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At least 847 records · Page 47Linked to original sources
USGS2015

Detailed interpretation of aeromagnetic data from the Patagonia Mountains area, southeastern Arizona

The induced magnetic field and the remanent magnetic field of rock masses are important to geologic modeling based on Earth’s magnetic field data. The orientation of the induced magnetic field is approximately parallel to the orientation of Earth’s geomagnetic field and its intensity can be derived from measured magnetic susceptibilities of rocks in a study area. The orientation and intensity of the natural remanent magnetic field is much harder to determine; therefore, few investigators have included magnetic remanence as a contributing factor to studies of continental magnetic anomalies. All rocks have remanent magnetism and, in intrusive or volcanic rocks, this component of the total magnetic intensity of the Earth’s magnetic field can be as large as or larger than the induced component. The Patagonia Mountains in southeastern Arizona were selected to produce a subsurface geologic model from aeromagnetic data by incorporating physical properties of rock including measured magnetic susceptibilities, estimated remanent magnetic field orientations and intensities, a known association of intrusive events, and information from existing geologic mapping. The result is a model of geology at depth that may better represent reality than previous poorly substantiated cross sectional models. This new model includes concealed intrusive rocks and defines areas where concealed mineral deposits may be found. It also shows that volcanic rocks might occupy basins at relatively shallow depths in basins with low aeromagnetic anomalies. Euler deconvolution depth estimates derived from aeromagnetic data with a structural index of 0 show that mapped faults on the northern margin of the Patagonia Mountains generally agree with the depth estimates in the new geologic model. The deconvolution depth estimates also show that the concealed Patagonia Fault southwest of the Patagonia Mountains is more complex than recent geologic mapping represents. Additionally, Euler deconvolution depth estimates with a structural index of 2 locate many potential intrusive bodies that might be associated with known and unknown mineralization.

Arizona↗
USGS2008

Geochemical data for samples collected in 2007 near the concealed pebble porphyry Cu-Au-Mo deposit, southwest Alaska

In the summer of 2007, the U.S. Geological Survey (USGS) began an exploration geochemical research study over the Pebble porphyry copper-gold-molydenum (Cu-Au-Mo) deposit in southwest Alaska. The Pebble deposit is extremely large and is almost entirely concealed by tundra, glacial deposits, and post-Cretaceous volcanic and volcaniclastic rocks. The deposit is presently being explored by Northern Dynasty Minerals, Ltd., and Anglo-American LLC. The USGS undertakes unbiased, broad-scale mineral resource assessments of government lands to provide Congress and citizens with information on national mineral endowment. Research on known deposits is also done to refine and better constrain methods and deposit models for the mineral resource assessments. The Pebble deposit was chosen for this study because it is concealed by surficial cover rocks, it is relatively undisturbed (except for exploration company drill holes), it is a large mineral system, and it is fairly well constrained at depth by the drill hole geology and geochemistry. The goals of the USGS study are (1) to determine whether the concealed deposit can be detected with surface samples, (2) to better understand the processes of metal migration from the deposit to the surface, and (3) to test and develop methods for assessing mineral resources in similar concealed terrains. This report presents analytical results for geochemical samples collected in 2007 from the Pebble deposit and surrounding environs. The analytical data are presented digitally both as an integrated Microsoft 2003 Access? database and as Microsoft 2003 Excel? files. The Pebble deposit is located in southwestern Alaska on state lands about 30 km (18 mi) northwest of the village of Illiamna and 320 km (200 mi) southwest of Anchorage (fig. 1). Elevations in the Pebble area range from 287 m (940 ft) at Frying Pan Lake just south of the deposit to 1146 m (3760 ft) on Kaskanak Mountain about 5 km (5 mi) to the west. The deposit is in an area of relatively subdued topographic relief with an elevation of around 300 m (1000 ft). This portion of Alaska is part of the subarctic regime mountains division, Yukon intermontane plateaus-tayga-meadow province ecoregion, as defined by Bailey (U.S. Forest Service, 2007). Between June 28th and July 12th, 2007, scientists from the USGS collected soil, water, stream sediment, vegetation, heavy-mineral concentrate, till, and rock samples from the deposit area. This report contains analytical results for soil, water, stream sediment, and vegetation samples. Analyses for the heavy-mineral concentrate, till, and rock samples are still in progress. The sampling was undertaken during relatively dry and stable weather conditions. Only minor scattered rain showers occurred during the sampling period, so surface conditions were largely unaffected by weather. The predominant sample media collected were soils and surface waters. Soil and water (mostly from ponds and springs, some from small creeks) samples were collected along a single 7.8 km-long (4.8 mi) east-west traverse across the Pebble East and Pebble West zones and from more distal background areas around Koktuli and Kaskanak Mountains. Sample sites are shown on figure 2 and plate 1, and locality coordinates are provided in the accompanying Access and Excel files named FieldSite. Water samples were analyzed by USGS laboratories with one subset analyzed by Activation Laboratories (Actlabs), as indicated below. Soils and stream sediments were analyzed for their total content by SGS Minerals Services under a contract with the USGS. Soil samples were also leached by selected partial-extraction leaching procedures and then analyzed by several commercial laboratories, as described below. Vegetation samples were analyzed as indicated below.

Alaska↗
USGS2001

Preliminary lithogeochemical map showing near-surface rock types in the Chesapeake Bay watershed, Virginia and Maryland

This preliminary experimental lithogeochemical map shows the distribution of rock types in the Virginia and Maryland parts of the Chesapeake Bay watershed. The map was produced digitally by classifying geologic-map units according to composition, mineralogy, and texture; rather than by age and stratigraphic relationships as shown on traditional geologic maps. This map differs from most lithologic maps in that the lithogeochemical unit classification distinguishes those rock units having key water-reactive minerals that may induce acid neutralization, or reduction, of hosted water at the weathering interface. The validity of these rock units, however, is independent of water chemistry, because the rock units are derived from geologic maps and rock descriptions. Areas of high soil carbon content, and sulfide metal deposits are also shown. Water-reactive minerals and their weathering reactions yield five lithogeochemical unit classes: 1) carbonate rock and calcareous rocks and sediments, the most acid-neutralizing; 2)carbonaceous-sulfidic rocks and sediments, oxygen-depleting and reducing; 3) quartzofeldspathic rocks and siliciclastic sediments, relatively weakly reactive with water; 4) mafic silicate rocks/sediments, oxygen consuming and high solute-load delivering; and, 5) the rarer calcareous-sulfidic (carbonaceous) rocks, neutralizing and reducing. Earlier studies in some parts of the map area have related solute loads in ground and stream waters to some aspects of bedrock lithology. More recent preliminary tests of relationships between four of the classes of mapped lithogeochemical units and ground water chemistry, in the Mid-Atlantic area using this map, have focused on and verified the nitrate-reducing and acid-neutralizing properties of some bedrock and unconsolidated aquifer rock types. Sulfide mineral deposits and their mine-tailings effects on waters are beginning to be studied by others. Additional testing of relationships among the lithogeochemical units and aspects of ground and surface water chemistry could help to refine the lithogeochemical classification, and this map. The testing could also improve the usefulness of the map for assessing aquifer reactivity and the transport properties of reactive contaminants such as acid rain, and nitrate from agricultural sources, in the Chesapeake Bay watershed.

Maryland, Virginia↗
USGS1997

Sedimentary carbonate-hosted giant Bayan Obo REE-Fe-Nb ore deposit of Inner Mongolia, China; a cornerstone example for giant polymetallic ore deposits of hydrothermal origin

Detailed, integrative field and laboratory studies of the textures, structures, chemical characteristics, and isotopically determined ages and signatures of mineralization of the Bayan Obo deposit provided evidence for the origin and characteristics favorable for its formation and parameters necessary for defining giant polymetallic deposits of hydrothermal origin. Bayan Obo is an epigenetic, metasomatic, hydrothermal rare earth element (REE)-Fe-Nb ore deposit that is hosted in the metasedimentary H8 dolostone marble of the Middle Proterozoic Bayan Obo Group. The metasedimentary sequence was deposited on the northern continental slope of the North China craton. The mine area is about 100 km south of the suture marking Caledonian subduction of the Mongolian oceanic plate from the north beneath the North China craton. The mineralogy of the deposit is very complex, consisting of more than 120 different minerals, some of which are epigenetic minerals introduced by hydrothermal solutions, and some of which are primary and secondary metamorphic minerals. The major REE minerals are monazite and bastnaesite, whereas magnetite and hematite are the dominant Fe-ore minerals, and columbite is the most abundant Nb mineral. Dolomite, alkali amphibole, fluorite, barite, aegirine augite, apatite, phlogopite, albite, and microcline are the most widespread gangue minerals. Three general types of ores occur at Bayan Obo: disseminated, banded, and massive ores. Broad zoning of these ore types occurs in the Main and East Orebodies. Disseminated ores are in the outermost zone, banded ores are in the intermediate zone, and massive ores are in the cores of the orebodies. On the basis of field relations, host rocks, textures, structures, and mineral assemblages, many varieties of these three types of ores have been recognized and mapped. Isotopic dating of monazite, bastnaesite, aeschynite, and metamorphic and metasomatic alkali amphiboles associated with the deposit provides constraints on the ages of mineralization and the history of the deposit. Textural relations, differences in chemical composition, and 232Th/208Pb internal isochron ages of monazite and bastnaesite samples indicate that many episodes of REE mineralization occurred at Bayan Obo, ranging from about 555 Ma to about 398 Ma. Initial 208Pb/204Pb ratios suggest different sources of REE's for different generations of REE minerals. Relative ages of Fe mineralization were deduced from textural relationships of Fe minerals with other, dated mineral phases in the deposit. Most Nb mineralization was in the area of the West Orebodies and resulted in disseminated ore. Aeschynite, an early stage of Nb mineralization (438+-25.1 Ma), occurs with huanghoite and alkali amphiboles in veins. The 40Ar/39Ar ages of amphiboles, as well as petrographic textures, were used to distinguish three periods of regional metamorphism in the Bayan Obo mine area: (1) Late Proterozoic, about 890 Ma, which recrystallized H8 carbonate to marble and crystallized lineated alkali amphiboles along foliation planes in the marble; (2) Caledonian, about 425-395 Ma, which resulted in metamorphic and metasomatic-metamorphic alkali amphiboles; and (3) Hercynian, about 300 Ma, based on biotite 40Ar/39Ar analyses from biotite schist and folded banded ores. The 40Ar/39Ar ages of metasomatic alkali amphiboles also place time constraints on the hydrothermal history of the ore deposit. Metasomatic amphiboles represent periods of intense hydrothermal activity, which began as early as 1.26 Ga; that date is based on the age of amphibole from a vein that crosscuts the H6 quartzite that underlies the H8 dolostone marble. Although much of the metasomatic amphibole formed during periods that overlapped the peak period of REE mineralization of banded ores, REE and alkali amphibole phases generally occur in different mineral assemblages or are of very different ages in the same assemblage and, therefore, may have been derived from

Bulletin↗
USGS2005

Missouri magnetic and gravity maps and data: A web site for distribution of data

Magnetic anomalies are due to variations in the Earth's magnetic field caused by the uneven distribution of magnetic minerals (primarily magnetite) in the rocks that make up the upper part of the Earth's crust. The features and patterns of the magnetic anomalies can be used to delineate details of subsurface geology, including the locations of buried faults and magnetite-bearing rocks and the depth to the base of sedimentary basins. This information is valuable for mineral exploration, geologic mapping, and environmental studies. The Missouri magnetic map is constructed from grids that combine information collected in 25 separate magnetic surveys conducted between 1943 and 1987. The data from these surveys are of varying quality. The design and specifications (terrain clearance, sampling rates, line spacing, and reduction procedures) varied from survey to survey depending on the purpose of the project and the technology of that time. Every attempt was made to acquire the data in digital form.

Missouri↗
USGS2005

Iowa magnetic and gravity maps and data: A web site for distribution of data

Magnetic anomalies are due to variations in the Earth's magnetic field caused by the uneven distribution of magnetic minerals (primarily magnetite) in the rocks that make up the upper part of the Earth's crust. The features and patterns of the magnetic anomalies can be used to delineate details of subsurface geology, including the locations of buried faults and magnetite-bearing rocks and the depth to the base of sedimentary basins. This information is valuable for mineral exploration, geologic mapping, and environmental studies. The Iowa magnetic map is constructed from grids that combine information collected in nine separate magnetic surveys conducted between 1953 and 1972. The data from these surveys are of varying quality. The design and specifications (terrain clearance, sampling rates, line spacing, and reduction procedures) varied from survey to survey depending on the purpose of the project and the technology of that time. Every attempt was made to acquire the data in digital form. All survey grids have been continued to 305 m (1,000 ft) above ground and merged together to form the State compilation.

Iowa↗
USGS2015

Mineral potential for nickel, copper, platinum group elements(PGE), and chromium deposits hosted in ultramafic rocks in the Islamic Republic of Mauritania (phase V, deliverable 67)

PRISM-I summary documents mention the presence of mafic-ultramafic igneous intrusive rocks in several areas of Mauritania and a number of chromium (Cr) and copper-nickel (Cu-Ni (±Co, Au)) occurrences associated with them. Permissive geologic settings generally include greenstone belts of any age, layered mafic-ultramafic and unlayered gabbro-anorthosite intrusive complexes in cratonic settings, ophiolite complexes, flood basalt provinces, and fluid-rich shear zones cutting accumulations of mafic-ultramafic rocks. Regions of Mauritania having these characteristics that are discussed in PRISM-I texts include the Mesoarchean greenstone belts of the TasiastTijirit terrane in the southwestern Rgueïbat Shield, two separate layered ultramafic complexes in the Amsaga Complex west of Atar, serpentinized metadunites in Mesoarchean rocks of the Rgueïbat Shield in the Zednes map sheet, several lateritized annular mafic-ultramafic complexes in the Paleoproterozoic northwestern portion of the Rgueïbat Shield, and the serpentinized ophiolitic segments of the Gorgol Noir Complex in the axial portion of the southern Mauritanides. Bureau de Recherches Géologiques et Minières (BRGM) work in the “Extreme Sud” zone also suggests that small copper occurrences associated with the extensive Jurassic microgabbroic intrusive rocks in the Taoudeni Basin of southeastern Mauritania could have potential for magmatic Cu-Ni (PGE, Co, Au) sulfide mineralization. Similarly, Jurassic mafic intrusive rocks in the northeastern Taoudeni Basin may be permissive. Known magmatic Cu-Ni deposits of these types in Mauritania are few in number and some uncertainty exists as to the nature of several of the more important ones.

Open-File Report↗
USGS2021

Groundwater flow conceptualization of the Pahute Mesa–Oasis Valley Groundwater Basin, Nevada—A synthesis of geologic, hydrologic, hydraulic-property, and tritium data

This report provides a groundwater-flow conceptualization that integrates geologic, hydrologic, hydraulic-property, and radionuclide data in the Pahute Mesa–Oasis Valley (PMOV) groundwater basin, southern Nevada. Groundwater flow in the PMOV basin is of interest because 82 underground nuclear tests were detonated, most near or below the water table. A potentiometric map and nine sets of hydrostratigraphic and hydrologic cross sections supplement the conceptualization. Potentiometric contours indicate that groundwater in the PMOV basin generally flows south-southwest and discharges at Oasis Valley. Groundwater encounters an alternating sequence of low- and high-transmissivity rocks, referred to as dams and pools, respectively, as it moves from east to west across eastern Pahute Mesa. Flow from all Pahute Mesa nuclear tests is to Oasis Valley and is well-constrained by water-level data. Flow converges along a corridor of high transmissivity between Pahute Mesa and Oasis Valley. The location of the lateral PMOV basin boundary is well defined, and this boundary, with a few minor exceptions, represents a no-flow boundary. Some boundary uncertainty exists in the northeastern part of the basin, but potential flow-rate estimates across the northeastern boundary resulting from this uncertainty are small relative to the basin groundwater budget. Recharge in the PMOV basin is derived from episodic pulses of modern water and the diffuse percolation of old water (greater than 1,000 years). Episodic recharge is a minor recharge component observed as a rise in groundwater levels that occurs 3 months to 1 year following a wet winter. Minor amounts of episodic recharge through an unsaturated zone in excess of 1,000 feet (ft) requires preferential flow through faults and fractures. The dominant recharge component is slow, steady, diffuse percolation of old water through the unsaturated zone. A large component of old water recharging the groundwater system is consistent with observations of isotopically light deuterium and oxygen 18 compositions in water from wells on Pahute Mesa and central Oasis Valley. About half the recharge in the PMOV basin is derived from the eastern Pahute Mesa area. The remaining recharge is derived primarily from other highland areas including Timber Mountain, Belted and Kawich Ranges, and Black Mountain. The PMOV groundwater system is nearly steady state, where recharge is balanced by the 5,900 acre-feet per year of natural discharge at Oasis Valley. This assumption is reasonable because the basin is dominated by steady-state conditions, where long-term changes in groundwater storage are minimal. Total groundwater withdrawals from 1963 to 2018 have amounted to less than 10 percent of annual groundwater discharge and less than 0.2 percent of the basin’s groundwater storage. Therefore, present-day (2020) conditions are considered representative of predevelopment (pre-1950) conditions in nearly all areas of the basin. The lower PMOV basin boundary is defined at 4,000 ft below the water table to encompass all underground nuclear tests and tritium plumes. This boundary defines the lower boundary of radionuclide migration. However, nearly all flow and tritium transport occur in the upper 1,600 ft of the saturated zone because a transmissivity-with-depth relation indicates that greater than 90 percent of the transmissivity contributing to groundwater flow occurs within 1,600 ft of the water table. Rocks at deeper depths have low transmissivity because argillic and mineralized alterations plug the fractures. Volcanic rocks form the primary aquifers and confining units in the PMOV basin. Volcanic hydrogeologic units (HGUs) and hydrostratigraphic units (HSUs) have transmissivity distributions that span up to eight orders of magnitude with considerable overlap between distributions. Despite the large overlap between units, mean transmissivities of aquifers are one-to-two orders of magnitude greater than the confining units. However, all volcanic-rock HGUs and HSUs are composite units, meaning that they can function spatially as either an aquifer or confining unit .

Nevada↗
USGS2016

Geochemistry, Nd-Pb Isotopes, and Pb-Pb Ages of the Mesoproterozoic Pea Ridge Iron Oxide-Apatite–Rare Earth Element Deposit, Southeast Missouri

Iron oxide-apatite and iron oxide-copper-gold deposits occur within ~1.48 to 1.47 Ga volcanic rocks of the St. Francois Mountains terrane near a regional boundary separating crustal blocks having contrasting depleted-mantle Sm-Nd model ages (T DM ). Major and trace element analyses and Nd and Pb isotope data were obtained to characterize the Pea Ridge deposit, improve identification of exploration targets, and better understand the regional distribution of mineralization with respect to crustal blocks. The Pea Ridge deposit is spatially associated with felsic volcanic rocks and plutons. Mafic to intermediate-composition rocks are volumetrically minor. Data for major element variations are commonly scattered and strongly suggest element mobility. Ratios of relatively immobile elements indicate that the felsic rocks are evolved subalkaline dacite and rhyolite; the mafic rocks are basalt to basaltic andesite. Granites and rhyolites display geochemical features typical of rocks produced by subduction. Rare earth element (REE) variations for the rhyolites are diagnostic of rocks affected by hydrothermal alteration and associated REE mineralization. The magnetite-rich rocks and REE-rich breccias show similar REE and mantle-normalized trace element patterns. Nd isotope compositions (age corrected) show that: (1) host rhyolites have ɛ Nd from 3.44 to 4.25 and T DM from 1.51 to 1.59 Ga; (2) magnetite ore and specular hematite rocks display ɛ Nd from 3.04 to 4.21 and T DM from 1.6 to 1.51 Ga, and ɛ Nd from 2.23 to 2.81, respectively; (3) REE-rich breccias have ɛ Nd from 3.04 to 4.11 and T DM from 1.6 to 1.51 Ga; and (4) mafic to intermediate-composition rocks range in ɛ Nd from 2.35 to 3.66 and in T DM from 1.66 to 1.56. The ɛ Nd values of the magnetite and specular hematite samples show that the REE mineralization is magmatic; no evidence exists for major overprinting by younger, crustal meteoric fluids, or by externally derived Nd. Host rocks, breccias, and magnetite ore shared a common origin from a similar source. Lead isotope ratios are diverse: (1) host rhyolite has 206 Pb/ 204 Pb from 24.261 to 50.091; (2) Pea Ridge and regional galenas have 206 Pb/ 204 Pb from 16.030 to 33.548; (3) REE-rich breccia, magnetite ore, and specular hematite rock are more radiogenic than galena; (4) REE-rich breccias have high 206 Pb/ 204 Pb (38.122–1277.61) compared to host rhyolites; and (5) REE-rich breccias are more radiogenic than magnetite ore and specular-hematite rock, having 206 Pb/ 204 Pb up to 230.65. Radiogenic 207 Pb/ 206 Pb age estimates suggest the following: (1) rhyolitic host rocks have ages of ~1.50 Ga, (2) magnetite ore is ~1.44 Ga, and (3) REE-rich breccias are ~1.48 Ga. These estimates are broadly consistent and genetically link the host rhyolite, REE-rich breccia, and magnetite ore as being contemporaneous. Alteration style and mineralogical or textural distinctions among the magnetite-rich rocks and REE-rich breccias do not correlate with different isotopic sources. In our model, magmatic fluids leached metals from the coeval felsic rocks (rhyolites), which provided the metal source reflected in the compositions of the REE-rich breccias and mineralized rocks. This model allows for the likelihood of contributions from other genetically related felsic and intermediate to more mafic rocks stored deeper in the crust. The deposit thus records an origin as a magmatic-hydrothermal system that was not affected by Nd and Pb remobilization processes, particularly if these processes also triggered mixing with externally sourced metal-bearing fluids. The Pea Ridge deposit was part of a single, widespread, homogeneous mixing system that produced a uniform isotopic composition, thus representing an excellent example of an igneous-dominated system that generated coeval magmatism and REE mineralization. Geochemical features suggest that components in the Pea Ridge deposit originated from sources in an orogenic margin. Basaltic magmatism produced by mantle decompression melting provided heat for extracting melts from the middle or lower crust. Continual addition of mafic magmas to the base of the subcontinental lithosphere, in a back-arc setting, remelted calc-alkaline rocks enriched in metals that were stored in the crust. The St. Francois Mountains terrane is adjacent to the regional T DM line (defined at a value of 1.55 Ga) that separates ~1600 Ma basement to the west, from younger basements to the east. Data for Pea Ridge straddle the T DM values proposed for the line. The Sm-Nd isotope system has been closed since formation of the deposit and the original igneous signatures have not been affected by cycles of alteration or superimposed mineralizing events. No evidence exists for externally derived Nd or Sm. The source region for metals within the Pea Ridge deposit had a moderate compositional variation and the REE-rich breccias and mineralized rocks are generally isotopically homogeneous. The Pea Ridge deposit thus constitutes a distinctive isotopic target for use as a model in identifying other mineralized systems that may share the same metal source in the St. Francois Mountains terrane and elsewhere in the eastern Granite-Rhyolite province.

Missouri↗
USGS1973

Aspects of the magmatic geochemistry of bismuth

Bismuth has been determined in 74 rocks from a differentiated tholeiitic dolerite, two calc-alkaline batholith suites and in 66 mineral separates from one of the batholiths. Average bismuth contents, weighted for rock type, of the Great Lake (Tasmania) dolerite, the Southern California batholith and the Idaho batholith are, 32, 50 and 70 ppb respectively. All three bodies demonstrate an enrichment of bismuth in residual magmas with magmatic differentiation. Bismuth is greatly enriched (relative to the host rock) in the calcium-rich accessory minerals, apatite and sphene, but other mineral analyses show that a Bi-Ca association is of little significance to the magmatic geochemistry of bismuth. Most of the bismuth, in the Southern California batholith at least, occurs in a trace mineral phase (possibly sulfides) present as inclusions in the rock-forming minerals.

Geochimica et Cosmochimica Acta↗
USGS2003

P-T-t paths and differential Alleghanian loading and uplift of the Bronson Hill terrane south central New England

Late Paleozoic U-Pb ages of sphene and 40 Ar/ 39 Ar cooling ages of amphibole and muscovite from rocks of the Bronson Hill terrane in Connecticut and central Massachusetts reflect a late Paleozoic (Alleghanian) overprint on Acadian metamorphic rocks. Prograde Alleghanian sphenes crystallized during the Late Pennsylvanian, and eliminate the possibility that amphibole ages reflect delayed Permian cooling from Devonian Acadian metamorphism. Fourteen new amphibole ages from Connecticut form a north-to-south trend of decreasing age from 294 to 245 Ma, while in Massachusetts four new amphibole ages together with three others from the literature produce a random Carboniferous pattern. Seven new muscovite ages support existing data indicating uniform cooling throughout the Bronson Hill terrane through ∼350°C in the Early Triassic. The rate of Permian cooling defined by amphibole-muscovite pairs increases from ∼4°C/my in northern Connecticut to ∼50°C/my near Long Island Sound. Hinged loading and hinged but delayed exhumation in the southern part of the Bronson Hill terrane (with the hinge in central Connecticut) explain these ages and cooling rates as well as a southerly increasing metamorphic field gradient. One-dimensional thermal modeling indicates that loading of Bronson Hill rocks must have begun by the Late Mississippian. The time of peak Alleghanian metamorphic temperature decreases southward from Early Permian in northern Connecticut to Late Permian to the south. These results demonstrate that the metamorphic effects of the Alleghanian orogeny are not restricted to the Avalon terrane of southeastern New England. On the contrary, the Alleghanian orogeny reset 40 Ar/ 39 Ar mineral ages, recrystallized minerals, partially melted felsic rocks, and transposed fabrics at least as far west as the Bronson Hill terrane in south-central New England.

American Journal of Science↗
USGS2003

A special issue devoted to gold deposits in northern Nevada: Part 2. Carlin-type Deposits

This is the second of two special issues of Economic Geology devoted to gold deposits in northern Nevada. Readers interested in a general overview of these deposits, their economic significance, their context within the tectonic evolution of the region, and synoptic references on each gold deposit type are directed to the preface of the first special issue (John et al., 2003). Volume 98, issue 2, contains five papers that address regional aspects important to the genesis of gold deposits in northern Nevada and five papers that present detailed studies of epithermal deposits and districts. All of the regional papers are pertinent to Carlin-type gold deposits, because they address the age of mineralization (Arehart et al., 2003), origin and evolutionary history of the northwest-striking mineral belts that localize many deposits (Grauch et al., 2003), nature of the middle and lower crust below these mineral belts (Howard, 2003), district- to deposit-scale stream sediment and lithogeochemical anomalies (Theodore et al., 2003), and stratigraphy and structure of a district located along a northeast-striking lineament (Peters et al., 2003). The nine papers in this second special issue focus on an array of problems pertinent to genetic and exploration models for Carlin-type deposits in northern Nevada (Fig. 1). These investigations sort out and characterize the sequence of deformational, igneous, and hydrothermal events in mining districts, constrain the age of mineralization, map paleothermal gradients, identify structures and lithologies that are preferentially mineralized, ascertain processes of ore formation, determine sources of ore fluid components, and define fluid flow paths. A common theme among these papers is inheritance, whereby older features in the mineral belts influence ore formation in subsequent Carlin-type hydrothermal systems. Three types of inheritance are inferred by one or more of these investigations: (1) structural inheritance, where older faults are reactivated during subsequent contractional and/or extensional tectonic events producing permeable fracture systems that focused flow of ore fluids; (2) alteration inheritance, where one or more preore alteration events produced reactive host rocks that are preferentially mineralized; and (3) geochemical inheritance, in which Au and other elements are recycled from older mineralization into younger Carlin-type deposits. Despite the similar age, tectonic setting, alteration types, mineral parageneses, and geochemical signatures of the deposits studied, these papers do not lead to consensus regarding genetic models for Carlin-type deposits. Rather, the separate investigations by different workers, utilizing both similar and unlike approaches, result in markedly different conclusions. Some of this disparity probably is due to real differences in the origin of different districts; however, the opposing conclusions arrived at by investigations on neighboring deposits in a single district are more problematic and most likely are due to difficulties resulting from the superposition of different types and ages of gold mineralization or to substantial variations in the hydrology and proportions of fluid components derived from deep and shallow sources in each deposit. Further work is needed to validate and understand the significance of these differences.

Nevada↗
USGS2022

Indicator mineral analyses of stream-sediment samples using automated mineralogy and mineral chemistry: Applicability to exploration in covered terranes in eastern Alaska, USA

In the past two decades, significant research efforts have been devoted to porphyry copper indicator mineral (PCIM) identification and mineral chemistry to assist exploration. Such studies are important in the Yukon-Tanana upland region of eastern Alaska because well-established geochemical exploration techniques, such as the geochemistry of stream-sediment samples, are less effective in the search for mineral resources owing to cover materials that subdue geochemical signatures. The unglaciated Yukon-Tanana upland region is well-endowed with mineral resources, including porphyry Cu-Mo-Au deposits at Taurus, Bluff, Dennison, and Oreo. Using automated scanning electron microscope (SEM) techniques, numerous PCIMs have been identified in rocks and stream-sediment samples that would likely not have been observed using visual binocular microscope methods. Sulfide minerals such as chalcopyrite, chalcocite, covellite, bornite, molybdenite, and pyrrhotite were identified in rock samples, and more than half of the stream-sediment samples from drainages containing known porphyry mineral occurrences contain chalcopyrite with or without bornite. Many drainages without known occurrences also contain these minerals, which suggests potential for additional occurrences. Svanbergite, an aluminum phosphate sulfate (APS) mineral [SrAl 3 (PO 4 )(SO 4 )(OH) 6 ], was identified in some of the altered or mineralized rock samples from Taurus, and in stream drainages containing porphyry occurrences and may represent the best indicator mineral for Taurus-like porphyry deposits. Apatite chemistry has great potential as a tool for assessing the presence of porphyry mineralization. Grains from rock and stream-sediment samples that contain high Cl (>∼0.4 wt%), Fe (>0.4 wt%), and Mn (>2000 ppm) clearly distinguish apatite from other sources (metamorphic, unmineralized igneous rocks). This study is one of the first to document new streamlined indicator mineral sample collection and processing methods and to combine automated SEM techniques and chemistry of minerals derived from both bedrock and surficial (stream) sediments as they apply to porphyry exploration.

Alaska↗
USGS2009

Stable isotope and petrologic evidence for open-system degassing during the climactic and pre-climactic eruptions of Mt. Mazama, Crater Lake, Oregon

Evaluation of the extent of volatile element recycling in convergent margin volcanism requires delineating likely source(s) of magmatic volatiles through stable isotopic characterization of sulfur, hydrogen and oxygen in erupted tephra with appropriate assessment of modification by degassing. The climactic eruption of Mt. Mazama ejected approximately 50 km 3 of rhyodacitic magma into the atmosphere and resulted in formation of a 10-km diameter caldera now occupied by Crater Lake, Oregon (lat. 43°N, long. 122°W). Isotopic compositions of whole-rocks, matrix glasses and minerals from Mt. Mazama climactic, pre-climactic and postcaldera tephra were determined to identify the likely source(s) of H 2 O and S. Integration of stable isotopic data with petrologic data from melt inclusions has allowed for estimation of pre-eruptive dissolved volatile concentrations and placed constraints on the extent, conditions and style of degassing. Sulfur isotope analyses of climactic rhyodacitic whole rocks yield δ 34 S values of 2.8–14.8‰ with corresponding matrix glass values of 2.4–13.2‰. δ 34 S tends to increase with stratigraphic height through climactic eruptive units, consistent with open-system degassing. Dissolved sulfur concentrations in melt inclusions (MIs) from pre-climactic and climactic rhyodacitic pumices varies from 80 to 330 ppm, with highest concentrations in inclusions with 4.8–5.2 wt% H 2 O (by FTIR). Up to 50% of the initial S may have been lost through pre-eruptive degassing at depths of 4–5 km. Ion microprobe analyses of pyrrhotite in climactic rhyodacitic tephra and andesitic scoria indicate a range in δ 34 S from −0.4‰ to 5.8‰ and from −0.1‰ to 3.5‰, respectively. Initial δ 34 S values of rhyodacitic and andesitic magmas were likely near the mantle value of 0‰. Hydrogen isotope (δD) and total H 2 O analyses of rhyodacitic obsidian (and vitrophyre) from the climactic fall deposit yielded values οf −103 to −53‰ and 0.23–1.74 wt%, respectively. Values of δD and wt% H 2 O of obsidian decrease towards the top of the fall deposit. Samples with depleted δD, and mantle δ 18 O values, have elevated δ 34 S values consistent with open-system degassing. These results imply that more mantle-derived sulfur is degassed to the Earth’s atmosphere/hydrosphere through convergent margin volcanism than previously attributed. Magmatic degassing can modify initial isotopic compositions of sulfur by >14‰ (to δ 34 S values of 14‰ or more here) and hydrogen isotopic compositions by 90‰ (to δD values of −127‰ in this case).

Oregon↗
USGS2016

Paleozoic magmatism and porphyry Cu-mineralization in an evolving tectonic setting in the North Qilian Orogenic Belt, NW China

The NWW-striking North Qilian Orogenic Belt records the Paleozoic accretion–collision processes in NW China, and hosts Paleozoic Cu–Pb–Zn mineralization that was temporally and spatially related to the closure of the Paleo Qilian-Qinling Ocean. The Wangdian Cu deposit is located in the eastern part of the North Qilian Orogenic Belt, NW China. Copper mineralization is spatially associated with an altered early Paleozoic porphyritic granodiorite, which intruded tonalites and volcaniclastic rocks. Alteration zones surrounding the mineralization progress outward from a potassic to a feldspar-destructive phyllic assemblage. Mineralization consists mainly of quartz-sulfide stockworks and disseminated sulfides, with ore minerals chalcopyrite, pyrite, molybdenite, and minor galena and sphalerite. Gangue minerals include quartz, orthoclase, biotite, sericite, and K-feldspar. Zircon LA-ICPMS U–Pb dating of the ore-bearing porphyritic granodiorite yielded a mean 206 Pb/ 238 U age of 444.6 ± 7.8 Ma, with a group of inherited zircons yielding a mean U–Pb age of 485 ± 12 Ma, consistent with the emplacement age (485.3 ± 6.2 Ma) of the barren precursor tonalite. Rhenium and osmium analyses of molybdenite grains returned model ages of 442.9 ± 6.8 Ma and 443.3 ± 6.2 Ma, indicating mineralization was coeval with the emplacement of the host porphyritic granodiorite. Rhenium concentrations in molybdenite (208.9–213.2 ppm) suggest a mantle Re source. The tonalities are medium-K calc-alkaline. They are characterized by enrichment of light rare-earth elements (LREEs) and large-ion lithophile elements (LILEs), depletion of heavy rare-earth elements (HREEs) and high-field-strength elements (HFSEs), and minor negative Eu anomalies. They have ε Hf ( t ) values in the range of +3.6 to +11.1, with two-stage Hf model ages of 0.67–1.13 Ga, suggesting that the ca. 485 Ma barren tonalites were products of arc magmatism incorporating melts from the mantle wedge and the lithosphere. In contrast, the 40-m.y.-younger ore-bearing porphyritic granodiorite is sub-alkaline and peraluminous. They are enriched in LREEs and LILEs, depleted in HFSEs, and show weak negative Eu anomalies. They display ε Hf ( t ) values of captured or inherited zircons in the range of +8.5 to +10.0, and younger two-stage Hf model ages of 0.78 Ga and 0.86 Ga, similar to those of ca. 485 Ma tonalite. The ca. 445 Ma zircons have ε Hf ( t ) values of −2.1 to +9.9, with two-stage Hf model ages of 0.75–1.27 Ga. Moreover, they have relatively high oxygen fugacity than that of the precursor barren tonalite. The ca. 445 Ma magmas at Wangdian thus formed in a subduction setting, and incorporated melts from the subduction-modified lithosphere that had previously been enriched by additions of chalcophile and siderophile element-rich materials by the earlier magmatism and metasomatism during the Paleo Qilian-Qinling Ocean subduction event.

North Qilian Orogenic Belt↗
USGS1969

Distribution of scandium between coexisting biotite and hornblende in igneous rocks

Scandium analyses of more than 90 pairs of coexisting biotite and hornblende from igneous rocks of various provinces (including Southern California, Boulder, Sierra Nevada, Boulder Creek batholiths and the Jemez Mountains volcanic rocks) indicate that the distribution ratio (K d = Sc hornblende /Sc biotite ) for most samples closely approached that of an equilibrium distribution. Median K d values for the igneous samples range from 4.8 to 8.0, which are higher than similar values derived from published data on metamorphic samples and apparently not related to the mode of crystallization (volcanic, hypabyssal, or plutonic). A correlation between Kd and mafic index, (FeO + Fe 2 O 3 )/(FeO + Fe 2 O 3 + MgO) X 100, of both the minerals and the host rock, and between K d and SiO 2 content of the host rock, can be established only for the Southern California batholith samples. However, whether this correlation reflects temperature dependence, compositional dependence, or both, cannot be specified uniquely with present data. The present data also cast doubt on the validity of the so-called “scandium geothermometer.”

GSA Bulletin↗
USGS2013

Porphyry copper assessment of Southeast Asia and Melanesia: Chapter D in Global mineral resource assessment

The U.S. Geological Survey collaborated with member countries of the Coordinating Committee for Geoscience Programmes in East and Southeast Asia (CCOP) on an assessment of the porphyry copper resources of Southeast Asia and Melanesia as part of a global mineral resource assessment. The region hosts world-class porphyry copper deposits and underexplored areas that are likely to contain undiscovered deposits. Examples of known porphyry copper deposits include Batu Hijau and Grasberg in Indonesia; Panguna, Frieda River, and Ok Tedi in Papua New Guinea; and Namosi in Fiji. This assessment covers the countries of Cambodia, Indonesia, Lao People&rsquo;s Democratic Republic, Malaysia, Myanmar, Papua New Guinea, Singapore, Thailand, and parts of southeastern China, India, the Solomon Islands, Vanuatu, and Fiji. Twenty-two geographic areas were delineated as tracts that are permissive for porphyry copper deposits in Southeast Asia. Permissive tracts are grouped into four broadly defined geographic/geologic areas, as follows: (1) the Indochina Peninsula area, (2) Indonesian and Malaysian Islands, (3) New Guinea Island and Papuan New Guinea islands, and (4) Melanesia. Individual tracts range from less than 1,000 to more than 350,000 square kilometers in area. Permissive tracts are based on mapped and inferred subsurface (<1 kilometer depth) distributions of igneous rocks of specific age ranges that define magmatic arcs and magmatic belts that are likely to contain porphyry copper deposits. Most of these magmatic arcs are subduction-related, although some have porphyry-style deposits occurring in postcollisional and (or) poorly understood tectonic settings. Although maps at a variety of different scales were used in the compilation, the final tract boundaries are intended for use at a scale of 1:1,000,000. Global grade and tonnage models for porphyry copper deposits were evaluated. Most of the known deposits are best described as fitting the copper-gold (Cu-Au) subtype of porphyry copper deposit. For some permissive tracts, a general porphyry copper-gold-molybdenum (Cu-Au-Mo) model was used. Assessment participants estimated numbers of undiscovered deposits at different levels of confidence for most of the permissive tracts. These estimates were combined with grade and tonnage models using a Monte Carlo simulation to estimate undiscovered resources. Additional resources in extensions of deposits with identified resources were not evaluated. Assessment results, presented in tables and graphs, show mean amounts of metal and mineralized rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. This assessment estimated a mean of 89 undiscovered porphyry copper deposits for the assessed permissive tracts in Southeast Asia and Melanesia. About 288 million metric tons (Mt) of copper and 18,000 metric tons (t) of gold, as well as byproduct molybdenum and silver, could be associated with undiscovered deposits. This represents about four times the number of deposits with identified resources (23) already discovered in Southeast Asia; reliable reported identified resources for those 23 deposits total 84 Mt of copper and 6,000 t of gold. Eleven permissive tracts have no known porphyry copper deposits with reported resources. Three of those 11 tracts lacked sufficient information for a probabilistic assessment and are discussed in qualitative terms. On a regional basis, both the Indochina Peninsula area and the Indonesian-Malaysian Islands area are estimated to contain about 10 times as much in place copper in undiscovered porphyry copper deposits as has been identified to date. For the New Guinea Island areas, the ratio of undiscovered to identified copper resources is about 2. Some parts of the region have a long history of porphyry exploration cycles and mine development, interrupted at times by political and social unrest, environmental concerns, and natural disasters. Changes in mining laws within the region and the recent high price of gold on the world market have prompted renewed interest in porphyry copper deposits in Southeast Asia and Melanesia. However, predicted undiscovered deposits may not be found, and if found, may not be developed. This assessment includes an overview of the assessment results with summary tables. Detailed descriptions of each tract are included in appendixes, with estimates of numbers of undiscovered deposits, and probabilistic estimates of amounts of copper, molybdenum, gold, and silver that could be contained in undiscovered deposits for each permissive tract. A geographic information system (GIS) that accompanies the report includes tract boundaries and a database of known porphyry copper deposits and significant prospects.

Scientific Investigations Report↗