shell material, such as aragonite or calcite (calcium carbonate minerals structured from carbonate ions), required by many shelled organism, from mollusks to corals to microscopic organisms at the base of the food chain. Direct biological effects in Alaska further along the food chain have yet to be studied and may vary among organisms. Some of the potentially most significant changes to Alaska that could result from a changing climate are the effects on the terrestrial cryosphere - particularly glaciers and permafrost. Alaskan glaciers are changing at a rapid rate, the primary driver appearing to be temperature. Statewide, glaciers lost 13 cubic miles of ice annually from the 1950s to the 1990s, and that rate doubled in the 2000s. However, like temperature and precipitation, glacier ice loss is not spatially uniform; most glaciers are losing mass, yet some are growing (for example Hubbard Glacier in southeast Alaska). Alaska glaciers with the most rapid loss are those terminating in sea water or lakes. With this increasing rate of melt, the contribution of surplus fresh water entering into the oceans from Alaska's glaciers, as well as those in neighboring British Columbia, Canada, is approximately 20 percent of that contributed by the Greenland Ice Sheet. Permafrost degradation (that is, the thawing of ice-rich soils) is currently (2012) impacting infrastructure and surface-water availability in areas of both discontinuous and continuous ground ice. Over most of the State, the permafrost is warming, with increasing temperatures broadly consistent with increasing air temperatures. On the Arctic coastal plain of Alaska, permafrost temperatures showed some cooling in the 1950s and 1960s but have been followed by a roughly 5°F increase since the 1980s. Many areas in the continuous permafrost zone have seen increases in temperature in the seasonally active layer and a decrease in re-freezing rates. Changes in the discontinuous permafrost zone are initially much more observable due to the resulting thermokarst terrain (land surface formed as ice rich permafrost thaws), most notable in boreal forested areas. Climate warming in Alaska has potentially broad implications for human health and food security, especially in rural areas, as well as increased risk for injury with changing winter ice conditions. Additionally, such warming poses the potential for increasing damage to existing water and sanitation facilities and challenges for development of new facilities, especially in areas underlain by permafrost. Non-infectious and infectious diseases also are becoming an increasing concern. For example, from 1999 to 2006 there was a statistically significant increase in medical claims for insectbite reactions in five of six regions of Alaska, with the largest percentage increase occurring in the most northern areas. The availability and quality of subsistence foods, normally considered to be very healthy, may change due to changing access, changing habitats, and spoilage of meat in food storage cellars. These and other trends and potential outcomes resulting from a changing climate are further described in this report. In addition, we describe new science leadership activities that have been initiated to address and provide guidance toward conducting research aimed at making available information for policy makers and land management agencies to better understand, address, and plan for changes to the local and regional environment. This report cites data in both metric and standard units due to the contributions by numerous authors and the direct reference of their data.

Alaska↗

Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment↗

Seismic hazards and land-use planning

Basic earth-science data are necessary for a realistic assessment of seismic hazards and as a basis for limiting corrective land-use controls only to those areas of greatest hazard. For example, the location, character, and amount of likely displacement and activity of surface faulting can be predicted if detailed geologic maps and seismic data are available and are augmented by field studies at critical localities. Because few structures can withstand displacement of their foundations, they should be located off active fault traces, the distance varying with the character of faulting, the certainty with which fault traces are known, and the importance of the structure. Recreational activities and other nonoccupancy land uses should be considered for fault zone areas where land is under pressure for development; elsewhere, such areas should remain as open space. Two methods of predicting ground shaking effects have applications to land-use decisions: (1) Relative earthquake effects can be related to firmness of the ground and can be used in a gross way to allocate population density in the absence of more sophisticated analyses; and (2) intensity maps, based on, (a) damage from former earthquakes, or (b) a qualitative analyses of geologic units added to a design earthquake, can be helpful both for general and specific plans. Theoretical models are used with caution to predict ground motion for critical structures to be located at specific sites with unique foundation conditions. Fully adequate methods of assessing possible shaking remain to be developed. Where land-use decisions do not reflect likely ground shaking effects, stringent building codes are needed, particularly for important structures. Ground failure (landsliding, ground cracking and lurching, differential settlement, sand boils, and subsidence) commonly results from liquefaction, loss of soil strength, or compaction. Areas suspected of being most likely to fail should not be developed unless detailed site studies can demonstrate the hazard does not exist or can be overcome. Various methods can be used to reduce the high, long-term public costs that follow development of unstable ground. However, areas subject to tectonic deformation generally cannot be predicted nor can effects of such deformation be minimized. Large water waves, such as produced by tsunamis, seiches, and dam failure or overtopping, can be anticipated in many places. Their effects can be lessened by land-use regulations similar to flood-plain zoning, restrictions on location of critical structures, and appropriate warning systems. Many local, state, and federal government agencies, universities, and private consultants may be able to assist planners by advising them of pertinent data and where those data can be obtained. Interpretation of the data for an evaluation of seismic risk commonly requires a team of planners, geologists, and soil and structural engineers.

Circular↗

Modifications to EPA Method 3060A to Improve Extraction of Cr(VI) from Chromium Ore Processing Residue-Contaminated Soils

It has been shown that EPA Method 3060A does not adequately extract Cr(VI) from chromium ore processing residue (COPR). We modified various parameters of EPA 3060A toward understanding the transformation of COPR minerals in the alkaline extraction and improving extraction of Cr(VI) from NIST SRM 2701, a standard COPR-contaminated soil. Aluminum and Si were the major elements dissolved from NIST 2701, and their concentrations in solution were correlated with Cr(VI). The extraction fluid leached additional Al and Si from the method-prescribed borosilicate glass vessels which appeared to suppress the release of Cr(VI). Use of polytetrafluoroethylene vessels and intensive grinding of NIST 2701 increased the amount of Cr(VI) extracted. These modifications, combined with an increased extraction fluid to sample ratio of ≥900 mL g –1 and 48-h extraction time resulted in a maximum release of 1274 ± 7 mg kg –1 Cr(VI). This is greater than the NIST 2701 certified value of 551 ± 35 mg kg –1 but less than 3050 mg kg –1 Cr(VI) previously estimated by X-ray absorption near edge structure spectroscopy. Some of the increased Cr(VI) may have resulted from oxidation of Cr(III) released from brownmillerite which rapidly transformed during the extractions. Layered-double hydroxides remained stable during extractions and represent a potential residence for unextracted Cr(VI).

Environmental Science & Technology↗

The approaching obsolescence of 137Cs dating of wetland soils in North America

The peak fallout in 1963 of the radionuclide 137 Cs has been used to date lake, reservoir, continental shelf, and wetland sedimentary deposits. In wetlands such dating is used to project the ability of wetlands to keep pace with sea level rise and develop strategies for mitigating carbon pollution using biological carbon sequestration. Here we demonstrate that reliable 137 Cs profiles are increasingly difficult to obtain from wetland soils. Among 58 soil cores recently collected from a range of wetland types and 137 Cs fallout densities across the United States, 25% contain no identifiable 137 Cs peaks. Less than 40% of 137 Cs ages are consistent with 210 Pb dating. We provide a new measure of 137 Cs peak clarity (τ) for our core dataset by comparing the 50% interquartile range of data around the 137 Cs peak for “ideal” cores profiles determined using 137 Cs fallout data to that of observed core profiles. Our results show that overall τ is approximately 10 times greater for observed cores than ideal cores. The deterioration in the 137 Cs peak has occurred due to radionuclide decay, 137 Cs migration in situ , which is ubiquitous in this study, and 137 Cs amendments from surface waters. Such deterioration likely extends to both Mexican and non-permafrost, Canadian wetlands. We recommend continued use of 137 Cs only if the full bound of dating uncertainty for both 137 Cs and an additional method such as 210 Pb is propagated into estimates of wetland vertical accretion and carbon sequestration.

Quaternary Science Reviews↗

Metal and sediment ingestion by dabbling ducks

The chemical analysis of intestinal digesta from hunter-killed carcasses or of wildlife scat is a promising means of estimating the exposure of wildlife to those environmental contaminants that, like lead, are poorly absorbed in the digestive tract. When evaluating contaminants at a site, biologists may find the results of this non-destructive approach more straightforward to interpret in terms of exposure to wildlife than would be analyses of soils, sediments, water, or wildlife tissues. To illustrate the approach, we collected digesta from 47 waterfowl shot by hunters at Prime Hook National Wildlife Refuge, in Delaware, USA. The waterfowl digesta contained an average of approximately 2.4% sediment, estimated from the Al concentrations in the digesta, a marker for sediment. Al concentrations were significantly correlated with concentrations of Cr (Spearman’s rank correlation coefficient, r= 0.57), V ( r =0.70), Ni ( r =0.31), and Pb ( r =0.55), and we concluded that these metals were ingested mainly with sediment. American widgeon ( Anas americana ) ingested sediment at a rate of about four times that of three other species of dabbling ducks ( Anas crecca , A. acuta , A. rubripes ) and had several times the exposure to the sediment-associated metals. The digesta of one American black duck contained a high concentration of lead (70 mg/kg, dry wt.), presumably from lead shot, but none of the other samples had notably elevated metal concentrations. We suggest that scat and digesta be analyzed more widely by biologists and resource managers seeking a simple, inexpensive assessment of contaminants in local wildlife habitat.

Science of the Total Environment↗

Hydrologic and microbiological factors affecting persistence and migration of petroleum hydrocarbons spilled in a continuous-permafrost region

Fuel spills, totaling about 1300 m3, occurred between 1976 and 1978 adjacent to Imikpuk Lake, a drinking water source near Barrow, AK. Substantial contamination of soils and groundwater near the lake persists. We examined the magnitude and direction of groundwater flux and the microbial activity at this site to understand the persistence of contamination and its effect on the lake. We found that groundwater flux is small due to shallow permafrost, which restricts the cross-sectional area available for flow, and to the short annual thaw season (ca. 90 days). The small flux and limited depth also constrain contaminant transport and dispersion, resulting in persistent, shallow contamination. The numbers of hydrocarbon-oxidizing microorganisms and their laboratory mineralization potentials for benzene (at 10 ??C) were higher in samples from contaminated areas than in reference samples. Benzene mineralization potentials in groundwater samples were comparable to more temperate systems (0.1-0.5 mg of benzene mineralized L-1 day-1) and were stimulated by nutrient additions. Field measurements of dissolved oxygen, nitrate, ferrous iron, and sulfide in groundwater provided evidence that biodegradation of petroleum hydrocarbons is occurring in situ. Despite evidence of an active microbial population, microbial processes, like contaminant transport, are likely limited at this site by the short annual thaw season.

Environmental Science & Technology↗

Hillslope-scale experiment demonstrates role of convergence during two-step saturation

Subsurface flow and storage dynamics at hillslope scale are difficult to ascertain, often in part due to a lack of sufficient high-resolution measurements and an incomplete understanding of boundary conditions, soil properties, and other environmental aspects. A continuous and extreme rainfall experiment on an artificial hillslope at Biosphere 2's Landscape Evolution Observatory (LEO) resulted in saturation excess overland flow and gully erosion in the convergent hillslope area. An array of 496 soil moisture sensors revealed a two-step saturation process. First, the downward movement of the wetting front brought soils to a relatively constant but still unsaturated moisture content. Second, soils were brought to saturated conditions from below in response to rising water tables. Convergent areas responded faster than upslope areas, due to contributions from lateral subsurface flow driven by the topography of the bottom boundary, which is comparable to impermeable bedrock in natural environments. This led to the formation of a groundwater ridge in the convergent area, triggering saturation excess runoff generation. This unique experiment demonstrates, at very high spatial and temporal resolution, the role of convergence on subsurface storage and flow dynamics. The results bring into question the representation of saturation excess overland flow in conceptual rainfall-runoff models and land-surface models, since flow is gravity-driven in many of these models and upper layers cannot become saturated from below. The results also provide a baseline to study the role of the co-evolution of ecological and hydrological processes in determining landscape water dynamics during future experiments in LEO.

Hydrology and Earth System Sciences↗

Management and natural regeneration in multiple ponderosa pine forests of the southwestern United States

Management treatments in ponderosa pine forests of the southwestern United States (SWUS) are largely done for wildfire mitigation and restoration to lower tree densities. However, lack of natural ponderosa pine regeneration in undisturbed forests (i.e., no occurrence of stand-replacing events) may require management treatments to promote regeneration. We conducted a field and modeling study in 77 ponderosa pine forests across 7 SWUS locations, with the goal of evaluating management impacts on recent natural regeneration ( ∼ "> ∼ 20 y). We categorized management into 3 broad categories: unmanaged, thinned from above and/or below (thinning), and thinned + "> + understory burned (burning). Although climate suitability declined from 1981-2020, management treatments – especially burning – promoted natural regeneration. High density regeneration, an undesirable outcome, occurred in 21 % "> % of managed sites. In addition to effects on near-surface temperature and soil moisture, management conducive to natural regeneration was associated with the density of competing tree species, understory litter and debris cover, and adult tree cone production. Natural regeneration occurred ∼ "> ∼ 5-10 y following management, underscoring sustained effects of management treatments on tree reproduction success. Our results show that forest management treatments have the potential to promote natural ponderosa pine regeneration in the SWUS, sometimes at undesirable high densities. Study Implications: Natural ponderosa pine regeneration is declining in forests of the southwestern United States (SWUS), and may increasingly be incorporated as a goal of forest management treatments. Across a diverse set of managed and unmanaged SWUS forest sites, we found that contemporary management treatments – especially thinning + "> + prescribed understory burning – supported natural ponderosa pine regeneration over the past two decades, which were climatically unfavorable in much of the region. Our results show that existing forest management treatments have the potential to promote natural ponderosa pine regeneration in the SWUS, but will require assessment and modification through time to remain effective.

Forest Science↗