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At least 829 records · Page 46Linked to original sources
USGS2002

Determining mineral weathering rates based on solid and solute weathering gradients and velocities: Application to biotite weathering in saprolites

Chemical weathering gradients are defined by the changes in the measured elemental concentrations in solids and pore waters with depth in soils and regoliths. An increase in the mineral weathering rate increases the change in these concentrations with depth while increases in the weathering velocity decrease the change. The solid-state weathering velocity is the rate at which the weathering front propagates through the regolith and the solute weathering velocity is equivalent to the rate of pore water infiltration. These relationships provide a unifying approach to calculating both solid and solute weathering rates from the respective ratios of the weathering velocities and gradients. Contemporary weathering rates based on solute residence times can be directly compared to long-term past weathering based on changes in regolith composition. Both rates incorporate identical parameters describing mineral abundance, stoichiometry, and surface area. Weathering gradients were used to calculate biotite weathering rates in saprolitic regoliths in the Piedmont of Northern Georgia, USA and in Luquillo Mountains of Puerto Rico. Solid-state weathering gradients for Mg and K at Panola produced reaction rates of 3 to 6 x 10-17 mol m-2 s-1 for biotite. Faster weathering rates of 1.8 to 3.6 ?? 10-16 mol m-2 s-1 are calculated based on Mg and K pore water gradients in the Rio Icacos regolith. The relative rates are in agreement with a warmer and wetter tropical climate in Puerto Rico. Both natural rates are three to six orders of magnitude slower than reported experimental rates of biotite weathering. ?? 2002 Elsevier Science B.V. All rights reserved.

Chemical Geology↗
USGS1989

Humic substances in the Suwannee River, Georgia; interactions, properties, and proposed structures

Humic substances as a collective term and humic and fulvic acids as specific terms are not household words. For about a century, these terms belonged to the domain of the soil scientist. Even^though their chemical structures remained elusive, they were recognized as important entities in soil. During the past decade or so, there has been a renewed interest in humic substances in soil and water. Such interest has been the result of improved analytical instrumentation, and by a need to understand the structure and function of natural organic substances in water. A responsibility of the U.S. Geological Survey is to assess the Nation's water resources; this includes water quality, which is the study of material in water. Such material may be suspended, colloidal, or in true solution. Because humic substances are a major carbon source in water, they have received attention by Geological Survey scientists. This attention has been a major focus by members of the Geological Survey's organic-chemistry group. For more than a decade, this group has collected samples, made analyses, and worked toward determining the structures and function of humic substances in water. Their work has brought worldwide recognition to the field, and in 1981, through Geological Survey support, they helped organize the International Humic Substances Society, which held its first meeting in Estes Park, Colorado, in August 1983. At the second meeting of the Society in Birmingham, England, in August 1984, it became apparent that Geological Survey scientists were rapidly advancing the study of the chemistry of humic substances. It seemed appropriate, therefore, to publish this Open-File report on humic and fulvic acids from the Suwannee River in Georgia. The results represent our most definitive findings to date (1986). Though this work is not conclusive, it is state-of-the-science. Hopefully, our reporting on this work will aid in moving the science of humic substances forward as others read of our progress, findings, and theories. If so, this Open-File report will have served its purpose.

Georgia↗
USGS2012

Groundwater quality in the Columbia Plateau, Snake River Plain, and Oahu basaltic-rock and basin-fill aquifers in the Northwestern United States and Hawaii, 1992-2010

This assessment of groundwater-quality conditions of the Columbia Plateau, Snake River Plain, and Oahu for the period 1992–2010 is part of the U.S. Geological Survey’s National Water Quality Assessment (NAWQA) program. It shows where, when, why, and how specific water-quality conditions occur in groundwater of the three study areas and yields science-based implications for assessing and managing the quality of these water resources. The primary aquifers in the Columbia Plateau, Snake River Plain, and Oahu are mostly composed of fractured basalt, which makes their hydrology and geochemistry similar. In spite of the hydrogeologic similarities, there are climatic differences that affect the agricultural practices overlying the aquifers, which in turn affect the groundwater quality. Understanding groundwater-quality conditions and the natural and human factors that control groundwater quality is important because of the implications to human health, the sustainability of rural agricultural economies, and the substantial costs associated with land and water management, conservation, and regulation. The principal regional aquifers of the Columbia Plateau, Snake River Plain, and Oahu are highly vulnerable to contamination by chemicals applied at the land surface; essentially, they are as vulnerable as many shallow surficial aquifers elsewhere. The permeable and largely unconfined character of principal aquifers in the Columbia Plateau, Snake River Plain, and Oahu allow water and chemicals to infiltrate to the water table despite depths to water commonly in the hundreds of feet. The aquifers are essentially unconfined over large areas, having few extensive clay layers to impede infiltration through permeable volcanic rock and alluvial sediments. Agriculture is intensive in all three study areas, and heavy irrigation has imposed large artificial flows of irrigation recharge that rival or exceed natural recharge rates. Fertilizers and pesticides applied at land surface are leached from soil and transported to deep water tables with the infiltrating irrigation recharge, resulting in a layer of degraded water quality overlying better quality regional groundwater beneath. This “irrigation-recharge layer” is best known on Oahu, where it has been studied since the 1960s; however, the extent of nitrate and pesticide contamination in the Columbia Plateau and Snake River Plain indicate that the same situation exists in those areas. Contamination from agricultural and urban activities is present not only at shallow depths in surficial materials of the three areas, but extends regionally in the deep, principal bedrock aquifers that are tapped for drinking water by domestic and public-supply wells. Naturally occurring constituents and nitrate concentrations above human-health benchmarks—Maximum Contaminant Levels (MCLs), and Health-Based Screening Levels (HBSLs)—were more common in the Columbia Plateau and the Snake River Plain than in Oahu. Concentrations of anthropogenic constituents (constituents related to human activities) above human-health benchmarks were more common in Oahu. Naturally occurring contaminants, such as arsenic and radon, may be present in groundwater at concentrations of potential concern for human health in relatively undeveloped settings that otherwise may not be perceived as susceptible to contamination. Even though the median depth to groundwater in Oahu is more than 300 feet, the common occurrence of anthropogenic compounds in groundwater indicates that Oahu has a high susceptibility to contamination. Nitrate concentrations in groundwater were above the national background concentrations of 1 milligram per liter (mg/L) in all three study areas. In the Columbia Plateau, nitrate exceeded the human-health benchmark of 10 mg/L in 20 percent of the wells sampled. In the Snake River Plain, nitrate exceeded the human-health benchmark of 10 mg/L in 3 percent of the wells sampled. Nitrate can persist in groundwater for years and even decades in the oxygen-rich groundwater of the Columbia Plateau and the Snake River Plain, so prudent groundwater protection measures are critical to protect drinking water resources by reducing nitrate leaching from the land surface. Nitrate logistic regression models indicated that areas with a high percentage of land in crops (such as potatoes or sugarcane) and soils with low amounts of organic matter are most likely to have elevated nitrate concentrations in the groundwater. Areas where agricultural activities were absent had much lower probabilities of detecting elevated nitrate concentrations. The Columbia Plateau had a much higher probability of having elevated nitrate concentrations, with most of the land area having greater than a 50 percent probability of elevated nitrate concentrations. Oahu and the Snake River Plain had a much lower probability of having elevated nitrate concentrations because of their lower percentage of agricultural land. Pesticides were detected at many sites in groundwater of the Columbia Plateau, Snake River Plain, and Oahu but generally at low concentrations below human-health benchmarks. Atrazine and its degradate (a compound produced from the breakdown of a parent pesticide), deethylatrazine, were the most commonly detected pesticides in groundwater sampled in the Columbia Plateau and Snake River Plain. Bromacil was the most commonly detected pesticide on Oahu. The other pesticides most commonly detected in the study areas include simazine, hexazinone, metribuzin, diuron, prometon, metolachlor, p,p’ -DDE, dieldrin, 2-4-D, and alachlor. DDE (a degradate of DDT) and dieldrin are still being detected in groundwater despite having been banned for more than 30 years. Codetection of multiple pesticides in water from a single well was common. The widespread occurrence of pesticides in groundwater in the study areas indicates that the groundwater is highly susceptible to pesticide contamination. Some pesticides were detected in groundwater samples from all three study areas, but other pesticides were detected only in samples from Oahu, or only in samples from the Columbia Plateau and Snake River Plain. This is because some pesticides (such as atrazine) are broad-spectrum pesticides that are used on many crops in many different areas of the United States. Other pesticides (such as simazine, metribuzin, and metolachlor) are used on row crops (such as potatoes, barley, and alfalfa) grown in the Columbia Plateau and Snake River Plain, but not on pineapple or sugarcane grown in Oahu. Atrazine logistic-regression models indicate that areas with a high percentage of land in crops (such as potatoes or sugarcane), a low percentage of fallow land, and highly permeable soils with low amounts of organic matter are most likely to have atrazine detected in the groundwater. Areas where agricultural activities were absent had much lower probabilities of atrazine being detected. The Snake River Plain had a much higher probability of atrazine detections, with more than 50 percent of the land area having greater than a 50 percent probability of atrazine contamination. Oahu had a much lower probability of atrazine contamination, with only 24 percent of the land area having greater than a 50 percent probability of atrazine contamination. Oahu and the Columbia Plateau had some of the highest percentages of soil fumigant detections in groundwater in the United States. Soil fumigants are volatile organic compounds (VOCs) used as pesticides, which are applied to soils to reduce populations of plant parasitic nematodes (harmful rootworms), weeds, fungal pathogens, and other soil-borne microorganisms. They are used in Oahu and the Columbia Plateau on crops such as pineapple and potatoes. All three areas (Columbia Plateau, Snake River Plain, and Oahu) had fumigant concentrations exceeding human-health benchmarks for drinking water.

Hawai'i, Idaho, Nevada, Oregon, Utah, Washington, ↗
USGS2012

Coal-tar-based pavement sealcoat and PAHs: implications for the environment, human health, and stormwater management

Coal-tar-based sealcoat products, widely used in the central and eastern U.S. on parking lots, driveways, and even playgrounds, are typically 20−35% coal-tar pitch, a known human carcinogen that contains about 200 polycyclic aromatic hydrocarbon (PAH) compounds. Research continues to identify environmental compartments—including stormwater runoff, lake sediment, soil, house dust, and most recently, air—contaminated by PAHs from coal-tar-based sealcoat and to demonstrate potential risks to biological communities and human health. In many cases, the levels of contamination associated with sealed pavement are striking relative to levels near unsealed pavement: PAH concentrations in air over pavement with freshly applied coal-tar-based sealcoat, for example, were hundreds to thousands of times higher than those in air over unsealed pavement. Even a small amount of sealcoated pavement can be the dominant source of PAHs to sediment in stormwater-retention ponds; proper disposal of such PAH-contaminated sediment can be extremely costly. Several local governments, the District of Columbia, and the State of Washington have banned use of these products, and several national and regional hardware and home-improvement retailers have voluntarily ceased selling them.

Environmental Science & Technology↗
USGS2018

Methane in groundwater from a leaking gas well, Piceance Basin, Colorado, USA

Site-specific and regional analysis of time-series hydrologic and geochemical data collected from 15 monitoring wells in the Piceance Basin indicated that a leaking gas well contaminated shallow groundwater with thermogenic methane. The gas well was drilled in 1956 and plugged and abandoned in 1990. Chemical and isotopic data showed the thermogenic methane was not from mixing of gas-rich formation water with shallow groundwater or natural migration of a free-gas phase. Water-level and methane-isotopic data, and video logs from a deep monitoring well, indicated that a shale confining layer ~125 m below the zone of contamination was an effective barrier to upward migration of water and gas. The gas well, located 27 m from the contaminated monitoring well, had ~1000 m of uncemented annular space behind production casing that was the likely pathway through which deep gas migrated into the shallow aquifer. Measurements of soil gas near the gas well showed no evidence of methane emissions from the soil to the atmosphere even though methane concentrations in shallow groundwater (16 to 20 mg/L) were above air-saturation levels. Methane degassing from the water table was likely oxidized in the relatively thick unsaturated zone (~18 m), thus rendering the leak undetectable at land surface. Drilling and plugging records for oil and gas wells in Colorado and proxies for depth to groundwater indicated thousands of oil and gas wells were drilled and plugged in the same timeframe as the implicated gas well, and the majority of those wells were in areas with relatively large depths to groundwater. This study represents one of the few detailed subsurface investigations of methane leakage from a plugged and abandoned gas well. As such, it could provide a useful template for prioritizing and assessing potentially leaking wells, particularly in cases where the leakage does not manifest itself at land surface.

Colorado↗
USGS2016

Cumulative drought and land-use impacts on perennial vegetation across a North American dryland region

Question The decline and loss of perennial vegetation in dryland ecosystems due to global change pressures can alter ecosystem properties and initiate land degradation processes. We tracked changes of perennial vegetation using remote sensing to address the question of how prolonged drought and land-use intensification have affected perennial vegetation cover across a desert region in the early 21st century? Location Mojave Desert, southeastern California, southern Nevada, southwestern Utah and northwestern Arizona, USA. Methods We coupled the Moderate-Resolution Imaging Spectroradiometer Enhanced Vegetation Index (MODIS-EVI) with ground-based measurements of perennial vegetation cover taken in about 2000 and about 2010. Using the difference between these years, we determined perennial vegetation changes in the early 21st century and related these shifts to climate, soil and landscape properties, and patterns of land use. Results We found a good fit between MODIS-EVI and perennial vegetation cover (2000: R 2 = 0.83 and 2010: R 2 = 0.74). The southwestern, far southeastern and central Mojave Desert had large declines in perennial vegetation cover in the early 21st century, while the northeastern and southeastern portions of the desert had increases. These changes were explained by 10-yr precipitation anomalies, particularly in the cool season and during extreme dry or wet years. Areas heavily impacted by visitor use or wildfire lost perennial vegetation cover, and vegetation in protected areas increased to a greater degree than in unprotected areas. Conclusions We find that we can extrapolate previously documented declines of perennial plant cover to an entire desert, and demonstrate that prolonged water shortages coupled with land-use intensification create identifiable patterns of vegetation change in dryland regions.

Applied Vegetation Science↗
USGS2021

The 2018 update of the US National Seismic Hazard Model: Where, why, and how much probabilistic ground motion maps changed

The 2018 US Geological Survey National Seismic Hazard Model (NSHM) incorporates new data and updated science to improve the underlying earthquake and ground motion forecasts for the conterminous United States. The NSHM considers many new data and component input models: (1) new earthquakes between 2013 and 2017 and updated earthquake magnitudes for some earlier earthquakes; (2) two updated smoothed seismicity models to forecast earthquake rates; (3) two suites of new central and eastern US (CEUS) ground motion models (GMMs) to translate ground shaking for various earthquake sizes and source-to-site distances considered in the model; (4) two CEUS GMMs for aleatory variability; (5) two CEUS site-effect models that modify ground shaking based on alternative shallow site conditions; (6) more advanced western US (WUS) lithologic and structural information to assess basin site effects for selected urban regions; and (7) a more comprehensive range of outputs (22 periods and 8 site classes) than in previous versions of the NSHMs. Each of these new datasets and models produces changes in the probabilistic ground shaking levels that are spatially and statistically analyzed. Recent earthquakes or changes to some older earthquake magnitudes and locations mostly result in probabilistic ground shaking levels that are similar to previous models, but local changes can reach up to +80% and −60% compared to the 2014 model. Newly developed CEUS models for GMMs, aleatory variability, and site effects cause overall changes up to ±64%. The addition of the WUS basin amplifications causes changes of up to +60% at longer periods for sites overlying deep soft soils. Across the conterminous United States, the hazard changes in the model are mainly caused by new GMMs in the CEUS, by sedimentary basin effects for long periods (≥1 s) in the WUS, and by seismicity changes for short (0.2 s) and long (1 s) periods for both areas.

Earthquake Spectra↗
USGS2023

Prediction of the probability of elevated nitrate concentrations at groundwater depths used for drinking-water supply in the Puget Sound basin, Washington, 2004–19

The Puget Sound basin encompasses the 13,700-square-mile area that drains to the Puget Sound and the adjacent marine waters of Washington State. Well more than 4 million people live within the basin, with numbers continuing to increase, who rely on the basin’s natural resources including groundwater. The Puget Sound Partnership was created by a Washington State statute to implement a science-based recovery of the Puget Sound to help address impacts to these resources. As part of the recovery, the partnership developed the Puget Sound Vital Signs as measures of ecosystem health that guide the assessment of progress toward Puget Sound recovery goals. The Puget Sound Partnership Leadership Council adopted a Drinking Water Vital Sign associated with human health and quality of life, recognizing certain indicators as integral to the sustainability of Puget Sound recovery efforts. One such Vital Sign indicator was the vulnerability of groundwater throughout the aquifers of the Puget Sound basin to elevated nitrate concentrations as defined by the probability of exceeding 2 milligrams/liter (mg/L) at a specific location and well depth. The U.S. Geological Survey (USGS) led the effort to characterize groundwater vulnerability. For this study, groundwater vulnerability refers to a probability with which a contaminant applied at or near the land surface can migrate to the aquifer of interest for a given set of land-use practices. Nitrate concentration data were selected for evaluation because elevated nitrate concentrations are typically caused by anthropogenic activities and have been associated with deleterious impacts on human health. To identify groundwater vulnerability to elevated nitrate concentrations, logistic regression was used to relate anthropogenic (human associated) and natural variables to the occurrence of elevated nitrate concentrations in untreated groundwater from large public water supply system wells found within the Washington State Department of Health Sentry database. Variables that were analyzed included well depth, soil hydraulic conductivity, precipitation, population density, fertilizer application amounts, and land-use types. Statistically significant models that predicted the probabilities of groundwater nitrate concentrations greater than 2 mg/L based on the predictor variables were created for the time periods 2000–04, 2005–09, 2010–14, and 2015–19. For all time periods, well depth and a measure of the abundance of urban and agricultural land over or near the well consistently helped explain the vulnerability of the well to elevated nitrate concentrations defined as a probability of exceeding 2 mg/L of nitrate. Precipitation and (or) soil hydraulic conductivity were also important predictor variables in the models. The models for each time period were used to create maps of groundwater vulnerability at 150- and 300-foot depths throughout the Puget Sound basin. As expected, the most vulnerable locations were associated with shallower well depths and increased agriculture and urban land cover. Across all four time periods, groundwater vulnerability throughout the Puget Sound was low, with probabilities of exceeding 2 mg/L concentrations of nitrate at depths at 150 and 300 feet typically less than 50 percent. Results also found a slight decrease in probabilities of elevated nitrate concentrations throughout the basin over time. More specifically, additional statistical tests found that groundwater with probabilities of less than about 60 percent declined from 2000 to 2019 and represented more than 75 percent of the modeled Puget Sound basin aquifer. Wells with greater than 60 percent probability increased over the same time period but represented only about 25 percent of the aquifer. The maps and statistical analysis presented in the study provide valuable and informative evaluation of the vulnerability of groundwater in the Puget Sound basin to elevated nitrate concentrations. The probability maps do not represent measured nitrate concentrations in groundwater, but rather they present the probability that nitrate concentrations exceed 2 mg/L. The models and predictions from this study are a viable indicator for the Puget Sound Partnership’s Healthy Human Population—Drinking Water Vital Sign. The logistic regression modeling approach presented here benefits water managers by allowing them to assess temporal trends in a range of probabilities, explore vulnerability changes as new regional land cover and anthropogenic data are generated, and distinguish vulnerabilities at different depths within the aquifer.

Washington↗
USGS2016

Groundwater

Introduction Groundwater represents the terrestrial subsurface component of the hydrologic cycle. As such, groundwater is generally in motion, moving from elevated areas of recharge to lower areas of discharge. Groundwater usually moves in accordance with Darcy’s law (Dalmont, Paris: Les Fontaines Publiques de la Ville de Dijon, 1856). Groundwater residence times can be under a day in small upland catchments to over a million years in subcontinental-sized desert basins. The broadest definition of groundwater includes water in the unsaturated zone, considered briefly here. Water chemically bound to minerals, as in gypsum (CaSO 4 • 2H 2 O) or hydrated clays, cannot flow in response to gradients in total hydraulic head (pressure head plus elevation head); such water is thus usually excluded from consideration as groundwater. In 1940, M. King Hubbert showed Darcy’s law to be a special case of thermodynamically based potential field equations governing fluid motion, thereby establishing groundwater hydraulics as a rigorous engineering science ( Journal of Geology 48, pp. 785–944). The development of computer-enabled numerical methods for solving the field equations with real-world approximating geometries and boundary conditions in the mid-1960s ushered in the era of digital groundwater modeling. An estimated 30 percent of global fresh water is groundwater, compared to 0.3 percent that is surface water, 0.04 percent atmospheric water, and 70 percent that exists as ice, including permafrost ( Shiklomanov and Rodda 2004 , cited under Groundwater Occurrence ). Groundwater thus constitutes the vast majority—over 98 percent—of the unfrozen fresh-water resources of the planet, excluding surface-water reservoirs. Environmental dimensions of groundwater are equally large, receiving attention on multiple disciplinary fronts. Riparian, streambed, and spring-pool habitats can be sensitively dependent on the amount and quality of groundwater inputs that modulate temperature and solutes, including nutrients and dissolved oxygen. Groundwater withdrawals can negatively impact riparian habitats by depriving ecosystems of adequate fresh water and fragmenting communities when streams go dry. Biochemical reactions in shallow groundwater can remove anthropogenically elevated nitrogen compounds and reduce—but only to a point—the greening of waterways and shorelines with periphyton and harmful algal blooms. Groundwater extraction for beneficial use is increasingly limited by water-quality constraints imposed by naturally occurring and introduced substances. Overdrafting can cause land-surface subsidence, damaging buildings and roads and disrupting canals, sewers, and other gravity-flow conveyances. Increases in groundwater levels can cause soil salinization in dry regions and erosive sapping and flooding in wet regions. Coastal saltwater intrusion, groundwater flooding, salinization associated with groundwater-irrigated agriculture, induced seismicity from injected wastes, and the detrimental impacts of groundwater depletion are among the major environmental challenges of our time.

Book chapter↗
USGS2001

Effect of flooding and draw-down disturbance on germination from a seashore meadow seed bank

The objective of this study was to investigate the effects of flooding and draw-down on the germination from the coastal grassland seed banks and to determine whether the effect of flooding varies between the delta and the seashore. Seed bank samples were collected from three shore transects in SW Finland, two on the shore of the Baltic Sea and one on the delta of River Kokemäenjoki. Samples were germinated in non-flooded and flooded conditions for over a month, after which both treatments were maintained in non-flooded conditions. A total of 9267 seedlings of 47 species germinated and mean density of seeds in the soil was ca. 84 000/m 2 . Most of the seedlings were monocots (98%) and perennials (98%). Ca. 30–40% of the species found in the above-ground vegetation had a seed bank including the majority of the most abundant species. The number of seeds and species richness increased as the organic layer became thicker. The organic layer was thicker in the seashore samples and the seed bank was significantly larger than in the delta. The flooding and draw-down treatment significantly increased the number of germinating seedlings in the seashore and also increased species richness in two transects, one in the delta and the other in the seashore. Two species, Schoenoplectus tabernaemontani and Typha latifolia , had significantly higher germination in the flooded treatment than in the non-flooded. Apparently, many species in these coastal grasslands have adapted to flood disturbance and for seeds of some species flooding may work as a positive signal, possibly breaking dormancy.

Pori↗
USGS2014

Stream classification of the Apalachicola-Chattahoochee-Flint River System to support modeling of aquatic habitat response to climate change

A stream classification and associated datasets were developed for the Apalachicola-Chattahoochee-Flint River Basin to support biological modeling of species response to climate change in the southeastern United States. The U.S. Geological Survey and the Department of the Interior’s National Climate Change and Wildlife Science Center established the Southeast Regional Assessment Project (SERAP) which used downscaled general circulation models to develop landscape-scale assessments of climate change and subsequent effects on land cover, ecosystems, and priority species in the southeastern United States. The SERAP aquatic and hydrologic dynamics modeling efforts involve multiscale watershed hydrology, stream-temperature, and fish-occupancy models, which all are based on the same stream network. Models were developed for the Apalachicola-Chattahoochee-Flint River Basin and subbasins in Alabama, Florida, and Georgia, and for the Upper Roanoke River Basin in Virginia. The stream network was used as the spatial scheme through which information was shared across the various models within SERAP. Because these models operate at different scales, coordinated pair versions of the network were delineated, characterized, and parameterized for coarse- and fine-scale hydrologic and biologic modeling. The stream network used for the SERAP aquatic models was extracted from a 30-meter (m) scale digital elevation model (DEM) using standard topographic analysis of flow accumulation. At the finer scale, reaches were delineated to represent lengths of stream channel with fairly homogenous physical characteristics (mean reach length = 350 m). Every reach in the network is designated with geomorphic attributes including upstream drainage basin area, channel gradient, channel width, valley width, Strahler and Shreve stream order, stream power, and measures of stream confinement. The reach network was aggregated from tributary junction to tributary junction to define segments for the benefit of hydrological, soil erosion, and coarser ecological modeling. Reach attributes are summarized for each segment. In six subbasins segments are assigned additional attributes about barriers (usually impoundments) to fish migration and stream isolation. Segments in the six sub-basins are also attributed with percent urban area for the watershed upstream from the stream segment for each decade from 2010–2100 from models of urban growth. On a broader scale, for application in a coarse-scale species-response model, the stream-network information is aggregated and summarized by 256 drainage subbasins (Hydrologic Response Units) used for watershed hydrologic and stream-temperature models. A model of soil erodibility based on the Revised Universal Soil Loss Equation also was developed at this scale to parameterize a model to evaluate stream condition. The reach-scale network was classified using multivariate clustering based on modeled channel width, valley width, and mean reach gradient as variables. The resulting classification consists of a 6-cluster and a 12-cluster classification for every reach in the Apalachicola-Chattahoochee-Flint Basin. We present an example of the utility of the classification that was tested using the occurrence of two species of darters and two species of minnows in the Apalachicola-Chattahoochee-Flint River Basin, the blackbanded darter and Halloween darter, and the bluestripe shiner and blacktail shiner.

Alabama, Florida, Georgia, Virginia↗
USGS2021

Effects of prescribed fire timing on vigor of the invasive forb sericea lespedeza (Lespedeza cuneata), total forage biomass accumulation, plant-community composition, and native fauna on tallgrass prairie in the Kansas Flint Hills

The predominant grazing-management practice of the Kansas Flint Hills involves annual prescribed burning in March or April with postfire grazing by yearling beef cattle at a high stocking density from April to August. There has been a dramatic increase in sericea lespedeza ( Lespedeza cuneata [Dumont] G. Don) coincident with this temporally focused use of prescribed fire in the Flint Hills region. The species is an aggressive invader and a statewide noxious weed in Kansas. Control has generally been attempted using repeated herbicide applications. This approach has not limited proliferation of sericea lespedeza and resulted in collateral damage to nontarget flora and fauna. Alternative timing of prescribed fire has not been evaluated for its control. Our objectives for this 4-yr experiment were to (1) document the effects of prescribed burning during early April, early August, or early September on vigor of sericea lespedeza, standing forage biomass, and basal cover of native graminoids, forbs, and shrubs and (2) measure responses to fire regimes by grassland bird and butterfly communities. Whole-plant dry mass, basal cover, and seed production of sericea lespedeza were markedly less ( P < 0.01) in areas treated with prescribed fire in August or September compared with April. Forage biomass did not differ ( P ≥ 0.43) among treatments when measured during July; moreover, frequencies of bare soil, litter, and total basal plant cover were not different ( P ≥ 0.29) among treatments. Combined basal covers of C4 grasses, C3 grasses, annual grasses, forbs, and shrubs also did not differ ( P ≥ 0.11) between treatments. Densities of grasshopper sparrow ( Ammodramus savannarum ), dickcissel ( Spiza americana ), and eastern meadowlark ( Sturnella magna ) were not negatively affected ( P > 0.10) by midsummer or late-summer fires relative to early-spring fires. There were no differences ( P > 0.10) in densities of grassland-specialist butterfly species across fire regimes. Under the conditions of our experiment, prescribed burning during summer produced no detrimental effects on forage production, desirable nontarget plant species, grassland birds, or butterfly communities but had strong suppressive effects on sericea lespedeza. Additional research is warranted to investigate how to best incorporate late-summer prescribed fire into common grazing-management practices in the Kansas Flint Hills.

Kansas↗
USGS1997

Sequestration of hydrophobic organic contaminants by geosorbents

The chemical interactions of hydrophobic organic contaminants (HOCs) with soils and sediments (geosorbents) may result in strong binding and slow subsequent release rates that significantly affect remediation rates and endpoints. The underlying physical and chemical phenomena potentially responsible for this apparent sequestration of HOCs by geosorbents are not well understood. This challenges our concepts for assessing exposure and toxicity and for setting environmental quality criteria. Currently there are no direct observational data revealing the molecular-scale locations in which nonpolar organic compounds accumulate when associated with natural soils or sediments. Hence macroscopic observations are used to make inferences about sorption mechanisms and the chemical factors affecting the sequestration of HOCs by geosorbents. Recent observations suggest that HOC interactions with geosorbents comprise different inorganic and organic surfaces and matrices, and distinctions may be drawn along these lines, particularly with regard to the roles of inorganic micropores, natural sorbent organic matter components, combustion residue particulate carbon, and spilled organic liquids. Certain manipulations of sorbates or sorbent media may help reveal sorption mechanisms, but mixed sorption phenomena complicate the interpretation of macroscopic data regarding diffusion of HOCs into and out of different matrices and the hysteretic sorption and aging effects commonly observed for geosorbents. Analytical characterizations at the microscale, and mechanistic models derived therefrom, are needed to advance scientific knowledge of HOC sequestration, release, and environmental risk.

Environmental Science & Technology↗
USGS2000

Sources and haloacetic acid/trihalomethane formation potentials of aquatic humic substances in the Wakarusa River and Clinton Lake near Lawrence, Kansas

Gram quantities of aquatic humic substances (AHS) were extracted from the Wakarusa River−Clinton Lake Reservoir system, near Lawrence, KS, to support nuclear magnetic resonance (NMR) experimental studies, report concentrations of dissolved organic carbon (DOC) and AHS, define sources of the AHS, and determine if the AHS yield sufficient quantities of haloacetic acids (HAA5) and trihalomethanes (THM4) that exceed U.S. Environmental Protection Agency (EPA) Maximum Contaminant Levels (MCL) in drinking water. AHS from the Wakarusa River and Clinton Lake originated from riparian forest vegetation, reflected respective effects of soil organic matter and aquatic algal/bacterial sources, and bore evidence of biological degradation and photodegradation. AHS from the Wakarusa River showed the effect of terrestrial sources, whereas Clinton Lake humic acid also reflected aquatic algal/bacterial sources. Greater amounts of carbon attributable to tannin-derived chemical structures may correspond with higher HAA5 and THM4 yields for Clinton Lake fulvic acid. Prior to appreciable leaf-fall from deciduous trees, the combined (humic and fulvic acid) THM4 formation potentials for the Wakarusa River approached the proposed EPA THM4 Stage I MCL of 80 μg/L, and the combined THM4 formation potential for Clinton Lake slightly exceeded the proposed THM4 Stage II MCL of 40 μg/L. Finally, AHS from Clinton Lake could account for most (>70%) of the THM4 concentrations in finished water from the Clinton Lake Water Treatment Plant based on September 23, 1996, THM4 results.

Environmental Science & Technology↗
USGS2013

Sorption of pure N 2 O to biochars and other organic and inorganic materials under anhydrous conditions

Suppression of nitrous oxide (N 2 O) emissions from soil is commonly observed after amendment with biochar. The mechanisms accounting for this suppression are not yet understood. One possible contributing mechanism is N 2 O sorption to biochar. The sorption of N 2 O and carbon dioxide (CO 2 ) to four biochars was measured in an anhydrous system with pure N 2 O. The biochar data were compared to those for two activated carbons and other components potentially present in soils—uncharred pine wood and peat—and five inorganic metal oxides with variable surface areas. Langmuir maximum sorption capacities ( Q max ) for N 2 O on the pine wood biochars (generated between 250 and 500 °C) and activated carbons were 17–73 cm 3 g –1 at 20 °C (median 51 cm 3 g –1 ), with Langmuir affinities ( b ) of 2–5 atm –1 (median 3.4 atm –1 ). Both Q max and b of the charred materials were substantially higher than those for peat, uncharred wood, and metal oxides [ Q max 1–34 cm 3 g –1 (median 7 cm 3 g –1 ); b 0.4–1.7 atm –1 (median 0.7 atm –1 )]. This indicates that biochar can bind N 2 O more strongly than both mineral and organic soil materials. Q max and b for CO 2 were comparable to those for N 2 O. Modeled sorption coefficients obtained with an independent polyparameter—linear free-energy relationship matched measured data within a factor 2 for mineral surfaces but underestimated by a factor of 5–24 for biochar and carbonaceous surfaces. Isosteric enthalpies of sorption of N 2 O were mostly between −20 and −30 kJ mol –1 , slightly more exothermic than enthalpies of condensation (−16.1 kJ mol –1 ). Q max of N 2 O on biochar (50000–130000 μg g –1 biochar at 20 °C) exceeded the N 2 O emission suppressions observed in the literature (range 0.5–960 μg g –1 biochar; median 16 μg g –1 ) by several orders of magnitude. Thus, the hypothesis could not be falsified that sorption of N 2 O to biochar is a mechanism of N 2 O emission suppression.

Environmental Science & Technology↗
USGS2016

ChemCam activities and discoveries during the nominal mission of the Mars Science Laboratory in Gale crater, Mars

At Gale crater, Mars, ChemCam acquired its first laser-induced breakdown spectroscopy (LIBS) target on Sol 13 of the landed portion of the mission (a Sol is a Mars day). Up to Sol 800, more than 188 000 LIBS spectra were acquired on more than 5800 points distributed over about 650 individual targets. We present a comprehensive review of ChemCam scientific accomplishments during that period, together with a focus on the lessons learned from the first use of LIBS in space. For data processing, we describe new tools that had to be developed to account for the uniqueness of Mars data. With regard to chemistry, we present a summary of the composition range measured on Mars for major-element oxides (SiO 2 , TiO 2 , Al 2 O 3 , FeO T , MgO, CaO, Na 2 O, K 2 O) based on various multivariate models, with associated precisions. ChemCam also observed H, and the non-metallic elements C, O, P, and S, which are usually difficult to quantify with LIBS. F and Cl are observed through their molecular lines. We discuss the most relevant LIBS lines for detection of minor and trace elements (Li, Rb, Sr, Ba, Cr, Mn, Ni, and Zn). These results were obtained thanks to comprehensive ground reference datasets, which are set to mimic the expected mineralogy and chemistry on Mars. With regard to the first use of LIBS in space, we analyze and quantify, often for the first time, each of the advantages of using stand-off LIBS in space: no sample preparation, analysis within its petrological context, dust removal, sub-millimeter scale investigation, multi-point analysis, the ability to carry out statistical surveys and whole-rock analyses, and rapid data acquisition. We conclude with a discussion of ChemCam performance to survey the geochemistry of Mars, and its valuable support of decisions about selecting where and whether to make observations with more time and resource-intensive tools in the rover's instrument suite. In the end, we present a bird's-eye view of the many scientific results: discovery of felsic Noachian crust, first observation of hydrated soil, discovery of manganese-rich coatings and fracture fills indicating strong oxidation potential in Mars' early atmosphere, characterization of soils by grain size, and wide scale mapping of sedimentary strata, conglomerates, and diagenetic materials.

Journal of Analytical Atomic Spectrometry↗
USGS2020

Improving the ability to include freshwater wetland plants in process-based models

Considerable effort and resources have been placed into conservation programs designed to reduce or alleviate negative environmental effects of crop production and into evaluation of the benefits of these programs. Wetlands are an important source of ecosystem services, but modeling wetland plants is an emerging science. To date, wetland plant growth has not been explicitly accounted for in ecosystem service models that quantify conservation program effects. As part of an effort to more accurately simulate wetland plants within process-based models, we expanded upon plant growth data collected in an earlier effort with additional sampling at two of four previously sampled areas, and included a fifth sampling site. We then used data from the five sites spanning five years as wetland plant parameters at both the species and functional group levels for the Agricultural Land Management Alternative with Numerical Assessment Criteria (ALMANAC) model. In addition to individual species, modelers are interested in functional groups representing a collection of species because it is unrealistic to model every species occurring in an ecosystem. ALMANAC simulations were completed at three sites for both individual wetland plant species and functional groups. At each site, simulated plant yields were within 1 Mg ha –1 (±7%) of measured values ( r 2 = 0.99). Multisite species simulated yields were within 37% of measured values ( r 2 = 0.95). Functional groups performed as well as individual species simulations. Functional group simulated yields were within 1 Mg ha –1 (±5%) of measured yields. Plant growth is a major component of these wetland ecosystems, and ALMANAC verified wetland plant parameters support more accurate assessments of conservation programs and practices on the influence of wetland ecosystems embedded within agricultural fields. The improved plant parameters we provide here will be transferred to other process-based models that focus on other ecosystem components such as soil and water effects, facilitating wetland evaluations across the United States and elsewhere.

California, Delaware, Maryland, North Dakota, Texa↗
USGS2006

Occurrence of antibiotics in wastewater treatment facilities in Wisconsin, USA

Samples from several wastewater treatment facilities in Wisconsin were screened for the presence of 21 antibiotic compounds. These facilities spanned a range of community size served (average daily flow from 0.0212 to 23.6 million gallons/day), secondary treatment processes, geographic locations across the state, and they discharged the treated effluents to both surface and ground waters (for ground water after a soil passage). A total of six antibiotic compounds were detected (1–5 compounds per site), including two sulfonamides (sulfamethazine, sulfamethoxazole), one tetracycline (tetracycline), fluoroquinolone (ciprofloxacin), macrolide (erythromycin-H 2 O) and trimethoprim. The frequency of detection of antibiotics was in the following order: tetracycline and trimethoprim (80%) > sulfamethoxazole (70%) > erythromycin-H 2 O (45%) > ciprofloxacin (40%) > sulfamethazine (10%). However, the soluble concentrations were in the parts-per-billion (ppb) range (≤ 1.3 μg/L), and importantly were unaffected by the size of the wastewater treatment facility. The concentrations detected were within an order of magnitude of those reported for similar systems in Europe and Canada: they were within a factor of two in comparison to those reported for Canada but generally lower relative to those measured in wastewater systems in Europe. Only sulfamethoxazole and tetracycline were detected in groundwater monitoring wells adjacent to the treatment systems. Future intensive wastewater monitoring programs in Wisconsin may be limited to the six antibiotic compounds detected in this study.

Science of the Total Environment↗