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A national reconnaissance for pharmaceuticals and other organic wastewater contaminants in the United States - II) Untreated drinking water sources

Numerous studies have shown that a variety of manufactured and natural organic compounds such as pharmaceuticals, steroids, surfactants, flame retardants, fragrances, plasticizers and other chemicals often associated with wastewaters have been detected in the vicinity of municipal wastewater discharges and livestock agricultural facilities. To provide new data and insights about the environmental presence of some of these chemicals in untreated sources of drinking water in the United States targeted sites were sampled and analyzed for 100 analytes with sub-parts per billion detection capabilities. The sites included 25 ground- and 49 surface-water sources of drinking water serving populations ranging from one family to over 8 million people. Sixty-three of the 100 targeted chemicals were detected in at least one water sample. Interestingly, in spite of the low detection levels 60% of the 36 pharmaceuticals (including prescription drugs and antibiotics) analyzed were not detected in any water sample. The five most frequently detected chemicals targeted in surface water were: cholesterol (59%, natural sterol), metolachlor (53%, herbicide), cotinine (51%, nicotine metabolite), β-sitosterol (37%, natural plant sterol), and 1,7-dimethylxanthine (27%, caffeine metabolite); and in ground water: tetrachloroethylene (24%, solvent), carbamazepine (20%, pharmaceutical), bisphenol-A (20%, plasticizer), 1,7-dimethylxanthine (16%, caffeine metabolite), and tri (2-chloroethyl) phosphate (12%, fire retardant). A median of 4 compounds were detected per site indicating that the targeted chemicals generally occur in mixtures (commonly near detection levels) in the environment and likely originate from a variety of animal and human uses and waste sources. These data will help prioritize and determine the need, if any, for future occurrence, fate and transport, and health-effects research for subsets of these chemicals and their degradates most likely to be found in water resources used for drinking water in the United States.

Science of the Total Environment↗

Report on the 2010 Chilean earthquake and tsunami response

In July 2010, in an effort to reduce future catastrophic natural disaster losses for California, the American Red Cross coordinated and sent a delegation of 20 multidisciplinary experts on earthquake response and recovery to Chile. The primary goal was to understand how the Chilean society and relevant organizations responded to the magnitude 8.8 Maule earthquake that struck the region on February 27, 2010, as well as how an application of these lessons could better prepare California communities, response partners and state emergency partners for a comparable situation. Similarities in building codes, socioeconomic conditions, and broad extent of the strong shaking make the Chilean earthquake a very close analog to the impact of future great earthquakes on California. To withstand and recover from natural and human-caused disasters, it is essential for citizens and communities to work together to anticipate threats, limit effects, and rapidly restore functionality after a crisis. The delegation was hosted by the Chilean Red Cross and received extensive briefings from both national and local Red Cross officials. During nine days in Chile, the delegation also met with officials at the national, regional, and local government levels. Technical briefings were received from the President’s Emergency Committee, emergency managers from ONEMI (comparable to FEMA), structural engineers, a seismologist, hospital administrators, firefighters, and the United Nations team in Chile. Cities visited include Santiago, Talca, Constitución, Concepción, Talcahuano, Tumbes, and Cauquenes. The American Red Cross Multidisciplinary Team consisted of subject matter experts, who carried out special investigations in five Teams on the (1) science and engineering findings, (2) medical services, (3) emergency services, (4) volunteer management, and (5) executive and management issues (see appendix A for a full list of participants and their titles and teams). While developing this delegation, it was clear that a multidisciplinary approach was required to properly analyze the emergency response, technical, and social components of this disaster. A diverse and knowledgeable delegation was necessary to analyze the Chilean response in a way that would be beneficial to preparedness in California, as well as improve mitigation efforts around the United States. By most standards, the Maule earthquake was a catastrophe for Chile. The economic losses totaled $30 billion USD or 17% of the GDP of the country. Twelve million people, or ¾ of the population of the country, were in areas that felt strong shaking. Yet only 521 fatalities have been confirmed, with 56 people still missing and presumed dead in the tsunami. The Science and Technology Team evaluated the impacts of the earthquake on built environment with implications for the United States. The fires following the earthquake were minimal in part because of the shutdown of the national electrical grid early in the shaking. Only five engineer-designed buildings were destroyed during the earthquake; however, over 350,000 housing units were destroyed. Chile has a law that holds building owners liable for the first 10 years of a building’s existence for any losses resulting from inadequate application of the building code during construction. This law was cited by many our team met with as a prime reason for the strong performance of the built environment. Overall, this earthquake demonstrated that strict building codes and standards could greatly reduce losses in even the largest earthquakes. In the immediate response to the earthquake and tsunami, first responders, emergency personnel, and search and rescue teams handled many challenges. Loss of communications was significant; many lives were lost and effective coordination to support life-sustaining efforts was gravely impacted due to a lack of inter- and intra-agency coordination. The Health and Medical Services Team sought to understand the medical disaster response strategies and operations of Chilean agencies, including perceived or actual failures in disaster preparation that impacted the medical disaster response; post-disaster health and medical interventions to save lives and limit suffering; and the lessons learned by public health and medical personnel as a result of their experiences. Despite devastating damage to the health care and civic infrastructure, the health care response to the Chilean earthquake appeared highly successful due to several factors. Like other first responders, the medical community had the ability and resourcefulness to respond without centralized control in the early response phase. The health care community maintained patient care under austere conditions, despite many obstacles that could have prevented such care. National and international resources were rapidly mobilized to support the medical response. The Emergency Services Team sought to collect information on all phases of emergency management (preparedness, mitigation, response, and recovery) and determine what worked well and what could be improved upon. The Chileans reported being surprised that they were not as ready for this event as they thought they were. The use of mass care sheltering was limited, given the scope of the disaster, because of the resiliency of the population. The impacts of the earthquake and the tsunami were quite different, as were the needs of urban and rural dwellers, necessitating different response activities. The Volunteer Services Team examined the challenges faced in mobilizing a large number of volunteers to assist in the aftermath of a disaster of this scale. One of the greatest challenges expressed was difficulty in communication; the need for redundancy in communication mechanisms was cited. The flexibility and ability to work autonomously by the frontline volunteers was a significant factor in effective response. It was also important for volunteer leadership to know the emergency plans. These plans need to be flexible, include alternative options, and be completed in conjunction with local officials and other volunteers. The Executive/Red Cross Management Team took a broad look at the impacts of the earthquake and the implications for California. Some of the most important preparation for the disaster came from relationships formed before the event. The communities with strong connections between different government services generally fared well. The initial response and resilience of individuals and communities was another important component. Communication system failures limited the ability of a central government to assist impacted communities, or to issue tsunami warnings. It also delayed the response since the government did not know (in some case for several days) the impact and needs of local governments. In general, plans for congregate care shelters existed but were little used as most people chose to stay at damaged homes or with relatives. Looting was a surprise to response officials as well as social scientists, but both public and private sector organizations, including NGOs (Non-Governmental Organizations), must consider security for damaged businesses as a priority in California’s multihazard planning. Class and ethnic divisions that become heightened during some cases of actual or perceived injustice may also emerge in natural disasters in California. Several factors contributed overall to the low casualty rate and rapid recovery. A major factor is the strong building code in Chile and its comprehensive enforcement. In particular, Chile has a law that holds building owners accountable for losses in a building they build for 10 years. A second factor was the limited number of fires after the earthquake. In the last few California earthquakes, 60% of the fires were started by electrical problems, so the rarity of fires may have been affected by the shut down of the electricity grid early in the earthquake. Third, in many areas, the local emergency response was very effective. The most effective regions had close coordination between emergency management, fire, and police and were empowered to respond without communication with the capital. The fourth factor was the overall high level of knowledge about earthquakes and tsunamis by much of the population that helped them respond more appropriately after the event.

Open-File Report↗

Hydrogeology and water quality of the Shell Valley Aquifer, Rolette County, North Dakota

The Shell Valley aquifer is the sole source of water for the city of Belcourt and the primary source of water for most of the Turtle Mountain Indian Reservation. The Turtle Mountain Band of Chippewa Indians is concerned about the quantity and quality of water in the Shell Valley aquifer, which underlies about 56 square miles in central Rolette County and has an average saturated thickness of about 35 feet. Water levels across most of the Shell Valley aquifer fluctuate with variations in precipitation but generally are stable. Withdrawals from the north well field decreased slightly during 1976-95, but withdrawals from the south well field increased during 1983-95. Water levels in the south well field declined as withdrawals increased. The average decline during the last 8 years was about 1.75 feet per year. The water level has reached the well screen in at least one of the production wells. Most of the water in the aquifer is a bicarbonate type and has dissolved-solids concentrations ranging from 479 to 1,510 milligrams per liter. None of the samples analyzed had detectable concentrations of pesticides, but hydrocarbons were detected in both ground- and surfacewater samples. Polycyclic aromatic hydrocarbons (PAH) were the most frequently detected hydrocarbons. Benzene, toluene, ethylbenzene, and xylene (BTEX), polychlorinated biphenyls (PCB), and pentachlorophenol (PCP) also were detected. Generally, the Shell Valley aquifer is an adequate source of water for current needs, but evaluation of withdrawals in relation to a knowledge of aquifer hydrology would be important in quantifying sustainable water supplies. Water quality in the aquifer generally is good; the Turtle Mountain Band of Chippewa Indians filters the water to reduce concentrations of dissolved constituents. Hydrocarbons, although present in the aquifer, have not been quantified and may not pose a general health risk. Further analysis of the quantity and distribution of the hydrocarbons would be useful to understand their sources and implications for water use.

Water-Resources Investigations Report↗

Development of a 14-digit Hydrologic Unit Code Numbering System for South Carolina

A Hydrologic Unit Map showing the cataloging units, watersheds, and subwatersheds of South Carolina has been developed by the U.S. Geological Survey in cooperation with the South Carolina Department of Health and Environmental Control, funded through a U.S. Environmental Protection Agency 319 Grant, and the U.S. Department of Agriculture, Natural Resources Conservation Service. These delineations represent 8-, 11-, and 14-digit Hydrologic Unit Codes, respectively. This map presents information on drainage, hydrography, and hydrologic boundaries of the water-resources regions, subregions, accounting units, cataloging units, watersheds, and subwatersheds. The source maps for the basin delineations are 1:24,000-scale 7.5-minute series topographic maps and the base maps are from 1:100,000-scale Digital Line Graphs; however, the data are published at a scale of 1:500,000. In addition, an electronic version of the data is provided on a compact disc. Of the 1,022 subwatersheds delineated for this project, 1,004 range in size from 3,000 to 40,000 acres (4.69 to 62.5 square miles). Seventeen subwatersheds are smaller than 3,000 acres and one subwatershed, located on St. Helena Island, is larger than 40,000 acres. This map and its associated codes provide a standardized base for use by water-resource managers and planners in locating, storing, retrieving, and exchanging hydrologic data. In addition, the map can be used for cataloging water-data acquisition activities, geographically organizing hydrologic data, and planning and describing water-use and related land-use activities.

South Carolina↗

Observational, virological, and serological data provide insights into an outbreak of highly pathogenic avian influenza among wild birds on the Yukon-Kuskokwim Delta, Alaska in 2022

In 2021–22, clade 2.3.4.4b highly pathogenic avian influenza (HPAI) viruses were introduced by wild birds into North America, leading to geographically widespread disease. In response to HPAI outbreaks throughout late 2021 and early 2022, we recorded observations of sick and dead birds, estimated abundance of carcasses, collected swab and sera samples to detect viruses, and monitored bird nesting on the Yukon-Kuskokwim Delta region of Alaska to document potential effects of disease. Thirty-six reports of sick and dead birds were registered across the region. Nineteen carcasses were opportunistically collected for diagnostic testing, of which 12 were confirmed to be infected with clade 2.3.4.4b HPAI viruses. Carcass abundance estimates from line-distance sampling provided evidence that the most common species of dead birds from the western Yukon-Kuskokwim Delta region were Cackling Goose ( Branta hutchinsii minima ), Glaucous Gull ( Larus hyperboreus ), and Black Brant ( Branta bernicla nigricans ). Only one paired cloacal and oropharyngeal swab sample from a Northern Pintail ( Anas acuta ) tested positive for clade 2.3.4.4b HPAI virus, out of 464 live-captured duck and goose samples. Of 195 sera samples from waterfowl screened for antibodies reactive to influenza A viruses, antibodies were found in 41–98% of samples collected from Emperor Goose ( Anser canagicus ), Cackling Goose, Black Brant, and Spectacled Eider ( Somateria fischeri ). In addition, 15–98% of the same sera samples were reactive to a clade 2.3.4.4b H5 antigen. Fewer Black Brant and Emperor Goose nests were found on long-term study plots during 2022 than in previous years. Collectively, we found that HPAI viruses affected at least seven species of wild birds inhabiting the region during 2022. The full scope of impacts of HPAI at this location during 2022 is unknown, but our data indicate that acute effects to avian population health on the Yukon-Kuskokwim Delta region were likely modest.

Alaska↗

Water Quality in the Delmarva Peninsula, Delaware, Maryland, and Virginia, 1999-2001

This report contains the major findings of a 1999-2001 assessment of water quality in the Delmarva Peninsula. It is one of a series of reports by the National Water-Quality Assessment (NAWQA) Program that present major findings in 51 major river basins and aquifer systems across the Nation. In these reports, water quality is assessed at many scales?from local ground-water flow paths to regional ground-water networks and in surface water?and is discussed in terms of local, State, and regional issues. Conditions in the Delmarva Peninsula are compared to conditions found elsewhere and to selected national benchmarks, such as those for drinking-water quality and the protection of aquatic organisms. This report is intended for individuals working with water-resource issues in Federal, State, or local agencies; universities; public interest groups; or in the private sector. The information will be useful in addressing a number of current issues, such as the effects of agricultural and urban land use on water quality, human health, drinking water, source-water protection, hypoxia and excessive growth of algae and plants, pesticide registration, and monitoring and sampling strategies. This report is also for individuals who wish to know more about the quality of streams and ground water in areas near where they live, and how that water quality compares to the quality of water in other areas across the Nation. Other products describing water-quality conditions in the Delmarva Peninsula are available. Detailed technical information, data and analyses, methodology, models, graphs, and maps that support the findings presented in this report can be accessed from http://md.water.usgs.gov/delmarva. Other reports in this series and data collected from other basins can be accessed from the national NAWQA Web site (http://water.usgs.gov/nawqa).

Circular↗

Evaluation of extraction methods for hexavalent chromium determination in dusts, ashes, and soils

One of the difficulties in performing speciation analyses on solid samples is finding a suitable extraction method. Traditional methods for extraction of hexavalent chromium, Cr(VI), in soils, such as SW846 Method 3060A, can be tedious and are not always compatible with some determination methods. For example, the phosphate and high levels of carbonate and magnesium present in the U.S. Environmental Protection Agency (USEPA) Method 3060A digestion for Cr(VI) were found to be incompatible with the High Performance Liquid Chromatography-Inductively Coupled Plasma-Mass Spectrometry (HPLC-ICP-MS) detection method used by our laboratory. Modification of Method 3060A by eliminating the use of the phosphate buffer provided improved performance with the detection method, however dilutions are still necessary to achieve good chromatographic separation and detection of Cr(VI). An ultrasonic extraction method using a 1 mM Na2CO3 - 9 mM NaHCO3 buffer solution, adapted from Occupational Safety and Health Administration (OSHA) Method ID215, has been used with good results for the determination of Cr(VI) in air filters. The average recovery obtained for BCR-545 - Welding Dust Loaded on Filter (IRMM, Belgium) using this method was 99 percent (1.2 percent relative standard deviation) with no conversion of Cr(VI) to Cr(III) during the extraction process. This ultrasonic method has the potential for use with other sample matrices, such as ashes and soils. Preliminary investigations using NIST 2701 (Hexavalent Chromium in Contaminated Soil) loaded onto quartz filters showed promising results with approximately 90 percent recovery of the certified Cr(VI) value. Additional testing has been done using NIST 2701 and NIST 2700 using different presentation methods. Extraction efficiency of bulk presentation, where small portions of the sample are added to the bottom of the extraction vessel, will be compared with supported presentation, where small portions of the sample are loaded onto a quartz filter prior to extraction. In addition, results obtained from the standard grinding preparation of NIST 2701 and NIST 2700 will be compared with micronizing to reduce particle size before extraction.

Open-File Report↗

Predevelopment Water-Level Contours for Aquifers in the Rainier Mesa and Shoshone Mountain area of the Nevada Test Site, Nye County, Nevada

Contaminants introduced into the subsurface of the Nevada Test Site at Rainier Mesa and Shoshone Mountain by underground nuclear testing are of concern to the U.S. Department of Energy and regulators responsible for protecting human health and safety. Although contaminants were introduced into low-permeability rocks above the regional flow system, the potential for contaminant movement away from the underground test areas and into the accessible environment is greatest by ground-water transport. The primary hydrologic control on this transport is evaluated and examined through a series of contour maps developed to represent the water-level distribution within each of the major aquifers underlying the area. Aquifers were identified and their extents delineated by merging and analyzing multiple hydrostratigraphic framework models developed by other investigators from existing geologic information. The contoured water-level distribution in each major aquifer was developed from a detailed evaluation and assessment of available water-level measurements. Multiple spreadsheets that accompany this report provide pertinent water-level and geologic data by well or drill hole. Aquifers are mapped, presented, and discussed in general terms as being one of three aquifer types?volcanic aquifer, upper carbonate aquifer, or lower carbonate aquifer. Each of these aquifer types was subdivided and mapped as independent continuous and isolated aquifers, based on the continuity of its component rock. Ground-water flow directions, as related to the transport of test-generated contaminants, were developed from water-level contours and are presented and discussed for each of the continuous aquifers. Contoured water-level altitudes vary across the study area and range from more than 5,000 feet in the volcanic aquifer beneath a recharge area in the northern part of the study area to less than 2,450 feet in the lower carbonate aquifer in the southern part of the study area. Variations in water-level altitudes within any single continuous aquifer range from a few hundred feet in a lower carbonate aquifer to just more than 1,100 feet in a volcanic aquifer. Flow directions throughout the study area are dominantly southward with minor eastward or westward deviations. Primary exceptions are westward flow in the northern part of the volcanic aquifer and eastward flow in the eastern part of the lower carbonate aquifer. Northward flow in the upper and lower carbonate aquifers in the northern part of the study area is possible but cannot be substantiated because data are lacking. Interflow between continuous aquifers is evaluated and mapped to define major flow paths. These flow paths delineate tributary flow systems, which converge to form the regional ground-water flow system. The implications of these tributary flow paths in controlling transport away from the underground test areas at Rainier Mesa and Shoshone Mountain are discussed. The obvious data gaps contributing to uncertainties in the delineation of aquifers and development of water-level contours are identified and evaluated.

Scientific Investigations Report↗

Decreased mortality of lake michigan chinook salmon after bacterial kidney disease challenge: Evidence for pathogen-driven selection?

In the late 1960s, Chinook salmon Oncorhynchus tshawytscha from the Green River, Washington, were successfully introduced into Lake Michigan. During spring from1988 to 1992, large fish die-offs affecting Chinook salmon occurred in the lake. Multiple ecological factors probably contributed to the severity of the fish kills, but the only disease agent found regularly was Renibacterium salmoninarum, the causative agent of bacterial kidney disease. in this study, survival after challenge by R. salmoninarum was compared between two Chinook salmon stocks: a Lake Michigan stock from Wisconsin (WI) and the progenitor stock from the Green River. We found that the WI stock had significantly greater survival than the Green River stock. Next, the WI and Green River stocks were exposed to the marine pathogen Listonella anguillarum (formerly Vibrio anguillarum), one of the causative agents of vibriosis; survival after this challenge was significantly poorer for the WI stock than for the Green River stock. A close genetic relationship between the Green River and WI stocks was confirmed by analyzing 13 microsatellite loci. These results collectively suggest that disease susceptibility of Lake Michigan Chinook salmon has diverged from that of the source population, possibly in response to pathogen-driven selection. ?? Copyright by the American Fisheries Society 2008.

Journal of Aquatic Animal Health↗

Microbial pathogens in source and treated waters from drinking water treatment plants in the United States and implications for human health

An occurrence survey was conducted on selected pathogens in source and treated drinking water collected from 25 drinking water treatment plants (DWTPs) in the United States. Water samples were analyzed for the protozoa Giardia and Cryptosporidium (EPA Method 1623); the fungi Aspergillus fumigatus , Aspergillus niger and Aspergillus terreus (quantitative PCR [qPCR]); and the bacteria Legionella pneumophila (qPCR), Mycobacterium avium , M. avium subspecies paratuberculosis , and Mycobacterium intracellulare (qPCR and culture). Cryptosporidium and Giardia were detected in 25% and in 46% of the source water samples, respectively (treated waters were not tested). Aspergillus fumigatus was the most commonly detected fungus in source waters (48%) but none of the three fungi were detected in treated water. Legionella pneumophila was detected in 25% of the source water samples but in only 4% of treated water samples. M. avium and M. intracellulare were both detected in 25% of source water, while all three mycobacteria were detected in 36% of treated water samples. Five species of mycobacteria, Mycobacterium mucogenicum , Mycobacterium phocaicum , Mycobacterium triplex , Mycobacterium fortuitum , and Mycobacterium lentiflavum were cultured from treated water samples. Although these DWTPs represent a fraction of those in the U.S., the results suggest that many of these pathogens are widespread in source waters but that treatment is generally effective in reducing them to below detection limits. The one exception is the mycobacteria, which were commonly detected in treated water, even when not detected in source waters.

Science of the Total Environment↗

Temporally dense monitoring of pathogen occurrence at four drinking-water well sites – Insights and Implications

Yearlong, event based, microbiological and chemical sampling was conducted at four public water supply well sites spanning a range of geologic settings and well depths to look for correlation between precipitation events and microbial occurrence. Near-continuous monitoring using autosamplers occurred just before, during, and after 5–7 sampling events triggered by rainfall and/or snowmelt. Microbial genetic material was noted at all four locations during all but one sampling event, but was exceedingly variable in time, where one sample would have no detections and the next sample could be a relatively high concentration. The highest microbial sums (microbial concentrations summed over an event) were observed during months in which precipitation exceeded historical averages. Extended wet conditions through the spring thaw resulted in the highest percentage of microbial positive samples, though at relatively low concentrations. Sampling events that followed drier than normal periods showed longer lag times between the onset of precipitation and microbial occurrence, as well as lower microbial detection rates. Although a general lag time pattern was observed at each site, the largest offset in time was observed at the site with the greatest depth to water. The study's temporally dense representation of drinking water pathogen characterization suggests that single event or infrequent periodic sampling of a drinking water supply cannot provide a representative characterization of the probability that pathogens are present, which likely has ramifications for calculating health risk assessments.

Minnesota↗

Comparison of remote sensing indices for monitoring of desert cienegas

This research considers the applicability of different vegetation indices at 30 m resolution for mapping and monitoring desert wetland (cienega) health and spatial extent through time at Cienega Creek in southeastern Arizona, USA. Multiple stressors including the risk of decadal-scale drought, the effects of current and predicted global warming, and continued anthropogenic pressures threaten aquatic habitats in the southwest and cienegas are recognized as important sites for conservation and restoration efforts. However, cienegas present a challenge to satellite-imagery based analysis due to their small size and mixed surface cover of open water, exposed soils, and vegetation. We created time series of five well-known vegetation indices using annual Landsat Thematic Mapper (TM) images retrieved during the April–June dry season, from 1984 to 2011 to map landscape-level distribution of wetlands and monitor the temporal dynamics of individual sites. Indices included the Normalized Difference Vegetation Index (NDVI), the Soil-Adjusted Vegetation Index (SAVI), the Normalized Difference Water Index (NDWI), and the Normalized Difference Infrared Index (NDII). One topographic index, the Topographic Wetness Index (TWI), was analyzed to examine the utility of topography in mapping distribution of cienegas. Our results indicate that the NDII, calculated using Landsat TM band 5, outperforms the other indices at differentiating cienegas from riparian and upland sites, and was the best means to analyze change. As such, it offers a critical baseline for future studies that seek to extend the analysis of cienegas to other regions and time scales, and has broader applicability to the remote sensing of wetland features in arid landscapes.

Arizona↗

Pesticide Occurrence and Distribution in the Lower Clackamas River Basin, Oregon, 2000-2005

Pesticide occurrence and distribution in the lower Clackamas River basin was evaluated in 2000?2005, when 119 water samples were analyzed for a suite of 86?198 dissolved pesticides. Sampling included the lower-basin tributaries and the Clackamas River mainstem, along with paired samples of pre- and post-treatment drinking water (source and finished water) from one of four drinking water-treatment plants that draw water from the lower river. Most of the sampling in the tributaries occurred during storms, whereas most of the source and finished water samples from the study drinking-water treatment plant were obtained at regular intervals, and targeted one storm event in 2005. In all, 63 pesticide compounds were detected, including 33 herbicides, 15 insecticides, 6 fungicides, and 9 pesticide degradation products. Atrazine and simazine were detected in about half of samples, and atrazine and one of its degradates (deethylatrazine) were detected together in 30 percent of samples. Other high-use herbicides such as glyphosate, triclopyr, 2,4-D, and metolachlor also were frequently detected, particularly in the lower-basin tributaries. Pesticides were detected in all eight of the lower-basin tributaries sampled, and were also frequently detected in the lower Clackamas River. Although pesticides were detected in all of the lower basin tributaries, the highest pesticide loads (amounts) were found in Deep and Rock Creeks. These medium-sized streams drain a mix of agricultural land (row crops and nurseries), pastureland, and rural residential areas. The highest pesticide loads were found in Rock Creek at 172nd Avenue and in two Deep Creek tributaries, North Fork Deep and Noyer Creeks, where 15?18 pesticides were detected. Pesticide yields (loads per unit area) were highest in Cow and Carli Creeks, two small streams that drain the highly urban and industrial northwestern part of the lower basin. Other sites having relatively high pesticide yields included middle Rock Creek and upper Noyer Creek, which drain basins having nurseries, pasture, and rural residential land. Some concentrations of insecticides (diazinon, chlorpyrifos, azinphos-methyl, and p,p?-DDE) exceeded U.S. Environmental Protection Agency (USEPA) aquatic-life benchmarks in Carli, Sieben, Rock, Noyer, Doane, and North Fork Deep Creeks. One azinphos-methyl concentration in Doane Creek (0.21 micrograms per liter [?g/L]) exceeded Federal and State of Oregon benchmarks for the protection of fish and benthic invertebrates. Concentrations of several other pesticide compounds exceeded non-USEPA benchmarks. Twenty-six pesticides or degradates were detected in the Clackamas River mainstem, typically at much lower concentrations than those detected in the lower-basin tributaries. At least 1 pesticide was detected in 65 percent of 34 samples collected from the Clackamas River, with an average of 2?3 pesticides per sample. Pesticides were detected in 9 (or 60 percent) of the 15 finished water samples collected from the study water-treatment plant during 2003?2005. These included 10 herbicides, 1 insecticide, 1 fungicide, 1 insect repellent, and 2 pesticide degradates. The herbicides diuron and simazine were the most frequently detected (four times each during the study), at concentrations far below human-health benchmarks?USEPA Maximum Contaminant Levels or U.S. Geological Survey human Health-Based Screening Levels (HBSLs). The highest pesticide concentration in finished drinking water was 0.18 ?g/L of diuron, which was 11 times lower than its low HBSL benchmark. Although 0?2 pesticides were detected in most finished water samples, 9 and 6 pesticides were detected in 2 storm-associated samples from May and September 2005, respectively. Three of the unregulated compounds detected in finished drinking water (diazinon-oxon, deethylatrazine [CIAT], and N, N-diethyl-m-toluamide [DEET]) do not have human-health benchmarks available for comparison. Although most of the 51 curren

Scientific Investigations Report↗

Groundwater quality in the Madera and Chowchilla subbasins of the San Joaquin Valley, California

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s untreated groundwater quality and increases public access to groundwater-quality information. The Madera and Chowchilla subbasins of the San Joaquin Valley constitute one of the study units being evaluated. The Madera-Chowchilla study unit is about 860 square miles and consists of the Madera and Chowchilla groundwater subbasins of the San Joaquin Valley Basin (California Department of Water Resources, 2003; Shelton and others, 2009). The study unit has hot, dry summers and cool, moist winters. Average annual rainfall ranges from 11 to 15 inches, most of which occurs between November and February. The main surface-water features in the study unit are the San Joaquin, Fresno, and Chowchilla Rivers, and the Madera and Chowchilla canals. Land use in the study unit is about 69 percent (%) agricultural, 28% natural (mainly grasslands), and 3% urban. The primary crops are orchards and vineyards. The largest urban area is the city of Madera. The primary aquifer system is defined as those parts of the aquifer corresponding to the perforated intervals of wells listed in the California Department of Public Health (CDPH) database. In the Madera-Chowchilla study unit, these wells typically are drilled to depths between 200 and 800 feet, consist of a solid casing from land surface to a depth of about 140 to 400 feet, and are perforated below the solid casing. Water quality in the primary aquifer system may differ from that in the shallower and deeper parts of the aquifer system. The primary aquifer system in the study unit consists of Quaternary-age alluvial-fan and fluvial deposits that were formed by the rivers draining the Sierra Nevada. Sediments consist of gravels, sands, silts, and clays and generally are coarser closest to the Sierra Nevada and become finer towards the center of the basin. The structure and composition of the deposits in the Madera-Chowchilla study unit are different from those in other parts of the eastern San Joaquin Valley because the Fresno and Chowchilla Rivers primarily drain the Sierra Nevada foothills, whereas the larger rivers drain higher elevations with greater sediment supply. These differences in the sources of sediments are important because they may affect the groundwater chemistry and the physical structure of the sedimentary deposits. Some of the clay layers are lacustrine deposits, the most extensive of which, the Corcoran Clay, underlies the western part of the study unit and divides the primary aquifer system into an unconfined to semi-confined upper system and a largely confined lower system. Regional lateral flow of groundwater is southwest towards the valley trough. Irrigation return flows are the major source of groundwater recharge, and groundwater pumping is the major source of discharge. Groundwater on a lateral flow path may be repeatedly extracted by pumping wells and reapplied at the surface multiple times before reaching the valley trough, resulting in a substantial component of downward vertical flow (Burow and others, 2004; Phillips and others, 2007; Faunt, 2009). This flow pattern enhances movement of water from shallow depths to the primary aquifer system.

California↗

Predicted nitrate and arsenic concentrations in basin-fill aquifers of the Southwestern United States

The National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS) is conducting a regional analysis of water quality in the principal aquifer systems across the United States. The Southwest Principal Aquifers (SWPA) study is building a better understanding of the susceptibility and vulnerability of basin-fill aquifers in the region to groundwater contamination by synthesizing baseline knowledge of groundwater-quality conditions in 16 basins previously studied by the NAWQA Program. The improved understanding of aquifer susceptibility and vulnerability to contamination is assisting in the development of tools that water managers can use to assess and protect the quality of groundwater resources. Human-health concerns and economic considerations associated with meeting drinking-water standards motivated a study of the vulnerability of basin-fill aquifers to nitrate con­tamination and arsenic enrichment in the southwestern United States. Statistical models were developed by using the random forest classifier algorithm to predict concentrations of nitrate and arsenic across a model grid that represents about 190,600 square miles of basin-fill aquifers in parts of Arizona, California, Colorado, Nevada, New Mexico, and Utah. The statistical models, referred to as classifiers, reflect natural and human-related factors that affect aquifer vulnerability to contamina­tion and relate nitrate and arsenic concentrations to explana­tory variables representing local- and basin-scale measures of source, aquifer susceptibility, and geochemical conditions. The classifiers were unbiased and fit the observed data well, and misclassifications were primarily due to statistical sampling error in the training datasets. The classifiers were designed to predict concentrations to be in one of six classes for nitrate, and one of seven classes for arsenic. Each classification scheme allowed for identification of areas with concentrations that were equal to or exceeding the U.S. Environmental Protection Agency drinking-water standard. Whereas 2.4 percent of the area underlain by basin-fill aquifers in the study area was predicted to equal or exceed this standard for nitrate (10 milligrams per liter as N; mg/L), 42.7 percent was predicted to equal or exceed the standard for arsenic (10 micrograms per liter; μg/L). Areas predicted to equal or exceed the drinking-water standard for nitrate include basins in central Arizona near Phoenix; the San Joaquin, Inland, and San Jacinto basins of California; and the San Luis Valley of Colorado. Much of the area predicted to equal or exceed the drinking-water standard for arsenic is within a belt of basins along the western portion of the Basin and Range Physiographic Province in Nevada, California, and Arizona. Predicted nitrate and arsenic concentrations are substantially lower than the drinking-water standards in much of the study area—about 93.0 percent of the area underlain by basin-fill aquifers was less than one-half the standard for nitrate (5.0 mg/L), and 50.2 percent was less than one-half the standard for arsenic (5.0 μg/L).

Arizona, California, Colorado, Nevada, New Mexico,↗

Assessing population genomic structure and polyploidy: A crucial step for native plant restoration

Establishing an effective restoration program requires baseline genetic information to make sound decisions for seed increase and transfer. For many plants this information is lacking, especially among native forbs that are critical for pollinator health. Erigeron speciosus is a widespread, perennial forb occupying montane environments in the western United States and Canada. This species is important in fostering pollinator diversity. Our study examines the population genetic patterns across the species range using reduced-representation sequencing and surveys for genome duplication using flow cytometry and cytology. These genomic tools provide critical information for seed increase and seed transfer, necessary for restoration programs. Population genetic differentiation ( F ST ) average was 0.13 and ranged from 0.05 to 0.24 among 23 collection sites. Model-based Bayesian clustering supported a model with collection sites grouped into two populations, occupying distinct geographic regions of this species range. A genetic distance-based neighbor-joining tree also supported this division. Flow cytometry of 53 samples from 17 populations had 2C values that ranged from 1.7 to 3.6 pg with a mean 2C value of 2.3 pg. Putative triploids were found in two individuals from one collection site. The spatial distribution of genetic structure supports regionally based taxonomic descriptions of two varieties: speciosus in the North and macranthus in the South. This assessment of genetic structure and genome duplication describes an effective approach in developing baseline genetic information for restoration species, especially those species that may harbor complex taxonomy and polyploidy.

Colorado, Idaho, Montana, Oregon, South Dakota, Ut↗

Use of satellite imagery to identify vegetation cover changes following the Waldo Canyon Fire event, Colorado, 2012-2013

The Waldo Canyon Fire of 2012 was one of the most destructive wildfire events in Colorado history. The fire burned a total of 18,247 acres, claimed 2 lives, and destroyed 347 homes. The Waldo Canyon Fire continues to pose challenges to nearby communities. In a preliminary emergency assessment conducted in 2012, the U.S. Geological Survey (USGS) concluded that drainage basins within and near the area affected by the Waldo Canyon Fire pose a risk for future debris flow events. Rainfall over burned, formerly vegetated surfaces resulted in multiple flood and debris flow events that affected the cities of Colorado Springs and Manitou Springs in 2013. One fatality resulted from a mudslide near Manitou Springs in August 2013. Federal, State, and local governments continue to monitor these hazards and other post-fire effects, along with the region’s ecological recovery. At the request of the Colorado Springs Office of Emergency Management, the USGS Special Applications Science Center developed a geospatial product to identify vegetation cover changes following the 2012 Waldo Canyon Fire event. Vegetation cover was derived from July 2012 WorldView-2 and September 2013 QuickBird multispectral imagery at a spatial resolution of two meters. The 2012 image was collected after the fire had reached its maximum extent. Per-pixel increases and decreases in vegetation cover were identified by measuring spectral changes that occurred between the 2012 and 2013 image dates. A Normalized Difference Vegetation Index (NDVI), and Green-Near Infrared Index (GRNIR) were computed from each image. These spectral indices are commonly used to characterize vegetation cover and health condition, due to their sensitivity to detect foliar chlorophyll content. Vector polygons identifying surface-cover feature boundaries were derived from the 2013 imagery using image segmentation software. This geographic software groups similar image pixels into vector objects based upon their spatial and spectral characteristics. The vector dataset was then populated with the per-pixel spectral change information to provide an estimated percentage of vegetation increase or decrease of pixels within each polygon. Information collected during a field visit to the Waldo Canyon burn scar in September 2013 was used to help validate this assessment (see photographs 1-3). The numbers on the satellite images correspond to the location of the photographs. For display purposes, the polygons shown on the map represent areas where significant decrease or increase in vegetation cover occurred. Only polygons that held a 70 percent or greater cover change are shown on this map (a GIS dataset with complete information is available upon request). A significant increase in vegetation cover was found in the burned area. This increase is likely due to the growth of grasses and other herbaceous vegetation. Minimal vegetation cover decrease was detected at this threshold. This product is meant to provide a broad survey of post-fire vegetation trends within the Waldo Canyon burned area to Federal, State, and local officials. It is not designed to quantify species-level vegetation change at this time.

Colorado↗

Geohydrology of southwestern Kansas

Southwestern Kansas is one of the principal areas of ground-water development for irrigation in the State, and many reports are available concerning ground-water conditions in the area. The purposes of this investigation were to consolidate and update data, to determine the extent and effects of irrigation development on the ground-water resource, to determine the chemical quality of the ground water in relation to irrigation use, to describe the general operation of the hydrologic system, and to identify problem areas where intensive quantitative studies will be needed by State and local agencies for planning and management of the resource. This study began in 1972 as part of a cooperative program of ground-water investigations between the Kansas Geological Survey and the U.S. Geological Survey. Support in this study was provided by the Division of Water Resources of the Kansas State Board of Agriculture and the Division of Environment of the Kansas Department of Health and Environment.

Kansas↗