Reply [to “Comment on ‘Identifying sources of groundwater pollution: An optimization approach’ by Steven M. Gorelick, Barbara Evans, and Irwin Remson”]
No abstract available.
Water Resources Research↗
SEARCH · Search USGS
Results for “Water Resource Research”
Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
On the treatment of evapotranspiration, soil moisture accounting, and aquifer recharge in monthly water balance models
Several two- to six-parameter regional water balance models are examined by using 50-year records of monthly streamflow at 10 sites in New Jersey. These models include variants of the Thornthwaite-Mather model, the Palmer model, and the more recent Thomas abcd model. Prediction errors are relatively similar among the models. However, simulated values of state variables such as soil moisture storage differ substantially among the models, and fitted parameter values for different models sometimes indicated an entirely different type of basin response to precipitation. Some problems in parameter identification are noted, including difficulties in identifying an appropriate time lag factor for the Thornthwaite-Mather-type model for basins with little groundwater storage, very high correlations between upper and lower storages in the Palmer-type model, and large sensitivity of parameter a of the abcd model to bias in estimates of precipitation and potential evapotranspiration. Modifications to the threshold concept of the Thornthwaite-Mather model were statistically valid for the six stations in northern New Jersey. The abcd model resulted in a simulated seasonal cycle of groundwater levels similar to fluctuations observed in nearby wells but with greater persistence. These results suggest that extreme caution should be used in attaching physical significance to model parameters and in using the state variables of the models in indices of drought and basin productivity.
Water Resources Research↗
Reply [to “Comment on ‘The Interaction of Lakes With Variably Saturated Porous Media’ by Thomas C. Winter”]
No abstract available.
Water Resources Research↗
Origin and distribution of carbon dioxide in the unsaturated zone of the southern High Plains of Texas
Partial pressures of CO 2 , O 2 , N 2 , and Ar were monitored at two locations in the Ogallala aquifer system on the Southern High Plains of Texas. Samples were collected monthly during parts of 1980–1981 from nine depths ranging from 0.6 to 36 meters below land surface. P CO 2 was observed to be greater at depth than in the active soil zone and thus appears to contradict the normal process in which CO 2 is generated in the soil zone and diffuses upward to the atmosphere and downward to the water table. The δ 13 C of the CO 2 gas was quite uniform and averaged −17.9 per mil. P O 2 declined with depth, suggesting in situ generation of CO 2 by the oxidation of carbon. Several hypotheses were considered to explain the origin of the CO 2 at depth. It was concluded that the most probable hypothesis was that dissolved and particulate organic carbon introduced by recharging water was oxidized to CO 2 by the aerobic microbial community that utilized oxygen diffusing in from the atmosphere. This hypothesis is consistent with the CO 2 concentration profile, calculated production profile of CO 2 , δ 13 C values of CO 2 gas, caliche, soil humic acid fraction, and dissolved carbonate in groundwater. The abundance of CO 2 , its concentration profile, and its probable origin provide information for evaluating the observed complex sequence of caliche dissolution and precipitation known to occur in the aquifer.
Texas↗
Note on the applicability of the James-Stein Estimator in regional hydrologic studies
The applicability of the James-Stein estimator in regional hydrologic studies which entail the estimation of an N -dimensional location parameter is discussed. Regional studies are frequently characterized by relatively short, generally correlated, samples drawn from nonsymmetric and bounded, i.e., nonnormal, populations. By means of computer simulation studies the James-Stein estimator, subject to the Lindley modification and adoption of the positive part rule suggested by Efron and Morris and conditioned on the assumption of independence, was shown to be robust in the case of the hydrologically plausible distribution considered here, namely, Weibull distributions with coefficient of skewness ranging from 0 to 10. However, in contrast to traditional methods of regionalization the effect of cross correlation is a diminishment of the relative risk advantage of the James-Stein estimator, even in the best case of normal variables : this is discussed and illustrated.
Water Resources Research↗
Interactions of solutes and streambed sediment: 1. An experimental analysis of cation and anion transport in a mountain stream
An experimental injection was performed to study the transport of stream water solutes under conditions of significant interaction with streambed sediments in a mountain pool-and-riffle stream. Experiments were conducted in Little Lost Man Creek, Humboldt County, California, in a period of low flow duringwhich only a part of the bank-full channel held active surface flow. The injection of chloride and several trace cations lasted 20 days. In this report we discuss the results of the first 24 hours of the injection and survey the results of the first 10 days. Solute-streambed interactions of two types were observed. First, the physical transport of the conservative tracer, chloride, was affected by intergravel flow and stagnant watt, zones created by the bed relief. Second, the transport of the cations (strontium, potassium, and lithium) was appreciably modified by sorption onto streambed sediment. In the stream the readily observable consequence of the solute-streambed interactions was an attenuation of the dissolved concentration of each of the tracers. The attenuation in the stream channel occurred concurrently with the storage of tracers in the streambed via both physical and chemical processes. All tracers were subsequently present in shallow wells dug several meters from the wetted part of the channel. Sediment samples collected approximately 3 weeks after the start of the injection contained increased concentrations of the injected cations.
California↗
Interactions of solutes and streambed sediment: 2. A dynamic analysis of coupled hydrologic and chemical processes that determine solute transport
Solute transport in streams is determined by the interaction of physical and chemical processes. Data from an injection experiment for chloride and several cations indicate significant influence of solutestreambed processes on transport in a mountain stream. These data are interpreted in terms of transient storage processes for all tracers and sorption processes for the cations. Process parameter values are estimated with simulations based on coupled quasi-two-dimensional transport and first-order mass transfer sorption. Comparative simulations demonstrate the relative roles of the physical and chemical processes in determining solute transport. During the first 24 hours of the experiment, chloride concentrations were attenuated relative to expected plateau levels. Additional attenuation occurred for the sorbing cation strontium. The simulations account for these storage processes. Parameter values determined by calibration compare favorably with estimates from other studies in mountain streams. Without further calibration, the transport of potassium and lithium is adequately simulated using parameters determined in the chloride-strontium simulation and with measured cation distribution coefficients.
Water Resources Research↗
Water balance models in one-month-ahead streamflow forecasting
T echniques are tested that incorporate information from water balance models in making 1-month-ahead streamflow forecasts in New Jersey. The results are compared to those based on simple autoregressive time series models. The relative performance of the models is dependent on the month of the year in question. The water balance models are most useful for forecasts of April and May flows. For the stations in northern New Jersey, the April and May forecasts were made in order of decreasing reliability using the water-balance-based approaches, using the historical monthly means, and using simple autoregressive models. The water balance models were useful to a lesser extent for forecasts during the fall months. For the rest of the year the improvements in forecasts over those obtained using the simpler autoregressive models were either very small or the simpler models provided better forecasts. When using the water balance models, monthly corrections for bias are found to improve minimum mean-square-error forecasts as well as to improve estimates of the forecast conditional distributions.
Water Resources Research↗
Interannual streamflow variability in the United States based on principal components
Interannual modes of streamflow variation at 106 locations across the United States during the period 1931–1978 are defined by using principal components. Five statistically significant components are found to account for more than 56% of the total streamflow variance. The first principal component represents a nationwide tendency for either above- or below-mean streamflow. The second component represents a north-south opposition in departures from mean flow, and the third, an east-west opposition. Higher-order components (fourth and fifth) geographically depict regional patterns of opposition in the sign of streamflow departures between coastal-continental areas and between the northern and southern plains, respectively. Analyses using spatially and temporally modified data sets indicate that the first three components (which explain 45% of the variance) are quite stable spatially, while only the first component is stable temporally. Time series analysis of principal component scores indicates that all but the fourth component are first-order autoregressive processes, as is mean annual nationwide streamflow. The fourth component is an autoregressive (AR)(2) process. In general, the principal components of streamflow are found to exhibit more persistence over annual time scales than the mean annual flow data themselves.
Water Resources Research↗
Nitrogen and phosphorus speciation and flux in a large Florida river wetland System
Hydrologic measurements and analyses of various nitrogen and phosphorus species were made on the Apalachicola River system in northern Florida in 1979 and 1980. Annual outflows of total nitrogen (TN) and total phosphorus (TP) were not substantially different from annual inflows. However, there was significant net import of ammonia and soluble reactive phosphorus and net export of some particulate and organic species. The TN: TP ratio ranged from 12 to 15, but the specific ratio of dissolved inorganic nitrogen: soluble reactive phosphorus was much higher (up to 40) and increased in a downstream direction; this contributed to a phosphorus-limiting situation in Apalachicola estuary. Processes within the flood plain ecosystem accounted for much of the release of organic and particulate species and retention of inorganic species. This flood plain function is probably critical for maintaining a nutrient pool in the estuary which supports secondary productivity and a detrital-based food web.
Florida↗
Unit hydrograph approximations assuming linear flow through topologically random channel networks
The instantaneous unit Hydrograph (IUH) of a drainage basin is derived in terms of fundamental basin characteristics ( Z , α, β), where α parameterizes the link (channel segment) length distribution, and β is a vector of hydraulic parameters, Z is one of three basin topological properties, N , ( N , D ), or ( N , M ), where N is magnitude (number of first-order streams), D is diameter (mainstream length), and M is order. The IUH is derived based on assumptions that the links are independent and identically distributed random variables and that the network is a member of a topologically random population. Linear routing schemes, including translation, diffusion, and general linear routing are used, and constant drainage density is assumed. By using ( N , α, β) as the fundamental basin characteristics, asymptotic (for large N ) considerations lead to a Weibull probability density function for the IUH, with time to peak given by t p = (2 N ) ½ α * /β * where α * is mean link length, and β * is a scalar hydraulic parameter (usually average celerity). This asymptotic IUH is identical for all linear routing schemes.
Water Resources Research↗
A quantitative analysis of the Lassen hydrothermal system, north central California
Our conceptual model of the Lassen system is termed a liquid-dominated hydrothermal system with a parasitic vapor-dominated zone. The essential feature of this model is that steam and steam-heated discharge at relatively high altitudes in Lassen Volcanic National Park (LVNP) and liquid discharge with high chloride concentrations at relatively low altitudes outside LVNP are both fed by an upflow of high-enthalpy two-phase fluid within the Park. Liquid flows laterally away from the upflow area toward the areas of high-chloride discharge, and steam rises through a vapor-dominated zone to feed the steam and steam-heated features. Numerical simulations show that several conditions are necessary for the development of this type of system, including (1) large-scale topographic relief; (2) an initial period of convective heating within an upflow zone followed by (3) a change in hydrologic or geologic conditions that initiates drainage of liquid from portions of the upflow zone; and (4) low-permeability barriers that inhibit the movement of cold water into the vapor zone. Simulations of thermal fluid withdrawal south of LVNP, carried out in order to determine the effects of such withdrawal on portions of the hydrothermal system within the Park, generally showed decreases in pressure and liquid saturation beneath the vapor zone which resulted in temporary increases and subsequent decreases in the rate of upflow of steam. A generalized production-injection scenario that could mitigate the effects of development on both the high-chloride and steam-fed features was identified.
California↗
Errors and parameter estimation in precipitation-runoff modeling: 2. Case study
A case study is presented which illustrates some of the error analysis, sensitivity analysis, and parameter estimation procedures reviewed in the first part of this paper. It is shown that those procedures, most of which come from statistical nonlinear regression theory, are invaluable in interpreting errors in precipitation-runoff modeling and in identifying appropriate calibration strategies.
Water Resources Research↗
Type curve analysis of inertial effects in the response of a well to a slug test.
The water level response to a slug or bailer test in a well completed in a confined aquifer has been evaluated taking into account well-bore storage and inertial effects of the water column in the well. The response range, from overdamped with negligible inertial effects to damped oscillation, was covered employing numerical inversions of the Laplace-transform solution. By scaling the time with respect to the undamped natural period of the well-aquifer system and by using the damping parameter for a second-order damped, inertial-elastic system, a set of type curves was constructed that enables water level response data from a slug or bailer test to be analyzed under conditions where the inertial parameter is large. Values of transmissivity and effective static water column length can be determined when an estimate of storage coefficient is available. The numerical solution and resulting type curves cover the transition range between the limiting cases of negligible inertial effects and of damped oscillation that have been treated by others. Two examples of slug test analysis show that precise results depend on accurate measurements of water level displacement (±1% of initial value).
Water Resources Research↗
Comment on “Evaluation of slug tests in wells containing a finite-thickness skin” by C. R. Faust and J. W. Mercer
No abstract available.
Water Resources Research↗
A comparison of several methods of solving nonlinear regression groundwater flow problems
Computational efficiency and computer memory requirements for four methods of minimizing functions were compared for four test nonlinear-regression steady state groundwater flow problems. The fastest methods were the Marquardt and quasi-linearization methods, which required almost identical computer times and numbers of iterations; the next fastest was the quasi-Newton method, and last was the Fletcher-Reeves method, which did not converge in 100 iterations for two of the problems. The fastest method per iteration was the Fletcher-Reeves method, and this was followed closely by the quasi-Newton method. The Marquardt and quasi-linearization methods were slower. For all four methods the speed per iteration was directly related to the number of parameters in the model. However, this effect was much more pronounced for the Marquardt and quasi-linearization methods than for the other two. Hence the quasi-Newton (and perhaps Fletcher-Reeves) method might be more efficient than either the Marquardt or quasi-linearization methods if the number of parameters in a particular model were large, although this remains to be proven. The Marquardt method required somewhat less central memory than the quasi-linearization metilod for three of the four problems. For all four problems the quasi-Newton method required roughly two thirds to three quarters of the memory required by the Marquardt method, and the Fletcher-Reeves method required slightly less memory than the quasi-Newton method. Memory requirements were not excessive for any of the four methods.
Water Resources Research↗
Geochemistry of groundwater in Cretaceous sediments of the southeastern coastal plain of eastern Mississippi and western Alabama
Geochemical samples of waters along two hydrologic flow paths in four Upper Cretaceous aquifers of northeastern Mississippi and western Alabama indicate similar geochemical evolution of their respective waters. The waters of the Coker, Gordo, and Eutaw-McShan aquifers, noncalcareous sands, increase downgradient in dissolved solids and p H, and are dominated by sodium and bicarbonate ions, which generally result from a calcite dissolution-cation exchange process. Increases in dissolved iron from oxidation reduction reactions followed by decreases in total inorganic carbon from siderite precipitation occur along the flow paths. As the total inorganic carbon increases, carbon 13 (δ 13 C) generally is enriched in the moving waters, indicating the addition of a predominantly heavy source of carbon, most likely dissolving calcite. In the Coker aquifer δ 13 C values in the waters become more negative downgradient, resulting from lignite oxidation, followed by δ 13 C values becoming more positive, resulting from dissolving calcite and perhaps some mixing with brines. In northeastern Mississippi the Ripley aquifer, a calcareous sand, initially contains calcium-bicarbonate dominated water that evolves to a sodium- bicarbonate dominated water downgradient, primarily from the calcite dissolution-cation exchange process. Feldspar hydrolysis to kaolinite dominates aluminosilicate reactions in the upgradient parts of the aquifers. Authigenesis of smectite clay may be occurring in the deeper, downgradient parts of the aquifers.
Alabama, Mississippi↗
Assessment of long-term salinity changes in an irrigated stream-aquifer system
Changes in salinity in groundwater and surface water in the Arkansas River valley of southeastern Colorado are primarily related to irrigation practices. A solute transport model was applied to an 11-mile reach of the valley to compute salinity changes in response to spatially and temporally varying stresses. The model was calibrated in 1973 using detailed field measurements made during 1971 and 1972. In 1973 the calibrated model was used to predict that a gradual long-term increase in groundwater salinity of about 2–3% per year would occur if the observed irrigation practices continued. The study area was resampled during the winter of 1982 to help evaluate if any long-term changes in salinity are actually occurring. Nonparametric and parametric statistical tests were used to help assess the significance of observed changes in groundwater salinity. These tests indicate that a statistically significant increase in salinity occurred between the winters of 1971 and 1972 (the model calibration period). However, a comparison of the winter 1972 and winter 1982 data indicates that no significant net change in salinity has occurred during this 10-year period. An analysis of the few available historical data (1895, 1923, 1959–1961, and 1964) supports the hypothesis that groundwater salinity in this irrigated area has reached a long-term dynamic equilibrium in response to irrigation practices. The model predictions of long-term salinity increases were invalid probably because the calibration period occurred during a short-term annual trend of increasing salinity in the river (and hence in leaky irrigation canals and in applied irrigation water), which was not representative of the long-term trend.
Colorado↗