SEARCH · Search USGS

Results for “Facies”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 865 records · Page 48Linked to original sources

USGS1996

Metamorphism and gold mineralization in the Blue Ridge, southernmost Appalachians

Lode gold mineralization in the Blue Ridge of the southernmost Appalachians is hosted by metavolcanic rocks (e.g., Anna Howe mine, AL; Royal Vindicator mine, GA), metaplutonic rocks (e.g., Hog Mountain mine, AL), and metasedimentary rocks (e.g., Lowe, Tallapoosa, and Jones Vein mines, AL). Most gold occurs in synkinematic quartz + or - plagioclase + or - pyrite + or - pyrrhotite + or - chlorite veins localized along polydeformational faults that juxtapose rocks with significantly different peak metamorphic mineral assemblages.Mineralogy, chemistry, and O and H isotope studies suggest that the three types of host rocks have undergone differing amounts and types of alteration during mineralization. Limited wall-rock alteration in metavolcanic- and metasediment-hosted deposits, and relatively extensive wall-rock alteration in granitoid-hosted deposits, suggests that most deposits formed from fluids that were close to equilibrium with metavolcanic and metasedimentary rocks. Stable isotope compositions of the fluids calculated from vein minerals and vein selvages are consistent with a predominantly metasedimentary fluid source, but vary from deposit to deposit (-22 to -47ppm delta D, 4-5ppm, delta 18 O, and 5-7ppm delta 34 S at Anna Howe and Royal Vindicator; -48 to -50ppm delta D, 9-13ppm delta 18 O, and ca. 19ppm delta 34 S at Lowe and Jones Vein; and -22 to -23ppm delta D, 8-11ppm delta 18 O, 9-10ppm delta 34 S, and -6 delta 13 C at Hog Mountain). Silicate mineral thermobarometry of vein, vein selvage, and wall-rock mineral assemblages indicate that mineralization and regional metamorphism occured at greenschist to amphibolite facies (480 degrees + or - 75 degrees C at Anna Howe, 535 degrees + or - 50 degrees C at 6.4 + or - 1 kbars at Lowe, 530 degrees + or - 50 degrees C at 6.9 + or - 1 kbars at Tallapoosa, and 460 degrees + or - 50 degrees C at 5.5 + or - 1 kbars at Hog Mountain). Oxygen isotope fractionation between vein minerals and selvage minerals consistently records equilibration temperatures that are similar to or slightly lower than those estimated from silicate thermometry.Auriferous veins contain numerous fluid inclusions that were emplaced in several stages and can be subdivided into five compositional types based on salt and CO 2 concentrations. Fluid inclusion isochores for early formed inclusions from these veins intercept the pressure and temperature conditions estimated from silicate mineral thermobarometry and stable isotope thermometry, and are compatible with entrapment at those conditions. These fluids exhibit significant variation in salinity (X (sub NaCl equiv ) ) = 0.0-0.2) and CO 2 (X (sub CO 2 ) = 0.0-0.2), suggesting variation in fluid-wall-rock interaction that accompanied gold deposition during declining temperatures. Less abundant and later fluids within the veins are dominantly CO 2 .The association of gold mineralization with structurally controlled concordant and discordant quartz sulfide veins, and the temperatures and pressures of wall-rock alteration and regional metamorphism indicate that the present distribution of gold is a result of metamorphism during progressive D 2 -D 3 deformation. Isotopic data for alteration envelopes date this event as Alleghanian: 279 + or - 14 Ma (K-Ar whole rock) and 343 + or - 18 Ma (K-Ar biotite) at Lowe; and 315 + or - 18 Ma (Rb-Sr whole-rock isochron; 87 Sr/ 86 Sr i = 0.7061 + or - 0.0008) and 294 + or - 16 Ma (K-Ar whole-rock) at Hog Mountain. Available data are compatible with development of the lodes during early Alleghanian overthrusting of allochthons over sedimentary rocks of the autochthonous North American margin. The implication is that the fluids were derived from metasedimentary and/or metavolcanic formations in the lower parts of the crystalline thrust stack (or possibly from underlying autochthonous sedimentary formations), ascended along permeable fault zones, and were emplaced as veins into dilatent areas in and adjacent to the fault zones.

Economic Geology↗

USGS2003

Geochemistry of the furnace magnetite bed, Franklin, New Jersey, and the relationship between stratiform iron oxide ores and stratiform zinc oxide-silicate ores in the New Jersey highlands

The New Jersey Highlands terrace, which is an exposure of the Middle Proterozoic Grenville orogenic belt located in northeastern United States, contains stratiform zinc oxide-silicate deposits at Franklin and Sterling Hill and numerous massive magnetite deposits. The origins of the zinc and magnetite deposits have rarely been considered together, but a genetic link is suggested by the occurrence of the Furnace magnetite bed and small magnetite lenses immediately beneath the Franklin zinc deposit. The Furnace bed was metamorphosed and deformed along with its enclosing rocks during the Grenvillian orogeny, obscuring the original mineralogy and obliterating the original rock fabrics. The present mineralogy is manganiferous magnetite plus calcite. Trace hydrous silicates, some coexisting with fluorite, have fluorine contents that are among the highest ever observed in natural assemblages. Furnace bed calcite has ??13C values of -5 ?? 1 per mil relative to Peedee belemnite (PDB) and ??18O values of 11 to 20 per mil relative to Vienna-standard mean ocean water (VSMOW). The isotopic compositions do not vary as expected for an original siderite layer that decarbonated during metamorphism, but they are consistent with nearly isochemical metamorphism of an iron oxide + calcite protolith that is chemically and minerlogically similar to iron-rich sediments found near the Red Sea brine pools and isotopically similar to Superior-type banded iron formations. Other magniferous magnite + calcite bodies occur at approximately the same stratigraphic position as far 50 km from the zinc deposits. A model is presented in which the iron and zinc deposits formed along the western edge of a Middle Proterozoic marine basin. Zinc was transported by sulfate-stable brines and was precipitated under sulfate-stable conditions as zincian carbonates and Fe-Mn-Zn oxides and silicates. Whether the zincian assemblages settled from the water column or formed by replacement reactions in shallowly buried sediments is uncertain. The iron deposits formed at interfaces between anoxic and oxygenated waters. The Furnace magnetite bed resulted from seawater oxidation of hydrothermally transported iron near a brine conduit. Iron deposits also formed regionally on the basin floor at the interface betveen anoxic deep waters and oxygenated shallower waters. These deposits include not only manganiferous magnetite + calcite bodies similar to the Furnace magnetite bed but also silicate-facies deposits that formed by iron oxide accumulation where detrital sediment was abundant. A basin margin model can be extended to Grenvillian stratiform deposits in the northwest Adirondacks of New York and the Mont Laurier basin of Quebec. In these areas iron deposits (pyrite or magnetite) are found basinward of marble-hosted sphalerite deposits, such as those in the Balmat-Edwards district. Whether the iron and zinc precipitated as sulfide assemblages or carbonate-oxide-silicate assemblages depended on whether sufficient organic matter or other reductants were available in local sediments or bottom waters to stabilize H2S.

New Jersey↗

USGS2004

A geologic framework for mineralization in the western Brooks Range

The Brooks Range is a 950-km-long north-vergent fold and thrust belt, which was formed during Mesozoic convergence of the continental Arctic Alaska terrane and the oceanic Angayucham terrane and was further shortened and uplifted in Tertiary time. The Arctic Alaska terrane consists of parautochthonous rocks and the Endicott Mountains and De Long Mountains subterranes. The Endicott Mountains allochthon of the western Brooks Range is the setting for many sulfide and barite occurrences, such as the supergiant Red Dog zinc-lead mine. Mineralization is sediment hosted and most commonly is present in black shale and carbonate turbidites of the Mississippian Kuna Formation. The reconstructed Kuna basin is a 200 by +600 km feature that represents the culmination of a remarkable chain of events that includes three fluvial-deltaic and two or more orogenic cycles, Middle Devonian to Mississippian episodes of extension and igneous activity, and the emergence of a seaward Lower Proterozoic landmass that may have constituted a barrier to marine circulation. Mississippian extension and related horst-and-graben architecture in the western Brooks Range is manifested in part by strong facies variability between coeval units of allochthons and structural plates. Shallow marine to possibly nonmarine arkose, platform to shelf carbonate, slope-to-basin shale, chert and carbonate turbidites, and submarine volcanic rocks are all represented in Mississippian time. The structural setting of Mississippian sedimentation, volcanism, and mineralization in the Kuna basin may be comparable to documented Devono-Mississippian extensional sags or half-grabens in the subsurface north of the Brooks Range. Climate, terrestrial ecosystems, multiple fluvial-deltaic aquifers, and structural architecture affected the liberation, movement, and redeposition of metals in ways that are incompletely understood.

Alaska↗

USGS2004

Paleozoic sedimentary rocks in the Red Dog Zn-Pb-Ag district and vicinity, western Brooks Range, Alaska: provenance, deposition, and metallogenic significance

Geochemical analyses of Paleozoic sedimentary rocks in the western Brooks Range reveal a complex evolutionary history for strata surrounding the large Zn-Pb-Ag deposits of the Red Dog district. Data for major elements, trace elements, and rare earth elements (REE) were obtained on 220 samples of unaltered and unmineralized siliciclastic rocks from the Upper Devonian-Lower Mississippian Endicott Group (Hunt Fork Shale, Noatak Sandstone, Kanayut Conglomerate, Kayak Shale), the overlying Carboniferous Lisburne Group (Kuna Formation, unnamed drowned shelf facies), and the Pennsylvanian-Permian Siksikpuk Formation. Major base metal sulfide deposits of the region are present only in the Kuna Formation, which in the Red Dog district comprises siliceous black shale and black chert, minor limestone (calcareous radiolarite), and sparse lithic turbidite and bedded siliceous rock. Gray and rare black shales of the Kayak Shale and common black shales of the Kuna Formation are anomalously low in iron (avg Fe/Ti = 6.25 and 6.34, respectively) relative to other Paleozoic shales in the region (9.58-10.6) and to average shales worldwide (10.1-10.5). In contrast, the bedded siliceous rocks contain appreciable hematite (avg Fe/Ti = 35.0) and high U/Ti and REE/Ti ratios that are interpreted to reflect low amounts of detrital material and a major Fe-rich eolian component. Geochemical data (e.g., MnO <0.01 wt %; avg Cr = 317 ppm), sizes of framboidal pyrite grains, and limited bioturbation suggest anoxic and denitrifying depositional conditions for most black shales of the Kuna Formation; low Mo/Ti ratios argue against euxinic (sulfate-reducing) conditions. Organic-rich black shales of the Kuna Formation with up to 8.4 wt percent C organic and gray to black shales of the Kayak Shale with up to 4.1 wt percent C organic typically have only sparse pyrite (<1 wt % S) and very low iron-limited S/C ratios (mostly <0.2). Immobile element plots (e.g., Th-Zr/10-Sc) suggest that source terranes for all of the formations were dominated by one or more felsic-rich continental arcs; a small proportion of recycled sediments is present locally. A minor mafic igneous component also occurs in several shales of the Kuna and Siksikpuk Formations. High average values for the chemical index of alteration [Al 2 O 3 /(Al 2 O 3 + CaO + Na 2 O + K 2 O)] ∞ 100 for shales of the Endicott Group (76.4-81.5) imply moderate to intense chemical weathering in source areas of these sediments. A lower average for black shales of the Kuna Formation (73.7) does not require such weathering. Textural and geochemical data record the effects of diagenetic and/or hydrothermal fluid flow in some of the Paleozoic rocks. Mobility of P, F, U, and light REE is documented in black shales of the Kuna Formation by phosphate replacements of carbonate clasts and of matrix material surrounding the clasts. A relatively low average Ce/Ce* value of 0.73 for P-poor black shales of the Kuna Formation ( < 0.05 wt % P 2 O 5 ) and a similar Ce/Ce* value of 0.78 for a siderite concretion in Kayak Shale suggest that these diagenetic fluids were oxidizing. Many shales of the Kuna Formation have high (K 2 O ∞ 100)/(K 2 O + Al 2 O 3 ) ratios of 21.0 to 23.0, which contrast with low ratios of generally <18.0 for shales of the underlying Endicott Group. The high ratios in shales of the Kuna Formation reflect preferential reaction of smectite to illite during the Jurassic-Cretaceous Brookian orogeny, owing to high silica activities in pore fluids that were generated by the dissolution of abundant biogenic silica. The distribution and composition of Paleozoic strata in the western Brooks Range may have played a fundamental role in Zn-Pb mineralization of the Red Dog district. In our model, deposition and early lithification of biogenic chert and bedded siliceous rocks in the upper part of the Kuna Formation served as a regional hydrologic seal, acting as a cap rock to heat and hydrothermal fluids during Late Mississippian base-metal mineralization. Equally important was the iron-poor composition of black shales of the Kuna Formation (i.e., low Fe/Ti ratios), which limited synsedimentary pyrite formation in precursor sediments, resulting in significant H 2 S production in pore waters through the interaction of aqueous sulfate with abundant organic matter. This H 2 S may have been critical to the subsurface deposition of the huge quantities of Zn and Pb in the district. On the basis of this model, we propose that low Fe/Ti and S/C ratios in black shale sequences are potential basin-scale exploration guides for giant sediment-hosted, stratiform Zn-Pb-Ag deposits.

Alaska↗

USGS2004

Nature of hydrothermal fluids at the shale-hosted Red Dog Zn-Pb-Ag deposits, Brooks Range, Alaska

The Red Dog Zn-Pb-Ag district in the western Brooks Range, northern Alaska, contains numerous shale-hosted Zn-Pb sulfide and barite deposits in organic-rich siliceous mudstone and shale, chert, and carbonate rocks of the Carboniferous Kuna Formation. The giant Red Dog shale-hosted deposits consist of a cluster of four orebodies (Main, Qanaiyaq, Aqqaluk, and Paalaaq) that lie within distinct thrust panels that offset a single ore deposit during the Mesozoic Brookian orogeny. These Zn-Pb-Ag-barite orebodies contain one of the world's largest reserves and resources of zinc. Fluid inclusions in samples of vein sphalerite, which accounts for about 20 percent of the ore in the Main deposit, and quartz that composes the bulk of the extensive silicification in the ore deposit, were studied by microthermometry, Raman spectrometry, and ion chromatography. The study of fluid inclusions in the vein sphalerite was limited by the intense postore deformation of the ore deposits. However, four primary aqueous fluid inclusion assemblages in vein sphalerite yield temperatures of homogenization of 115° to 120°C, 123° to 127°C, 110° to 120°C and 175° to 180°C. More abundant final-melting temperatures indicate that the fluid inclusions in sphalerite have salinities of about 14 to 19 wt percent NaCl equiv. The fluid inclusion electrolyte data show that the ore fluid responsible for the vein sphalerite derived its salinity from the evaporation of seawater. Considering the salinity of the fluid inclusions together with the electrolyte data, it is possible that the evaporative brine was initially about 30 wt percent saline fluid and that it mixed with a more dilute fluid somewhere along its flow path. The temperature, salinity, and electrolyte composition of vein sphalerite in the Red Dog deposits are remarkably similar to those characteristics in sphalerite veins near the Century zinc deposit, Australia. Together, these data compose the majority of information on the temperature and composition of sphalerite in deposits of this type. On the basis of data describing fluid inclusions in sphalerite and the geologic setting of the ore deposits, a "reflux brine" model is suggested for the Red Dog deposits. In this model, brines were produced in evaporative environments in supratidal carbonate facies of the Lisburne Group less than 100 km from the Red Dog deposits. These reflux brines may have infiltrated the underlying rocks of Endicott Group or fractured metasedimentary basement rocks. In the absence of a local heat source at the Red Dog deposits, the temperature of the ore fluids (~100° to <200°C) requires that the fluids circulated at depths between ~ 2.4 and 7.4 km. In the Red Dog area, the metalliferous fluids ascended into the organic-rich rocks of the Kuna Formation, probably along zones of active extensional faults or breaches in the shale aquitards overlying the aquifers in the Endicott Group. Fluid inclusions were also studied in the abundant quartz that constitutes the majority of the silica rock in the ore deposits. This postore quartz extensively replaced barite and was traditionally thought to be part of the main ore event. Primary fluid inclusion assemblages contain two-phase aqueous inclusions, single-phase inclusions of dense methane, or both. Primary assemblages that contain single-phase, dense-methane inclusions together with two-phase aqueous inclusions yield consistent homogenization temperatures that provide unequivocal evidence for the coeval trapping of immiscible gas and aqueous fluids. The densities of the methane inclusions, together with the temperature of homogenization of coexisting aqueous fluid inclusions, show that these fluid inclusions were trapped between pressures of 800 and 3,400 bars and temperatures between 187° and 214°C. The pressures obtained provide unequivocal evidence that the quartz formed after ore deposition in the Carboniferous because such high fluid pressures could only have been produced from thrust loading during the Mesozoic Brookian orogeny. The observed large variation in pressure is best explained by transient fluid pressures from hydrostatic to lithostatic conditions during thrust loading. The 3,400 bars pressure corresponds with about 12 km of lithostatic burial, whereas the lower pressures (800 bars) correspond with about 8 km of hydrostatic pressure. Because of their low salinity (0-5 wt % NaCl equiv) the electrolyte compositions of the quartz fluid inclusions do not constrain their origin.

Alaska↗

USGS2003

Tectonic evolution of the Proterozoic Colorado Province, Southern Rocky Mountains: A summary and appraisal

The Colorado province is a major component of a >1000-km-wide belt of Paleoproterozoic ocean-arc rocks that occupies the southwestern United States. Known as the Transcontinental Proterozoic provinces, this belt of largely juvenile rocks was added to the southern margin of the North American craton during the interval 1.8-1.70 Ga by convergent tectonism along the Cheyenne belt. A growing body of data suggests that these rocks were deposited, at least locally, on older rocks of earliest Proterozoic and Archean ages, probably correlative with the Trans-Hudson and Penokean orogens. The volcano-plutonic and associated sedimentary rocks of the Colorado province record two major, regional orogenies: (1) an older, protracted thermotectonic episode (1.78-1.70 Ga), named the Colorado orogeny, which involved mainly amphibolite-facies metamorphism during piecemeal assembly of various ocean-arc terranes; and (2) a younger, Mesoproterozoic intra-continental orogeny, named the Berthoud orogeny, which involved associated regional heating and A-type plutonism chiefly during the interval 1.45-1.40 Ga. The term "Colorado orogeny" is proposed for the regional Paleoproterozoic dynamothermal deformation. To distinguish differences in the geodynamics and ages of deformation and facilitate comparisons from place to place, type localities are proposed for separate phases or events of the Colorado orogeny. The central Front Range is suggested as a type area for the Berthoud orogeny, because the character and orientation of structures there are readily distinguished from those of the older Colorado orogeny.

Colorado↗

USGS2009

Structural development of high-temperature mylonites in the Archean Wyoming province, northwestern Madison Range, Montana

The Crooked Creek mylonite, in the northwestern Madison Range, southwestern Montana, is defined by several curved lenses of high non-coaxial strain exposed over a 7-km-wide, northeast-trending strip. The country rocks, part of the Archean Wyoming province, are dominantly trondhjemitic to granitic orthogneiss with subordinate amphibolite, quartzite, aluminous gneiss, and sills of metabasite (mafic granulite). Data presented here support an interpretation that the mylonite formed during a period of rapid, heterogeneous strain at near-peak metamorphic conditions during an early deformational event (D 1 ) caused by northwest–southeast-directed transpression. The mylonite has a well-developed L-S tectonite fabric and a fine-grained, recrystallized (granoblastic) texture. The strong linear fabric, interpreted as the stretching direction, is defined by elongate compositional “fish,” fold axes, aligned elongate minerals, and mullion axes. The margins of the mylonitic zones are concordant with and grade into regions of unmylonitized gneiss. A second deformational event (D 2 ) has folded the mylonite surface to produce meter- to kilometer-scale, tight-to-isoclinal, gently plunging folds in both the mylonite and country rock, and represents a northwest–southeast shortening event. Planar or linear fabrics associated with D 2 are remarkably absent. A third regional deformational event (D 3 ) produced open, kilometer-scale folds generally with gently north-plunging fold axes. Thermobarometric measurements presented here indicate that metamorphic conditions during D 1 were the same in both the mylonite and the country gneiss, reaching upper amphibolite- to lower granulite-facies conditions: 700 ± 50° C and 8.5 ± 0.5 kb. Previous geochronological studies of mylonitic and cross-cutting rocks in the Jerome Rock Lake area, east of the Crooked Creek mylonite, bracket the timing of this high-grade metamorphism and mylonitization between 2.78 and 2.56 Ga, nearly a billion years before the 1.78-Ga Big Sky orogeny, which overprinted the basement rocks exposed in adjacent ranges of the Wyoming province.

Montana↗

USGS2016

Application of ground penetrating radar for identification of washover deposits and other stratigraphic features: Assateague Island, MD

A combination of ground penetrating radar (GPR) data, core data, and aerial photographs were analyzed to better understand the evolution of two portions of Assateague Island, Maryland. The focus of the study was to investigate the applicability of using GPR data to image washover deposits in the stratigraphic record. High amplitude reflections observed in two shore-perpendicular GPR profiles were correlated to shallow (<1 m) lithologic contacts observed in sediment cores. At these contacts, deposits consisting primarily of quartz sand overlie sediments with organic matter that include degraded plant root or stem material. The underlying organic matter likely represents the vegetated portion of the barrier island that was buried by washover fans deposited during hurricanes Irene (2011) and Sandy (2012), as indicated in high-resolution aerial photographs. The GPR data were able to delineate the washover deposits from the underlying stratigraphic unit; however, the radar data did not resolve finer structures necessary to definitively differentiate washover facies from other sand-rich deposits ( e.g., flood-tide deltas and dunes). Other GPR profiles contain reflections that likely correlate to geomorphic features like tidal channels and vegetated zones observed in historical aerial imagery. Burial of these features by overwash fluxes were observed in the aerial imagery and thus the resulting radar sequence is largely interpreted as washover deposits. Deeper, channel-like features that have been infilled were also observed in shore-parallel profiles and these features coincide with scour channels observed in the 1966 aerial photography. Additional sedimentological data are required to determine what role overwash played in the in-filling of these features.

Journal of Environmental & Engineering Geophysics↗

USGS2024

A methodology to estimate CO2 and energy gas storage resources in depleted conventional gas reservoirs

Depleted hydrocarbon reservoirs are subsurface geological structures capable of sequestering vast quantities of carbon dioxide (CO 2 ) as well as storing other energy gases for later usage, such as natural gas, and potentially hydrogen (H 2 ). Here we outline a methodology to quantify multi-gas storage resources in depleted conventional gas reservoirs for usage in assessments by the United States Geological Survey (USGS) at the scale of sedimentary basins. The methodology consists first of quantifying accessible pore volume in a depleted reservoir for natural gas storage using up to three equations. Input data are derived from commonly reported or estimated reservoir parameters and natural gas production volumes, and equations may be combined in linear models to improve pore volume estimates. Storage estimates from these equations are tested and validated for 31 reservoirs in the Michigan Basin Province, USA that were previously converted to underground gas storage facilities and have known (federally reported) natural gas storage capacities. Secondly, natural gas storage capacities can be transformed via fluid substitution calculations to estimate the storage resources for non-native fluids, applied here for, CO 2 , H 2 , and methane-H 2 blends, accounting for molecule-specific deviations from ideal gas behavior at reservoir pressures and temperatures as well as differing storage efficiencies. Importantly, the storage of non-native fluids may not be appropriate in all depleted gas reservoir settings due to potential risks like leakage, in particular in the case of H 2 storage, requiring additional knowledge of caprock sealing capacity. Given this caveat, we demonstrate the fluid substitution method for natural gas reservoirs of the Northern Niagaran Reef and Southern Niagaran Reef USGS plays in the Michigan Basin Province, as these trends of Silurian pinnacle reefs are capped with tight-sealing evaporite facies. The deterministic equations outlined from this methodology can be incorporated into future probabilistic USGS gas storage assessments for CO 2 , H 2 , and natural gas resources in the United States.

Michigan↗

USGS2017

Application of organic petrology in high maturity shale gas systems

Application of incident light microscopy techniques for organic petrology in high temperature thermogenic shale gas systems demonstrates that solid bitumen is the dominant organic matter. Solid bitumen is retained as a residual conversion product as oil-prone kerogen cracks to hydrocarbons or occurs from the cracking of once liquid oil. Oil-prone Type I/II kerogens are not present in shale gas reservoirs, already having converted to hydrocarbons. Type III/IV kerogens (vitrinite and inertinite) are refractory and persist in shale gas reservoirs to high maturity with little morphological change apart from condensation and aromatization causing higher reflectance. Organic petrology applications are most useful for thermal maturity determination and delineation of hydrocarbon windows through measurement of vitrinite reflectance and vitrinite reflectance equivalents from other organic matter (zooclasts and/or solid bitumen). Depositional organo-facies determination generally is not possible in the gas window of thermal maturity; fluorescence microscopy is not useful as organic matter is no longer autofluorescent. Application of scanning electron microscopy (SEM) allows observation of an interconnected nano-scale organic porosity in shale gas systems but suffers from inability to identify organic matter types. SEM approaches to shale gas reservoir characterization therefore should not attempt differentiation of kerogen types or kerogen vs. solid bitumen identification unless correlative organic microscopy is performed. Herein are reviewed organic petrology results as used in the shale gas systems of North America, Europe and China, including SEM applications, citing recent examples from the literature.

Book chapter↗

USGS1983

Late Holocene ice wedges near Fairbanks, Alaska, USA: Environmental setting and history of growth

Test trenches excavated into muskeg near Fairbanks in 1969 exposed a polygonal network of active ice wedges. The wedges occur in peat that has accumulated since about 3500 yr BP and have grown episodically as the permafrost table fluctuated in response to fires, other local site conditions and perhaps regional climatic changes. Radiocarbon dates suggest one or two episodes of ice-wedge growth between about 3500 and 2000 yr BP as woody peat accumulated at the site. Subsequent wedge truncation evidently followed a fire that charred the peat. Younger peat exhibits facies changes between sedge-rich components that filled troughs over the ice wedges and woody bryophytic deposits that formed beyond the troughs. A final episode of wedge development took place within the past few hundred years. Pollen data from the site indicate that boreal forest was present throughout the past 6000 yr, but that it underwent a gradual transition from a predominantly deciduous to a spruce-dominated assemblage. This change may reflect either local site conditions or a more general climatic shift to cooler, moister summers in late Holocene time. The history of ice-wedge growth shows that wedges can form and grow to more than 1 m apparent width under mean annual temperatures that probably are close to those of the Fairbanks area today (-3.5°C) and under vegetation cover similar to that of the interior Alaskan boreal forest. The commonly held belief that ice wedges develop only below mean annual air temperatures of -6 to -8°C in the zone of continuous permafrost is invalid.

Alaska↗

USGS1998

The ichnologic record of the continental invertebrate invasion; evolutionary trends in environmental expansion, ecospace utilization, and behavioral complexity

The combined study of continental trace fossils and associated sedimentary facies provides valuable evidence of colonization trends and events throughout the Phanerozoic. Colonization of continental environments was linked to the exploitation of empty or under-utilized ecospace. Although the nonmarine trace fossil record probably begins during the Late Ordovician, significant invasion of nonmarine biotopes began close to the Silurian-Devonian transition with the establishment of a mobile arthropod epifauna (Diplichnites ichnoguild) in coastal marine to alluvial plain settings. Additionally, the presence of vertical burrows in Devonian high-energy fluvial deposits reflects the establishment of a stationary, deep suspension-feeding infauna of the Skolithos ichnoguild. The earliest evidence of plant-arthropod interaction occurred close to the Silurian-Devonian boundary, but widespread and varied feeding patterns are known from the Carboniferous. During the Carboniferous, permanent subaqueous lacustrine settings were colonized by a diverse, mobile detritus-feeding epifauna of the Mermia ichnoguild, which reflects a significant palaeoenvironmental expansion of trace fossils. Paleozoic ichnologic evidence supports direct routes to the land from marginal marine environments, and migration to lakes from land settings. All nonmarine sedimentary environments were colonized by the Carboniferous, and subsequent patterns indicate an increase in ecospace utilization within already colonized depositional settings. During the Permian, back-filled traces of the Scoyenia ichnoguild record the establishment of a mobile, intermediate-depth, deposit-feeding in-fauna in alluvial and transitional alluvial-lacustrine sediment. Diversification of land plants and the establishment of ecologically diverse plant communities through time provided new niches to be exploited by arthropods. Nevertheless, most ot the evolutionary feeding innovations took place relatively early, during the Late Palaeozoic or early Mesozoic. A stationary deep unfauna, the Camborygma ichnoguild, was developed in Triassic transitional alluvial-lacustrinbe deposits. Terrestrial environments hosted the rise of complex social behavioral patterns, as suggested by the probable presence of hymenopteran and isopteran nests in Triassic paleosols. An increase in diversity of trace fossils is detected in Triassic-Jurassic eolian deposits, where the ichnofauna displays more varied behavioral patterns than their Paleozoic counterparts. Also, a mobile, intermediate-depth, deposit-feeding infauna, the Vagorichnus ichnoguild, was established in deep lake environments during the Jurassic. In contrast to Paleozoic permanent subaqueous assemblages typified by surface trails, Jurassic ichnocoenoses are dominated by infaunal burrows. High density of infaunal deposit-feeding traces of the Planolites ichnoguild caused major disruption of lacustrine sedimentary fabrics during the Cretaceous. Most insect mouthpart classes, functional feeding groups, and dietary guilds were established by the end of the Cretaceous. Diversification of modern insects is recorded by the abundance and complexity of structures produced by wasps, bees, dung-beetles, and termites in Cretaceous-Tertiary paleosols. The increase in bioturbation migrated from fluvial and lake-margin settings to permanent subaqueous lacustrine environments through time.

Palaios↗

USGS2024

Deformation by pressure solution and grain boundary sliding in a retrograde shear zone in southern New England, USA

Alleghanian phyllonites in a shear zone in southern New England were formed by the retrogression and hydration of a high-grade Acadian pelitic schist. The retrogression was locally incomplete, resulting in both heterogeneous mineralogy and mineral compositions, and in many arrested reaction textures. These features, documented by backscattered electron and element map imaging, and by 40 Ar/ 39 Ar dating, provide a record of the processes active as the schist was converted to a phyllonite. On the margins of the shear zone relic biotite and garnet grains survive but are partially replaced by chlorite. Relic high-grade muscovite flakes containing up to 35 % paragonite (pg) also persist but are entrained in swarms of pg-poor muscovite flakes producing folia with an anastomosing network of muscovite grains of variable composition. Single crystals of pg-rich muscovite are truncated by muscovite in successively younger cross-cutting folia that contain decreasing pg contents, falling to <5% pg in the youngest folia. In the core of the shear zone all high-grade minerals are destroyed, but recrystallization continues with earlier greenschist facies folia replaced by lower grade and pg-poorer muscovite in younger folia. Muscovite grains in truncated folia are commonly kinked and selective recrystallization of muscovite in kink bands to pg-poor-compositions demonstrates that strain energy helped drive recrystallization. The boundaries of these new pg-poor muscovite folia are sharp, and truncations indicate that grain boundary sliding (GBS) involved dissolution. GBS also enabled folding by flexural slip along muscovite grain boundaries. Fold amplitudes increased as chlorite dissolved from fold limbs precipitated in fold hinges producing crescent-shaped saddle-reef-like structures. Together these observations of truncation and replacement by dissolution and precipitation demonstrate that pressure solution and GBS facilitated both the formation of the phyllonitic shear zone and slip along it.

Connecticut↗

USGS2017

Petrology and geochronology of Mesoproterozoic basement of the Mount Rogers area of southwestern Virginia and northwestern North Carolina: Implications for the Precambrian tectonic evolution of the southern Blue Ridge province

Results from new geologic mapping, SHRIMP U-Pb geochronology, and petrologic studies indicate that Mesoproterozoic basement in the northern French Broad massif near Mount Rogers consists of multiple, mostly granitic plutons, map- and outcrop-scale xenoliths of pre-existing crustal rocks, and remnants of formerly overlying meta-sedimentary lithologies. Zircon and titanite ages demonstrate that these rocks collectively record nearly 350 m.y. of tectonic evolution including periods of igneous intrusion at ca . 1190 to 1130 Ma (Early Magmatic Suite) and ca . 1075 to 1030 Ma (Late Magmatic Suite) and three episodes of regional metamorphism at ca . 1170 to 1140, 1070 to 1020, and 1000 to 970 Ma. The existence of ca . 1.3 Ga age crust is indicated by (1) orthogranofels of ca . 1.32 Ga age in a map-scale xenolith, (2) inherited zircons of ca . 1.33 to 1.29 Ga age in Early Magmatic Suite plutons, and (3) ca . 1.36 to 1.30 Ga age detrital zircons in meta-sedimentary lithologies. Mineral assemblages developed in amphibolites and granofelses indicate that metamorphism during both Mesoproterozoic episodes occurred at upper amphibolite- to lower granulite-facies conditions. Syn-orogenic Early Magmatic Suite plutons emplaced at ca . 1190 to 1145 Ma are characterized by high-K, variably magnesian, dominantly calc-alkalic compositions, and have trace-element characteristics indicative of continental-arc magmatic origin involving melting of thick continental crust. In contrast, ca . 1140 Ma age quartz syenite displays A-type features indicating derivation from depleted crustal sources with increased mantle input during waning stages of regional contraction. Plutons of the compositionally bimodal Late Magmatic Suite include (1) ca . 1060 Ma meta-granite with geochemical characteristics transitional between silicic rocks of arc systems and post-collisional granites of A-type lineage, and (2) ca . 1055 Ma monzodioritic rocks with A-type compositional characteristics that likely reflect derivation from fertile, mafic sources in the lower crust. Collectively, these data suggest that Mesoproterozoic rocks of the study area preserve evidence of multiple orogenic episodes that likely involved continental-arc development and deformation at ca . 1150 Ma followed by crustal thickening at ca . 1060 Ma. Field relations and geochronologic data indicate that regional uplift and sedimentation occurred at ca . 1100 Ma between the two episodes of overlapping magmatism and orogenesis. The nature and timing of Mesoproterozoic events recorded in basement rocks of the study area illustrate significant differences in the lithologic assemblages and geologic history preserved by Mesoproterozoic basement of the adjacent Shenandoah and French Broad massifs, suggesting that the Blue Ridge massifs occupied different locations within the regional Grenville-age orogen until about 1070 Ma when the effects of Ottawan-age tectonics began to affect both areas. The near ubiquity of Ottawan-age orogenic activity recorded in Mesoproterozoic rocks of the Blue Ridge, other Appalachian inliers such as the New Jersey Highlands, and the Grenville province of Canada, including the Adirondacks, suggests that these formerly disparate terranes were amalgamated to form a common, regional orogen by this time.

North Carolina, Virginia↗

USGS2022

New Idria serpentinite protrusion, Diablo Range, California: From upper mantle to the surface

The New Idria serpentinite body in the Coast Ranges of California is a diapir that resulted from the interaction of the migrating Mendocino trench-ridge-transform fault triple junction, transpression, metasomatic fluids, and previously subducted oceanic crust and mantle. Northward propagation of the San Andreas fault progressively eliminated the original subduction zone, allowing seawater to penetrate into the formerly subducting abyssal peridotite mantle, triggering serpentinization. The associated physical changes in density, volume, and strength yielded an expanding, buoyantly rising serpentinite protrusion, facilitated by transpression along the San Andreas fault. Sedimentary facies and intrusion of minor cross cutting syenite and alkali basalt dikes indicate that the serpentinization-driven diapir buoyantly rose and widely breached the surface by ca. 14 Ma, attending migration of the Mendocino Triple Junction past the latitude of New Idria.

California↗

USGS2026

Paleocene-Eocene dinoflagellate biostratigraphy in the central Delaware coastal plain

Dinoflagellate cyst palynology and lithostratigraphy from three continuously cored boreholes (Blackbird, Smyrna, and Woodland Beach), supplemented by calcareous nannofossil biostratigraphic data, were used to refine the age and correlation of three Paleocene-Eocene formations in northern Delaware: the Vincentown, Manasquan, and Shark River. Lithologic logs reveal significant facies changes in the upper Paleocene Vincentown Formation over a short distance (*9 km) southeastward, transitioning from very permeable glauconite-quartz-shell-rich sands that form the regionally important Rancocas/Aquia aquifer to much less permeable muddy sands and sandy muds. These lithologic changes represent a shift from nearshore, clear, warm-water, carbonate-rich sand shoals to mud-dominated deeper-water, offshore shelfal environments. Dinocyst assemblages including Areoligera gippingensis, Cribroperidinium giuseppei, and Stenodinium meckelfeldensis confirm the Paleogene ages and track these paleoceanographic changes from shallow coastal settings updip to neritic or outer marine settings downdip. The Vincentown Formation is unconformably overlain by the lower Eocene Manasquan Formation, which consists predominantly of silt and clay with relatively consistent lithology across the study area, representing general neritic or open marine conditions. Lithology, dinoflagellate cyst assemblages, and calcareous nannofossil data indicate that the Marlboro Clay and its record of the onset of the Paleocene-Eocene Thermal Maximum (PETM) global warming event is absent from the Paleocene-Eocene transition at these sites, with an unconformity marking the boundary between the Vincentown and Manasquan formations. The youngest unit examined, the Eocene Shark River Formation, unconformably overlies the Manasquan Formation and consists of interbedded clayey silts and sands, with dinoflagellate assemblages suggesting a return to coastal or inner neritic settings. Calcareous nannofossil zones recognized from the Woodland Beach core corroborate the depositional ages determined using dinoflagellates throughout the sequence, confirming the chronostratigraphic framework for these important coastal plain units.

Delaware↗

USGS2001

Leg 188 synthesis: Transitions in the glacial history of the Prydz Bay region, East Antarctica, from ODP drilling

Drilling during Leg 119 (1988) and Leg 188 (2000; Sites 1165–1167) of the Ocean Drilling Program (ODP) provides direct evidence for long- and short-term changes in Cenozoic paleoenvironments in the Prydz Bay region. Cores from across the continental margin reveal that in preglacial times the present shelf was an alluvial plain system with austral conifer woodland in the Late Cretaceous that changed to cooler Nothofagus rainforest scrub by the middle to late Eocene (Site 1166). Earliest recovered evidence of nearby mountain glaciation is seen in late Eocene–age grain textures in fluvial sands. In the late Eocene to early Oligocene, Prydz Bay permanently shifted from being a fluvio-deltaic complex to an exclusively marine continental shelf environment. This transition is marked by a marine flooding surface later covered by overcompacted glacial sediments that denote the first advance of the ice sheet onto the shelf. Cores do not exist for the early Oligocene to early Miocene, and seismic data are used to infer the transition from a shallow to normal depth prograding continental shelf with submarine canyons on the slope and channel/levees on the rise. Cores from the continental rise at Site 1165 show long-term (millions of years) early Miocene and younger decreases in sedimentation rates as well as short-term (Milankovitch periods) cyclicity between principally biogenic and terrigenous sediment supply—resulting from the cyclic presence of onshore glaciers and changes in ocean circulation. Middle Miocene transitions include rapid decreases in sedimentation rates, increased ice-rafted debris, shifts in clays and other minerals, and regional erosion of the slope and rise. These transitions may reflect enhanced glacial erosion and reduced glacial meltwater from progressively colder ice. At this time, seismic data show that depocenters began to shift from the outer continental rise to the base of the continental slope coincident with the initial stages of the glacial erosion and overdeepening of the continental shelf. During the late Miocene to early Pliocene there was a transition to greater subglacial activity on the shelf and more pronounced cyclic facies variations on the continental rise. At this time, severe glacial morphologies initiated on the shelf with the erosion of Prydz Channel and other troughs by fast-moving ice and the deposition of overcompacted glacial diamictons by slow-moving ice on adjacent banks. The Prydz trough-mouth fan also began to form with alternating deposition of debris flows (ice at shelf edge) and muddy units (reduced ice) (Site 1167). The fan also records a transition during the late Pleistocene for times younger than 780 k.y. when short-term glacial variations continued but ice reached the shelf edge only a few times. Both short-term and long-term transitions characterize the Cenozoic evolution of the Prydz Bay region from the Cretaceous nonglacial to late Neogene full-glacial paleoenvironments. These transitions are known only from ODP cores, and further insights will require additional drilling.

Prydz Bay region↗

USGS1990

Consolidation, triaxial shear-strength, and index-property characteristics of organic-rich sediment from the Peru continental margin: Results from Leg 112

Sites 679, 680, and 681 of the Ocean Drilling Program were drilled along an east-west transect across an organic-rich, diatomaceous, coastal upwelling facies that occurs as a shelf/slope lens along the Peru continental margin. Seven 60-cm-long, unsplit core sections from these sites were tested for consolidation, triaxial shear strength, and geotechnical index properties. The testing showed that the sediment has unusually high water content, Atterberg limits, degree of overconsolidation, compressibility, and shear strength. The sediment has unusually low density and grain specific gravity. Atterberg limits, grain specific gravity, compressibility, and apparent excess maximum past stress increase linearly with organic-carbon content, which also correlates positively with diatom content. Overconsolidation measured in these tests is probably not a result of sediment erosion or slumping, but rather the result of diagenesis or interparticle bonding by organic matter. High shear strengths were measured throughout, but particularly high relative shear strengths (as indicated by friction angles and degrees of dilatancy during shear) occur near 20 mbsf. This "crustlike" behavior is probably produced by early diagenesis (perhaps including dolotomization) within the upper 20 m, and is complemented by interlocking of diatoms.

Proceedings of the Ocean Drilling Program: Scienti↗