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At least 865 records · Page 48Linked to original sources
USGS2012

Presence of selected chemicals of emerging concern in water and bottom sediment from the St. Louis River, St. Louis Bay, and Superior Bay, Minnesota and Wisconsin, 2010

The St. Louis Bay of Lake Superior receives substantial urban runoff, wastewater treatment plant effluent, and industrial effluent. In 1987, the International Joint Commission designated the St. Louis Bay portion of the lower St. Louis River as one of the Great Lakes Areas of Concern. Concerns exist about the potential effects of chemicals of emerging concern on aquatic biota because many of these chemicals, including endocrine active chemicals, have been shown to affect the endocrine systems of fish. To determine the occurrence of chemicals of emerging concern in the St. Louis River, the St. Louis Bay, and Superior Bay, the U.S. Geological Survey in cooperation with the Minnesota Pollution Control Agency and the Wisconsin Department of Natural Resources collected water and bottom-sediment samples from 40 sites from August through October 2010. The objectives of this study were to (1) identify the extent to which chemicals of emerging concern, including pharmaceuticals, hormones, and other organic chemicals, occur in the St. Louis River, St. Louis Bay, and Superior Bay, and (2) identify the extent to which the chemicals may have accumulated in bottom sediment of the study area. Samples were analyzed for selected wastewater indicators, hormones, sterols, bisphenol A , and human-health pharmaceuticals. During this study, 33 of 89 chemicals of emerging concern were detected among all water samples collected and 56 of 104 chemicals of emerging concern were detected in bottom-sediment samples. The chemical N,N -diethyl- meta -toluamide (DEET) was the most commonly detected chemical in water samples and 2,6-dimethylnaphthalene was the most commonly detected chemical in bottom-sediment samples. In general, chemicals of emerging concern were detected at a higher frequency in bottom-sediment samples than in water samples. Estrone (a steroid hormone) and hexahydrohexamethyl cyclopentabensopyran (a synthetic fragrance) were the most commonly detected endocrine active chemicals in water samples; beta -sitosterol (a plant sterol), estrone, and 4- tert -octylphenol (an alkylphenol) were the most commonly detected endocrine active chemicals in bottom-sediment samples. The greater detection frequency of chemicals in bottom-sediment samples compared to the detection frequency in water samples indicates that bottom sediment is an important sink for chemicals of emerging concern. At least one polycyclic aromatic hydrocarbon was detected in every sample; and in most samples, all nine polycyclic aromatic hydrocarbons included in analyses were detected. Bottom sediment collected from Superior Bay had the most polycyclic aromatic hydrocarbon detections of the sediment sampling locations.

Minnesota;Wisconsin↗
USGS1994

Waterbird use of saltmarsh ponds created for open marsh water management

Open Marsh Water Management (OMWM) as an alternative to pesticides for mosquito control in saltmarshes along the Atlantic Coast has created debate among biologists. We designed an experiment to determine waterbird (American black duck [ Anas rubripe ]) and other waterfowl, wading birds, shorebirds, gulls, and terns) use (during daylight) of ponds created for mosquito control compared with use of pre-existing water bodies (i.e., natural tidal ponds, creeks, old ditches) and refuge impoundments. We also evaluated the influence of pond size and depth on waterbird use of wetlands. We documented bird use of different habitats for 1 year. The highest densities of waterfowl, in autumn, occurred in 0.030.06ha ponds ( P < 0.05) versus ponds either <0.02 ha or > 0.08 ha; highest shorebird densities occurred in summer in ponds > 0.10 ha ( P < 0.05). Pond depth affected shorebird and other waterfowl use in some seasons. Comparisons of mean number of birds using created (OMWM) ponds with mean number of birds using other water bodies revealed that most species showed no pattern (P <0.05) of disproportionate use versus availability. At high tidal levels, most species groups used OMWM ponds in the marsh more often ( P < 0.05) than other water bodies. Black ducks and other waterfowl used nearby refuge impoundments in higher densities than they did OMWM ponds, for nesting and during autumn-winter (all P s < 0.05). Creating small (> 0.1 ha) ponds for mosquito control does not enhance waterbird habitat, at least not where large impoundments are in close proximity. We recommend that in areas where OMWM practices seem appropriate, fewer large (gt 0.10 ha) ponds be constructed with shallow (< 15 cm) basins and sloping sides.

New Jersey↗
USGS1963

Public water supplies in Gloucester County, New Jersey

Gloucester County is in the southwestern part of New Jersey, below Camden, and is a part of the Lower Delaware River Valley. This area is attracting new industry and has shown a population increase of about 47 percent from 1950 to 1960, mostly urban. With the economic growth of the county, the availability and quality of water become increasingly important. The county is in the Coastal Plain of New Jersey. It is underlain by unconsolidated sands and clays of Quaternary, Tertiary, and Cretaceous age. The Raritan and Magothy Formations constitute the most important aquifers and yield more than 95 percent of the water pumped by the public water systems in the county. These formations are capable of yielding 1,400 gpm (gallons per minute) or more to large diameter wells. High yielding wells generally can be drilled anywhere in the county, although the formations are deeper toward the Atlantic Ocean. The Cohansey Sand, second most important aquifer, yields up to 800 gpm or more from large diameter wells. This aquifer is present only in the sparsely populated southeastern half of the county. The Wenonah Formation and Mount Laurel Sand are capable of yielding 100 to 200 gpm in certain areas. The overall chemical quality of the naturally occurring ground water is good. The water generally meets the U.S. Public Health Service's (1962) suggested limit for dissolved solids; however, in some areas, the water carries objectionable amounts of iron and nitrate in solution and has a low pH. Contamination of ground water by salt-water encroachment or by pollution from industrial activity or organic waste in densely populated areas should be prevented. The quality rather than the quantity of water may be the important factor in future ground-water developments. The 21 public water systems in Gloucester County pumped about 1.3 billion gallons of water during 1948 and some 2.7 billion gallons during 1959. This is slightly more than a hundred percent increase in pumpage in 12 year s. The average per capita public water supply consumption in 1959 was approximately 75 gallons per day. This report includes a summary of the history of the present installations, groundwater conditions, quality and availability of water, and potential future yield for the 2 public water systems in Gloucester County.

New Jersey↗
USGS2008

Hydrogeochemical investigation of the Standard Mine Vicinity, Upper Elk Creek Basin, Colorado

Ground- and surface-water samples were collected in the vicinity of the Standard Mine in west-central Colorado in order to characterize the local ground-water flow system, determine metal concentrations in local ground water, and better understand factors controlling the discharge of metal-rich waters from the mine. The sampling program included a one-time sampling of springs, mine adits, and exploration pits in Elk Basin and Redwell Basin; repeated sampling throughout one year of Standard Mine Level 1 discharge and Elk Creek near its confluence with Coal Creek; and a one-time sampling of underground sites in Levels 3 and 5 of the Standard Mine. Samples were analyzed for major ions and trace elements, stable isotopes of hydrogen (2H/1H) and oxygen (18O/16O), strontium isotopes, and tritium and dissolved noble gases (including helium isotopes) for tritium/helium-3 age dating. No clear correlations were observed between natural ground-water discharge locations and map-scale faults and lithology. Surface observations and the location of ground-water discharge suggest that simple topography, rather than large-scale geologic features, primarily controls the occurrence and flow of shallow ground water in Elk Basin. Discrete inflows from cross faults or other features were not observed in Levels 3 and 5 of the Standard Mine. Instead, water entered the mine as relatively persistent dripping from gouge and breccia within the Standard fault, which both tunnels follow. Therefore, the Standard fault itself is probably the main pathway of ground-water flow from the shallow subsurface to the mine workings. Low pH (as low as 3.2) and elevated concentrations of zinc, lead, cadmium, copper, and manganese (commonly exceeding water-quality standards for Elk Creek) were measured in samples located within or immediately downgradient of areas where sulfides are abundant, including the Standard fault, the Elk Lode portal, and the breccia pipe in Redwell Basin. Concentrations of these metals were typically low and pH values were circumneutral at surrounding locations. Metal concentrations in samples collected from underground workings in the Standard Mine were also generally higher than in samples collected at aboveground sites located outside of sulfide-rich areas. Metal concentrations in discharge from the Level 1 tunnel were among the highest measured in Elk Basin. All of these observations suggest that sulfide-rich mineralized rock is the primary control on dissolved metal concentrations and pH in ground water in the Standard Mine vicinity. Waste-rock piles apparently exert another major control on metal concentrations and pH; the lowest pH and highest metal concentrations typically are found in discharge from waste-rock piles. Concentrations of several chemical constituents along with strontium isotope data indicate that none of the sampled waters could have been the primary source of metals in discharge from Level 1. Therefore, this study did not identify the primary source location for metals in Level 1 discharge. Possible sources must be located below Levels 3 and 5 or farther back into the mountainside than the ends of Levels 3 and 5. Apparent tritium/helium-3 ground-water ages ranged from 0 to 9 yr, and a considerable majority were <1 yr. Tritium data and computed initial tritium values (measured tritium plus measured tritiogenic helium-3) suggest that much of the ground water in the Standard Mine vicinity was weeks to months old rather than years old. Tritium, d2H, and d18O data from water entering into and discharging from the Standard Mine displayed spatial and temporal patterns indicating that these tracers were influenced by seasonal variations in their concentration in precipitation. The tracer data therefore suggest that ground water entering into and discharging from the Standard Mine was largely composed of water <1 yr old. Pronounced seasonal variations in geochemistry in Level 1 discharge also are consistent with short r

Colorado↗
USGS2018

Ecosystems science: Genes to landscapes

Bountiful fisheries, healthy and resilient wildlife, flourishing forests and vibrant grasslands are coveted resources that benefit all Americans. U.S. Geological Survey (USGS) science supports the conservation and management of the Nation’s fish and wildlife, and the landscapes they inhabit. Our biological resources—ecosystems and the wild things that live in them—are the foundation of our conservation heritage and an economic asset to current and future generations of Americans. The USGS Ecosystems Mission Area, the biological research arm of the Department of the Interior (DOI), provides science to help America achieve sustainable management and conservation of its biological resources. This work is done within the broader mission of the USGS—to serve the Nation with science that advances understanding of our natural resources, informs land and water stewardship, and helps safeguard communities from natural and environmental hazards. The Ecosystems Mission Area provides research, technical assistance, and education conducted by Cooperative Research Units and Science Centers located in nearly every State. The quality of life and economic strength in America hinges on healthy ecosystems that support living things and natural processes. Ecosystem science better enables society to understand how and why ecosystems change and to guide actions that can prevent damage to, and restore and sustain ecosystems. It is through this knowledge that informed decisions are made about natural resources that can enhance our Nation’s economic and environmental well-being.

Fact Sheet↗
USGS1987

Surface-water-quality assessment of the Yakima River basin, Washington: Project description

In April 1986, the U.S. Geological Survey began the National Water Quality Assessment program to: (1) provide a nationally consistent description of the current status of water quality, (2) define water quality trends that have occurred over recent decades, and (3) relate past and present water quality conditions to relevant natural features, the history of land and water use, and land management and waste management practices. At present (1987), The National Water Quality Assessment program is in a pilot studies phase, in which assessment concepts and approaches are being tested and modified to prepare for possible full implementation of the program. Seven pilot projects (four surface water projects and three groundwater projects) have been started. The Yakima River basin in Washington is one of the pilot surface water project areas. The Yakima River basin drains in area of 6,155 sq mi and contains about 1,900 river mi of perennial streams. Major land use activities include growing and harvesting timber, dryland pasture grazing, intense farming and irrigated agriculture, and urbanization. Water quality issues that result from these land uses include potentially large concentrations of suspended sediment, bacteria, nutrients, pesticides, and trace elements that may affect water used for human consumption, fish propagation and passage, contact recreation, livestock watering, and irrigation. Data will be collected in a nine year cycle. The first three years of the cycle will be a period of concentrated data acquisition and interpretation. For the next six years, sample collection will be done at a much lower level of intensity to document the occurrence of any gross changes in water quality. This nine year cycle would then be repeated. Three types of sampling activities will be used for data acquisition: fixed location station sampling, synoptic sampling, and intensive reach studies. (Lantz-PTT)

Washington↗
USGS2011

Assessing groundwater availability in the Northern Atlantic Coastal Plain aquifer system

The U.S. Geological Survey's Groundwater Resources Program is conducting an assessment of groundwater availability throughout the United States to gain a better understanding of the status of the Nation's groundwater resources and how changes in land use, water use, and climate may affect those resources. The goal of this National assessment is to improve our ability to forecast water availability for future economic and environmental uses. Assessments will be completed for the Nation's principal aquifer systems to help characterize how much water is currently available, how water availability is changing, and how much water we can expect to have in the future (Reilly and others, 2008). The concept of groundwater availability is more than just how much water can be pumped from any given aquifer. Groundwater availability is a function of many factors, including the quantity and quality of water and the laws, regulations, economics, and environmental factors that control its use. The primary objective of the North Atlantic Coastal Plain groundwater-availability study is to identify spatial and temporal changes in the overall water budget by more fully determining the natural and human processes that control how water enters, moves through, and leaves the groundwater system. Development of tools such as numerical models can help hydrologists gain an understanding of this groundwater system, allowing forecasts to be made about the response of this system to natural and human stresses, and water quality and ecosystem health to be analyzed, throughout the region.

Fact Sheet↗
USGS2008

Characteristics of mangrove swamps managed for mosquito control in eastern Florida, USA

Manipulations of the vegetation and hydrology of wetlands for mosquito control are common worldwide, but these modifications may affect vital ecosystem processes. To control mosquitoes in mangrove swamps in eastern Florida, managers have used rotational impoundment management (RIM) as an alternative to the worldwide practice of mosquito ditching. Levees surround RIM swamps, and water is pumped into the impoundment during the summer, a season when natural swamps have low water levels. In the New World, these mosquito-managed swamps resemble the mixed basin type of mangrove swamp (based on PCA analysis). An assessment was made of RIM, natural (control), and breached-RIM (restored) swamps in eastern Florida to compare their structural complexities, soil development, and resistance to invasion. Regarding structural complexity, dominant species composition differed between these swamps; the red mangrove Rhizophora mangle occurred at a higher relative density in RIM and breached-RIM swamps, and the black mangrove Avicennia germinans had a higher relative density in natural swamps. Tree density and canopy cover were higher and tree height lower in RIM swamps than in natural and breached-RIM swamps. Soil organic matter in RIM swamps was twice that in natural or breached-RIM swamps. RIM swamps had a lower resistance to invasion by the Brazilian pepper tree Schinus terebinthifolius , which is likely attributable to the lower porewater salinity in RIM swamps. These characteristics may reflect differences in important ecosystem processes (primary production, trophic structure, nutrient cycling, decomposition). Comparative assessments of managed wetlands are vital for land managers, so that they can make informed decisions compatible with conservation objectives.

Florida↗
USGS2010

Relation of carbon 14 concentrations to saline water contamination of coastal aquifers

Naturally occurring stable or radioactive isotopes may be used in some places to identify the origin of saline water that contaminates some coastal aquifers. In a recent study to determine the origin of saline water in the Ocala Limestone aquifer near Brunswick, Georgia, the following sources were analyzed for C 14 and deuterium concentrations: potable water from the Ocala Limestone, contaminated water from the Ocala Limestone, saune water from the underlying Claiborne Group, and nearby ocean water. The chloride concentration of the groundwater ranges from about 25 ppm in the potable water to more than 2000 ppm in the deeper part of the Claiborne Group. From an interpretation of piezometric maps and other hydrologic data, previous investigators had concluded that the source of the contaminating water was the Claiborne Group and not the nearby ocean. The essentially uniform range of low values of −965 to −987‰ of the modern standard (National Bureau Standard C 14 oxalic acid) for the C 14 activity of the groundwater samples (regardless of the degree of contamination) is in agreement with this conclusion. If recent ocean water, which had a C 14 value of +285‰, were the source of contamination, the contaminated water would have had a C 14 activity higher than the activity of the fresh water. Deuterium analyses are not inconsistent with the interpretation that water from the Claiborne Group, rather than recent ocean water, is the source of the contaminating water. The concurrence of the hydrologic and the isotopic data in this area where the hydrology is well known suggests that isotopic analysis may be used to identify the origin of water in different portions of a hydrologic environment.

Georgia↗
USGS2009

Structural and geochemical characteristics of faulted sediments and inferences on the role of water in deformatiion, Rio Grande Rift, New Mexico

The San Ysidro fault is a spectacularly exposed normal fault located in the northwestern Albuquerque Basin of the Rio Grande Rift. This intrabasin fault is representative of many faults that formed in poorly lithified sediments throughout the rift. The fault is exposed over nearly 10 km and accommodates nearly 700 m of dip slip in subhorizontal, siliciclastic sediments. The extent of the exposure facilitates study of along-strike variations in deformation mechanisms, archi tecture, geochemistry, and permeability. The fault is composed of structural and hydrogeologic components that include a clay-rich fault core, a calcite-cemented mixed zone, and a poorly developed damage zone primarily consisting of deformation bands. Structural textures suggest that initial deformation in the fault occurred at low temperature and pressure, was within the paleosaturated zone of the evolving Rio Grande Rift, and was dominated by particulate flow. Little geochemical change is apparent across the fault zone other than due to secondary processes. The lack of fault-related geochemical change is interpreted to reflect the fundamental nature of water-saturated, particulate fl ow. Early mechanical entrainment of low-permeability clays into the fault core likely caused damming of groundwater flow on the up-gradient, footwall side of the fault. This may have caused a pressure gradient and flow of calcite-saturated waters in higher-permeability, fault-entrained siliciclastic sediments, ultimately promoting their cementation by sparry calcite. Once developed, the cemented and clay-rich fault has likely been, and continues to be, a partial barrier to cross-fault groundwater flow, as suggested by petrophysical measurements. Aeromagnetic data indicate that there may be many more unmapped faults with similar lengths to the San Ysidro fault buried within Rio Grande basins. If these buried faults formed by the same processes that formed the San Ysidro fault and have persistent low-permeability cores and cemented mixed zones, they could compartmentalize the basin-fill aquifers more than is currently realized, particularly if pumping stresses continue to increase in response to population growth. ?? 2009 Geological Society of America.

Geological Society of America Bulletin↗
USGS2024

Adaptable plasmonic membrane sensors for fast and reliable detection of trace low micrometer microplastics in lake water

In freshwater environments, low-micrometer microplastics (LMMPs) have captured significant attention due to their prevalence and toxicity. Yet, rapid detection of LMMPs (1–10 μm) at the single-particle level within complex freshwater matrices remains a hurdle. We developed an adaptable plasmonic membrane sensor for fast detection of individual LMMPs in eutrophic lake waters. The plasmonic membrane sensor functions both as a membrane filter and as a sensor for LMMP collection and analysis. Among the four types of membrane sensors, polycarbonate track-etch (PCTE) membrane sensors exhibit superior imaging quality for LMMPs due to their flat and homogeneous surfaces. Besides the significantly improved imaging contrast and reduced background interferences, the Raman intensity of LMMPs is enhanced by 48% ± 25% on PCTE membrane sensors compared to unmodified membranes. The increased Raman intensities of a chemical probe with an increasing gold layer thickness and a decreasing membrane pore size suggest a surface-enhanced Raman scattering effect from the membrane sensors. The membrane sensors achieve a detection limit of 1 μg/L and an ultrafast scanning time of 0.01 s for individual LMMPs across natural eutrophic lake water. The developed membrane sensors offer an adaptable tool for the swift and reliable detection of individual LMMPs in complex environmental matrices.

Environmental Science and Technology↗
USGS1972

Test-observation well near Odessa, Washington: description and preliminary results

The test-observation well drilled near Odessa, Wash., provides information on the area's aquifer characteristics which is not otherwise available from existing deep irrigation wells. The information is of value to the State of Washington Department of Ecology in its management decisions in this area where heavy ground-water withdrawals have resulted in increasing annual water-level declines. The 10-inch well is 750 feet deep and penetrates six aquifer zones (A through F) in basalt. The upper 60 feet of the well is cased while the remainder of the hole is open in the basalt. The well was test pumped during drilling and showed specific capacities of (1) 0.65 gpm (gallon per minute) per foot of drawdown when at the 258-foot depth and open to aquifers A and B. (2) 0.62 gpm per foot of drawdown when at the 540-foot depth and open to aquifers A through D, and (3) 22 gpm foot of drawdown when at full 750-foot depth and open to all six aquifers. To supplement the driller's log of the well, borehole geophysical logging provided information on natural gamma radiation, water temperature and resistivity, downhole movement (via flowmeter) of the water, and borehole diameter (via caliper log). Upon completion of the well each aquifer zone was isolated from the others by cement seals, and piezometer pipes were installed to each zone to allow definition of the vertical hydraulic gradient and an estimate of the vertical ground-water movement in the area, along with chemical-quality sampling of the various zones and monitoring of any changes in water quality with time. The initial measurements of water levels showed that the levels generally decrease with aquifer depth, with about 200 feet of head difference existing between the uppermost and lowermost aquifer zones. Another pipe, installed for providing thermometer access, permits recording the geothermal gradient with depth in the well, and provides another basis for estimating vertical ground-water movement in the area. Prior to isolation of the various aquifer zones, the composite water level was recovering from the cessation of pumping at the end of the 1970 irrigation season. On April 6, 1971, this composite water level had begun declining, presumably as a result of p[umping of an irrigation well 1 mile to the northwest, By May 6, after the aquifer zones had been isolated and piezometer pieces installed, water levels in aquifers E and F had declined 11 feet in 15 days, in response to pumping for irrigation in the area. Water levels in aquifers B, C, and D declined somewhat, but mostly in response to the draining of these aquifers to deeper aquifers down the many deep-well boreholes in the area.

Washington↗
USGS1980

Utah water use data: Public water supplies, 1960-1978

This report was prepared as a part of the Statewide cooperative water-resources investigation program administered jointly by the Utah Department of Natural Resources, Division of Water Rights and the United States Geological Survey. The program is conducted to meet the water administration and water-resources data needs of the State, as well as the water information needs of many units of government and the general public.

Utah↗
USGS2023

A review of natural and managed revegetation responses in two de-watered reservoirs after large dam removals on the Elwha River, Washington, USA

Large dam removals are increasing in frequency and the response of natural and managed revegetation is a critical consideration for managed restoration of dewatered reservoir landscapes post dam removal. The removal of two large dams on the Elwha River in 2011-2014 provides insight into reservoir revegetation. We review literature and datasets from 2012 through 2018, 1-6 years since reservoir dewatering, to compare pre-dam removal predictions on the Elwha to post-dam removal of natural revegetation, managed revegetation effects and invasive non-native vegetation response. Pre-dam removal hypotheses about natural revegetation did not predict species performance on reservoir sediments, seed rain patterns, or seed bank response. Sediment texture and landform affected multiple aspects of revegetation, including vegetation cover, species richness, woody stem densities and species composition. Reservoir drawdown timing influenced species composition and seedling densities. Predictions about managed revegetation effects were mixed. Planting trees and shrubs did not accelerate woody cover but did increase species richness. Seeding reduced non-native vegetation frequency and species richness, had no effect on vegetation cover on fine sediments, but increased vegetation cover on coarse sediments. Planting trees and shrubs during drawdown appeared to result in higher survival rates compared to plantings installed 1+ years post drawdown. Seeding Lupinus rivularis (riverbank lupine) on coarse sediments was successful and increased foliar nitrogen in planted conifers. Invasive non-native vegetation was correctly predicted to be more abundant in the Aldwell reservoir but did not preclude native species establishment in either reservoir, likely due to rapid establishment of native species and robust management that occurred before, during and after dam removal.

Washington↗
USGS2007

Discovery of the invasive Mayan Cichlid fish "Cichlasoma" urophthalmus (Günther 1862) in Thailand, with comments on other introductions and potential impacts

We report on the occurrence and possible establishment of a non-native cichlid fish in a brackish-water system in the lower Chao Phraya River delta region, Thailand. Although, the possibility of some degree of introgressive hybridization can not be ruled out, Thailand specimens agree best with Mayan Cichlid “Cichlasoma” urophthalmus (Günther 1862). Our collections represent the first records of this New World, highly-invasive, euryhaline fish from Thailand and coincides with recent collections from Singapore. Positive identification of specimens as “C.” urophthalmus requires caution due to the diversity of the Cichlidae (>1,300 species), widespread introduction of many family members, variation within species, extensive interspecific overlap in characters, and proliferation of artificial cichlid hybrids (e.g., Flowerhorns). We first became aware of the Thailand population in 2005 when “C.” urophthalmus began appearing in the catches of local fishermen. We visited the site in November 2006 and obtained and examined voucher specimens. The abundance and wide size range of juveniles and adults in local ponds and an adjacent canal is evidence of natural reproduction. Because water bodies throughout the Chao Phraya delta are interconnected and subject to flooding, it is likely that “C.” urophthalmus is already established and is dispersing, but surveys and monitoring are needed to determine their exact geographic range. The Thailand population is compared to “C.” urophthalmus introduced into Florida (USA). Based on what is known about Florida “C.” urophthalmus , it is predicted that this cichlid will further invade coastal and inland waters in Thailand and elsewhere in Southeast Asia. This cichlid has a long history in the aquarium trade in Europe. However, there are no records from the wild in European waters and, because of the colder climate, the possibility of establishment in that region is relatively low.

Chao Phraya River Delta↗
USGS2008

Quality of Shallow Ground Water in Three Areas of Unsewered Low-Density Development in Wyoming and Montana, 2001

The quality of shallow ground water underlying unsewered low-density development outside of Sheridan and Lander, Wyo., and Red Lodge, Mont., was evaluated. In 2001, 29 wells (10 each in Sheridan and Lander and 9 in Red Lodge) were installed at or near the water table and sampled for a wide variety of constituents to identify potential effects of human activities on shallow ground-water quality resulting from development on the land surface. All wells were completed in unconfined aquifers in unconsolidated deposits of Quaternary age with shallow water tables (less than 50 feet below land surface). Land use and land cover was mapped in detail within a 500-meter radius surrounding each well, and potential contaminant sources were inventoried within the radii to identify human activities that may affect shallow ground-water quality. This U.S. Geological Survey National Water-Quality Assessment ground-water study was conducted to examine the effects of unsewered low-density development that often surrounds cities and towns of many different sizes in the western United States?a type of development that often is informally referred to as ?exurban? or ?rural ranchette? development. This type of development has both urban and rural characteristics. Residents in these developments typically rely on a private ground-water well for domestic water supply and a private septic system for sanitary waste disposal. Although the quality of shallow ground water generally was suitable for domestic or other uses without treatment, some inorganic constituents were detected infrequently in ground water in the three study areas at concentrations larger than U.S. Environmental Protection Agency drinking-water standards or proposed standards. Natural factors such as geology, aquifer properties, and ground-water recharge rates likely influence most concentrations of these constituents. These inorganic constituents generally occur naturally in the study areas and were more likely to limit suitability of water for drinking or other intended uses rather than any constituents suspected of being introduced as a result of human activities. Effects of human activities associated with low-density development, such as septic systems; fertilizer and pesticide use on pastures, lawns and gardens; manure from horses, cattle, and pets; and increases in road construction and vehicular traffic, were minimal at the time of sampling (2001) but were apparent in the presence of a few types of constituents in shallow ground water. Concentrations of nitrate generally were less than a national background level (1.1 milligrams per liter) assumed to indicate effects from human activities. Total coliform bacteria were detected infrequently (in samples from three wells), and Escherichia coli were not detected in samples from a subset of wells. Trace concentrations of methylene blue active substances (ingredients in laundry detergents) were detected at concentrations slightly greater than laboratory reporting levels in samples from 11 wells, but it is unclear if the detections are indicative of natural sources or possible aquifer contamination from septic-tank effluent. Pesticides were detected in both the Sheridan and Lander, Wyo., study areas. Volatile organic compounds were detected very infrequently in all three study areas. Most pesticides and volatile organic compounds were found in water from a few wells in each study area, and commonly as mixtures. The primary exception to this generalization was the relatively widespread detection of the pesticide prometon at trace levels in the Sheridan and Lander study areas. Concentrations of pesticides and volatile organic compounds generally were small and always were smaller than applicable drinking-water standards. Detections of all constituents indicating possible human effects on shallow ground-water quality were consistent with overlying land use mapped during the study, and potential sources of contamination inventoried du

Scientific Investigations Report↗
USGS1969

Ion association in natural brines

Natural brines, both surface and subsurface, are highly associated aqueous solutions. Ion complexes in brines may be ion pairs in which the cation remains fully hydrated and the bond between the ions is essentially electrostatic, or coordination complexes in which one or more of the hydration water molecules are replaced by covalent bonds to the anion. Except for Cl − , the major simple ions in natural brines form ion pairs; trace and minor metals in brines form mainly coordination complexes. Limitations of the Debye-Hückel relations for activity coefficients and lack of data on definition and stability of all associated species in concentrated solutions tend to produce underestimates of the degree of ion association, except where the brines contain a very high proportion of Cl − . Data and calculations on closed basin brines of highly varied composition have been coupled with electrode measurements of single-ion activities in an attempt to quantify the degree of ion association. Such data emphasize the role of magnesium complexes. Trace metal contents of closed basin brines are related to complexes formed with major anions. Alkaline sulfo- or chlorocarbonate brines (western Great Basin) carry significant trace metal contents apparently as hydroxides or hydroxy polyions. Neutral high chloride brines (Bonneville Basin) are generally deficient in trace metals. With a knowledge of the thermodynamic properties of a natural water, many possible reactions with other phases (solids, gases, other liquids) may be predicted. A knowledge of these reactions is particularly important in the study of natural brines which may be saturated with many solid phases (silicates, carbonates, sulfates, etc.), which may have a high pH and bring about dissolution of other phases (silica, amphoteric hydroxides, CO 2 , etc.), and which because of their high density may form relatively stable interfaces with dilute waters.

Chemical Geology↗
USGS2017

Hydrogeology and water quality of sand and gravel aquifers in McHenry County, Illinois, 2009–14, and comparison to conditions in 1979

Baseline conditions for the sand and gravel aquifers (groundwater) in McHenry County, Illinois, were assessed using data from a countywide network of 44 monitoring wells collecting continuous water-level data from 2009–14. In 2010, water-quality data were collected from 41 of the monitoring wells, along with five additional monitoring wells available from the U.S. Geological Survey National Water Quality Assessment Program. Periodic water-quality data were collected from 2010–14 from selected monitoring wells. The continuous water-level data were used to identify the natural and anthropogenic factors that influenced the water levels at each well. The water-level responses to natural influences such as precipitation, seasonal and annual variations, barometric pressure, and geology, and to anthropogenic influences such as pumping were used to determine (1) likely hydrogeologic setting (degree of aquifer confinement and interconnections) that, in part, are related to lithostratigraphy; and (2) areas of recharge and discharge related to vertical flow directions. Water-level trends generally were determined from the 6 years of data collection (2009–14) to infer effects of weather variability (drought) on recharge. Precipitation adds an estimated 2.4 inches per year of recharge to the aquifer. Some of this recharge is subsequently discharged to streams and some is discharged to supply wells. A few areas in the eastern half of the county had higher average recharge rates, indicating a need for adequate protection of these recharge areas. Downward vertical flow gradients in upland areas indicate that recharge to the confined aquifer units occurs near upland areas. Upward vertical flow gradients in lowland areas indicate discharge at locations of surface water and groundwater interaction (wetlands, ponds, and streams). Monitoring wells were sampled for major and minor ions, metals, and nutrients and a subset of wells was sampled for trace elements, dissolved gases, pesticides, and volatile organic compounds. The results were compared to health ‑ based and aesthetically based standards, which include the U.S. Environmental Protection Agency Maximum Contaminant Level (EPA MCL), and EPA Secondary Maximum Contaminant Levels (SMCL), as well as EPA Health-based Standards Drinking Water Advisories. Health‑based standards were exceeded for arsenic in 22 percent, sodium in 20 percent, and nitrates in 2 percent of the monitoring wells sampled. Aesthetically based standards were exceeded for total dissolved solids in 33 percent, chloride in 11 percent, iron in 85 percent, and manganese in 30 percent of the wells sampled. Many of these same constituents, such as arsenic, iron, and manganese, are naturally occurring but become elevated in areas that have anoxic, mixed, and suboxic conditions. Some areas of potential vulnerability to anthropogenic-sourced constituents in the sand and gravel aquifers were evidenced by trace amounts of volatile organic compounds and pesticides detected in water-quality samples from shallow wells (total depth less of than 46 feet below land surface) near urban settings, and by the detection of elevated major ions (chloride, sodium, magnesium, and calcium) associated, in part, with road-salt applications. Source analysis for chloride indicates mixtures of road salt, water softeners, and sewage. Continuously measured specific conductance values were used as a surrogate for continuously measured chloride concentrations in the groundwater. The estimated chloride concentrations generally were highest in spring and lowest in summer, and occasionally peak during spring melt. Overall, the range of concentrations varied depending on the local thickness and hydraulic conductivity of the aquifer. Water levels and water quality from the countywide groundwater monitoring network were compared to water levels and water-quality results in 1979 from a previous U.S. Geological Survey study. Potentiometric surface maps show areas with inferred decreases of water levels near the southern and southeastern areas of McHenry County. Significant increases were noted for total dissolved solids and specific conductance. Chloride concentrations increased as much as 521 percent in three of six wells resampled in 2015 from the previous study.

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