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Water-surface elevations for the high tide of December 15, 1977, in the Puget Sound region, Washington

An unusually high oceanic tide on December 15, 1977, caused flooding of lowlying, nearshore parts of western Washington, including several areas in the Puget Sound region. At Seattle, the December 15 high tide of 14.8 feet above MLLW (mean lower low water datum; 8.55 feet above the National Geodetic Vertical Daltum of 1929, or NGVD) was 0.1 foot higher than the 100-year high tide. At Neah Bay, near the western end of the Straits of Juan de Fuca, however, the high tide of 8.77 feet MLLW (4.55 feet NGVD) on that date was 3.2 feet lower than the 100-year high tide. This study has identified the observed December 15 high-tide elevations at many locations in the Puget Sound region. The observed high tide then was much higher than predicted in most of the Puget Sound region, primarily as the result of a very low barametric pressure. Little damage from wind waves was reported. Elevation profiles for the predicted and observed high tides on December 15 and for several other selected tide levels indicate an increase in the maximum height in the inland direction, except near Port Angeles, and show abrupt changes in tidal elevations at three constrictions - Admiralty Inlet, Tacoma Narrows, and Deception Pass. (USGS)

Water-Resources Investigations Report↗

Methods for estimating streamflow at mountain fronts in southern New Mexico

The infiltration of streamflow is potential recharge to alluvial-basin aquifers at or near mountain fronts in southern New Mexico. Data for 13 streamflow-gaging stations were used to determine a relation between mean annual stream- flow and basin and climatic conditions. Regression analysis was used to develop an equation that can be used to estimate mean annual streamflow on the basis of drainage areas and mean annual precipi- tation. The average standard error of estimate for this equation is 46 percent. Regression analysis also was used to develop an equation to estimate mean annual streamflow on the basis of active- channel width. Measurements of the width of active channels were determined for 6 of the 13 gaging stations. The average standard error of estimate for this relation is 29 percent. Stream- flow estimates made using a regression equation based on channel geometry are considered more reliable than estimates made from an equation based on regional relations of basin and climatic conditions. The sample size used to develop these relations was small, however, and the reported standard error of estimate may not represent that of the entire population. Active-channel-width measurements were made at 23 ungaged sites along the Rio Grande upstream from Elephant Butte Reservoir. Data for additional sites would be needed for a more comprehensive assessment of mean annual streamflow in southern New Mexico.

Water-Resources Investigations Report↗

Water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin: Major and trace elements in water, sediment, and biota, 1978-90

The distribution of 22 major and trace elements was examined in water, sediment, and biota in the upper Illinois River Basin in Illinois, Indiana, and Wisconsin as part of a pilot National Water-Quality Assessment project done by the U.S. Geological Survey from 1987 through 1990. The 22 elements are aluminum, antimony, arsenic, barium, beryllium, boron, cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, molybdenum, nickel, phosphorus, selenium, silver, strontium, vanadium, and zinc. Concentrations of U.S. Environmental Protection Agency (USEPA) priority pollutants among the 22 elements were elevated in the Chicago area in all three aquatic components (water, sediment, and biota). Further, some of the priority pollutants also were found at elevated concentrations in biota in agricultural areas in the basin. Cadmium, chromium, copper, iron, lead, mercury, silver, and zinc concentrations in water exceeded USEPA acute or chronic water-quality criteria at several sites in the Chicago area. Correlations among concentrations of elements in water, sediment, and biota were found, but the correlation analysis was hindered by the large proportion of observations less than the minimum reporting level in water. Those sites where water-quality criteria were sometimes exceeded were not always the same sites where concentrations in biota were the largest. This relation indicates that accumulation of these pollutants in biota is confounded by complex geochemical and biological processes that differ throughout the upper Illinois River Basin.

Illinois, Indiana, Wisconsin↗

Factors affecting reservoir and stream-water quality in the Cambridge, Massachusetts, drinking-water source area and implications for source-water protection

This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the city of Cambridge, Massachusetts, Water Department, to assess reservoir and tributary-stream quality in the Cambridge drinking-water source area, and to use the information gained to help guide the design of a comprehensive water-quality monitoring program for the source area. Assessments of the quality and trophic state of the three primary storage reservoirs, Hobbs Brook Reservoir, Stony Brook Reservoir, and Fresh Pond, were conducted (September 1997-November 1998) to provide baseline information on the state of these resources and to determine the vulnerability of the reservoirs to increased loads of nutrients and other contaminants. The effects of land use, land cover, and other drainage-basin characteristics on sources, transport, and fate of fecal-indicator bacteria, highway deicing chemicals, nutrients, selected metals, and naturally occurring organic compounds in 11 subbasins that contribute water to the reservoirs also was investigated, and the data used to select sampling stations for incorporation into a water-quality monitoring network for the source area. All three reservoirs exhibited thermal and chemical stratification, despite artificial mixing by air hoses in Stony Brook Reservoir and Fresh Pond. The stratification produced anoxic or hypoxic conditions in the deepest parts of the reservoirs and these conditions resulted in the release of ammonia nitrogen orthophosphate phosphorus, and dissolved iron and manganese from the reservoir bed sediments. Concentrations of sodium and chloride in the reservoirs usually were higher than the amounts recommended by the U.S. Environmental Protection agency for drinking-water sources (20 milligrams per liter for sodium and 250 milligrams per liter for chloride). Maximum measured sodium concentrations were highest in Hobbs Brook Reservoir (113 milligrams per liter), intermediate in Stony Brook Reservoir (62 milligrams per liter), and lowest in Fresh Pond (54 milligrams per liter). Bed sediments in Hobbs Brook and Stony Brook Reservoirs were enriched in iron, manganese, and arsenic relative to those in the impounded lower Charles River in Boston, Massachusetts. Trophic state indices, calculated for each reservoir based on nutrient concentrations, water-column transparency, and phytoplankton abundances, indicated that the upper and middle basins of Hobbs Brook Reservoir were moderately to highly productive and likely to produce algal blooms; the lower basin of Hobbs Brook Reservoir and Stony Brook Reservoir were similar and intermediate in productivity, and Fresh Pond was relatively unproductive and unlikely to produce algal blooms. This pattern is likely due to sedimentation of organic and inorganic particles in the three basins of Hobbs Brook Reservoir and in Stony Brook Reservoir. Molar ratios of nitrogen to phosphorus ranged from 55 in Stony Brook Reservoir to 120 in Hobbs Brook Reservoir, indicating that phytoplankton algae in these water bodies may be phosphorus limited and therefore sensitive to small increases in phosphorus loading from the drainage basin. Nitrogen loads were found to be less important than phosphorus to the trophic condition of the reservoirs. Hobbs Brook and Stony Brook, the two principle streams draining the Cambridge drinking-water source area, differed in their relative contributions to many of the estimated constituent loads. The estimated load of fecal coliform bacteria was more than seven times larger for the mainly residential Stony Brook subbasin upstream from Kendal Green, Mass., than it was for the more commercial and industrial Hobbs Brook subbasin, though the drainage areas of the two subbasins differ only by about 20 percent. The State standard for fecal coliform bacteria in streams in the Cambridge drinking-water source area (20 colony forming units per 100 milliliters) was exceeded at all sampling stations. Estimated s

Massachusetts↗

Nationwide summary of US Geological Survey regional regression equations for estimating magnitude and frequency of floods for ungaged sites, 1993

For many years, the U.S. Geological Survey (USGS) has been involved in the development of regional regression equations for estimating flood magnitude and frequency at ungaged sites. These regression equations are used to transfer flood characteristics from gaged to ungaged sites through the use of watershed and climatic characteristics as explanatory or predictor variables. Generally these equations have been developed on a statewide or metropolitan area basis as part of cooperative study programs with specific State Departments of Transportation or specific cities. The USGS, in cooperation with the Federal Highway Administration and the Federal Emergency Management Agency, has compiled all the current (as of September 1993) statewide and metropolitan area regression equations into a micro-computer program titled the National Flood Frequency Program.This program includes regression equations for estimating flood-peak discharges and techniques for estimating a typical flood hydrograph for a given recurrence interval peak discharge for unregulated rural and urban watersheds. These techniques should be useful to engineers and hydrologists for planning and design applications. This report summarizes the statewide regression equations for rural watersheds in each State, summarizes the applicable metropolitan area or statewide regression equations for urban watersheds, describes the National Flood Frequency Program for making these computations, and provides much of the reference information on the extrapolation variables needed to run the program.

Water-Resources Investigations Report↗

Estimated public-water supply and industrial-commercial ground-water withdrawals and returns in Nassau County, Long Island, New York, 1973-79

Nassau County, New York depends upon ground water for its freshwater supply. The primary water uses are for public-water supply and industrial-commercial purposes, which together accounted for 202 Mgal/d (million gallons per day) in 1975. Public-water suppliers withdrew 85 percent of their water from the Magothy Formation. About 133 Mgal/d was returned to the ground after use in 1975, and about 69; Mgal/d was discharged to tidewater. In addition, about 34 Mgal/d infiltrated into sewerlines in 1975 and was also discharged to tidewater. Because of the importance of this freshwater supply, the New York State Department of Environmental conservation reviews applications for the installation of wells and compiles data on pumpage throughout Long Island. It also reviews applications to discharge wastewater into the surface water and ground water of the State. This report summarizes the data filed with the New York State Department of Environmental Conservation for Nassau County during 1973-79. It presents data and estimates on withdrawals for public and industrial-commercial supply, returns to the ground, and discharges through sewer systems. It also includes information on population and land use.

New York↗

Ground-water age, flow, and quality near a landfill, and changes in ground-water conditions from 1976 to 1996 in the Swinomish Indian Reservation, northwestern Washington

This report describes the results of two related studies: a study of ground-water age, flow, and quality near a landfill in the south-central part of the Swinomish Indian Reservation; and a study of changes in ground-water conditions for the entire reservation from 1976 to 1996. The Swinomish Indian Reservation is a 17-square-mile part of Fidalgo Island in northwestern Washington. The groundwater flow system in the reservation is probably independent of other flow systems in the area because it is almost completely surrounded by salt water. There has been increasing stress on the ground-water resources of the reservation because the population has almost tripled during the past 20 years, and 65 percent of the population obtain their domestic water supply from the local ground-water system. The Swinomish Tribe is concerned that increased pumping of ground water might have caused decreased ground-water discharge into streams, declines in ground-water levels, and seawater intrusion into the ground-water system. There is also concern that leachate from an inactive landfill containing mostly household and wood-processing wastes may be contaminating the ground water. The study area is underlain by unconsolidated glacial and interglacial deposits of Quaternary age that range from about 300 to 900 feet thick. Five hydrogeologic units have been defined in the unconsolidated deposits. From top to bottom, the hydrogeologic units are a till confining bed, an outwash aquifer, a clay confining bed, a sea-level aquifer, and an undifferentiated unit. The ground-water flow system of the reservation is similar to other island-type flow systems. Water enters the system through the water table as infiltration and percolation of precipitation (recharge), then the water flows downward and radially outward from the center of the island. At the outside edges of the system, ground water flows upward to discharge into the surrounding saltwater bodies. Average annual recharge is estimated to be about 3 inches, or 12 percent of the average annual precipitation. Ground water in the outwash aquifer near the landfill is estimated to be between 15 and 43 years old. Some deeper ground waters and ground water near the discharge areas close to the shoreline are older than 43 years. Analysis of water-quality data collected for this study and review of existing data indicate that material in the landfill has had no appreciable impact on the current quality of ground water outside of the landfill. The water quality of samples from seven wells near to and downgradient from the landfill appears to be similar to the ground-water quality throughout the entire study area. The high iron and manganese concentrations found in most of the samples from wells near the landfill are probably within the range of natural concentrations for the study area. Ground-water pumping during the past 20 years has not caused any large changes in ground-water discharge to streams, ground-water levels, or seawater intrusion into the ground-water system. Ground-water discharge into Snee-oosh Creek and Munks Creek had similar magnitudes in the summers of 1976 and 1996; flows in both creeks during those summers ranged from 0.07 t 0.15 cubic feet per second. Ground-water levels changed minimally between 1976 and 1996. The average water-level change for 20 wells with more than 10 years between measurements was -0.7 feet and the two largest waterlevel declines were 6 and 9 feet. No appreciable seawater intrusion was found in the ground water in 1996, and there was no significant increase in the extent of seawater intrusion from 1976 to 1996. Median chloride concentrations of water samples collected from wells were 22 milligrams per liter in 1976 and 18 milligrams per liter in 1996.

Washington↗

Ground-water withdrawals, water levels, and ground-water quality in the Houston district, Texas, with emphasis on 1985-89

This report is one in a series of reports prepared by the U.S. Geological Survey, beginning in 1937, on the ground-water resources in the Houston district. The Houston district includes Harris and Galveston Counties, and parts of Brazoria, Fort Bend, Waller, Montgomery, Liberty, and Chambers Counties. The primary emphasis of this report includes ground-water resources information for the district from 1985-89. Some data collected before 1985 and in early 1990 are included to present long-term trends and relations. Ground-water withdrawal in the Houston district decreased from 451 to 419 Mgal/d (million gallons per day) between 1985 and 1989. Public supply used 77 percent of the ground water withdrawn in the district in 1985. From 1985 through 1989, withdrawals for public supply decreased from 349 to 338 Mgal/d, withdrawals for industrial use decreased from 37 to 32 Mgal/d, and withdrawals for irrigation use decreased from 65 to 49 Mgal/d. From 1985 through 1989, ground-water withdrawals decreased from about 197.9 Mgal/d to about 166.9 Mgal/d in the Houston area and increased from about 179.5 Mgal/d to about 180.8 Mgal/d in the Katy area, and remained constant at about 67 Mgal/d in the rest of Harris County. Galveston County ground-water withdrawal decreased from about 6.1 to 4.0 Mgal/d during 1985-89. During 1977-90, water levels in wells completed in the Chicot aquifer in the eastern part of the Houston district rose as much as 160 ft (feet) and declined as much as 80 ft in the western part. During 1985-90, water levels in wells completed in the Chicot aquifer in the western part of the Houston district rose as much as 140 ft, and declined as much as 40 ft in the western part. During 1977-90, water levels in wells completed in the Evangeline aquifer in the southeastern part of the Houston district rose as much as 140 ft and declined as much as 200 ft in the northwestern part. During 1985-90, water levels in wells completed in the Evangeline aquifer in the eastern part of the Houston district rose as much as 40 ft, and declined as much as 140 ft in the northern part. Dissolved-chloride concentrations in water from wells in the Houston district have not changed more than 100 mg/L during 1985-89, except for a decrease at one well in the eastern part of Galveston County. Well KH-65-48-316 yielded water with dissolved-chloride concentration decreasing from 720 mg/L in 1986 to 590 mg/L in 1989.

Texas↗

Index to water-quality data available from the U.S. Geological Survey in machine-readable form to December 31, 1972; Northeastern region

This report lists water quality stations operated by the U.S. Geological Survey for which data are available in machine-readable form. The data are the results of analyses of water samples and indicate the chemical and physical characteristics of surface and ground water. Samples of surface water were collected at designated sites at predetermined intervals such as once daily, weekly, monthly, or less frequently. Samples of ground water were collected from wells infrequently and on an irregular basis.

Water-Resources Investigations Report↗

Water budget and hydraulic aspects of artificial recharge, south coast of Puerto Rico

An analog model was used to evaluate ground-water conditions on the south coast of Puerto Rico. Water levels during a normal period and during an extended drought were simulated. Recharge and discharge values are reported. The model was also used to evaluate the possibilities of using treated waste water to recharge the aquifer. Three methods were considered: infiltration basins, injection, and irrigation. The tests were planned to determine what changes in water levels would result if certain rates of application were used. Because of the limited vertical hydraulic conductivity, irrigation is suggested as the most practical method of waste-water use. (Woodard-USGS)

Puerto Rico↗

Water-quality assessment of the Albermarle-Pamlico drainage basin, North Carolina and Virginia— A summary of selected trace element, nutrient, and pesticide data for bed sediments, 1969-90

Spatial distributions of metals and trace elements, nutrients, and pesticides and polychiorinated biphenyls (PCB's) in bed sediment were characterized using data collected from 1969 through 1990 and stored in the U.S. Geological Survey's National Water Data Storage and Retrieval (WATSTORE) system and the U.S. Environmental Protection Agency's Storage and Retrieval (STORET) system databases. Bed-sediment data from WATSTORE and STORET were combined to form a single database of 1,049 records representing 301 sites. Data were examined for concentrations of 16 metals and trace elements, 4 nutrients, 10 pesticides, and PCB's. Maximum bed-sediment concentrations were evaluated relative to sediment-quality guidelines developed by the National Oceanic and Atmospheric Administration, the Ontario Ministry of Environment and Energy, and the Virginia Department of Environmental Quality. Sites were not selected randomly; therefore, results should not be interpreted as representing average conditions. Many sites were located in or around lakes and reservoirs, urban areas, and areas where special investigations were conducted. Lakes and reservoirs function as effective sediment traps, and elevated concentrations of some constituents occurred at these sites. High concentrations of many metals and trace elements also occurred near urban areas where streams receive runoff or inputs from industrial, residential, and municipal activities. Elevated nutrient concentrations occurred near lakes, reservoirs, and the mouths of major rivers. The highest concentrations of arsenic, beryllium, chromium, iron. mercury, nickel, and selenium occurred in the Roanoke River Basin and may be a result of geologic formations or accumulations of bed sediment in lakes and reservoirs. The highest concentrations of cadmium, lead, and thallium were detected in the Chowan River Basin; copper and zinc were reported highest in the Neuse River Basin. Total phosphorus and total ammonia plus organic nitrogen concentrations exceeded the sediment evaluation guidelines in each major river basin, possibly resulting from wastewater inputs and agricultural applications. Exceedances of pesticide guidelines were detected in the upper Neuse River Basin near Falls Lake and in the lower Tar River Basin.

North Carolina, Virginia↗

River and Reservoir Operations Model, Truckee River basin, California and Nevada, 1998

The demand for all uses of water in the Truckee River Basin, California and Nevada, commonly is greater than can be supplied. Storage reservoirs in the system have a maximum effective total capacity equivalent to less than two years of average river flows, so longer-term droughts can result in substantial water-supply shortages for irrigation and municipal users and may stress fish and wildlife ecosystems. Title II of Public Law (P.L.) 101-618, the Truckee?Carson?Pyramid Lake Water Rights Settlement Act of 1990, provides a foundation for negotiating and developing operating criteria, known as the Truckee River Operating Agreement (TROA), to balance interstate and interbasin allocation of water rights among the many interests competing for water from the Truckee River. In addition to TROA, the Truckee River Water Quality Settlement Agreement (WQSA), signed in 1996, provides for acquisition of water rights to resolve water-quality problems during low flows along the Truckee River in Nevada. Efficient execution of many of the planning, management, or environmental assessment requirements of TROA and WQSA will require detailed water-resources data coupled with sound analytical tools. Analytical modeling tools constructed and evaluated with such data could help assess effects of alternative operational scenarios related to reservoir and river operations, water-rights transfers, and changes in irrigation practices. The Truckee?Carson Program of the U.S. Geological Survey, to support U.S. Department of the Interior implementation of P.L. 101-618, is developing a modeling system to support efficient water-resources planning, management, and allocation. The daily operations model documented herein is a part of the modeling system that includes a database management program, a graphical user interface program, and a program with modules that simulate river/reservoir operations and a variety of hydrologic processes. The operations module is capable of simulating lake/ reservoir and river operations including diversion of Truckee River water to the Truckee Canal for transport to the Carson River Basin. In addition to the operations and streamflow-routing modules, the modeling system is structured to allow integration of other modules, such as water-quality and precipitation-runoff modules. The USGS Truckee River Basin operations model was designed to provide simulations that allow comparison of the effects of alternative management practices or allocations on streamflow or reservoir storages in the Truckee River Basin over long periods of time. Because the model was not intended to reproduce historical streamflow or reservoir storage values, a traditional calibration that includes statistical comparisons of observed and simulated values would be problematic with this model and database. This report describes a chronology and background of decrees, agreements, and laws that affect Truckee River operational practices; the construction of the Truckee River daily operations model; the simulation of Truckee River Basin operations, both current and proposed under the draft TROA and WQSA; and suggested model improvements and limitations. The daily operations model uses Hydrological Simulation Program?FORTRAN (HSPF) to simulate flow-routing and reservoir and river operations. The operations model simulates reservoir and river operations that govern streamflow in the Truckee River from Lake Tahoe to Pyramid Lake, including diversions through the Truckee Canal to Lahontan Reservoir in the Carson River Basin. A general overview is provided of daily operations and their simulation. Supplemental information that documents the extremely complex operating rules simulated by the model is available.

Water-Resources Investigations Report↗

Concentration of selected sulfonylurea, sulfonamide, and imidazolinone herbicides, other pesticides, and nutrients in 71 streams, 5 reservoir outflows, and 25 wells in the Midwestern United States, 1998

Sulfonylurea (SU), sulfonamide (SA), and imidazolinone (IMI) herbicides are recently developed herbicides that function by inhibiting the action of a key plant enzyme, stopping plant growth, and eventually killing the plant. These compounds generally have low mammalian toxicity, but crop and non-crop plants demonstrate a wide range in sensitivity to SUs, SAs, and IMIs, with over a 10,000-fold difference in observed toxicity levels for some compounds. SUs, SAs, and IMIs are applied either pre- or post-emergence to crops commonly at 1/50th or less of the rate of other herbicides. Little is known about their occurrence, fate, or transport in surface water or ground water in the United States. To obtain information on the occurrence of SU, SA, and IMI herbicides in the Midwestern United States, 214 water samples were collected from 76 surface-water and 25 ground-water sites in 1998. These samples were analyzed for 16 SU, SA, and IMI herbicides by using highperformance liquid chromatography/mass spectrometry. Samples also were analyzed for 46 pesticides and pesticide degradation products and 13 herbicides and 10 herbicide degradates. At least 1 of the 16 SUs, SAs, or IMIs was detected at or above the method reporting limit of 0.010 microgram per liter (ug/L) in 83 percent of 133 stream samples. Imazethapyr was detected most frequently (69 percent of samples), followed by flumetsulam (65 percent of samples) and nicosulfuron (53 percent of samples). At least one SU, SA, or IMI herbicide was detected at or above the method reporting limit in 6 of 8 reservoir samples and 5 of 25 ground-water samples. SU, SA, and IMI herbicides occurred less frequently and at a fraction (often 1/50th or less) of the concentrations of other herbicides such as atrazine. Acetochlor, atrazine, cyanazine, and metolachlor were all detected in 95 percent or more of 136 stream samples.

Water-Resources Investigations Report↗

Partial compilation and revision of basic data in the WATEQ programs

Several portions of the basic data in the WATEQ series of computer programs (WATEQ, WATEQF, WATEQ2, WATEQ3, and PHREEQE) are compiled. The density and dielectric constant of water and their temperature dependence are evaluated for the purpose of updating the Debye-Huckel solvent parameters in the activity coefficient equations. The standard state thermodynamic properties of the Fe2+ and Fe3+ aqueous ions are refined. The main portion of this report is a comprehensive listing of aluminum hydrolysis constants, aluminum fluoride, aluminum sulfate, calcium chloride, magnesium chloride, potassium sulfate and sodium sulfate stability constants, solubility product constants for gibbsite and amorphous aluminum hydroxide, and the standard electrode potentials for Fe (s)/Fe2+(aq) and Fe2 +(aq)/Fe3+(aq). (USGS)

Water-Resources Investigations Report↗

Estimation of Median Streamflows at Perennial Stream Sites in Hawaii

The most accurate estimates of median streamflows at perennial stream sites in Hawaii are those made at streamflow-gaging stations. Two alternative methods for estimating median streamflows at ungaged sites are described in this report. Multiple-regression equations were developed for estimating median streamflows at ungaged, unregulated, perennial stream sites. The equations relate combinations of drainage area, mean altitude of the main stream channel, and mean annual precipitation to median streamflow. Streamflow data from 56 long-term continuous-record gaging stations were used in the analysis. Median-streamflow data for all 56 sites were adjusted using record-extension techniques to reflect base period (1912 through 1986) conditions. Hawaii was subdivided into two geographic groups and multiple-regression equations were developed for each. The standard error of predication for the equation developed for the first group, the islands of Oahu, Molokai, and Hawaii, is 41 percent. The standard error of predication for the equation developed for the second group, the islands of Kauai and Maui, is 54 percent. A method for estimating median-streamflow, based on discharge measurements and data from nearby streamflow-gaging stations, was also developed for 27 regulated, perennial windward Oahu sites. Standard errors of prediction for 23 of the sites range from 5 to 34 percent. Median-streamflow estimates for the four remaining sites were considered poor and no measures of accuracy are provided. Discharge measurements can be used to make estimates of median streamflows at ungaged, regulated sites where the regression equations developed in this report are not applicable. Discharge measurements can also be used to make estimates of median streamflows at ungaged, unregulated sites. Estimates of median streamflows based on discharge measurements have greater standard errors than estimates based on continuous streamflow records and in general have smaller standard errors than estimates based on regression equations.

Water-Resources Investigations Report↗

Surface-water and suspended-sediment inflow and outflow for Nutria Reservoir No. 3, Zuni Indian Reservation, New Mexico, March 1994 to September 1995

Surface-water and suspended-sediment inflow to and outflow from Nutria Reservoir No. 3 on the Zuni Indian Reservation, western New Mexico, were calculated. The period of study was March 3, 1994, to September 30, 1995. Total runoff into Nutria Reservoir No. 3 during the study period was 6,812 acre-feet. During the study period, 24,310 tons of suspended sediment was transported into Nutria Reservoir No. 3, and 259 tons of suspended sediment was transported out of Nutria Reservoir No. 3. Runoff during the study period, recorded at an upstream gage with 25 years of record, was 137 percent higher than that for a 19-month period similar to the study period. This may indicate that suspended-sediment loads transported into Nutria Reservoir No. 3 also were larger than average. Based on the difference between inflow and outflow of suspended sediment, 24,050 tons of suspended sediment was deposited in Nutria Reservoir No. 3. From March 1994 to May 1994 the spillway elevation of Nutria Reservoir No. 3 was raised to allow water to be diverted into an adjacent reservoir, Nutria Reservoir No. 4. This flow and sediment transported into Nutria Reservoir No. 4 were not recorded. If the elevation of the spillway had not been raised, suspended- sediment loads recorded downstream from Nutria Reservoir No. 3 would have been larger and the calculated amount of sediment deposited in Nutria Reservoir would have been smaller. Of the total suspended-sediment load entering Nutria Reservoir No. 3 during the study period, 94 percent was transported by an arroyo, Garcia Draw. Garcia Draw drains only 15 percent of the total drainage area of Nutria Reservoir No. 3 and contributed less than 5 percent of the total surface runoff to the reservoir. The average annual amount of sediment deposited in Nutria Reservoir No. 3 during the study was 15,355 tons. By using a dry-weight density of 99.4 pounds per cubic foot for the deposited sediment, the annual volume of sediment deposited in Nutria Reservoir No. 3 is 7.09 acre-feet per year. This number is smaller than the previously reported sedimentation rate of 15.0 acre-feet per year obtained from past surveys. The capacity of Nutria Reservoir No. 3 in 1993 was 191 acre-feet. By using the calculated average sedimentation rate of 7.09 acre-feet per year, Nutria Reservoir No. 3 could be completely filled approximately 27 years after the 1993 survey.

New Mexico↗

Users manual for an expert system (HSPEXP) for calibration of the hydrological simulation program; Fortran

Expert system software was developed to assist less experienced modelers with calibration of a watershed model and to facilitate the interaction between the modeler and the modeling process not provided by mathematical optimization. A prototype was developed with artificial intelligence software tools, a knowledge engineer, and two domain experts. The manual procedures used by the domain experts were identified and the prototype was then coded by the knowledge engineer. The expert system consists of a set of hierarchical rules designed to guide the calibration of the model through a systematic evaluation of model parameters. When the prototype was completed and tested, it was rewritten for portability and operational use and was named HSPEXP. The watershed model Hydrological Simulation Program--Fortran (HSPF) is used in the expert system. This report is the users manual for HSPEXP and contains a discussion of the concepts and detailed steps and examples for using the software. The system has been tested on watersheds in the States of Washington and Maryland, and the system correctly identified the model parameters to be adjusted and the adjustments led to improved calibration.

Water-Resources Investigations Report↗

Ground-water quality, water year 1995, and statistical analysis of ground-water-quality data, water years 1994-95, at the chromic acid pit site, U.S. Army Air Defense Artillery Center and Fort Bliss, El Paso, Texas

The Chromic Acid Pit site is an inactive waste disposal site that is regulated by the Resource Conservation and Recovery Act of 1976. The 2.2-cubic-yard cement-lined pit was operated from 1980 to 1983 by a contractor to the U.S. Army Air Defense Artillery Center and Fort Bliss. The pit, located on the Fort Bliss military reservation in El Paso, Texas, was used for disposal and evaporation of chromic acid waste generated from chrome plating operations. The site was closed in 1989, and the Texas Natural Resources Conservation Commission issued permit number HW-50296 (U.S. Environmental Protection Agency number TX4213720101), which approved and implemented post-closure care for the Chromic Acid Pit site. In accordance with an approved post-closure plan, the U.S. Geological Survey is cooperating with the U.S. Army in monitoring and evaluating ground-water quality at the site. One upgradient ground-water monitoring well (MW1) and two downgradient ground-water monitoring wells (MW2 and MW3), installed adjacent to the chromic acid pit, are monitored on a quarterly basis. Ground-water sampling of these wells by the U.S. Geological Survey began in December 1993. The ground-water level, measured in a production well located approximately 1,700 feet southeast of the Chromic Acid Pit site, has declined about 29.43 feet from 1982 to 1995. Depth to water at the Chromic Acid Pit site in September 1995 was 284.2 to 286.5 feet below land surface; ground-water flow at the water table is assumed to be toward the southeast. Ground-water samples collected from monitoring wells at the Chromic Acid Pit site during water year 1995 contained dissolved- solids concentrations of 481 to 516 milligrams per liter. Total chromium concentrations detected above the laboratory reporting limit ranged from 0.0061 to 0.030 milligram per liter; dissolved chromium concentrations ranged from 0.0040 to 0.010 milligram per liter. Nitrate as nitrogen concentrations ranged from 2.1 to 2.8 milligrams per liter; nitrite plus nitrate as nitrogen concentrations ranged from 2.4 to 3.2 milligrams per liter. Water samples from wells MW1 and MW2 were analyzed for volatile organic compounds for the first quarter; no confirmed volatile organic compounds were detected above laboratory reporting limits. Detected chemical concentrations in water from the chromic acid pit monitoring wells during the four sampling periods were below U.S. Environmental Protection Agency-established maximum contaminant levels for public drinking-water supplies. Overall, water-quality characteristics of water from the chromic acid pit ground-water monitoring wells are similar to those of other wells in the surrounding area. Statistical analyses were performed on 56 of the chemical constituents analyzed for in ground water from the chromic acid pit monitoring wells. Concentrations of chloride, fluoride, sulfate, and potassium were significantly less in water from one or both downgradient wells than in water from the upgradient well. Concentrations of nitrate as nitrogen, nitrite plus nitrate as nitrogen, and dissolved solids were significantly greater in water from the downgradient wells than in water from the upgradient well. Concentrations of nitrate as nitrogen, chloride, and potassium were significantly different in water from the two downgradient wells. Statistical analysis of chemical constituents in water from the chromic acid pit monitoring wells did not appear to indicate a release of hazardous chemicals from the chromic acid pit. There was no indication of ground-water contamination in either downgradient well.

Texas↗