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Apparent chlorofluorocarbon age of ground water of the shallow aquifer system, Naval Weapons Station Yorktown, Yorktown, Virginia

Apparent ages of ground water are useful in the analysis of various components of flow systems, and results of this analysis can be incorporated into investigations of potential pathways of contaminant transport. This report presents the results of a study in 1997 by the U.S. Geological Survey (USGS), in cooperation with the Naval Weapons Station Yorktown, Base Civil Engineer, Environmental Directorate, to describe the apparent age of ground water of the shallow aquifer system at the Station. Chlorofluorocarbons (CFCs), tritium ( 3 H), dissolved gases, stable isotopes, and water-quality field properties were measured in samples from 14 wells and 16 springs on the Station in March 1997. Nitrogen-argon recharge temperatures range from 5.9°C to 17.3°C with a median temperature of 10.9°C, which indicates that ground-water recharge predominantly occurs in the cold months of the year. Concentrations of excess air vary depending upon geohydrologic setting (recharge and discharge areas). Apparent ground-water ages using a CFC-based dating technique range from 1 to 48 years with a median age of 10 years. The oldest apparent CFC ages occur in the upper parts of the Yorktown-Eastover aquifer, whereas the youngest apparent ages occur in the Columbia aquifer and the upper parts of the discharge area setting, especially springs. The vertical distribution of apparent CFC ages indicates that groundwater movement between aquifers is somewhat retarded by the leaky confining units, but the elapsed time is relatively short (generally less than 35 years), as evidenced by the presence of CFCs at depth. The identification of binary mixtures by CFC-based dating indicates that convergence of flow lines occurs not only at the actual point of discharge, but also in the subsurface. The CFC-based recharge dates are consistent with expected 3 H concentrations measured in the water samples from the Station. The concentration of 3H in ground water ranges from below the USGS laboratory minimum reporting limit of 0.3 to 15.9 tritium units (TU) with a median value of 10.8 TU. Water-quality field properties are highly variable for ground water with apparent CFC ages less than 15 years because of geochemical processes within local flow systems. Ground water with apparent CFC ages greater than 15 years represents more stable conditions in subregional flow systems. The range of apparent CFC ages is slightly greater than the ranges in time of travel of ground water calculated for shallow wells (less than 60- feet deep) from flow-path analysis. Calculated travel times to springs can be up to two orders of magnitude greater than the CFC-based apparent ages. Reasonable assumptions of values for hydraulic parameters can result in substantial overestimates for time of travel to springs. Recharge rates computed from apparent CFC ages range from 0.29 to 0.89 feet per year (ft/ yr) with an average value of 0.54 ft/yr. The analysis of apparent CFC ages in conjunction with geohydrologic data indicates that young water (less than 50 years) is present at depth (nearly 120 feet) and that both local and subregional flow systems occur in the shallow aquifer system at the Station. The addition of the dimension of time to the three-dimensional framework of Brockman and others (1997) will benefit current (2001) and future remediation activities by providing estimates of advective transport rates and how these rates vary depending upon geohydrologic setting and position within the ground-water-flow system. Estimated ground-water apparent ages and recharge rates can be used as calibration criteria in simulations of ground-water flow on the Station to refine and constrain future ground-water-flow models of the shallow aquifer system.

Virginia↗

Ground-water data on the Hudson River basin, New York

Ground water in the Hudson River basin occurs in unconsolidated deposits and consolidated rock. Sand and gravel units of the unconsolidated deposits, which occur principally in valley bottoms, form the best aquifers and commonly provide well yields of several hundred gallons per minute. Carbonate aquifers are the most productive consolidated rock units. Ground water in the Hudson River basin is generally hard and may contain appreciable amounts of iron, salts in solution, or sulfur locally. Basic data on the availability of ground water in the Hudson River drainage area are compiled in (1) a hydrogeologic map of the drainage basin; (2) a table of well depths, yields, concentrations of selected chemical constituents, and hardness of ground water, listed by county and aquifer type; (3) a short text describing the occurrence of ground water in the basin; and (4) a bibliography of ground-water reports pertinent to the area studied. (Woodard-USGS)

Open-File Report↗

Inventory of ground-water resources in the Kabul Basin, Afghanistan

In 2004, the U.S. Geological Survey began working with engineers at the Afghanistan Geological Survey to provide hydrologic training and equipment and to apply these tools to build an inventory of water wells in the Kabul Basin of Afghanistan. An inventory of 148 wells now includes information on well location, depth, and access. Water-level and water-quality measurements have been made at most of these wells. A water-level elevation map has been constructed, and general directions of ground-water flow have been defined. Ground-water flow in the Kabul Basin is primarily through saturated alluvium and other basin-fill sediments. The water-table surface generally mirrors topography, and ground water generally flows in the directions of surface-water discharge. The quality of ground water in the Kabul Basin varies widely. In some areas, ground-water quality is excellent, with low concentrations of dissolved solids and no problematic constituents. In other areas, however, high concentrations of dissolved solids and the presence of some constituents at concentrations deemed harmful to humans and crops render untreated ground water marginal or unsuitable for public supply and/or agricultural use. Of particular concern are elevated concentrations of nitrate, boron, and dissolved solids, and an indication of fecal pollution in some parts of the basin. As Afghanistan emerges from years of conflict, as institutional capacities rejuvenate and grow, and as the need for wise water-management decisions continues, adequate data and a fuller understanding of the ground-water resource in the Kabul Basin will be imperative. The work described in this report represents only a modest beginning in what will be a long-term data-collection and interpretive effort.

Scientific Investigations Report↗

Hydrogeologic framework and estimates of ground-water volumes in Tertiary and upper Cretaceous hydrogeologic units in the Powder River basin, Wyoming

The Powder River Basin in Wyoming and Montana is an important source of energy resources for the United States. Coalbed methane gas is contained in Tertiary and upper Cretaceous hydrogeologic units in the Powder River Basin. This gas is released when water pressure in coalbeds is lowered, usually by pumping ground water. Issues related to disposal and uses of by-product water from coalbed methane production have developed, in part, due to uncertainties in hydrologic properties. One hydrologic property of primary interest is the amount of water contained in Tertiary and upper Cretaceous hydrogeologic units in the Powder River Basin. The U.S. Geological Survey, in cooperation with the Bureau of Land Management, conducted a study to describe the hydrogeologic framework and to estimate ground-water volumes in different facies of Tertiary and upper Cretaceous hydrogeologic units in the Powder River Basin in Wyoming. A geographic information system was used to compile and utilize hydrogeologic maps, to describe the hydrogeologic framework, and to estimate the volume of ground water in Tertiary and upper Cretaceous hydrogeologic units in the Powder River structural basin in Wyoming. Maps of the altitudes of potentiometric surfaces, altitudes of the tops and bottoms of hydrogeologic units, thicknesses of hydrogeologic units, percent sand of hydrogeologic units, and outcrop boundaries for the following hydrogeologic units were used: Tongue River-Wasatch aquifer, Lebo confining unit, Tullock aquifer, Upper Hell Creek confining unit, and the Fox Hills-Lower Hell Creek aquifer. Literature porosity values of 30 percent for sand and 35 percent for non-sand facies were used to calculate the volume of total ground water in each hydrogeologic unit. Literature specific yield values of 26 percent for sand and 10 percent for non-sand facies, and literature specific storage values of 0.0001 ft-1 (1/foot) for sand facies and 0.00001 ft-1 for non-sand facies, were used to calculate a second volume of ground water for each hydrogeologic unit. Significant figure considerations limited estimates of ground-water volumes to two significant digits. A total ground-water volume of 2.0x1014 ft3 (cubic feet) was calculated using porosity values, and a total ground-water volume of 3.6x1013 ft3 was calculated using specific yield and specific storage values. These results are consistent with retention properties, which would have some of the total water being retained in the sediments. Sensitivity analysis shows that the estimates of ground-water volume are most sensitive to porosity. The estimates also are sensitive to confined thickness and saturated thickness. Better spatial information for hydrogeologic units could help refine the ground-water volume estimates.

Scientific Investigations Report↗

Hydrogeochemistry of Bermuda: A case history of ground-water diagenesis of biocalcarenites

Bermuda is composed of relatively young skeletal limestones currently undergoing diagenesis by the ground water passing through them. The saturated zone consists of separate fresh-water bodies laterally surrounded and underlain by extensive brackish aureoles, in which the meteoric water is mixed with sea water. The meteoric water enters the aquifer after passing through the soil or through marshes (outcrops of the ground-water bodies), in each case causing an influx of CO 2 to the saturated zone. Examination of the ground-water chemistry enables mapping of (a) the extent of mixing of meteoric ground water and sea water; (b) P CO2 ; (c) the extent of saturation with calcite and aragonite; (d) concentration of Sr; and (e) the amount of calcium and magnesium derived from the limestones. It is concluded that three processes control the chemistry of Bermudian ground water: (a) generation of elevated CO 2 partial pressures in soils and marshes; (b) dissolution of metastable carbonate minerals (principally aragonite); and (c) mixing with sea water. Bermuda ground water apparently approaches a steady state of aragonite dissolution (at slight subsaturation) and concurrent precipitation of calcite cement. Large Sr/Ca ratios in the ground water indicate that the dissolution of aragonite is incongruent. Dissolution is most pronounced near the marshes where CO 2 content is highest. Mixing with sea water is not significant in controlling calcite saturation. Only small amounts of magnesium enter the ground water by incongruent dissolution of magnesium calcite, an apparently slow process on the time scale of passage of the ground water through the saturated zone. All of the waters are well undersaturated with respect to dolomite. It is estimated that the present rate of recrystallization of aragonite to calcite is about 0.32 cm 3 of aragonite to calcite per m 3 of the saturated zone per year. At the present rate of chemical weathering, 360 m 3 of the saturated zone is lost each year through solution and transported to the sea by ground water.

Geological Society of America Bulletin↗

A system for calibrating seepage meters used to measure flow between ground water and surface water

A system has been developed for generating controlled rates of seepage across the sediment-water interface representing flow between ground water and surface water. The seepage- control system facilitates calibration and testing of seepage measurement devices commonly called seepage meters. Two slightly different seepage-control systems were evaluated. Both designs make use of a 1.5-m-diameter by 1.5-m-tall polyethylene flux tank partially filled with sand that overlies a pipe manifold and diffuser plate to provide a uniform flux of water through the sand. The flux tank is filled with water to maintain a water depth above the sand bed of about 0.6 m. Flow is generated by routing water through tubing that connects an adjustable-height reservoir to the base of the flux tank, through the diffuser plate and sand, and across the sediment-water interface. Seepage rate is controlled by maintaining a constant water depth in the reservoir while routing flow between the reservoir and the flux tank. The rate of flow is controlled by adjusting the height of the reservoir with a manually operated fork lift. Flow from ground water to surface water (inflow) occurs when the water surface of the reservoir is higher than the water surface of the flux tank. Flow from surface water to ground water (outflow) occurs when the water surface of the reservoir is lower than the water surface of the flux tank. Flow rates as large as ±55 centimeters per day were generated by adjusting the reservoir to the extremes of the operable range of the fork lift. The minimum seepage velocity that the flowmeter can reliably measure is about 7 centimeters per day. Water in the reservoir is maintained at a nearly constant depth by pumping return flow between the reservoir and flux tanks based on output from a submersible pressure transducer placed in the reservoir. A datalogger switches the pump on and off at appropriate intervals to maintain a nearly constant water depth inside the reservoir, which maintains a virtually constant hydraulic gradient between the reservoir and flux tanks. The datalogger also records flow, in units of volume per time, as measured by an in-line flowmeter positioned between the base of the flux tank and the reservoir. Seepage flux in units of distance per time is determined by dividing the flowmeter output by the surface area at the sediment-water interface in the flux tank. Spatial heterogeneity in seepage was evident in both flux tanks in spite of attempts to minimize heterogeneity during tank construction. Medium sand was used in both flux tanks and care was taken to homogenize the sand during and after filling of the tanks. Time was provided for release or dissolution of trapped air, and water was circulated to remove fine-grained sediments prior to system use. In spite of these precautions, seepage measured with five to six small 20.25-cm-diameter seepage meters varied by about a factor of two. Use of larger diameter seepage meters, which cover a larger percentage of the sediment surface of the flux tanks, greatly minimized measured seepage heterogeneity. The seepage-control system was used to demonstrate that seepage-meter efficiency is sensitive to the type of seepage-meter bag and that bag-measured seepage rate is sensitive to the duration of the seepage-meter measurement only during very short measurement times. The in-line flowmeter used with this system is incapable of measuring seepage rates below about 7 centimeters per day. Smaller seepage rates can be measured manually. The seepage- control system also can be modified for measuring slower seepage rates with the use of two flowmeters and a slightly different water-routing system, or a fluid-metering pump can be used to control flow through the flux tank instead of an adjustable-height reservoir.

Scientific Investigations Report↗

Arsenic in ground water of the United States: occurrence and geochemistry

Concentrations of naturally occurring arsenic in ground water vary regionally due to a combination of climate and geology. Although slightly less than half of 30,000 arsenic analyses of ground water in the United States were 1 μg/L, about 10% exceeded 10 μg/L. At a broad regional scale, arsenic concentrations exceeding 10 μg/L appear to be more frequently observed in the western United States than in the eastern half. Arsenic concentrations in ground water of the Appalachian Highlands and the Atlantic Plain generally are very low ( 1 μg/L). Concentrations are somewhat greater in the Interior Plains and the Rocky Mountain System. Investigations of ground water in New England, Michigan, Minnesota, South Dakota, Oklahoma, and Wisconsin within the last decade suggest that arsenic concentrations exceeding 10 μg/L are more widespread and common than previously recognized. Arsenic release from iron oxide appears to be the most common cause of widespread arsenic concentrations exceeding 10 μg/L in ground water. This can occur in response to different geochemical conditions, including release of arsenic to ground water through reaction of iron oxide with either natural or anthropogenic (i.e., petroleum products) organic carbon. Iron oxide also can release arsenic to alkaline ground water, such as that found in some felsic volcanic rocks and alkaline aquifers of the western United States. Sulfide minerals are both a source and sink for arsenic. Geothermal water and high evaporation rates also are associated with arsenic concentrations 10g/L in ground and surface water, particularly in the west. Arsenic release from iron oxide appears to be the most common cause of widespread arsenic concentrations exceeding 10 µg/L a ground water. This can occur in response to different geochemical conditions, including release of arsenic to ground water through reaction of iron oxide with either natural or anthropogenic (i.e., petroleum products) organic carbon. Iron oxide also can release arsenic to alkaline ground water, such as that found in some felsic volcanic rocks and alkaline aquifers of the Western United States. Sulfide minerals are both a source and sink for arsenic. Geothermal water and high evaporation rates also are associated with arsenic concentrations ≥ 10g/L in ground and surface water, particularly in the west.

Ground Water↗

Vulnerability of the uppermost ground water to contamination in the greater Denver area, Colorado

Information about vulnerability of ground water to contamination is needed to facilitate ground-water management. Vulnerability of ground water refers to the intrinsic characteristics that determine the sensitivity of the water to being adversely affected by an imposed contaminant load. Within the greater Denver area, vulnerability of the uppermost ground water to contamination from the surface was assessed by considering the intrinsic characteristics included in a method developed by the U.S. Environmental Protection Agency and the National Water Well Association, the DRASTIC method. The seven geohydrologic characteristics considered are: (1) Aquifer media, (2) hydraulic conductivity, (3) unsaturated media, (4) depth to water, (5) recharge, (6) soil media, and (7) land-surface slope. Recharge from precipitation generally is less than 2 inches per year; no effort was made to quantify the variation of recharge throughout the study area. Data for geology, depth to water, soils, and elevation were obtained and processed to produce maps of the other six characteristics. Spatial and attribute data for these maps were stored and processed by geographic-information-system software to produce a map showing vulnerability of the uppermost ground water to contamination from the surface. This report describes the assessment of each geohydrologic characteristic and the 157 vulnerability response units that were delineated within the greater Denver area. These response units are unique with respect to the geohydrologic characteristics considered. The uppermost ground water within each of the vulnerability response units are described in a series of tables, which include qualitative and selected quantitative data and the vulnerability rating assigned for each of the seven geohydrologic characteristics.

Water-Resources Investigations Report↗

Relation of Chlorofluorocarbon Ground-Water Age Dates to Water Quality in Aquifers of West Virginia

The average apparent age of ground water in fractured-bedrock aquifers in West Virginia was determined using chlorofluorocarbon (CFC) dating methods. Since the introduction of CFC gases as refrigerants in the late 1930s, atmospheric concentrations have increased until production ceased in the mid-1990s. CFC dating methods are based on production records that date to the early 1940s, and the preservation of atmospheric CFC concentrations in ground water at the time of recharge. As part of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) and Ambient Ground-Water Monitoring Network (AGN) programs in West Virginia from 1997 to 2005, 80 samples from the Appalachian Plateaus Physiographic Province, 27 samples from the Valley and Ridge Physiographic Province, and 5 samples from the Ohio River alluvial aquifers were collected to estimate ground-water ages in aquifers of West Virginia. Apparent CFC ages of water samples from West Virginia aquifers ranged from 5.8 to 56 years. In the Appalachian Plateaus, topographically driven ground-water flow is evident from apparent ages of water samples from hilltop, hillside, and valley settings (median apparent ages of 12, 14, and 25 years, respectively). Topographic setting was the only factor that was found to be related to apparent ground-water age in the Plateaus at the scale of this study. Similar relations were not found in Valley and Ridge aquifers, indicating that other factors such as bedding or geologic structure may serve larger roles in controlling ground-water flow in that physiographic province. Degradation of CFCs was common in samples collected from methanogenic/anoxic aquifers in the Appalachian Plateaus and suboxic to anoxic aquifers in the Valley and Ridge. CFC contamination was most common in Ohio River alluvial aquifers and carbonate units of the Valley and Ridge, indicating that these highly transmissive surficial aquifers are the most vulnerable to water-quality degradation and may contain wastewater from domestic or industrial sources with CFC concentrations greater than modern atmospheric levels. However, based on a lack of detections of the volatile organic compounds analyzed for in most of the water samples collected for this and similar USGS investigations, ground-water resources of West Virginia used for public and private consumption do not appear to be routinely affected by anthropogenic activities despite their young apparent age.

Scientific Investigations Report↗

Geology and ground-water resources of the Lawrenceville area, Georgia

The population of the Atlanta Metropolitan area continues to grow at a rapid pace and the demand for water supplies steadily increases. Exploration for ground-water resources, as a supplement to surface-water supplies, is being undertaken by many city and county governments. The application of effective investigative methods to characterization of the complex igneous and metamorphic fractured bedrock aquifers of the Piedmont physiographic province is essential to the success of these ground-water exploration programs. The U.S. Geological Survey, in cooperation with the City of Lawrenceville, Ga., began a study in December 1994 to apply various investigative techniques for field characterization of fractured crystalline-bedrock aquifers near Lawrenceville. Five major lithologic units were mapped in the Lawrenceville, Ga., area as part of an ongoing study of ground-water resources-amphibolite, biotite gneiss, button schist, granite gneiss, and quartzite/aluminous schist. These units generally are thin in outcrop width, have low angles of dip (nearly 0 to 20 degrees, dip reversals occur over short distances), and exhibit some shearing characteristics. The most productive unit for ground-water resources, on the basis of subsurface data collected through 1997, is the amphibolite. Historically, two wells drilled into this unit are recognized as having possibly the highest yields in the Piedmont region of northern Georgia. The City of Lawrenceville refurbished one well at the Rhodes Jordan Wellfield in 1990, and has pumped this well at an average rate of about 230 gallons per minute since 1995. In general, the composition of water collected from the bedrock wells, regolith wells, and City Lake is similar; calcium and bicarbonate are the dominant cation and anion, respectively. Water from the regolith wells and the lake have lower concentrations of major ions than does water from the bedrock wells. Many of the ground-water samples collected from the Rhodes Jordan Wellfield during October-November 1995, and from the wellfield and three additional observation well sites during August 1996, contain volatile organic compounds. Volatile organic compounds were detected in ground-water samples collected from several bedrock and regolith wells located in urban areas. Trace concentrations of tetrachloroethylene, trichloroethylene, 1,1-dichloroethane, trichlorofluoromethane, 1,1,1-trichloroethane, and cis-1,2-dichloroethene were detected. Methyl-tert-butyl ether (MTBE)-a compound used to increase the octane level in gasoline-was detected at concentrations above expected urban background levels in bedrock wells in the Rhodes Jordan Wellfield. Concentrations of MTBE ranged from 0.6 to 12 micrograms per liter in October-November 1995, and from 0.6 to 26 micrograms per liter in August 1996. Continuous ground-water-level data suggest that the fractured crystalline-bedrock aquifer (amphibolite unit) at the Rhodes Jordan Wellfield, generally is dewatered to a depth near a productive fracture during the regular pumping cycle of 18 hours per day, 5 days on and 2 days off per week. However, when the stress on the aquifer is increased by extending the pumping period up to as much as 18 days, or by pumping longer that 18 hours per day, the aquifer exhibits an unusual condition of recovery. Areal effects of pumping have been observed at distances of as much as one mile, extending across surface-water drainage divides.

Georgia↗

Preliminary delineation of salty ground water in the northern Atlantic Coastal Plain

Salty ground water underlies freshwater in the eastern part of the northern Atlantic Coastal Plain. The transition zone between freshwater and saltwater is represented in this report by a series of maps showing the depths to chloride concentrations of 250, 1,000, 10,000, and 18,000 milligrams per liter. The maps are based on chloride concentrations obtained from self-potential logs as well as from water-quality analyses. Depths to the designated chloride concentrations generally increase inland from the coast except in New Jersey where they are greatest along the coast and in North Carolina where depths to the 10,000 and 18,000 milligrams per liter concentrations are greatest beneath Pamlico Sound. The transition zone between 250 and 18,000 milligrams per liter of chloride is generally 1,500 to 2,300 feet thick except in part of North Carolina, where it is less than 1,000 feet. Depths to 250 and 1,000 milligrams per liter of chloride are probably controlled by the natural flow pattern of fresh ground water. Areas where these concentrations are relatively shallow generally coincide with areas of natural ground-water discharge. Depths to 10,000 and 18,000 milligrams per liter of chloride, and the occurrence offshore of ground water that is fresher than seawater, is attributed to long-term hydrologic conditions during which sea level fluctuations of a few hundred feet recurred several times. The origin of ground water that is saltier than seawater is attributed to the leaching of evaporitic strata beneath the Continental Shelf and Slope followed by westward movement of the brines during periods of sea-level rise.

Northern Atlantic Coastal Plain↗

Summary appraisals of the Nation's ground-water resources; Alaska

Alaska has enormous surface-water resources, but many of the streams are frozen for most of the year and most contain glacial silt that makes them unacceptable for human use. These factors lend special significance to ground water as a water-supply source, even though perennially frozen ground (permafrost) profoundly modifies ground-water flow systems in much of Alaska north of the maritime southern coast and southeastern panhandle areas. Frozen ground is a virtually impermeable layer that restricts recharge, discharge, and movement of ground water, acts as a confining layer and limits the volume of unconsolidated deposits and bedrock in which water may be stored. Ground water is an untested resource in most of Alaska, but in many areas potential development of ground water far exceeds current use. Alluvium of major river valleys, such as the Yukon, Tanana, Kuskokwim and Susitna Rivers, probably contains the most extensive aquifers in the State. Large amounts of ground water are also stored in glacial outwash aquifers that underlie coastal basins and valleys, such as those at Kenai and Anchorage in the Cook Inlet lowland. Individual wells yielding more than 1,000 gallons per minute have been developed in the Tanana River valley, Cook Inlet lowland, and the coastal valleys at Seward and Juneau. Comparable yields should be possible in other areas that have similar geohydrologic environments. No major aquifers have been identified in glacial and glaciolacustrine deposits of interior valleys or in deltaic deposits. Major bedrock aquifers have been identified only in carbonate rocks of the Brooks Range and on the north side of the Alaska Range. Springs issuing from the carbonate rocks of the Brooks Range have discharges as great as 16,000 gallons per minute. Most ground-water recharge occurs beneath reaches of stream channels that are losing flow to the ground-water system. Most ground-water discharge also takes place along reaches of stream channels. This discharge augments streamflows during summer and maintains low flows during winter when there is no surface-water runoff. On the basis of a streamflow hydrograph separation technique and using the 60 percent flow-duration value as an indicator of ground-water discharge, it is estimated that 25 percent of the total volume of streamflow in Alaska (exclusive of coastal, maritime environments) is contributed by ground-water discharge. The thawing of frozen ground in the permafrost regions of Alaska causes construction and engineering problems. Disturbance of the ground surface disrupts the natural thermal equilibrium and tends to thaw part of the permafrost. Thawing can cause loss of strength, a decrease in volume, and an increase in erosion potential, particularly if the frozen ground is fine grained and poorly drained. Present deficiencies in the ground-water information base are obvious limiting factors to ground-water development in Alaska. There is a need to extend the ground-water data-collection network and to pursue special research into the quantitative aspects of ground-water hydrology in cold regions, particularly the continuous permafrost zone.

Alaska↗

Determining sources of water and contaminants to wells in a carbonate aquifer near Martinsburg, Blair County, Pennsylvania, by use of geochemical indicators, analysis of anthropogenic contaminants, and simulation of ground-water flow

Water supply for the Borough of Martinsburg, Pa., is from two well fields (Wineland and Hershberger) completed in carbonate-bedrock aquifers in the Morrison Cove Valley. Water supply is plentiful; however, waters with high concentrations of nitrate are a concern. This report describes the sources of water and contaminants to the supply wells. A review of previous investigations was used to establish the aquifer framework and estimate aquifer hydraulic properties. Aquifer framework and simulation of ground-water flow in a 25-square-mile area using the MODFLOW model helped to further constrain aquifer hydraulic properties and identify water-source areas in the zone of contribution of ground water to the well fields. Flow simulation identified potential contaminant-source areas. Data on contaminants and geochemical characteristics of ground water at the well fields were compared to the results of flow simulation. The Woodbury Anticline controls the aquifer framework near the well fields and four carbonate-bedrock formations contain the primary aquifers. Three carbonate-bedrock aquifers of Ordovician age overlie the Gatesburg aquifer of Cambrian age on the flanks of the anticline. Fracture, not conduit, permeability was determined to be the dominant water-bearing characteristic of the bedrock. The horizontal hydraulic conductivity of the Gatesburg aquifer is about 36 feet per day. The other carbonate aquifers (Nittany/Stonehenge, Bellefonte/Axemann, and Coburn through Loysburg aquifers) overlying and flanking the Gatesburg aquifer have horizontal hydraulic conductivities of about 1 foot per day. Regional directions of ground-water flow are toward the major streams with Clover Creek as the major discharge point for ground water in the east. Ground-water flow to the well fields is anisotropic with a 5:1 preferential horizontal direction along strike of the axial fold of the anticline. Thus, the zone of contribution of ground water to the well fields is elongate in a north-south direction along the anticline axis, with the majority of the flow to the well fields originating from the south. Human activity in the areal extent of the zone of contribution to the well fields was the source of contaminants. The areal extent of the zone of contribution included both urban areas in the Borough and a large amount of agricultural land. By relating results of flow simulation, natural geochemistry, and analyses of anthropogenic (human-made) contaminants, the source areas for water and contaminants were determined with more confidence than by using only flow simulation. Analysis of natural geochemistry identified water sources from both limestone and dolomite aquifers. Geochemistry results also indicated fractures, not conduits, were the dominant source of water from aquifers; however, quantitative source identification was not possible. Chemical ratios of chloride and bromide were useful to show that all samples of ground water had sources with chemical contributions from land surface. Nitrogen isotope ratio analysis indicated animal manure as the possible primary source of nitrate in most ground water. Some of the nitrate in ground water had chemical fertilizer as a source. At the Wineland well field, chemical fertilizer was likely the source of nitrate. The nitrate in water from the Hershberger well field was from a mixture of fertilizer and animal-manure sources. Human sewage was ruled out as a major source of nitrate in water from the municipal wells by results showing 1) wastewater compounds in sewage were rarely detected and 2) a mass-balance calculation indicating the small contribution of nitrogen that could be attributed to septic systems.

Scientific Investigations Report↗

Water resources and related geology of Dera Ismail Khan district, West Pakistan, with reference to the availability of ground water for development

Dera Ismail (D.I.) Khan District contains an area of 3,450 square miles between the right bank of the Indus River and the Sulaiman Range in westcentral West Pakistan. Agriculture is the principal source of income in the District, but only a small part of the arable land is fully utilized. The region is semiarid and has an average annual rainfall of about 9 inches and a potential evapotranspirational rate of eight to nine times the annual rainfall. Thus, rainfall alone is not adequate for high-intensity cropping. Irrigation is practiced near the Indus River; the Paharpur Canal is used, as well as the traditional inundation method. Elsewhere in the District, adequate water is supplied to local areas by karezes, perennial streams from the mountains, and some recently installed tubewells (see 'Glossary'). Further development of ground-water supplies would permit a more effective utilization of most of the presently tilled land and would allow additional land to be farmed. D.I. Khan District is primarily an alluvial plain that slopes from the mountain ranges in the northern and western parts of the District toward the Indus River. Rocks in the bordering mountains are of Paleozoic to early or middle Pleistocene age. The unconsolidated rocks of the plain, of middle (?) Pleistocene to Holocene (Recent) age, consist of piedmont deposits derived from the hills to the north and west and of alluvium laid down by the Indus River. These deposits interfinger in a transitional zone about 8 to 12 miles west of the river. Lithologic and structural features indicate that the unconsolidated rocks possibly may be divided into broad units. The investigations in D.I. Khan District have revealed two main areas of potential ground-water development based on considerations of both permeability and chemical quality of the ground water: 1. A belt about 10 miles wide parallels the Indus River from the Khisor Range southward to the area immediately south of D.I. Khan town. In this belt, the material penetrated by test holes and tubewells consists predominantly of sand, which in tubewells can yield from 2 to 3 cfs (cubic feet per second) of water with only moderate drawdown. Also in this belt, ground water of good chemical quality extends to depths of 1,000 feet or more. 2. The area from the mouth of the Gumal River gorge to the vicinity of Kot Azam contains sand and gravel strata that may yield from 1 to 3 cfs of water, which contains 500 to 1,500 ppm (parts per million) of total dissolved solids. Other marginal parts of the District also contain water of good chemical quality, but developmental prospects are somewhat poorer because of greater depths to water, lower permeabilities, or greater depths to aquifers, all of which would require greater costs in the tubewell installations. The stratification or zoning of water of different chemical qualities to some extent governs the local availability of useful water. Generally, the ground water of poorest quality is found in the shallow zone, and quality improves with depth. The central part of the District, in a belt reaching from the vicinity of Tank southward to the Indus River near Dera Ghfizi Khan District, contains highly mineralized water and few aquifers. The mineralization of water in this belt is due primarily to large concentrations of sodium and sulfate and thus differs from the main part of the Punjab region where highly mineralized waters are generally chloride waters. Radical changes in water quality, both horizontally and vertically, are common in the District. Changes in chemical quality of water from large-capacity wells near areas of highly mineralized water are taking place, and further changes may be expected as withdrawals continue and increase in magnitude. Under present conditions, surface-water supplies are fully utilized, and ground water is the largest supply available for development-other than that from the Indus River.

Water Supply Paper↗

Reconnaissance of ground water in vicinity of Wichita Mountains southwestern Oklahoma

Urbanization and industrial growth have increased demands on water supplies in the vicinity of the Wichita Mountains in southwestern Oklahoma. The principal city, Lawton, uses surface water, supplemented by small quantities of ground water from the Arbuckle Group (Cambrian-Ordovician), for industrial and recreational use. During periods of drought, surface-water supplies in the Wichita Mountains area are not adequate to meet fully the increased water demands. An alternative source of water may be ground water from the Arbuckle Group. Other urban and rural consumers use ground water from Quaternary alluvium, the Rush Springs Formation (Permian), or the Arbuckle Group.

Oklahoma↗

Technology Transfer Opportunities: Automated Ground-Water Monitoring

Introduction A new automated ground-water monitoring system developed by the U.S. Geological Survey (USGS) measures and records values of selected water-quality properties and constituents using protocols approved for manual sampling. Prototypes using the automated process have demonstrated the ability to increase the quantity and quality of data collected and have shown the potential for reducing labor and material costs for ground-water quality data collection. Automation of water-quality monitoring systems in the field, in laboratories, and in industry have increased data density and utility while reducing operating costs. Uses for an automated ground-water monitoring system include, (but are not limited to) monitoring ground-water quality for research, monitoring known or potential contaminant sites, such as near landfills, underground storage tanks, or other facilities where potential contaminants are stored, and as an early warning system monitoring groundwater quality near public water-supply wells.

Fact Sheet↗